WO2013049665A3 - Process for producing a refinery stream compatible bio -oil from a lignocellulosic feedstock - Google Patents

Process for producing a refinery stream compatible bio -oil from a lignocellulosic feedstock Download PDF

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Publication number
WO2013049665A3
WO2013049665A3 PCT/US2012/058049 US2012058049W WO2013049665A3 WO 2013049665 A3 WO2013049665 A3 WO 2013049665A3 US 2012058049 W US2012058049 W US 2012058049W WO 2013049665 A3 WO2013049665 A3 WO 2013049665A3
Authority
WO
WIPO (PCT)
Prior art keywords
oil
oxygen content
bio
producing
lignocellulosic feedstock
Prior art date
Application number
PCT/US2012/058049
Other languages
French (fr)
Other versions
WO2013049665A2 (en
Inventor
Douglas G. Naae
Jason C. Hicks
Jerome F. Mayer
Horacio Trevino
Jose VILLEGAS
Original Assignee
Chevron U.S.A., Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chevron U.S.A., Inc. filed Critical Chevron U.S.A., Inc.
Priority to CA2850510A priority Critical patent/CA2850510A1/en
Publication of WO2013049665A2 publication Critical patent/WO2013049665A2/en
Publication of WO2013049665A3 publication Critical patent/WO2013049665A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • C10B53/02—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of cellulose-containing material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/40—Thermal non-catalytic treatment
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
    • C10C5/00—Production of pyroligneous acid distillation of wood, dry distillation of organic waste
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C10G2300/203—Naphthenic acids, TAN
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y02P20/145—Feedstock the feedstock being materials of biological origin
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

In one aspect, a method for rendering biomass-derived pyrolysis oil miscible with refinery hydrocarbons comprises mixing a high oxygen content bio-oil having an oxygen content of at least about 10 wt. % with a low oxygen content bio-oil having an oxygen content of less than about 8 wt. % to produce a blended oil. The blended oil may be hydrotreated to produce a deoxygenated hydrotreated mixture from which water is removed using a separator, resulting in a low oxygen content hybrid bio-oil intermediate miscible in refinery process streams. A portion of the low oxygen content hybrid bio-oil intermediate may be recycled with the high oxygen content bio-oil or removed for use in a refinery process stream for further hydroprocessing.
PCT/US2012/058049 2011-09-30 2012-09-28 Process for producing a refinery stream-compatible bio-oil from a lignocellulosic feedstock WO2013049665A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CA2850510A CA2850510A1 (en) 2011-09-30 2012-09-28 Process for producing a refinery stream-compatible bio-oil from a lignocellulosic feedstock

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201161542083P 2011-09-30 2011-09-30
US61/542,083 2011-09-30

Publications (2)

Publication Number Publication Date
WO2013049665A2 WO2013049665A2 (en) 2013-04-04
WO2013049665A3 true WO2013049665A3 (en) 2013-05-23

Family

ID=47040817

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2012/058049 WO2013049665A2 (en) 2011-09-30 2012-09-28 Process for producing a refinery stream-compatible bio-oil from a lignocellulosic feedstock

Country Status (3)

Country Link
US (1) US20130212930A1 (en)
CA (1) CA2850510A1 (en)
WO (1) WO2013049665A2 (en)

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EP2007744B1 (en) 2006-04-03 2017-05-17 Pharmatherm Chemicals Inc. Thermal extraction method for producing a taxane extract
US20110284359A1 (en) 2010-05-20 2011-11-24 Uop Llc Processes for controlling afterburn in a reheater and for controlling loss of entrained solid particles in combustion product flue gas
US8499702B2 (en) 2010-07-15 2013-08-06 Ensyn Renewables, Inc. Char-handling processes in a pyrolysis system
US9441887B2 (en) 2011-02-22 2016-09-13 Ensyn Renewables, Inc. Heat removal and recovery in biomass pyrolysis
US9347005B2 (en) 2011-09-13 2016-05-24 Ensyn Renewables, Inc. Methods and apparatuses for rapid thermal processing of carbonaceous material
US10400175B2 (en) 2011-09-22 2019-09-03 Ensyn Renewables, Inc. Apparatuses and methods for controlling heat for rapid thermal processing of carbonaceous material
US9109177B2 (en) 2011-12-12 2015-08-18 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US9206365B2 (en) * 2012-01-10 2015-12-08 Kior, Llc Fungible bio-oil
US9670413B2 (en) 2012-06-28 2017-06-06 Ensyn Renewables, Inc. Methods and apparatuses for thermally converting biomass
US10633606B2 (en) 2012-12-10 2020-04-28 Ensyn Renewables, Inc. Systems and methods for renewable fuel
US20150159093A1 (en) * 2013-12-10 2015-06-11 Uop Llc Methods and systems for deoxygenating biomass-derived pyrolysis oil with a recycle column
WO2015095498A1 (en) * 2013-12-18 2015-06-25 Battelle Memorial Institute Lignin-enriched biomass pyrolysis
CN104711001B (en) * 2015-03-23 2017-01-11 华中科技大学 Wood vinegar vapor condensation and dehydration treatment method and wood vinegar vapor condensation and dehydration treatment equipment
CA2984198A1 (en) * 2015-04-30 2016-11-03 Domenico TANFOGLIO Pyrolysis furnace
EP3337966B1 (en) 2015-08-21 2021-12-15 Ensyn Renewables, Inc. Liquid biomass heating system
WO2018026907A1 (en) * 2016-08-02 2018-02-08 Chevron U.S.A. Inc. Surfactant compositions
BR112019013387B1 (en) 2016-12-29 2023-03-28 Ensyn Renewables, Inc DEMETALIZATION OF BIOMASS
US11401474B2 (en) * 2017-04-13 2022-08-02 Alliance For Sustainable Energy, Llc Systems and methods for producing fuel intermediates
CN112964595B (en) * 2021-02-20 2023-07-14 辽宁科技大学 Method for measuring water content in biomass pyrolysis oil or biomass and coal co-pyrolysis oil

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WO2010088486A1 (en) * 2009-01-29 2010-08-05 Kior Inc. Selective upgrading of bio-crude
US20110119994A1 (en) * 2009-11-24 2011-05-26 Johannes Antonius Hogendoorn Process for catalytic hydrotreatment of a pyrolysis oil
US20110283601A1 (en) * 2010-05-18 2011-11-24 Kior, Inc. Biomass pyrolysis conversion process with high olefin production and upgrade

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Publication number Publication date
WO2013049665A2 (en) 2013-04-04
US20130212930A1 (en) 2013-08-22
CA2850510A1 (en) 2013-04-04

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