WO2012087612A3 - High purity heavy normal paraffins utilizing integrated systems - Google Patents

High purity heavy normal paraffins utilizing integrated systems Download PDF

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Publication number
WO2012087612A3
WO2012087612A3 PCT/US2011/064142 US2011064142W WO2012087612A3 WO 2012087612 A3 WO2012087612 A3 WO 2012087612A3 US 2011064142 W US2011064142 W US 2011064142W WO 2012087612 A3 WO2012087612 A3 WO 2012087612A3
Authority
WO
WIPO (PCT)
Prior art keywords
normal paraffins
high purity
integrated systems
utilizing integrated
heavy normal
Prior art date
Application number
PCT/US2011/064142
Other languages
French (fr)
Other versions
WO2012087612A2 (en
Inventor
Stephen W. Sohn
Andrea G. Bozzano
Jeffrey L. PIEPER
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Priority to CN2011800601027A priority Critical patent/CN103261377A/en
Priority to EP11851587.3A priority patent/EP2655565A2/en
Publication of WO2012087612A2 publication Critical patent/WO2012087612A2/en
Publication of WO2012087612A3 publication Critical patent/WO2012087612A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/06—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil
    • C10G25/08—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents with moving sorbents or sorbents dispersed in the oil according to the "moving bed" method
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00—Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/12—Recovery of used adsorbent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44—Hydrogenation of the aromatic hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G7/00—Distillation of hydrocarbon oils
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/30—Aromatics

Abstract

A process is presented for producing a purified normal paraffin product stream. The process includes passing a hydrocarbon stream having the desired normal paraffins to an adsorption separation system. A process stream generated from the separation system and having the normal paraffins is passed to an adsorption unit for the selective adsorption of aromatic compounds from the process stream, thereby producing a purified product.
PCT/US2011/064142 2010-12-22 2011-12-09 High purity heavy normal paraffins utilizing integrated systems WO2012087612A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2011800601027A CN103261377A (en) 2010-12-22 2011-12-09 High purity heavy normal paraffins utilizing integrated systems
EP11851587.3A EP2655565A2 (en) 2010-12-22 2011-12-09 High purity heavy normal paraffins utilizing integrated systems

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/976,295 US20120160742A1 (en) 2010-12-22 2010-12-22 High Purity Heavy Normal Paraffins Utilizing Integrated Systems
US12/976,295 2010-12-22

Publications (2)

Publication Number Publication Date
WO2012087612A2 WO2012087612A2 (en) 2012-06-28
WO2012087612A3 true WO2012087612A3 (en) 2012-10-04

Family

ID=46314738

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/064142 WO2012087612A2 (en) 2010-12-22 2011-12-09 High purity heavy normal paraffins utilizing integrated systems

Country Status (4)

Country Link
US (1) US20120160742A1 (en)
EP (1) EP2655565A2 (en)
CN (1) CN103261377A (en)
WO (1) WO2012087612A2 (en)

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US20150045597A1 (en) * 2013-08-07 2015-02-12 Uop Llc Integrated process for gasoline or aromatics production
WO2016094843A2 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system comprising mesoporous organosilica support
US10183272B2 (en) 2014-12-12 2019-01-22 Exxonmobil Research And Engineering Company Adsorbent for heteroatom species removal and uses thereof
US9956541B2 (en) 2014-12-12 2018-05-01 Exxonmobil Research And Engineering Company Methods of separating aromatic compounds from lube base stocks
US10047304B2 (en) 2014-12-12 2018-08-14 Exxonmobil Research And Engineering Company Aromatic hydrogenation catalysts and uses thereof
SG11201702538PA (en) 2014-12-12 2017-06-29 Exxonmobil Res & Eng Co Methods of separating aromatic compounds from lube base stockes
US10207249B2 (en) 2014-12-12 2019-02-19 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
SG11201702577SA (en) 2014-12-12 2017-06-29 Exxonmobil Res & Eng Co Coating methods using organosilica materials and uses thereof
US10576453B2 (en) 2014-12-12 2020-03-03 Exxonmobil Research And Engineering Company Membrane fabrication methods using organosilica materials and uses thereof
US10155826B2 (en) 2014-12-12 2018-12-18 Exxonmobil Research And Engineering Company Olefin polymerization catalyst system comprising mesoporous organosilica support
US10022700B2 (en) 2014-12-12 2018-07-17 Exxonmobil Research And Engineering Company Organosilica materials and uses thereof
WO2016094848A1 (en) 2014-12-12 2016-06-16 Exxonmobil Chemical Patents Inc. Organosilica materials for use as adsorbents for oxygenate removal
CN107949624B (en) 2015-09-04 2021-02-05 国际壳牌研究有限公司 Process for preparing paraffins and waxes
WO2017213667A1 (en) 2016-06-10 2017-12-14 Exxonmobil Research And Engineering Company Organosilica materials, methods of making, and uses thereof
EP3468712A1 (en) 2016-06-10 2019-04-17 Exxonmobil Research And Engineering Company Organosilica polymer catalysts and methods of making the same
EP3535354A1 (en) 2016-11-07 2019-09-11 Shell Internationale Research Maatschappij B.V. Process to prepare normal paraffins
BR112019008964A2 (en) 2016-11-07 2019-07-09 Shell Int Research preparing a normal paraffin composition, and process for preparing linear alkyl benzene sulfonate
US20190276754A1 (en) 2016-11-07 2019-09-12 Shell Oil Company Process to prepare normal paraffins
US10179839B2 (en) 2016-11-18 2019-01-15 Exxonmobil Research And Engineering Company Sulfur terminated organosilica materials and uses thereof
US10052580B2 (en) 2016-12-28 2018-08-21 Uop Llc Trim bed for adsorption separation zone
US11111352B2 (en) 2017-12-21 2021-09-07 Exxonmobil Research And Engineering Company Methods of producing organosilica materials and uses thereof

Citations (4)

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Publication number Priority date Publication date Assignee Title
US4719007A (en) * 1986-10-30 1988-01-12 Uop Inc. Process for hydrotreating a hydrocarbonaceous charge stock
US5139646A (en) * 1990-11-30 1992-08-18 Uop Process for refractory compound removal in a hydrocracker recycle liquid
WO1998030523A1 (en) * 1997-01-08 1998-07-16 Catalytic Distillation Technologies Process and apparatus for the production and recovery of p-xylene
US20100116711A1 (en) * 2008-11-12 2010-05-13 Kellogg Brown & Root Llc Systems and Methods for Producing N-Paraffins From Low Value Feedstocks

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US5510564A (en) * 1994-12-12 1996-04-23 Uop N-paraffin purification process with removal of aromatics
US6162956A (en) * 1998-08-18 2000-12-19 Exxon Research And Engineering Co Stability Fischer-Tropsch diesel fuel and a process for its production
MY143120A (en) * 2003-02-20 2011-03-15 Shell Int Research A process for the preparation of detergent compounds
US20050040078A1 (en) * 2003-08-20 2005-02-24 Zinnen Herman A. Process for the desulfurization of hydrocarbonacecus oil
US8053620B2 (en) * 2008-06-30 2011-11-08 Uop Llc Guard bed for removing contaminants from feedstock to a normal paraffin extraction unit

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4719007A (en) * 1986-10-30 1988-01-12 Uop Inc. Process for hydrotreating a hydrocarbonaceous charge stock
US5139646A (en) * 1990-11-30 1992-08-18 Uop Process for refractory compound removal in a hydrocracker recycle liquid
WO1998030523A1 (en) * 1997-01-08 1998-07-16 Catalytic Distillation Technologies Process and apparatus for the production and recovery of p-xylene
US20100116711A1 (en) * 2008-11-12 2010-05-13 Kellogg Brown & Root Llc Systems and Methods for Producing N-Paraffins From Low Value Feedstocks

Also Published As

Publication number Publication date
CN103261377A (en) 2013-08-21
WO2012087612A2 (en) 2012-06-28
US20120160742A1 (en) 2012-06-28
EP2655565A2 (en) 2013-10-30

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