WO2011138620A1 - Aerosol compositions - Google Patents
Aerosol compositions Download PDFInfo
- Publication number
- WO2011138620A1 WO2011138620A1 PCT/GB2011/050886 GB2011050886W WO2011138620A1 WO 2011138620 A1 WO2011138620 A1 WO 2011138620A1 GB 2011050886 W GB2011050886 W GB 2011050886W WO 2011138620 A1 WO2011138620 A1 WO 2011138620A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- aerosol
- canister
- corrosion
- water
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 69
- 239000000443 aerosol Substances 0.000 title claims abstract description 45
- 239000003380 propellant Substances 0.000 claims abstract description 31
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003205 fragrance Substances 0.000 claims abstract description 16
- 239000003755 preservative agent Substances 0.000 claims abstract description 15
- 230000002335 preservative effect Effects 0.000 claims abstract description 15
- 239000004094 surface-active agent Substances 0.000 claims abstract description 15
- 150000001642 boronic acid derivatives Chemical class 0.000 claims abstract description 12
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 238000005260 corrosion Methods 0.000 claims description 32
- 230000007797 corrosion Effects 0.000 claims description 30
- 229910000831 Steel Inorganic materials 0.000 claims description 20
- 239000010959 steel Substances 0.000 claims description 20
- 239000007789 gas Substances 0.000 claims description 16
- 229910052751 metal Inorganic materials 0.000 claims description 16
- 239000002184 metal Substances 0.000 claims description 16
- 229910021538 borax Inorganic materials 0.000 claims description 13
- 235000015393 sodium molybdate Nutrition 0.000 claims description 13
- 239000011684 sodium molybdate Substances 0.000 claims description 13
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 13
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 13
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 claims description 13
- 239000002386 air freshener Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- 239000004479 aerosol dispenser Substances 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000001419 dependent effect Effects 0.000 claims 1
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 10
- 239000003112 inhibitor Substances 0.000 description 8
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 8
- 239000004411 aluminium Substances 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 238000009472 formulation Methods 0.000 description 6
- 239000005028 tinplate Substances 0.000 description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 235000010288 sodium nitrite Nutrition 0.000 description 4
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- -1 polishes Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 2
- JQYHQFPJDPCKMM-UHFFFAOYSA-N OOO.[Sn] Chemical compound OOO.[Sn] JQYHQFPJDPCKMM-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000001593 sorbitan monooleate Substances 0.000 description 2
- 229940035049 sorbitan monooleate Drugs 0.000 description 2
- 235000011069 sorbitan monooleate Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000011362 coarse particle Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000004005 nitrosamines Chemical class 0.000 description 1
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 108700004121 sarkosyl Proteins 0.000 description 1
- 229940045885 sodium lauroyl sarcosinate Drugs 0.000 description 1
- KSAVQLQVUXSOCR-UHFFFAOYSA-M sodium lauroyl sarcosinate Chemical compound [Na+].CCCCCCCCCCCC(=O)N(C)CC([O-])=O KSAVQLQVUXSOCR-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
- C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
- C23F11/18—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using inorganic inhibitors
- C23F11/182—Sulfur, boron or silicon containing compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/14—Disinfection, sterilisation or deodorisation of air using sprayed or atomised substances including air-liquid contact processes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/30—Materials not provided for elsewhere for aerosols
Definitions
- the present invention relates to household aerosol compositions using a compressed gas propellant that are free of hydrocarbon propellants, and particularly the use of such compositions with metal aerosol canister that are capable of corrosion.
- Examples of household aerosol products are air fresheners, car products, household products, fabric care, waxes, polishes, insecticides, ironing aids, fabric refreshers, and carpet cleaners.
- Tinplating protects the metal canisters against rapid corrosion, but tends itself to dissolve in aqueous based formulations.
- aerosol formulations containing less than 50 ppm of water corrosion of tinplated canisters is not generally a serious problem.
- water content of an aerosol product is more than 50 ppm (and particularly when greater than 150 ppm), problems due to corrosion are more likely to occur.
- VOC volatile organic content
- non-VOC propellant such as compressed gas (compressed gas referring to compressed air, compressed nitrogen or mixtures thereof) since this is of less impact to the environment, less expensive than VOC propellant and safer to handle from a manufacturing perspective as well as a consumer perspective due to the likely reduction in flammability.
- the common 'wet' (i.e. water rather than solvent based) air freshener aerosol compositions using VOC propellants typically contain nitrite as a corrosion inhibitor and sorbitan monooleate as an emulsifier to ensure uniform emulsification of water soluble and oily components such as water insoluble fragrance.
- the best recognised inhibitor system for tin-plated canisters is sodium nitrite and morpholine. Morpholine is a volatile base that helps to preserve the vapour phase in the aerosol containers and gives an alkaline pH to the formula. This system can involve the formation of nitrosamines that are very carcinogenic.
- sodium nitrite and morpholine are not generally able to prevent the dissolution of the tin coating, but to reduce the rate of dissolution of the tin coating to an acceptable level in VOC propellant systems.
- the amount of morpholine, sodium nitrite and thickness of tin plate are designed for around the required shelf life, for example two years.
- the dissolution of the tin plate to form a tin hydroxyl-oxide complex has been shown to have a negative effect on cleaning performances.
- the tin complex generally gives a pale yellow to an intense yellow colour when deposited, especially when sprayed onto a white surface.
- White fabrics or carpets can remain coloured by the liquids of aged aerosol products.
- Other considerations relate to certain stains like coffee, tea and wine that contain cationic metals. These metals can form brown coloured complex with tin hydroxyl-oxide complex, causing an evident negative effect of the cleaning formulation and its overall cleaning performance.
- an aerosol composition with compressed gas propellant that is free of hydrocarbon propellants, wherein the composition comprises:
- composition is an air freshening composition.
- the composition further comprises 0.00wt% to 0.5wt% sodium molybdate, and even more preferably comprises 0.0wt% to 0.1wt% sodium molybdate.
- the composition comprises:
- composition consists essentially of:
- composition consists essentially of:
- the compressed gas propellant used with the composition is preferably compressed air or compressed nitrogen or a mixture thereof.
- the borate salt for use in the compositions of the present invention is preferably sodium borate, although other commercially available borate salts may be used either alone or in combination with sodium borate.
- the low MW alcohol for use in the compositions of the present invention is preferably ethanol, although other commercially available low MW alcohols may be used either alone or in combination with ethanol.
- an aerosol dispenser wherein the dispenser is a steel aerosol canister, tin-plated steel canister or other metal canister capable of corrosion and wherein the composition is an air freshener propelled, in use, by compressed gas propellant that is free of hydrocarbon propellants, the air freshener composition comprising:
- corrosion is understood in the context of the present invention to refer to the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings, in particular in the context of metal canisters corrosion means electrochemical oxidation of the metal canister in reaction with an oxidant such as oxygen.
- the dispenser is a steel aerosol canister or a tin-plate steel aerosol canister.
- the composition further comprises 0.00wt% to 0.5wt% sodium molybdate, and even more preferably comprises 0.0wt% to 0.1 wt% sodium molybdate.
- an anti-corrosion air freshening composition for use with a compressed gas propellant in a steel aerosol canister, tin-plated steel canister or other metal canister capable of corrosion wherein the composition comprises:
- the dispenser is a steel aerosol canister or a tin-plate steel aerosol canister.
- the composition further comprises 0.00wt% to 0.5wt% sodium molybdate, and even more preferably comprises 0.0wt% to 0.1wt% sodium molybdate.
- the surfactant(s) used in the composition(s) of the present invention are preferably a non- ionic surfactant. More preferably the non-ionic surfactant(s) are ethoxylates of fatty alcohols, most preferably saturated C 8- 2o alcohols and the like, and most preferably saturated iso-C 13 alcohols such as those available from BASF under their LUTENSOL® brand of surfactants.
- the preservative(s) used in the composition(s) of the present invention are preferably formed from lox toxicity biocides suitable for use in water-based canister systems such as
- a fourth aspect of the present invention there is provided a method of preventing corrosion of a metal aerosol canister capable of corrosion wherein the method involves the step of introducing a composition according to the first or third aspect of the present invention into said aerosol container along with a compressed gas propellant that is free of hydrocarbon propellants.
- Example 1 Two example formulations were prepared as set out below.
- Example 1 Two example formulations were prepared as set out below.
- wt% of the composition adds up to exactly 100wt%.
- Each sample was then loaded into a tin-plated steel aerosol canister having a 15 bar pressure rating and filled with compressed air until the internal pressure within the canister reached 9.0 bar @ 20°C.
- Samples of examples 1 & 2 were then held in a secure storage container at respective constant temperatures of 20°C, 30°C and 40°C for a period of 10 weeks and then tested for spray performance and, once exhausted, corrosion. All samples of examples 1 & 2 at all temperatures showed no signs of impairment after the storage, they all sprayed within consumer acceptable spray performance parameters and no canisters showed any signs of corrosion therein.
Landscapes
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Dispersion Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
- Cosmetics (AREA)
Priority Applications (8)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA2797339A CA2797339A1 (en) | 2010-05-07 | 2011-05-09 | Aerosol compositions |
| KR1020127031748A KR20130101445A (ko) | 2010-05-07 | 2011-05-09 | 에어로졸 조성물 |
| RU2012152655/15A RU2012152655A (ru) | 2010-05-07 | 2011-05-09 | Аэрозольные композиции |
| MX2012012968A MX2012012968A (es) | 2010-05-07 | 2011-05-09 | Composiciones en aerosol. |
| US13/643,601 US20130090283A1 (en) | 2010-05-07 | 2011-05-09 | Aerosol Compositions |
| BR112012028456A BR112012028456A2 (pt) | 2010-05-07 | 2011-05-09 | composições de aerossol |
| EP11720840A EP2566525A1 (en) | 2010-05-07 | 2011-05-09 | Aerosol compositions |
| ZA2012/08127A ZA201208127B (en) | 2010-05-07 | 2012-10-29 | Aerosol compositions |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB1007660.2A GB2480103B (en) | 2010-05-07 | 2010-05-07 | Aerosol compositions |
| GB1007660.2 | 2010-05-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011138620A1 true WO2011138620A1 (en) | 2011-11-10 |
Family
ID=42314983
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB2011/050886 WO2011138620A1 (en) | 2010-05-07 | 2011-05-09 | Aerosol compositions |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US20130090283A1 (pt) |
| EP (1) | EP2566525A1 (pt) |
| KR (1) | KR20130101445A (pt) |
| AU (1) | AU2011101757A4 (pt) |
| BR (1) | BR112012028456A2 (pt) |
| CA (1) | CA2797339A1 (pt) |
| GB (1) | GB2480103B (pt) |
| MX (1) | MX2012012968A (pt) |
| RU (1) | RU2012152655A (pt) |
| WO (1) | WO2011138620A1 (pt) |
| ZA (1) | ZA201208127B (pt) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012089842A2 (en) | 2010-12-31 | 2012-07-05 | Direvo Industrial Biotechnology Gmbh | Improved production processes of haematococcus cell components |
| WO2012089843A2 (en) | 2010-12-31 | 2012-07-05 | Direvo Industrial Biotechnology Gmbh | Extraction of scenedesmus cell components |
| US8927474B2 (en) | 2012-03-16 | 2015-01-06 | S.C. Johnson & Son, Inc. | Compressed gas aerosol composition in steel can |
| WO2017015273A1 (en) * | 2015-07-20 | 2017-01-26 | S.C. Johnson & Son, Inc. | Water-based fragrance composition, fragrance delivery device, and method of providing a long-lasting scent |
| WO2018007785A1 (en) * | 2016-07-06 | 2018-01-11 | Reckitt Benckiser (Brands) Limited | Air freshening formulation |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106456815A (zh) | 2014-03-28 | 2017-02-22 | 约翰逊父子公司 | 泵式浓缩空气清新剂 |
| US20150335778A1 (en) * | 2014-05-21 | 2015-11-26 | The Procter & Gamble Company | Freshening product comprising an aqueous perfume composition contained in a pressurized plastic container |
| US20180044525A1 (en) | 2015-02-27 | 2018-02-15 | Cargill, Incorporated | Polymerized oils & methods of manufacturing the same |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010044392A1 (en) * | 1994-08-12 | 2001-11-22 | The Procter & Gamble Company | Method for reducing malodor impression on inanimate surfaces |
| WO2006005007A1 (en) * | 2004-06-30 | 2006-01-12 | The Procter & Gamble Company | Method of freshening air |
| US20090020621A1 (en) * | 2007-07-17 | 2009-01-22 | S.C. Johnson & Son, Inc. | Aerosol dispenser assembly haveing voc-free propellant and dispensing mechanism therefor |
| EP2047869A1 (en) * | 2007-10-11 | 2009-04-15 | Reckitt Benckiser (UK) LIMITED | Aerosol compositions |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7041279B1 (en) * | 1999-11-01 | 2006-05-09 | The Clorox Company | Method and product for mitigating pet malodors |
| GB2380231A (en) * | 2001-09-26 | 2003-04-02 | Reckitt Benckiser Nv | Corrosion inhibitors for tin plated aerosol canisters |
| US20040144406A1 (en) * | 2003-01-16 | 2004-07-29 | Aram Garabedian | Dry aerosol carpet cleaning process |
| US8465728B2 (en) * | 2005-06-28 | 2013-06-18 | S.C. Johnson & Son, Inc. | Composition and aerosol spray dispenser for eliminating odors in air |
| US20090202446A1 (en) * | 2006-05-03 | 2009-08-13 | Florin Joseph Vlad | Microemulsion composition for air freshener |
-
2010
- 2010-05-07 GB GB1007660.2A patent/GB2480103B/en active Active
-
2011
- 2011-05-09 EP EP11720840A patent/EP2566525A1/en not_active Withdrawn
- 2011-05-09 RU RU2012152655/15A patent/RU2012152655A/ru unknown
- 2011-05-09 US US13/643,601 patent/US20130090283A1/en not_active Abandoned
- 2011-05-09 WO PCT/GB2011/050886 patent/WO2011138620A1/en active Application Filing
- 2011-05-09 KR KR1020127031748A patent/KR20130101445A/ko not_active Application Discontinuation
- 2011-05-09 BR BR112012028456A patent/BR112012028456A2/pt not_active IP Right Cessation
- 2011-05-09 MX MX2012012968A patent/MX2012012968A/es not_active Application Discontinuation
- 2011-05-09 CA CA2797339A patent/CA2797339A1/en not_active Abandoned
- 2011-05-09 AU AU2011101757A patent/AU2011101757A4/en not_active Expired
-
2012
- 2012-10-29 ZA ZA2012/08127A patent/ZA201208127B/en unknown
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20010044392A1 (en) * | 1994-08-12 | 2001-11-22 | The Procter & Gamble Company | Method for reducing malodor impression on inanimate surfaces |
| WO2006005007A1 (en) * | 2004-06-30 | 2006-01-12 | The Procter & Gamble Company | Method of freshening air |
| US20090020621A1 (en) * | 2007-07-17 | 2009-01-22 | S.C. Johnson & Son, Inc. | Aerosol dispenser assembly haveing voc-free propellant and dispensing mechanism therefor |
| EP2047869A1 (en) * | 2007-10-11 | 2009-04-15 | Reckitt Benckiser (UK) LIMITED | Aerosol compositions |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012089842A2 (en) | 2010-12-31 | 2012-07-05 | Direvo Industrial Biotechnology Gmbh | Improved production processes of haematococcus cell components |
| WO2012089841A1 (en) | 2010-12-31 | 2012-07-05 | Direvo Industrial Biotechnology Gmbh | Novel algae extraction methods |
| WO2012089843A2 (en) | 2010-12-31 | 2012-07-05 | Direvo Industrial Biotechnology Gmbh | Extraction of scenedesmus cell components |
| US8927474B2 (en) | 2012-03-16 | 2015-01-06 | S.C. Johnson & Son, Inc. | Compressed gas aerosol composition in steel can |
| EP2825696B1 (en) | 2012-03-16 | 2021-05-26 | S.C. Johnson & Son, Inc. | Compressed gas aerosol composition in steel can |
| CN108025097A (zh) * | 2015-07-20 | 2018-05-11 | 约翰逊父子公司 | 水基香料组合物，香料传递装置及提供持久气味的方法 |
| JP2018522014A (ja) * | 2015-07-20 | 2018-08-09 | エス．シー． ジョンソン アンド サン、インコーポレイテッド | 水系香料組成物、香料送達装置、及び長持ちする香りを提供する方法 |
| US10610611B2 (en) | 2015-07-20 | 2020-04-07 | S. C. Johnson & Son, Inc. | Water-based fragrance composition, fragrance delivery device, and method of providing a long-lasting scent |
| WO2017015273A1 (en) * | 2015-07-20 | 2017-01-26 | S.C. Johnson & Son, Inc. | Water-based fragrance composition, fragrance delivery device, and method of providing a long-lasting scent |
| WO2018007785A1 (en) * | 2016-07-06 | 2018-01-11 | Reckitt Benckiser (Brands) Limited | Air freshening formulation |
| CN109414522A (zh) * | 2016-07-06 | 2019-03-01 | 雷克特本克斯尔(品牌)有限公司 | 空气清新制剂 |
| AU2017294133B2 (en) * | 2016-07-06 | 2021-08-19 | Reckitt Benckiser (Brands) Limited | Air freshening formulation |
| US11452790B2 (en) | 2016-07-06 | 2022-09-27 | Reckitt Benckiser (Brands) Limited | Air freshening formulation |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2480103B (en) | 2012-10-10 |
| GB201007660D0 (en) | 2010-06-23 |
| RU2012152655A (ru) | 2014-06-20 |
| CA2797339A1 (en) | 2011-11-10 |
| BR112012028456A2 (pt) | 2015-09-22 |
| GB2480103A (en) | 2011-11-09 |
| ZA201208127B (en) | 2013-12-23 |
| EP2566525A1 (en) | 2013-03-13 |
| US20130090283A1 (en) | 2013-04-11 |
| MX2012012968A (es) | 2012-12-17 |
| AU2011101757A4 (en) | 2015-05-28 |
| KR20130101445A (ko) | 2013-09-13 |
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