WO2012047651A3 - Tough iron-based metallic glass alloys - Google Patents

Tough iron-based metallic glass alloys Download PDF

Info

Publication number
WO2012047651A3
WO2012047651A3 PCT/US2011/053464 US2011053464W WO2012047651A3 WO 2012047651 A3 WO2012047651 A3 WO 2012047651A3 US 2011053464 W US2011053464 W US 2011053464W WO 2012047651 A3 WO2012047651 A3 WO 2012047651A3
Authority
WO
WIPO (PCT)
Prior art keywords
alloys
metallic glass
iron
based metallic
glass alloys
Prior art date
Application number
PCT/US2011/053464
Other languages
French (fr)
Other versions
WO2012047651A2 (en
Inventor
Samuel T. Kim
Marios D. Demetriou
William L. Johnson
Original Assignee
California Institute Of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by California Institute Of Technology filed Critical California Institute Of Technology
Priority to JP2013531722A priority Critical patent/JP2013542322A/en
Priority to KR1020137010092A priority patent/KR20130092586A/en
Priority to AU2011312524A priority patent/AU2011312524B2/en
Priority to CN201180055651.5A priority patent/CN103348032B/en
Priority to EP11831296.6A priority patent/EP2622109A4/en
Publication of WO2012047651A2 publication Critical patent/WO2012047651A2/en
Publication of WO2012047651A3 publication Critical patent/WO2012047651A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C45/00—Amorphous alloys
    • C22C45/02—Amorphous alloys with iron as the major constituent
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/10—Ferrous alloys, e.g. steel alloys containing cobalt
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C38/00—Ferrous alloys, e.g. steel alloys
    • C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Soft Magnetic Materials (AREA)
  • Powder Metallurgy (AREA)
  • Luminescent Compositions (AREA)
  • Hard Magnetic Materials (AREA)

Abstract

A family of iron-based, phosphor-containing bulk metallic glasses having excellent processibility and toughness, methods for forming such alloys, and processes for manufacturing articles therefrom are provided. The inventive iron-based alloy is based on the observation that by very tightly controlling the composition of the metalloid moiety of the Fe-based, P-containing bulk metallic glass alloys it is possible to obtain highly processable alloys with surprisingly low shear modulus and high toughness. Further, by incorporating small fractions of silicon (Si) and cobalt (Co) into the Fe-Ni-Mo-P-C-B system, alloys of 3 and 4 mm have been synthesized with high saturation magnetization and low switching losses.
PCT/US2011/053464 2010-09-27 2011-09-27 Tough iron-based metallic glass alloys WO2012047651A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2013531722A JP2013542322A (en) 2010-09-27 2011-09-27 Tough iron-based bulk metallic glass alloy
KR1020137010092A KR20130092586A (en) 2010-09-27 2011-09-27 Tough iron-based metallic glass alloys
AU2011312524A AU2011312524B2 (en) 2010-09-27 2011-09-27 Tough iron-based metallic glass alloys
CN201180055651.5A CN103348032B (en) 2010-09-27 2011-09-27 The based bulk metallic glasses shape alloy of toughness
EP11831296.6A EP2622109A4 (en) 2010-09-27 2011-09-27 Tough iron-based metallic glass alloys

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US38691010P 2010-09-27 2010-09-27
US61/386,910 2010-09-27

Publications (2)

Publication Number Publication Date
WO2012047651A2 WO2012047651A2 (en) 2012-04-12
WO2012047651A3 true WO2012047651A3 (en) 2012-08-16

Family

ID=45928320

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/053464 WO2012047651A2 (en) 2010-09-27 2011-09-27 Tough iron-based metallic glass alloys

Country Status (7)

Country Link
US (1) US8911572B2 (en)
EP (1) EP2622109A4 (en)
JP (2) JP2013542322A (en)
KR (1) KR20130092586A (en)
CN (1) CN103348032B (en)
AU (1) AU2011312524B2 (en)
WO (1) WO2012047651A2 (en)

Families Citing this family (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MY156933A (en) * 2009-05-19 2016-04-15 California Inst Of Techn Tough iron-based bulk metallic glass alloys
JP5990270B2 (en) 2011-08-22 2016-09-07 カリフォルニア インスティテュート オブ テクノロジー Bulk nickel-based chromium and phosphorus-containing metallic glass
US20150047463A1 (en) * 2012-06-26 2015-02-19 California Institute Of Technology Systems and methods for implementing bulk metallic glass-based macroscale gears
WO2014058498A2 (en) 2012-07-17 2014-04-17 California Institute Of Technology Systems and methods for implementing bulk metallic glass-based macroscale compliant gears
WO2014043722A2 (en) 2012-09-17 2014-03-20 Glassimetal Technology Inc., Bulk nickel-silicon-boron glasses bearing chromium
DE112013005202T5 (en) * 2012-10-30 2015-08-27 Glassimetal Technology, Inc. Nickel-based solid chromium and phosphorus-containing solid glass with high hardness
US9365916B2 (en) 2012-11-12 2016-06-14 Glassimetal Technology, Inc. Bulk iron-nickel glasses bearing phosphorus-boron and germanium
US9556504B2 (en) 2012-11-15 2017-01-31 Glassimetal Technology, Inc. Bulk nickel-phosphorus-boron glasses bearing chromium and tantalum
US9211564B2 (en) 2012-11-16 2015-12-15 California Institute Of Technology Methods of fabricating a layer of metallic glass-based material using immersion and pouring techniques
CN103060724B (en) * 2013-01-04 2015-02-18 大连理工大学 Iron-based bulk metallic glass alloy with large supercooled liquid phase region
JP2014132116A (en) * 2013-01-07 2014-07-17 Glassimetal Technology Inc Bulk nickel-silicon-boron glasses bearing iron
US9579718B2 (en) 2013-01-24 2017-02-28 California Institute Of Technology Systems and methods for fabricating objects including amorphous metal using techniques akin to additive manufacturing
EP2951329A1 (en) 2013-01-29 2015-12-09 Glassimetal Technology Inc. Golf club fabricated from bulk metallic glasses with high toughness and high stiffness
US9328813B2 (en) 2013-02-11 2016-05-03 California Institute Of Technology Systems and methods for implementing bulk metallic glass-based strain wave gears and strain wave gear components
US9816166B2 (en) 2013-02-26 2017-11-14 Glassimetal Technology, Inc. Bulk nickel-phosphorus-boron glasses bearing manganese
US20140342179A1 (en) 2013-04-12 2014-11-20 California Institute Of Technology Systems and methods for shaping sheet materials that include metallic glass-based materials
US9610650B2 (en) 2013-04-23 2017-04-04 California Institute Of Technology Systems and methods for fabricating structures including metallic glass-based materials using ultrasonic welding
US9777359B2 (en) * 2013-05-07 2017-10-03 California Institute Of Technology Bulk ferromagnetic glasses free of non-ferrous transition metals
US10081136B2 (en) 2013-07-15 2018-09-25 California Institute Of Technology Systems and methods for additive manufacturing processes that strategically buildup objects
US9708699B2 (en) 2013-07-18 2017-07-18 Glassimetal Technology, Inc. Bulk glass steel with high glass forming ability
US9863025B2 (en) 2013-08-16 2018-01-09 Glassimetal Technology, Inc. Bulk nickel-phosphorus-boron glasses bearing manganese, niobium and tantalum
US9868150B2 (en) 2013-09-19 2018-01-16 California Institute Of Technology Systems and methods for fabricating structures including metallic glass-based materials using low pressure casting
US9920400B2 (en) 2013-12-09 2018-03-20 Glassimetal Technology, Inc. Bulk nickel-based glasses bearing chromium, niobium, phosphorus and silicon
US9957596B2 (en) 2013-12-23 2018-05-01 Glassimetal Technology, Inc. Bulk nickel-iron-based, nickel-cobalt-based and nickel-copper based glasses bearing chromium, niobium, phosphorus and boron
US10000834B2 (en) 2014-02-25 2018-06-19 Glassimetal Technology, Inc. Bulk nickel-chromium-phosphorus glasses bearing niobium and boron exhibiting high strength and/or high thermal stability of the supercooled liquid
US10287663B2 (en) 2014-08-12 2019-05-14 Glassimetal Technology, Inc. Bulk nickel-phosphorus-silicon glasses bearing manganese
US10487934B2 (en) 2014-12-17 2019-11-26 California Institute Of Technology Systems and methods for implementing robust gearbox housings
US10151377B2 (en) 2015-03-05 2018-12-11 California Institute Of Technology Systems and methods for implementing tailored metallic glass-based strain wave gears and strain wave gear components
US10174780B2 (en) 2015-03-11 2019-01-08 California Institute Of Technology Systems and methods for structurally interrelating components using inserts made from metallic glass-based materials
US10155412B2 (en) 2015-03-12 2018-12-18 California Institute Of Technology Systems and methods for implementing flexible members including integrated tools made from metallic glass-based materials
US10968527B2 (en) 2015-11-12 2021-04-06 California Institute Of Technology Method for embedding inserts, fasteners and features into metal core truss panels
CN105598652B (en) * 2016-03-18 2018-01-19 中国科学院力学研究所 A kind of method for making ductile metal glass produce macroscopical stretching plastic
US11905582B2 (en) 2017-03-09 2024-02-20 Glassimetal Technology, Inc. Bulk nickel-niobium-phosphorus-boron glasses bearing low fractions of chromium and exhibiting high toughness
DE112018001284T5 (en) 2017-03-10 2019-11-28 California Institute Of Technology METHOD OF MANUFACTURING DEVICE GEAR FLEX PLINES BY ADDITIVE METAL PRODUCTION
US10458008B2 (en) 2017-04-27 2019-10-29 Glassimetal Technology, Inc. Zirconium-cobalt-nickel-aluminum glasses with high glass forming ability and high reflectivity
EP3630395A4 (en) * 2017-05-24 2020-11-25 California Institute of Technology Hypoeutectic amorphous metal-based materials for additive manufacturing
US11014162B2 (en) 2017-05-26 2021-05-25 California Institute Of Technology Dendrite-reinforced titanium-based metal matrix composites
US11077655B2 (en) 2017-05-31 2021-08-03 California Institute Of Technology Multi-functional textile and related methods of manufacturing
EP3630397A4 (en) 2017-06-02 2020-11-11 California Institute of Technology High toughness metallic glass-based composites for additive manufacturing
DE102018112491A1 (en) * 2017-10-27 2019-05-02 Vacuumschmelze Gmbh & Co. Kg High permeability soft magnetic alloy and method of making a high permeability soft magnetic alloy
CN110257734A (en) * 2018-10-15 2019-09-20 天津师范大学 Corrosion resistant iron-base amorphous alloy material and its preparation method and application
US11371108B2 (en) 2019-02-14 2022-06-28 Glassimetal Technology, Inc. Tough iron-based glasses with high glass forming ability and high thermal stability
US11859705B2 (en) 2019-02-28 2024-01-02 California Institute Of Technology Rounded strain wave gear flexspline utilizing bulk metallic glass-based materials and methods of manufacture thereof
US11680629B2 (en) 2019-02-28 2023-06-20 California Institute Of Technology Low cost wave generators for metal strain wave gears and methods of manufacture thereof
US11400613B2 (en) 2019-03-01 2022-08-02 California Institute Of Technology Self-hammering cutting tool
US11591906B2 (en) 2019-03-07 2023-02-28 California Institute Of Technology Cutting tool with porous regions
SE545332C2 (en) * 2019-05-22 2023-07-04 Questek Europe Ab Bulk metallic glass-based alloys for additive manufacturing
CN114150236A (en) * 2020-12-24 2022-03-08 佛山市中研非晶科技股份有限公司 Iron-based amorphous alloy film, preparation method thereof, electromagnetic shielding film and equipment applying iron-based amorphous alloy film
CN115198209A (en) * 2021-04-09 2022-10-18 泰州市新龙翔金属制品有限公司 Iron-based alloy applied to tooth root implant and preparation process thereof
DE102021113306A1 (en) 2021-05-21 2022-11-24 Technische Universität Darmstadt, Körperschaft des öffentlichen Rechts Process for producing a base material for a permanent magnet
US11687124B2 (en) * 2021-05-25 2023-06-27 Microsoft Technology Licensing, Llc Computing device hinge assembly
CN115305320A (en) * 2022-07-12 2022-11-08 龙志文 Pretreatment equipment for die steel

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005264260A (en) * 2004-03-19 2005-09-29 Nec Tokin Corp Soft magnetic yoke and electromagnetic actuator using the same
JP2005290468A (en) * 2004-03-31 2005-10-20 Akihisa Inoue Iron-based metallic glass alloy
KR100582579B1 (en) * 1997-07-09 2006-05-24 바쿰슈멜체 게엠베하 운트 코. 카게 Resonator and method of making the same, system of apparatuses including said resonator and method of making the system of apparatuses
KR20090038016A (en) * 2006-08-23 2009-04-17 도꾸리쯔교세이호징 가가꾸 기쥬쯔 신꼬 기꼬 Iron-based alloy and process for producing the same

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4152144A (en) * 1976-12-29 1979-05-01 Allied Chemical Corporation Metallic glasses having a combination of high permeability, low magnetostriction, low ac core loss and high thermal stability
JP3904250B2 (en) 1995-06-02 2007-04-11 独立行政法人科学技術振興機構 Fe-based metallic glass alloy
JP3710226B2 (en) 1996-03-25 2005-10-26 明久 井上 Quench ribbon made of Fe-based soft magnetic metallic glass alloy
JPH10226856A (en) 1997-02-19 1998-08-25 Alps Electric Co Ltd Production of metallic glass alloy
US6053989A (en) * 1997-02-27 2000-04-25 Fmc Corporation Amorphous and amorphous/microcrystalline metal alloys and methods for their production
JPH1171657A (en) 1997-08-29 1999-03-16 Alps Electric Co Ltd Net for electromagnetic shield and sheet for electromagnetic shield
JP3644248B2 (en) 1998-04-13 2005-04-27 Ｊｆｅスチール株式会社 Iron-based amorphous alloy for transformers with excellent soft magnetic properties
JP2001338808A (en) 2000-03-21 2001-12-07 Alps Electric Co Ltd Filter and amplifier
CN1204570C (en) 2002-03-01 2005-06-01 北京科技大学 Rare earth iron base soft magnetic metallic glass having very large super cooling region
US7282103B2 (en) 2002-04-05 2007-10-16 Nippon Steel Corporation Iron-base amorphous alloy thin strip excellent in soft magnetic properties, iron core manufactured by using said thin strip, and mother alloy for producing rapidly cooled and solidified thin strip
JP3913167B2 (en) 2002-12-25 2007-05-09 独立行政法人科学技術振興機構 Bulk Fe-based sintered alloy soft magnetic material made of metallic glass and manufacturing method thereof
USRE47529E1 (en) * 2003-10-01 2019-07-23 Apple Inc. Fe-base in-situ composite alloys comprising amorphous phase
US7918946B2 (en) 2007-02-28 2011-04-05 Nippon Steel Corporation Fe-based amorphous alloy excellent in soft magnetic properties
CN101289718A (en) 2007-12-06 2008-10-22 上海中亚阀门有限公司 Metallic glass material synthesized from metallic elements
MY156933A (en) 2009-05-19 2016-04-15 California Inst Of Techn Tough iron-based bulk metallic glass alloys

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100582579B1 (en) * 1997-07-09 2006-05-24 바쿰슈멜체 게엠베하 운트 코. 카게 Resonator and method of making the same, system of apparatuses including said resonator and method of making the system of apparatuses
JP2005264260A (en) * 2004-03-19 2005-09-29 Nec Tokin Corp Soft magnetic yoke and electromagnetic actuator using the same
JP2005290468A (en) * 2004-03-31 2005-10-20 Akihisa Inoue Iron-based metallic glass alloy
KR20090038016A (en) * 2006-08-23 2009-04-17 도꾸리쯔교세이호징 가가꾸 기쥬쯔 신꼬 기꼬 Iron-based alloy and process for producing the same

Also Published As

Publication number Publication date
WO2012047651A2 (en) 2012-04-12
US8911572B2 (en) 2014-12-16
US20120073710A1 (en) 2012-03-29
AU2011312524A1 (en) 2013-05-02
AU2011312524B2 (en) 2015-10-29
JP2013542322A (en) 2013-11-21
CN103348032B (en) 2015-09-09
CN103348032A (en) 2013-10-09
EP2622109A4 (en) 2017-05-31
EP2622109A2 (en) 2013-08-07
JP2016027207A (en) 2016-02-18
KR20130092586A (en) 2013-08-20

Similar Documents

Publication Publication Date Title
WO2012047651A3 (en) Tough iron-based metallic glass alloys
WO2010135415A3 (en) Tough iron-based bulk metallic glass alloys
WO2011160617A3 (en) Nickel-based alloy
WO2008129803A1 (en) Soft magnetic alloy, magnetic component using the same, and their production methods
WO2007027724A3 (en) Steel compositions, methods of forming the same, and articles formed therefrom
WO2017082687A8 (en) Non-quenched and tempered wire rod having excellent cold workability and manufacturing method therefor
WO2012010941A8 (en) Watch-making or clock-making component comprising an amorphous metal alloy
MX2016001013A (en) Steel sheet having very high mechanical properties of strength and ductility, manufacturing method and use of such sheets.
WO2007144516A3 (en) Duplex stainless steel
WO2009025314A1 (en) High-strength low-alloy steel excellent in the resistance to high-pressure hydrogen environment embrittlement and process for manufacturing the steel
MX2007011944A (en) High tensile steel product excellent in delayed fracture resistance and method for production thereof.
WO2008051623A3 (en) Soft magnetic alloy and uses thereof
WO2009028671A1 (en) Low-thermal-expansion ni-based super-heat-resistant alloy for boiler and having excellent high-temperature strength, and boiler component and boiler component production method using the same
WO2011081386A3 (en) Non-oriented electrical steel sheet having superior magnetic properties and a production method therefor
MY145700A (en) Oil country tubular good for expansion in well and manufacturing method thereof
WO2017082684A8 (en) Wire rod having excellent cold forgeability and manufacturing method therefor
MX2014002694A (en) Rolled steel that hardens by means of precipitation after hot-forming and/or quenching with a tool having very high strength and ductility, and method for manufacturing same.
WO2014014540A3 (en) High strength, high toughness steel alloy
CA2630716A1 (en) Tool with a coating
WO2011081360A3 (en) Ultra-high-strength steel wire having excellent resistance to delayed fracture and manufacturing method thereof
IN2014KN01170A (en)
GB2441330B (en) Alloys, bulk metallic glass, and methods of forming the same
WO2011003857A3 (en) Auxiliary material for soldering sheets
MY181980A (en) Soft magnetic alloy for magnetic recording, sputtering target material, and magnetic recording medium
IN2014KN01068A (en)

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11831296

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2013531722

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2011831296

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 20137010092

Country of ref document: KR

Kind code of ref document: A

ENP Entry into the national phase

Ref document number: 2011312524

Country of ref document: AU

Date of ref document: 20110927

Kind code of ref document: A