WO2011143397A3 - Hydroprocessing of pyrolysis oil and its use as a fuel - Google Patents

Hydroprocessing of pyrolysis oil and its use as a fuel Download PDF

Info

Publication number
WO2011143397A3
WO2011143397A3 PCT/US2011/036212 US2011036212W WO2011143397A3 WO 2011143397 A3 WO2011143397 A3 WO 2011143397A3 US 2011036212 W US2011036212 W US 2011036212W WO 2011143397 A3 WO2011143397 A3 WO 2011143397A3
Authority
WO
WIPO (PCT)
Prior art keywords
pyrolysis oil
hydroprocessed
hydroprocessing
fuels
stable
Prior art date
Application number
PCT/US2011/036212
Other languages
French (fr)
Other versions
WO2011143397A2 (en
Inventor
William J. Novak
Randolph J. Smiley
Richard J. Quann
Karlton J. Hickey
Original Assignee
Exxonmobil Research And Engineering Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Research And Engineering Company filed Critical Exxonmobil Research And Engineering Company
Priority to CN201180023021XA priority Critical patent/CN102884159A/en
Priority to CA2798714A priority patent/CA2798714A1/en
Priority to SG2012073763A priority patent/SG184443A1/en
Priority to AU2011253089A priority patent/AU2011253089A1/en
Priority to EP11721194A priority patent/EP2569398A2/en
Publication of WO2011143397A2 publication Critical patent/WO2011143397A2/en
Publication of WO2011143397A3 publication Critical patent/WO2011143397A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C10L1/026Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for compression ignition
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1011Biomass
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10Feedstock materials
    • C10G2300/1037Hydrocarbon fractions
    • C10G2300/1048Middle distillates
    • C10G2300/1059Gasoil having a boiling range of about 330 - 427 °C
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20Characteristics of the feedstock or the products
    • C10G2300/201Impurities
    • C10G2300/202Heteroatoms content, i.e. S, N, O, P
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00Technologies relating to oil refining and petrochemical industry
    • Y02P30/20Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

This invention provides low sulfur fuels, particularly low sulfur bunker fuels, comprising hydroprocessed pyrolysis oil. The hydroprocessed pyrolysis oil can be produced using a catalyst suited to processing pyrolysis oils that may be relatively high in water content and under relatively low severity conditions to limit water formation, while making the hydroprocessed pyrolysis oil more stable than prior to hydroprocessing. The pyrolysis oil can be converted to a more stable hydroprocessed product, e.g., by converting at least a majority of the aldehydes, ketones, and/or carboxylic acids in the pyrolysis oil to more highly stable compounds, such as alcohols. The hydroprocessed product can be particularly suited as a blend component for producing a variety of reduced sulfur fuels.
PCT/US2011/036212 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel WO2011143397A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
CN201180023021XA CN102884159A (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel
CA2798714A CA2798714A1 (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel
SG2012073763A SG184443A1 (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel
AU2011253089A AU2011253089A1 (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel
EP11721194A EP2569398A2 (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39560010P 2010-05-14 2010-05-14
US61/395,600 2010-05-14

Publications (2)

Publication Number Publication Date
WO2011143397A2 WO2011143397A2 (en) 2011-11-17
WO2011143397A3 true WO2011143397A3 (en) 2012-02-16

Family

ID=44626550

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2011/036212 WO2011143397A2 (en) 2010-05-14 2011-05-12 Hydroprocessing of pyrolysis oil and its use as a fuel

Country Status (7)

Country Link
US (1) US20110277377A1 (en)
EP (1) EP2569398A2 (en)
CN (1) CN102884159A (en)
AU (1) AU2011253089A1 (en)
CA (1) CA2798714A1 (en)
SG (1) SG184443A1 (en)
WO (1) WO2011143397A2 (en)

Families Citing this family (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130014431A1 (en) * 2011-07-11 2013-01-17 Phillips 66 Company Advanced, biomass-derived, low-sulfur bunker fuels
WO2013064563A1 (en) * 2011-10-31 2013-05-10 Shell Internationale Research Maatschappij B.V. A method for upgrading an oil, a fuel product and a hydrocarbon product fraction
US20130261355A1 (en) * 2012-03-28 2013-10-03 Kior, Inc. Catalyst Compositions for Use in a Two-Stage Reactor Assembly Unit for the Thermolysis and Catalytic Conversion of Biomass
MY174963A (en) * 2012-08-24 2020-05-29 Ensyn Renewables Inc Devolatilization of thermally produced liquids
CN103394505B (en) * 2013-08-05 2015-04-29 中国科学院城市环境研究所 Method for using plants to control and restore soil and to generate biological fuel
US9057035B1 (en) 2014-02-17 2015-06-16 Shell Oil Company Fuel compositions
EP2907867A1 (en) * 2014-02-17 2015-08-19 Shell International Research Maatschappij B.V. Fuel compositions
CN106414675B (en) * 2014-05-22 2019-10-01 国际壳牌研究有限公司 Fuel composition
US20150353851A1 (en) * 2014-06-05 2015-12-10 Sunoco Partners Marketing & Terminals L.P. Low sulfur marine fuel
KR20170092620A (en) * 2014-12-04 2017-08-11 엑손모빌 리서치 앤드 엔지니어링 컴퍼니 Low sulfur marine bunker fuels and methods of making same
EP3565664A4 (en) 2016-12-29 2020-08-05 Ensyn Renewables, Inc. Demetallization of liquid biomass
US12025435B2 (en) 2017-02-12 2024-07-02 Magēmã Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil
US11788017B2 (en) 2017-02-12 2023-10-17 Magëmã Technology LLC Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil
US20190233741A1 (en) 2017-02-12 2019-08-01 Magēmā Technology, LLC Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil
US10604709B2 (en) 2017-02-12 2020-03-31 Magēmā Technology LLC Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials
US10696906B2 (en) 2017-09-29 2020-06-30 Marathon Petroleum Company Lp Tower bottoms coke catching device
US12000720B2 (en) 2018-09-10 2024-06-04 Marathon Petroleum Company Lp Product inventory monitoring
US10597594B1 (en) 2018-11-27 2020-03-24 Exxonmobil Research And Engineering Company Low sulfur marine fuel compositions
US10781391B2 (en) 2018-11-27 2020-09-22 Exxonmobil Research And Engineering Company Low sulfur marine fuel compositions
US10443006B1 (en) 2018-11-27 2019-10-15 Exxonmobil Research And Engineering Company Low sulfur marine fuel compositions
US11975316B2 (en) 2019-05-09 2024-05-07 Marathon Petroleum Company Lp Methods and reforming systems for re-dispersing platinum on reforming catalyst
SG11202111706PA (en) * 2019-05-15 2021-11-29 Steeper Energy Aps Low sulphur fuel blend of hydrocarbon containing fuels and method for producing such blend
FR3103822B1 (en) * 2019-12-02 2022-07-01 Ifp Energies Now METHOD FOR TREATMENT OF PYROLYSIS OILS FROM PLASTICS WITH A VIEW TO RECYCLING THEM IN A STEAM CRACKING UNIT
CA3109675A1 (en) 2020-02-19 2021-08-19 Marathon Petroleum Company Lp Low sulfur fuel oil blends for stability enhancement and associated methods
FR3107530B1 (en) * 2020-02-21 2022-02-11 Ifp Energies Now OPTIMIZED PROCESS FOR THE TREATMENT OF PLASTICS PYROLYSIS OILS WITH A VIEW TO THEIR RECOVERY
US20220268694A1 (en) 2021-02-25 2022-08-25 Marathon Petroleum Company Lp Methods and assemblies for determining and using standardized spectral responses for calibration of spectroscopic analyzers
US11905468B2 (en) 2021-02-25 2024-02-20 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11898109B2 (en) 2021-02-25 2024-02-13 Marathon Petroleum Company Lp Assemblies and methods for enhancing control of hydrotreating and fluid catalytic cracking (FCC) processes using spectroscopic analyzers
US11692141B2 (en) 2021-10-10 2023-07-04 Marathon Petroleum Company Lp Methods and systems for enhancing processing of hydrocarbons in a fluid catalytic cracking unit using a renewable additive
CA3188122A1 (en) 2022-01-31 2023-07-31 Marathon Petroleum Company Lp Systems and methods for reducing rendered fats pour point

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005105961A1 (en) * 2004-04-28 2005-11-10 Sasol Technology (Pty) Ltd Crude oil derived and gas-to-liquids diesel fuel blends
US20050288537A1 (en) * 2004-06-29 2005-12-29 Conocophillips Company Blending for density specifications using Fischer-Tropsch diesel fuel
US20080302001A1 (en) * 2007-06-11 2008-12-11 Neste Oil Oyj Process for producing branched hydrocarbons
US20090151233A1 (en) * 2007-12-12 2009-06-18 Chevron U.S.A. Inc. System and method for producing transportation fuels from waste plastic and biomass
WO2009088454A1 (en) * 2007-12-31 2009-07-16 Exxonmobil Research And Engineering Company Integrated two-stage desulfurization/dewaxing with stripping high-temperature separator

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4308411A (en) 1980-08-28 1981-12-29 Occidental Research Corporation Process for converting oxygenated hydrocarbons into hydrocarbons
US5149680A (en) 1987-03-31 1992-09-22 The British Petroleum Company P.L.C. Platinum group metal alloy catalysts for hydrogenation of carboxylic acids and their anhydrides to alcohols and/or esters
US7513989B1 (en) 1997-07-15 2009-04-07 Exxonmobil Research And Engineering Company Hydrocracking process using bulk group VIII/Group VIB catalysts
US7288182B1 (en) 1997-07-15 2007-10-30 Exxonmobil Research And Engineering Company Hydroprocessing using bulk Group VIII/Group VIB catalysts
US7435335B1 (en) 1998-12-08 2008-10-14 Exxonmobil Research And Engineering Company Production of low sulfur distillates
CA2407066A1 (en) 2000-04-18 2001-10-25 Exxonmobil Research And Engineering Company Selective hydroprocessing and mercaptan removal
US20050218039A1 (en) * 2002-03-25 2005-10-06 Kalnes Tom N Hydrocarbon desulfurization process
US7220352B2 (en) 2002-04-02 2007-05-22 Exxonmobil Research And Engineering Company Selective hydrodesulfurization of naphtha streams
US7288181B2 (en) 2003-08-01 2007-10-30 Exxonmobil Research And Engineering Company Producing low sulfur naphtha products through improved olefin isomerization
US7425657B1 (en) 2007-06-06 2008-09-16 Battelle Memorial Institute Palladium catalyzed hydrogenation of bio-oils and organic compounds
US8158842B2 (en) * 2007-06-15 2012-04-17 Uop Llc Production of chemicals from pyrolysis oil
WO2009018531A1 (en) * 2007-08-01 2009-02-05 Virginia Tech Intellectual Properties, Inc. Fractional catalytic pyrolysis of biomass
US7794585B2 (en) * 2007-10-15 2010-09-14 Uop Llc Hydrocarbon conversion process
AU2009233957B2 (en) 2008-04-06 2013-09-26 Battelle Memorial Institute Fuel and fuel blending components from biomass derived pyrolysis oil
US9290703B2 (en) * 2010-04-23 2016-03-22 Exxonmobil Research And Engineering Company Low pressure production of low cloud point diesel

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005105961A1 (en) * 2004-04-28 2005-11-10 Sasol Technology (Pty) Ltd Crude oil derived and gas-to-liquids diesel fuel blends
US20050288537A1 (en) * 2004-06-29 2005-12-29 Conocophillips Company Blending for density specifications using Fischer-Tropsch diesel fuel
US20080302001A1 (en) * 2007-06-11 2008-12-11 Neste Oil Oyj Process for producing branched hydrocarbons
US20090151233A1 (en) * 2007-12-12 2009-06-18 Chevron U.S.A. Inc. System and method for producing transportation fuels from waste plastic and biomass
WO2009088454A1 (en) * 2007-12-31 2009-07-16 Exxonmobil Research And Engineering Company Integrated two-stage desulfurization/dewaxing with stripping high-temperature separator

Also Published As

Publication number Publication date
WO2011143397A2 (en) 2011-11-17
CN102884159A (en) 2013-01-16
CA2798714A1 (en) 2011-11-17
SG184443A1 (en) 2012-11-29
AU2011253089A1 (en) 2012-12-06
EP2569398A2 (en) 2013-03-20
US20110277377A1 (en) 2011-11-17

Similar Documents

Publication Publication Date Title
WO2011143397A3 (en) Hydroprocessing of pyrolysis oil and its use as a fuel
WO2012092046A3 (en) Pretreatment of fats and oils in the production of biofuels
MY149322A (en) A biofuel composition, process of preparation and a method of fueling thereof
HRP20190597T1 (en) Methods for renewable fuel
MX2018002109A (en) Fuels and fuel additives that have high biogenic content derived from renewable organic feedstock.
WO2012061005A3 (en) Hydrocarbons from pyrolysis oil
WO2009126508A3 (en) Fuel and fuel blending components from biomass derived pyrolysis oil
WO2010039693A3 (en) Co-processing diesel fuel with vegetable oil to generate a low cloud point hybrid diesel biofuel
WO2010074923A3 (en) Production of fuel from co-processing multiple renewable feedstocks
WO2012058218A3 (en) Process for producing high quality pyrolysis oil from biomass
WO2008157226A3 (en) Engineered plant biomass with increased oil production
WO2012057986A3 (en) Production of renewable bio-gasoline
CA3009991A1 (en) Chemicals and fuel blendstocks by a catalytic fast pyrolysis process
FI125844B (en) Process for producing hydrocarbons
WO2012109035A3 (en) Stable bio-oil
WO2009039015A3 (en) Methods for refining hydrocarbon feedstocks
WO2010074756A3 (en) Co-processing of diesel biofeed and heavy oil
WO2012012260A3 (en) Low water biomass-derived pyrolysis oils and processes for producing the same
WO2009117337A3 (en) Production of transportation fuel from renewable feedstocks
DE602009000211D1 (en) Process for removing tar from synthesis gas
NZ599954A (en) Methods for producing hydrocarbon products from bio-oils and/or coal -oils
WO2010046746A3 (en) Hydrocarbon composition useful as fuel and combustible obtained from oil components and a biological component
WO2013049665A3 (en) Process for producing a refinery stream compatible bio -oil from a lignocellulosic feedstock
WO2013033580A3 (en) Hydroprocessed product
WO2012136981A3 (en) Oil absorbent composition

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 201180023021.X

Country of ref document: CN

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 11721194

Country of ref document: EP

Kind code of ref document: A2

ENP Entry into the national phase

Ref document number: 2798714

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2011721194

Country of ref document: EP

ENP Entry into the national phase

Ref document number: 2011253089

Country of ref document: AU

Date of ref document: 20110512

Kind code of ref document: A