WO2012017277A1 - Agent sanitaire - Google Patents

Agent sanitaire Download PDF

Info

Publication number
WO2012017277A1
WO2012017277A1 PCT/IB2011/001164 IB2011001164W WO2012017277A1 WO 2012017277 A1 WO2012017277 A1 WO 2012017277A1 IB 2011001164 W IB2011001164 W IB 2011001164W WO 2012017277 A1 WO2012017277 A1 WO 2012017277A1
Authority
WO
WIPO (PCT)
Prior art keywords
sanitary
agent
sanitary agent
appliance
treatment
Prior art date
Application number
PCT/IB2011/001164
Other languages
English (en)
Inventor
Fabio Pagani
Original Assignee
Re.Le.Vi. S.P.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Re.Le.Vi. S.P.A. filed Critical Re.Le.Vi. S.P.A.
Priority to EP11727520.6A priority Critical patent/EP2601283B1/fr
Priority to ES11727520.6T priority patent/ES2528369T3/es
Publication of WO2012017277A1 publication Critical patent/WO2012017277A1/fr

Links

Classifications

    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D9/03—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing consisting of a separate container with an outlet through which the agent is introduced into the flushing water, e.g. by suction ; Devices for agents in direct contact with flushing water
    • E03D9/032—Devices connected to or dispensing into the bowl
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047—Detergents in the form of bars or tablets
    • C11D17/0056—Lavatory cleansing blocks
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
    • C11D2111/14—
    • E—FIXED CONSTRUCTIONS
    • E03—WATER SUPPLY; SEWERAGE
    • E03D—WATER-CLOSETS OR URINALS WITH FLUSHING DEVICES; FLUSHING VALVES THEREFOR
    • E03D9/00—Sanitary or other accessories for lavatories ; Devices for cleaning or disinfecting the toilet room or the toilet bowl; Devices for eliminating smells
    • E03D9/02—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing
    • E03D2009/024—Devices adding a disinfecting, deodorising, or cleaning agent to the water while flushing using a solid substance

Definitions

  • the invention relates to a sanitary agent for cleaning, disinfecting and/or perfuming a sanitary appliance.
  • the present invention relates to a sanitary agent which can adhere to an internal wall of a water-closet bowl or a urinal, remaining attached for a high number of water flushes up to its final consumption.
  • Sanitary appliances for example hygienic toilet bowls or urinals fixed to a wall, have to be subjected to repeated cleaning and disinfecting operations in order to be able to maintain adequate hygienic sanitary conditions.
  • the prior art comprises hanging sanitary agents by means of hooking device positioned in the water closet container, where one exists; the emission of the sanitary agent occurs at each discharge flush operation into the bowl.
  • sanitary agents which are fixed to the perimeter edge of the toilet bowl by means of a support; these sanitary agents are normally inserted in particular devices, like cages, provided with the support means, such as for example a plastic bracket, and which also include slits and/or holes such as to enable a portion of the sanitary agent to exit at each flush of the water.
  • the above-described sanitary agents when struck by the water which irrigates the toilet bowl, enriches the water with the substances contained in the agents, thus providing the elements required for deterging, descaling, deodorising and/or disinfecting the bowl.
  • these devices are not very practical and hygienic; during manual cleaning of the edge of the toilet bowl or during the cleaning of the inside of the bowl by use of the toilet brush, the support means fixed to the edge of the bowl can be accidentally shifted and it is therefore necessary to reposition it. Further, on substitution of the sanitary agent, due to its consumption, it is necessary to act manually with ensuing operative and hygienic difficulties for 5 the user, as the devices are often positioned in poorly-accessible places, in any case not ideal from the hygienic point of view.
  • the prior art comprises certain solutions to the above-cited problem, in which sanitary agents, in particular solid or semi-solid soaps can adhere stably to the internal wall of a WC bowl or a urinal in order to be subjected to regular water flushes.
  • European patent EP 1 086 199 in the name of Buck-Chemie GmbH 0 describes a sanitary agent which can be applied directly on the surface of the sanitary appliance, the sanitary agent having a viscosity of at least 15,000 mPas and comprising an adhesion promoter such as poly oxy alcohol alkane, cellulose, etc.
  • an adhesion promoter such as poly oxy alcohol alkane, cellulose, etc.
  • the sanitary agent deforms, causing the components constituting it to drip downwards in an undesirable way.
  • a further disadvantage is given by the fact that in order to be applied adequately to the part of the sanitary appliance, the sanitary agent described in the patent application obligatorily requires the use of a batching system normally constituted by rigid plastic material, with the consequence of an undesired and significant use of plastic material.
  • EP application 2 141 221 in the name of Manitoba described a detergent pastille having a substantially flat adhesive surface for anchoring to a wall of the WC bowl and a shell-shaped surface such as to be subjected to the action of the flush water.
  • a problem of the products using an adhesive part is that the adhesive part does not completely dissolve following the action of the flush water and therefore, once the detergent part of the pastille has been consumed, a manual intervention is required to remove the residue of the detergent pastille that has remained adhering to the part of the WC bowl.
  • the aim of the present invention is to provide a sanitary agent for treatment of a sanitary appliance which constitutes an alternative to the solutions provided by the prior-art documents as cited above.
  • the aim of the present invention is to provide a sanitary agent for treatment of a sanitary appliance, the sanitary agent comprising at least an adhesive component and at least a component that is useful for the treatment, the adhesive component being capable of enabling the sanitary agent to remain in adherence for a large number of water flushes to a sanitary appliance of any shape and, at the same time, once the component of the sanitary agent used for the treatment is consumed, to be easily dissolved in the water of further flushes.
  • the present invention relates to a sanitary agent to be used for deterging, disinfecting and/or perfuming a sanitary appliance.
  • a sanitary agent for treating a sanitary appliance comprising an active body, solid or semi-solid, including a treatment compound having at least an active element for treatment of the sanitary appliance and at least a surfactant, characterised in that it comprises an adhesive layer positioned on a portion of the external surface of the active body, in which the adhesive layer comprises at least an adhesive element deriving from colophony resin, destined to realise adhesion of the active body to the wall of the sanitary appliance, is capable of enabling the adhesion to last for a high number of water flushes, the sanitary agent dissolving substantially completely at the end of the operating cycle thereof and being of a shape such as to be able to adhere to sanitary appliances of any shape.
  • the present invention has the advantage of providing a sanitary agent which comprises an adhesive layer and a treatment compound, in which the treatment compound can be any of the traditionally known treatment compositions.
  • sanitary appliance is understood to mean a water-closet toilet bowl, a urinal bowl, a urinal or any other like apparatus which is usually subjected to water flushes in order to maintain cleanliness and hygiene thereof.
  • treatment of a sanitary appliance is understood to mean cleaning, hygienising, disinfecting, perfuming and removing limescale, and other like operations applicable to the sanitary appliance.
  • active element for the treatment is understood to means an element dedicated to cleaning, deterging, foaming, perfuming, deodorising, disinfecting, water-colouring, polishing, or any other element which is soluble in water and useful for the treatment to which the sanitary appliance is to be subjected.
  • si-solid body is intended to mean a body having a pasty consistency, or having a consistency which is such as to be slightly modifiable in shape by manual pressure, but such as to maintain over time the given shape, even following the action of weak external forces, such as a water flush or discharge.
  • the shape of the sanitary agent can be appropriately modelled on the basis of the shape of the wall in order to guarantee good adhesion. This shape can be maintained over time, except for the reduction in mass due to its dissolving by action of the flush water.
  • the sanitary agent of the present invention can be consumed progressively and appropriately at each flush of water of the sanitary appliance, activating an emulsifying and/or solubilising process. Following each water discharge, first the treatment compound comprising the active ingredient for treatment of the sanitary appliance is progressively dissolved into the water.
  • the adhesive element of the sanitary agent begins to be exposed to the action of the water which, in combination with the residual part of the treatment compound, enables complete removal of the adhesive element.
  • the adhesive element is preferably a terpene deriving from colophony (colophony resin); more preferably, the terpene is a linear colophony ester, such as for example Bremasin 1205.
  • Colphony is a solid yellow vegetable resin (abietic anhydride), which is transparent and a residue of the distillation of trementine (conifer resins Pinus palustris and other pines of the pinaceae family.
  • the quantity of the adhesive element derived from colophony resin is comprised in the range 0.2-20%, more preferably in the range of 0.2-10%, still more preferably 1 -3% in weight with respect to the total weight of the sanitary agent.
  • the adhesive element preferably derived from colophony resin is applied on the external surface of the active body by application via spreading, spraying, or any other known method which enables a homogeneous distribution of the adhesive element on the external surface of the active body.
  • the adhesive layer positioned on a portion of the external surface of the active body of the sanitary agent preferably comprises, beyond the adhesive element derived from colophony resin, a fatty substance and/or at least a silicone substance, such as for example partially-hydrogenated mineral oils or fats, silicone fats or derivatives thereof, Vaseline, petroleum jelly, silicone polymers, hydrocarbon synthetic copolymers with a kinematic viscosity comprised between 3,000 and 9,000 cStokes (at 100°C).
  • the sanitary agent comprises a treatment compound having at least an active element for the treatment and at least a surfactant.
  • the active element is preferably a detergent element, a perfume or a disinfectant.
  • the quantity of the at least an active element is preferably comprised in the interval from 1 -75% in weight with respect to the total weight of the sanitary agent.
  • the at least a surfactant is preferably selected from a group consisting of non-ionic surfactants, anionic surfactants, cationic surfactants, amphoteric surfactants, and combinations thereof.
  • the non-ionic surfactants are preferably selected from the group consisting of long-chain alcohols (from about 10 to about 20 carbon atoms), such as polyoxyethylene derivatives of fatty acids, starch alkanols of fatty acids, alkyi polyglucosides (APG), natural and/or synthetic etoxylated alchohols, amine oxides.
  • the anionic surfactants are preferably selected from the group consisting of compounds having carbon atom chains ending with a caroxylate or sulphanate group, such as for example soaps, alkyi ether sulphates (LES/AES), alkyi sulphates (LS/AS), a-olefin sulphonates (AOS), alkyi ether carboxylates, sulphosuccinates, aromatic sulphonates.
  • LES/AES alkyi ether sulphates
  • LS/AS alkyi sulphates
  • AOS a-olefin sulphonates
  • alkyi ether carboxylates sulphosuccinates
  • aromatic sulphonates such as for example soaps, alkyi ether sulphates (LES/AES), alkyi sulphates (LS/AS), a-olefin sulphonates (AOS), alkyi ether carboxylates, sulphosuccinates,
  • the cationic surfactants are preferably selected from the group consisting of long carbon atom chains (from about 10 to about 20 carbon atoms) terminating with a quaternary amine group, such as for example alkyi hydroxyethyl dimethyl ammonium chloride, banzalconium chloride, cetyl- trimethyl ammonium bromide or chloride, hexadecyl-trimethyl ammonium bromide or chloride, and the like.
  • a quaternary amine group such as for example alkyi hydroxyethyl dimethyl ammonium chloride, banzalconium chloride, cetyl- trimethyl ammonium bromide or chloride, hexadecyl-trimethyl ammonium bromide or chloride, and the like.
  • the surfactant amphoterics are preferably selected from a group consisting of amino carboxyl acids, alkyi betaine, such as for example 12 betaine, starch alkyls, propyl betaine, and amphoacetates.
  • the at least a surfactant is a mixture of at least a non-ionic surfactant and/or at least an anionic surfactant.
  • the quantity of the at least a surfactant is comprised in the range from 25- 75%, more preferably in the range from 30-70% in weight with respect to the total weight of the sanitary agent.
  • the treatment composition preferably comprises at least an inorganic salt; more preferably, the at least an inorganic salt is selected from among the group consisting in sulphates in various stages of hydration, monovalent and bivalent metals, such as for example sodium sulphate or magnesium sulphate; monovalent and bivalent metal carbonates and bicarbonates, such as for example sodium carbonate, magnesium carbonate and sodium bicarbonate; monovalent and bivalent metal chlorides, such as for example sodium chloride.
  • the quantity of the at least an inorganic salt is preferably comprised in the range from 10-70%, and more preferably in the range from 10-20% in weight with respect to the total weight of the sanitary agent.
  • the treatment compound can preferably further comprise various agents, 5 such as for example bleaches, perfumes, disinfectants, colorants, dispersants, plastifiers, in quantities from 0.1 to 30% in weight with respect to the total weight of the sanitary agent.
  • agents, 5 such as for example bleaches, perfumes, disinfectants, colorants, dispersants, plastifiers, in quantities from 0.1 to 30% in weight with respect to the total weight of the sanitary agent.
  • the present invention relates to a method for deterging, disinfecting and/or perfuming a sanitary appliance characterised by direct i o application thereof on the wall of the sanitary appliance of the present invention to be treated of a sanitary agent such as the above-described ones.
  • Sanitary agent 1 (invention).
  • the first treatment compound for a sanitary appliance was prepared.
  • the compound comprised the non-ionic surfactant marketed under the name of 0 mergital CS25 (cethearet25) by Cognis, the non-ionic surfactant marketed under the name of comperlanl OO by Cognis, the non-ionic surfactant marketed under the name glucopon by Cognis, the anionic surfactant alkyl sulphate marketed under the name Texapon V95 by Cognis, sodium sulphate and a perfume in percentages as follows:
  • Foamer DERIPHAT 160 C (Cognis) 3% The compound was prepared by mixing the various components in a laboratory vertical-arm mixer at ambient temperature, leaving it to mix for about 30 minutes up to obtaining a homogeneous, plastic and modellable paste.
  • the sanitary agent 1 presented as a semi-solid active body, with a substantially flattened-cylinder shape, with a diameter of the base surfaces of about 4cm, and a height (thickness) of about 0.4 cm, including the treatment compound 1 and comprising an adhesive layer positioned on a portion of the external surface of the active body.
  • a sanitary agent 1 having a total weight of 12 grams, which was made to adhere to the hard surface of the internal wall of a toilet bowl, following a flushing of the toilet and pressing the adhesive layer against the wall of the sanitary appliance to be treated for about ten seconds, to guarantee good adhesion.
  • the sanitary agent 1 was subjected to a series of 100 homogeneous water flushes, which caused progressive release up to complete consumption of the treatment compound, leaving a residue of colophony resin of less than 10% of the initial quantity of the colophony present in the sanitary agent; this resin residue was easily eliminated by using a toilet brush.
  • the sanitary agent 1 of the present invention a good adhesion of the sanitary agent to the sanitary appliance to be treated was obtained, as well as an efficient hygienisation of the sanitary appliance and at the same time it was not necessary to touch non-hygienic zones of the sanitary appliance (the toilet bowl) with the hands in order to remove the residues of the sanitary agent 1 at the end of its use phase. Finally, it was not necessary to use an applicator object in order to position the sanitary agent correctly without entering into contact with the walls of the toilet bowl.

Abstract

L'invention concerne un agent sanitaire servant à traiter un appareil sanitaire, l'agent sanitaire comprenant un corps actif solide ou semi-solide comportant un composé de traitement contenant au moins un élément actif pour traiter l'appareil sanitaire et au moins un tensioactif. Le corps actif comprend une couche adhésive positionnée sur une partie de sa surface externe, la couche adhésive comprenant au moins un élément adhésif dérivant d'une résine de colophane et servant à faire adhérer le corps actif à une paroi de l'appareil sanitaire. De cette manière, l'agent sanitaire adhère parfaitement à l'appareil sanitaire à traiter qui est ainsi efficacement nettoyé et, dans le même temps, il n'est pas nécessaire de toucher des zones non hygiéniques de l'appareil sanitaire (la cuvette des toilettes) avec les mains afin de retirer les résidus de l'agent sanitaire à la fin de sa période d'utilisation.
PCT/IB2011/001164 2010-08-06 2011-05-27 Agent sanitaire WO2012017277A1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
EP11727520.6A EP2601283B1 (fr) 2010-08-06 2011-05-27 Agent sanitaire
ES11727520.6T ES2528369T3 (es) 2010-08-06 2011-05-27 Agente sanitario

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ITRE20100065 2010-08-06
ITRE2010A000065 2010-08-06

Publications (1)

Publication Number Publication Date
WO2012017277A1 true WO2012017277A1 (fr) 2012-02-09

Family

ID=43127789

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/IB2011/001165 WO2012017278A1 (fr) 2010-08-06 2011-05-27 Agent sanitaire
PCT/IB2011/001164 WO2012017277A1 (fr) 2010-08-06 2011-05-27 Agent sanitaire

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/IB2011/001165 WO2012017278A1 (fr) 2010-08-06 2011-05-27 Agent sanitaire

Country Status (11)

Country Link
US (1) US20130125297A1 (fr)
EP (2) EP2601284B1 (fr)
CN (1) CN103052705B (fr)
AU (1) AU2011287328B2 (fr)
CA (1) CA2805335A1 (fr)
EA (1) EA022707B1 (fr)
ES (2) ES2528369T3 (fr)
IL (1) IL224340A (fr)
IT (2) ITRE20110041A1 (fr)
MA (1) MA34455B1 (fr)
WO (2) WO2012017278A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014072677A1 (fr) 2012-11-09 2014-05-15 Reckitt Benckiser Llc Distributeur pliable à usage unique pour une composition de traitement de toilettes adhésive
WO2020025642A1 (fr) 2018-08-03 2020-02-06 Ludwig Institute For Cancer Research Ltd. Vecteurs viraux codant pour des antigènes cancer/testis destinés à être utilisés dans une méthode de prévention ou de traitement du cancer

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102013108019B3 (de) * 2013-07-26 2014-08-28 Buck-Chemie Gmbh Haftendes Mittel zur Applikation auf einem Sanitärgegenstand
EP4305136A1 (fr) * 2021-03-08 2024-01-17 Unilever IP Holdings B.V. Bloc nettoyant wc façonné

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1086199A1 (fr) 1998-06-12 2001-03-28 Buck-Chemie GmbH . Produit d'assainissement adhesif
WO2008100393A1 (fr) 2007-02-12 2008-08-21 S. C. Johnson & Son, Inc. Bloc désintégrant auto-adhésif pour toilettes ou urinoir
WO2008125451A1 (fr) * 2007-04-16 2008-10-23 Unilever N.V. Bloc de nettoyage pour surface dure auto-adhésif
EP2141221A1 (fr) 2008-06-30 2010-01-06 Bolton Manitoba SpA Produit adhésif pour la cuvette de toilette, un conteneur et un applicateur à cela

Family Cites Families (7)

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Publication number Priority date Publication date Assignee Title
US3257478A (en) * 1965-02-12 1966-06-21 Nat Starch Chem Corp Pressure sensitive adhesive compositions
US4373219A (en) * 1980-04-07 1983-02-15 Gruber Systems, Inc. Cast toilet base structure
EP0784091A1 (fr) * 1996-01-12 1997-07-16 The Procter & Gamble Company Composition de blanchiment stable parfumée
DE102004056554A1 (de) * 2004-11-23 2006-05-24 Buck-Chemie Gmbh Haftendes Sanitärreinigungs- und Beduftungsmittel
US20060260031A1 (en) * 2005-05-20 2006-11-23 Conrad Joseph M Iii Potty training device
WO2007148053A1 (fr) * 2006-06-20 2007-12-27 Reckitt Benckiser Inc. Blocs de traitement pleins améliorés pour appareils sanitaires
EP2254980B2 (fr) * 2008-02-21 2016-11-30 S.C. Johnson & Son, Inc. Composition de nettoyage ayant une auto-adherence elevee et offrant des benefices d'appoint

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1086199A1 (fr) 1998-06-12 2001-03-28 Buck-Chemie GmbH . Produit d'assainissement adhesif
WO2008100393A1 (fr) 2007-02-12 2008-08-21 S. C. Johnson & Son, Inc. Bloc désintégrant auto-adhésif pour toilettes ou urinoir
WO2008125451A1 (fr) * 2007-04-16 2008-10-23 Unilever N.V. Bloc de nettoyage pour surface dure auto-adhésif
EP2141221A1 (fr) 2008-06-30 2010-01-06 Bolton Manitoba SpA Produit adhésif pour la cuvette de toilette, un conteneur et un applicateur à cela

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2014072677A1 (fr) 2012-11-09 2014-05-15 Reckitt Benckiser Llc Distributeur pliable à usage unique pour une composition de traitement de toilettes adhésive
WO2020025642A1 (fr) 2018-08-03 2020-02-06 Ludwig Institute For Cancer Research Ltd. Vecteurs viraux codant pour des antigènes cancer/testis destinés à être utilisés dans une méthode de prévention ou de traitement du cancer

Also Published As

Publication number Publication date
AU2011287328A1 (en) 2013-02-28
CN103052705A (zh) 2013-04-17
EP2601284A1 (fr) 2013-06-12
AU2011287328B2 (en) 2013-09-12
EA201390062A1 (ru) 2013-06-28
EP2601283B1 (fr) 2014-11-19
CN103052705B (zh) 2015-07-29
WO2012017278A1 (fr) 2012-02-09
IL224340A (en) 2015-10-29
EP2601283A1 (fr) 2013-06-12
ITRE20110042A1 (it) 2012-02-07
CA2805335A1 (fr) 2012-02-09
EP2601284B1 (fr) 2016-01-13
ES2561529T3 (es) 2016-02-26
ITRE20110041A1 (it) 2012-02-07
ES2528369T3 (es) 2015-02-09
MA34455B1 (fr) 2013-08-01
US20130125297A1 (en) 2013-05-23
EA022707B1 (ru) 2016-02-29

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