JP2012164480A - Battery - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a battery having a higher charging/discharging capacity density than conventional.SOLUTION: The battery 1 comprises a positive electrode 2, a negative electrode 3, and an electrolytic solution containing an electrolyte provided between the positive electrode 2 and the negative electrode 3. The positive electrode 2 contains a rubeanic acid or a rubeanic acid derivative as an active material, and a mol concentration of the electrolyte in the electrolytic solution is higher than 1.0 mol/L. In the battery 1, a large amount of anion derived from the electrolyte exists, and the rubeanic acid or the rubeanic acid derivative can take a form from an oxidant to a reductant, so as to obtain a higher charging/discharging capacity density than conventional.

Description

  The present invention relates to a battery including rubeanic acid or a rubeanic acid derivative as an active material of a positive electrode.

  In recent years, lithium batteries have attracted attention as batteries with high energy density. It is known that a lithium battery can obtain a high voltage of 3 V or more by using a non-aqueous electrolyte. However, the conventional lithium battery has a problem that the capacity per mass of the positive electrode material and the negative electrode material is low.

Therefore, the present applicant has proposed a battery containing rubeanic acid (dithiooxamide) or a rubeanic acid derivative (hereinafter referred to as “rubeanic acid (derivative)”) as an active material of the positive electrode (see Patent Document 1). In this battery, as shown in the following formula (I), rubeanic acid (derivative) binds to lithium ions during discharge (reduction) and releases lithium ions during charge (oxidation). Lithium ions are supplied from the negative electrode side including a carbon material into which lithium ions are inserted and a silicon-tin-based material in addition to lithium metal. According to this battery, a high capacity density can be obtained even at room temperature or lower.

JP 2008-147015 A

  However, even if it has a battery of patent document 1, it cannot be said that it has sufficient charging / discharging capacity density, and the further improvement of charging / discharging capacity density is calculated | required.

  This invention is made | formed in view of the above, The objective is to provide the battery which has a charge / discharge capacity density higher than before.

  In order to achieve the above object, the present invention comprises a positive electrode (for example, a positive electrode 2 described later), a negative electrode (for example, a negative electrode 3 described later), and an electrolytic solution containing an electrolyte interposed between the positive electrode and the negative electrode. The positive electrode includes rubeanic acid or a rubeanic acid derivative as an active material, and a molar concentration of the electrolyte in the electrolytic solution is higher than 1.0 mol / L. It is characterized by that.

In the present invention, rubeanic acid (derivative) is used as the positive electrode active material, and the molar concentration of the electrolyte in the electrolytic solution is set higher than 1.0 mol / L. That is, in a battery using rubeanic acid (derivative) as the positive electrode active material, the electrolyte concentration in the electrolytic solution was increased to increase the molar amount of the anion derived from the electrolyte.
Thereby, since anion derived from an electrolyte is present in a large amount, an oxidized form in which electrons are further extracted from the state of rubeanic acid (derivative) can be formed during charging (oxidation). Moreover, at the time of discharge (reduction), it can be made to discharge until a reductant is formed from this oxidant. Therefore, since rubeanic acid (derivative) can take a form from an oxidant to a reductant, a higher charge / discharge capacity density can be obtained than in the prior art.

  In this case, it is preferable that the ratio of the molar amount of the anion derived from the electrolyte to the molar amount of the rubeanic acid or rubeanic acid derivative is 27 or more.

In this invention, the ratio of the molar amount of the anion derived from the electrolyte to the molar amount of rubeanic acid (derivative) was set to 27 or more.
Thereby, since the anion derived from electrolyte exists in large quantities with respect to rubeanic acid (derivative), the effect of the said invention is acquired more reliably.

［前記式（１）中、Ｒ^１及びＲ^２は、それぞれ独立して、水素原子、ハロゲン原子、飽和鎖状炭化水素基、不飽和鎖状炭化水素基、飽和環状炭化水素基、不飽和環状炭化水素基、飽和複素環基、不飽和複素環基、芳香族炭化水素基、芳香族複素環基、カルボニル基、カルボキシル基、アミノ基、アミド基、水酸基、スルフィド基、ジスルフィド基又はスルホン基を表す。］ In this case, it is preferable that the rubeanic acid or rubeanic acid derivative has a structural unit represented by the following formula (1).

[In the formula (1), R ¹ and R ² are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, a saturated cyclic hydrocarbon group, or an unsaturated cyclic group. Hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, disulfide group or sulfone group To express. ]

［前記式（２）中、Ｒ^１、Ｒ^２、Ｒ^３及びＲ^４は、それぞれ独立して、水素原子、ハロゲン原子、飽和鎖状炭化水素基、不飽和鎖状炭化水素基、飽和環状炭化水素基、不飽和環状炭化水素基、飽和複素環基、不飽和複素環基、芳香族炭化水素基、芳香族複素環基、カルボニル基、カルボキシル基、アミノ基、アミド基、水酸基、スルフィド基、ジスルフィド基又はスルホン基を表し、ｎは１以上の整数を表す。］ In this case, the rubeanic acid or rubeanic acid derivative is preferably represented by the following formula (2).

[In the formula (2), R ¹ , R ² , R ³ and R ⁴ are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, or a saturated cyclic hydrocarbon. Hydrogen group, unsaturated cyclic hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, A disulfide group or a sulfone group is represented, and n represents an integer of 1 or more. ]

In this case, the anion includes PF ₆ ⁻ , AsF ₆ ⁻ , BF ₄ ⁻ , Cl ⁻ , Br ⁻ , ClO ₄ ⁻ , CH ₃ SO ₃ ⁻ , CF ₃ SO ₃ ⁻ , C ₄ F ₉ SO ₃ ⁻ , It is preferably at least one selected from the group consisting of (CF ₃ SO ₂ ) ₂ N ⁻ and (CF ₃ SO ₂ ) ₃ C ⁻ .

［上記式（ＩＩ）中、Ｒ^１及びＲ^２は、上記式（１）又は（２）と同様であり、Ａ⁻は、上記で列挙した各種アニオンを表し、Ｍ^＋は、Ｌｉ^＋、Ｎａ^＋及びＫ^＋を含むアルカリ金属カチオン、並びに、Ｂｅ^２＋、Ｍｇ^２＋及びＣａ^２＋を含む第２族元素の２価の金属カチオンからなる群より選ばれる少なくとも１種の金属カチオンを表す。］ According to rubeanic acid (derivative) represented by the above formula (1) or (2), it can take a form from an oxidant to a reductant as shown in the following formula (II). Therefore, a higher charge / discharge capacity density can be obtained than in the prior art.

[In the above formula (II), R ¹ and R ² are the same as in the above formula (1) or (2), A ⁻ represents the various anions listed above, and M ⁺ represents Li ⁺ , Na ^It represents at least one metal cation selected from the group consisting of alkali metal cations including ⁺ and K ⁺ and divalent metal cations of Group 2 elements including Be ²⁺ , Mg ²⁺ and Ca ²⁺ . ]

  ADVANTAGE OF THE INVENTION According to this invention, the battery which has high charge / discharge capacity compared with the past can be provided.

It is a longitudinal cross-sectional view which shows the structure of the battery which concerns on one Embodiment of this invention. 2 is a charge / discharge curve diagram of the battery obtained in Example 1. FIG. 4 is a charge / discharge curve diagram of the battery obtained in Example 2. FIG. It is a figure which shows the relationship between the discharge capacity density (mAh / g) in each Example and a comparative example, and the amount of anions / positive electrode active material (mol / mol ratio).

Hereinafter, an embodiment of the present invention will be described in detail with reference to the drawings.
FIG. 1 is a longitudinal sectional view showing a configuration of a battery 1 according to an embodiment of the present invention. In the following description, the vertical direction will be described with reference to the vertical direction in FIG.

As shown in FIG. 1, the battery 1 is a coin-type lithium battery whose outer shape is a disk shape, and corresponds to the CR2032 standard. The battery 1 includes a positive electrode can 7 disposed on the lower side and a negative electrode can 8 disposed on the upper side, and includes a positive electrode 2 and a negative electrode 3 provided in this order from the lower side. .
A separator 4 is sandwiched between the positive electrode 2 and the negative electrode 3 to separate them from each other. A current collector 5 is disposed between the positive electrode 2 and the positive electrode can 7, and the positive electrode can 7 and the negative electrode can 8 are electrically insulated by a gasket 6.

［前記式（１）中、Ｒ^１及びＲ^２は、それぞれ独立して、水素原子、ハロゲン原子、飽和鎖状炭化水素基、不飽和鎖状炭化水素基、飽和環状炭化水素基、不飽和環状炭化水素基、飽和複素環基、不飽和複素環基、芳香族炭化水素基、芳香族複素環基、カルボニル基、カルボキシル基、アミノ基、アミド基、水酸基、スルフィド基、ジスルフィド基又はスルホン基を表す。］ The positive electrode 2 contains rubeanic acid or a rubeanic acid derivative as an active material. Here, the “rubberic acid derivative” means a compound containing rubeanic acid, and includes a rubeanic acid polymer and the like.
Rubeanic acid (derivative) preferably has a structural unit represented by the following formula (1).

[In the formula (1), R ¹ and R ² are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, a saturated cyclic hydrocarbon group, or an unsaturated cyclic group. Hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, disulfide group or sulfone group To express. ]

［前記式（２）中、Ｒ^１、Ｒ^２、Ｒ^３及びＲ^４は、それぞれ独立して、水素原子、ハロゲン原子、飽和鎖状炭化水素基、不飽和鎖状炭化水素基、飽和環状炭化水素基、不飽和環状炭化水素基、飽和複素環基、不飽和複素環基、芳香族炭化水素基、芳香族複素環基、カルボニル基、カルボキシル基、アミノ基、アミド基、水酸基、スルフィド基、ジスルフィド基又はスルホン基を表し、ｎは１以上の整数を表す。］ Moreover, it is preferable that a rubeanic acid (derivative) is represented by following formula (2).

[In the formula (2), R ¹ , R ² , R ³ and R ⁴ are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, or a saturated cyclic hydrocarbon. Hydrogen group, unsaturated cyclic hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, A disulfide group or a sulfone group is represented, and n represents an integer of 1 or more. ]

In the present embodiment, rubeanic acid _{(NH 2 -CS-CS-NH} 2) it is particularly preferred. Rubeanic acid itself does not have electrical conductivity.

  As will be described later, rubeanic acid (derivative) may contain lithium (lithium ions) in a previously reduced form.

The positive electrode 2 preferably contains a conductive additive and a binder.
Examples of the conductive assistant include carbon materials such as acetylene black, ketjen black, graphite, and scaly graphite, metal powders such as nickel powder, titanium powder, silver powder, and tungsten powder, and conductive materials such as polyaniline, polypyrrole, and polyacetylene. Examples include molecular compounds.
Examples of the binder include polytetrafluoroethylene and polyvinylidene fluoride.

Moreover, the positive electrode 2 may contain the electrolyte mentioned later and may contain other active materials other than rubeanic acid (derivative).
Other active materials are not particularly limited as long as they can occlude and release lithium ions. For example, what contains lithium ions, such as lithium salt, is mentioned, Among these, lithium transition metal complex oxide is preferable.
Examples of the lithium transition metal composite oxide include lithium cobaltate, lithium nickelate, lithium manganate, and nickel cobalt lithium manganate.

  The content of rubeanic acid (derivative) contained in the positive electrode 2 is preferably 1 to 100% by mass, and more preferably 50 to 100% by mass.

The negative electrode 3 includes an active material that can occlude (insert) and release (desorb) lithium ions.
Examples of the active material include those containing lithium element (for example, lithium atom, metallic lithium, lithium ion, lithium salt) and those not containing lithium element.
Examples of those containing lithium element include metal lithium (including lithium alloys containing aluminum and the like), lithium nitride such as Li _2.4 Co _0.6 N, and lithium oxide such as lithium titanate. Things.
Examples of materials that do not contain lithium element include graphite materials such as mesocarbon microbeads (MCMB), those obtained by firing and carbonizing phenol resins and pitches, carbon-based materials such as activated carbon and graphite, SiO, SiO _{2 and the} like. silicon-based materials, SnO, tin-based materials SnO ₂ or the like, PbO, lead-based materials such as PbO _2, GeO, germanium-based material GeO ₂ or the like, phosphorus-based materials, niobium-based material, an antimony-based material, and, of these A mixture of materials can be mentioned.

The negative electrode 3 may contain the above-mentioned conductive additive and a binder.
As the negative electrode 3, for example, when the positive electrode 2 contains no lithium element, for example, one containing metallic lithium is used, and when the positive electrode 2 contains lithium element (lithium ions or the like), the lithium element contains lithium element. Although the thing used is also used, what does not contain lithium element can also be used.
Note that a non-aqueous solution battery that does not contain lithium element in the positive electrode 2 and contains metallic lithium in the negative electrode 3 can also function as a primary battery.

Examples of the separator 4 include a resin sheet containing an electrolyte solution described later, a gel-like material containing an electrolyte described later, and a solid material.
The resin that forms the resin sheet may be a conventionally known resin, and examples thereof include polyolefin resins. As matrix resin of the separator 4 which consists of a solid substance containing electrolyte, a polyethylene oxide polymer, a boric-ester polymer, etc. are mentioned, for example.
The gel and solid are used after being formed into a plate shape. By using a gel-like material and a solid material as the separator 4, it is avoided that rubeanic acid (derivative) contained in the positive electrode 2 elutes into the electrolytic solution over time, and deterioration of the battery 1 is suppressed.

An electrolytic solution in which an electrolyte is dissolved in a solvent is used.
Examples of the electrolyte include LiPF ₆ , LiAsF ₆ , LiBF ₄ , LiCl, LiBr, LiClO ₄ , LiCH ₃ SO ₃ , LiCF ₃ SO ₃ , LiC ₄ F ₉ SO ₃ , LiN (CF ₃ SO ₂ ) ₂ and LiC ( CF ₃ SO ₂ ) ₃ is preferably at least one selected from the group consisting of ₃ .
According to these electrolytes, PF ₆ ⁻ , AsF ₆ ⁻ , BF ₄ ⁻ , Cl ⁻ , Br ⁻ , ClO ₄ ⁻ , CH ₃ SO ₃ ⁻ , CF ₃ SO ₃ ⁻ , C ₄ F are used as electrolyte-derived anions. ₉ SO ₃ ⁻ , (CF ₃ SO ₂ ) ₂ N ⁻ , and (CF ₃ SO ₂ ) ₃ C ⁻ are supplied.

  Examples of the solvent that dissolves the electrolyte include carbonate esters such as ethylene carbonate, propylene carbonate, dimethyl carbonate, methyl ethyl carbot, and diethyl carbonate, and esters such as methyl propionate, ethyl propionate, and γ-butyrolactone. (Including cyclic esters) type solvents, monoglyme (ethylene glycol dimethyl ether), diglyme (diethylene glycol dimethyl ether), triglyme (triethylene glycol dimethyl ether), tetraglyme (tetraethylene glycol dimethyl ether) and other ether type solvents, and mixed solvents thereof Is mentioned.

  The molar concentration of the electrolyte in the electrolytic solution is set higher than 1.0 mol / L. By doing in this way, many anions derived from electrolyte exist, and rubeanic acid (derivative) can take the form from an oxidant to a reductant.

  In the battery 1 of the present embodiment having the above-described configuration, the ratio of the molar amount of the anion derived from the electrolyte to the molar amount of rubeanic acid (derivative) (the molar amount of anion / the molar amount of rubeanic acid (derivative)) is , 27 or more is preferable. In this case, the electrolyte concentration is higher than the conventional one and the amount of anion derived from the electrolyte is large, so that a higher charge / discharge capacity density than the conventional one can be obtained as will be described later.

  Next, operation | movement of the battery 1 of this embodiment is demonstrated. Specifically, the oxidation-reduction reaction of rubeanic acid (derivative) contained in the positive electrode 2 in the battery 1 having the negative electrode 3 containing metallic lithium will be described.

In the battery 1, rubeanic acid (derivative) contained in the positive electrode 2 changes reversibly into an oxidized form and a reduced form shown in the following formula (II). Here, R ¹ , R ² , A ⁻ and M ⁺ in the following formula (II) are as described above.

First, in the initial state in which neither charging nor discharging is performed, at the time of discharging (reducing), rubeanic acid (derivative) at the center of the above formula (II) is changed to a reductant on the right side.
At this time, the electrons (e ⁻ ) are generated when the metal lithium (Li) of the negative electrode 3 becomes lithium ions (Li ⁺ ), and the positive electrode 2 passes through the negative electrode can 8, the positive electrode can 7 and the current collector 5. To be supplied. Lithium ions (Li ⁺ ) are supplied to the positive electrode 2 via the electrolyte contained in the separator 4.

In addition, when the positive electrode 2 contains lithium and the negative electrode 3 is a lithium-free compound (for example, graphite), the battery 1 is in a discharged state immediately after assembling, and rubeanic acid (derivative) is represented by the above formula (II). It exists as a reductant on the right side. For this reason, when it starts from charge (oxidation), the reductant on the right side of the formula (II) changes to central rubeanic acid (derivative).
At this time, at the positive electrode 2, Li ions (Li ⁺ ) in the reductant are desorbed, and at the same time, electrons (e ⁻ ) are generated. The desorbed lithium ions (Li ⁺ ) go to the negative electrode 3 through the electrolyte contained in the separator 4 and are donated with electrons (e ⁻ ), thereby becoming metallic lithium (Li) and deposited on the negative electrode 3. To do. The generated electrons (e ⁻ ) are supplied to the negative electrode 3 via the positive electrode can 7, the load, and the negative electrode can 8. In the negative electrode 3, one lithium is inserted by receiving and taking out one π electron from six carbon groups having a hexagonal shape.

Furthermore, after changing to central rubeanic acid (derivative), it changes to the left oxidant.
At this time, rubeanic acid (derivative) releases electrons (e ⁻ ) at the positive electrode 2, and an anion (A ⁻ ) is supplied from the electrolyte contained in the separator 4 to the positive electrode 2. The emitted electrons (e ⁻ ) are supplied to the negative electrode 3 through the positive electrode can 7, the load, and the negative electrode can 8.

Next, when discharge is started, the left oxidant changes to central rubeanic acid (derivative).
At this time, the electrons (e ⁻ ) are generated when the metal lithium (Li) of the negative electrode 3 becomes lithium ions (Li ⁺ ), and the positive electrode 2 passes through the negative electrode can 8, the positive electrode can 7 and the current collector 5. To be supplied. Further, anions (A ⁻ ) are released and supplied to the electrolyte contained in the separator 4.

  Further, the discharge further proceeds, and the central rubeanic acid (derivative) is changed to the right reduced form. The battery 1 operates as described above.

Here, when rubeanic acid (derivative) emits electrons to form an oxidant, the counter anion A ⁻ for canceling the positive charge of rubeanic acid (derivative) is present only in the electrolytic solution. In addition, in the initial charge and discharge, a solid electrolyte interface (Solid Electrolyte Interface) called SEI having a function of suppressing the decomposition of the electrolytic solution and the electrode is formed on the surface of the electrode. Anions in the electrolyte are also consumed. For this reason, in a conventional battery, an oxidized form of rubeanic acid (derivative) cannot be formed during charging (oxidation).
On the other hand, as described above, in the battery 1 of the present embodiment, the molar concentration of the electrolyte in the electrolytic solution is set to a concentration higher than 1.0 mol / L, and the anion derived from the electrolyte as compared with the conventional case. A large amount is present. Thereby, the form from an oxidant to a reductant can be taken. In particular, when the ratio of the molar amount of the anion derived from the electrolyte to the molar amount of rubeanic acid (derivative) is set to 27 or more, the tendency is remarkable.

  Next, a method for manufacturing the battery 1 of the present embodiment will be described. The description will be divided into a first manufacturing method in the case where the negative electrode 3 contains metallic lithium and a second manufacturing method in the case where the negative electrode 3 does not contain metallic lithium.

The first manufacturing method will be described.
First, after kneading rubeanic acid (derivative), a conductive additive, and a binder, the kneaded material is spread into a sheet shape and punched into a predetermined shape to form the positive electrode 2.
Moreover, the negative electrode 3 is formed by punching a foil containing metallic lithium such as lithium or a lithium alloy into a predetermined shape.

  Next, the positive electrode 2 is disposed on the bottom of the positive electrode can 7 via the current collector 5, and the separator 4 is disposed on the positive electrode 2. The separator 4 is formed, for example, by impregnating a porous resin sheet disposed on the positive electrode 2 with an electrolytic solution. The separator 4 can also be formed by disposing a gel or solid containing an electrolyte on the positive electrode 2.

  Next, the negative electrode 3 is disposed on the separator 4, and the negative electrode can 8 is disposed on the negative electrode 3. At this time, the gasket 6 is disposed in order to electrically insulate the positive electrode can 7 and the negative electrode can 8. Then, the outer peripheral edge of the positive electrode can 7 is caulked and the positive electrode can 7 and the negative electrode can 8 are joined via the gasket 6. Thereby, the battery 1 is manufactured.

The second manufacturing method will be described.
First, an electrode body containing rubeanic acid (derivative) is prepared. In this step, an electrode body is manufactured in the same manner as the step of forming the positive electrode 2 by the first manufacturing method.

  Next, lithium (lithium ions) is occluded in the obtained electrode body to produce a first electrode. The first electrode can be obtained by reducing rubeanic acid (derivative) contained in the electrode body to change it into a reduced form and binding lithium ions thereto. As such a 1st electrode, after discharging the battery 1 obtained by the 1st manufacturing method, the positive electrode 2 taken out from this battery 1 can be used, for example.

  On the other hand, the second electrode is manufactured from an electrode material that is an active material capable of inserting and extracting lithium ions and does not contain metallic lithium. This second electrode is obtained by spreading a kneaded material containing an active material for a negative electrode such as the above-mentioned graphite material, carbon-based material, metal oxide, etc., a binder and, if necessary, a conductive additive into a sheet, It is produced by punching into a predetermined shape.

Next, the battery 1 is manufactured through a process of incorporating the first electrode as the positive electrode 2 and incorporating the second electrode as the negative electrode 3. As this process, except that the first electrode and the second electrode are used for the positive electrode 2 and the negative electrode 3, the current collector 5, the positive electrode 2, the separator 4, and the positive electrode can 7 are formed in the same manner as in the first manufacturing method. A process of sequentially assembling the negative electrode can 8 can be employed.
In the second manufacturing method as described above, the negative electrode 3 that does not contain highly reactive metallic lithium can be used.

According to the battery 1 of the present embodiment, the following effects are exhibited.
In this embodiment, rubeanic acid (derivative) was used as the active material of the positive electrode 2, and the molar concentration of the electrolyte in the electrolytic solution was set higher than 1.0 mol / L. That is, in the battery 1 using rubeanic acid (derivative) as the active material of the positive electrode 2, the electrolyte concentration in the electrolytic solution was increased more than before, and the molar amount of the anion derived from the electrolyte was increased.
Thereby, since anion derived from an electrolyte is present in a large amount, an oxidized form in which electrons are further extracted from the state of rubeanic acid (derivative) can be formed during charging (oxidation). Moreover, at the time of discharge (reduction), it can be made to discharge until a reductant is formed from this oxidant. Therefore, since rubeanic acid (derivative) can take a form from an oxidant to a reductant, a higher charge / discharge capacity density can be obtained than in the prior art.

  Further, in this embodiment, when the ratio of the molar amount of the electrolyte-derived anion to the molar amount of rubeanic acid (derivative) is set to 27 or more, the amount of anion derived from the electrolyte is large relative to rubeanic acid (derivative). Therefore, the above effect can be obtained more reliably.

  The battery 1 of the present embodiment can be applied to both a non-aqueous solution primary battery and a non-aqueous solution secondary battery. The non-aqueous solution type primary battery can be used, for example, as a power source for a wristwatch, a power source for a small music playback device, a power source for a small electronic device such as a personal computer backup. The nonaqueous solution secondary battery can be used for a mobile device such as a mobile phone and a digital camera, a power source for a moving body of an electric vehicle, a bipedal walking robot, and the like.

It should be noted that the present invention is not limited to the above-described embodiment, and modifications and improvements within the scope that can achieve the object of the present invention are included in the present invention.
In the above embodiment, a coin-type lithium battery is applied as the battery 1, but the present invention is not limited to this. For example, the present invention may be applied to a prismatic, cylindrical or paper type battery.

  Next, the present invention will be described in more detail based on examples, but the present invention is not limited thereto.

<Example 1>
[Production of positive electrode]
First, rubeanic acid having a purity of 99% or more (“D0957” manufactured by Tokyo Chemical Industry Co., Ltd.) was classified to prepare 5 g of rubeanic acid powder having a particle diameter of 5 to 40 μm.

  Next, 4 g of vapor-grown carbon fiber (“VGCF (registered trademark)” manufactured by Showa Denko KK) as a conductive auxiliary agent and 0.5 g of polytetrafluoroethylene (“6-J” manufactured by Mitsui DuPont Fluorochemical Co., Ltd.) as a binder, The rubeanic acid powder 0.5 g prepared above was sufficiently stirred with a small V mixer. After stirring, the mixture was kneaded in an automatic mortar to prepare a kneaded product.

  Next, the prepared kneaded material was formed into a sheet having a thickness of 0.3 mm and then punched out with a punch having a diameter of 14 mm, and a circular pure titanium net having a diameter of 14 mm (manufactured by Hokuto Denko Co., Ltd.). ) And pressed with a hydraulic press. As a result, a positive electrode in which a disc and a net were integrated was obtained.

  The obtained positive electrode was vacuum-dried at 80 ° C. for 16 hours, and then stored in a glove box having a dew point of −70 ° C. or lower in which argon gas circulates.

[Production of battery]
Using a coin-type battery member (made by Hosen Co., Ltd.) corresponding to the CR2032 standard, a non-aqueous solution type coin-type battery was produced. The positive electrode produced above was used as the positive electrode, and a circular metal lithium foil (thickness 0.2 mm, diameter 16 mm) with a purity of 99.95% was used as the negative electrode. As the separator, a disk (thickness 30 μm, diameter 20 mm) made of a polyolefin-based porous membrane (“Hypore (registered trademark)” manufactured by Asahi Kasei E-Materials) was vacuum-dried at 60 ° C. for 24 hours. The separator was impregnated by injecting 200 μL of the following polymer gel electrolyte precursor solution.

As the preparation of the polymer gel electrolyte precursor solution, first, a commercially available electrolytic solution in which LiPF ₆ was dissolved at 1.0 mol / L in a mixed solvent in which ethylene carbonate and diethyl carbonate were mixed at a volume ratio of 3: 7. (“LBG-94913” manufactured by Kishida Chemical Co., Ltd.) and LiPF ₆ (“LBG-45864” manufactured by Kishida Chemical Co., Ltd.) are added to prepare an electrolyte solution having a LiPF ₆ molar concentration of 1.8 mol / L. did.
Next, 3 parts by mass of an acrylate polymer solution having a substituent that crosslinks by heating is added to 97 parts by mass of the prepared electrolytic solution, and the mixture is stirred and mixed at room temperature for 15 minutes, whereby a polymer gel electrolyte precursor solution Was prepared.

  Finally, the coin-type battery impregnated with the polymer gel electrolyte precursor solution was heated in a thermostatic bath at 80 ° C. for 30 minutes. Thereby, the precursor solution of the polymer gel electrolyte was gelled, and a non-aqueous solution type coin type battery having the polymer gel electrolyte was obtained.

<Example 2>
Except that the method for preparing the polymer gel electrolyte precursor solution was different from that of Example 1, the same operation as in Example 1 was performed to obtain a non-aqueous solution type coin-type battery having a polymer gel electrolyte.
As the preparation of the polymer gel electrolyte precursor solution, first, a commercially available electrolytic solution in which LiPF ₆ was dissolved at 1.0 mol / L in a mixed solvent in which ethylene carbonate and diethyl carbonate were mixed at a volume ratio of 3: 7. (“LBG-94913” manufactured by Kishida Chemical Co., Ltd.) and LiPF ₆ (“LBG-45864” manufactured by Kishida Chemical Co., Ltd.) are added to prepare an electrolytic solution having a LiPF ₆ molar concentration of 1.5 mol / L. did.
Next, 3 parts by mass of an acrylate polymer solution having a substituent that crosslinks by heating is added to 97 parts by mass of the prepared electrolytic solution, and the mixture is stirred and mixed at room temperature for 15 minutes, whereby a polymer gel electrolyte precursor solution Was prepared.

<Comparative Example 1>
Except that the method for preparing the polymer gel electrolyte precursor solution was different from that of Example 1, the same operation as in Example 1 was performed to obtain a non-aqueous solution type coin-type battery having a polymer gel electrolyte.
As the preparation of the polymer gel electrolyte precursor solution, first, a commercially available electrolytic solution in which LiPF ₆ was dissolved at 1.0 mol / L in a mixed solvent in which ethylene carbonate and diethyl carbonate were mixed at a volume ratio of 3: 7. (“LBG-94913” manufactured by Kishida Chemical Co., Ltd.) was used as it was.
Next, 3 parts by mass of an acrylate polymer solution having a substituent that crosslinks by heating is added to 97 parts by mass of the commercially available electrolytic solution, and the mixture is stirred and mixed at room temperature for 15 minutes, whereby a precursor of a polymer gel electrolyte is obtained. A solution was prepared.

<Charge / discharge test>
The battery obtained in each example and comparative example was subjected to a charge / discharge test. The charge / discharge test was carried out after leaving each battery immediately after fabrication at room temperature for 1 hour. Specifically, the voltage (potential difference between the positive and negative electrodes) that changes with time when charged and discharged at a constant current of 0.1 mA in a thermostat maintained at 25 ° C. ± 2 ° C. was measured.

  FIG. 2 shows the charge / discharge curve of Example 1, and FIG. 3 shows the charge / discharge curve of Example 2. Moreover, the relationship between the discharge capacity density (mAh / g) and the anion amount / positive electrode active material amount (mol / mol ratio) in each Example and Comparative Example is shown in FIG. 4 based on the charge / discharge test results. Furthermore, Table 1 summarizes the compositions and charge / discharge test results of Examples and Comparative Examples.

2 and 3, the vertical axis represents voltage (V), and the horizontal axis represents the capacity density (mAh / g) per mass of the positive electrode active material (rubberic acid). 2, 3, and 4, it can be seen that Example 1 and Example 2 have a higher discharge capacity density than Comparative Example 1, and in particular, Example 1 has a higher discharge capacity density.
From the above results, as shown in Table 1, the battery of Example 1 and the battery of Example 2 in which the electrolyte concentration in the electrolytic solution is higher than 1.0 mol / L have an electrolyte concentration of 1.0 mol in the electrolytic solution. It was confirmed that the charge / discharge capacity density was high as compared with the battery of Comparative Example 1 which was / L. Here, the battery of Comparative Example 1 corresponds to the battery disclosed in Patent Document 1, and according to the present invention, it was confirmed that a battery having a higher charge / discharge capacity density than the conventional battery can be provided. .
Further, the battery of Example 1 in which the amount of anion / positive electrode active material (mol / mol ratio) is 27 or more is the battery of Example 2 in which the amount of anion / positive electrode active material (mol / mol ratio) is less than 27. It was also confirmed that the charge / discharge capacity density was higher than that of the battery of Comparative Example 1.

DESCRIPTION OF SYMBOLS 1 ... Battery 2 ... Positive electrode 3 ... Negative electrode 4 ... Separator

Claims (5)

A battery comprising a positive electrode, a negative electrode, and an electrolyte solution containing an electrolyte interposed between the positive electrode and the negative electrode,
The positive electrode includes rubeanic acid or a rubeanic acid derivative as an active material,
The battery, wherein a molar concentration of the electrolyte in the electrolytic solution is higher than 1.0 mol / L.   The battery according to claim 1, wherein a ratio of a molar amount of the anion derived from the electrolyte to a molar amount of the rubeanic acid or rubeanic acid derivative is 27 or more. The battery according to claim 1 or 2, wherein the rubeanic acid or rubeanic acid derivative has a structural unit represented by the following formula (1).

[In the formula (1), R ¹ and R ² are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, a saturated cyclic hydrocarbon group, or an unsaturated cyclic group. Hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, disulfide group or sulfone group To express. ] The battery according to claim 1 or 2, wherein the rubeanic acid or rubeanic acid derivative is represented by the following formula (2).

[In the formula (2), R ¹ , R ² , R ³ and R ⁴ are each independently a hydrogen atom, a halogen atom, a saturated chain hydrocarbon group, an unsaturated chain hydrocarbon group, or a saturated cyclic hydrocarbon. Hydrogen group, unsaturated cyclic hydrocarbon group, saturated heterocyclic group, unsaturated heterocyclic group, aromatic hydrocarbon group, aromatic heterocyclic group, carbonyl group, carboxyl group, amino group, amide group, hydroxyl group, sulfide group, A disulfide group or a sulfone group is represented, and n represents an integer of 1 or more. ] The anion derived from the electrolyte includes PF ₆ ⁻ , AsF ₆ ⁻ , BF ₄ ⁻ , Cl ⁻ , Br ⁻ , ClO ₄ ⁻ , CH ₃ SO ₃ ⁻ , CF ₃ SO ₃ ⁻ , C ₄ F ₉ SO ₃ ⁻ , ( CF ₃ SO _{2) 2} N ^- and _{(CF 3 SO 2) 3 C} -, battery of claims 1 4, wherein any one, characterized in that at least one selected from the group consisting of.

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