WO2012039624A1 - System and method for control of side layer formation in an aluminium electrolysis cell - Google Patents
System and method for control of side layer formation in an aluminium electrolysis cell Download PDFInfo
- Publication number
- WO2012039624A1 WO2012039624A1 PCT/NO2011/000263 NO2011000263W WO2012039624A1 WO 2012039624 A1 WO2012039624 A1 WO 2012039624A1 NO 2011000263 W NO2011000263 W NO 2011000263W WO 2012039624 A1 WO2012039624 A1 WO 2012039624A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- heat
- sidelining
- tube
- control
- layer formation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/20—Automatic control or regulation of cells
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/12—Casings; Linings; Walls; Roofs incorporating cooling arrangements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D9/00—Cooling of furnaces or of charges therein
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the invention regards heat regulation in general and particularly method and system for use for control of layer formation in an aluminium electrolysis cell and exploitation of heat.
- the operations of the cells depend on the formation and maintenance of a protective layer of frozen electrolyte in the side walls of the cell.
- This 5 frozen bath is called side layer and protects the side lining of the cells against chemical and mechanical wear, and is an essential condition for achieving long lifetime of the cells.
- the crystallized bath operates simultaneously as a buffer for the cell with regards of changes in the heat balance.
- the heat generation and the heat balance of the cell will vary due to unwanted disturbances of the operation (changes in bath acidity, changes in alumina concentration, changes in interpolar distances, etc.) and desired activities on the cells (metal tapping, change of anode, fire, etc.).
- GB 2076428A describing an aluminium cell with isolating layers in bottom and walls.
- the walls In the walls there are carbon blocks with heat tubes moulded in for the removal of heat from the cell.
- the heat tubes can be adjusted with different distances in order to vary the degree of heat removal.
- the object of the invention is to provide a method and system for use for control of layer formation in an aluminium electrolysis cell and exploitation of the heat.
- a sidelining provided with heat tube for transport of heat is provided.
- the present invention relates to structural elements for forming a sidelining material for cooling of sidelining in aluminium electrolysis cells for the purpose of controlling and adjusting sidelining thickness in the cell.
- the sidelining materials it is also possible to provide heat exchange of such cells with possibility of regeneration of heat as electrical energy and/or heat.
- By the forming of sidelining materials in the present invention one should understand design, formation and production of hollows in the material for the purpose of mounting of heat tubes such as heat pipes to lead heat to the outside of the aluminium electrolysis bath.
- the evaporation end of the heat tube is mounted on the inside of the electrolysis bath and is in contact with the above mentioned sidelining material while on the heat tube condensation end a cooling element is mounted transferring the transported heat to a suited cooling medium such as for instance oil.
- the present invention achieves the objectives outlined above by a sidelining as described in claim 1 and a method as described in claim 4.
- the sidelining material is manufactured without requirements for inserting thin canals. Instead a plurality of heat tubes are utilized, attached to the sidelining.
- the technical effect of the difference is that one achieves efficient transfer of heat without having to sinter sidelinings with thin canals along with the problems that this incurs.
- heat tubes can be more efficient in transferring heat than use of cooling medium in the canals.
- a further technical effect is that the heat tubes will be more stably fastened to the longitudinal canals in the surface of the sidelining and that there will be a low thermal gradient along the canal compared to canals known from the state of the art.
- Figure 1 shows a typical embodiment of the invention in the form of a sidelining block with hollows and heat tube for an electrolysis cell
- Figure 2 shows a detail section of the embodiment of figure 1 together with section as seen from the side
- Figure 3 shows an example of providing heat tubes in the sidelining block
- Figure 4 shows another example of providing heat tubes in the sidelining block.
- sidelining block 1 1 together with the heat isolation 10, wherein the sidelining block is provided with heat tube 12.
- the sidelining block 1 1 is typically made from SiC 1 1a, l ib as in example a and b.
- figure 1 schematically shows a typical embodiment of the invention in the form of a sidelining block with hollows and heat tubes for an electrolysis cell.
- the sidelining block is manufactured from a ceramic material. It is manufactured in a particular way to achieve the intended hollows.
- Figure 1 shows one example of possible positioning of hollows.
- Figure 2 shows the detail section also from the side where the heat tubes are positioned standing along the canals in the surface of the sidelining block.
- Heat tubes are positioned against these hollows and an example of such a heat tube in the form of a heat pipe.
- a cooling element On the cold end of the heat tube, also known as the condensation side, a cooling element is mounted comprising a condensation unit for heat tube 13 and condensation fins 14.
- the invention achieves its solution by the assembly of plurality of principles.
- heat tube where the phase transition liquid to vapour in the hot end transports large amounts of heat to the cold end where the vapour condenses to liquid which then is returned to the hot end.
- heat tube there are two embodiments intended: “heat pipe” where a wick or other capillary effect pulls the liquid back to the hot end, and “thermosyphon” where the gravity pulls the liquid back to the hot end.
- An aluminium electrolysis cell will comprise several tens of such "heat pipe” heat exchangers in the sidewalls. The heat removed from the cells will be transported in a cooling medium. This heat can for instance be exploited to produce electrical energy. A plurality of electrolysis cells can also be connected together in order to regenerate the cooled effect in an efficient manner.
- the invention is applicable for control of layer formation in a aluminium electrolysis cell and exploitation of the heat.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Electrolytic Production Of Metals (AREA)
- Coating By Spraying Or Casting (AREA)
- Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EA201390309A EA201390309A1 (ru) | 2010-09-22 | 2011-09-20 | Система и способ регулирования образования слоя на боковых стенках электролизера для получения алюминия |
AU2011306524A AU2011306524A1 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminium electrolysis cell |
EP11827027.1A EP2619518A4 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminium electrolysis cell |
CN201180045617XA CN103210273A (zh) | 2010-09-22 | 2011-09-20 | 在铝电解槽中控制侧层形成的系统和方法 |
AP2013006815A AP2013006815A0 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminum electolysis cell |
CA2811873A CA2811873A1 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminium electrolysis cell |
US13/825,752 US20130199938A1 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminium electrolysis cell |
BR112013006526A BR112013006526A2 (pt) | 2010-09-22 | 2011-09-20 | sistema e método para controle de formação de camada lateral em uma célula eletrolítica de alumínio |
ZA2013/01798A ZA201301798B (en) | 2010-09-22 | 2013-03-08 | System and method for control of side layer formation in an aluminium electrolysis cell |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO20101321 | 2010-09-22 | ||
NO20101321 | 2010-09-22 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2012039624A1 true WO2012039624A1 (en) | 2012-03-29 |
Family
ID=45874019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/NO2011/000263 WO2012039624A1 (en) | 2010-09-22 | 2011-09-20 | System and method for control of side layer formation in an aluminium electrolysis cell |
Country Status (11)
Country | Link |
---|---|
US (1) | US20130199938A1 (pt) |
EP (1) | EP2619518A4 (pt) |
CN (1) | CN103210273A (pt) |
AP (1) | AP2013006815A0 (pt) |
AR (1) | AR083049A1 (pt) |
AU (1) | AU2011306524A1 (pt) |
BR (1) | BR112013006526A2 (pt) |
CA (1) | CA2811873A1 (pt) |
EA (1) | EA201390309A1 (pt) |
WO (1) | WO2012039624A1 (pt) |
ZA (1) | ZA201301798B (pt) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013055229A1 (en) * | 2011-10-10 | 2013-04-18 | Goodtech Recovery Technology As | System and method for control pf layer in an aluminium electrolysis cell |
WO2013055228A1 (en) * | 2011-10-10 | 2013-04-18 | Goodtech Recovery Technology As | System and method for control of layer formation in an aluminium electrolysis cell |
WO2014182176A1 (en) * | 2013-05-06 | 2014-11-13 | Goodtech Recovery Technology As | Aluminium electrolysis cell comprising sidewall temperature control system |
NO20150613A1 (en) * | 2015-05-18 | 2016-11-21 | Goodtech Recovery Tech As | Heat recovery |
WO2019177464A1 (en) | 2018-03-16 | 2019-09-19 | Cronus Technology As | A system for recovery of waste heat from an industrial plant |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3003996B1 (en) * | 2013-05-30 | 2020-07-08 | Johns Manville | Submerged combustion glass melting systems and methods of use |
CN108866574B (zh) * | 2018-09-05 | 2020-06-12 | 辽宁石油化工大学 | 一种用于铝电解槽的热交换装置 |
Citations (5)
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DE1934486A1 (de) * | 1969-07-08 | 1971-01-21 | Siegener Ag Geisweid | Einrichtung zur Kuehlung hochhitzebeanspruchter Mauerwerksteile,insbesondere von Metallschmelzoefen |
GB2076428A (en) * | 1980-05-19 | 1981-12-02 | Carblox Ltd | Aluminium manufacture |
EP0047227A2 (de) * | 1980-09-02 | 1982-03-10 | Schweizerische Aluminium Ag | Vorrichtung zum Regulieren des Wärmeflusses einer Aluminiumschmelzflusselektrolysezelle und Verfahren zum Betrieb dieser Zelle |
EP0095854A2 (en) * | 1982-05-28 | 1983-12-07 | Alcan International Limited | Improvements in electrolytic reduction cells for aluminium production |
GB2270146A (en) * | 1992-08-24 | 1994-03-02 | Voest Alpine Ind Anlagen | Gas-cooled metallurgical vessel |
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US4608134A (en) * | 1985-04-22 | 1986-08-26 | Aluminum Company Of America | Hall cell with inert liner |
US4913065A (en) * | 1989-03-27 | 1990-04-03 | Indugas, Inc. | In situ thermal waste disposal system |
US6110430A (en) * | 1998-04-06 | 2000-08-29 | Cmi Corporation | Decontamination plant including an indirectly heated desorption system |
NO313462B1 (no) * | 2000-06-07 | 2002-10-07 | Elkem Materials | Elektrolysecelle for fremstilling av aluminium, en rekke elektrolyseceller i en elektrolysehall, fremgangsmåte for åopprettholde en kruste på en sidevegg i en elektrolysecelle samtfremgangsmåte for gjenvinning av elektrisk energi fra en elektr |
FR2842215B1 (fr) * | 2002-07-09 | 2004-08-13 | Pechiney Aluminium | Procede et systeme de refroidissement d'une cuve d'electrolyse pour la production d'aluminium |
NO20024048D0 (no) * | 2002-08-23 | 2002-08-23 | Norsk Hydro As | Fremgangsmåte for drift av en elektrolysecelle samt midler for samme |
US20050132672A1 (en) * | 2003-12-17 | 2005-06-23 | Hershey Lerner | Packaging machine and process |
US20050160735A1 (en) * | 2004-01-26 | 2005-07-28 | Anju Nelson | Water hydrogen engine system |
FR2893329B1 (fr) * | 2005-11-14 | 2008-05-16 | Aluminium Pechiney Soc Par Act | Cuve d'electrolyse avec echangeur thermique. |
CN101376991B (zh) * | 2007-08-31 | 2011-08-31 | 沈阳铝镁设计研究院有限公司 | 铝电解槽的强制冷却系统 |
CN100494506C (zh) * | 2008-04-17 | 2009-06-03 | 东北大学 | 一种铝电解槽散发余热的回收方法及其装置 |
US20100092164A1 (en) * | 2008-05-16 | 2010-04-15 | Ziehm Raymond G | Tankless heater instant hot water |
CN101610046B (zh) * | 2008-06-16 | 2011-04-20 | 湖南晟通科技集团有限公司 | 铝电解槽废热利用方法 |
CN101615870B (zh) * | 2008-06-26 | 2011-06-29 | 湖南晟通科技集团有限公司 | 一种铝电解槽风管废热利用方法及装置 |
NO337977B1 (no) * | 2008-10-31 | 2016-07-18 | Norsk Hydro As | Fremgangsmåte og anordning for ekstrahering av varme fra aluminium elektrolyseceller |
-
2011
- 2011-09-19 AR ARP110103417A patent/AR083049A1/es unknown
- 2011-09-20 US US13/825,752 patent/US20130199938A1/en not_active Abandoned
- 2011-09-20 EP EP11827027.1A patent/EP2619518A4/en not_active Withdrawn
- 2011-09-20 AU AU2011306524A patent/AU2011306524A1/en not_active Abandoned
- 2011-09-20 AP AP2013006815A patent/AP2013006815A0/xx unknown
- 2011-09-20 CA CA2811873A patent/CA2811873A1/en not_active Abandoned
- 2011-09-20 CN CN201180045617XA patent/CN103210273A/zh active Pending
- 2011-09-20 EA EA201390309A patent/EA201390309A1/ru unknown
- 2011-09-20 WO PCT/NO2011/000263 patent/WO2012039624A1/en active Application Filing
- 2011-09-20 BR BR112013006526A patent/BR112013006526A2/pt not_active IP Right Cessation
-
2013
- 2013-03-08 ZA ZA2013/01798A patent/ZA201301798B/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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DE1934486A1 (de) * | 1969-07-08 | 1971-01-21 | Siegener Ag Geisweid | Einrichtung zur Kuehlung hochhitzebeanspruchter Mauerwerksteile,insbesondere von Metallschmelzoefen |
GB2076428A (en) * | 1980-05-19 | 1981-12-02 | Carblox Ltd | Aluminium manufacture |
EP0047227A2 (de) * | 1980-09-02 | 1982-03-10 | Schweizerische Aluminium Ag | Vorrichtung zum Regulieren des Wärmeflusses einer Aluminiumschmelzflusselektrolysezelle und Verfahren zum Betrieb dieser Zelle |
EP0095854A2 (en) * | 1982-05-28 | 1983-12-07 | Alcan International Limited | Improvements in electrolytic reduction cells for aluminium production |
GB2270146A (en) * | 1992-08-24 | 1994-03-02 | Voest Alpine Ind Anlagen | Gas-cooled metallurgical vessel |
Non-Patent Citations (1)
Title |
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See also references of EP2619518A4 * |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013055229A1 (en) * | 2011-10-10 | 2013-04-18 | Goodtech Recovery Technology As | System and method for control pf layer in an aluminium electrolysis cell |
WO2013055228A1 (en) * | 2011-10-10 | 2013-04-18 | Goodtech Recovery Technology As | System and method for control of layer formation in an aluminium electrolysis cell |
WO2014182176A1 (en) * | 2013-05-06 | 2014-11-13 | Goodtech Recovery Technology As | Aluminium electrolysis cell comprising sidewall temperature control system |
NO337186B1 (no) * | 2013-05-06 | 2016-02-08 | Goodtech Recovery Tech As | Varmerørsammenstilling med returlinjer |
NO20150613A1 (en) * | 2015-05-18 | 2016-11-21 | Goodtech Recovery Tech As | Heat recovery |
WO2016186512A1 (en) * | 2015-05-18 | 2016-11-24 | Goodtech Recovery Technology As | A system and method for recovering waste heat from a combined industrial and thermal power plant. |
NO340554B1 (en) * | 2015-05-18 | 2017-05-08 | Goodtech Recovery Tech As | Heat recovery |
WO2019177464A1 (en) | 2018-03-16 | 2019-09-19 | Cronus Technology As | A system for recovery of waste heat from an industrial plant |
Also Published As
Publication number | Publication date |
---|---|
BR112013006526A2 (pt) | 2016-08-02 |
CN103210273A (zh) | 2013-07-17 |
EP2619518A1 (en) | 2013-07-31 |
ZA201301798B (en) | 2014-05-28 |
AR083049A1 (es) | 2013-01-30 |
AP2013006815A0 (en) | 2013-04-30 |
US20130199938A1 (en) | 2013-08-08 |
AU2011306524A1 (en) | 2013-03-21 |
EA201390309A1 (ru) | 2013-08-30 |
EP2619518A4 (en) | 2017-05-17 |
CA2811873A1 (en) | 2012-03-29 |
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