WO2012150327A1 - Method and apparatus for handling transportation and supply of large amount of small-size torrefied biomass/peat materials - Google Patents

Method and apparatus for handling transportation and supply of large amount of small-size torrefied biomass/peat materials Download PDF

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Publication number
WO2012150327A1
WO2012150327A1 PCT/EP2012/058220 EP2012058220W WO2012150327A1 WO 2012150327 A1 WO2012150327 A1 WO 2012150327A1 EP 2012058220 W EP2012058220 W EP 2012058220W WO 2012150327 A1 WO2012150327 A1 WO 2012150327A1
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WO
WIPO (PCT)
Prior art keywords
mixture
small particles
small
liquid fluid
torrefied
Prior art date
Application number
PCT/EP2012/058220
Other languages
French (fr)
Inventor
Giuliano Grassi
Original Assignee
Modern Bioenergy Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Modern Bioenergy Sa filed Critical Modern Bioenergy Sa
Publication of WO2012150327A1 publication Critical patent/WO2012150327A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K3/00Feeding or distributing of lump or pulverulent fuel to combustion apparatus
    • F23K3/02Pneumatic feeding arrangements, i.e. by air blast
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65GTRANSPORT OR STORAGE DEVICES, e.g. CONVEYORS FOR LOADING OR TIPPING, SHOP CONVEYOR SYSTEMS OR PNEUMATIC TUBE CONVEYORS
    • B65G53/00Conveying materials in bulk through troughs, pipes or tubes by floating the materials or by flow of gas, liquid or foam
    • B65G53/30Conveying materials in bulk through pipes or tubes by liquid pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/326Coal-water suspensions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L5/00Solid fuels
    • C10L5/40Solid fuels essentially based on materials of non-mineral origin
    • C10L5/44Solid fuels essentially based on materials of non-mineral origin on vegetable substances
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L9/00Treating solid fuels to improve their combustion
    • C10L9/08Treating solid fuels to improve their combustion by heat treatments, e.g. calcining
    • C10L9/083Torrefaction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K1/00Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
    • F23K1/02Mixing solid fuel with a liquid, e.g. preparing slurries
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2201/00Pretreatment of solid fuel
    • F23K2201/30Separating
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23KFEEDING FUEL TO COMBUSTION APPARATUS
    • F23K2203/00Feeding arrangements
    • F23K2203/006Fuel distribution and transport systems for pulverulent fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

Method for handling transportation and supply of large amount of small particles like pellets, granules, small-chips, powder and the like obtained by biomass and peat, comprising the steps of: a) providing a liquid fluid adapted to be mixed with said small particles; b) mixing said small particles with said liquid fluid to obtain a mixture to be delivered; c) providing a suitable pipeline and connected means for pumping a fluid along said pipeline; d) pumping said mixture along said pipeline from first location to a second location; e) collecting said mixture at said second location; f) separation of the original small particles from the mixture.

Description

METHOD AND APPARATUS FOR HANDLING TRANSPORTATION AND SUPPLY OF LARGE AMOUNT OF SMALL-SIZE TORREFIED BIOMASS/PEAT MATERIALS
Field of the invention
The present invention refers to the technical field of alternative and renewable energy production and in particular it refers to torrefied biomasses/peat and apparatuses and methods of handling and delivering torrefied biomasses/peat. State of the art
It is known that a huge amount of biomass and peat is potentially available, for energy and industrial utilisation, from a wide range of agro-forestry residues, wastes, energy-crops, peat fields. According to the EU, the long-term biomass potential is estimated at 600 MTOE / year (Million Tons of Oil Equivalent per year) with a large share obtained from low-quality agro-forestry residues.
New, high energy efficient technology for the production of so called "agro pellets" - which are pellets energetically and physically similar to conventional wood pellets, but obtainable from any type of agro-forestry residues, wastes or mixtures thereof - is based on the fact that most of the moisture content of said agro- forestry residues is eliminated mechanically and not thermally. This technology is already able to allow the direct pelletising of very humid biomasses / peat, and it will allow, in the near future, the production of a very large volume of lower-quality agro-pellets that will soon be available on the market for trading and delivery to biomasses based power plants and factories.
A large fraction of said very large volume of lower-quality agro-pellets will then very likely be processed by torrefaction. In fact, torrefaction will have a benefit homogenisation effect in that the final torrefied products (in form of chips, pellets or granules), coming from different types of biomasses including low-quality biomasses, will acquire very similar energy characteristics.
Therefore, it's easy to envisage that in the near future as already being anticipated a very large volume of torrefied agro-pellets, obtained with biomasses, peat, or their mixtures will be made available because of their many good qualities as solid-refined bio fuel: lower emissions, higher volumetric energy density, improved homogeneity, low moisture content, hydrophobicity, easy grindability, etc. As an obvious consequence of said increasing availability of large quantities of torrefied agro-pellets(peat/biomass) a corresponding growth of international trading of said torrefied agro-pellets is to be expected due to the worldwide increasing use of Bio-Heat (district heating), Bio-electricity (cofiring with coal, cogeneration), Biofuels for transportation and Biochemicals.
The handling, transportation and logistics connected to the delivery of large volumes of torrefied biomasses and peat will thus become a very important and challenging activity, requiring considerable infrastructures and investments, like it happens today regarding coal and petroleum. It's therefore an object of the present invention to provide a new apparatus and a new method for handling transportation and supply of torrefied biomasses and peat, in particular in the form of agro-pellet
Summary of the invention
The method according to the present invention exploits, in particular, the high hydrophobicity of torrefied material. In fact, torrefied materials show, at normal equilibrium conditions, a low moisture rate of 3-4% in weight and they do not absorb water even when immerged in water for periods of time as long as many days or months. According to the present invention, the hydrophobicity of torrefied material is not only exploited for low-cost outside storage, but also for low-cost handling, charging, discharging, transportation and supply of torrefied small size biomass and/or peat (in form of chips, pellets, granules etc.) by mixing the torrefied materials with a liquid (like water, slurry - which is made of torrefied powder mixed with water - vegetal oil, exhausted vetegal oils, biethanol and others liquid biofuels), and pumping the torrefied solid-liquid mixture to the remote storage / handling, utilisation site, where the separation of the solid matter from the liquid vessel will be carried out to make the original high value of the refined solid biofuel thus available for its efficient use.
Brief description of drawings
Fig. 1 describes a schematic block diagram of a preferred embodiment of the apparatus for the delivery of torrefied small biomass and peat material according to the present invention. Fig. 2 describes a schematic diagram showing preparation of "slurry" as a transport fluid.
Fig. 3 describes a schematic diagram showing a possible layout of a torrefied biomass/peat charging system.
Fig. 4 describes a schematic diagram showing a possible layout of a torrefied biomass/peat discharging system.
Detailed description of the invention
Method and apparatus for handling transportation and supply of large amount of torrefied biomass and peat material in form of pellets, granules, small-chips and powder.
It is well known that torrefied materials show, at normal equilibrium conditions, a low moisture content rate of 3-4% in weight and do not absorb more water even when immerged in water for periods of time of several days or months. Tests carried out on torrified pellets - having diameter of 6 to 8 mm and specific density of about 1 .2 gr/cm3 - completely immersed in water for a long period of time (150hr and more), show that the water absorption of said torrified pellets is neglectable and they show no sign of disintegration or physical deformation. Further trials demonstrated that after a 6 months immersion period, in water 6mm diameter torrefied pellets absorbe nearly 0% of water, maintaining the same mechanical/physical characteristics. Because of this important quality, torrefied pellets, granules, small-chips etc. can be mixed with a fluid, like e. g. water or slurry, acting as fluid-dynamic transport means, and efficiently pumped and delivered - with a capacity ranging up to hundreds of tons per hour and more - to the utilisation site where easy separation of the refined solid material from said fluid can be easily carried out by state of the art well known systems to restablish the original high value biofuel making it available for a prompt use.
Torrefied biomass or peat material, in particular in form of "torrefied pellets" obtained by direct torrefaction treatment of crude pellets - e.g. by large scale process of conversion adaptable for very large production capacity (i.e; 1 , 2, 3 million tons/year or more) - represent a promising new solid biofuel and even a promising new commodity of large potential use and great economic and environmental interest. Considering the improved characteristics of the torrefied materials in comparison with the original feedstocks, higher heating value, higher volumetric energy density, hydrophobicity, better grindability, lower emissions, etc. two aspects appear of particular interest for large-scale utilisation of torrefied biomass or peat: the homogenization of the refined product, even when obtained from different feedstocks, and the Hydrophobic nature of torrefied materials.
The homogenization of the refined product induced by the torrefaction refining process will have a strong beneficial effects on the deployment and enlarged use of all types of biomasses available, with special reference to the large amounts of agro-pellets potentially widely available, ( first of all obtained from every type of agro-forestry residue) the quality of which can be considerably improved through torrefaction (low water, low oxygen and low chlorine content).
The hydrophobic characteristic of torrefied materials like biomasses and peat that allow also important benefits for long-term outside storage and for the logistics like handling, charging, discharging and transport and can be exploited, according to the present invention, by mixing the torrefied fuel with a fluid like e.g. water or slurry and pumping the mixture of the transport fluid like water or torrefied material to the final storage/utilization sites, .where separation from the water is carried out to restablish the original biofuel.
With reference to the enclosed figure 1 , a preferred embodiment of the apparatus according to the present invention comprises means 1 1 for producing a mixture 15 of small torrefied particles 10 like pellets, granules, small-chips, powder and the like obtained by biomass and peat and a liquid transport fluid 16 like, e.g., water, means for pumping 12 said mixture 15 along a suitable pipeline 14 adapted to deliver said mixture 15 at a required distance, means for separating said mixture 15 into said torrefied small particles 10 and said liquid transport fluid 16.
Said small particles 10 are made of torrefied material, said means for separating said mixture 15 into said small particles 10 and said liquid fluid vessel 16 comprise a rotating screen, a trommel screen, a simple sifter or similar device, said means for pumping 12 comprise pumping systems for solid-liquid mixtures of the type normally available on the market and in particular centrifugal pumps with very large delivery capacity and said suitable pipeline 14 comprises plastic material pipes.
In a preferred embodiment, in order to save and re-use the said transport liquid, said suitable pipeline 14 comprises a closed loop pipeline.
In a further preferred embodiment of the present invention, , said suitable pipeline 14 comprises a single pipeline with a bidirectional pumping means.
For the transport of torrefied material, said liquid transport fluid 16 comprises water or slurry. Also sea water can be advantageously employed. Other suitable transport liquid fluids can be chosen in the group of liquid transport biofuels comprising vegetal oil, exhausted vetegal oil, biethanol, etc., depending on the solid refined material to be transported.
The apparatus and method according to the present invention will be suitable for charging and discharging torrefied solid fuel, in the form of pellets, granules, small- chips, powder and the like, in and from trucks, trains or ships and for supplying said solid torrefied refined biofuel to power plants and conversion plants.
The logistics correlated to the apparatus and method according to the present invention is very similar to the logistics regarding heavy oil handling and distribution due to the fact that the small torrified material(pellets, granules, small- chips) are temporarily transformed into a solid-liquid mixture easy to be efficiently pumped and finally separated into the liquid vessel (preferably water) plus the small particles to recover the torrefied material with the original characteristics.
The method and apparatus according to the present invention can be adapted to deliver small torrefied material like pellets, granules, small-chips etc. to wide distances range, up to several hundreds of kilometres and it will be able to match future large scale trading and diversified torrefied material demand (biomass/peat) all over the world.
Some very important side effects are connected to the use of the apparatus and method according to the present invention: the actual constrains situation of ports will be improved by reducing the quantity of goods which are received and stored at the port facility; in fact, the mixtures of small torrefied material and water can be pumped directly from ships through underground pipeline to low-cost storage sites away from the very expensive storage locations within the port area with obvious benefits in terms of reduction of the port activity congestion, cost reduction of the storage in the port of the fuel waiting to be delivered to its final destination and reduction of the operating time and cost connected to the charging and discharging of the torrefied materials.
The method according to the present invention will allow huge amounts of highly refined torrefied biomass / peat material - that could become a new recognised commodity ("Torrefied Agro-pellets") of universal value.
For example: In the contest of a future international large scale trading, three situation exploiting the present invention can be envisaged:
1 ) Long distances transportation from internal torrefaction plants to port charging/discharging sites
2) Charging and discharging operations on cargos away from congested port areas as already explained above.
3) Delivering large amount of torrefied material from large storage to the utilisation/conversion sites.
. Torrefied agro-pellets may represent thus a vital resource for a more friendly production of Energy and Chemicals world wide, progressively replacing oil, natural gas and coal.
Considering as an example a mixture comprising water at 70% in weight and torrefied pellets at 30% in weight and a moderate speed of transfer of about 1 m/sec (3.6 km/h) inside the pipeline: in 150 hrs time, the mixture will cover a distance of about 450Km with no energy density loss for the delivered torrefied materials (biomass - peat) once separate from the water, and with a very low energy consumption for their transport, due to the low energy input required for pumping mixture with specific density higher than 1 gr / cm3. To achieve the above result with the delivery of 1 million tons of torrefied pellets per year (equivalent to about 125 tons of torrefied pellets per hour) and considering the above example of mixture (water at 70%, torrefied pellets at 30%), the required volume transfer through the pipeline is about 350 m3/h = 0.097 m3/sec. Choosing a simple pipeline in plastic material with an internal diameter of 35cm (0.09 m2), the speed of transfer of the mixture corresponds to about 1 m/sec. According to the present invention, mixtures characterised by a ratio in weight between said small particles and said transport liquid in the ranges from 20% to 60% and more (preferentially above 30%) can be easy delivered.
The major and typical applications connected to the present invention can be summarised by the following: 1 ) the replacement of old type conveyor systems such as mechanical belt or screw-conveyors for the transfer of solid biomass; 2) the replacement of large scale road transport & distribution network in congested urban and suburban areas by pipelines and pumping /separation systems; 3) the replacement of mechanical torrefied biomass/peat supply systems to power-plants or conversion-plants with large delivery of torrefied materials (pellets, granules, small chips) that can easily reach 0.5 -1 million tons /year and more; 4) the replacement of conventional charging and discharging operations (i.e. to and from cargo ships and the like) of torrefied material, with systems for the pumping of solid / liquid mixtures through underground pipelines up to the storage site located outside the port area, to avoid the high storage costs in the port, the road congestion around the port area thus reducing local air pollution. When a liquid bio fuel is employed as transfer liquid the final separation phase between the solid bio fuel and the said liquid may not be required in some cases because the produced solid / liquid slurry could be directly used for the combustion/conversion purpose.

Claims

1 . Method for handling transportation and supply of large amount of small particles like pellets, granules, small-chips, powder and the like obtained by biomass and peat, comprising the steps of: a) providing a liquid fluid adapted to be mixed with said small particles; b) mixing said small particles with said liquid fluid to obtain a mixture to be delivered; c) providing a suitable pipeline and connected means for pumping a fluid along said pipeline; d) pumping said mixture along said pipeline from first location to a second location; e) collecting said mixture at said second location.
2. Method according to claim 1 comprising a further step f) of separating said mixture into its components: small biomass particles and liquid fluid.
3. Method according to claims 1 - 2 wherein said liquid fluid adapted to be mixed with said small biomass particles is chosen in the group comprising: water, slurry bio ethanol, bio methanol, new or exhausted vegetal oils, pyrolysis oil.
4. Method according to claims 1 - 3 wherein said small particles comprise torrefied small particles.
5. Method according to claims 1 - 4 wherein, within said mixture, the ratio in weight between said small particles and said liquid fluid ranges from 10% to 70% or more.
6. Method according to claims 1 - 5 wherein said suitable pipeline is a closed loop pipeline adapted to save and re-use said liquid fluid.
7. Apparatus for handling transportation and supply of large amount of small particles like pellets, granules, small-chips, powder and the like obtained by biomass and peat, comprising: means (1 1 ) for producing a mixture (15) of said small particles (10) and a liquid fluid vessel (16); means for pumping (12) said mixture (15) along a suitable pipeline (14) adapted to deliver said mixture (15) at a required distance.
8. Apparatus according to claim 7 further comprising means for separating said mixture (15) into said small particles (10) and said liquid fluid vessel (16).
9. Apparatus according to claims 7 - 8 wherein said liquid fluid vessel (16) is chosen in the group comprising: water, slurry, bio ethanol, bio methanol, new or exhausted vegetal oils, pyrolysis oil
10. Apparatus according to claims 7 - 9 wherein said small particles (10) comprise torrefied small particles.
1 1 . Apparatus according to claims 7 - 10 wherein said means for separating said mixture (15) into said small particles (10) and said liquid fluid vessel (16) are chosen in the group comprising: sifters, rotating screens, Trommel screens, heating systems,.
12. Apparatus according to claims 7 - 1 1 wherein said means for pumping (12) comprise centrifugal pumps.
13. Apparatus according to claims 7 - 12 wherein said suitable pipeline (14) comprises plastic pipes.
14. Apparatus according to claims 7 - 13 wherein said suitable pipeline (14) comprises an open loop pipeline adapted to save and re-use said liquid fluid (13) and said means for pumping (12) comprise bidirectional pumping means.
PCT/EP2012/058220 2011-05-04 2012-05-04 Method and apparatus for handling transportation and supply of large amount of small-size torrefied biomass/peat materials WO2012150327A1 (en)

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Application Number Priority Date Filing Date Title
LU91813 2011-05-04
LU91813A LU91813B1 (en) 2011-05-04 2011-05-04 Method and apparatus for handling transportation and supply of large amount of smallsize torrefied biomass/peat materials

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015193335A1 (en) * 2014-06-17 2015-12-23 Rhodia Operations Carbonaceous material suspension

Citations (6)

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US3774971A (en) * 1971-11-16 1973-11-27 Oji Paper Co Safety device for a system of hydraulically transporting solid matters
US4685840A (en) * 1985-08-02 1987-08-11 Wolff Robert C Method of transporting large diameter particulate matter
JPH0549898A (en) * 1991-08-09 1993-03-02 Japan Tobacco Inc Grain lifting device for granulation system
JP2005118011A (en) * 2003-10-20 2005-05-12 Osaka Industrial Promotion Organization Method and system for transporting forest biomass
US20080038815A1 (en) * 2006-08-10 2008-02-14 Foody Sr Patrick Method and system for the large scale collection, preparation, handling and refining of ligno-cellulosic biomass
WO2010068773A1 (en) * 2008-12-10 2010-06-17 Kior Inc. Process for preparing a fluidizable biomass-catalyst composite material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3774971A (en) * 1971-11-16 1973-11-27 Oji Paper Co Safety device for a system of hydraulically transporting solid matters
US4685840A (en) * 1985-08-02 1987-08-11 Wolff Robert C Method of transporting large diameter particulate matter
JPH0549898A (en) * 1991-08-09 1993-03-02 Japan Tobacco Inc Grain lifting device for granulation system
JP2005118011A (en) * 2003-10-20 2005-05-12 Osaka Industrial Promotion Organization Method and system for transporting forest biomass
US20080038815A1 (en) * 2006-08-10 2008-02-14 Foody Sr Patrick Method and system for the large scale collection, preparation, handling and refining of ligno-cellulosic biomass
WO2010068773A1 (en) * 2008-12-10 2010-06-17 Kior Inc. Process for preparing a fluidizable biomass-catalyst composite material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2015193335A1 (en) * 2014-06-17 2015-12-23 Rhodia Operations Carbonaceous material suspension
EP2957623A1 (en) * 2014-06-17 2015-12-23 Rhodia Opérations Carbonaceous material suspension

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