WO2012161602A1 - Binary agent for the modification of polyurethane materials - Google Patents

Binary agent for the modification of polyurethane materials Download PDF

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Publication number
WO2012161602A1
WO2012161602A1 PCT/PL2012/000032 PL2012000032W WO2012161602A1 WO 2012161602 A1 WO2012161602 A1 WO 2012161602A1 PL 2012000032 W PL2012000032 W PL 2012000032W WO 2012161602 A1 WO2012161602 A1 WO 2012161602A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
polyurethane
polyurethane materials
modification
materials
Prior art date
Application number
PCT/PL2012/000032
Other languages
French (fr)
Inventor
Dariusz Stachura
Wiesław ΖΑDĘCΚΙ
Witold Rams
Original Assignee
Termo Organika Sp. Z O. O.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Termo Organika Sp. Z O. O. filed Critical Termo Organika Sp. Z O. O.
Priority to EP12726914.0A priority Critical patent/EP2710048A1/en
Publication of WO2012161602A1 publication Critical patent/WO2012161602A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3893—Low-molecular-weight compounds having heteroatoms other than oxygen containing silicon
    • C08G18/3895—Inorganic compounds, e.g. aqueous alkalimetalsilicate solutions; Organic derivatives thereof containing no direct silicon-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic

Definitions

  • the present invention relates to a binary agent for the modification of polyurethane materials, in particular as regards controlled forming of the porosity and structure of polyurethane materials, reducing fire threats and improving the physico-chemical properties of the final polyurethane material modified with such an agent.
  • Polyurethanes are polymers with a very wide range of applications in many branches of industry. Depending on the method of their production and the technological additives, they are used to produce clothing laminates, protective coatings, lacquer paints, glues as well as widely applied rigid or elastic foams. Polyurethanes are characterised by elasticity of closed and open pores and mechanical resistance to fire threats.
  • the main two groups of polyurethanes are polyurethanes with the names: PUR and PIR which are mixtures of polyols with the appropriate cross-linking additives.
  • Polyisocyanurates belong to the polyurethane group.
  • PUR polyurethane
  • polyisocyanurate foams The difference between typical polyurethane (PUR) and polyisocyanurate foams is that the proportion of isocyanates in the production of PIR is decisively higher than in PUR and, as a result, material with better mechanical and thermal insulation properties is obtained.
  • the most important characteristics to distinguish between PIR and PUR materials is a much higher temperature resistance and reduced flammability.
  • Typical polyurethanes undergo thermal decomposition at the temperature of 200°C, whilst in polyisocyanurates this temperature is 300°C,
  • Polyurethane foams are polyurethane materials with a very wide range of applications.
  • the main classification of foams is their division into elastic and rigid ones.
  • Elastic foams are applied for example in the textile industry, whilst rigid foams are used in the production of furniture, and in the automotive, aircraft and construction industries.
  • rigid foams especially the ones used in construction as thermal insulation materials, one of their important characteristics which has an effect on their mechaniuai properties is i. a. ineir porosity.
  • the quality of the pores (open, closed), their number in a unit of volume, and the method of their manufacture, as well as technological additives have a major impact in the final product.
  • Korean patent application WO0901 1533A1 presents adiabatic material which comprises expanded perlite and polyurethane, and the method of obtaining them as well as construction materials containing adiabatic material.
  • the material according to the invention contains expanded perlite particles with a definite diameter and expanded perlite with such an average particle diameter as to fill in the gaps between the perlite particles with the definite particle diameter, as well as a single-component water-expandable urethane binder.
  • the adiabatic material according to the invention is light, has perfect adiabatic properties, is fire resistant and holds back the spreading of flames.
  • thermosetting foams preferably polyisocyanurate or polyurethane ones, obtained through extrusion, which enables the application of a large filler quantity.
  • the method of obtaining the material comprises the introduction of polyol, isocyanate and filler particles in an extruder and mixing them.
  • a catalyser is added while the components are being integrated in the extruder.
  • the catalyser may be added also in the last barrel of the extruder or in its head.
  • the foam with the filler content of more than 12% is easy to obtain.
  • the filler may be: aluminum trihydrate, perlite, carbon black, diatomite, ammonium phosphate, fly ashes, calcium silicate, calcium carbonate.
  • the method according to the invention is appneu iu uuiain iuam boards.
  • the subject of examination was therefore a binary agent for controlled forming of the porosity and structure of polyurethane materials which would make it possible to obtain PUR and PIR foams with the required physico-chemical properties and would thus enable controlled production of materials with the required pore parameters, such as quality (open, closed) and quantity and, simultaneously, the materials obtained would meet the environmental quality requirements, particularly where chemical compounds are released in high temperature.
  • the aim of the invention is to provide a binary agent for the modification of polyurethane materials, particularly as regards controlled forming of the porosity and structure of polyurethane materials which would make it possible to obtain polyurethane materials with very good thermal insulation properties, and especially high resistance to moisture penetration, with considerable thermal resistance and increased fire resistance.
  • the nature of the invention is therefore a binary agent for the modification of polyurethane materials, characterised in that it consists of a liquid component containing potassium hydrate of between 2 and 65 % by weight, potassium silicate of between 1 .8 to 29.8 % by weight, water of 5.5 % by weight and a solid component in the form of expanded perlite of between 0.1 and 45 % by weight.
  • the perlite grain size is between 0.3 and 12.0 mm.
  • the operation of potassium silicate in water environment containihy uiassium nyui cne, uy regulating the porosity of the polyurethane mass, causes linear development of polymerization with parallel formation of microsphere nuclei containing inert gas.
  • a derivative of the transformations as described is also the unexpected additive building in of silicate polymers and sub-polymers (of potassium silicate) into the formed structure of the polyurethane polymer.
  • Controlled forming of the porosity and structure of polyurethane materials with the use of the binary agent as a modifier according to the invention is effected through reactions and conversions with isocyanates during egzothermic transformations. It was unexpectedly found that the increase in electrical conductivity caused by the alkaline environment results in the homogenization of the components and an even distribution of the gaseous phase.
  • the application of the solid component in the form of expanded perlite with the appropriate grain size of the binary agent according to the invention enables the adsorption and absorption of water released from this component with a delay, which is advantageous for the kinetics of the reaction and the ultimate structure of the polyurethane material.
  • the mixing arm is set to motion and, after approx. 5 minutes, ca. 3.3 kg of a liquid component of the binary agent according to the invention is obtained which is ready to be used together with perlite - the solid component - in the quantity of 0.8 kg and with the grain size of 0.5 mm. Both components are prepared independently, stoi
  • a liquid component with the following composition is introduced in a vessel with a mixing arm:
  • the mixing arm is set to motion and, after approx. 5 minutes, a mixture is obtained which, in the quantity of 1.8 % by weight, is introduced in the polyol (PUR), and then, all material is mixed for 2 minutes and, while mixing continuously, the quantity of 2.1 % by weight of the solid component in the form of perlite with the grain size of 1 .8 mm is introduced in the mixture, and then, all material is mixed for 1.5 minutes and the masterbatch is treated with isocyanate of 105% by weight.
  • PUR polyol
  • the quantities of the liquid component, the solid component and of the isocyanate are calculated with relation to the quantity of the polyol.
  • a liquid component with the following composition is introduced in a vessel with a mixing arm:
  • the mixing arm is set to motion and, after approx. 5 minutes, a mixture is obtained which is introduced, in the quantity of 1.9 % by weight, in the polyol (PIR), then all material is mixed for 2 minutes, and wuue i niAn iy uununuuusiy, the quantity of 2.9 % by weight of perlite with the grain size of 0.5 mm is introduced in the mixture, and then, all material is mixed for 1 .5 minutes and the masterbatch is treated with isocyanate in the quantity of 160% by weight.
  • PIR polyol
  • the quantity of the liquid component, the solid component and of the isocyanate is calculated with relation to the quantity of the polyol.
  • Reaction time 3.0 min.
  • the introduction of the solid component in the form of perlite with the required grain size into the liquid component mixed with polyol enables more effective homogenisation of the polyol with the liquid component and does not have an effect on distorting the quantitative proportions between the different components of the agent according to the invention.
  • Polyurethane materials modified with the binary agent according to the invention demonstrate advantageous geometrical distribution of pores.
  • the application of the binary agent for the modification of polyurethane materials according to the invention enables regulation of the structure of the pores (open, closed) and a reduction of the material's density, and has an effect on the elasticity of the material, its resistance parameters, thermal resistance and vibroacoustic properties.

Abstract

The subject of the invention is a binary agent for the modification of polyurethane materials, characterised by that it comprises a liquid component containing potassium hydroxide of between 2 and 65 % by weight, potassium silicate of between 1.8 and 29.8 % by weight, water of between 5.5 % by weight and a solid component in the form of expanded perlite of between 0.1 and 45 % by weight.

Description

BINARY AGENT FOR THE MODIFICATION OF POLYURETHANE MATERIALS
The present invention relates to a binary agent for the modification of polyurethane materials, in particular as regards controlled forming of the porosity and structure of polyurethane materials, reducing fire threats and improving the physico-chemical properties of the final polyurethane material modified with such an agent. Polyurethanes are polymers with a very wide range of applications in many branches of industry. Depending on the method of their production and the technological additives, they are used to produce clothing laminates, protective coatings, lacquer paints, glues as well as widely applied rigid or elastic foams. Polyurethanes are characterised by elasticity of closed and open pores and mechanical resistance to fire threats. The main two groups of polyurethanes are polyurethanes with the names: PUR and PIR which are mixtures of polyols with the appropriate cross-linking additives.
Polyisocyanurates (PIR) belong to the polyurethane group. The difference between typical polyurethane (PUR) and polyisocyanurate foams is that the proportion of isocyanates in the production of PIR is decisively higher than in PUR and, as a result, material with better mechanical and thermal insulation properties is obtained. However, the most important characteristics to distinguish between PIR and PUR materials is a much higher temperature resistance and reduced flammability. Typical polyurethanes undergo thermal decomposition at the temperature of 200°C, whilst in polyisocyanurates this temperature is 300°C,
Polyurethane foams are polyurethane materials with a very wide range of applications. The main classification of foams is their division into elastic and rigid ones. Elastic foams are applied for example in the textile industry, whilst rigid foams are used in the production of furniture, and in the automotive, aircraft and construction industries. As regards rigid foams, especially the ones used in construction as thermal insulation materials, one of their important characteristics which has an effect on their mechaniuai properties is i. a. ineir porosity. The quality of the pores (open, closed), their number in a unit of volume, and the method of their manufacture, as well as technological additives have a major impact in the final product.
The requirements for the composition and properties of polyurethane and polyisocyanurate materials especially in view of the impact of the additives on the natural environment get stricter together with the increase in the quantity and scope of application of materials of this type, hence, there is a need to replace existing technological additives such as expanding agents, plasticizers, fillers, etc. with substances which would provide the material with the required mechanical and insulation properties and which, at the same time, would be neutral to the natural environment during use, and also in their thermal decomposition.
Korean patent application WO0901 1533A1 presents adiabatic material which comprises expanded perlite and polyurethane, and the method of obtaining them as well as construction materials containing adiabatic material. The material according to the invention contains expanded perlite particles with a definite diameter and expanded perlite with such an average particle diameter as to fill in the gaps between the perlite particles with the definite particle diameter, as well as a single-component water-expandable urethane binder. The adiabatic material according to the invention is light, has perfect adiabatic properties, is fire resistant and holds back the spreading of flames.
US patent application US RE37095 (E1 ) presents thermosetting foams, preferably polyisocyanurate or polyurethane ones, obtained through extrusion, which enables the application of a large filler quantity. The method of obtaining the material comprises the introduction of polyol, isocyanate and filler particles in an extruder and mixing them. A catalyser is added while the components are being integrated in the extruder. The catalyser may be added also in the last barrel of the extruder or in its head. The foam with the filler content of more than 12% is easy to obtain. The filler may be: aluminum trihydrate, perlite, carbon black, diatomite, ammonium phosphate, fly ashes, calcium silicate, calcium carbonate. The method according to the invention is appneu iu uuiain iuam boards.
The subject of examination was therefore a binary agent for controlled forming of the porosity and structure of polyurethane materials which would make it possible to obtain PUR and PIR foams with the required physico-chemical properties and would thus enable controlled production of materials with the required pore parameters, such as quality (open, closed) and quantity and, simultaneously, the materials obtained would meet the environmental quality requirements, particularly where chemical compounds are released in high temperature.
The aim of the invention is to provide a binary agent for the modification of polyurethane materials, particularly as regards controlled forming of the porosity and structure of polyurethane materials which would make it possible to obtain polyurethane materials with very good thermal insulation properties, and especially high resistance to moisture penetration, with considerable thermal resistance and increased fire resistance. The nature of the invention is therefore a binary agent for the modification of polyurethane materials, characterised in that it consists of a liquid component containing potassium hydrate of between 2 and 65 % by weight, potassium silicate of between 1 .8 to 29.8 % by weight, water of 5.5 % by weight and a solid component in the form of expanded perlite of between 0.1 and 45 % by weight.
Preferably, according to the invention, the perlite grain size is between 0.3 and 12.0 mm. During laboratory tests on the production of polyurethane materials using the well-known method, with the use of the binary agent according to the invention, and on the production of said materials for semi-technological and technological scale with the application of the binary agent according to the invention, it was unexpectedly found that it was unexpectedly found that the operation of potassium silicate in water environment containihy uiassium nyui cne, uy regulating the porosity of the polyurethane mass, causes linear development of polymerization with parallel formation of microsphere nuclei containing inert gas.
A derivative of the transformations as described is also the unexpected additive building in of silicate polymers and sub-polymers (of potassium silicate) into the formed structure of the polyurethane polymer.
Controlled forming of the porosity and structure of polyurethane materials with the use of the binary agent as a modifier according to the invention is effected through reactions and conversions with isocyanates during egzothermic transformations. It was unexpectedly found that the increase in electrical conductivity caused by the alkaline environment results in the homogenization of the components and an even distribution of the gaseous phase.
The application of the solid component in the form of expanded perlite with the appropriate grain size of the binary agent according to the invention enables the adsorption and absorption of water released from this component with a delay, which is advantageous for the kinetics of the reaction and the ultimate structure of the polyurethane material.
The modifier according to the invention is presented in more detail in preferable examples of its production which, however, do not restrict its scope. Example 1
The following are introduced in a vessel with a mixing arm:
potassium hydroxide of 2.5 kg
potassium silicate of 0.2 kg
water of 0.6 kg.
Then, the mixing arm is set to motion and, after approx. 5 minutes, ca. 3.3 kg of a liquid component of the binary agent according to the invention is obtained which is ready to be used together with perlite - the solid component - in the quantity of 0.8 kg and with the grain size of 0.5 mm. Both components are prepared independently, stoi
and added at different stages of obtaining the modified polyurethanes.
Example 2
A stationary example of obtaining PUR polyurethanes modified with the binary agent according to the invention.
A liquid component with the following composition is introduced in a vessel with a mixing arm:
potassium hydroxide of 2.5 kg
potassium silicate of 0.2 kg
water of 0.6 kg.
Then, the mixing arm is set to motion and, after approx. 5 minutes, a mixture is obtained which, in the quantity of 1.8 % by weight, is introduced in the polyol (PUR), and then, all material is mixed for 2 minutes and, while mixing continuously, the quantity of 2.1 % by weight of the solid component in the form of perlite with the grain size of 1 .8 mm is introduced in the mixture, and then, all material is mixed for 1.5 minutes and the masterbatch is treated with isocyanate of 105% by weight.
The quantities of the liquid component, the solid component and of the isocyanate are calculated with relation to the quantity of the polyol.
All material is mixed for 10 seconds until expansion begins.
Reaction time: 3.5 min. Example 3
A stationary example of obtaining PIR polyurethanes modified with the binary agent according to the invention.
A liquid component with the following composition is introduced in a vessel with a mixing arm:
potassium hydroxide of 2.5 kg
potassium silicate of 0.3 kg
water of 0.7 kg.
Then, the mixing arm is set to motion and, after approx. 5 minutes, a mixture is obtained which is introduced, in the quantity of 1.9 % by weight, in the polyol (PIR), then all material is mixed for 2 minutes, and wuue i niAn iy uununuuusiy, the quantity of 2.9 % by weight of perlite with the grain size of 0.5 mm is introduced in the mixture, and then, all material is mixed for 1 .5 minutes and the masterbatch is treated with isocyanate in the quantity of 160% by weight.
The quantity of the liquid component, the solid component and of the isocyanate is calculated with relation to the quantity of the polyol.
All material is mixed for 9 seconds until expansion begins.
Reaction time: 3.0 min. The introduction of the solid component in the form of perlite with the required grain size into the liquid component mixed with polyol enables more effective homogenisation of the polyol with the liquid component and does not have an effect on distorting the quantitative proportions between the different components of the agent according to the invention.
Polyurethane materials modified with the binary agent according to the invention demonstrate advantageous geometrical distribution of pores. The application of the binary agent for the modification of polyurethane materials according to the invention enables regulation of the structure of the pores (open, closed) and a reduction of the material's density, and has an effect on the elasticity of the material, its resistance parameters, thermal resistance and vibroacoustic properties.

Claims

What is claimed is:
1. Binary agent for the modification of polyurethane materials, wherein it comprises a liquid component containing potassium hydroxide of between 2 do 65 % by weight, potassium silicate of between 1.8 and 29.8 % by weight, water of between 5.5 % by weight and a solid component in the form of expanded perlite of between 0.1 and 45 % by weight.
2. Binary agent according to claim 1 wherein the perlite grain size is between 0.3 and 12.0 mm.
PCT/PL2012/000032 2011-05-20 2012-05-15 Binary agent for the modification of polyurethane materials WO2012161602A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP12726914.0A EP2710048A1 (en) 2011-05-20 2012-05-15 Binary agent for the modification of polyurethane materials

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
PL394959A PL217607B1 (en) 2011-05-20 2011-05-20 Two-component agent for the modification of polyurethane plastics
PLP.394959 2011-05-20

Publications (1)

Publication Number Publication Date
WO2012161602A1 true WO2012161602A1 (en) 2012-11-29

Family

ID=46246156

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/PL2012/000032 WO2012161602A1 (en) 2011-05-20 2012-05-15 Binary agent for the modification of polyurethane materials

Country Status (3)

Country Link
EP (1) EP2710048A1 (en)
PL (1) PL217607B1 (en)
WO (1) WO2012161602A1 (en)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4346180A (en) * 1981-04-06 1982-08-24 Blount David H Process for the production of organic alkali metal silicate compounds
US4357429A (en) * 1981-07-17 1982-11-02 Blount David H Process for the production of alkali metal silicate-organic plastics
WO1994000004A1 (en) * 1992-06-26 1994-01-06 University Of Strathclyde Porous solid material
USRE37095E1 (en) 1992-09-18 2001-03-13 Apache Products Company Extruded polymer foam with filler particles and method
US6403688B1 (en) * 1998-11-18 2002-06-11 Advanced Construction Materials Corp. Strengthened, light weight wallboard and method and apparatus for making the same
US20050281999A1 (en) * 2003-03-12 2005-12-22 Petritech, Inc. Structural and other composite materials and methods for making same
WO2009011533A2 (en) 2007-07-16 2009-01-22 Uray Co,. Ltd. Adiabatic material comprising expanded perlite and polyurethane and method of preparing the same and construction meterials comprising the adiabatic material
GB2454990A (en) * 2007-11-21 2009-05-27 3Gates Patent Ltd Polyurethane or polyisocyanurate foam compositions

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4346180A (en) * 1981-04-06 1982-08-24 Blount David H Process for the production of organic alkali metal silicate compounds
US4357429A (en) * 1981-07-17 1982-11-02 Blount David H Process for the production of alkali metal silicate-organic plastics
WO1994000004A1 (en) * 1992-06-26 1994-01-06 University Of Strathclyde Porous solid material
USRE37095E1 (en) 1992-09-18 2001-03-13 Apache Products Company Extruded polymer foam with filler particles and method
US6403688B1 (en) * 1998-11-18 2002-06-11 Advanced Construction Materials Corp. Strengthened, light weight wallboard and method and apparatus for making the same
US20050281999A1 (en) * 2003-03-12 2005-12-22 Petritech, Inc. Structural and other composite materials and methods for making same
WO2009011533A2 (en) 2007-07-16 2009-01-22 Uray Co,. Ltd. Adiabatic material comprising expanded perlite and polyurethane and method of preparing the same and construction meterials comprising the adiabatic material
GB2454990A (en) * 2007-11-21 2009-05-27 3Gates Patent Ltd Polyurethane or polyisocyanurate foam compositions

Also Published As

Publication number Publication date
PL394959A1 (en) 2012-12-03
PL217607B1 (en) 2014-08-29
EP2710048A1 (en) 2014-03-26

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