WO2012131499A3 - Composite of manganese compound and carbon, manufacturing method therefor, and electrode and electrochemical element using composite - Google Patents

Composite of manganese compound and carbon, manufacturing method therefor, and electrode and electrochemical element using composite Download PDF

Info

Publication number
WO2012131499A3
WO2012131499A3 PCT/IB2012/001077 IB2012001077W WO2012131499A3 WO 2012131499 A3 WO2012131499 A3 WO 2012131499A3 IB 2012001077 W IB2012001077 W IB 2012001077W WO 2012131499 A3 WO2012131499 A3 WO 2012131499A3
Authority
WO
WIPO (PCT)
Prior art keywords
composite
carbon
manganese compound
electrode
manufacturing
Prior art date
Application number
PCT/IB2012/001077
Other languages
French (fr)
Japanese (ja)
Other versions
WO2012131499A2 (en
Inventor
Katsuhiko Naoi
Yoshiyuki Igarashi
Wako Naoi
Kenji Tamamitsu
Shuichi Ishimoto
Daisuke YONEKURA
Original Assignee
Nippon Chemi-Con Corporation
National University Corporation, Tokyo University Of Agriculture And Technology
K & W Incorporated
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Chemi-Con Corporation, National University Corporation, Tokyo University Of Agriculture And Technology, K & W Incorporated filed Critical Nippon Chemi-Con Corporation
Publication of WO2012131499A2 publication Critical patent/WO2012131499A2/en
Publication of WO2012131499A3 publication Critical patent/WO2012131499A3/en

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/02—Oxides; Hydroxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H01M4/364—Composites as mixtures
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/483—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides for non-aqueous cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/01—Particle morphology depicted by an image
    • C01P2004/04—Particle morphology depicted by an image obtained by TEM, STEM, STM or AFM
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Composite Materials (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)

Abstract

The present invention is a composite of manganese compound and carbon with which an electrode and an electrochemical element with output characteristics and high energy density can be obtained, and a manufacturing method therefor. The composite comprises a manganese compound with 2-8 Å subnano-sized tunnel structures and carbon, and is obtained by a first composite treatment in which composite powder is generated by subjecting a solution containing manganese compound and carbon powder starting materials to sheer stress and centrifugal force within a rotation reactor vessel to induce a reaction; and a heat treatment in which the composite powder resulting from the composite treatment is heated in a vacuum. The composite includes MnO, MnOOH, or Mn3O4. Furthermore, ketjen black can be used for the carbon particles.
PCT/IB2012/001077 2011-03-28 2012-04-25 Composite of manganese compound and carbon, manufacturing method therefor, and electrode and electrochemical element using composite WO2012131499A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2011-071178 2011-03-28
JP2011071178A JP5836620B2 (en) 2011-03-28 2011-03-28 Method for producing composite of manganese oxide and carbon powder

Publications (2)

Publication Number Publication Date
WO2012131499A2 WO2012131499A2 (en) 2012-10-04
WO2012131499A3 true WO2012131499A3 (en) 2012-12-06

Family

ID=46931305

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/JP2012/058273 WO2012133599A1 (en) 2011-03-28 2012-03-29 Manganese compound and carbon complex, method for producing same, and electrode and electrochemical element using said complex
PCT/IB2012/001077 WO2012131499A2 (en) 2011-03-28 2012-04-25 Composite of manganese compound and carbon, manufacturing method therefor, and electrode and electrochemical element using composite

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/JP2012/058273 WO2012133599A1 (en) 2011-03-28 2012-03-29 Manganese compound and carbon complex, method for producing same, and electrode and electrochemical element using said complex

Country Status (2)

Country Link
JP (1) JP5836620B2 (en)
WO (2) WO2012133599A1 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5916021B2 (en) * 2012-03-29 2016-05-11 国立大学法人東京農工大学 Composite of manganese oxide and carbon powder, production method thereof, electrode and electrochemical device using the composite
CN103730257A (en) * 2012-10-16 2014-04-16 海洋王照明科技股份有限公司 Manganese dioxide/graphene composite electrode material, preparing method thereof, and electrochemical capacitor
CN105244483A (en) * 2015-09-16 2016-01-13 常州大学 Preparation method modified manganese-based composite material used for lithium ion battery
CN112768665B (en) * 2021-01-31 2021-11-02 湖南科技大学 Preparation method of MnO/LiF/C composite anode material
CN112908729B (en) * 2021-02-05 2023-01-13 广州金立电子有限公司 Electrode material of capacitor and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09213322A (en) * 1996-02-02 1997-08-15 Matsushita Electric Ind Co Ltd Manufacture of battery and manganese oxide for it
JP2003086179A (en) * 2001-09-10 2003-03-20 Nippon Telegr & Teleph Corp <Ntt> Electrode material, its method of manufacture, and battery using the same
JP2011251889A (en) * 2010-03-31 2011-12-15 Nippon Chemicon Corp Composite of metal oxide nanoparticle and carbon, method for producing the composite, electrode using the composite, and electrochemical element
JP2012104288A (en) * 2010-11-08 2012-05-31 Nippon Chemicon Corp Composite of manganese oxide nanoparticle and carbon, method for manufacturing the same, and electrode and electrochemical element using the composite

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3318607B2 (en) * 2000-02-15 2002-08-26 独立行政法人産業技術総合研究所 New selective NH3 deodorization method
JP2007160151A (en) * 2005-12-09 2007-06-28 K & W Ltd Reaction method, metal oxide nanoparticle or metal oxide nanoparticle-deposited carbon obtained thereby, electrode containing the carbon and electrochemical element using the electrode
JP2012099436A (en) * 2010-11-05 2012-05-24 Univ Of Tokyo Positive electrode material for battery and method for producing the same, and nonaqueous electrolyte secondary battery
JP2012164480A (en) * 2011-02-04 2012-08-30 Honda Motor Co Ltd Battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09213322A (en) * 1996-02-02 1997-08-15 Matsushita Electric Ind Co Ltd Manufacture of battery and manganese oxide for it
JP2003086179A (en) * 2001-09-10 2003-03-20 Nippon Telegr & Teleph Corp <Ntt> Electrode material, its method of manufacture, and battery using the same
JP2011251889A (en) * 2010-03-31 2011-12-15 Nippon Chemicon Corp Composite of metal oxide nanoparticle and carbon, method for producing the composite, electrode using the composite, and electrochemical element
JP2012104288A (en) * 2010-11-08 2012-05-31 Nippon Chemicon Corp Composite of manganese oxide nanoparticle and carbon, method for manufacturing the same, and electrode and electrochemical element using the composite

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
DAISUKE YONEKURA ET AL.: "Cho Enshinryoku Shori ni yoru Ko Bunsan Sanka Manganese/Nano Tanso Fukugo Fukyoku Zairyo no Sosei", ABSTRACTS, BATTERY SYMPOSIUM IN JAPAN, DAI 51 KAI, THE COMMITTEE OF BATTERY TECHNOLOGY, THE ELECTROCHEMICAL SOCIETY OF JAPAN, 8 November 2010 (2010-11-08), pages 245 *
TANG WEIPING ET AL.: "SS-Mn02/Carbon Black no Nano Fukugotai no Gosei to Hoden Seino", ABSTRACTS, BATTERY SYMPOSIUM IN JAPAN, DAI 43 KAI, THE COMMITTEE OF BATTERY TECHNOLOGY, THE ELECTROCHEMICAL SOCIETY OF JAPAN, 12 October 2002 (2002-10-12), pages 136 - 137 *
YOSHIYUKI IGARASHI ET AL.: "Cho Enshin Nano Hybrid Gijutsu o Mochiita Sub Nanoporous Manganese Sankabutsu/Carbon Fukugotai no Sosei to Daiyoryo Fukyoku Tokusei", ABSTRACTS, BATTERY SYMPOSIUM IN JAPAN, DAI 52 KAI, THE COMMITTEE OF BATTERY TECHNOLOGY, THE ELECTROCHEMICAL SOCIETY OF JAPAN, 17 October 2011 (2011-10-17), pages 221 *

Also Published As

Publication number Publication date
WO2012131499A2 (en) 2012-10-04
WO2012133599A1 (en) 2012-10-04
JP2014028707A (en) 2014-02-13
JP5836620B2 (en) 2015-12-24

Similar Documents

Publication Publication Date Title
Sun et al. Interfacial coupled design of epitaxial Graphene@ SiC Schottky junction with built-in electric field for high-performance anodes of lithium ion batteries
Kan et al. Unravelling solid-state redox chemistry in Li1. 3Nb0. 3Mn0. 4O2 single-crystal cathode material
Manthiram et al. Nickel‐rich and lithium‐rich layered oxide cathodes: progress and perspectives
JP6143945B2 (en) Zinc ion secondary battery and manufacturing method thereof
Zheng et al. Mitigating voltage fade in cathode materials by improving the atomic level uniformity of elemental distribution
Wang et al. A type of sodium-ion full-cell with a layered NaNi 0.5 Ti 0.5 O 2 cathode and a pre-sodiated hard carbon anode
Verde et al. Effect of morphology and manganese valence on the voltage fade and capacity retention of Li [Li2/12Ni3/12Mn7/12] O2
WO2012131499A3 (en) Composite of manganese compound and carbon, manufacturing method therefor, and electrode and electrochemical element using composite
Yu et al. Continuous activation of Li 2 MnO 3 component upon cycling in Li 1.167 Ni 0.233 Co 0.100 Mn 0.467 Mo 0.033 O 2 cathode material for lithium ion batteries
Castro et al. The spin-polarized electronic structure of LiFePO4 and FePO4 evidenced by in-lab XPS
Chen et al. Advanced cathode materials for lithium-ion batteries
PL2318315T3 (en) Positive electrode material formed from a lamellar-type oxide for a lithium battery
WO2010079965A3 (en) Positive electrode active material for lithium secondary battery
CN103474623B (en) The preparation method of cathode pole piece and electrochemical appliance
WO2010047552A3 (en) Positive electrode active material with enhanced electrode efficiency and energy density characteristics
WO2012023768A3 (en) Fuel cell including cathode electrode using fe oxidation-reduction pair
WO2012138186A3 (en) Silver paste composition for forming an electrode, and method for preparing same
CN103151543A (en) Mn-M/MOFs catalyst for lithium-air battery and preparation method
Watanabe et al. Capacity improvement by nitrogen doping to lithium-rich cathode materials with stabilization effect of oxide ions redox
CN103887481A (en) Method for preparing heterojunction nanostructure material
WO2008090832A1 (en) Polyradical compound-conductive material composite body, method for producing the same, and battery using the same
CN106207115B (en) A kind of preparation method of nickel hydroxide electrode material
Chen et al. Recycled LiCoO 2 in spent lithium-ion battery as an oxygen evolution electrocatalyst
CN103579595B (en) A kind of zinc-base binary layered mixed oxide is as the purposes of zinc-nickel cell electrode material
KR102042098B1 (en) Seawater Battery

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 12763299

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 12763299

Country of ref document: EP

Kind code of ref document: A2