WO2012043030A1

WO2012043030A1 - Surface brazing method of aluminum alloy material

Info

Publication number: WO2012043030A1
Application number: PCT/JP2011/066790
Authority: WO
Inventors: 貴訓小久保; 堀　久司; 智浩佐々木
Original assignee: 日本軽金属株式会社
Priority date: 2010-09-29
Filing date: 2011-07-19
Publication date: 2012-04-05
Also published as: CN103068512A; TWI504460B; CN103068512B; KR20130058055A; JP5532520B2; KR101504046B1; JP2012071335A; TW201213028A

Abstract

Disclosed is a flux-free method of surface brazing two aluminum alloy members using a single-layer brazing sheet. While maintaining the brazing temperature at 570C or greater in an inert gas atmosphere and while applying a surface pressure of at least 0.6 gf/mm², the aluminum alloy members, which have a solidus temperature of 570C or greater, are brazed flux-free in a state in which a single-layer brazing sheet 15-200μm thick comprising a brazing material (having a component composition of 3-12 mass% Si, 0.1-5.0 mass% Mg, and the remaining portion consisting of Al and unavoidable impurities) is positioned between and in surface contact with the aluminum alloy members.

Description

Surface brazing method for aluminum alloy members

The present invention relates to a method of brazing aluminum alloy members to each other without flux in an inert gas atmosphere using a brazing sheet.

For example, as seen in the brazing of fins and tubes of aluminum heat exchangers, the conventional brazing techniques have been based on line contact so that a fillet shape is obtained. In such a brazing method, for example, when the lower plate is a brazing sheet and a plate-like fin is joined vertically thereto, the molten brazing material flows on the brazing sheet to form a fillet. .
In such a brazing technique based on line contact, brazing is generally performed using a flux in the air or in an inert gas atmosphere in order to suppress oxidation during brazing heating. ing. However, in recent years, a brazing sheet in which three or five clad layers are formed and an Al—Si alloy brazing material is clad as an intermediate material between a thin skin material and a core material is brazed in an inert gas with no flux. A method has been developed.
For example, in Japanese Patent No. 3780380, an Al—Si alloy brazing material is used as an intermediate material between a thin skin material and a core material, and the thin skin material and the core material have a solidus temperature higher than the liquidus temperature of the brazing material. An aluminum alloy is used, the thickness of the entire brazing sheet is 0.05 to 2.0 mm, and the clad rate of the thin skin material is set to 0.1 to 10%. This thin skin material is a brazing material melted by heating. There has been proposed an aluminum alloy brazing sheet that is brazed without flux in an inert gas atmosphere that is a thin skin material that melts in contact therewith.
By the way, in recent years, a demand for a heat exchange system that cools heat generated by an in-vehicle IGBT or the like by surface contact is increasing, and a technique for brazing the surfaces of aluminum plate materials with a brazing material is required.
In this surface brazing technique, a brazing material is inserted between the surfaces of the aluminum plate material and brazing heating is performed, so that void defects or the like are likely to occur at the joint, and the use of flux makes it easy to contain the flux. ing. Therefore, it is a very difficult technique compared to the brazing technique based on the fillet formation.
Regarding the technology for performing this surface brazing without flux in the atmosphere, for example, according to Japanese Patent No. 3701847, in the aluminum brazing performed by previously inserting an aluminum thin laminated plate material into the overlapping interface of a plurality of aluminum base materials, The aluminum thin laminated plate material is made of a thin laminated plate material having a three-layer structure, the core material is made of a brazing material having a melting point of 600 ° C. or less, both skin materials are made of an aluminum alloy having a melting point higher than that of the core material, and In addition, 0.1 to 6% (mass%, the same shall apply hereinafter) of Mg or 0.01 to 1% of Bi is further added to one or more of the core materials, and the entire overlapped member is pressed and adhered. In this state, the aluminum alloy is heated to a temperature not lower than the liquidus temperature of the brazing material and not exceeding the minimum value of the solidus temperature of each member other than the brazing material. Atmospheric flux-free superimposed brazing method has been developed of.
Japanese Patent No. 4547032 discloses an Al—Si brazing material containing, by mass, 0.1 to 5.0% Mg and 3 to 13% Si, with the balance being Al and inevitable impurities. An aluminum clad material that is clad by a material and located on the outermost surface is heated by bringing the Al-Si brazing material and a member to be brazed into close contact with each other in a non-oxidizing atmosphere without pressure reduction, and heating the core material And a method for joining the brazing target member.

However, because the brazing sheet used is a three-layer or five-layer clad material, although it can be laminated and brazed without flux in the atmosphere by the techniques proposed in the above-mentioned Patent Nos. 3780380 and 3701847. Cost will increase.
Further, in the technique proposed in Japanese Patent No. 4547032, the contact state between the brazing material and the member to be brazed is merely ambiguously defined as “contact adhesion”, so that a stable brazed state is obtained. It was difficult.
Therefore, it is desired to develop a surface brazing technique that is low in cost and stable in quality as compared with the prior art.
The present invention has been devised to solve such a problem, and an object thereof is to provide a technique for brazing two aluminum alloy members to each other with a single layer brazing sheet without flux. It is.
It is another object of the present invention to provide a technique for brazing one aluminum alloy member and a skin material constituting the two-layer brazing sheet with a two-layer brazing sheet.
In order to achieve the object, the surface brazing method for an aluminum alloy member of the present invention includes Si: 3 to 12% by mass, Mg: 0.1 to 5.0% by mass, with the balance being Al and inevitable impurities. The aluminum alloy members are brazed to each other using a single layer brazing sheet made of a brazing material with a thickness of 15 to 200 μm, and the brazing sheet has a solidus temperature of 570 ° C. The surface pressure of 0.6 gf / mm ² or more is applied while maintaining the brazing temperature at 570 ° C. or higher in an inert gas atmosphere in a state of sandwiching the surfaces between the aluminum alloy members as described above. However, it is characterized by brazing aluminum alloy members without flux.
Further, it contains Si: 3 to 12% by mass, Mg: 0.1 to 5.0% by mass, and the balance is composed of Al and inevitable impurities, and the brazing material and solid phase have a thickness of 15 to 200 μm. A method of brazing an aluminum alloy member and the skin material using a two-layer brazing sheet comprising a skin material made of an aluminum alloy plate having a linear temperature of 570 ° C. or higher, the two-layer brazing sheet 0.6 gf / mm ² while maintaining the brazing temperature at 570 ° C. or higher in an inert gas atmosphere in a state where the brazing filler metal surface is in surface contact with an aluminum alloy member having a solidus temperature of 570 ° C. or higher. The aluminum alloy member and the skin material may be brazed without flux while applying the above surface pressure.
Cu, Mn, and Zn as unavoidable impurities contained in the brazing material are each preferably less than 1.0% by mass.
The brazing material is preferably 15 to 150 μm thick, more preferably 20 to 100 μm thick.
Further, the aluminum alloy member to be surface brazed is AA1000 type, and the oxide film formed on the brazed surface preferably has a thickness of 30 nm or less.
Furthermore, the solidus temperature of the aluminum alloy member or the aluminum alloy member and the skin material is preferably 580 ° C. or higher, and the brazing temperature is 580 ° C. or higher.
The holding time at the brazing temperature during surface brazing is preferably 2 minutes or more, particularly 5 minutes or more.
Furthermore, it is preferable that the inert gas at the time of surface brazing is nitrogen gas, and the oxygen concentration of the inert gas is 500 ppm or less.
According to the surface brazing method of an aluminum alloy member provided by the present invention, a single layer brazing sheet or a two-layer brazing sheet allows two aluminum alloy members to be flux-free and a surface pressure between the two aluminum alloy members. And brazing the surface.
Since a brazing sheet made of a three-layer or five-layer clad material is not used but a single-layer or two-layer brazing sheet is used, the overall cost can be reduced. Moreover, since the surface pressure is applied between the two aluminum alloy members without using the flux and brazing is performed, void defects or the like that are likely to occur between the two aluminum alloy members can be suppressed. Stable surface brazing can be performed.

FIG. 1 is a diagram for explaining the shape of an inverted T-shaped test piece.
FIG. 2 is a conceptual diagram illustrating a small brazing test furnace.
FIG. 3 is a conceptual diagram illustrating a shear test method.
FIG. 4 is a diagram showing the influence of brazing temperature and holding time.
FIG. 5 is a diagram showing the influence of the amount of Mg added in the brazing material.
FIG. 6 is a diagram showing the influence of the amount of Si added in the brazing material.
FIG. 7 is a diagram showing the influence of the impurity content in the brazing material.
FIG. 8 is a diagram showing the influence of the thickness of the brazing material.
FIG. 9 is a diagram illustrating the influence of the applied pressure during brazing.
FIG. 10 is a diagram showing the influence of the oxide film thickness on the surface of the Al alloy material to be brazed.
FIG. 11 is a diagram showing the influence of the oxygen concentration in the brazing atmosphere.

Normally, when brazing, the brazing material is inserted between the surfaces of the aluminum alloy members to be joined and brazing heating is performed, so void defects are likely to occur at the joint, and flux is contained when using flux. It becomes an easy structure. For this reason, the quality of brazed products tends to vary. Moreover, in the conventional surface brazing method, since the clad material of 3 layers or 5 layers is used as a brazing sheet, it is expensive.
Therefore, the inventors of the present invention have reached the present invention in the process of earnestly studying a surface brazing method that is lower in cost and stable in quality than the prior art.
Details will be described below.
First, in the first invention, a brazing sheet is sandwiched between two aluminum alloy members and the brazing sheet is sufficiently dissolved in a state where the brazing sheet is in contact with the brazing material. It is a method of wet brazing and brazing.
Of the two aluminum alloy members, one aluminum alloy member may be an aluminum alloy plate, or both may be aluminum alloy plates. For example, an engaging portion may be provided so that parts made of aluminum alloy can be connected to each other, and a portion where the brazing sheet is sandwiched may be provided in the engaging portion. In short, in the first invention of the present application, the material to be joined is not limited to the aluminum alloy plate, and may be anything made of an aluminum alloy having a smooth surface that can be brazed at least partially.
According to a second aspect of the present invention, the brazing filler metal is sufficiently dissolved in a state in which the brazing filler metal surface of the two-layer brazing sheet made of the brazing filler metal and the skin material is in surface contact with the aluminum alloy member. In this method, the surface of the skin material constituting the brazing sheet is wetted with a brazing material and brazed.
The aluminum alloy member may be an aluminum alloy plate. In the second invention, the material to be joined is not limited to the aluminum alloy plate, and may be anything made of an aluminum alloy having a smooth surface that can be brazed at least partially.
The aluminum alloy member to which the surface brazing method of the present invention is applied is made of an aluminum alloy having a solidus temperature of 570 ° C. or higher.
When using an Al—Si brazing material described in detail later, a brazing temperature of 570 ° C. or higher is required to sufficiently dissolve the brazing material, and as an aluminum alloy member to be joined, It is necessary to apply to those whose solidus temperature is 570 ° C. or higher. If the solidus temperature of the aluminum alloy member to be joined is less than 570 ° C., at least a part of the aluminum alloy member may be melted during surface brazing heating. A more preferable solidus temperature of the aluminum alloy member is 575 ° C. or higher. A more preferable solidus temperature of the aluminum alloy member is 580 ° C. or higher.
Further, when a skin material is used in the second invention, it is necessary to use a skin material made of an aluminum alloy having a solidus temperature of 570 ° C. or higher.
In a state where the brazing filler metal surface of the two-layer brazing sheet composed of the brazing filler metal and the skin material is in surface contact with the aluminum alloy member, the brazing filler metal is sufficiently dissolved so that the interface between the aluminum alloy member and the skin material is brazed. Therefore, a brazing temperature of 570 ° C. or higher is required to sufficiently dissolve the brazing material. In order to suppress the dissolution of the skin material at this brazing temperature, the solidus temperature of the skin material constituting the two-layer brazing sheet needs to be 570 ° C. or higher. If the solidus temperature of the skin material is less than 570 ° C., part of the skin material may be dissolved by surface brazing heating. A more preferable solidus temperature of the skin material is 575 ° C. or higher. A more preferable solidus temperature of the skin material is 580 ° C. or higher.
The first feature of the present invention is that the brazing sheet is composed of a single layer of brazing material having a predetermined thickness and composition, or has two layers of brazing material and skin material in order to reduce costs. Is in the point of using.
First, the brazing material will be described.
As a brazing material, Si: 3 to 12% by mass, Mg: 0.1 to 5.0% by mass, the balance is an alloy having a component composition composed of Al and inevitable impurities, and has a thickness of 15 to 200 μm An aluminum alloy thin plate is used.
Si: 3 to 12% by mass
Si is an element for lowering the temperature of the liquidus line of the brazing sheet depending on its content and improving wettability during surface brazing. When the Si content is less than 3% by mass, the temperature of the liquidus line of the brazing sheet becomes too high, and even if the brazing sheet reaches a predetermined brazing temperature, the brazing sheet is not sufficiently dissolved, and sufficient brazing is performed. Strength (shear stress) may not be obtained. If the Si content exceeds 12% by mass, there is a high possibility that primary Si precipitates (crystallizes) in the center of the ingot during casting, and even if a healthy hot-rolled sheet is obtained, it is microscopic. It becomes difficult to obtain a brazing sheet having a homogeneous structure.
Therefore, the Si content in the brazing filler metal is in the range of 3 to 12% by mass. A more preferable Si content is in the range of 4 to 12% by mass. A more preferable Si content is in the range of 5 to 12% by mass.
Mg: 0.1 to 5.0% by mass
Since Mg acts as a reducing agent when oxidized itself, Mg suppresses oxidation of aluminum at the interface between the aluminum alloy plate and the brazing material of the brazing sheet due to brazing heating, and improves wettability during surface brazing. It is considered to be an element for improvement. If the Mg content is less than 0.1% by mass, depending on the brazing temperature and holding time, the effect is insufficient and sufficient brazing strength (shear stress) may not be obtained. . When the Mg content exceeds 5.0% by mass, the load on the roll when hot rolling the ingot is increased, and ear cracks also occur, so that hot rolling becomes difficult.
Therefore, the Mg content in the brazing filler metal is in the range of 0.1 to 5.0% by mass. A more preferable Mg content is in the range of 0.2 to 4.0% by mass. A more preferable Mg content is in the range of 0.3 to 3.0% by mass.
Remainder: Al and inevitable impurities Examples of inevitable impurities include Fe, Cu, Mn, Zn, etc. These elements include Fe: less than 1.0 mass%, Cu: less than 1.0 mass%, Mn: If it is the range of less than 1.0 mass% and Zn: less than 1.0 mass%, the effect of this invention is not prevented. Therefore, the content of the components as inevitable impurities is preferably less than 1.0% by mass.
As other impurity elements, Cr, Ni, Zr, Ti, V, B, Sr, Sb, Ca, Na, and the like can be considered, but Cr: less than 0.5 mass%, Ni: less than 0.5 mass% Zr: less than 0.2% by mass; Ti: less than 0.2% by mass; V: less than 0.1% by mass; B: less than 0.05% by mass; Sr: less than 0.05% by mass; If it is in the range of less than 05% by mass, Ca: less than 0.05% by mass, and Na: less than 0.01% by mass, the performance characteristics of the brazing sheet according to the present invention will not be significantly impaired. May be included. About Pb, Bi, Sn, and In, each is less than 0.02 mass%, and each other is less than 0.02 mass%, and even if it contains an element outside the control in this range, the effect of the present invention is not hindered. .
The thickness of the brazing material constituting the brazing sheet; 15 to 200 μm
The thickness of the brazing material constituting the single-layer brazing sheet according to the first invention may be any thickness that can achieve sound surface brazing. If the thickness is less than 15 μm, sufficient brazing strength may not be obtained. When the thickness exceeds 200 μm, the amount of the brazing material that oozes out from the joint surface becomes too large, resulting in an increase in cost. Accordingly, the thickness range of the brazing material is 15 to 200 μm. A more preferable thickness range is 15 to 150 μm. A more preferable thickness range is 20 to 100 μm.
Manufacturing method of single layer type brazing sheet made of brazing material For example, a single layer type brazing sheet made of 100 μm thick brazing material is manufactured as follows.
Ingots, scraps, and the like as raw materials are blended and put into a melting furnace to melt a molten aluminum having a predetermined brazing material composition. The melting furnace is generally a burner furnace in which the raw material is heated and melted directly by a burner flame. After the molten aluminum reaches a predetermined temperature, for example, 800 ° C., an appropriate amount of the flux for removing the debris is added, and the molten metal is stirred with a stirring rod to dissolve all raw materials. Thereafter, for adjusting the components, an additional raw material, such as Mg, is added, and after calming for about 30 to 60 minutes, the metal soot floating on the surface is removed. After the molten aluminum is cooled to a predetermined temperature, for example, 740 ° C., the molten aluminum is poured out from the hot water outlet into a bowl, and if necessary, casting is started through an inline rotary degasser, a CFF filter, and the like. In the case where a melting furnace and a holding furnace are provided side by side, after the molten metal melted in the melting furnace is transferred to the holding furnace, casting is started after further sedation or the like in the holding furnace.
The jacket of the DC casting machine may be a single pour, but may be a multi-pour that places importance on production efficiency. For example, while pouring through a dip tube and float into a water-cooled mold of 700 mm × 450 mm size, the lower mold is lowered at a casting speed of 60 mm / min, and direct water cooling (Direct) is performed on the solidified shell layer at the bottom of the water-cooled mold. While performing (Chill), the molten metal in the sump is solidified and cooled to obtain a slab having a predetermined size, for example, 700 mm × 450 mm × 4500 mm. After the end of casting, the front and rear ends of the slab are cut and double-sided with 25mm on one side. The 400mm-thick slab is inserted into a soaking furnace and homogenized at 450-540 ° C for 1-12 hours ( HO treatment). After the homogenization treatment, the slab is taken out from the soaking furnace, subjected to several passes of hot rolling by a hot rolling mill, and, for example, cut in a state of 40 mm thickness to obtain a 40 mm thick hot rolled plate ( Flat plate) One sheet of 700 mm × 40 mm × 4000 mm is secured. Thereafter, most of the remaining hot-rolled sheets are subsequently hot-rolled in several passes by a hot rolling mill to obtain, for example, a 6 mm-thick hot-rolled sheet coil (Reroll).
The 6 mm thick hot rolled plate coil is subjected to several passes of cold rolling to obtain a single layer brazing sheet made of a brazing material having a predetermined thickness, for example, 100 μm. In the cold rolling process, if the work hardening of the cold rolled sheet is significant, if necessary, the coil is inserted into an annealer and subjected to an intermediate annealing treatment at a holding temperature of 300 to 450 ° C. It is desirable to soften the plate.
The same applies to the thickness of the brazing material constituting the two-layer brazing sheet according to the second invention. 15 to 200 μm.
The skin material in the two-layer brazing sheet according to the second invention may be an aluminum alloy having a solidus temperature of 570 ° C. or higher, and the thickness thereof is not particularly limited.
However, although depending on the brazing heating temperature, if the skin material is too thin, the melted brazing material may ooze out of the skin material, and therefore the thickness of the skin material is preferably 100 μm or more. A more preferable thickness of the skin material is 150 μm or more. A more preferable thickness of the skin material is 200 μm or more. Thus, in the second invention, it is preferable that the thickness of the skin material is larger than the thickness of the brazing material. For example, when the brazing material type is AA4045 alloy and the thickness is 60 μm, a two-layer brazing sheet in which the skin material type is AA1100 alloy and the thickness is 500 μm may be used.
2. Method for producing a two-layer brazing sheet comprising a brazing material and a skin material For example, a two-layer brazing sheet comprising a brazing material having a thickness of 40 μm and a skin material having a thickness of 400 μm is produced as follows.
As described above, a slab of 700 mm × 450 mm × 4500 mm having a predetermined skin material composition is obtained by DC casting. After cutting the front and rear ends of the slab and carrying out double-side chamfering of 25 mm on one side, the slab after chamfering having a thickness of 400 mm made of the above-mentioned skin material composition and 40 mm made of the brazing material composition secured as described above. A thick hot-rolled plate (flat plate) 700 mm × 40 mm × 4000 mm (one sheet) is temporarily joined in a state of being bonded on a 700 mm × 4000 mm surface. This two-layer clad slab is inserted into a soaking furnace and subjected to a homogenization treatment (HO treatment) at 450 to 540 ° C. for 1 to 12 hours. After the homogenization treatment, the slab is taken out of the soaking furnace and subjected to several passes of hot rolling with a hot rolling mill to obtain, for example, a 6 mm thick hot rolled sheet coil (Reroll).
This hot-rolled plate coil is subjected to several passes of cold rolling to form a two-layer type comprising a brazing material (thickness 40 μm) and a skin material (thickness 400 μm) having a predetermined thickness, for example, 440 μm Obtain a brazing sheet. In the cold rolling process, if the work hardening of the cold rolled sheet is significant, if necessary, the coil is inserted into an annealer and subjected to an intermediate annealing treatment at a holding temperature of 300 to 450 ° C. It is desirable to soften the plate.
The second feature of the present invention is that a specific surface pressure is applied under an inert gas atmosphere in order to perform surface brazing without flux and to obtain a sufficient brazing strength (shear stress) at the joint surface. This is the point to braze.
In order to sufficiently braze the brazing sheet (brazing material) as described above under an inert gas atmosphere and wet the interface between the aluminum alloy members or the interface between the skin material and the aluminum alloy member, It is necessary to hold at a holding temperature of 570 ° C. or higher for a predetermined time.
For this reason, even during brazing heating, it is necessary to perform brazing in an inert gas atmosphere in order to suppress oxidation of the brazing surface of the aluminum alloy member or the brazing material surface of the brazing sheet. .
As the inert gas, nitrogen gas, argon gas, helium gas, or the like can be used. The oxygen concentration in the inert gas is preferably 500 ppm or less. If the oxygen concentration in the inert gas exceeds 500 ppm, the joint strength (shear stress) after surface brazing decreases.
A more preferable oxygen concentration in the inert gas is 100 ppm. A more preferable oxygen concentration in the inert gas is 10 ppm or less. Specifically, for the industrial nitrogen gas, since the standard is defined as an oxygen concentration of 10 ppm or less, it is most preferable to use the industrial nitrogen gas from the viewpoint of cost.
Of course, it is preferable to fill the inside of the heating apparatus with an inert gas atmosphere during brazing heating, brazing temperature holding and cooling. However, in the case of rapid heating such as electromagnetic induction heating, the inert gas may be injected to replace the atmosphere in the heating device with the inert gas before reaching a predetermined holding temperature.
Additional surface pressure: 0.6 gf / mm ² or more In the surface brazing method according to the present invention, a brazing sheet (brazing material) having a predetermined composition is dissolved and the brazing material and the aluminum alloy member are in surface contact. In this case, brazing heating is performed, and at this time, it is necessary to maintain a predetermined brazing temperature while applying a surface pressure of 0.6 gf / mm ² or more to the joint surface. Of course, it is possible to perform surface brazing by applying a surface pressure of 0.6 gf / mm ² or more to the joint surface after reaching a predetermined holding temperature without applying surface pressure during brazing heating. Good.
When the surface pressure is less than 0.6 gf / mm ² , sufficient brazing strength (shear stress) cannot be obtained. Of course, in order to sufficiently secure the brazing strength (shear stress) after the surface brazing, it is preferable that the surface pressure applied to the joint surface is high. Therefore, a more preferable surface pressure is 1.0 gf / mm ² or more. A more preferable surface pressure is 2.0 gf / mm ² or more.
Brazing temperature condition: maintained at 570 ° C. or higher In the surface brazing method according to the present invention, a brazing sheet (brazing material) having a predetermined composition is dissolved, and the interface between the aluminum alloy members or the skin material and the aluminum alloy member It is necessary that the brazing temperature be at least 570 ° C. or higher in order to wet the interface of the surface and reliably braze the surface to ensure sufficient brazing strength (shear strength).
When the brazing temperature is less than 570 ° C., the brazing material is not sufficiently dissolved, and sufficient brazing strength (shear strength) cannot be obtained. Of course, the higher the holding temperature, the more sufficient brazing strength (shear strength) can be obtained. Accordingly, the holding temperature is 575 ° C. or higher. A more preferable holding temperature is 580 ° C. or higher.
Brazing holding time The holding time at the brazing temperature is preferably 2 minutes or more. Although depending on the brazing temperature, if the holding time is less than 2 minutes, sufficient brazing strength (shear strength) cannot be obtained due to uneven temperature at the joint surface. A more preferable holding time is 5 minutes or more.

Preparation of brazing sheet Various predetermined ingots were weighed and blended, and 9 kg (total 13 samples) of raw materials were charged into a # 30 crucible coated with a release material. These crucibles were inserted into an electric furnace and melted at 760 ° C. to remove the soot, and then the molten metal temperature was kept at 740 ° C. Next, degassing treatment was performed by blowing nitrogen gas into the molten metal at a flow rate of 1 Nl / min for 10 minutes with a small rotary degassing apparatus. Thereafter, the sedation was performed for 30 minutes, and the cocoon floating on the surface of the molten metal was removed with a stirring rod, and a disk sample was collected with a spoon as a mold for component analysis.
Next, the crucible was sequentially taken out from the electric furnace using a jig, and molten aluminum was cast into five molds (70 mm × 70 mm × 15 mm) preheated to 200 ° C. The disk sample of each sample was subjected to composition analysis by emission spectroscopic analysis. The results are shown in Table 1.

The ingot was chamfered by 3 mm after cutting the hot water to a thickness of 9 mm. The ingot is charged into an electric heating furnace, heated to 480 ° C. at a heating rate of 100 ° C./hr, homogenized at 480 ° C. for 1 hour, and then 3 mm thick by a hot rolling mill. Hot rolling was applied.
Thereafter, the hot-rolled plate was cold-rolled to obtain a cold-rolled plate having a thickness of 1.2 mm, and subjected to primary intermediate annealing at 390 ° C. for 2 hours in order to soften. Further, it was cold-rolled to form a cold rolled sheet having a thickness of 0.3 mm, and subjected to secondary intermediate annealing at 390 ° C. × 2 hours for softening. Further, cold rolling was performed to obtain a final cold rolled plate of 0.06 mm (60 μm). In order to investigate the influence of the brazing material thickness on the brazing strength (shear stress), for the D alloy brazing material, final rolled sheets of five levels having thicknesses of 15 μm, 20 μm, 30 μm, 60 μm and 100 μm were prepared.
This final cold rolled sheet was cut into a predetermined size (15 mm × 8 mm) to obtain a plurality of brazing sheets (brazing materials).
Production of inverted T-shaped test piece As shown in FIG. 1, a brazing sheet (15 mm × 8 mm) is placed on the center of a 35 mm × 35 mm surface of block A (35 mm × 35 mm × 10 mm) made of AA1100 alloy, and made of AA1100 alloy. The block B was erected at the center on the 35 mm × 35 mm surface of the block A so that the 15 mm × 8 mm surface of the block B (18 mm × 15 mm × 8 mm) of the block A was overlaid on the brazing sheet.
Further, a weight of a predetermined mass for pressurization was placed on the upper surface of the block B, and the assembled block or the like was inserted into a test furnace covered with a quartz tube (φ125 × 330 mm) as shown in FIG. PID control until the thermocouple attached to block A shows a predetermined brazing temperature while flowing industrial nitrogen gas (nitrogen with an oxygen concentration of 10 ppm or less) at a flow rate of 10 Nl / min to replace the atmosphere with inert gas After heating at a rate of 50 ° C./min and holding at a predetermined brazing temperature for a predetermined time, the output to the resistance wire was turned off and the assembled block or the like was cooled in the furnace. After the thermocouple attached to block A showed 400 ° C. or lower, the assembled block and the like were taken out of the furnace and cooled to room temperature.
In addition, in order to investigate the influence of the oxygen concentration on the brazing strength (shear stress) by the brazing atmosphere, for the D alloy brazing material (brazing material thickness: 60 μm), industrial nitrogen (nitrogen having an oxygen concentration of 10 ppm or less) is used. In addition, an inverted T-shaped test piece in the same manner under the conditions of brazing temperature of 605 ° C. and holding time of 10 minutes in the air with or without flowing nitrogen of oxygen concentration of 500 ppm, 2000 ppm of oxygen. Was made.
Furthermore, in order to investigate the influence of the oxide film thickness on the brazing surface of the material to be joined on the brazing strength (shear stress), the block A is preliminarily subjected to heat treatment at 600 ° C. for 1 hour and 600 ° C. for 5 hours in the air. And after preparing a material to be bonded (block A) with a thick oxide film thickness, using a D alloy brazing material (brazing material thickness: 60 μm), while flowing industrial nitrogen (nitrogen having an oxygen concentration of 10 ppm or less), Brazing was performed under predetermined conditions, and an inverted T-shaped test piece was produced in the same manner.
In addition, the measurement of the oxide film thickness on the surface of the material to be bonded before brazing is performed by TEM observation on the cross section of the material to be bonded. It was found that the oxide film thickness was 30 nm for the bonded material subjected to the heat treatment for 1 hour and the oxide film thickness was 90 nm for the bonded material subjected to the heat treatment at 600 ° C. for 5 hours.
Measurement of Shear Stress The inverted T-shaped test piece prepared as described above is fixed to a jig as shown in FIG. 3 and pressed from the end face (35 mm × 10 mm face) of the block A with an Amsler (strain rate: 1 mm). / Min), brazing strength (breaking shear stress) on the brazed surface was measured.
The results are shown in Tables 2 to 9 and FIGS.
In addition, in the explanation of the above-mentioned examples, for those that do not have a particularly detailed indication, a D alloy brazing material (brazing material thickness: 60 μm) and a to-be-joined material (untreated material) are used, and industrial nitrogen ( A reverse T-shaped test piece was prepared by brazing under a condition of brazing temperature 605 ° C., holding time 10 minutes, and applied pressure 5.6 gf / mm ² while flowing nitrogen (oxygen concentration of 10 ppm or less). It is.

First, the results shown in Table 2 indicate that the brazing temperature is preferably 580 ° C. or higher. It can also be seen that the brazing temperature holding time is preferably 2 minutes or longer, particularly 5 minutes or longer.
Next, regarding the influence of the components in the aluminum alloy constituting the brazing material, it is sufficient to contain 0.1% by mass of Mg in order to obtain a desired shear stress when brazing at 605 ° C. However, if 0.5% by mass is not contained, a desired shear stress cannot be obtained when brazing at 580 ° C. In addition, in a sample having an Mg content exceeding 3.0% by mass, the shear stress is reduced when brazing at 605 ° C. is performed. Therefore, it can be seen that the preferable content of Mg is 0.5 to 3.0% by mass.
As for the Si content, sufficient shear stress is obtained for all the samples included in the range of 3.0 to 12.0% by mass, but some shear is obtained when the Si content is 3.0% by mass. The stress is low. Therefore, it can be seen that the preferable content of Si is 5.0 to 12.0% by mass.
About Cu, Mn, and Zn which are unavoidable impurities, if it contains less than 1.0 mass%, it turns out that shear stress is hardly influenced.
With regard to the thickness of the brazing material, if the thickness is 15 μm or more, sufficient shear stress is obtained for the time being, but when the thickness is 15 μm, the obtained shear stress is slightly low. Therefore, the thickness of the brazing material is preferably 20 μm or more. If it is too thick, the brazing filler metal becomes excessive, so that the upper limit is 200 μm as described above.
As for the applied pressure at the time of brazing, if brazing is performed while applying a surface pressure of 0.6 gf / mm ² or more, a sufficient shear stress is obtained for the time being. However, it can be seen that it is preferable to apply a surface pressure of 1.0 gf / mm ² or more in order to increase the shear stress.
When the oxide film formed on the surface of the aluminum alloy member to be brazed exceeds 30 nm, the resulting shear stress is rapidly reduced. Therefore, the aluminum alloy member to be brazed should have an oxide film formed on the surface of less than 30 nm.
Further, when looking at the atmosphere during brazing, it can be seen that the atmosphere should be at least inert such as nitrogen. In particular, it can be seen that an inert gas atmosphere having an oxygen content of 500 ppm or less is preferable.

Claims

Single layer brazing made of brazing material having a composition of Si: 3 to 12% by mass, Mg: 0.1 to 5.0% by mass, the balance being Al and inevitable impurities, and a thickness of 15 to 200 μm A method in which aluminum alloy members are brazed to each other using a sheet, wherein the brazing sheet is sandwiched between aluminum alloy members having a solidus temperature of 570 ° C. or higher, and inactive in a state where they are in contact with each other. An aluminum alloy member characterized by brazing aluminum alloy members without flux while applying a surface pressure of 0.6 gf / mm 2 or more while maintaining a brazing temperature of 570 ° C. or higher in a gas atmosphere. Surface brazing method.
Si: 3 to 12% by mass, Mg: 0.1 to 5.0% by mass, the balance being a component composition consisting of Al and inevitable impurities, a brazing material having a thickness of 15 to 200 μm and a solidus temperature A method for brazing an aluminum alloy member and the skin material using a two-layer brazing sheet composed of a skin material made of an aluminum alloy having a temperature of 570 ° C. or higher, the brazing material of the two-layer brazing sheet A surface having a surface temperature of 0.6 gf / mm 2 or more while maintaining a brazing temperature of 570 ° C. or more in an inert gas atmosphere in a state where the surface is in surface contact with an aluminum alloy member having a solidus temperature of 570 ° C. or more. A surface brazing method for an aluminum alloy member, characterized by brazing the aluminum alloy member and the skin material without flux while applying pressure.
The method for brazing aluminum alloy members according to claim 1 or 2, wherein Cu as an inevitable impurity contained in the brazing material is limited to less than 1.0 mass%.
4. The method of brazing an aluminum alloy member according to claim 1, wherein Mn as an inevitable impurity contained in the brazing material is limited to less than 1.0 mass%.
The method for brazing an aluminum alloy member according to any one of claims 1 to 4, wherein Zn as an inevitable impurity contained in the brazing material is limited to less than 1.0 mass%.
The method for brazing an aluminum alloy member according to any one of claims 1 to 5, wherein the brazing material constituting the brazing sheet has a thickness of 15 to 150 µm.
The method for brazing an aluminum alloy member according to any one of claims 1 to 6, wherein the aluminum alloy member is formed with an oxide film having a thickness of 30 nm or less on a brazing surface thereof. .
The method for brazing an aluminum alloy member according to any one of claims 1 to 7, wherein a holding time at the brazing temperature is 2 minutes or more.
The method for brazing an aluminum alloy member according to any one of claims 1 to 8, wherein the holding time at the brazing temperature is 5 minutes or more.
The method for brazing an aluminum alloy member according to any one of claims 1 to 9, wherein the inert gas is nitrogen gas.
The method for brazing an aluminum alloy member according to any one of claims 1 to 10, wherein an oxygen concentration of the inert gas is 500 ppm or less.