WO2012073840A1 - Production method for shredded cabbage - Google Patents

Production method for shredded cabbage Download PDF

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Publication number
WO2012073840A1
WO2012073840A1 PCT/JP2011/077254 JP2011077254W WO2012073840A1 WO 2012073840 A1 WO2012073840 A1 WO 2012073840A1 JP 2011077254 W JP2011077254 W JP 2011077254W WO 2012073840 A1 WO2012073840 A1 WO 2012073840A1
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WO
WIPO (PCT)
Prior art keywords
cabbage
aqueous solution
bactericidal
shredded
ppm
Prior art date
Application number
PCT/JP2011/077254
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French (fr)
Japanese (ja)
Inventor
藤村亮太郎
山川真美
Original Assignee
キユーピー 株式会社
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Publication date
Application filed by キユーピー 株式会社 filed Critical キユーピー 株式会社
Priority to JP2012510467A priority Critical patent/JP4994524B2/en
Priority to CN201180057018.XA priority patent/CN103228157B/en
Publication of WO2012073840A1 publication Critical patent/WO2012073840A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/157Inorganic compounds
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L19/00Products from fruits or vegetables; Preparation or treatment thereof
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L3/00Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
    • A23L3/34Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
    • A23L3/3454Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
    • A23L3/358Inorganic compounds

Definitions

  • the present invention relates to a method for producing shredded cabbage.
  • the shredded cabbage product which is a shredded cabbage sealed with nitrogen gas in a polypropylene bag, is widely sold at the supermarket fresh vegetables section.
  • As an industrial production method of such shredded cabbage for example, a method in which cut cabbage is washed with a sodium hypochlorite solution, then washed with water and then washed with an acetic acid solution (Patent Document 1), and cut cabbage is chlorinated.
  • Patent Document 2 After treating with an acid salt solution, draining without rinsing and storing as it is (Patent Document 2), after cabbage before shredding is immersed in a sterilizing solution such as hypochlorite aqueous solution and primary sterilizing treatment, Chopping with a slicer, followed by dipping in a bactericidal solution having a weaker bactericidal power than hypochlorite aqueous solution, secondary sterilization treatment, washing with water, and draining with a centrifuge (Patent Document 3), etc. Has been proposed.
  • a sterilizing solution such as hypochlorite aqueous solution and primary sterilizing treatment, Chopping with a slicer, followed by dipping in a bactericidal solution having a weaker bactericidal power than hypochlorite aqueous solution, secondary sterilization treatment, washing with water, and draining with a centrifuge
  • JP-A-6-46812 Japanese Patent Application Laid-Open No. 11-196763 JP 2006-61069 A
  • An object of the present invention is to solve the above-described conventional problems, and to provide a method for industrially producing shredded cabbage that exhibits good storage stability and greatly reduces or does not feel the taste. is there.
  • the present inventors investigated at which stage the cabbage's egg flavor appears in the shredded cabbage production line, and found that after the cabbage was shredded, the egg flavor was developed.
  • the taste of the cabbage shredded with a food slicer is expressed while receiving it in a large colander for batch injection into a sterilized water tank. It has been found that the shrimp can not be removed even if the shredded cabbage in which the odor is expressed is put into the sterilization treatment step.
  • this invention is a manufacturing method of shredded cabbage, Comprising: The manufacturing method which has the following (sterilization process), (striping process), and (water exposure process) is provided.
  • the shredded cabbage that has been sterilized by being brought into contact with a bactericide aqueous solution is shredded while pouring fresh water into the cut portion, and then subjected to water exposure for a certain time or longer. For this reason, the cabbage before shredding is sufficiently sterilized, the cross section of the cabbage and the cut surface of the shredded cabbage are cleaned almost simultaneously with the cutting, and the cleaned shredded cabbage is exposed to water. The shredded cabbage is greatly reduced or can not be felt.
  • the cabbage before shredding is sterilized by bringing it into contact with a bactericidal solution.
  • the purpose of this treatment is to thoroughly sterilize before the subsequent process consisting of a shredding process and subsequent water exposure process, while pouring water into the cut part for the purpose of reducing or preventing the appearance of the taste. is there.
  • the bacteria to be sterilized are typically soil-derived bacteria that can adhere to vegetables and reduce their freshness.
  • the level of bactericidal power (relatively strong bactericidal power) of a bactericidal agent that can obtain a sufficient bactericidal effect is the food hygiene inspection guidelines supervised by the Ministry of Health, Labor and Welfare (Microorganisms, pages 116-123, 2004: Issuer: Association)
  • the number of general bacteria measured according to Japan Food Hygiene Association, publisher; Takeshi Tamaki) can be used as an index. Specifically, it means that the number of general bacteria is less than 1 ⁇ 10 4 CFU / g.
  • Examples of such a bactericidal agent having a relatively strong bactericidal power include hypochlorite aqueous solution, hypochlorous acid generating electrolyte solution, aqueous solution of alkaline agent such as alkali hydroxide and calcined calcium, and mineral acid such as hydrochloric acid.
  • Examples include bactericides such as aqueous solutions. Specifically, it is preferable to use at least one aqueous solution selected from the group consisting of sodium hypochlorite, sodium hydroxide, potassium hydroxide, calcined calcium and hydrochloric acid. Two or more aqueous bactericidal agents can be used in combination.
  • hypochlorite aqueous solution, particularly sodium hypochlorite aqueous solution can be preferably used from the viewpoint of flavor.
  • the content of the sterilization treatment is to bring the bactericide aqueous solution into contact with the cabbage before shredding.
  • the cabbage before shredding is immersed in the bactericidal aqueous solution, or the cabbage before shredding the sanitizer aqueous solution.
  • Spraying can be mentioned.
  • cabbage before shredding it is possible to apply a cabbage from which inedible parts such as a core are removed, for example, a hole cabbage from which a core has been removed, a product obtained by cutting it into two or four equal parts, Alternatively, leaves separated from whole cabbage can be applied. Moreover, you may wash with water before sterilizing.
  • the treatment conditions for the sterilization treatment can be appropriately determined according to the type of the bactericidal solution used, the type and size of the cabbage to be sterilized, and the like.
  • a hypochlorite aqueous solution for example, a sodium hypochlorite aqueous solution is used as the bactericide aqueous solution and the cabbage is immersed
  • the hypochlorite concentration in the hypochlorite aqueous solution is too low.
  • the bactericidal effect is not sufficient, and if it is too high, the damage to the plant cells tends to be too great. Therefore, it is preferably set to 10 to 500 ppm, more preferably 30 to 400 ppm, and particularly preferably 100 to 200 ppm.
  • the pH of the hypochlorite aqueous solution is too low, the damage to the plant cells is great, and if it is too high, the bactericidal effect tends to be insufficient, so it is preferably 4-10, more preferably 6-9.
  • it is preferably 4-10, more preferably 6-9.
  • the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
  • an alkali hydroxide aqueous solution for example, a sodium hydroxide aqueous solution or a potassium hydroxide aqueous solution is used as the bactericide aqueous solution and the cabbage is immersed
  • the bactericidal effect is sufficient if the alkali hydroxide concentration in the aqueous alkali hydroxide solution is too low.
  • it is preferably set to 10 to 40,000 ppm, more preferably 100 to 20000 ppm, and particularly preferably 100 to 10,000 ppm.
  • the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
  • a calcined calcium aqueous solution as a bactericidal aqueous solution and immersing cabbage
  • the calcined calcium concentration in the calcined calcium aqueous solution is too low, the bactericidal effect is not sufficient, and if it is too high, damage to plant cells increases. Therefore, it is preferably set to 10 to 40000 ppm, more preferably 100 to 10000 ppm, and particularly preferably 100 to 1000 ppm.
  • the pH of the calcined calcium aqueous solution is too low, the damage to the plant cells is large, and when it is too high, the bactericidal effect tends to be insufficient.
  • the pH is preferably 11 to 13.5, more preferably 11 to 13.
  • the pH is preferably 11 to 13.5, more preferably 11 to 13.
  • it is preferably 0 to 50 ° C., more preferably 0 to 15 ° C.
  • the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
  • the concentration of hydrochloric acid in the aqueous hydrochloric acid solution is too low if the bactericidal effect is sufficient, and if it is too high, damage to plant cells tends to be too great. Therefore, it is preferably set to 10 to 40000 ppm, more preferably 10 to 10000 ppm, and particularly preferably 10 to 5000 ppm.
  • the pH of the aqueous hydrochloric acid solution is preferably set to 2 to 5, more preferably 2 to 4, since the damage to the plant cells is great if it is too low and the bactericidal effect tends to be insufficient if it is too high. If the cabbage before chopping to be sterilized in hydrochloric acid aqueous solution is too low, there is a possibility of freezing damage to plant bacteria, and if it is too high, there is a tendency to increase the number of bacteria and promote browning.
  • the temperature is preferably 0 to 50 ° C., more preferably 0 to 15 ° C.
  • the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
  • various additives such as sodium chlorite may be blended in the above-mentioned bactericidal solution including the hypochlorite aqueous solution as long as the effects of the present invention are not impaired.
  • sterilized cabbage that has been sterilized and obtained in the sterilization process may be washed with water and further drained as necessary before being put into the shredding process described below.
  • the width of shredded cabbage if the width of shredded cabbage is too narrow, the cut area of cabbage becomes large and the taste of the shredded cabbage tends to be expressed, and the preferred taste of shredded cabbage becomes difficult to obtain. It is 3 mm, more preferably 0.5 to 2 mm.
  • specific methods of pouring fresh water include pouring water from a hose, pouring water from a shower head, and the like. Also, if the flow rate of fresh water when pouring fresh water is too small, it becomes difficult to sufficiently remove the cabbage's taste, so it is preferably 0.1 L / min or more with respect to 1 kg / min of shredded cabbage. More preferably, it is 0.2 L / min or more.
  • the preferred range of fresh water flow rate is 1 kg of cabbage shredder processing amount 0.1 to 10 L / min relative to / min, a more preferable range is 0.1 to 5 L / min, and a particularly preferable range is 0.2 to 3 L / min.
  • the shredded cabbage obtained in the shredded process is preferably immediately put into the water exposure process described later, but may be stored on a colander or a belt conveyor until a predetermined amount of shredded cabbage is accumulated. In that case, it is preferable to continue pouring fresh water.
  • the water exposure treatment temperature is usually 0 to 50 ° C., more preferably 0 to 10 ° C. Further, if the exposure time is too short, there is a possibility that a taste remains, so that the exposure is performed for 3 minutes or more, preferably 5 minutes or more, more preferably 10 minutes or more. If the water exposure time is too long, the cabbage tissue after shredding will be damaged or the cabbage juice that has oozed out will flow too much, resulting in an effect on the cabbage taste (specifically, The water exposure time is preferably 60 minutes or less, more preferably 30 minutes or less.
  • the shredded cabbage after the water exposure step is drained using a known centrifugal drainer, and the resulting shredded cabbage is applied to a thermoplastic resin bag such as polypropylene with nitrogen gas as necessary.
  • a shredded cabbage product can be obtained by filling and sealing with an inert gas such as.
  • this water exposure process it may replace with fresh water and may use the bactericide aqueous solution containing the bactericide which has weaker bactericidal power than the bactericide used at the bactericidal process.
  • the preservability of shredded cabbage can be improved without impairing the flavor.
  • the level of the bactericidal power (relatively weak bactericidal power) of the bactericidal agent having a weaker bactericidal power than the bactericidal agent used in the sterilizing process is the food hygiene inspection guidelines supervised by the Ministry of Health, Labor and Welfare (microorganism edition, pages 116 to 123, 2004: Issuer: The number of general bacteria measured according to Japan Food Sanitation Association, issuer: Takeshi Tamaki) can be used as an index. Specifically, it means a case where the number of general bacteria is 1 ⁇ 10 4 CFU / g or more to less than 1 ⁇ 10 6 CFU / g.
  • chlorite preferably sodium salt
  • acetic acid citric acid, phosphoric acid, ethanol and the like
  • citric acid citric acid
  • phosphoric acid ethanol
  • the like can be used as such a bactericidal agent exhibiting a relatively weak bactericidal power.
  • at least one aqueous solution selected from the group consisting of ozone, sodium chlorite and acetic acid can be used.
  • sodium chlorite and ozone water can be preferably used from the viewpoint of flavor.
  • the ozone concentration in the ozone water is too low if the bactericidal effect is sufficient, and if it is too high, there is a concern of damaging plant cells,
  • it is set to 0.5 to 10 ppm, more preferably 1 to 5 ppm. If the temperature at which the shredded cabbage to be sterilized is immersed in ozone water is too low, there is a possibility of freezing damage to the plant, and if it is too high, the bacterial count increases and browning is promoted.
  • ° C more preferably 0 to 5 ° C.
  • chlorite (especially sodium salt) aqueous solution as the bactericidal solution in the water exposure step
  • the chlorite concentration in the chlorite aqueous solution is too low, the bactericidal effect is not sufficient, If it is too high, there is a concern that chlorine may remain in the plant body. Therefore, it is preferably set to 50 to 400 ppm, more preferably 100 to 200 ppm. If the pH of the aqueous chlorite solution is too low, chlorine dioxide gas may be generated, and if it is too high, the bactericidal effect tends to be insufficient, so it is preferably 6 to 11, more preferably 8 to 10. Set to.
  • the temperature when dipping the shredded cabbage to be sterilized in the aqueous chlorite solution is too low, there is a possibility of plant freezing damage, and if it is too high, the increase in the number of bacteria and the promotion of browning occur. It is 0 to 10 ° C, more preferably 0 to 5 ° C.
  • acetic acid aqueous solution as a bactericide aqueous solution in the water exposure step
  • the acetic acid concentration in the aqueous acetic acid solution is too low, the bactericidal effect is not sufficient, and if it is too high, there is a concern of damaging plant cells. It is preferably set to 100 to 5000 ppm, more preferably 100 to 1000 ppm.
  • the shredded cabbage to be sterilized in the acetic acid aqueous solution is too low, there is a possibility of freezing damage to the plant, and when it is too high, the number of bacteria increases and browning is promoted.
  • ° C more preferably 0 to 5 ° C.
  • the water exposure process when a bactericide aqueous solution having a weaker bactericidal power than the bactericide used in the sterilization process is used, it may be further exposed to fresh water after being exposed to water with the bactericide aqueous solution. What is necessary is just to allocate suitably the time allocation of the water exposure by the disinfectant aqueous solution and the subsequent water exposure by the fresh water within the time of the water exposure process.
  • the water exposure in the clear water here also has the meaning of the water washing process which rinses the cabbage which passed through the water exposure process by the disinfectant aqueous solution with fresh water.
  • the shredded cabbage thus drained is filled and sealed in a thermoplastic resin bag such as polypropylene together with an inert gas such as nitrogen gas as necessary, whereby a shredded cabbage product can be obtained.
  • a thermoplastic resin bag such as polypropylene together with an inert gas such as nitrogen gas as necessary, whereby a shredded cabbage product can be obtained.
  • Filling and sealing together with an inert gas such as nitrogen gas is preferable because it can further suppress the deterioration of flavor over time during storage.
  • Examples 1 to 11 and Comparative Example 2 Hole cabbage from which the core and dirty outer leaves have been removed is divided into approximately four equal parts, and 250 g of cabbage lump is washed with fresh water and then immersed in 4 liters of an aqueous bactericidal solution at 20 ° C for 5 minutes for sterilization. did.
  • the chopped cabbage that had been sterilized was exposed to 4 liters of fresh water for water exposure or an aqueous sterilizing agent solution at 5 ° C. for the time shown in Table 1, and then a centrifugal drainer (DT-2S, Ltd.) Die draining treatment (treatment conditions: 1100 rpm, 1 minute) was performed using Daiei Seisakusho to obtain 200 g of shredded cabbage.
  • DT-2S, Ltd. Die draining treatment
  • 100 g of the shredded cabbage obtained was put into a 40 ⁇ m thick stretched propylene bag together with nitrogen gas, and the shredded cabbage product was manufactured by heat-sealing the opening of the bag, and stored refrigerated at 10 ° C.
  • Comparative Example 1 Cut shredded cabbage in the same way as in Example 1 except that it was shredded with a slicer (Naginata rotating electric slicer) without irrigating fresh water into the cut portion of the sterilized cabbage lump, and manufactured into shredded cabbage products And stored refrigerated at 10 ° C.
  • a slicer Naginata rotating electric slicer
  • Comparative Example 3 The whole cabbage from which the core and dirty outer leaves have been removed is divided into approximately four equal parts, and the cabbage lump of 250 g is washed with fresh water and then immediately sterilized and immediately cut in the conditions shown in Table 1 and further exposed to water. By carrying out, shredded cabbage was obtained, further shredded cabbage products were produced, and refrigerated at 10 ° C.
  • ⁇ Preservation evaluation> The general bacterial count of shredded cabbage in the shredded cabbage product immediately after production was measured by a test method in accordance with the Food Sanitation Inspection Guidelines (Ministry of Health, Labor and Welfare), and evaluated according to the following criteria.
  • Rank Criteria A Less than 1 ⁇ 10 4 CFU / g B: 1 ⁇ 10 4 CFU / g or more and less than 1 ⁇ 10 6 CFU / g C: 1 ⁇ 10 6 CFU / g or more
  • the shredded cabbage of Examples 1 to 11 had a small number of general bacteria, and even after being stored for a full 3 days immediately after shredding, the taste was not felt.
  • Examples 12 to 16 A shredded cabbage product was prepared in the same manner as in Example 1 except that the water exposure time was changed to the time shown in Table 2, and the taste evaluation was performed. The obtained results are shown in Table 2.
  • Examples 17-20 A shredded cabbage product was prepared in the same manner as in Example 1 except that the disinfectant aqueous solution shown in Table 3 was used in place of fresh water at the time of water exposure, and the taste evaluation was performed. The obtained results are shown in Table 3.
  • the method for producing shredded cabbage of the present invention cabbage that has been sterilized by bringing it into contact with a bactericide aqueous solution is shredded while pouring fresh water into the cut portion, and then subjected to a water exposure treatment for a certain time or longer. For this reason, the cross section of the cabbage and the cut surface of the shredded cabbage are cleaned almost simultaneously with the cutting, and the shredded cabbage cleaned in this way is exposed to water, so that the cabbage's taste is greatly reduced or not felt. Cabbage can be obtained. Therefore, the production method of the present invention is useful for industrial production of shredded cabbage.

Abstract

A method for industrial production of shredded cabbage that demonstrates good storage properties and a great reduction in or elimination of harsh taste is provided. The production method for shredded cabbage comprises the following sterilization, shredding, and leaching steps, namely: a step for sterilizing a cabbage prior to shredding by bringing said cabbage into contact with an aqueous sterilization liquid (sterilization step); a step for shredding the cabbage sterilized in the sterilization step while rinsing the cut sections thereof in pure water (shredding step); and a step for leaching the shredded cabbage obtained in the shredding step for 3 or more minutes (leaching step).

Description

千切りキャベツの製造方法Manufacturing method of shredded cabbage
 本発明は、千切りキャベツの製造方法に関する。 The present invention relates to a method for producing shredded cabbage.
 千切りキャベツをポリプロピレン製袋に窒素ガスと共に密封した千切りキャベツ製品が、スーパーマーケットの生鮮野菜売り場で広く販売されている。このような千切りキャベツの工業的製造方法としては、例えば、カットキャベツを次亜塩素酸ソーダ溶液で洗浄し、次いで水洗いの後、酢酸溶液で洗浄する方法(特許文献1)、カットキャベツを亜塩素酸塩溶液で処理した後水洗せずに水切りし、そのまま保存する方法(特許文献2)、千切り前のキャベツを、次亜塩素酸塩水溶液等の殺菌液に浸漬して一次殺菌処理した後、スライサーで千切りし、続いて、次亜塩素酸塩水溶液よりも弱い殺菌力を有する殺菌液に浸漬して二次殺菌処理し、水洗し、そして遠心分離装置で水切りする方法(特許文献3)等が提案されている。 The shredded cabbage product, which is a shredded cabbage sealed with nitrogen gas in a polypropylene bag, is widely sold at the supermarket fresh vegetables section. As an industrial production method of such shredded cabbage, for example, a method in which cut cabbage is washed with a sodium hypochlorite solution, then washed with water and then washed with an acetic acid solution (Patent Document 1), and cut cabbage is chlorinated. After treating with an acid salt solution, draining without rinsing and storing as it is (Patent Document 2), after cabbage before shredding is immersed in a sterilizing solution such as hypochlorite aqueous solution and primary sterilizing treatment, Chopping with a slicer, followed by dipping in a bactericidal solution having a weaker bactericidal power than hypochlorite aqueous solution, secondary sterilization treatment, washing with water, and draining with a centrifuge (Patent Document 3), etc. Has been proposed.
特開平6-46812号公報JP-A-6-46812 特開平11-196763号公報Japanese Patent Application Laid-Open No. 11-196763 特開2006-61069号公報JP 2006-61069 A
 ところで、特許文献1~3の方法で製造された千切りキャベツの場合、良好な保存性を示すものの、キャベツ独特のエグ味が感じられるものであり、時間経過とともにそのエグ味が増して感じられるものであった。このようなエグ味を、キャベツそのものの味としてあまり違和感を感じていない消費者がいる一方で、幼児・年少児を含む若年層を中心に、そのようなエグ味を好ましくないものとして感じている消費者も多く存在する。このため、千切りキャベツ製品を幅広い消費者に受け入れて貰うためには、良好な保存性を示すことはもちろん、エグ味が大きく軽減されもしくは感じられない千切りキャベツを工業的に製造できるようにすることが求められていた。 By the way, in the case of shredded cabbage produced by the methods of Patent Documents 1 to 3, the cabbage has a unique savory taste, but the savory taste increases with time. Met. While there are consumers who do not feel such a taste of cabbage itself as a taste of cabbage itself, such taste is felt as unfavorable mainly by young people including infants and young children. There are many consumers. For this reason, in order to accept shredded cabbage products to a wide range of consumers, it should be possible to industrially produce shredded cabbage that not only shows good storage but also greatly reduces or prevents the taste. Was demanded.
 本発明の目的は、以上の従来の課題を解決することであり、良好な保存性を示し、且つエグ味が大きく軽減されもしくは感じられない千切りキャベツを工業的に製造する方法を提供することである。 An object of the present invention is to solve the above-described conventional problems, and to provide a method for industrially producing shredded cabbage that exhibits good storage stability and greatly reduces or does not feel the taste. is there.
 本発明者らは、千切りキャベツの製造ラインにおいて、キャベツのエグ味がどの段階で発現するようになるかを調査したところ、キャベツを千切りした後にエグ味が発現するようになっていること、具体的には、フードスライサーで千切りしたキャベツを、殺菌処理水槽にバッチで投入するために大きなザルに受けている間にエグ味が発現するようになっていること、また、そのように一旦エグ味が発現した千切りキャベツを殺菌処理工程に投入してもエグ味を除去することができないこと、を知見した。そして本発明者らは、このような千切りキャベツのエグ味の発現が、千切り開始から殺菌処理水槽に投入されるまでの間(通常、5~60分間)、キャベツの断面や千切りキャベツの切断面にしみ出したキャベツ汁が付着したままであることに起因しているのではないか、という仮定の下、キャベツの断面と千切りキャベツの切断面とが、常に洗浄されるように、キャベツの切断部(即ち、フードスライサーの刃先が切れ込む部分)に清水を注ぎながら千切り処理し、更に、千切りしたキャベツを一定時間以上水晒し処理したところ、キャベツのエグ味が大きく軽減されもしくは感じられなくなることを見出し、本発明を完成させた。
 即ち、本発明は、千切りキャベツの製造方法であって、以下の(殺菌工程)、(千切り工程)及び(水晒し工程)を有する製造方法を提供する。
The present inventors investigated at which stage the cabbage's egg flavor appears in the shredded cabbage production line, and found that after the cabbage was shredded, the egg flavor was developed. In particular, the taste of the cabbage shredded with a food slicer is expressed while receiving it in a large colander for batch injection into a sterilized water tank. It has been found that the shrimp can not be removed even if the shredded cabbage in which the odor is expressed is put into the sterilization treatment step. Then, the inventors of the present invention have found that the shrimp cabbage has a savory taste until it is put into the sterilized water tank (usually 5 to 60 minutes), and the cross section of the cabbage and the cut surface of the shredded cabbage Cutting the cabbage so that the cross section of the cabbage and the cut surface of the shredded cabbage are always washed under the assumption that the cabbage juice that oozes out remains attached. Pour fresh water into the part (that is, the part where the blade edge of the food slicer cuts), and then, after the shredded cabbage is exposed to water for a certain period of time, the egg flavor of the cabbage is greatly reduced or not felt The headline and the present invention were completed.
That is, this invention is a manufacturing method of shredded cabbage, Comprising: The manufacturing method which has the following (sterilization process), (striping process), and (water exposure process) is provided.
(殺菌工程)
 千切り前のキャベツを、殺菌剤水溶液に接触させて殺菌処理する工程;
(千切り工程)
 殺菌工程で殺菌処理されたキャベツを、その切断部に清水を注ぎながら千切り処理する工程; 及び
(水晒し工程)
 千切り工程で得られた千切りキャベツを、3分以上水晒しする工程。
 また、本発明は、上述の製造方法により得られた千切りキャベツが熱可塑性樹脂製袋に密封された千切りキャベツ製品を提供する。
(Sterilization process)
A step of sterilizing cabbage before cutting into contact with a bactericidal solution;
(Chopping process)
A process of cutting cabbage sterilized in the sterilization process while pouring fresh water into the cut part; and (water exposure process)
The process of exposing the shredded cabbage obtained in the shredded process to water for 3 minutes or more.
Moreover, this invention provides the shredded cabbage product by which the shredded cabbage obtained by the above-mentioned manufacturing method was sealed by the thermoplastic resin bag.
 本発明の千切りキャベツの製造方法では、殺菌剤水溶液に接触させて殺菌処理した千切り前のキャベツを、その切断部に清水を注ぎながら千切り処理した上で一定時間以上水晒し処理する。このため、千切り前のキャベツが十分に殺菌され、しかも、キャベツの断面と千切りキャベツの切断面とが切断とほぼ同時に洗浄され、そしてそのように洗浄された千切りキャベツが水晒しされるため、キャベツのエグ味が大きく軽減されもしくは感じられない千切りキャベツを得ることができる。 In the method for producing shredded cabbage of the present invention, the shredded cabbage that has been sterilized by being brought into contact with a bactericide aqueous solution is shredded while pouring fresh water into the cut portion, and then subjected to water exposure for a certain time or longer. For this reason, the cabbage before shredding is sufficiently sterilized, the cross section of the cabbage and the cut surface of the shredded cabbage are cleaned almost simultaneously with the cutting, and the cleaned shredded cabbage is exposed to water. The shredded cabbage is greatly reduced or can not be felt.
 以下、(殺菌工程)、(千切り工程)及び(水晒し工程)を有する本発明の千切りキャベツの製造方法について、工程毎に詳細に説明する。 Hereinafter, the manufacturing method of the shredded cabbage of the present invention having the (sterilization step), the (chopping step), and the (water exposure step) will be described in detail for each step.
(殺菌工程)
 まず、千切り前のキャベツに対し、殺菌剤水溶液に接触させて殺菌処理を行う。この処理の目的は、エグ味の発現の軽減ないしは防止を目的として切断部分に水を注ぎながら行う千切り工程及びその後の水晒し工程からなる後工程に至る前に、十分に殺菌しておくことである。ここで、殺菌の対象となる菌としては、代表的には土壌由来の雑菌であって、野菜に付着してその鮮度を低下させたりする菌等を挙げることができる。
(Sterilization process)
First, the cabbage before shredding is sterilized by bringing it into contact with a bactericidal solution. The purpose of this treatment is to thoroughly sterilize before the subsequent process consisting of a shredding process and subsequent water exposure process, while pouring water into the cut part for the purpose of reducing or preventing the appearance of the taste. is there. Here, the bacteria to be sterilized are typically soil-derived bacteria that can adhere to vegetables and reduce their freshness.
 従って、本工程の殺菌処理では、十分な殺菌効果が得られる種々の殺菌剤を使用する。ここで、十分な殺菌効果が得られる殺菌剤の殺菌力(比較的強い殺菌力)のレベルは、厚生労働省監修の食品衛生検査指針(微生物編、116~123頁、2004年:発行所:社団法人日本食品衛生協会、発行人;玉木武)に準拠して測定した一般細菌数を指標とすることができる。具体的には、一般細菌数が1×10CFU/g未満である場合を意味する。 Therefore, in the sterilization treatment in this step, various sterilizing agents that can provide a sufficient sterilizing effect are used. Here, the level of bactericidal power (relatively strong bactericidal power) of a bactericidal agent that can obtain a sufficient bactericidal effect is the food hygiene inspection guidelines supervised by the Ministry of Health, Labor and Welfare (Microorganisms, pages 116-123, 2004: Issuer: Association) The number of general bacteria measured according to Japan Food Hygiene Association, publisher; Takeshi Tamaki) can be used as an index. Specifically, it means that the number of general bacteria is less than 1 × 10 4 CFU / g.
 このような比較的強い殺菌力を示す殺菌剤としては、次亜塩素酸塩水溶液、次亜塩素酸発生電解液、水酸化アルカリ、焼成カルシウムなどのアルカリ剤の水溶液や、塩酸等の鉱酸の水溶液等の殺菌剤が挙げられる。具体的には、次亜塩素酸ナトリウム、水酸化ナトリウム、水酸化カリウム、焼成カルシウムおよび塩酸からなる群より選択される少なくとも一種の水溶液を使用することが好ましい。なお、二種以上の殺菌剤水溶液を併用することもできる。このような殺菌剤の中でも、風味の点から次亜塩素酸塩水溶液、特に次亜塩素酸ナトリウム水溶液を好ましく使用することができる。 Examples of such a bactericidal agent having a relatively strong bactericidal power include hypochlorite aqueous solution, hypochlorous acid generating electrolyte solution, aqueous solution of alkaline agent such as alkali hydroxide and calcined calcium, and mineral acid such as hydrochloric acid. Examples include bactericides such as aqueous solutions. Specifically, it is preferable to use at least one aqueous solution selected from the group consisting of sodium hypochlorite, sodium hydroxide, potassium hydroxide, calcined calcium and hydrochloric acid. Two or more aqueous bactericidal agents can be used in combination. Among such bactericides, hypochlorite aqueous solution, particularly sodium hypochlorite aqueous solution can be preferably used from the viewpoint of flavor.
 殺菌処理の処理内容は、殺菌剤水溶液と千切り前のキャベツとを接触させることであり、具体的には、殺菌剤水溶液に千切り前のキャベツを浸漬することや、殺菌剤水溶液を千切り前のキャベツにスプレーすること等を挙げることができる。ここで、千切り前のキャベツとしては、芯などの不可食部を取り除いたものを適用することができ、例えば、芯を取り除いたホールキャベツ、それを二等分や四等分にカットしたもの、あるいはホールキャベツから切り離した葉、を適用することもできる。また、殺菌処理する前に予め水洗しておいてもよい。 The content of the sterilization treatment is to bring the bactericide aqueous solution into contact with the cabbage before shredding. Specifically, the cabbage before shredding is immersed in the bactericidal aqueous solution, or the cabbage before shredding the sanitizer aqueous solution. Spraying can be mentioned. Here, as cabbage before shredding, it is possible to apply a cabbage from which inedible parts such as a core are removed, for example, a hole cabbage from which a core has been removed, a product obtained by cutting it into two or four equal parts, Alternatively, leaves separated from whole cabbage can be applied. Moreover, you may wash with water before sterilizing.
 殺菌処理の処理条件は、使用する殺菌剤水溶液の種類、殺菌すべきキャベツの種類や大きさ等に応じて適宜決定することができる。例えば、殺菌剤水溶液として次亜塩素酸塩水溶液、例えば、次亜塩素酸ナトリウム水溶液を使用し、キャベツを浸漬させる場合、次亜塩素酸塩水溶液中の次亜塩素酸塩濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞へのダメージが大きくなりすぎる傾向があるので、好ましくは10~500ppm、より好ましくは30~400ppm、特に好ましくは100~200ppmに設定する。また、次亜塩素酸塩水溶液のpHは、低すぎると植物細胞へのダメージが大きく、高すぎると殺菌効果が不十分となる傾向があるので、好ましくは4~10、より好ましくは6~9に設定する。次亜塩素酸塩水溶液に殺菌すべき千切り前のキャベツを浸漬させる際の温度は、低すぎると植物細菌への凍結障害の可能性があり、高すぎると細菌数の増大及び褐変の促進が生じる傾向があるので、好ましくは0~50℃、より好ましくは0~15℃である。また、浸漬時間は、短すぎると殺菌効果が不十分であり、長すぎると植物細胞へのダメージが大きくなる傾向があるので、好ましくは1~20分、より好ましくは2~10分である。 The treatment conditions for the sterilization treatment can be appropriately determined according to the type of the bactericidal solution used, the type and size of the cabbage to be sterilized, and the like. For example, when a hypochlorite aqueous solution, for example, a sodium hypochlorite aqueous solution is used as the bactericide aqueous solution and the cabbage is immersed, the hypochlorite concentration in the hypochlorite aqueous solution is too low. The bactericidal effect is not sufficient, and if it is too high, the damage to the plant cells tends to be too great. Therefore, it is preferably set to 10 to 500 ppm, more preferably 30 to 400 ppm, and particularly preferably 100 to 200 ppm. Further, the pH of the hypochlorite aqueous solution is too low, the damage to the plant cells is great, and if it is too high, the bactericidal effect tends to be insufficient, so it is preferably 4-10, more preferably 6-9. Set to. If the cabbage before chopping to be sterilized in the hypochlorite aqueous solution is too low, there is a possibility of freezing damage to plant bacteria, and if it is too high, the number of bacteria increases and browning is accelerated. Since there is a tendency, it is preferably 0 to 50 ° C., more preferably 0 to 15 ° C. In addition, if the immersion time is too short, the bactericidal effect is insufficient, and if it is too long, damage to plant cells tends to increase. Therefore, the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
 また、殺菌剤水溶液として水酸化アルカリ水溶液、例えば水酸化ナトリウム水溶液や水酸化カリウム水溶液を使用し、キャベツを浸漬させる場合、水酸化アルカリ水溶液中の水酸化アルカリ濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞へのダメージが大きくなりすぎる傾向があるので、好ましくは10~40000ppm、より好ましくは100~20000ppm、特に好ましくは100~10000ppmに設定する。また、水酸化アルカリ水溶液のpHは、低すぎると植物細胞へのダメージが大きく、高すぎると殺菌効果が不十分となる傾向があるので、好ましくは11~13.5、より好ましくは11~13に設定する。水酸化アルカリ水溶液に殺菌すべき千切り前のキャベツを浸漬させる際の温度は、低すぎると植物細菌への凍結障害の可能性があり、高すぎると細菌数の増大及び褐変の促進が生じる傾向があるので、好ましくは0~50℃、より好ましくは0~15℃である。また、浸漬時間は、短すぎると殺菌効果が不十分であり、長すぎると植物細胞へのダメージが大きくなる傾向があるので、好ましくは1~20分、より好ましくは2~10分である。 In addition, when an alkali hydroxide aqueous solution, for example, a sodium hydroxide aqueous solution or a potassium hydroxide aqueous solution is used as the bactericide aqueous solution and the cabbage is immersed, the bactericidal effect is sufficient if the alkali hydroxide concentration in the aqueous alkali hydroxide solution is too low. On the other hand, if it is too high, damage to plant cells tends to be too great, so it is preferably set to 10 to 40,000 ppm, more preferably 100 to 20000 ppm, and particularly preferably 100 to 10,000 ppm. In addition, if the pH of the aqueous alkali hydroxide solution is too low, damage to plant cells is large, and if it is too high, the bactericidal effect tends to be insufficient, so that it is preferably 11 to 13.5, more preferably 11 to 13. Set to. If the cabbage before chopping to be sterilized in the aqueous alkali hydroxide solution is too low, there is a possibility of freezing damage to plant bacteria, and if it is too high, the number of bacteria and the promotion of browning tend to occur. Therefore, it is preferably 0 to 50 ° C., more preferably 0 to 15 ° C. In addition, if the immersion time is too short, the bactericidal effect is insufficient, and if it is too long, damage to plant cells tends to increase. Therefore, the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
 また、殺菌剤水溶液として焼成カルシウム水溶液を使用し、キャベツを浸漬させる場合、焼成カルシウム水溶液中の焼成カルシウム濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞へのダメージが大きくなりすぎる傾向があるので、好ましくは10~40000ppm、より好ましくは100~10000ppm、特に好ましくは100~1000ppmに設定する。また、焼成カルシウム水溶液のpHは、低すぎると植物細胞へのダメージが大きく、高すぎると殺菌効果が不十分となる傾向があるので、好ましくは  11~13.5、より好ましくは11~13に設定する。焼成カルシウム水溶液に殺菌すべき千切り前のキャベツを浸漬させる際の温度は、低すぎると植物細菌への凍結障害の可能性があり、高すぎると細菌数の増大及び褐変の促進が生じる傾向があるので、好ましくは0~50℃、より好ましくは0~15℃である。また、浸漬時間は、短すぎると殺菌効果が不十分であり、長すぎると植物細胞へのダメージが大きくなる傾向があるので、好ましくは1~20分、より好ましくは2~10分である。 In addition, when using a calcined calcium aqueous solution as a bactericidal aqueous solution and immersing cabbage, if the calcined calcium concentration in the calcined calcium aqueous solution is too low, the bactericidal effect is not sufficient, and if it is too high, damage to plant cells increases. Therefore, it is preferably set to 10 to 40000 ppm, more preferably 100 to 10000 ppm, and particularly preferably 100 to 1000 ppm. Moreover, since the pH of the calcined calcium aqueous solution is too low, the damage to the plant cells is large, and when it is too high, the bactericidal effect tends to be insufficient. Therefore, the pH is preferably 11 to 13.5, more preferably 11 to 13. Set. If the cabbage before chopping to be sterilized in the calcined calcium aqueous solution is too low, there is a possibility of freezing damage to plant bacteria, and if it is too high, there is a tendency to increase the number of bacteria and promote browning. Therefore, it is preferably 0 to 50 ° C., more preferably 0 to 15 ° C. In addition, if the immersion time is too short, the bactericidal effect is insufficient, and if it is too long, damage to plant cells tends to increase. Therefore, the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
 また、殺菌剤水溶液として塩酸水溶液を使用し、キャベツを浸漬させる場合、塩酸水溶液中の塩酸濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞へのダメージが大きくなりすぎる傾向があるので、好ましくは10~40000ppm、より好ましくは10~10000ppm、特に好ましくは10~5000ppmに設定する。また、塩酸水溶液のpHは、低すぎると植物細胞へのダメージが大きく、高すぎると殺菌効果が不十分となる傾向があるので、好ましくは2~5、より好ましくは2~4に設定する。塩酸水溶液に殺菌すべき千切り前のキャベツを浸漬させる際の温度は、低すぎると植物細菌への凍結障害の可能性があり、高すぎると細菌数の増大及び褐変の促進が生じる傾向があるので、好ましくは0~50℃、より好ましくは0~15℃である。また、浸漬時間は、短すぎると殺菌効果が不十分であり、長すぎると植物細胞へのダメージが大きくなる傾向があるので、好ましくは1~20分、より好ましくは2~10分である。 In addition, when using a hydrochloric acid aqueous solution as the bactericidal aqueous solution and immersing cabbage, the concentration of hydrochloric acid in the aqueous hydrochloric acid solution is too low if the bactericidal effect is sufficient, and if it is too high, damage to plant cells tends to be too great. Therefore, it is preferably set to 10 to 40000 ppm, more preferably 10 to 10000 ppm, and particularly preferably 10 to 5000 ppm. Further, the pH of the aqueous hydrochloric acid solution is preferably set to 2 to 5, more preferably 2 to 4, since the damage to the plant cells is great if it is too low and the bactericidal effect tends to be insufficient if it is too high. If the cabbage before chopping to be sterilized in hydrochloric acid aqueous solution is too low, there is a possibility of freezing damage to plant bacteria, and if it is too high, there is a tendency to increase the number of bacteria and promote browning. The temperature is preferably 0 to 50 ° C., more preferably 0 to 15 ° C. In addition, if the immersion time is too short, the bactericidal effect is insufficient, and if it is too long, damage to plant cells tends to increase. Therefore, the immersion time is preferably 1 to 20 minutes, more preferably 2 to 10 minutes.
 また、次亜塩素酸塩水溶液はじめとする上述の殺菌剤水溶液には、本発明の効果を損なわない範囲で、種々の添加剤、例えば、亜塩素酸ナトリウムを配合してもよい。 In addition, various additives such as sodium chlorite may be blended in the above-mentioned bactericidal solution including the hypochlorite aqueous solution as long as the effects of the present invention are not impaired.
 なお、殺菌工程で得られた殺菌処理済みの千切り前のキャベツは、後述の千切り工程に投入する前に、必要に応じて水洗し、更に水切りしてもよい。 Note that the sterilized cabbage that has been sterilized and obtained in the sterilization process may be washed with water and further drained as necessary before being put into the shredding process described below.
(千切り工程)
 次に、殺菌工程で殺菌処理されたキャベツを、その切断部分に清水を注ぎながら、例えば、市販のフードスライサーを用いて千切り処理する。これにより、キャベツの断面と千切りキャベツの切断面とが常に洗浄されるため、千切りキャベツのエグ味を大きく軽減もしくは感じられなくなるようにすることができる。
(Chopping process)
Next, the cabbage sterilized in the sterilization process is shredded using, for example, a commercially available food slicer while pouring fresh water into the cut portion. As a result, the cross section of the cabbage and the cut surface of the shredded cabbage are always washed, so that the savory taste of the shredded cabbage can be greatly reduced or not felt.
 千切りキャベツの千切り巾に関し、千切り巾を狭くしすぎるとキャベツの切断面積が大きくなってエグ味が発現しやすくなり、また、千切りキャベツの好ましい食味が得られにくくなるので、好ましくは0.5~3mm、より好ましくは0.5~2mmである。 Regarding the shredded width of shredded cabbage, if the width of shredded cabbage is too narrow, the cut area of cabbage becomes large and the taste of the shredded cabbage tends to be expressed, and the preferred taste of shredded cabbage becomes difficult to obtain. It is 3 mm, more preferably 0.5 to 2 mm.
 本工程において、清水を注ぐ具体的な手法としては、ホースから注水することや、シャワーヘッドから注水すること等が挙げられる。また、清水を注ぐ際の清水流量は、少なすぎるとキャベツのエグ味を十分に除去することができにくくなるので、キャベツの千切り処理量1kg/分に対し、好ましくは0.1L/分以上、より好ましくは0.2L/分以上である。なお、清水流量が多すぎてもそれに見合うエグ味除去効果が得られるわけではなく、かえってキャベツがダメージを受け食味が低下する場合もあるので、清水流量の好ましい範囲は、キャベツの千切り処理量1kg/分に対し0.1~10L/分、より好ましい範囲は0.1~5L/分、特に好ましい範囲は0.2~3L/分である。 In this step, specific methods of pouring fresh water include pouring water from a hose, pouring water from a shower head, and the like. Also, if the flow rate of fresh water when pouring fresh water is too small, it becomes difficult to sufficiently remove the cabbage's taste, so it is preferably 0.1 L / min or more with respect to 1 kg / min of shredded cabbage. More preferably, it is 0.2 L / min or more. In addition, even if there is too much fresh water flow rate, the effect of removing the egg taste corresponding to that is not obtained, but the cabbage may be damaged and the taste may be lowered, so the preferred range of fresh water flow rate is 1 kg of cabbage shredder processing amount 0.1 to 10 L / min relative to / min, a more preferable range is 0.1 to 5 L / min, and a particularly preferable range is 0.2 to 3 L / min.
 なお、千切り工程において得られた千切りキャベツは、直ちに後述する水晒し工程に投入することが好ましいが、所定量の千切りキャベツが蓄積されるまで、ザルやベルトコンベア上に貯めておいてもよい。その場合、清水を注ぎつづけることが好ましい。 It should be noted that the shredded cabbage obtained in the shredded process is preferably immediately put into the water exposure process described later, but may be stored on a colander or a belt conveyor until a predetermined amount of shredded cabbage is accumulated. In that case, it is preferable to continue pouring fresh water.
(水晒し工程)
 次に、千切りしたキャベツを3分以上清水に晒す。これにより、キャベツのエグ味をより取り除くことができる。この場合、水晒し処理温度は、通常、0~50℃、より好ましくは0~10℃である。また、晒す時間が短すぎるとエグ味が残る可能性があるので、3分以上、好ましくは5分以上、より好ましくは10分以上晒すようにする。なお、水晒し時間が長すぎると、千切り後のキャベツ組織が傷んだり、しみだしたキャベツ汁が流れ過ぎたりし、その結果、キャベツの食味に影響がでる場合(具体的には、かえってエグ味がでてしまう場合)があるため、水晒し時間は、好ましくは60分以下、より好ましくは30分以下である。
(Water exposure process)
Next, expose the shredded cabbage to fresh water for at least 3 minutes. Thereby, the savory taste of cabbage can be removed more. In this case, the water exposure treatment temperature is usually 0 to 50 ° C., more preferably 0 to 10 ° C. Further, if the exposure time is too short, there is a possibility that a taste remains, so that the exposure is performed for 3 minutes or more, preferably 5 minutes or more, more preferably 10 minutes or more. If the water exposure time is too long, the cabbage tissue after shredding will be damaged or the cabbage juice that has oozed out will flow too much, resulting in an effect on the cabbage taste (specifically, The water exposure time is preferably 60 minutes or less, more preferably 30 minutes or less.
 水晒し工程の後の千切りキャベツに対し、必要に応じて、公知の遠心水切り装置を用いて水切り処理を施し、得られた千切りキャベツを、ポリプロピレン等の熱可塑性樹脂袋に必要に応じて窒素ガス等の不活性ガスと共に充填密封することにより、千切りキャベツ製品を得ることができる。 If necessary, the shredded cabbage after the water exposure step is drained using a known centrifugal drainer, and the resulting shredded cabbage is applied to a thermoplastic resin bag such as polypropylene with nitrogen gas as necessary. A shredded cabbage product can be obtained by filling and sealing with an inert gas such as.
 なお、この水晒し工程においては、清水に代えて、殺菌工程で使用した殺菌剤よりも弱い殺菌力を有する殺菌剤を含有する殺菌剤水溶液を使用してもよい。これにより、千切りキャベツの保存性を風味を損なわずにより向上させることができる。ここで、殺菌工程で使用した殺菌剤よりも弱い殺菌力を有する殺菌剤の殺菌力(比較的弱い殺菌力)のレベルは、厚生労働省監修の食品衛生検査指針(微生物編、116~123頁、2004年:発行所:社団法人日本食品衛生協会、発行人;玉木武)に準拠して測定した一般細菌数を指標とすることができる。具体的には、一般細菌数が1×10CFU/g以上~1×10CFU/g未満である場合を意味する。 In addition, in this water exposure process, it may replace with fresh water and may use the bactericide aqueous solution containing the bactericide which has weaker bactericidal power than the bactericide used at the bactericidal process. Thereby, the preservability of shredded cabbage can be improved without impairing the flavor. Here, the level of the bactericidal power (relatively weak bactericidal power) of the bactericidal agent having a weaker bactericidal power than the bactericidal agent used in the sterilizing process is the food hygiene inspection guidelines supervised by the Ministry of Health, Labor and Welfare (microorganism edition, pages 116 to 123, 2004: Issuer: The number of general bacteria measured according to Japan Food Sanitation Association, issuer: Takeshi Tamaki) can be used as an index. Specifically, it means a case where the number of general bacteria is 1 × 10 4 CFU / g or more to less than 1 × 10 6 CFU / g.
 このような比較的弱い殺菌力を示す殺菌剤としては、オゾン、亜塩素酸塩(好ましくはナトリウム塩)、酢酸、クエン酸、リン酸、エタノールなどを使用することができる。具体的には、オゾン、亜塩素酸ナトリウム及び酢酸からなる群より選択される少なくとも一種の水溶液を使用することができる。中でも、風味の点から亜塩素酸ナトリウム、オゾン水を好ましく使用することができる。 Ozone, chlorite (preferably sodium salt), acetic acid, citric acid, phosphoric acid, ethanol and the like can be used as such a bactericidal agent exhibiting a relatively weak bactericidal power. Specifically, at least one aqueous solution selected from the group consisting of ozone, sodium chlorite and acetic acid can be used. Among these, sodium chlorite and ozone water can be preferably used from the viewpoint of flavor.
 なお、水晒し工程で殺菌剤水溶液としてオゾン水を使用する場合、オゾン水中のオゾン濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞にダメージを与えることが懸念されるので、好ましくは0.5~10ppm、より好ましくは1~5ppmに設定する。オゾン水に殺菌すべき千切りキャベツを浸漬させる際の温度は、低すぎると植物体の凍結障害の可能性が有り、高すぎると細菌数の増大及び褐変の促進が生じるので、好ましくは0~10℃、より好ましくは0~5℃である。 In addition, when using ozone water as a bactericide aqueous solution in the water exposure step, the ozone concentration in the ozone water is too low if the bactericidal effect is sufficient, and if it is too high, there is a concern of damaging plant cells, Preferably it is set to 0.5 to 10 ppm, more preferably 1 to 5 ppm. If the temperature at which the shredded cabbage to be sterilized is immersed in ozone water is too low, there is a possibility of freezing damage to the plant, and if it is too high, the bacterial count increases and browning is promoted. ° C, more preferably 0 to 5 ° C.
 また、水晒し工程で殺菌剤水溶液として亜塩素酸塩(特にナトリウム塩)水溶液を使用する場合、亜塩素酸塩水溶液中の亜塩素酸塩濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物体に塩素が残留することが懸念されるので、好ましくは50~400ppm、より好ましくは100~200ppmに設定する。亜塩素酸塩水溶液のpHは、低すぎると二酸化塩素ガスが発生する可能性があり、高すぎると殺菌効果が不十分となる傾向があるので、好ましくは6~11、より好ましくは8~10に設定する。亜塩素酸塩水溶液に殺菌すべき千切りキャベツを浸漬させる際の温度は、低すぎると植物体の凍結障害の可能性が有り、高すぎると細菌数の増大及び褐変の促進が生じるので、好ましくは0~10℃、より好ましくは0~5℃である。 Also, when using a chlorite (especially sodium salt) aqueous solution as the bactericidal solution in the water exposure step, if the chlorite concentration in the chlorite aqueous solution is too low, the bactericidal effect is not sufficient, If it is too high, there is a concern that chlorine may remain in the plant body. Therefore, it is preferably set to 50 to 400 ppm, more preferably 100 to 200 ppm. If the pH of the aqueous chlorite solution is too low, chlorine dioxide gas may be generated, and if it is too high, the bactericidal effect tends to be insufficient, so it is preferably 6 to 11, more preferably 8 to 10. Set to. If the temperature when dipping the shredded cabbage to be sterilized in the aqueous chlorite solution is too low, there is a possibility of plant freezing damage, and if it is too high, the increase in the number of bacteria and the promotion of browning occur. It is 0 to 10 ° C, more preferably 0 to 5 ° C.
 なお、水晒し工程で殺菌剤水溶液として酢酸水溶液を使用する場合、酢酸水溶液中の酢酸濃度は、低すぎると殺菌効果が十分でなく、高すぎると植物細胞にダメージを与えることが懸念されるので、好ましく100~5000ppm、より好ましくは100~1000ppmに設定する。酢酸水溶液に殺菌すべき千切りキャベツを浸漬させる際の温度は、低すぎると植物体の凍結障害の可能性が有り、高すぎると細菌数の増大及び褐変の促進が生じるので、好ましくは0~10℃、より好ましくは0~5℃である。 In addition, when using an acetic acid aqueous solution as a bactericide aqueous solution in the water exposure step, if the acetic acid concentration in the aqueous acetic acid solution is too low, the bactericidal effect is not sufficient, and if it is too high, there is a concern of damaging plant cells. It is preferably set to 100 to 5000 ppm, more preferably 100 to 1000 ppm. When the shredded cabbage to be sterilized in the acetic acid aqueous solution is too low, there is a possibility of freezing damage to the plant, and when it is too high, the number of bacteria increases and browning is promoted. ° C, more preferably 0 to 5 ° C.
 なお、水晒し工程において、殺菌工程で使用した殺菌剤よりも弱い殺菌力を有する殺菌剤水溶液を使用した場合、殺菌剤水溶液で水晒しした後に、更に清水で水晒ししてもよい。殺菌剤水溶液による水晒しとそれに続く清水による水晒しの時間配分は、水晒し工程の時間内で適宜配分すればよい。なお、ここでの清水での水晒しは、殺菌剤水溶液による水晒し工程を経たキャベツを清水で水洗する水洗工程という意義も有する。 In addition, in the water exposure process, when a bactericide aqueous solution having a weaker bactericidal power than the bactericide used in the sterilization process is used, it may be further exposed to fresh water after being exposed to water with the bactericide aqueous solution. What is necessary is just to allocate suitably the time allocation of the water exposure by the disinfectant aqueous solution and the subsequent water exposure by the fresh water within the time of the water exposure process. In addition, the water exposure in the clear water here also has the meaning of the water washing process which rinses the cabbage which passed through the water exposure process by the disinfectant aqueous solution with fresh water.
 水晒し工程後の千切りキャベツに対しては、必要に応じて、公知の遠心水切り装置を用いて水切り処理を施すことが好ましい。 For the shredded cabbage after the water exposure step, it is preferable to perform a draining treatment using a known centrifugal draining device, if necessary.
 このようにして水切りされた千切りキャベツを、ポリプロピレン等の熱可塑性樹脂製袋に必要に応じて窒素ガス等の不活性ガスと共に充填密封することにより、千切りキャベツ製品を得ることができる。窒素ガス等の不活性ガスと共に充填密封すると保存中の時間経過による風味の劣化をより抑えることができ好ましい。 The shredded cabbage thus drained is filled and sealed in a thermoplastic resin bag such as polypropylene together with an inert gas such as nitrogen gas as necessary, whereby a shredded cabbage product can be obtained. Filling and sealing together with an inert gas such as nitrogen gas is preferable because it can further suppress the deterioration of flavor over time during storage.
 以下、本発明を実施例により具体的に説明する。 Hereinafter, the present invention will be specifically described with reference to examples.
  実施例1~11、比較例2
 芯や汚れた外側の葉を取り除いたホールキャベツを約四等分し、250gのキャベツ塊を清水で水洗した後、20℃の表1の殺菌剤水溶液4リットル中に5分間浸漬して殺菌処理した。
Examples 1 to 11 and Comparative Example 2
Hole cabbage from which the core and dirty outer leaves have been removed is divided into approximately four equal parts, and 250 g of cabbage lump is washed with fresh water and then immersed in 4 liters of an aqueous bactericidal solution at 20 ° C for 5 minutes for sterilization. did.
 殺菌処理したキャベツ塊の切断部に対し、清水を表1の流量でホースから注水しながら、スライサー(なぎ刃回転式の電動スライサー)で表1に示す巾に3kg/分の速度で千切した。千切りされたキャベツは、千切りスライサーの下方に位置するザルに入るようにした。 To the cut portion of the sterilized cabbage lump, fresh water was poured from the hose at a flow rate shown in Table 1, and then sliced into a width shown in Table 1 at a rate of 3 kg / min with a slicer (a rotary blade-type electric slicer). The shredded cabbage was placed in a colander located below the shredded slicer.
 次に、殺菌処理した千切りキャベツを、5℃の表1の水晒し用清水又は殺菌剤水溶液4リットル中に表1に示す時間で水晒した後、遠心水切り機(DT-2S、(株)大栄製作所)を用いて水切り処理(処理条件:1100rpm、1分)を行い、200gの千切りキャベツを得た。 Next, the chopped cabbage that had been sterilized was exposed to 4 liters of fresh water for water exposure or an aqueous sterilizing agent solution at 5 ° C. for the time shown in Table 1, and then a centrifugal drainer (DT-2S, Ltd.) Die draining treatment (treatment conditions: 1100 rpm, 1 minute) was performed using Daiei Seisakusho to obtain 200 g of shredded cabbage.
 得られた千切りキャベツ100gを、厚さ40μmの延伸プロピレン製袋に窒素ガスと共に入れ、袋の開口部をヒートシールすることにより千切りキャベツ製品を製造し、10℃で冷蔵保存した。 100 g of the shredded cabbage obtained was put into a 40 μm thick stretched propylene bag together with nitrogen gas, and the shredded cabbage product was manufactured by heat-sealing the opening of the bag, and stored refrigerated at 10 ° C.
  比較例1
 殺菌処理したキャベツ塊の切断部に対して清水を注水することなくスライサー(なぎ刃回転式の電動スライサー)で千切りしたこと以外、実施例1と同様に千切りキャベツを得、更に千切りキャベツ製品を製造し、10℃で冷蔵保存した。
Comparative Example 1
Cut shredded cabbage in the same way as in Example 1 except that it was shredded with a slicer (Naginata rotating electric slicer) without irrigating fresh water into the cut portion of the sterilized cabbage lump, and manufactured into shredded cabbage products And stored refrigerated at 10 ° C.
 比較例3
 芯や汚れた外側の葉を取り除いたホールキャベツを約四等分し、250gのキャベツ塊を清水で水洗した後、殺菌処理せずに、ただちに表1に示す条件のカット工程、更に水晒し工程を実施することにより、千切りキャベツを得、更に千切りキャベツ製品を製造し、10℃で冷蔵保存した。
Comparative Example 3
The whole cabbage from which the core and dirty outer leaves have been removed is divided into approximately four equal parts, and the cabbage lump of 250 g is washed with fresh water and then immediately sterilized and immediately cut in the conditions shown in Table 1 and further exposed to water. By carrying out, shredded cabbage was obtained, further shredded cabbage products were produced, and refrigerated at 10 ° C.
<エグ味評価>
 実施例1~1及び比較例1~3で得られた直後の千切りキャベツ、並びに10℃で24時間、48時間又は72時間保存した千切りキャベツ製品中の千切りキャベツを、10人の専門パネラーに食してもらい、エグ味が感じられるか否かについて、3段階(2点;エグ味が気にならない場合、1点:エグ味を感じる場合、0点:エグ味を強く感じる場合)に点数化し、そして10人の専門パネラーの評価点の合計を以下の評価基準に従ってランク付けした。得られた結果を表1に示す。
<Eg taste evaluation>
10 expert panelists eat the shredded cabbage immediately after obtained in Examples 1-1 and Comparative Examples 1-3 and shredded cabbage in shredded cabbage products stored at 10 ° C. for 24 hours, 48 hours, or 72 hours. And whether or not the taste of the taste is felt, it is scored in three stages (2 points; if the taste is not concerned, 1 point: if the taste is felt, 0 points: if the taste is felt strongly), And the total of the evaluation points of 10 expert panelists was ranked according to the following evaluation criteria. The obtained results are shown in Table 1.
 ランク 評価基準
  A: 合計点が14点以上
  B: 合計点が7点以上~13点以下
  C: 合計点が6点以下
Rank Evaluation Criteria A: Total score 14 points or more B: Total score 7 points to 13 points C: Total score 6 points or less
<保存性評価>
 製造直後の千切りキャベツ製品の中身の千切りキャベツの一般細菌数を、食品衛生検査指針(厚生労働省)に準拠する試験方法により測定し、以下基準により評価した。
<Preservation evaluation>
The general bacterial count of shredded cabbage in the shredded cabbage product immediately after production was measured by a test method in accordance with the Food Sanitation Inspection Guidelines (Ministry of Health, Labor and Welfare), and evaluated according to the following criteria.
ランク  基準
 A: 1×10CFU/g未満
 B: 1×10CFU/g以上1×10CFU/g未満
 C: 1×10CFU/g以上
Rank Criteria A: Less than 1 × 10 4 CFU / g B: 1 × 10 4 CFU / g or more and less than 1 × 10 6 CFU / g C: 1 × 10 6 CFU / g or more
Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001
 表1からわかるように、実施例1~11の千切りキャベツは、一般細菌数も少なく、千切り直後から丸3日保存した後でもエグ味が感じられないものであった。 As can be seen from Table 1, the shredded cabbage of Examples 1 to 11 had a small number of general bacteria, and even after being stored for a full 3 days immediately after shredding, the taste was not felt.
 それに対し、千切り工程を注水下で行っていない比較例1の千切りキャベツの場合、千切り直後~48時間後でエグ味評価が「B」であり、3日保存後には「C」評価であった。また、水晒し時間が1分である比較例2の千切りキャベツの場合、千切り直後でエグ味評価が「B」であり、24時間保存後には「C」評価であった。殺菌工程を行っていない比較例3の場合には、一般細菌数が非常に多く、製造直後から食用に適さないものであった。 On the other hand, in the case of the shredded cabbage of Comparative Example 1 in which the shredding process was not performed under water injection, the taste evaluation was “B” immediately after shredding to 48 hours later, and “C” was evaluated after storage for 3 days. . Further, in the case of the shredded cabbage of Comparative Example 2 in which the water exposure time was 1 minute, the taste evaluation was “B” immediately after shredding, and the “C” evaluation after 24 hours storage. In the case of Comparative Example 3 where the sterilization process was not performed, the number of general bacteria was very large, and it was not suitable for food use immediately after production.
  実施例12~16
 水晒し時間を表2に示す時間に変える以外は、実施例1と同様に千切りキャベツ製品を作成し、エグ味評価を行った。得られた結果を表2に示す。
Examples 12 to 16
A shredded cabbage product was prepared in the same manner as in Example 1 except that the water exposure time was changed to the time shown in Table 2, and the taste evaluation was performed. The obtained results are shown in Table 2.
Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002
 表2から、水晒し時間が長くなりすぎると、エグ味が発現してくることがわかる。加えて、比較例2の結果から、水晒し時間が短すぎるとエグ味が取れないことから、好ましい水晒し時間範囲(3~60分、好ましくは3~30分)があることがわかる。 From Table 2, it can be seen that if the water exposure time becomes too long, the taste becomes apparent. In addition, from the results of Comparative Example 2, it is understood that there is a preferable water exposure time range (3 to 60 minutes, preferably 3 to 30 minutes) because the taste is not removed when the water exposure time is too short.
  実施例17~20
 水晒しの際、清水に代えて表3の殺菌剤水溶液を使用すること以外は、実施例1と同様に千切りキャベツ製品を作成し、エグ味評価を行った。得られた結果を表3に示す。
Examples 17-20
A shredded cabbage product was prepared in the same manner as in Example 1 except that the disinfectant aqueous solution shown in Table 3 was used in place of fresh water at the time of water exposure, and the taste evaluation was performed. The obtained results are shown in Table 3.
Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003
 表3から、オゾン水又は亜塩素酸ナトリウム水溶液を使用して水晒し処理をしてもエグ味の発生を防止えきることがわかる。 From Table 3, it can be seen that even if it is exposed to water using ozone water or an aqueous sodium chlorite solution, it is possible to prevent the occurrence of taste.
 本発明の千切りキャベツの製造方法によれば、殺菌剤水溶液に接触させて殺菌処理したキャベツを、その切断部に清水を注ぎながら千切り処理した上で一定時間以上水晒し処理する。このため、キャベツの断面と千切りキャベツの切断面とが切断とほぼ同時に洗浄され、更にこのように洗浄された千切りキャベツが水晒しされるため、キャベツのエグ味が大きく軽減されもしくは感じられない千切りキャベツを得ることができる。よって、本発明の製造方法は、千切りキャベツの工業的製造に有用である。
 
 
According to the method for producing shredded cabbage of the present invention, cabbage that has been sterilized by bringing it into contact with a bactericide aqueous solution is shredded while pouring fresh water into the cut portion, and then subjected to a water exposure treatment for a certain time or longer. For this reason, the cross section of the cabbage and the cut surface of the shredded cabbage are cleaned almost simultaneously with the cutting, and the shredded cabbage cleaned in this way is exposed to water, so that the cabbage's taste is greatly reduced or not felt. Cabbage can be obtained. Therefore, the production method of the present invention is useful for industrial production of shredded cabbage.

Claims (11)

  1.  千切りキャベツの製造方法であって、以下の(殺菌工程)、(千切り工程)及び(水晒し工程):
    (殺菌工程)
     千切り前のキャベツを、殺菌剤水溶液に接触させて殺菌処理する工程;
    (千切り工程)
     殺菌工程で殺菌処理されたキャベツを、その切断部分に清水を注ぎながら千切り処理する工程;
    (水晒し工程)
     千切り工程で得られた千切りキャベツを、3分以上水晒しする工程
    を有する製造方法。
    A method for producing shredded cabbage, which includes the following (sterilization step), (chopping step) and (water exposure step):
    (Sterilization process)
    A step of sterilizing cabbage before cutting into contact with a bactericidal solution;
    (Chopping process)
    A step of cutting the cabbage sterilized in the sterilization process into a cut portion while pouring fresh water into the cut portion;
    (Water exposure process)
    A production method comprising a step of exposing the shredded cabbage obtained in the shredding step to water for 3 minutes or more.
  2.  千切り工程において、清水を注ぐ際の清水流量が、キャベツの千切り処理量1kg/分に対し、0.1L/分以上である請求項1記載の製造方法。 2. The production method according to claim 1, wherein in the shredding step, the flow rate of fresh water when pouring fresh water is at least 0.1 L / min with respect to 1 kg / min of cabbage shredder processing amount.
  3.  千切り工程において、0.5~3mmの巾に千切り処理する請求項1又は2記載の製造方法。 The manufacturing method according to claim 1 or 2, wherein in the shredding step, shredding is performed to a width of 0.5 to 3 mm.
  4.  殺菌工程において、殺菌剤水溶液が、次亜塩素酸ナトリウム、水酸化ナトリウム、水酸化カリウム、焼成カルシウムおよび塩酸からなる群より選択される少なくとも一種の水溶液であり、キャベツを殺菌剤水溶液に浸漬させて殺菌処理する請求項1~3のいずれかに記載の製造方法。 In the sterilization step, the aqueous sterilizing agent is at least one aqueous solution selected from the group consisting of sodium hypochlorite, sodium hydroxide, potassium hydroxide, calcined calcium and hydrochloric acid, and cabbage is immersed in the sterilizing aqueous solution. The production method according to any one of claims 1 to 3, wherein a sterilization treatment is performed.
  5.  殺菌剤水溶液が、次亜塩素酸ナトリウム30~400ppm水溶液、水酸化ナトリウム10~40000ppm水溶液、水酸化カリウム10~40000ppm水溶液、焼成カルシウム10~40000ppm水溶液及び塩酸10~40000ppm水溶液からなる群より選択される少なくとも一種である殺菌剤水溶液である請求項4記載の製造方法。 The disinfectant aqueous solution is selected from the group consisting of an aqueous solution of sodium hypochlorite 30 to 400 ppm, an aqueous solution of sodium hydroxide 10 to 40000 ppm, an aqueous solution of potassium hydroxide 10 to 40000 ppm, an aqueous solution of calcined calcium 10 to 40,000 ppm and an aqueous solution of hydrochloric acid 10 to 40,000 ppm. The production method according to claim 4, which is an aqueous bactericide solution that is at least one kind.
  6.  水晒し工程において、千切りキャベツを、清水又は殺菌工程で使用した殺菌剤水溶液よりも弱い殺菌力を有する殺菌剤水溶液に水晒し処理する請求項1~5のいずれかに記載の製造方法。 6. The production method according to any one of claims 1 to 5, wherein in the water exposure step, the shredded cabbage is subjected to a water exposure treatment with fresh water or a bactericidal aqueous solution having a weaker bactericidal power than the bactericidal aqueous solution used in the sterilizing step.
  7.  殺菌工程で使用した殺菌剤水溶液よりも弱い殺菌力を有する殺菌剤水溶液が、オゾン、亜塩素酸ナトリウム及び酢酸からなる群より選択される少なくとも一種の水溶液である請求項6記載の製造方法。 The method according to claim 6, wherein the bactericidal solution having weaker bactericidal power than the bactericidal solution used in the sterilizing step is at least one aqueous solution selected from the group consisting of ozone, sodium chlorite and acetic acid.
  8.  殺菌工程で使用した殺菌剤水溶液よりも弱い殺菌力を有する殺菌剤水溶液が、オゾン0.5~10ppm水溶液、亜塩素酸ナトリウム50~400ppm水溶液及び酢酸100~5000ppm水溶液からなる群より選択される少なくとも一種である請求項7記載の製造方法。 The bactericidal aqueous solution having a sterilizing power weaker than the bactericidal aqueous solution used in the sterilizing step is at least selected from the group consisting of ozone 0.5 to 10 ppm aqueous solution, sodium chlorite 50 to 400 ppm aqueous solution, and acetic acid 100 to 5000 ppm aqueous solution. The production method according to claim 7, which is a kind.
  9.  水晒し工程が3分~60分である請求項1~8のいずれかに記載の製造方法。 The manufacturing method according to any one of claims 1 to 8, wherein the water exposure step is 3 minutes to 60 minutes.
  10.  水晒し工程が3分~30分である請求項1~8のいずれかに記載の製造方法。 The method according to any one of claims 1 to 8, wherein the water exposure step is 3 minutes to 30 minutes.
  11.  請求項1~10のいずれかの製造方法により得られた千切りキャベツが樹脂製袋に不活性ガスと共に密封された千切りキャベツ製品。
     
    A shredded cabbage product obtained by sealing the shredded cabbage obtained by the production method according to any one of claims 1 to 10 together with an inert gas in a resin bag.
PCT/JP2011/077254 2010-11-29 2011-11-25 Production method for shredded cabbage WO2012073840A1 (en)

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