WO2012039752A2 - Production de gaz naturel mélangé renouvelable et de laine de roche au moyen d'un système à base de plasma - Google Patents

Production de gaz naturel mélangé renouvelable et de laine de roche au moyen d'un système à base de plasma Download PDF

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Publication number
WO2012039752A2
WO2012039752A2 PCT/US2011/001614 US2011001614W WO2012039752A2 WO 2012039752 A2 WO2012039752 A2 WO 2012039752A2 US 2011001614 W US2011001614 W US 2011001614W WO 2012039752 A2 WO2012039752 A2 WO 2012039752A2
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WO
WIPO (PCT)
Prior art keywords
gassifier
fuel
syngas
plasma
delivering
Prior art date
Application number
PCT/US2011/001614
Other languages
English (en)
Other versions
WO2012039752A3 (fr
Inventor
James Charles Juranitch
Thomas Robert Juranitch
Richard Tarrant
Original Assignee
James Charles Juranitch
Thomas Robert Juranitch
Richard Tarrant
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by James Charles Juranitch, Thomas Robert Juranitch, Richard Tarrant filed Critical James Charles Juranitch
Priority to EP11827083.4A priority Critical patent/EP2619289A4/fr
Priority to CA2813066A priority patent/CA2813066C/fr
Priority to US13/825,122 priority patent/US20130326952A1/en
Publication of WO2012039752A2 publication Critical patent/WO2012039752A2/fr
Priority to US13/715,915 priority patent/US20140196370A1/en
Publication of WO2012039752A3 publication Critical patent/WO2012039752A3/fr

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
    • C10K3/06—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by mixing with gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/20—Agglomeration, binding or encapsulation of solid waste
    • B09B3/25—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix
    • B09B3/29—Agglomeration, binding or encapsulation of solid waste using mineral binders or matrix involving a melting or softening step
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03B—MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/02—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating
    • C03B5/025—Melting in furnaces; Furnaces so far as specially adapted for glass manufacture in electric furnaces, e.g. by dielectric heating by arc discharge or plasma heating
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/02—Fixed-bed gasification of lump fuel
    • C10J3/06—Continuous processes
    • C10J3/18—Continuous processes using electricity
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72—Other features
    • C10J3/723—Controlling or regulating the gasification process
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
    • C10K1/00—Purifying combustible gases containing carbon monoxide
    • C10K1/04—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials
    • C10K1/06—Purifying combustible gases containing carbon monoxide by cooling to condense non-gaseous materials combined with spraying with water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/003—Additives for gaseous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00—Details of gasification apparatus
    • C10J2200/12—Electrodes present in the gasifier
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0903—Feed preparation
    • C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913—Carbonaceous raw material
    • C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0953—Gasifying agents
    • C10J2300/0973—Water
    • C10J2300/0976—Water as steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0983—Additives
    • C10J2300/0996—Calcium-containing inorganic materials, e.g. lime
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/12—Heating the gasifier
    • C10J2300/123—Heating the gasifier by electromagnetic waves, e.g. microwaves
    • C10J2300/1238—Heating the gasifier by electromagnetic waves, e.g. microwaves by plasma
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1618—Modification of synthesis gas composition, e.g. to meet some criteria
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/1603—Integration of gasification processes with another plant or parts within the plant with gas treatment
    • C10J2300/1621—Compression of synthesis gas
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/20—Waste processing or separation

Definitions

  • This invention relates generally to processes and systems for generating a blended Natural Gas of a BTU content high enough to be reinjected into the gas main. This is also combined with the production of rock wool to develop a high efficiency renewable energy plant at a low capital cost when the feedstock is renewable such as Municipal Solid Waste (MSW). This design of plant is becoming more desirable as high tipping fees and high transportation costs demand small, distributed, cost effective, MSW / renewable energy facilities.
  • MSW Municipal Solid Waste
  • Thermal plasma has consistently distinguished itself as a high efficiency, low emissions gasification process for just about any feedstock, and has been identified as one of the most desirable processes for use in producing energy from renewable fuels.
  • Plasma technology is not inexpensive when compared to disposition of waste using landfill, incineration, or conventional gasification.
  • the process and system of the present invention overcomes the economic hurdles noted above for a plasma system. It is to be understood, however, that the invention herein described is not limited to the use of a plasma gassifier. In some embodiments of the invention, conventional gassifiers, inductively heated gassifiers, or inductively heated gassifiers with plasma assist, can be employed. The use of a plasma gassifier in the practice of the present invention simply increases overall system effectiveness.
  • the system of the present invention is simple, flexible, and very energy efficient. In short, it produces a large amount of renewable energy from a feedstock such as Municipal Solid Waste ("MSW”), for a very small capital investment. Any feedstock can be used, including, for example, biomass or algae. SW is but a common example of a renewable feedstock.
  • MSW Municipal Solid Waste
  • this invention provides a method of extracting energy from a gassifier and delivering the energy to an energy transfer medium, the method including the steps of:
  • the gassifier is a plasma gassifier.
  • the further step of re-injecting the gas product into a gas main supply there is provided the further step of delivering the gas product to a pre-gassifier to increase system efficiency.
  • Reclaimed heat is, in some embodiments, delivered heat to the pre-gassifier.
  • the gaseous fuel includes any combination of natural gas, butane, propane, pentane, ethane, and any other suitable gaseous fuel.
  • the step of controlling the thermal content of the blended fuel includes, in some embodiments, the further step of employing a sensor in a feedback loop.
  • the sensor can be any of a flame ionization detector, a calorimeter, or a
  • the step of producing rock wool there is further provided the step of producing rock wool.
  • the further step of producing accessory heat Prior to performing the step of extracting syngas from a gas product issued by the plasma gassifier there are provided, in some embodiments, the further steps of:
  • the invention provides a method of producing blended natural gas to be used on-site, or re-injected into the main, or any other gaseous fuel, rock wool production, and accessory heat production all at a low capital cost.
  • This process is due in part to modern syngas production methods. Syngas production has taken a large step forward in quality when it is produced using a pyrolysis method combined with plasma generated heat. This process has proven itself to be far superior to conventional gassifiers.
  • the thermal (BTU) content of the product syngas can consistently be held to about 300 BTU/Cu ft. This relatively low quality fuel is a step forward for renewable feedstock gasification but falls far short of the requirements of modern boilers, internal combustion engines, and turbines.
  • a key attribute of the plasma based gasification system is the ability to control the process and generate relatively consistent thermal (BTU) content in the resultant gas. This allows the blending of the syngas with other fuels such as natural gas to produce a fuel of consistently high quality.
  • FIG. 1 is a simplified schematic representation of a process and system for generating blended natural gas from a renewable energy source constructed in accordance with the principles of the invention.
  • Fig. 1 is a simplified schematic representation of a process and system 100 for generating blended natural gas from an energy source constructed in accordance with the principles of the invention.
  • Municipal solid waste or other feedstock designated as MSW 1
  • the feedstock can be any organic material, or an inorganic mix.
  • Crane 2 transfers MSW 1 to a shredder 3.
  • the shredded feedstock (not shown) is then delivered to a pre-gassifier chamber 4.
  • pre- gassifier 4 helps to reduce the work of plasma torch 21, which is the primary heat source of plasma chamber 9.
  • the feed system which includes shredder 3, compresses the incoming feedstock MSW 1 so as to minimize the introduction of air.
  • Plasma chamber 9, or other conventional gassifier is, in this specific illustrative embodiment of the invention, advantageously operated in a pyrolysis mode, or in air and/or oxygen combustion boosted modes of operation.
  • Additives such as lime 5 are added, in this embodiment, to the gassifier to control emissions and improve the quality of an output slag 24.
  • Methods of chemically boosted heat such as the use of liquid or gaseous fuels and an oxidant injected into port 6 can be used in the practice of the invention. Additionally, any of several fuels such as propane, recirculated syngas, ethane, butane, pentane, etc. can be used in the practice of the invention to supplement the heat input of plasma torch 21.
  • fuels such as propane, recirculated syngas, ethane, butane, pentane, etc. can be used in the practice of the invention to supplement the heat input of plasma torch 21.
  • the quality of the syngas is improved in this embodiment, by the injection of steam 25 into plasma chamber 9.
  • a syngas product is supplied via a syngas line 10 to a quench system 23 to reduce particulate and other emissions and to reduce the temperature of the syngas to a level that is acceptable to a final syngas purification system 13.
  • a quench system 23 to reduce particulate and other emissions and to reduce the temperature of the syngas to a level that is acceptable to a final syngas purification system 13.
  • sour water cleanup systems for the quench system have been omitted from the drawing for the sake of clarity.
  • a final Heat recovery system 14 is generates heat that is used in this embodiment to operate pre-gassifier 4. Alternatively, in other embodiments such heat is sold as accessory heat. Heat produced by quench system 11 can also be sold or delivered to the pre-gassifier. A cooling tower for the facility has been omitted from this figure for the sake of clarity.
  • Compressor 15 draws a slight vacuum on system 100 and directs the syngas to a three way valve 26 and a calorimeter 16.
  • other fuel quality measuring devices such as a flame ionization detector (FID)
  • FID flame ionization detector
  • the syngas in line 17 is directed to a blending valve 27 that mixes natural gas 18, or any other fuel such as ethane, propane, butane, pentane etc.
  • Mixing valve 27 is employed in a closed loop control arrangement that maintains a quality of fuel appropriate for re-injection into a natural gas main 29.
  • a quality of fuel appropriate for re-injection into a natural gas main 29.
  • typically about 5% to 10% concentration of syngas is utilized in this embodiment. It should be understood this invention is not limited to 5% to 10% blend concentrations.
  • the product gas is pressurized by compressor 28 prior to being re-injected into gas main 29.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Materials Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Abstract

L'invention concerne un procédé et un système pour convertir de manière peu onéreuse une charge, en utilisant du plasma thermique ou d'autres types de gazéifieurs, en un support de transfert d'énergie, au moyen d'un combustible gazeux mélangé. Ladite charge peut se présenter sous la forme d'une matière organique quelconque ou d'une association inorganique pour générer un gaz de synthèse. Ce gaz de synthèse est mélangé à un combustible quelconque présentant une énergie thermique (exprimée en BTU) supérieure à celle du gaz de synthèse. Le combustible mélangé ainsi produit qui présente une énergie thermique supérieure est utilisé sur place ou réinjecté dans la ligne d'approvisionnement en combustible. De la laine de roche et de la chaleur supplémentaire sont générées pour accroître l'efficacité de l'installation.
PCT/US2011/001614 2010-09-22 2011-09-19 Production de gaz naturel mélangé renouvelable et de laine de roche au moyen d'un système à base de plasma WO2012039752A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP11827083.4A EP2619289A4 (fr) 2010-09-24 2011-09-19 Production de gaz naturel mélangé renouvelable et de laine de roche au moyen d'un système à base de plasma
CA2813066A CA2813066C (fr) 2010-09-24 2011-09-19 Production de gaz naturel melange renouvelable et de laine de roche au moyen d'un systeme a base de plasma
US13/825,122 US20130326952A1 (en) 2010-09-24 2011-09-19 Renewable Blended Natural Gas and Rock Wool Production from a Plasma-Based System
US13/715,915 US20140196370A1 (en) 2010-09-22 2012-12-14 Co-Fired Syngas System

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US40399110P 2010-09-24 2010-09-24
US61/403,991 2010-09-24

Related Child Applications (1)

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PCT/US2011/001611 Continuation-In-Part WO2012039749A1 (fr) 2010-09-22 2011-09-19 Gaz de synthèse mélangé renouvelable produit au moyen d'un système à base de plasma

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WO2012039752A3 WO2012039752A3 (fr) 2014-03-20

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US (1) US20130326952A1 (fr)
EP (1) EP2619289A4 (fr)
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US20160333571A1 (en) * 2014-01-16 2016-11-17 Axenic Power, Llc Hybrid, high-temperature insulation product, and related system and process

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Title
See also references of EP2619289A4

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WO2012039752A3 (fr) 2014-03-20
EP2619289A4 (fr) 2015-10-21
CA2813066C (fr) 2019-02-05
CA2813066A1 (fr) 2012-03-29
US20130326952A1 (en) 2013-12-12
EP2619289A2 (fr) 2013-07-31

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