WO2012146779A3 - Verfahren zur herstellung gezonter katalysatoren - Google Patents

Verfahren zur herstellung gezonter katalysatoren Download PDF

Info

Publication number
WO2012146779A3
WO2012146779A3 PCT/EP2012/057893 EP2012057893W WO2012146779A3 WO 2012146779 A3 WO2012146779 A3 WO 2012146779A3 EP 2012057893 W EP2012057893 W EP 2012057893W WO 2012146779 A3 WO2012146779 A3 WO 2012146779A3
Authority
WO
WIPO (PCT)
Prior art keywords
catalyst
production
ducts
zoned
catalysts
Prior art date
Application number
PCT/EP2012/057893
Other languages
English (en)
French (fr)
Other versions
WO2012146779A2 (de
Inventor
Markus Hutt
Sascha Podehl
Ingo Stender
Original Assignee
Clariant Produkte (Deutschland) Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Clariant Produkte (Deutschland) Gmbh filed Critical Clariant Produkte (Deutschland) Gmbh
Publication of WO2012146779A2 publication Critical patent/WO2012146779A2/de
Publication of WO2012146779A3 publication Critical patent/WO2012146779A3/de

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/50Catalysts, in general, characterised by their form or physical properties characterised by their shape or configuration
    • B01J35/56Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0205Impregnation in several steps
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/06Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
    • C01B3/12Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
    • C01B3/16Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N3/00Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust
    • F01N3/08Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous
    • F01N3/10Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust
    • F01N3/24Exhaust or silencing apparatus having means for purifying, rendering innocuous, or otherwise treating exhaust for rendering innocuous by thermal or catalytic conversion of noxious components of exhaust characterised by constructional aspects of converting apparatus
    • F01N3/28Construction of catalytic reactors
    • F01N3/2803Construction of catalytic reactors characterised by structure, by material or by manufacturing of catalyst support
    • F01N3/2825Ceramics
    • F01N3/2828Ceramic multi-channel monoliths, e.g. honeycombs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/90Physical characteristics of catalysts
    • B01D2255/905Catalysts having a gradually changing coating
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0205Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02Processes for making hydrogen or synthesis gas
    • C01B2203/0283Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005Arrangement or shape of catalyst
    • C01B2203/1023Catalysts in the form of a monolith or honeycomb
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1052Nickel or cobalt catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041Composition of the catalyst
    • C01B2203/1047Group VIII metal catalysts
    • C01B2203/1064Platinum group metal catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Combustion & Propulsion (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Toxicology (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Catalysts (AREA)

Abstract

Es wird ein Verfahren zur Herstellung eines Katalysators bereitgestellt, umfassend a) Bereitstellen eines Katalysator-Formkörpers, der eine Mehrzahl von Strömungskanälen enthält, die jeweils eine Eintrittssöffnung und eine Austrittsöffnung aufweisen; und b) schrittweises Imprägnieren der Strömungskanäle mit einer Lösung einer Verbindung einer katalytisch aktiven Komponente. Ferner wird ein Katalysator und eine Verwendung des Katalysators angegeben.
PCT/EP2012/057893 2011-04-29 2012-04-30 Verfahren zur herstellung gezonter katalysatoren WO2012146779A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102011100017.1 2011-04-29
DE102011100017A DE102011100017A1 (de) 2011-04-29 2011-04-29 Verfahren zur Herstellung gezonter Katalysatoren

Publications (2)

Publication Number Publication Date
WO2012146779A2 WO2012146779A2 (de) 2012-11-01
WO2012146779A3 true WO2012146779A3 (de) 2014-07-24

Family

ID=46044681

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2012/057893 WO2012146779A2 (de) 2011-04-29 2012-04-30 Verfahren zur herstellung gezonter katalysatoren

Country Status (2)

Country Link
DE (1) DE102011100017A1 (de)
WO (1) WO2012146779A2 (de)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT513851B1 (de) 2013-05-27 2014-08-15 Scheuch Gmbh Vorrichtung zur katalytischen Entstickung und regenerativen thermischen Nachverbrennung
GB201518784D0 (en) * 2015-10-23 2015-12-09 Johnson Matthey Plc Catalysed monolith substrate for a diesel engine
GB201616269D0 (en) 2016-09-26 2016-11-09 Johnson Matthey Public Limited Company Oxidation catalyst for a diesel engine exhaust
CN114669424B (zh) * 2022-03-15 2023-05-12 苏州西热节能环保技术有限公司 催化剂梯级负载方法

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1554875A (en) * 1975-09-23 1979-10-31 Degussa Internal combustion engine exhaust catalyst
WO2001074476A1 (en) * 2000-03-17 2001-10-11 Engelhard Corporation Multi-zoned catalytic trap and methods of making and using the same
WO2005077497A1 (en) * 2004-02-11 2005-08-25 Umicore Ag & Co. Kg Exhaust gas cleaning catalyst with an axially varying precious metal concentration and processes for making the catalyst
DE102004040549A1 (de) * 2004-08-21 2006-02-23 Umicore Ag & Co. Kg Katalytisch beschichtetes Partikelfilter und Verfahren zu seiner Herstellung sowie seine Verwendung
WO2006080369A1 (en) * 2005-01-31 2006-08-03 Toyota Jidosha Kabushiki Kaisha Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same
EP2105197A1 (de) * 2008-03-27 2009-09-30 Ibiden Co., Ltd. Wabenstruktur und Abgasverarbeitungsvorrichtung
JP2009254987A (ja) * 2008-04-17 2009-11-05 Ne Chemcat Corp ハニカム構造体の部分含浸方法、ハニカム型構造触媒の製造方法、及び得られるハニカム構造型触媒

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5712820A (en) * 1980-06-24 1982-01-22 Toyota Motor Corp Monolithic type catalyst structure for cleaning automobile exhaust
FR2622126B1 (fr) * 1987-10-21 1991-06-14 Procatalyse Ste Fse Produits C Catalyseur pour le traitement des gaz d'echappement des moteurs a combustion interne et procede de fabrication de ce catalyseur
DE4342914C1 (de) * 1993-12-16 1995-07-27 Degussa Verfahren zum Impr{gnieren der Str¦mungskan{le von Wabenk¦rpern mit definierten Konzentrationsprofilen
BR9909986A (pt) * 1998-04-28 2000-12-26 Engelhard Corp Catalisadores monolìticos e processo afim para a fabricação
DE102007029418A1 (de) * 2007-06-26 2009-01-08 Robert Bosch Gmbh Katalysatorelement, Katalysator zur Abgasnachbehandlung einer Brennkraftmaschine und Verfahren zur Herstellung eines erfindungsgemäßen Katalysatorelements

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1554875A (en) * 1975-09-23 1979-10-31 Degussa Internal combustion engine exhaust catalyst
WO2001074476A1 (en) * 2000-03-17 2001-10-11 Engelhard Corporation Multi-zoned catalytic trap and methods of making and using the same
WO2005077497A1 (en) * 2004-02-11 2005-08-25 Umicore Ag & Co. Kg Exhaust gas cleaning catalyst with an axially varying precious metal concentration and processes for making the catalyst
DE102004040549A1 (de) * 2004-08-21 2006-02-23 Umicore Ag & Co. Kg Katalytisch beschichtetes Partikelfilter und Verfahren zu seiner Herstellung sowie seine Verwendung
WO2006080369A1 (en) * 2005-01-31 2006-08-03 Toyota Jidosha Kabushiki Kaisha Catalyst for purifying exhaust gases and exhaust-gas purification controller using the same
EP2105197A1 (de) * 2008-03-27 2009-09-30 Ibiden Co., Ltd. Wabenstruktur und Abgasverarbeitungsvorrichtung
JP2009254987A (ja) * 2008-04-17 2009-11-05 Ne Chemcat Corp ハニカム構造体の部分含浸方法、ハニカム型構造触媒の製造方法、及び得られるハニカム構造型触媒

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
BOBROVA L ET AL: "Syngas formation by selective catalytic oxidation of liquid hydrocarbons in a short contact time adiabatic reactor", CHEMICAL ENGINEERING JOURNAL, ELSEVIER SEQUOIA, LAUSANNE, CH, vol. 107, no. 1-3, 15 March 2005 (2005-03-15), pages 171 - 179, XP027702859, ISSN: 1385-8947, [retrieved on 20050315] *

Also Published As

Publication number Publication date
DE102011100017A1 (de) 2012-10-31
WO2012146779A2 (de) 2012-11-01

Similar Documents

Publication Publication Date Title
EP3450419A4 (de) Katalysatorkonfiguration und herstellung sowie verfahren zur direkten synthese von ethylen durch katalyse von methan unter sauerstofffreien bedingungen
WO2012083236A3 (en) Catalysts, methods of preparation of catalyst, methods of deoxygenation, and systems for fuel production
MY171816A (en) Process for preparing fisher-tropsch catalyst
WO2012166472A3 (en) Production of propene
WO2014072887A3 (en) Process for producing a carbon-supported nickel-cobalt-oxide catalyst and its use in rechargeable electrochemical metal-oxygen cells
MX357583B (es) Capsulas de nucleo-corteza.
BR112014028474A2 (pt) catalisador heterogêneo, e, processos para preparar ácido adípico ou derivados do mesmo e para produzir um produto de ácido adípico.
BR112013018701A2 (pt) catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
ZA201503633B (en) High performance ziegler-natta catalyst systems, process for producing such supported catalysts and use thereof
WO2012030065A3 (en) Catalyst composition for hydroformylation reaction and a hydroformylation process using the same
SG11201408066UA (en) Catalyst for methanol production, method of producing the same and process of methanol production
WO2013022565A8 (en) Olefin hydration process with an integrated membrane reactor
WO2013078205A3 (en) Catalyst preparations for high conversion catalysts for producing ethanol
WO2015008247A3 (en) Process and catalyst for resin hydrogenation
WO2012146779A3 (de) Verfahren zur herstellung gezonter katalysatoren
WO2013019013A3 (ko) 금속 구조체 촉매 및 이의 제조방법
WO2012082232A8 (en) Process for producing cycloalkylaromatic compounds
EP3056273A4 (de) Katalysator zur dehydrierung von ameisensäure, verfahren zur dehydrierung von ameisensäure und verfahren zur herstellung von wasserstoff
MY163332A (en) Catalysts
BR112012028770A2 (pt) catalisador de aromatização de metano, e, processos para preparar um catalisador de aromatização de metano e para produzir hidrocarbonetos aromáticos
WO2014207765A3 (en) Synthesis of functionalized carbon microspheres and their catalyst activity in c-o and c-n bond formation reactions
WO2009138204A3 (de) Verfahren zur herstellung einer platinkatalysator-vorstufe
IT1398304B1 (it) Procedimento di produzione di supporto di dialcossimagnesio per catalizzatore per la polimerizzazione di olefine, procedimento di produzione di catalizzatore per la polimerizzazione di olefine impiegante il medesimo e procedimento di polimerizzazione di olefine impiegante il medesimo.
MY165648A (en) Process for the impregnation of air core reactors, impregnated air core reactor and use of an impregnation system
WO2011077255A3 (en) Exhaust gas catalyst carrier, exhaust gas catalyst employing the exhaust gas catalyst carrier, and method of manufacturing the exhaust gas catalyst carrier

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12719349

Country of ref document: EP

Kind code of ref document: A2

122 Ep: pct application non-entry in european phase

Ref document number: 12719349

Country of ref document: EP

Kind code of ref document: A2