WO2012039624A1 - System and method for control of side layer formation in an aluminium electrolysis cell - Google Patents

System and method for control of side layer formation in an aluminium electrolysis cell Download PDF

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Publication number
WO2012039624A1
WO2012039624A1 PCT/NO2011/000263 NO2011000263W WO2012039624A1 WO 2012039624 A1 WO2012039624 A1 WO 2012039624A1 NO 2011000263 W NO2011000263 W NO 2011000263W WO 2012039624 A1 WO2012039624 A1 WO 2012039624A1
Authority
WO
WIPO (PCT)
Prior art keywords
heat
sidelining
tube
control
layer formation
Prior art date
Application number
PCT/NO2011/000263
Other languages
English (en)
French (fr)
Inventor
John Paul Salvador
Veroslav Sedlak
Original Assignee
Goodtech Recovery Technology As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodtech Recovery Technology As filed Critical Goodtech Recovery Technology As
Priority to EA201390309A priority Critical patent/EA201390309A1/ru
Priority to AU2011306524A priority patent/AU2011306524A1/en
Priority to EP11827027.1A priority patent/EP2619518A4/en
Priority to CN201180045617XA priority patent/CN103210273A/zh
Priority to AP2013006815A priority patent/AP2013006815A0/xx
Priority to CA2811873A priority patent/CA2811873A1/en
Priority to US13/825,752 priority patent/US20130199938A1/en
Priority to BR112013006526A priority patent/BR112013006526A2/pt
Publication of WO2012039624A1 publication Critical patent/WO2012039624A1/en
Priority to ZA2013/01798A priority patent/ZA201301798B/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/20Automatic control or regulation of cells
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D1/00Casings; Linings; Walls; Roofs
    • F27D1/12Casings; Linings; Walls; Roofs incorporating cooling arrangements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F27FURNACES; KILNS; OVENS; RETORTS
    • F27DDETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS, OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
    • F27D9/00Cooling of furnaces or of charges therein
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • the invention regards heat regulation in general and particularly method and system for use for control of layer formation in an aluminium electrolysis cell and exploitation of heat.
  • the operations of the cells depend on the formation and maintenance of a protective layer of frozen electrolyte in the side walls of the cell.
  • This 5 frozen bath is called side layer and protects the side lining of the cells against chemical and mechanical wear, and is an essential condition for achieving long lifetime of the cells.
  • the crystallized bath operates simultaneously as a buffer for the cell with regards of changes in the heat balance.
  • the heat generation and the heat balance of the cell will vary due to unwanted disturbances of the operation (changes in bath acidity, changes in alumina concentration, changes in interpolar distances, etc.) and desired activities on the cells (metal tapping, change of anode, fire, etc.).
  • GB 2076428A describing an aluminium cell with isolating layers in bottom and walls.
  • the walls In the walls there are carbon blocks with heat tubes moulded in for the removal of heat from the cell.
  • the heat tubes can be adjusted with different distances in order to vary the degree of heat removal.
  • the object of the invention is to provide a method and system for use for control of layer formation in an aluminium electrolysis cell and exploitation of the heat.
  • a sidelining provided with heat tube for transport of heat is provided.
  • the present invention relates to structural elements for forming a sidelining material for cooling of sidelining in aluminium electrolysis cells for the purpose of controlling and adjusting sidelining thickness in the cell.
  • the sidelining materials it is also possible to provide heat exchange of such cells with possibility of regeneration of heat as electrical energy and/or heat.
  • By the forming of sidelining materials in the present invention one should understand design, formation and production of hollows in the material for the purpose of mounting of heat tubes such as heat pipes to lead heat to the outside of the aluminium electrolysis bath.
  • the evaporation end of the heat tube is mounted on the inside of the electrolysis bath and is in contact with the above mentioned sidelining material while on the heat tube condensation end a cooling element is mounted transferring the transported heat to a suited cooling medium such as for instance oil.
  • the present invention achieves the objectives outlined above by a sidelining as described in claim 1 and a method as described in claim 4.
  • the sidelining material is manufactured without requirements for inserting thin canals. Instead a plurality of heat tubes are utilized, attached to the sidelining.
  • the technical effect of the difference is that one achieves efficient transfer of heat without having to sinter sidelinings with thin canals along with the problems that this incurs.
  • heat tubes can be more efficient in transferring heat than use of cooling medium in the canals.
  • a further technical effect is that the heat tubes will be more stably fastened to the longitudinal canals in the surface of the sidelining and that there will be a low thermal gradient along the canal compared to canals known from the state of the art.
  • Figure 1 shows a typical embodiment of the invention in the form of a sidelining block with hollows and heat tube for an electrolysis cell
  • Figure 2 shows a detail section of the embodiment of figure 1 together with section as seen from the side
  • Figure 3 shows an example of providing heat tubes in the sidelining block
  • Figure 4 shows another example of providing heat tubes in the sidelining block.
  • sidelining block 1 1 together with the heat isolation 10, wherein the sidelining block is provided with heat tube 12.
  • the sidelining block 1 1 is typically made from SiC 1 1a, l ib as in example a and b.
  • figure 1 schematically shows a typical embodiment of the invention in the form of a sidelining block with hollows and heat tubes for an electrolysis cell.
  • the sidelining block is manufactured from a ceramic material. It is manufactured in a particular way to achieve the intended hollows.
  • Figure 1 shows one example of possible positioning of hollows.
  • Figure 2 shows the detail section also from the side where the heat tubes are positioned standing along the canals in the surface of the sidelining block.
  • Heat tubes are positioned against these hollows and an example of such a heat tube in the form of a heat pipe.
  • a cooling element On the cold end of the heat tube, also known as the condensation side, a cooling element is mounted comprising a condensation unit for heat tube 13 and condensation fins 14.
  • the invention achieves its solution by the assembly of plurality of principles.
  • heat tube where the phase transition liquid to vapour in the hot end transports large amounts of heat to the cold end where the vapour condenses to liquid which then is returned to the hot end.
  • heat tube there are two embodiments intended: “heat pipe” where a wick or other capillary effect pulls the liquid back to the hot end, and “thermosyphon” where the gravity pulls the liquid back to the hot end.
  • An aluminium electrolysis cell will comprise several tens of such "heat pipe” heat exchangers in the sidewalls. The heat removed from the cells will be transported in a cooling medium. This heat can for instance be exploited to produce electrical energy. A plurality of electrolysis cells can also be connected together in order to regenerate the cooled effect in an efficient manner.
  • the invention is applicable for control of layer formation in a aluminium electrolysis cell and exploitation of the heat.

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Coating By Spraying Or Casting (AREA)
  • Heat-Exchange Devices With Radiators And Conduit Assemblies (AREA)
PCT/NO2011/000263 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell WO2012039624A1 (en)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EA201390309A EA201390309A1 (ru) 2010-09-22 2011-09-20 Система и способ регулирования образования слоя на боковых стенках электролизера для получения алюминия
AU2011306524A AU2011306524A1 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell
EP11827027.1A EP2619518A4 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell
CN201180045617XA CN103210273A (zh) 2010-09-22 2011-09-20 在铝电解槽中控制侧层形成的系统和方法
AP2013006815A AP2013006815A0 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminum electolysis cell
CA2811873A CA2811873A1 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell
US13/825,752 US20130199938A1 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell
BR112013006526A BR112013006526A2 (pt) 2010-09-22 2011-09-20 sistema e método para controle de formação de camada lateral em uma célula eletrolítica de alumínio
ZA2013/01798A ZA201301798B (en) 2010-09-22 2013-03-08 System and method for control of side layer formation in an aluminium electrolysis cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
NO20101321 2010-09-22
NO20101321 2010-09-22

Publications (1)

Publication Number Publication Date
WO2012039624A1 true WO2012039624A1 (en) 2012-03-29

Family

ID=45874019

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/NO2011/000263 WO2012039624A1 (en) 2010-09-22 2011-09-20 System and method for control of side layer formation in an aluminium electrolysis cell

Country Status (11)

Country Link
US (1) US20130199938A1 (pt)
EP (1) EP2619518A4 (pt)
CN (1) CN103210273A (pt)
AP (1) AP2013006815A0 (pt)
AR (1) AR083049A1 (pt)
AU (1) AU2011306524A1 (pt)
BR (1) BR112013006526A2 (pt)
CA (1) CA2811873A1 (pt)
EA (1) EA201390309A1 (pt)
WO (1) WO2012039624A1 (pt)
ZA (1) ZA201301798B (pt)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013055229A1 (en) * 2011-10-10 2013-04-18 Goodtech Recovery Technology As System and method for control pf layer in an aluminium electrolysis cell
WO2013055228A1 (en) * 2011-10-10 2013-04-18 Goodtech Recovery Technology As System and method for control of layer formation in an aluminium electrolysis cell
WO2014182176A1 (en) * 2013-05-06 2014-11-13 Goodtech Recovery Technology As Aluminium electrolysis cell comprising sidewall temperature control system
NO20150613A1 (en) * 2015-05-18 2016-11-21 Goodtech Recovery Tech As Heat recovery
WO2019177464A1 (en) 2018-03-16 2019-09-19 Cronus Technology As A system for recovery of waste heat from an industrial plant

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3003996B1 (en) * 2013-05-30 2020-07-08 Johns Manville Submerged combustion glass melting systems and methods of use
CN108866574B (zh) * 2018-09-05 2020-06-12 辽宁石油化工大学 一种用于铝电解槽的热交换装置

Citations (5)

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DE1934486A1 (de) * 1969-07-08 1971-01-21 Siegener Ag Geisweid Einrichtung zur Kuehlung hochhitzebeanspruchter Mauerwerksteile,insbesondere von Metallschmelzoefen
GB2076428A (en) * 1980-05-19 1981-12-02 Carblox Ltd Aluminium manufacture
EP0047227A2 (de) * 1980-09-02 1982-03-10 Schweizerische Aluminium Ag Vorrichtung zum Regulieren des Wärmeflusses einer Aluminiumschmelzflusselektrolysezelle und Verfahren zum Betrieb dieser Zelle
EP0095854A2 (en) * 1982-05-28 1983-12-07 Alcan International Limited Improvements in electrolytic reduction cells for aluminium production
GB2270146A (en) * 1992-08-24 1994-03-02 Voest Alpine Ind Anlagen Gas-cooled metallurgical vessel

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NO313462B1 (no) * 2000-06-07 2002-10-07 Elkem Materials Elektrolysecelle for fremstilling av aluminium, en rekke elektrolyseceller i en elektrolysehall, fremgangsmåte for åopprettholde en kruste på en sidevegg i en elektrolysecelle samtfremgangsmåte for gjenvinning av elektrisk energi fra en elektr
FR2842215B1 (fr) * 2002-07-09 2004-08-13 Pechiney Aluminium Procede et systeme de refroidissement d'une cuve d'electrolyse pour la production d'aluminium
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DE1934486A1 (de) * 1969-07-08 1971-01-21 Siegener Ag Geisweid Einrichtung zur Kuehlung hochhitzebeanspruchter Mauerwerksteile,insbesondere von Metallschmelzoefen
GB2076428A (en) * 1980-05-19 1981-12-02 Carblox Ltd Aluminium manufacture
EP0047227A2 (de) * 1980-09-02 1982-03-10 Schweizerische Aluminium Ag Vorrichtung zum Regulieren des Wärmeflusses einer Aluminiumschmelzflusselektrolysezelle und Verfahren zum Betrieb dieser Zelle
EP0095854A2 (en) * 1982-05-28 1983-12-07 Alcan International Limited Improvements in electrolytic reduction cells for aluminium production
GB2270146A (en) * 1992-08-24 1994-03-02 Voest Alpine Ind Anlagen Gas-cooled metallurgical vessel

Non-Patent Citations (1)

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See also references of EP2619518A4 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013055229A1 (en) * 2011-10-10 2013-04-18 Goodtech Recovery Technology As System and method for control pf layer in an aluminium electrolysis cell
WO2013055228A1 (en) * 2011-10-10 2013-04-18 Goodtech Recovery Technology As System and method for control of layer formation in an aluminium electrolysis cell
WO2014182176A1 (en) * 2013-05-06 2014-11-13 Goodtech Recovery Technology As Aluminium electrolysis cell comprising sidewall temperature control system
NO337186B1 (no) * 2013-05-06 2016-02-08 Goodtech Recovery Tech As Varmerørsammenstilling med returlinjer
NO20150613A1 (en) * 2015-05-18 2016-11-21 Goodtech Recovery Tech As Heat recovery
WO2016186512A1 (en) * 2015-05-18 2016-11-24 Goodtech Recovery Technology As A system and method for recovering waste heat from a combined industrial and thermal power plant.
NO340554B1 (en) * 2015-05-18 2017-05-08 Goodtech Recovery Tech As Heat recovery
WO2019177464A1 (en) 2018-03-16 2019-09-19 Cronus Technology As A system for recovery of waste heat from an industrial plant

Also Published As

Publication number Publication date
BR112013006526A2 (pt) 2016-08-02
CN103210273A (zh) 2013-07-17
EP2619518A1 (en) 2013-07-31
ZA201301798B (en) 2014-05-28
AR083049A1 (es) 2013-01-30
AP2013006815A0 (en) 2013-04-30
US20130199938A1 (en) 2013-08-08
AU2011306524A1 (en) 2013-03-21
EA201390309A1 (ru) 2013-08-30
EP2619518A4 (en) 2017-05-17
CA2811873A1 (en) 2012-03-29

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