WO2012046876A2 - Composition de lutte contre les maladies des plantes, et méthode de lutte contre les maladies des plantes - Google Patents

Composition de lutte contre les maladies des plantes, et méthode de lutte contre les maladies des plantes Download PDF

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Publication number
WO2012046876A2
WO2012046876A2 PCT/JP2011/073462 JP2011073462W WO2012046876A2 WO 2012046876 A2 WO2012046876 A2 WO 2012046876A2 JP 2011073462 W JP2011073462 W JP 2011073462W WO 2012046876 A2 WO2012046876 A2 WO 2012046876A2
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WO
WIPO (PCT)
Prior art keywords
procymidone
plant disease
present
composition
controlling
Prior art date
Application number
PCT/JP2011/073462
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English (en)
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WO2012046876A3 (fr
Inventor
So Kiguchi
Soichi Tanaka
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Sumitomo Chemical Company, Limited
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Filing date
Publication date
Application filed by Sumitomo Chemical Company, Limited filed Critical Sumitomo Chemical Company, Limited
Priority to AU2011313144A priority Critical patent/AU2011313144A1/en
Priority to KR1020137009158A priority patent/KR101844099B1/ko
Priority to CN201180048511.5A priority patent/CN103153055B/zh
Priority to BR112013008512-6A priority patent/BR112013008512B1/pt
Publication of WO2012046876A2 publication Critical patent/WO2012046876A2/fr
Publication of WO2012046876A3 publication Critical patent/WO2012046876A3/fr
Priority to ZA2013/01903A priority patent/ZA201301903B/en

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/32—Cyclic imides of polybasic carboxylic acids or thio analogues thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N2300/00—Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48

Definitions

  • the present invention relates to a plant disease controlling composition and a method for controlling a plant disease.
  • An object of the present invention is to provide a composition having an excellent control effect on a plant disease .
  • the present inventors have intensively studied to find out a composition having an excellent control effect on a plant disease. As a result, they have found that a composition comprising the compound represented by Formula (1) and procymidone shows a synergistic activity, and thus has an excellent control effect on a plant disease, and therefore the present invention has been completed.
  • the present invention provides :
  • a plant disease controlling composition comprising a compound represented by Formula (1) :
  • a method for controlling a plant disease comprising applying an effective amount in total of a compound of Formula (1) :
  • procymidone to a plant or a soil for cultivating the plant.
  • the present invention enables to control a plant disease .
  • a plant disease controlling composition of the present invention (hereinafter, referred to as a composition of the present invention) comprises a compound represented by Formula (1) :
  • an amide compound of the present invention (hereinafter, referred to as an amide compound of the present invention) and procymidone.
  • the present amide compound is described in for example, WO 95/27693 pamphlet and WO 02/10101 pamphlet, and thus can be prepared according to the method described therein.
  • the present amide compound has one asymmetric carbon.
  • a compound represented by Formula (1) wherein an enantiomer having R-absolute configuration is enriched is referred to as an amide compound having R-absolute configuration .
  • the present amide compound encompasses the following compounds :
  • Procymidone to be used in the present invention is a known compound, which is described in for example, ''The PESTICIDE MANUAL - 15th EDITION (BCPC published) ISBN 1901396188'', page 930. Procymidone is either commercially available, or can be prepared by a known method.
  • the weight ratio of the present amide compound to procymidone in the composition of the present invention is usually from 0.0125/1 to 500/1 (the present amide compound/procymidone), preferably 0.025/1 to 100/1, and more preferably 0.1/1 to 10/1.
  • composition of the present invention may be a mixture as itself of the present amide compound and procymidone
  • the composition of the present invention is usually prepared by mixing the present amide compound, procymidone and an inert carrier, and if necessary, adding a surfactant or other pharmaceutical additives, and then formulating into the form of oil solution, emulsifiable concentrate, flowable formulation, wettable powder, granulated wettable powder, dust formulation, granules and so on.
  • oil solution emulsifiable concentrate
  • flowable formulation wettable powder
  • granulated wettable powder granulated wettable powder
  • dust formulation granules and so on.
  • Such formulations can be used by itself or with an addition of other inert components as an agent for controlling a plant disease.
  • the composition of the present invention can contain 0.1 to 99 % by weight, preferably 0.2 to 90 % by weight, and more preferably 1 to 80 % by weight of the present amide compound and procymidone in total.
  • Examples of a solid carrier used on the formulation include finely-divided powder or particles of clay consisting of minerals (e.g., kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite , talc, diatomaceous earth, or calcite) , natural organic substances (e.g., corncob powder, or walnut shell powder), synthetic organic substances (e.g., urea), salts (e.g., calcium carbonate, or ammonium sulfate) , synthetic inorganic substances (e.g., synthetic hydrous silicon oxide) and so on.
  • minerals e.g., kaolin clay, attapulgite clay, bentonite, montmorillonite, acid clay, pyrophyllite , talc, diatomaceous earth, or calcite
  • natural organic substances e.g., corncob powder, or walnut shell powder
  • synthetic organic substances e.g., urea
  • liquid carrier examples include aromatic hydrocarbons (e.g., xylene, alkyl benzene, or methylnaphtalene) , alcohols (e.g., 2-propanol, ethylene glycol, propylene glycol, or ethylene glycol monoethyl ether), ketones (e.g., acetone, cyclohexanone, or isophorone) , vegetable oils (e.g., soybean oil, or cotton oils) , petroleum-derived aliphatic hydrocarbons, esters, dimethylsulfoxide, acetonitrile and water.
  • aromatic hydrocarbons e.g., xylene, alkyl benzene, or methylnaphtalene
  • alcohols e.g., 2-propanol, ethylene glycol, propylene glycol, or ethylene glycol monoethyl ether
  • ketones e.g., acetone, cyclohexanone, or isophorone
  • surfactant examples include anionic surfactant (e.g., alkyl sulfate salts, alkylaryl sulfate salts, dialkyl sulfosuccinate salts, polyoxyethylene alkylaryl ether phosphates, lignin sulfonate, or naphthalenesulfonate formaldehyde polycondensation) , nonionic surfactant (e.g., polyoxyethylene alkylaryl ether, polyoxyethylene alkyl polyoxypropylene block copolymer, or sorbitan fatty acid ester) and cationic surfactant (e.g., alkyltrimethyl ammonium salts) .
  • anionic surfactant e.g., alkyl sulfate salts, alkylaryl sulfate salts, dialkyl sulfosuccinate salts, polyoxyethylene alkylaryl ether phosphates, lignin sulfonate,
  • water-soluble polymer e.g., polyvinyl alcohol, orpolyvinyl pyrrolidone
  • polysaccharides e.g. arabic gum, alginic acid and salts thereof, CMC ( carboxymethyl- cellulose) , or xanthan gum
  • inorganic substances e.g, aluminum magnesium silicate, or alumina-sol
  • antiseptic agent coloring agent
  • PAP isopropyl acid phosphate
  • stabilizing agent e.g., BHT
  • composition of the present invention can also be prepared by separately formulating the present amide compound and procymidone into different formulations by the above procedures, if necessary, further diluting each of them with water, thereafter, mixing the separately prepared different formulations or the dilute solutions.
  • composition of the present invention may further contain one or more other fungicide (s) and/or insecticide ( s ) .
  • composition of the present invention is used to control a plant disease by applying it to a plant or a soil for cultivating the plant.
  • Citrus diseases melanose ⁇ Diaporthe citri) , scab
  • Pear diseases scab (Venturia nashicola, V. pirina) , black spot ⁇ Alternaria alternata Japanese pear pathotype) , rust ⁇ Gymnosporangium asiaticum) and late blight ⁇ Phytophtora cactorum) ;
  • Grapes diseases anthracnose ⁇ Elsinoe ampelina) , ripe rot ⁇ Glomerella cingulata) , powdery mildew ⁇ Uncinula necator) , rust ⁇ Phakopsora ampelopsidis) , black rot ⁇ Guignardia bidwellii) , downy mildew ⁇ Plasmopara viticola) and Gray mold ⁇ Botrytis cinerea) ;
  • Tomato diseases early blight (Alternaria solani) , leaf mold ⁇ Cladosporium fulvum) and late blight ⁇ Phytophthora infestans) ;
  • Rapeseed diseases Sclerotinia rot ⁇ Sclerotinia sclerotiorum) , black spot ⁇ Alternaria brassicae) , powdery mildew ⁇ Erysiphe cichoracearum) , blackleg ⁇ Leptosphaeria maculans) ;
  • Soybean diseases purple seed stain ⁇ Cercospora kikuchii) , Sphaceloma scad ⁇ Elsinoe glycines) , pod and stem blight ⁇ Diaporthe phaseolorum var. sojae), rust ⁇ Phakopsora pachyrhizi) and phytophthora stem rot ⁇ Phytophthora sojae) ;
  • Adzuki-bean diseases Gray mold ⁇ Botrytis cinerea) , Sclerotinia rot ⁇ Sclerotinia sclerotiorum) ;
  • Kidney bean diseases Gray mold ⁇ Botrytis cinerea) , Sclerotinia rot ⁇ Sclerotinia sclero tiorum) , anthracnose ⁇ Colletotrichum lindemthianum) ;
  • Peanut diseases leaf spot ⁇ Cercospora personata) , brown leaf spot ⁇ Cercospora arachidicola) and southern blight ⁇ Sclerotium rolfsii) ;
  • Plant pea diseases powdery mildew ⁇ Erysiphe pisi
  • Potato diseases early blight (Alternaria solani) and late blight [Phytophthora infestans) ;
  • Tea diseases net blister blight [Exobasidium reticulatum) , white scab ⁇ Elsinoe leucospila) , gray blight ⁇ Pestalotiopsis sp.) and anthracnose ⁇ Colletotrichum theae- sinensis) ;
  • Cotton diseases fusarium wilt ⁇ Fusarium oxysporum) , damping-off ⁇ Rhizoctonia solani) ;
  • Tabacco diseases brown spot ⁇ Alternaria longipes) , powdery mildew (Erysiphe cichoracearum) , anthracnose ⁇ Colletotrichum tabacum) , downy mildew ⁇ Peronospora tabacina) and late blight ⁇ Phytophthora nicotianae) ;
  • Rose diseases black spot ⁇ Diplocarpon rosae) and powdery mildew ⁇ Sphaerotheca pannosa) ;
  • Chrysanthemum diseases leaf blight ⁇ Septoria chrysanthemi-indici) and white rust (Puccinia horiana) ;
  • Turfgrass diseases dollar spot ⁇ Sclerotinia homeocarpa) , brown patch and large patch ⁇ Rhizoctonia solani) ;
  • Banana diseases Sigatoka disease ⁇ Mycosphaerella fij iensis, Mycosphaerella musicola , Pseudocercospora musae) .
  • Crops corn, rice, wheat, barley, rye, oat, sorghum, cotton, soybean, adzuki-bean, kidney bean, peanut, buckwheat, beet, rapeseed, sunflower, sugar cane, and tobacco, etc . ;
  • Vegetables solanaceous vegetables (eggplant, tomato, pimento, pepper, and potato, etc.), cucurbitaceous vegetables (cucumber, pumpkin, zucchini, water melon, melon, and squash, etc.), cruciferous vegetables (Japanese radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, and cauliflower, etc.
  • asteraceous vegetables (burdock, crown daisy, artichoke, and lettuce, etc.), liliaceous vegetables (welsh onion, onion, garlic, and asparagus) , ammiaceous vegetables (carrot, parsley, celery, and parsnip, etc.), chenopodiaceous vegetables (spinach, and Swiss chard, etc.), laitiiaceous vegetables (Perilla frutescens, mint, and basil, etc.), strawberry, sweet potato, Japanese yam, and taro, etc . ;
  • Fruits pomaceous fruits (apple, pear, Japanese pear, Chinese quince, and quince, etc.), stone fleshy fruits (peach, plum, nectarine, Japanese apricot, cherry fruit, apricot, and prune, etc.), citrus fruits (Citrus unshiu, orange, lemon, lime, and grapefruit, etc.), nuts (chestnut, walnuts, hazelnuts, almond, pistachio, cashew nuts, and macadamia nuts, etc.), berrys (blueberry, cranberry, blackberry, and raspberry, etc.), grape, kaki persimmon, olive, Japanese plum, banana, coffee, date palm, and coconuts, etc.; and
  • Trees other than fruit trees tea, mulberry, flowering plant, roadside trees (ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate), etc.
  • plants include plants which resistances have been imparted by genetic recombination.
  • compositions comprising the present amide compound and procymidone wherein the weight ratio of the present amide compound to procymidone is from 0.0125/1 to 500/1; a composition comprising the present amide compound and procymidone wherein the weight ratio of the present amide compound to procymidone is from 0.025/1 to 100/1; and a composition comprising the present amide compound and procymidone wherein the weight ratio of the present amide compound to procymidone is from 0.1/1 to 10/1.
  • the method for controlling a plant disease of the present invention comprises applying an effective amount in total of the present amide compound and procymidone to the plants or the soil for cultivating the plant.
  • Such plants include foliages of plant, seeds of plant, or bulbs of plant.
  • the bulbs herein are intended to mean bulb, corm, rootstock, tuber, tuberous root and rhizophore.
  • the present amide compound and procymidone may be applied separately around the same time to the plant or the soil for cultivating the plant, but is usually applied as the composition of the present invention because of a convenience on applying.
  • examples of the method of applying the present amide compound and procymidone include foliage treatment, soil treatment, root treatment and seed treatment.
  • Such foliage treatment includes for example, a method of applying the composition of the present invention to a surface of the plant to be cultivated by a foliage application or a stem application.
  • Such root treatment includes a method of soaking a whole or a root of the plant into a medicinal solution comprising the present amide compound and procymidone, and a method of attaching a solid formulation comprising the present amide compound, procymidone and the solid carrier to a root of the plant.
  • Such soil treatment includes soil broadcast, soil incorporation, and irrigation of the medicinal solution to a soil.
  • Such seed treatment includes an applying of the composition of the present invention to a seed or a bulb of the plant to be prevented from the plant disease, specifically, a spray treatment by spraying a suspension of the composition of the present invention in a mist form to a surface of a seed or a surface of a bulb, a smear treatment by smearing the wettable powder, the emulsifiable concentrate or the flowable formulation of the composition of the present invention with an addition of small amounts of water or as itself to a seed or a bulb, an immerse treatment of a seed into a solution of the composition of the present invention for a given time, a film-coating treatment, and a pellet-coating treatment.
  • a spray treatment by spraying a suspension of the composition of the present invention in a mist form to a surface of a seed or a surface of a bulb
  • a smear treatment by smearing the wettable powder
  • Each dose of the present amide compound and procymidone in the method for controlling of the present invention may vary depending on a kind of plant to be treated, a kind or a frequency of an occurrence of a plant disease as a control subject, a dosage form, a treatment period, a treatment method, a treatment site, a climate condition, etc.
  • a total amount of the present amide compound and procymidone is usually 1 to 500 g, preferably 2 to 200 g, and more preferably 10 to 100 g, per 1000 m 2 .
  • Each dose of the present amide compound and procymidone in the treatment for seed is usually 0.001 to 10 g, and preferably 0.01 to 1 g, per 1kg of seeds as a total amount of the present amide compound and procymidone .
  • the emulsifiable concentrate, the wettable powder or the flowable formulation, etc. is usually applied by diluting them with water, and then spreading them.
  • each concentration of the present amide compound and procymidone contains 0.0005 to 2% by weight, and preferably 0.005 to 1% by weight of the present amide compound and procymidone in total.
  • the dust formulation or the granular formulation, etc is usually applied as itself without diluting them.
  • 10 parts of the present amide compound, 5 parts of procymidone and 1.5 parts of sorbitan trioleate are mixed into 28 parts of an aqueous solution that contains 2 parts of polyvinyl alcohol, and the mixed solution is then subjected to fine grinding according to wet grinding method. Thereafter, 45.50 parts of an aqueous solution that contains 0.05 parts of xanthan gum and 0.1 part of aluminum magnesium silicate is added to the resultant, and 10 parts of propylene glycol is further added thereto. The obtained mixture is blended by stirring, so as to obtain the flowable formulation.
  • test examples are given below.
  • Test Examples 1 to 2 True leaf of cucumber was punched out with cork borer to 13mm in diameter to prepare a leaf disk.
  • 24 well microwell plate that was dispensed with 1ml 0.8% water agar, the leaf disk was placed such that the upper side of the leaf was in an upward direction.
  • Thereto was added 20 micro liter a testing solution prepared by mixing a dimethyl sulfoxide solution of the present amide compound and a dimethyl sulfoxide solution of procymidone to a predetermined concentration to treat the leaf disk.
  • onset area rate (hereinafter, referred to as an onset area rate belonging to treated group) .
  • an onset area rate (hereinafter, referred to an onset area rate belonging to non-treated group) .
  • a preventive value was calculated from the above onset area rate belonging to treated group and the onset area rate belonging to non-treated group by the following equation :
  • onset area rate (onset area of the leaf disk) /(the total area of the leaf disk)
  • test Examples 1 to 2 For comparison, the same operations as described in Test Examples 1 to 2 were carried out except that the testing medicine solution was substituted with a predetermined concentration of a dimethyl sulfoxide solution of the present amide compound or procymidone, so as to calculate a preventive value.

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

La présente invention concerne une composition présentant une excellente activité de lutte contre une maladie des plantes. La composition comprend un composé représenté par la formule (1), et la procymidone présente une excellente activité de lutte contre une maladie des plantes.
PCT/JP2011/073462 2010-10-07 2011-10-05 Composition de lutte contre les maladies des plantes, et méthode de lutte contre les maladies des plantes WO2012046876A2 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
AU2011313144A AU2011313144A1 (en) 2010-10-07 2011-10-05 Plant disease controlling composition and method for controlling plant disease
KR1020137009158A KR101844099B1 (ko) 2010-10-07 2011-10-05 식물 병해 방제 조성물 및 식물 병해 방제 방법
CN201180048511.5A CN103153055B (zh) 2010-10-07 2011-10-05 植物病害防治组合物及用于防治植物病害的方法
BR112013008512-6A BR112013008512B1 (pt) 2010-10-07 2011-10-05 Composição e método para controle de doença de planta e uso
ZA2013/01903A ZA201301903B (en) 2010-10-07 2013-03-13 Plant disease controlling composition and method for controlling plant disease

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2010227398 2010-10-07
JP2010-227398 2010-10-07
JP2011-049970 2011-03-08
JP2011049970A JP2012097063A (ja) 2010-10-07 2011-03-08 植物病害防除組成物及び植物病害防除方法

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WO2012046876A2 true WO2012046876A2 (fr) 2012-04-12
WO2012046876A3 WO2012046876A3 (fr) 2012-11-08

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JP (1) JP2012097063A (fr)
KR (1) KR101844099B1 (fr)
CN (1) CN103153055B (fr)
AR (1) AR083270A1 (fr)
AU (1) AU2011313144A1 (fr)
BR (1) BR112013008512B1 (fr)
CL (1) CL2013000925A1 (fr)
WO (1) WO2012046876A2 (fr)
ZA (1) ZA201301903B (fr)

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CN105210760A (zh) * 2015-09-23 2016-01-06 无锡市阳山镇福寿水蜜桃专业合作社 防治水蜜桃炭疽病的方法

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WO2002010101A1 (fr) 2000-08-01 2002-02-07 Shionogi & Co., Ltd. Procede de production d'un alcool en presence d'un complexe de metaux de transition contenant un compose amide en tant que liant

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CN103153055A (zh) 2013-06-12
KR101844099B1 (ko) 2018-03-30
WO2012046876A3 (fr) 2012-11-08
BR112013008512A8 (pt) 2017-10-10
KR20130117770A (ko) 2013-10-28
AU2011313144A1 (en) 2013-04-04
BR112013008512B1 (pt) 2018-02-06
CL2013000925A1 (es) 2014-03-14
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