WO2012017447A3 - Method for selective hydration of aroma olefins to alcohols in continuous solid catalyst column reactor - Google Patents

Method for selective hydration of aroma olefins to alcohols in continuous solid catalyst column reactor Download PDF

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Publication number
WO2012017447A3
WO2012017447A3 PCT/IN2011/000493 IN2011000493W WO2012017447A3 WO 2012017447 A3 WO2012017447 A3 WO 2012017447A3 IN 2011000493 W IN2011000493 W IN 2011000493W WO 2012017447 A3 WO2012017447 A3 WO 2012017447A3
Authority
WO
WIPO (PCT)
Prior art keywords
aroma
column reactor
olefins
alcohols
solid catalyst
Prior art date
Application number
PCT/IN2011/000493
Other languages
French (fr)
Other versions
WO2012017447A8 (en
WO2012017447A2 (en
Inventor
Vijay Kumar Doppalapudi Rao
Manish Vardharaj Petkar
Arvind M Lali
Original Assignee
Vijay Kumar Doppalapudi Rao
Manish Vardharaj Petkar
Arvind M Lali
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vijay Kumar Doppalapudi Rao, Manish Vardharaj Petkar, Arvind M Lali filed Critical Vijay Kumar Doppalapudi Rao
Publication of WO2012017447A2 publication Critical patent/WO2012017447A2/en
Publication of WO2012017447A8 publication Critical patent/WO2012017447A8/en
Publication of WO2012017447A3 publication Critical patent/WO2012017447A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/03—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2
    • C07C29/04—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by addition of hydroxy groups to unsaturated carbon-to-carbon bonds, e.g. with the aid of H2O2 by hydration of carbon-to-carbon double bonds

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Present invention is related to method for selective hydration of aroma olefins to alcohols in continuous solid catalyst column reactor. The invention discloses the continuous production of unsaturated aroma alcohol and/or ester comprising of C10-12 carbon chain by selective solid acid catalyzed hydration reaction. According to the process of the invention production of Octa-1-ene-7- ol, 3,7-dimethyl- (Dihydromyrcenol) and/or dihydromyrcenyl acetate can be carried out by passing 1,6-Octadiene, 3,7-dimethyl- (dihydromyrcene) and water continuously through a packed bed column reactor wherein the residence time of column is not more than 90 minutes and reaction temperature not substantially above 100 degree C. The present disclosure solves the problem of effluent treatment and increases the yield of the process due to selectivity in reaction.
PCT/IN2011/000493 2010-08-04 2011-07-26 Method for selective hydration of aroma olefins to alcohols in continuous solid catalyst column reactor WO2012017447A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN2211MU2010 2010-08-04
IN2211/MUM/2010 2010-08-04

Publications (3)

Publication Number Publication Date
WO2012017447A2 WO2012017447A2 (en) 2012-02-09
WO2012017447A8 WO2012017447A8 (en) 2012-05-10
WO2012017447A3 true WO2012017447A3 (en) 2012-06-07

Family

ID=44764194

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2011/000493 WO2012017447A2 (en) 2010-08-04 2011-07-26 Method for selective hydration of aroma olefins to alcohols in continuous solid catalyst column reactor

Country Status (1)

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WO (1) WO2012017447A2 (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104926610B (en) * 2015-05-27 2016-09-07 广西梧松林化集团有限公司 The preparation method of dihydromyrcenol
US11008271B2 (en) * 2016-09-08 2021-05-18 P2 Science, Inc. Methods for the continuous alkoxylation and derivatization of terpenes

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684065A (en) * 2009-07-21 2010-03-31 厦门中坤化学有限公司 Efficient energy-saving process for continuously processing dihydromyrcenol

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL113984C (en) 1956-04-09
US3487118A (en) 1966-10-17 1969-12-30 Int Flavors & Fragrances Inc Preparation of dihydromyrcenol
GB1506131A (en) 1976-02-04 1978-04-05 Shell Bv Preparation of dihydromyrcenol or a carboxylic ester thereof
US4791222A (en) 1984-07-31 1988-12-13 International Flavors & Fragrances Inc. Process for preparing dihydromyrcenol and dihydromyrcenyl acetate
FR2597861B1 (en) 1986-04-29 1990-11-09 Derives Resiniques Terpenique NEW PROCESS FOR THE PREPARATION OF DIHYDROMYRCENOL
DE4021578A1 (en) 1990-07-06 1992-01-09 Huels Chemische Werke Ag METHOD FOR PRODUCING DIHYDROMYRCENOL FROM DIHYDROMYRCENYL CHLORIDE
ES2143281T3 (en) 1996-01-15 2000-05-01 Quest Int TRANSESTERIFICATION PROCEDURE FOR THE PREPARATION OF DIHIDROMIRCENOL AND MIRCENOL.

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101684065A (en) * 2009-07-21 2010-03-31 厦门中坤化学有限公司 Efficient energy-saving process for continuously processing dihydromyrcenol

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 201029, Derwent World Patents Index; AN 2010-E07057, XP002663149 *

Also Published As

Publication number Publication date
WO2012017447A8 (en) 2012-05-10
WO2012017447A2 (en) 2012-02-09

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