WO2011077141A1 - Enhancing the disintegration and/or degradation of a smoking article - Google Patents

Enhancing the disintegration and/or degradation of a smoking article Download PDF

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Publication number
WO2011077141A1
WO2011077141A1 PCT/GB2010/052177 GB2010052177W WO2011077141A1 WO 2011077141 A1 WO2011077141 A1 WO 2011077141A1 GB 2010052177 W GB2010052177 W GB 2010052177W WO 2011077141 A1 WO2011077141 A1 WO 2011077141A1
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WO
WIPO (PCT)
Prior art keywords
filter
smoking article
capsule
liquid
degradation
Prior art date
Application number
PCT/GB2010/052177
Other languages
English (en)
French (fr)
Inventor
David Rushforth
Original Assignee
British American Tobacco (Investments) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British American Tobacco (Investments) Limited filed Critical British American Tobacco (Investments) Limited
Priority to MX2012006678A priority Critical patent/MX2012006678A/es
Priority to EP10803475A priority patent/EP2515688A1/en
Priority to AU2010334634A priority patent/AU2010334634A1/en
Priority to CA2784479A priority patent/CA2784479C/en
Priority to UAA201208616A priority patent/UA103712C2/uk
Priority to BR112012015710A priority patent/BR112012015710A2/pt
Priority to US13/518,352 priority patent/US20130047999A1/en
Priority to JP2012545446A priority patent/JP2013514802A/ja
Priority to CN2010800644278A priority patent/CN102781265A/zh
Priority to RU2012131045/12A priority patent/RU2012131045A/ru
Publication of WO2011077141A1 publication Critical patent/WO2011077141A1/en

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Classifications

    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
    • A—HUMAN NECESSITIES
    • A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06—Use of materials for tobacco smoke filters
    • A24D3/067—Use of materials for tobacco smoke filters characterised by functional properties
    • A24D3/068—Biodegradable or disintegrable

Definitions

  • the invention relates to enhancing the disintegration and/or degradation of used smoking articles, and particularly, but not exclusively, to enhancing the
  • the spent smoking article During smoking most of the tobacco rod and its circumscribing paper wrapper are converted to gases and ash in an incineration process.
  • the remaining components of the spent smoking article include a small portion of ash, part of the original tobacco rod and wrapper, and the filter which is made up of the filter plug, plugwrap, and tipping paper wrapped about the tobacco rod and filter.
  • Spent smoking articles are generally completely dissociated into their individual constituent parts within a relatively short period of time when exposed to moisture, and/ or mechanical abrasion. The individual components of the spent smoking articles are thus subsequently able to disperse and degrade.
  • the plug of filter material typically does not readily disperse or degrade.
  • filters are presently formed from highly crimped cellulose acetate fibres bonded at their contact points using plasticizers to provide a significant volume of interstitial space for the passage of smoke.
  • the bonded contact points of such filter elements degrade very slowly under normal environmental conditions.
  • the cellulose acetate fibres are themselves generally poorly biodegradable.
  • improved techniques for producing filters having an enhanced biodegradation rate At the same time, there is also a need to retain the filtration chemistry, smoke characteristics and consumer acceptability provided by currently available smoking article filters.
  • a further problem is that the cellulose acetate tow commonly used as filter material is not readily degradable or biodegradable. Thus, despite efforts to promote the dissociation of the spent smoking article, the filter material itself will not subsequently degrade. Therefore, much of the effort expended to reduce the environmental burden of spent smoking articles or to make such spent smoking articles more environmentally compatible has been directed to improving the biodegradability of the cellulose acetate fibres.
  • Water soluble polymers have been used instead of triacetin which solvent bonds the cellulose acetate fibres typically used to make filters.
  • soluble polymeric materials such as polyvinyl alcohol and ethylene vinyl alcohol copolymers may be used in place of cellulose acetate.
  • a tobacco smoke filter made of a creped paper manufactured from a wood pulp sheet and a tobacco filter made from a regenerated cellulose fibre bundle are also known. Compared with a filter comprising a cellulose acetate fibre bundle, these filters disintegrate slightly more readily when exposed to moisture. While there are clearly environmentally preferable alternatives to cellulose acetate, degradability again generally depends on the presence of moisture, which as mentioned previously, may be scarce in some areas.
  • At least one embodiment of the invention provides a smoking article having enhanced disintegration, dispersion and/or degradation.
  • at least one embodiment of the invention provides a filter for a smoking article which is capable of degrading in the absence of environmental water.
  • a filter for a smoking article which comprises a vehicle containing a liquid capable of enhancing the
  • the vehicle which can be a capsule, may be broken or otherwise actuated to release the liquid immediately prior to disposal of the smoking article, or may be broken or otherwise actuated at a later time following disposal.
  • the vehicle is arranged to be actuated to release the liquid after the smoking article has been smoked.
  • the vehicle can be arranged to be actuated by a longitudinal or bending force acting on the filter, such that, for instance, the action of 'stubbing out' the smoking article acts to release the liquid.
  • the process of actuation of the vehicle to release the liquid may substantially deform the filter.
  • the liquid may enhance the degradation of the smoking article in one or more of the following ways.
  • the various components of the smoking article may be induced by the liquid to dissociate, resulting in their increased exposure to the environment and accelerated dispersion and biodegradation.
  • the degradation of one or more of the components of the smoking article may be directly enhanced by the liquid.
  • the filter may comprise a filter material which may be degraded by the hquid carried in the vehicle.
  • the liquid is released, and the degradation of the filter material is enhanced.
  • a smoking article comprising a filter as described herein is provided.
  • a capsule containing a liquid for enhancing the disintegration and/ or degradation of a smoking article is provided.
  • a method of enhancing the disintegration and/ or degradation of a smoking article wherein the smoking article comprises a capsule containing a hquid capable of enhancing the disintegration and/ or degradation of the smoking article.
  • the present invention provides a filter for use in a smoking article, comprising a vehicle containing a liquid capable of enhancing the disintegration, dispersion and/ or degradation of the smoking article.
  • the vehicle is preferably resistant to manipulation during use of the smoking article, and is intended to be actuated upon disposal of the smoking article to release the liquid contents into the filter.
  • the disintegration and degradation of the filter may occur directly, for example, by the dissolution or dispersion of one or more of the components of the filter, such as the filter material, in the Uquid.
  • the enhancement of degradation may be indirect, for example, as a result of increased environmental exposure resulting from the accelerated dissociation of the filter by the liquid.
  • Figure 1 shows a smoking article 1 comprising a filter 2.
  • the filter 2 comprises two sections of substantially cylindrical filter plug 3, separated by a cavity 6.
  • the filter plug and cavity are wrapped in a plugwrap 4.
  • a capsule 5 comprising a liquid is situated within the cavity 6 of the filter 2.
  • the smoking article further comprises a cylindrical rod of smokeable material 7 aligned with the filter 2 such that the end of the smokeable material rod 7 abuts the end of the filter 2.
  • the rod is wrapped in a paper wrapper 8, and is joined to the filter 2 by tipping paper 9 in a conventional manner.
  • Figure 2 shows an alternative embodiment in which corresponding features have the same reference numerals. This embodiment differs from that shown in Figure 1 in that the capsule 15 is elongate in shape. In addition, rather than being positioned with a cavity within the filter 2, the capsule 15 is embedded within the material of the filter plug 13.
  • the liquid held within the capsule is capable of enhancing the degradation of the smoking article. Consequently, the selection of the Uquid is dependent upon the composition of the materials comprising the remainder of the smoking article and vice-versa.
  • the liquid is water and various components of the smoking article are water-dispersible or wet-degradable to some extent as outlined below. In this way, the degradation of the smoking article is enhanced relative to an identical smoking article lacking a water-containing capsule.
  • the capsule 15 is enclosed within the filter material 13.
  • the filter may be a composite filter comprising multiple filter segments.
  • the filter shown in Figure 1 comprises two sections of filter material 3 separated by a cavity 6, which contains the capsule.
  • the capsule may be located in a cavity formed between the filter material and the rod of smokeable material, or the filter may comprise more than two filter sections, and may even include multiple cavities.
  • the smoking article comprises a single capsule. In alternative embodiments, however, more than one capsule may be used, and in such embodiments, the capsules will generally be held within a cavity section formed in a multi-section filter.
  • the capsule may be inserted into the filter using any suitable method, and various methods of capsule insertion will be known to the skilled person.
  • Suitable apparatus may, for example, include a means for supplying a continuous stream of filter material from a source of such material (e.g., a bale, bobbin, or the like).
  • the apparatus may further include a capsule insertion unit for inserting or depositing the individual capsules at predetermined intervals within the filter material.
  • the filter material having capsules deposited therein may then be received into a rod-making means for providing a continuous rod which may subsequently be subdivided into the desired length at predetermined intervals to form the individual filters of the invention.
  • the capsules are designed to resist breakage only during transport and storage, when the filter is not generally subject to significant external pressure.
  • the capsule is subsequently intended to be ruptured immediately prior to use of the smoking article, and since this is the first exposure of the smoking article to significant manipulation and external pressure, the capsule is not necessarily required to be particularly robust.
  • capsules for use in the invention are intended to be broken after the smoking article has been smoked, and thus are preferably capable of tolerating a significant degree of manipulation as the smoking article is smoked. Consequently, the capsule of the present invention should be more robust than those generally described in the prior art. It is important that the capsule is not accidentally ruptured before the smoking article is ready to be discarded. Such premature rupture could lead to the filtration characteristics of the smoking article being changed and deliveries being thereby altered compared to what is expected.
  • the capsule for use in the present invention may, for example, have a crush strength of between 1.5 and 2.5kp, preferably between 1.7 and 2kp.
  • the capsule may be designed and inserted into the filter in such a way that the capacity to rupture is dependent upon the nature of the pressure exerted. Pressure exerted by the user during smoking will predominantly be exerted by the fingers and mouth to the circumferential surface of the smoking article ("transverse" pressure). In some embodiments of the invention, the capsule is to be relatively resistant to transverse pressure to prevent premature rupture. On the other hand, the stubbing out process is likely to involve the application of "longitudinal" pressure along the length of the smoking article, and consequently the capsule should demonstrate a relatively reduced resistance to breakage in response to longitudinal pressure.
  • This directional capsule resilience may be achieved in a number of ways.
  • the capsule may be elliptical or ovoid and consequently demonstrate an increased resistance to rupture when pressure is exerted in one direction versus another.
  • directional resilience may be achieved using a capsule which has been specifically strengthened in certain areas.
  • Such a capsule may be produced, for example, having an increased shell thickness in selected areas.
  • a similar effect may be achieved by weakening the capsule wall in certain areas, to facilitate breakage or rupture in response to force being applied in a particular manner or direction.
  • the stubbing out process can also involve bending of the filter. Therefore, in some embodiments the capsule is designed to demonstrate increased susceptibility to rupture when the filter is bent or buckled.
  • a long cylindrical capsule may be used which may be ruptured by being snapped.
  • Such elongate capsules will be positioned longitudinally within the filter, so that they are easily bent and ruptured when the filter of the smoking article is stubbed out and bent.
  • the capsule should generally be resistant to the degrading action of the intended contents.
  • the capsule should also comprise material which has a melting point above the temperature of the smoke within the filter.
  • the capsule may exhibit brittleness under stress and/or may comprise a line of weakness, such as a scored line, a brittle point, or a weak section.
  • a piercing means may be incorporated within the filter.
  • the capsule is constructed from a frangible material.
  • the capsule is composed of a low solubility, high molecular weight polyvinyl alcohol.
  • suitable alternative materials are known, and by way of example, capsules typically utilized in the pharmaceutical industry may be used.
  • Such capsules may be gelatin based, for example, or may be formed from a polymeric material, such as modified cellulose.
  • modified cellulose One type of modified cellulose which may be used is hydroxypropylmethyl cellulose.
  • biodegradable materials which may be suitable for use in the production of capsules and these include high molecular weight polyethylene glycols, polylactic acid, plastarch material, polycaprolactone, polyglycolide, a polyhydroxyalkanoate such as poly-3- hydroxybutyrate, and zein-derived bioplastics.
  • the capsule may comprise a length of thin-walled glass tubing, the ends of which may be sealed by heating or with a material capable of withstanding manual handling prior to and during smoking, yet which can be fractured after smoking.
  • suitable materials include thin-walled aluminium tubing or hollow foodstuff material, such as, for example, pasta, or extruded hollow tubing of reconstituted tobacco material.
  • the inner walls of the capsule material may advantageously be coated with a varnish or waterproof material, such as silicone, to preserve the rigidity of the capsule material by preventing absorption of, or degradation by, the liquid contents over a prolonged period.
  • the capsule may alternatively be comprised of a wax, resin, natural or synthetic gum, latex or plastic material which retains its shape and strength at room temperature and at smoking temperature but which fractures to release the liquid contents upon pressure applied to extinguish the smoking article.
  • suitable waxes include beeswax, candelilla, carnauba, Shellac wax, caranday, sugarcane wax, myrtle wax and petroleum wax.
  • Suitable resins include epoxy resins, terpene resins, petroleum resins, ester gum, phenolic resins and rosin based resins.
  • Preferred gums include gum arable, locust bean, guar, alginates, carrageenan and pectin.
  • the substances comprising the capsule have no effect on the taste of the mainstream smoke as smoking occurs.
  • the capsule may be formed in a variety of physical formations including singular part or multipart capsules, large capsules, small capsules, microcapsules, etc.
  • a number of different capsule configurations are suitable for use in the invention; for example, the capsule may be generally spherical (as shown in Figure 1), ovoid, ellipsoidal (as shown in Figure 2), cylindrical, or may approximate to a polygonal prism in shape.
  • the capsule may be coloured.
  • the capsule may comprise a colouring agent.
  • the colouring agent may be used to render more easily the location of the capsule within the filter during the manufacturing process.
  • the colouring agent may provide an interesting and attractive appearance to the smoking article, particularly if the capsule or capsules are intended to be only partially enclosed within the filter material, or if the tipping paper is intended to have a transparent window portion.
  • the liquid held in the capsule may be coloured. This would give the user an additional, visual indication that the hquid has been successfully released and that degradation of the spent smoking article will be enhanced.
  • a coloured liquid also has the added benefit that it could act as an indicator when the capsule is accidentally ruptured before smoking. The colour would be a warning to the smoker that the smoking article has been damaged and should not be smoked.
  • the size of the capsule is clearly dependent on the volume of liquid required, but consideration should be given to the fact that the presence of the capsule in the filter should not have an adverse effect on the filtration or draw characteristics of the filter.
  • the capsule is 5mm in diameter.
  • the diameter of the capsule may be up to 80% of the diameter of the smoking article.
  • the capsule diameter is up to 70%, up to 60%, or up to 50% of the diameter of the smoking article.
  • the diameter of the capsule may be between 2 and 7mm, and preferably the diameter is between 4 and 6mm.
  • the capsule should be large enough to accommodate sufficient contents to enhance the degradation of the smoking article.
  • the volume required will vary according to the nature of the liquid held within the capsule, the composition of the remainder of the smoking article and the associated capacity of the hquid to enhance the degradation of the smoking article.
  • the volume of the capsule may be up to 60%, up to 50%, up to 40%, or up to 30% of the total volume of the filter.
  • the requirement for a large volume of liquid should be balanced, however, with the need to retain sufficient filter material within the filter to provide the required degree of filtration.
  • the volume of the capsule may be as large as possible, as the size of the capsule is increased, the risk of premature breakage of the capsule is also increased.
  • the larger the capsule the greater is the obstruction to the smoke flow path. Consequently, to accommodate the required amount of liquid, it may be preferable for the filter to comprise two, three, four or more capsules.
  • Multiple capsules may be positioned, for example, at regularly spaced intervals along the length of the filter.
  • multiple capsules may be situated as a cluster within the filter, for example within a cavity formed between two sections of filter material.
  • long cylindrical or ellipsoidal capsules or tubes may be used, having a length equal to a significant proportion of the length of the filter, or even equal to the entire length of the filter.
  • Such capsules may be up to 5mm in diameter.
  • Multiple capsules may be used comprising different liquids.
  • the capsule or capsules may be further encapsulated in a second capsule, or a sheath, or the like. This may allow greater protection from accidental or premature breakage, or incidental leakage. In this way, single wall or multi-wall capsules may be used to tailor capsule stability, strength, rupture resistance, processing ease in filter making, etc.
  • the capsule may be manufactured using any suitable method, the method of manufacture of the capsule clearly being dependent on the precise composition and make-up required.
  • Various methods of capsule manufacture will be known to the skilled person, including techniques such as co-extrusion, spin coating,
  • the capsule may be produced using a co-extrusion process.
  • the co-extrusion process is a
  • the first (co-extrusion) step involves forming a droplet having the Hquid core material inside the liquid shell material.
  • the "capsule” is solidified by cooling or by immersion in a curing agent, for example.
  • the capsules may then be subjected to various treatments, such as washing, removal of surplus liquid, colouring, application of additional coatings, etc.
  • annular jet forming technique may be used. This method utilises two concentric jets to eject an inner jet of Uquid core material and an outer jet of liquid shell material. The fluid stream breaks into droplets and the Uquid shell material solidifies by phase transition induced by the presence of cross-linking ions, pH differences, temperature changes, etc.
  • the capsule may be formed, for example, by a method comprising freezing a solution of the Uquid core material until small crystals are formed. According to this method, the crystals are then dropped into molten wax and removed by spatula after a wax coat has formed around the cold crystals. The frozen core material gradually becomes Uquid as the coated capsule reaches room temperature.
  • the capsule may be manufactured in situ.
  • the capsule may be constructed by crimping a continuous tube into filter-length fragments as part of the filter manufacturing process.
  • the Uquid held within the capsule may be any Uquid capable of enhancing the degradation of one or more of the materials comprising the remainder of the smoking article.
  • the nature of the liquid is dependent upon the composition of the materials of the smoking article and vice-versa.
  • the disintegration and/ or degradation of the smoking article may be enhanced in one or more of the following ways.
  • the dissociation of the smoking article may be enhanced, resulting in the individual components having greatly increased exposure to the environment and thus being susceptible to accelerated degradation.
  • the degradation of one or more of the individual components may be directly enhanced, for example one or more of the components may be soluble or otherwise reactive with the liquid held within the capsule.
  • Smoking articles generally comprise a number of different papers (tipping paper, plugwrap, and tobacco wrapping paper) which bind the various components of the smoking article and hold them together.
  • the dispersion of the adhesive which binds these papers, and/ or the papers themselves is enhanced by the action of the liquid in the capsule.
  • the liquid is water
  • the adhesive is a water-soluble or a water-dispersible adhesive
  • the plugwrap and tipping papers comprise moisture disintegrative papers.
  • the liquid may enhance the degradation of the smoking article.
  • the liquid held within the capsule is an aqueous solution, and one or more of the remaining components of the smoking article are in some way water-degradable, for example, composed of water-soluble or water-dispersible material.
  • the liquid within the capsule is water
  • the filter material is a water-soluble or water- dispersible material, such as polyvinyl alcohol.
  • other liquids may be used in the capsule, and clearly the selection of liquid to be used is dependent on the composition of the other components of the smoking article.
  • the preferred hquids for use in the capsule are aqueous solutions, and the most preferred liquid is water. Weak acidic or basic solutions may be used. In general, any liquid may be used that is not potentially toxic or harmful to the user. In case of the accidental premature breakage of the capsule, it is also important that none of the other components of the smoking article degrade to yield products which are potentially toxic or harmful to the user.
  • the liquid may be coloured. This may serve as a visible indication that the capsule has been ruptured, which may be important for two reasons. Firstly, this will inform the user if the capsule is prematurely broken, thus alerting the user that the smoking article should not be smoked. Secondly, when the user is attempting to break the capsule, this will serve as confirmation to the user that the capsule has indeed been satisfactorily ruptured. The interesting possibility of observing a coloured liquid may also serve as an incentive to encourage users to break the capsule upon disposal of the smoking article.
  • the degradation of the smoking article is enhanced by means of a chemical reaction between the liquid and one or more of the remaining components of the smoking article, such as the filter material.
  • the chemical contained within the capsule may be selected to react specifically with the particular component of the smoking article.
  • the chemical may show a less selective capacity to chemically react with and degrade the smoking article, for example the chemical may be a weakly acidic solution.
  • the filter may comprise two or more capsules containing different liquids. The different hquids may react together or otherwise combine to form a liquid capable of enhancing the degradation of the smoking article.
  • different components of the smoking article may be subject to degradation by different liquids.
  • the capsule contains a solution which acts as an attractant to microorganisms, insects, or other organisms.
  • the rate of degradation of the smoking article is effectively enhanced by the action of the living organisms.
  • the capsule may contain an environmentally acceptable aqueous solution of, for example, glucose (or other sugar solution), salt (as a saline solution), or starch (as a thin corn starch syrup).
  • glucose or other sugar solution
  • salt as a saline solution
  • starch as a thin corn starch syrup
  • the capsule is intended to be ruptured upon disposal of the smoking article, and frequently, spent smoking articles are associated with undesired odours. Therefore, in addition to the degrading action, the liquid may additionally possess deodorising qualities. Alternatively, individual degrading and deodorising liquids may be incorporated into the filter in separate capsules, to be ruptured simultaneously.
  • the deodorising agent may be a neutralising agent or a masking agent, or be a combination of neutralising and masking agents.
  • Preferred deodorisers include 2-trans-3,7-dimethyl-2,6-octadien-8-ol (often known as geraniol), 1-carvone, 1-carveol, terpinyl acetate, geranyl propionate, citronellyl butyrate, citral, cis-3-hexenol, triacetin, benzyl benzoate, acetone, safrole, terpinyl propionate, methyl salicylate, hexyl cinnamic aldehyde, isopropyl alcohol, triethylglycol diacetate (TEGDA), OdorGoneTM, methyl cinnamaldehyde, linalyl propionate, acetic acid, citronellal, citronellyl formate, geranyl formate and linalool. Mixtures of these compounds are also suitable. Many other masking agents, such as perfumes, e.g. essential
  • the filter material used in the filters of the vast majority of currently available smoking articles is composed of cellulose acetate fibres and does not readily disintegrate or biodegrade.
  • the filter material of one embodiment of the invention is composed of polyvinyl alcohol.
  • Polyvinyl alcohol is commercially available as a thermoplastic, water soluble, solid polymer that is relatively inexpensive and non-toxic. Polyvinyl alcohol is unique in being the only biodegradable, carbon-carbon backbone polymer capable of complete biodegradation under environmental conditions.
  • the user when the spent smoking article is discarded, the user ruptures the capsule, for example by squeezing the filter, or by stepping on the spent smoking article. This releases the water contained within the capsule, which migrates throughout the filter, and promotes the degradation of the polyvinyl alcohol filter material.
  • water-degradable substances such as starch, ethylene vinyl alcohol copolymers, polylactic acid, creped paper manufactured from a wood pulp sheet, or a regenerated cellulose fibre bundle.
  • the liquid may not act to dissolve the filter material, but may enhance the degradation of the smoking article via some other mechanism.
  • the filter material may be cellulose acetate which has been manufactured using a water-soluble plasticizer to bind the cellulose acetate fibres.
  • the liquid may be water, and other components, such as the plugwrap, tipping paper, and/ or adhesive, may also preferably be water-soluble or water-dispersible. Consequently, rupture of the capsule results in dissociation of the components of the filter, including dispersion or dissolution of the plasticizer.
  • cellulose acetate fibres are no longer bound to one another and the filter material disintegrates and the individual cellulose acetate fibres are able to disperse.
  • non-woven or loose processed cellulose acetate fibres may be used.
  • the filter may further comprise a material or powder which is capable of expansion upon the action of the liquid.
  • a material or powder which is capable of expansion upon the action of the liquid.
  • rupture of the capsule results in expansion of this substance and consequent rupture of the filter.
  • Suitable materials capable of expansion will be known to the skilled person.
  • materials which will swell upon contact with water include carboxymethyl cellulose, water-dispersible starch, chemically modified starch, and super absorbent polymers such as a cross-linked copolymer of acrylic acid and sodium acrylate or a cross-linked copolymer of acrylamide and potassium acrylate.
  • These materials may be incorporated into the filter, for example in powder form, and will swell when exposed to water, for example water from the capsule of the invention.
  • the swelling action physically separates the components of the filter, enhancing disintegration of the structure and dispersion of the components.
  • the liquid may be an aqueous solution comprising biological agents capable of degrading the cellulose, such as cellulase enzymes.
  • the filter material may comprise paper.
  • the liquid may be water, which will not dissolve paper but will nevertheless enhance its disintegration and degradation.
  • Filter materials may be used which are not biodegradable per se but may be disintegrated or converted into a biodegradable form by the action of a particular chemical held within the capsule.
  • flavouring smoking articles is not obviously compatible with the degradable smoking articles described herein, however. This is due to the abundance of capsules that would be required in the filter, and the fact that the flavourant capsules should be ruptured prior to smoking, whereas the capsules of degrading liquid should be broken upon disposal of the spent smoking article.
  • the filter may comprise a thread passing along a longitudinal axis of the filter from the tobacco rod end to the mouth end.
  • the threads are loaded with aromatic or flavourant material.
  • flavourant held within the thread becomes entrained in the smoke.
  • the use of a flavourant-enriched thread also provides a simple means of incorporating flavourant into the smoking article filter, requiring minimal modification of the manufacturing process.
  • flavour refers to materials which may be used to create a desired taste or aroma.
  • Preferred flavourants include extracts (e.g., licorice, hydrangea, Japanese white bark magnolia leaf, chamomile, fenugreek, clove, menthol, Japanese mint, aniseed, cinnamon, herb, wintergreen, cherry, berry, peach, apple, Drambuie, bourbon, scotch, whiskey, spearmint, peppermint, lavender, cardamon, celery, cascarilla, nutmeg, sandalwood, bergamot, geranium, honey essence, rose oil, vanilla, lemon oil, orange oil, cassia, caraway, cognac, jasmine, ylang-ylang, sage, fennel, piment, ginger, anise, coriander, coffee, or a mint oil from any species of the genus Mentha), flavour masking agents,
  • extracts e.g., licorice, hydrangea,
  • the preferred material for the manufacture of the thread is cotton, although other materials such as cellulose acetate and rayon, or natural materials such as plant fibres, may also be used. According to these embodiments, the liquid held within the capsule may be capable of degrading the flavourant-enriched thread.
  • moisture disintegrative papers are used as the plugwrap, tobacco wrapping paper and tipping paper.
  • the capsule is ruptured, water is released, and the degradation of the paper wrappers is enhanced, promoting the dissociation of the smoking article.
  • one or more of the papers used in the smoking article may not be disintegrated by water, but may be otherwise biodegradable.
  • one or more of the papers are not biodegradable per se but may be disintegrated by the action of a particular chemical held within the capsule, such as a weakly acidic solution, for example.
  • the filter comprises a transparent window which allows visualisation of the filter material and/or capsule within the filter.
  • the capsule is held in a cavity formed between two pieces of filter material and the transparent window is aligned with the cavity section of the filter material.
  • the tipping paper may comprise a single piece of transparent material, which can be, but is not limited to, one of polypropylene, polyvinyl chloride (PVC), cellulose acetate film, polyethylene terephthalate (PET), polyethylene oxide (PEOX), polyethylene, cellophane,
  • the tipping paper has an opaque coating on certain portions to leave a transparent uncoated section which defines the window. Since the material will be in contact with moisture from the user's mouth and fingers, the transparent material used is either insoluble, or is treated with a water-resistant external coating. According to these embodiments comprising a transparent material, the liquid held within the capsule may be capable of degrading the transparent material.
  • Adhesive is generally used to bond the seams of the plugwrap, tipping paper, and cigarette paper of a smoking article.
  • water-soluble or water-dispersible adhesives are used. Water released from the capsule when it is ruptured causes loss of the bonding between the various components of the smoking article, resulting in the individual components having greatly increased exposure to the environment, and thus being susceptible to accelerated disintegration and biodegradation.
  • the preferred water soluble adhesives for the seam adhesives are liquid starch adhesives. Hot melt adhesives, or EVA and PVA adhesives may also be used.
  • one or more of the adhesives used are not water soluble.
  • a solvent is held within the capsule which acts to soften or solubilise the adhesive, promoting disintegration of the smoking article.
  • the vehicle containing the liquid capable of enhancing the disintegration and/or dispersion of the smoking article has been generally described above as being a capsule, other fluid-containing vehicles can be used.
  • pockets or pouches formed directly within a filter material or from a separate material such as polyethylene could be used, to be ruptured once the smoking article has been smoked.
  • a sponge-like porous material such as a foamed plastic polymer could be used to contain the fluid, which could be released via a squeezing or twisting action once the smoking article has been smoked.
  • Other suitable fluid- containing arrangements would be evident to those skilled in the art.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Filtering Materials (AREA)
PCT/GB2010/052177 2009-12-21 2010-12-21 Enhancing the disintegration and/or degradation of a smoking article WO2011077141A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
MX2012006678A MX2012006678A (es) 2009-12-21 2010-12-21 Mejoras en la desintegracion y/o degradacion de un articulo para fumar.
EP10803475A EP2515688A1 (en) 2009-12-21 2010-12-21 Enhancing the disintegration and/or degradation of a smoking article
AU2010334634A AU2010334634A1 (en) 2009-12-21 2010-12-21 Enhancing the disintegration and/or degradation of a smoking article
CA2784479A CA2784479C (en) 2009-12-21 2010-12-21 Enhancing the disintegration and/or degradation of a smoking article
UAA201208616A UA103712C2 (uk) 2009-12-21 2010-12-21 Покращення розпадання і/або розкладання курильного виробу
BR112012015710A BR112012015710A2 (pt) 2009-12-21 2010-12-21 filtro para um artigo de fumar, artigo de fumar, utilização de um instrumento e método para aumentar a desintegração e/ou degradação de um artigo de fumar
US13/518,352 US20130047999A1 (en) 2009-12-21 2010-12-21 Enhancing the Disintegration and/or Degradation of a Smoking Article
JP2012545446A JP2013514802A (ja) 2009-12-21 2010-12-21 喫煙品の崩壊性および／または分解性の向上
CN2010800644278A CN102781265A (zh) 2009-12-21 2010-12-21 改善吸烟物品的分解和／或降解
RU2012131045/12A RU2012131045A (ru) 2009-12-21 2010-12-21 Способ улучшения распадения и/или разложения курительного изделия

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0922254.8 2009-12-21
GBGB0922254.8A GB0922254D0 (en) 2009-12-21 2009-12-21 Enhancing the disintegration and/or degradation of a smoking article

Publications (1)

Publication Number Publication Date
WO2011077141A1 true WO2011077141A1 (en) 2011-06-30

Family

ID=41717266

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2010/052177 WO2011077141A1 (en) 2009-12-21 2010-12-21 Enhancing the disintegration and/or degradation of a smoking article

Country Status (15)

Country Link
US (1) US20130047999A1 (uk)
EP (1) EP2515688A1 (uk)
JP (1) JP2013514802A (uk)
KR (1) KR20120103727A (uk)
CN (1) CN102781265A (uk)
AR (1) AR081053A1 (uk)
AU (1) AU2010334634A1 (uk)
BR (1) BR112012015710A2 (uk)
CA (1) CA2784479C (uk)
CL (1) CL2012001701A1 (uk)
GB (1) GB0922254D0 (uk)
MX (1) MX2012006678A (uk)
RU (1) RU2012131045A (uk)
UA (1) UA103712C2 (uk)
WO (1) WO2011077141A1 (uk)

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012003092A1 (en) * 2010-06-30 2012-01-05 R.J. Reynolds Tobacco Company Degradable filter element for smoking article
WO2012156704A3 (en) * 2011-05-13 2013-01-03 British American Tobacco (Investments) Limited Smoking article filter
WO2013020280A1 (zh) * 2011-08-10 2013-02-14 深圳梵活生物科技有限公司 香烟过滤嘴及其制造方法和香烟及其使用方法
US8397733B2 (en) 2010-01-15 2013-03-19 Celanese Acetate Llc Degradable cigarette filter: pill with multilayered coating
WO2013068100A1 (en) * 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with visible contents
WO2013068081A1 (en) 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with colour change segment
WO2013068304A1 (en) * 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with liquid delivery material
US20130319429A1 (en) * 2012-05-17 2013-12-05 Loec, Inc. Method and compositions to deliver variable quantities of flavor from filtered cigarettes
WO2014019804A2 (en) * 2012-08-02 2014-02-06 Philip Morris Products S.A. Smoking article with menthol filter
EP2745717A1 (en) * 2012-12-18 2014-06-25 JT International SA Frozen capsules and method of making same
JP2015533512A (ja) * 2012-11-12 2015-11-26 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッドＢｒｉｔｉｓｈ Ａｍｅｒｉｃａｎｔｏｂａｃｃｏ （Ｉｎｖｅｓｔｍｅｎｔｓ） Ｌｉｍｉｔｅｄ カプセル含有製品、その利用及び調製
JP2016501547A (ja) * 2012-12-31 2016-01-21 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 流量制限器を含む喫煙物品
WO2016087463A1 (en) 2014-12-03 2016-06-09 Philip Morris Products S.A. Smoking article with flow restrictor adapted to promote filter degradation
JP5984232B2 (ja) * 2013-03-26 2016-09-06 日本たばこ産業株式会社 液体を封入したカプセルを搭載したフィルタ及びこのフィルタを備えた喫煙物品
WO2018007561A1 (en) * 2016-07-07 2018-01-11 Philip Morris Products S.A. Smoking article mouthpiece for receiving an insert unit
TWI623273B (zh) * 2012-08-06 2018-05-11 菲利浦莫里斯製品股份有限公司 形成具有嘴端空腔的煙品之方法
TWI623274B (zh) * 2012-08-06 2018-05-11 菲利浦莫里斯製品股份有限公司 具有嘴端空腔的煙品
WO2018122115A1 (en) * 2016-12-29 2018-07-05 Philip Morris Products S.A. Aerosol generating article having water dispersible filter component
CN109393556A (zh) * 2018-12-12 2019-03-01 武汉锐致科技有限公司 一种卷烟制品的保润降温过滤嘴棒及其制备方法

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2816909B1 (en) * 2012-02-21 2018-04-18 JT International SA Smoking article filter
TWI654942B (zh) * 2013-05-14 2019-04-01 瑞士商菲利浦莫里斯製品股份有限公司 包含液體傳送構件及包覆材的菸品
GB201316210D0 (en) * 2013-09-11 2013-10-30 Filtrona Filter Prod Dev Co Tobacco smoke filter
AR106163A1 (es) * 2015-09-30 2017-12-20 Philip Morris Products Sa Artículo generador de aerosol que tiene un saborizante disperso
SG11201804879TA (en) * 2015-12-30 2018-07-30 Philip Morris Products Sa Aerosol-generating article comprising a liquid delivery element
CN105672030A (zh) * 2016-01-26 2016-06-15 广西中烟工业有限责任公司 一种涂布复配天然草本香料的增香型卷烟纸及其制备方法
US10524500B2 (en) * 2016-06-10 2020-01-07 R.J. Reynolds Tobacco Company Staple fiber blend for use in the manufacture of cigarette filter elements
KR101710833B1 (ko) * 2016-06-29 2017-02-27 주식회사 케이티앤지 흡연속도 감응 변색 필터부 및 그를 구비한 담배
CN109963475B (zh) * 2016-10-31 2021-12-28 Jt国际公司 带有充液定向胶囊的吸烟制品
CN107183783B (zh) * 2017-07-25 2020-04-21 云南中烟工业有限责任公司 一种可防止滤嘴热塌陷的高截留效率滤嘴
EA202091553A1 (ru) * 2017-12-22 2020-09-18 Джапан Тобакко Инк. Курительное изделие и фильтр курительного изделия
CN111491525B (zh) * 2017-12-27 2022-04-26 日本烟草产业株式会社 吸烟物品
CN109602082A (zh) * 2018-10-20 2019-04-12 南通烟滤嘴有限责任公司 具有预埋混合物料段的复合滤棒
ES1221696Y (es) * 2018-11-13 2019-03-04 Ragues Daniel Garcia Filtro para tabaco hidrosoluble
CN211910498U (zh) * 2020-01-20 2020-11-13 华健 一种胶囊调味装置
CN111602845B (zh) * 2020-04-27 2022-08-09 深圳烟草工业有限责任公司 一种卷烟降温凝胶颗粒及其应用
GB202115251D0 (en) * 2021-10-22 2021-12-08 Essentra Filter Products Dev Co Pte Ltd Paper tube
EP4176736A1 (en) * 2021-11-08 2023-05-10 Essentra Filter Products Development Co. Pte. Ltd. Active paper

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0649607A2 (en) * 1993-09-30 1995-04-26 British-American Tobacco Company Limited Improvements relating to tobacco smoke filter elements
US6776168B1 (en) * 1999-10-22 2004-08-17 Rhodia Acetow Gmbh Disintegratable cigarette filter

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5709227A (en) * 1995-12-05 1998-01-20 R. J. Reynolds Tobacco Company Degradable smoking article
US20050268926A1 (en) * 2004-06-02 2005-12-08 Wei-Cheng Hsu Cigarette
EP1754419A1 (en) * 2005-08-15 2007-02-21 Philip Morris Products S.A. Liquid release device for a smoking article
EP2323506B2 (en) * 2008-05-21 2016-07-27 R.J.Reynolds Tobacco Company Apparatus and associated method for forming a filter component of a smoking article and smoking articles made therefrom

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0649607A2 (en) * 1993-09-30 1995-04-26 British-American Tobacco Company Limited Improvements relating to tobacco smoke filter elements
EP0920816A2 (en) * 1993-09-30 1999-06-09 British American Tobacco (Investments) Limited Improvements relating to tobacco smoke filter elements
US6776168B1 (en) * 1999-10-22 2004-08-17 Rhodia Acetow Gmbh Disintegratable cigarette filter

Cited By (43)

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Publication number Priority date Publication date Assignee Title
US8397733B2 (en) 2010-01-15 2013-03-19 Celanese Acetate Llc Degradable cigarette filter: pill with multilayered coating
WO2012003092A1 (en) * 2010-06-30 2012-01-05 R.J. Reynolds Tobacco Company Degradable filter element for smoking article
WO2012156704A3 (en) * 2011-05-13 2013-01-03 British American Tobacco (Investments) Limited Smoking article filter
WO2013020280A1 (zh) * 2011-08-10 2013-02-14 深圳梵活生物科技有限公司 香烟过滤嘴及其制造方法和香烟及其使用方法
KR101787816B1 (ko) * 2011-11-07 2017-10-18 필립모리스 프로덕츠 에스.에이. 가시적 내용물을 가진 흡연물품
CN103929987A (zh) * 2011-11-07 2014-07-16 菲利普莫里斯生产公司 具有可见内容物的发烟制品
WO2013068304A1 (en) * 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with liquid delivery material
US9986759B2 (en) 2011-11-07 2018-06-05 Philip Morris Products S.A. Smoking article with liquid delivery material
US10165794B2 (en) 2011-11-07 2019-01-01 Philip Morris Products S.A. Smoking article with visible contents
JP2017113036A (ja) * 2011-11-07 2017-06-29 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 可視内容物を含む喫煙物品
WO2013068100A1 (en) * 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with visible contents
WO2013068081A1 (en) 2011-11-07 2013-05-16 Philip Morris Products S.A. Smoking article with colour change segment
JP2014532433A (ja) * 2011-11-07 2014-12-08 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 可視内容物を含む喫煙物品
JP2014534818A (ja) * 2011-11-07 2014-12-25 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 色変化セグメントを有する喫煙物品
CN103917116B (zh) * 2011-11-07 2017-06-06 菲利普莫里斯生产公司 具有颜色变化分段的发烟制品
RU2607535C2 (ru) * 2011-11-07 2017-01-10 Филип Моррис Продактс С.А. Курительное изделие с материалом для доставки жидкости
AU2012334405B2 (en) * 2011-11-07 2015-10-01 Philip Morris Products S.A. Smoking article with colour change segment
RU2564600C1 (ru) * 2011-11-07 2015-10-10 Филип Моррис Продактс С.А. Курительное изделие с изменяющим окраску сегментом
US9497991B2 (en) 2011-11-07 2016-11-22 Philip Morris Products S.A. Smoking article with colour change segment
US20130319429A1 (en) * 2012-05-17 2013-12-05 Loec, Inc. Method and compositions to deliver variable quantities of flavor from filtered cigarettes
JP2015523091A (ja) * 2012-08-02 2015-08-13 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム メンソールフィルタを備える喫煙品
CN104540403A (zh) * 2012-08-02 2015-04-22 菲利普·莫里斯产品股份有限公司 带有薄荷滤嘴的吸烟制品
WO2014019804A3 (en) * 2012-08-02 2014-04-03 Philip Morris Products S.A. Smoking article with menthol filter
WO2014019804A2 (en) * 2012-08-02 2014-02-06 Philip Morris Products S.A. Smoking article with menthol filter
US10357057B2 (en) 2012-08-06 2019-07-23 Philip Morris Products S.A. Smoking article with mouth end cavity
US11051544B2 (en) 2012-08-06 2021-07-06 Philip Morris Products S.A. Method of forming smoking articles with mouth end cavities
US10123561B2 (en) 2012-08-06 2018-11-13 Philip Morris Products S.A. Method of forming smoking articles with mouth end cavities
TWI623274B (zh) * 2012-08-06 2018-05-11 菲利浦莫里斯製品股份有限公司 具有嘴端空腔的煙品
TWI623273B (zh) * 2012-08-06 2018-05-11 菲利浦莫里斯製品股份有限公司 形成具有嘴端空腔的煙品之方法
JP2015533512A (ja) * 2012-11-12 2015-11-26 ブリティッシュ アメリカン タバコ （インヴェストメンツ） リミテッドＢｒｉｔｉｓｈ Ａｍｅｒｉｃａｎｔｏｂａｃｃｏ （Ｉｎｖｅｓｔｍｅｎｔｓ） Ｌｉｍｉｔｅｄ カプセル含有製品、その利用及び調製
EP2745717A1 (en) * 2012-12-18 2014-06-25 JT International SA Frozen capsules and method of making same
US10925311B2 (en) 2012-12-31 2021-02-23 Philip Morris Products S.A. Smoking article including flow restrictor
JP2016501547A (ja) * 2012-12-31 2016-01-21 フィリップ・モーリス・プロダクツ・ソシエテ・アノニム 流量制限器を含む喫煙物品
JPWO2014156839A1 (ja) * 2013-03-26 2017-02-16 日本たばこ産業株式会社 液体を封入したカプセルを搭載したフィルタ及びこのフィルタを備えた喫煙物品
JP5984232B2 (ja) * 2013-03-26 2016-09-06 日本たばこ産業株式会社 液体を封入したカプセルを搭載したフィルタ及びこのフィルタを備えた喫煙物品
US10327469B2 (en) 2014-12-03 2019-06-25 Philip Morris Products S.A. Smoking article with flow restrictor adapted to promote filter degradation
WO2016087463A1 (en) 2014-12-03 2016-06-09 Philip Morris Products S.A. Smoking article with flow restrictor adapted to promote filter degradation
WO2018007561A1 (en) * 2016-07-07 2018-01-11 Philip Morris Products S.A. Smoking article mouthpiece for receiving an insert unit
US11632984B2 (en) 2016-07-07 2023-04-25 Philip Morris Products S.A. Smoking article mouthpiece for receiving an insert unit
WO2018122115A1 (en) * 2016-12-29 2018-07-05 Philip Morris Products S.A. Aerosol generating article having water dispersible filter component
RU2749663C2 (ru) * 2016-12-29 2021-06-16 Филип Моррис Продактс С.А. Изделие, генерирующее аэрозоль, имеющее диспергируемый в воде фильтрующий компонент
US11291243B2 (en) 2016-12-29 2022-04-05 Philip Morris Products S.A. Aerosol generating article having water dispersible filter component
CN109393556A (zh) * 2018-12-12 2019-03-01 武汉锐致科技有限公司 一种卷烟制品的保润降温过滤嘴棒及其制备方法

Also Published As

Publication number Publication date
CA2784479A1 (en) 2011-06-30
KR20120103727A (ko) 2012-09-19
GB0922254D0 (en) 2010-02-03
AR081053A1 (es) 2012-06-06
US20130047999A1 (en) 2013-02-28
CA2784479C (en) 2014-04-08
CN102781265A (zh) 2012-11-14
AU2010334634A1 (en) 2012-07-19
EP2515688A1 (en) 2012-10-31
RU2012131045A (ru) 2014-01-27
MX2012006678A (es) 2012-07-30
BR112012015710A2 (pt) 2016-05-17
JP2013514802A (ja) 2013-05-02
UA103712C2 (uk) 2013-11-11
CL2012001701A1 (es) 2013-07-12

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