WO2011076680A1 - Tyre with improved tread - Google Patents

Tyre with improved tread Download PDF

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Publication number
WO2011076680A1
WO2011076680A1 PCT/EP2010/070054 EP2010070054W WO2011076680A1 WO 2011076680 A1 WO2011076680 A1 WO 2011076680A1 EP 2010070054 W EP2010070054 W EP 2010070054W WO 2011076680 A1 WO2011076680 A1 WO 2011076680A1
Authority
WO
WIPO (PCT)
Prior art keywords
rubber compound
tyre
tread
equal
axial
Prior art date
Application number
PCT/EP2010/070054
Other languages
French (fr)
Inventor
Jean-Claude Faure
Emmanuel Igier
Jean-Luc Mangeret
Original Assignee
Societe De Technologie Michelin
Michelin Recherche Et Technique S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Societe De Technologie Michelin, Michelin Recherche Et Technique S.A. filed Critical Societe De Technologie Michelin
Priority to US13/518,795 priority Critical patent/US9302546B2/en
Priority to CN201080058559.XA priority patent/CN102686413B/en
Priority to BR112012015426A priority patent/BR112012015426A8/en
Priority to JP2012545254A priority patent/JP5655092B2/en
Priority to EP10794989.3A priority patent/EP2516180B1/en
Priority to RU2012131172/11A priority patent/RU2529041C2/en
Publication of WO2011076680A1 publication Critical patent/WO2011076680A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/0041Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
    • B60C11/005Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers
    • B60C11/0058Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers with different cap rubber layers in the axial direction
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C1/00Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
    • B60C1/0016Compositions of the tread
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/03Tread patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/03Tread patterns
    • B60C11/0327Tread patterns characterised by special properties of the tread pattern
    • B60C11/0332Tread patterns characterised by special properties of the tread pattern by the footprint-ground contacting area of the tyre tread
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B60VEHICLES IN GENERAL
    • B60CVEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
    • B60C11/00Tyre tread bands; Tread patterns; Anti-skid inserts
    • B60C11/0008Tyre tread bands; Tread patterns; Anti-skid inserts characterised by the tread rubber
    • B60C2011/0016Physical properties or dimensions
    • B60C2011/0025Modulus or tan delta
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T152/00Resilient tires and wheels
    • Y10T152/10Tires, resilient
    • Y10T152/10495Pneumatic tire or inner tube

Definitions

  • the present invention relates to tyres for passenger vehicles. It relates more particularly to tyres suited to sporty road driving.
  • a vehicle even if designed for sporty use, has to be driven in variable weather conditions. It is, therefore, a known practice for the tyre to be provided with means that provide good grip on dry ground and on wet ground.
  • the tread pattern it is possible to adapt at least part of the tread pattern to use on wet ground, for example by providing recesses able to drain away and/or to store water, or by increasing the number of tread pattern edges able to cut through the film of water formed between the tread and the ground.
  • a tread comprising the two types of rubber compound is able to achieve good grip under all circumstances.
  • An example of such a tyre is given in document EP 1 308 319.
  • the "side of the contact area furthest from the centre of the bend” is the side via which the elements of the tread come into contact with the ground in the direction of the rate of drift of the centre of the wheel on which the tyre is mounted. For this reason, it is sometimes referred to as "(transverse) leading edge”.
  • the opposite side, that is to say the "side of the contact area closest to the centre of the bend” is sometimes referred to as the "(transverse) trailing edge”.
  • Rubber compounds suited for use on wet ground are generally more fragile with respect to the very high thermal and mechanical stresses generated in the contact area of a tyre under severe cornering conditions on a dry road surface. If the tread of the tyre is provided with portions made of a rubber compound with better grip on dry ground and with portions made of a rubber compound with better grip on wet ground, then it is preferable to ensure that the rubber compound that has better grip on dry ground is placed on the side of the contact area that is furthest from the centre of the bend. Thus, even if the contact area becomes trapezoidal, the tyre will maintain good grip on dry ground, that is to say a good ability to develop a high transverse force.
  • One of the objectives of the present invention is, therefore, to provide a tyre that provides a better compromise between grip on dry ground and grip on wet ground.
  • a tyre that has a predetermined direction of mounting, in which a portion of that part of the tread that is traditionally reserved for the rubber compounds that have better grip on wet ground is made of a rubber compound that has better grip on dry ground.
  • a portion of that part of the tread that is situated on that side of the vehicle which faces toward the vehicle when the tyre is mounted on the vehicle in said predetermined direction of mounting is made of a rubber compound that has better grip on dry ground.
  • a tyre designed to be mounted on a mounting rim of a wheel of a vehicle and having a predetermined direction of mounting on the vehicle, comprising a tread having a mean radial height HB, comprising a rolling surface designed to come into contact with a ground when the tyre is rolling on the ground, the tread having an outer edge and an inner edge, the outer edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle, the inner edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle, the axial distance between the outer edge and the inner edge defining the axial width L of the tread.
  • the tread comprises a first portion made of at least one first rubber compound, the first portion extending, in any radial section, from the outer edge to a first axial position, the axial distance of the first axial position from the outer edge being greater or equal to 20% and smaller or equal than 40% of the axial width L of the tread.
  • the tread also comprises a second portion made of at least one second rubber compound, the second portion extending, in any radial section, from said first axial position to a second axial position, the axial distance of the second axial position from the outer edge being greater or equal to 50% and smaller or equal than 60% of the axial width L of the tread.
  • the tread also comprises a third portion made of at least one third rubber compound, the third portion extending, in any radial section, from said second axial position to a third axial position, the axial distance of the third axial position from the outer edge being greater or equal to 80% and smaller or equal than 90% of the axial width L of the tread.
  • the tread comprises a fourth portion made of at least one fourth rubber compound, the fourth portion extending, in any radial section, from said third axial position to the inner edge of the tread.
  • Said first, second, third and fourth portions extend over the entire circumference of the tyre and have an intersection with the rolling surface when the tyre is new or, at the latest, after at most 10% of the height HB has been worn away,
  • Said at least one first rubber compound and said at least one third rubber compound contain at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler, and wherein said at least one second rubber compound and said at least one fourth rubber compound contain at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler.
  • Said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 0°C, at a stress of 0.7 MPa, that is lower (preferably lower by at least 0.05) than that of said at least one second rubber compound and said at least one fourth rubber compound.
  • said portions made of said at least one first, second, third and fourth rubber compounds all have an intersection with the rolling surface when the tyre is new.
  • said at least one third rubber compound is identical to said at least one first rubber compound and said at least one fourth rubber compound is identical to said at least one second rubber compound.
  • said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 10°C, at a stress of 0.7 MPa, that is higher (preferably higher by at least 0.05) than that of said at least one second rubber compound and said at least one fourth rubber compound.
  • the value tan5 of the rubber compound at 10°C, at a stress of 0.7 MPa neatly characterizes the grip on dry ground.
  • the difference between the value of tan5 for said at least one first rubber compound and said at least one second rubber compound is greater than or equal to 0.05, wherein the difference between the value of tan5 for said at least one second rubber compound and said at least one third rubber compound is greater than or equal to 0.05, and wherein the difference between the value of tan5 for said at least one third rubber compound and said at least one fourth rubber compound is also greater than or equal to 0.05.
  • Figure 1 depicts a tyre according to the prior art.
  • Figure 2 depicts a partial perspective view of a tyre according to the prior art.
  • Figure 3 depicts, in radial cross section, a quarter of a tyre according to the prior art.
  • Figures 4 and 5 illustrate how the axial edge of a tread is determined.
  • Figure 6 illustrates the terms “inner edge” and “outer edge” of a tread.
  • Figure 7 schematically depicts the crown of a tyre according to the prior art.
  • Figure 8 schematically depicts the deformation of a tyre according to the prior art when it experiences substantial transverse stresses.
  • Figure 9 illustrates the trapezoidal distortion of the contact area of such a tyre.
  • Figures 10 and 1 1 illustrate the trapezoidal distortion of the contact area of two tyres mounted on one and the same axle of a vehicle, depending on the direction in which the vehicle is cornering.
  • the expression refers to a radius of the tyre. It is in that sense that a point P1 is said to be “radially inside” a point P2 (or “radially on the inside of” the point P2) if it is closer to the axis of rotation of the tyre than is the point P2. Conversely, a point P3 is said to be “radially outside” a point P4 (or “radially on the outside of” the point P4) if it is further from the axis of rotation of the tyre than is the point P4. Progress “radially inward (or outward)” will mean progress toward smaller (or larger) radii. In terms of radial distances, it is this sense of the word that applies also.
  • a thread or a reinforcement is said to be "radial" when the thread or the reinforcing elements of the reinforcement make an angle greater than or equal to 80° and less than or equal to 90° with the circumferential direction.
  • thread is to be understood in a very general sense of the word and encompasses threads in the form of monofilaments, multifilaments, a cord, a yarn or an equivalent assembly, irrespective of the material of which the thread is made or of the surface treatment it has undergone to enhance its bonding with the rubber.
  • a "radial cross section” or “radial section” here means a cross section or a section on a plane which contains the axis of rotation of the tyre.
  • An “axial” direction is a direction parallel to the axis of rotation of the tyre.
  • a point P5 is said to be “axially inside” a point P6 (or “axially on the inside of” the point P6) if it is closer to the median plane of the tyre than is the point P6.
  • a point P7 is said to be “axially outside” a point P8 (or “axially on the outside of” the point P8) if it is further from the median plane of the tyre than is the point P8.
  • the “median plane” of the tyre is the plane which is perpendicular to the axis of rotation of the tyre and which lies equal distances from the annular reinforcing structures of each bead.
  • a “circumferential” direction is a direction perpendicular both to a radius of the tyre and to the axial direction.
  • a “circumferential section” is a section on a plane perpendicular to the axis of rotation of the tyre.
  • rubber compound denotes a compound of rubber containing at least one elastomer and one filler.
  • FIG. 1 schematically depicts a tyre 10 according to the prior art.
  • the tyre 10 comprises a crown comprising a crown reinforcement (not visible in Figure 1 ) surmounted by a tread 40, two sidewalls 30 extending the crown radially inward, and two beads 20 radially inside of the sidewalls 30.
  • FIG. 2 schematically depicts a partial perspective view of a tyre 10 according to the prior art and illustrates the various components of the tyre.
  • the tyre 10 comprises a carcass reinforcement 60 made up of threads 61 coated with rubber compound, and two beads 20 each comprising annular reinforcing structures 70 which hold the tyre 10 on the rim (not depicted).
  • the carcass reinforcement 60 is anchored in each of the beads 20.
  • the tyre 10 further comprises a crown reinforcement comprising two plies 80 and 90.
  • Each of the plies 80 and 90 is reinforced with thread-like reinforcing elements 81 and 91 which are parallel within each layer and cross from one layer to the next, making angles ranging between 10° and 70° with the circumferential direction.
  • the tyre further comprises a hooping reinforcement 100, arranged radially on the outside of the crown reinforcement, this hooping reinforcement being formed of circumferentially directed spiral-wound reinforcing elements 101 .
  • a tread 40 is laid on the hooping reinforcement; it is this tread 40 that provides contact between the tyre 10 and the road surface.
  • the tyre 10 depicted is a "tubeless" tyre: it comprises an "inner liner" 50 made of a rubber compound impervious to the inflation gas, covering the interior surface of the tyre.
  • FIG 3 schematically depicts, in radial cross section, one quarter of a reference tyre 10 of the "Pilot Sport 2" type commercialised by Michelin.
  • the tyre 10 comprises two beads 20 designed to come into contact with a mounting rim (not depicted), each bead 20 comprising a plurality of annular reinforcing structures 70.
  • Two sidewalls 30 extend the beads 20 radially outward and meet in a crown 25 comprising a crown reinforcement formed of a first layer of reinforcing elements 80 and of a second layer of reinforcing elements 90, and radially surmounted by a hooping reinforcement 100, which is itself radially surmounted by a tread 40.
  • the median plane 130 of the tyre is also indicated.
  • the axial edge is the point at which the angle a (alpha) between said tangent and an axial direction is equal to 30°.
  • the axial edge 45 has been determined in this way.
  • Each layer of reinforcing elements 80 and 90 comprises thread-like reinforcing elements, coated in a matrix formed of rubber compound.
  • the reinforcing elements of each layer are substantially mutually parallel; the reinforcing elements of the two layers cross from one layer to the next at an angle of about 20°, as is well known to those skilled in the art for tyres known as radial tyres.
  • the tyre 10 further comprises a carcass reinforcement 60 which extends from the beads 20 through the sidewalls 30 as far as the crown 25.
  • This carcass reinforcement 60 here comprises thread-like reinforcing elements that are directed substantially radially, that is to say that make an angle greater than or equal to 80° and less than or equal to 90° with the circumferential direction.
  • the carcass reinforcement 60 comprises a plurality of carcass reinforcing elements; it is anchored in the two beads 20 between the annular reinforcing structures 70.
  • FIG. 7 schematically depicts the crown of a tyre according to the prior art, designed to be mounted on a mounting rim of a wheel of a vehicle and having a predetermined direction of mounting on the vehicle.
  • This crown notably comprises a tread having a mean radial height HB.
  • the tread comprises a rolling surface 47 designed to come into contact with the ground when the tyre is rolling on the ground.
  • the tread has an outer edge 45 and an inner edge 46, the outer edge 45 being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle (see Fig. 6), the inner edge 46 being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle (see Fig.6).
  • the axial distance between the outer edge 45 and the inner edge 46 defines the axial width L of the tread
  • the tread comprises a first portion 41 1 made of a first rubber compound.
  • the first portion 41 1 extends, in any radial section, from the outer edge 45 to a first axial position 41 , the axial distance L1 of the first axial position from the outer edge 45 being equal to 40% of the axial width L of the tread.
  • the first portion 41 1 extends around the entire circumference of the tyre and has an intersection with the rolling surface when the tyre is new (unworn).
  • the tread also comprises a second portion 412 made of a second rubber compound.
  • the second portion 412 extends, in any radial section, from said first axial position 41 to the inner edge 46 of the tread,
  • the second rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound and a grip on dry ground that is inferior to the grip on dry ground of the first rubber compound.
  • This portion extends over the entire circumference of the tyre and has an intersection with the rolling surface when the tyre is new (unworn).
  • Figures 8 and 9 schematically depict the deformation of a tyre 10 according to the prior art, inflated to 3 bar and heavily loaded (load of 7100 N) when it experiences substantial transverse stresses (camber: -4.4°, rate of sideslip: 3 m/s).
  • Figure 8 corresponds to a view in the direction of forward travel of the tyre.
  • the reference 2 indicates the axis of rotation of the tyre 10 and the reference 3 the ground on which the tyre 10 is rolling.
  • Figure 9 depicts the footprint of the tyre 10 on the ground 3. To a first approximation, this footprint is in the shape of a trapezium 4 the long side 5 of which is the side furthest from the centre of the bend being taken by the vehicle on which the tyre 10 is mounted. Because the grip of the tyre is greater on dry ground than on wet ground, the transverse forces that the tyre may experience are also greater on dry ground and the trapezoidal deformation is more pronounced. It is, therefore, advantageous to ensure that the portion of rubber compound with better grip on dry ground is on that side of the contact area that is furthest from the centre of the bend, as is the case in the tyre depicted in Figure 7. By providing a portion made of rubber compound with better grip on wet ground on that side of the contact area that is closest to the centre of the bend, an advantageous compromise can be reached between the grip of the tyre on dry ground and on wet ground.
  • Figure 10 illustrates the trapezoidal deformation of the contact area of two tyres 1 1 and 12 mounted on one and the same axle 7 of a vehicle, viewed upward from the ground on which the tyres are rolling. The case being considered is a left-hand bend (when considered from the point of view of the driver of the vehicle), that is to say a bend in the direction indicated using the arrow 151 .
  • the tyres 1 1 and 12 have been mounted in their predetermined directions of mounting: the inner edges 46 of their treads are on the side facing in toward the body of the vehicle (the body is not depicted), and the outer edges 45 facing toward the outside of the vehicle. Strictly speaking, the situation is optimized only for the tyre 1 1 because the rubber compound with better grip on dry ground, which is on the outer edge 45 side, is on the side furthest from the centre of the bend. By contrast, for the tyre 12, the rubber compound with better grip on dry ground is on the side closest to the centre of the bend. As has been depicted in Figure 1 1 , the situation reverses when the driver corners to the right (from his point of view) that is to say in the direction indicated using the arrow 152.
  • Fig. 1 1 it is the tyre 12 that is best suited. Whatever the direction of the bend, there is always one tyre that "does not suit". Because an ordinary vehicle corners as often to the left as to the right, it is none the less preferable to favour the tyre that is on the side furthest from the centre of the bend, because it is that tyre which bears more load and has the greater contact area. It is that tyre which, therefore, plays a dominant part in the overall grip of the vehicle. Therefore, such an arrangement corresponds to an advantageous compromise for vehicles that corner as often to the right as to the left.
  • An embodiment of the invention provides a way to improve the overall grip performance still further and, more particularly, to improve the compromise between grip on dry ground and grip on wet ground. This objective is achieved using a tyre that has a predetermined direction of mounting, in which a portion of that part of the tread that is traditionally reserved for the rubber compounds that have better grip on wet ground is made of a rubber compound that has better grip on dry ground.
  • a portion of that part of the tread that is situated on that side of the vehicle which faces toward the vehicle when the tyre is mounted on the vehicle in the predetermined direction of mounting is made of a rubber compound that has better grip on dry ground.
  • FIG. 12 schematically depicts the crown of a tyre according to an embodiment of the invention.
  • This crown notably comprises a tread of axial width L and mean radial height HB.
  • the tread comprises a rolling surface 47 designed to make contact with the ground when the tyre is rolling on the ground.
  • the tread has an outer edge 45 and an inner edge 46, the outer edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle (see figure 6), the inner edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle (see figure 6).
  • the axial distance between the outer edge 45 and the inner edge 46 defining the axial width L of the tread.
  • the tread comprises a first portion 41 1 made of a first rubber compound, the first portion extending, in any radial section, from the outer edge 45 to a first axial position 41 .
  • the axial distance L1 of the first axial position 41 from the outer edge 45 is equal to 40% of the axial width L of the tread,
  • the first rubber compound is a compound that has good grip on dry ground : it contains at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler.
  • the tread comprises a second portion 412 made of a second rubber compound, the second portion 412 extending, in any radial section, from said first axial position 41 to a second axial position 42.
  • the axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 60% of the axial width L of the tread.
  • the second rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound : it contains at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler.
  • the tread also comprises a third portion 413 made of a third rubber compound, the third portion 413 extending, in any radial section, from said second axial position 42 to a third axial position 43.
  • the axial distance L3 of the second axial position 43 from the outer edge 45 is equal to 80% of the axial width L of the tread.
  • the third rubber compound contains at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN 1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler.
  • the first and third rubber compounds have the same composition, which is advantageous from the manufacturing point of view. None the less, it is possible to have a third rubber compound that differs from the first rubber compound.
  • the tread also comprises a fourth portion 414 made of a fourth rubber compound, the fourth portion 414 extending, in any radial section, from said third axial position 43 to the inner edge 46 of the tread.
  • the fourth rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound : it contains at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler.
  • the second and fourth rubber compounds have the same composition, which is advantageous from the manufacturing point of view. None the less, it is possible to have a fourth rubber compound that differs from the second rubber compound.
  • Said first, second, third and fourth portions extend over the entire circumference of the tyre and have an intersection with the rolling surface 47 when the tyre is new (unworn).
  • the first and third rubber compound have a value for tan5 at 0°C, at a stress of 0.7 MPa, that is lower than that of the second and fourth rubber compounds.
  • Figure 13 schematically depicts the crown of a tyre according to another embodiment of the invention. Unlike the case of the tyre depicted in Figure 12, the axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 50% of the axial width L of the tread and the axial distance L3 of the third axial position 43 from the outer edge 45 is equal to 90% of the axial width L. This figure also illustrates that in a tyre according to an embodiment of the invention, the transitions between the various compounds do not necessarily lie at a circumferential groove.
  • Figure 14 schematically depicts the crown of a tyre according to another embodiment of the invention.
  • the axial distance L1 of the first axial position 41 from the outer edge 45 is equal to 30% of the axial width L
  • the axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 55% of the axial width L
  • the axial distance L3 of the third axial position 43 from the outer edge 45 is equal to 85% of the axial width L.
  • Table 1 gives, by way of example, the composition of rubber compounds that can be used.
  • the composition is given in pee ("per cent elastomer") that is to say in parts by weight for 100 parts by weight of elastomer.
  • the rubber compounds are preferably based on at least one diene elastomer, one reinforcing filler and a crosslinking system.
  • a “diene” elastomer (or interchangeably rubber) is, in the known way, an elastomer derived at least in part from (i.e. a homopolymer or a copolymer of) diene monomers, that is to say monomers bearing two carbon-carbon double bonds, conjugated or otherwise.
  • the diene elastomer used is preferably chosen from the group consisting of polybutadienes (BR), natural rubber (NR), synthetic polyisoprenes (IR), styrene butadiene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR), butadiene-styrene-isoprene copolymers (SBIR) and blends of these elastomers.
  • BR polybutadienes
  • NR natural rubber
  • IR synthetic polyisoprenes
  • SBR styrene butadiene copolymers
  • BIR isoprene-butadiene copolymers
  • SIR isoprene-styrene copolymers
  • SBIR butadiene-styrene-isoprene copolymers
  • One preferred embodiment is to use an "isoprene” elastomer, that is to say a homopolymer or copolymer of isoprene, or in other words, a diene elastomer chosen from the group consisting of natural rubber (NR), synthetic polyisoprenes (IR), the various copolymers of isoprene and blends of these elastomers.
  • NR natural rubber
  • IR synthetic polyisoprenes
  • the isoprene elastomer is preferably natural rubber or a synthetic polyisoprene of the cis-1 ,4 type. Of these synthetic polyisoprenes, use is preferably made of polyisoprenes that have a cis-1 ,4 bond content (mol%) in excess of 90%, or more preferably still, in excess of 98%. According to other preferred embodiments, the diene elastomer may consist, in full or in part, of another diene elastomer such as, for example, an SBR (E-SBR or S-SBR) elastomer used in combination or otherwise with another elastomer for example of the BR type.
  • SBR SBR
  • the rubber composition may also contain all or some of the additives conventionally employed in the rubber matrices used for the manufacture of tyres, such as, for example, reinforcing fillers such as carbon black or inorganic fillers such silica, coupling agents for inorganic fillers, anti-aging agents, antioxidants, plasticizers or extender oils, whether the latter are of aromatic or non-aromatic nature (notably oils that are only very slightly aromatic or non-aromatic, for example of the naphthene or paraffin type, with a high or preferably low viscosity, MES or TDAE oils, plasticizing resins with a high T g in excess of 30°C), agents that improve the processability of the compositions in the green state, tackifying resins, a crosslinking system based either on sulphur or sulphur donors and/or peroxides, accelerators, vulcanization activators or retarders, anti-reversion agents, methylene acceptors and donors such as, for example
  • compositions are manufactured in appropriate mills, using two successive phases of preparation well known to those skilled in the art, namely a first phase of thermomechanical work or kneading (the so-called “non-productive” phase) at high temperature, up to a maximum temperature of between 1 10°C and 190°C, preferably between 130°C and 180°C, followed by a second phase of mechanical work (the so- called “productive” phase) down to a lower temperature, typically of less than 1 10°C, during which finishing stage the crosslinking system is incorporated.
  • a first phase of thermomechanical work or kneading at high temperature, up to a maximum temperature of between 1 10°C and 190°C, preferably between 130°C and 180°C
  • a second phase of mechanical work the so- called “productive” phase
  • the non-productive phase is conducted in a single thermomechanical step lasting a few minutes (for example between 2 and 10 min) during which all the required basic ingredients and other additives, apart from the crosslinking or vulcanizing system, are introduced into an appropriate mixer such as a conventional internal mixer.
  • an appropriate mixer such as a conventional internal mixer.
  • the vulcanizing system is then incorporated with it in an external mixer such as an open mill kept at a low temperature (for example between 30°C and 100°C). This is then blended (productive phase) for a few minutes (for example for between 5 and 15 min).
  • Vulcanizing may be performed in the known way at a temperature generally between 130°C and 200°C, preferably under pressure, for a sufficient length of time which may vary, for example, between 5 and 90 min depending in particular on the curing temperature, on the vulcanizing system adopted and on the vulcanization dynamics of the composition considered.
  • Table II gives the properties of the rubber compounds the composition of which is given in Table I Compound with better Compound with better
  • tan5 at 0°C is representative of the potential to grip on wet ground: the higher tan5 at 0°C, the better the grip.
  • the values of tan5 at temperatures higher than 10°C are representative of the hysteresis of the material and of the potential to grip on dry ground.
  • the second composition has a value of tan5 at 0°C (imposed stress 0.7 MPa) that is higher by comparison with the first composition, indicating that its grip on wet ground will be superior; and has a value of tan5 at 10°C that is lower by comparison with the first composition, indicating that the grip on dry ground would be inferior.
  • Tests were carried out using a Porsche 997 fitted with Pilot Super Sport tyres, size 245/35 R20 (on the front) and 295/30 R20 (on the rear).
  • a tyre equipped with a tread as depicted in Figure 12 was compared against a reference tyre equipped with a tread as depicted in Figure 7.
  • the rubber compounds of Table I were used.
  • the tyres according to the invention saved an average of 1 second per lap (on the Nardo (Italy) "handling" circuit with a circuit length of 6.2 km) on dry ground, at the expense of just 0.2 seconds per lap on wet ground. These improved times were backed by the subjective assessment of the drivers who reported better grip on dry ground and substantially unchanged grip on wet ground. The invention therefore provides a better compromise between grip on dry ground and grip on wet ground.

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Abstract

Tyre (10) comprising a tread (40) having a mean radial height HB, an outer edge (45) and an inner edge (46), the axial distance between the outer edge (45) and the inner edge (46) defining the axial width L of the tread, the tread comprisinga first portion (411) made of a first rubber compound, extending from the outer edge (45) to a first axial position at an axial distance from the outer edge of between 20% and 40% of the axial width; a second portion (412) made of a second rubber compound, extending from said first axial position to a second axial position at an axial distance from the outer edge of between 50% and 60% of the axial width L; a third portion (413) made of a third rubber compound extending from said second axial position to a third axial position at an axial distance from the outer edge of between 80% and 90% of the axial width L; and a fourth portion (414) made of a fourth rubber compound, extending from said third axial position to the inner edge (46) of the tread, wherein said first and third rubber compounds are predominantly filled with carbon black filler, wherein said second and fourth rubber compounds are predominantly filled with non carbon black filler, and wherein said first rubber compound and said third rubber compound have a value for tanδ at 0°C, at a stress of 0.7 MPa, that is lower than that of said second rubber compound and said fourth rubber compound.

Description

TYRE WITH IMPROVED TREAD
FIELD OF THE INVENTION
[0001 ] The present invention relates to tyres for passenger vehicles. It relates more particularly to tyres suited to sporty road driving.
BACKGROUND
[0002] The grip that tyres have on the ground on which they are rolling is one of the most important features from the point of view of the safety of the driver of a vehicle fitted with tyres. It is also of key importance in determining the performance of the vehicle in sporty road driving. If its tyres lose their ability to steer as a result of a lack of grip, the vehicle can no longer be steered.
[0003] Of course, a vehicle, even if designed for sporty use, has to be driven in variable weather conditions. It is, therefore, a known practice for the tyre to be provided with means that provide good grip on dry ground and on wet ground. In particular, it is possible to adapt at least part of the tread pattern to use on wet ground, for example by providing recesses able to drain away and/or to store water, or by increasing the number of tread pattern edges able to cut through the film of water formed between the tread and the ground. It is also possible to vary the materials of which the tread is made, using rubber compounds more particularly suited to use on wet ground and/or on dry ground. A tread comprising the two types of rubber compound is able to achieve good grip under all circumstances. An example of such a tyre is given in document EP 1 308 319.
[0004] Under sporty road driving conditions, the tyres of a vehicle experience substantial transverse stresses when the vehicle fitted with the tyres is cornering. During the corner, the transverse stresses cause, on the contact area where each tyre makes contact with the ground on which it is rolling, deformation resulting in a substantially trapezoidal shape. The side of the contact area which is furthest away from the centre of the bend lengthens, while the side of the contact area closest to the centre of the bend shortens.
[0005] The "side of the contact area furthest from the centre of the bend" is the side via which the elements of the tread come into contact with the ground in the direction of the rate of drift of the centre of the wheel on which the tyre is mounted. For this reason, it is sometimes referred to as "(transverse) leading edge". The opposite side, that is to say the "side of the contact area closest to the centre of the bend" is sometimes referred to as the "(transverse) trailing edge".
[0006] This "trapezoidal" deformation alters both the load borne by the various ribs of the tread and the contribution that each makes to the transverse force developed by the tyre. For a given load that the tyres of the vehicle have to support in a given cornering situation, the ribs that have become lengthened bear a greater share of the total load borne by the tyre. The ribs which have shortened bear a correspondingly lower proportion of the total load borne by the tyre. For a given transverse force, delivered by one of the tyres in a given cornering situation, it follows that the most heavily loaded ribs (in general, those on the side furthest from the centre of the bend) are those which make the greatest contribution to the total transverse force.
[0007] Rubber compounds suited for use on wet ground are generally more fragile with respect to the very high thermal and mechanical stresses generated in the contact area of a tyre under severe cornering conditions on a dry road surface. If the tread of the tyre is provided with portions made of a rubber compound with better grip on dry ground and with portions made of a rubber compound with better grip on wet ground, then it is preferable to ensure that the rubber compound that has better grip on dry ground is placed on the side of the contact area that is furthest from the centre of the bend. Thus, even if the contact area becomes trapezoidal, the tyre will maintain good grip on dry ground, that is to say a good ability to develop a high transverse force. Further, because the ground contact pressures are higher on this same side of the contact area (which is the furthest from the centre of the bend), the drainage of the water with which the road surface is wetted is generally rather satisfactory in this part of the contact area. As a consequence, conditions that establish good grip contact and that allow use of a rubber compound with better grip on dry ground are created in this region of the tread. In other words, the tyre, in this region, behaves as if it were rolling on dry ground. There is therefore no need to provide in this part of the tread a rubber compound that has better grip on wet ground and of which the performance on dry ground is inferior than that of a rubber compound that has better grip on dry ground. The "Pilot Sport 2" tyre commercialised by Michelin is an example of a tyre that has such a distribution of rubber compounds within its tread. [0008] In spite of the good performance offered by this tyre in terms of grip, there is still an increasing need to improve the compromise between grip on dry ground and grip on wet ground of tyres, and more particularly of tyres designed for sporty road driving.
SUMMARY OF THE INVENTION
[0009] One of the objectives of the present invention is, therefore, to provide a tyre that provides a better compromise between grip on dry ground and grip on wet ground.
[0010] This objective is achieved using a tyre that has a predetermined direction of mounting, in which a portion of that part of the tread that is traditionally reserved for the rubber compounds that have better grip on wet ground is made of a rubber compound that has better grip on dry ground. In other words, a portion of that part of the tread that is situated on that side of the vehicle which faces toward the vehicle when the tyre is mounted on the vehicle in said predetermined direction of mounting (that is to say on the "inside" of the tyre; the corresponding sidewall commonly bearing the inscription "inside" and/or the opposite sidewall commonly bearing the inscription "outside") is made of a rubber compound that has better grip on dry ground.
[001 1 ] More specifically, the objective is achieved using a tyre designed to be mounted on a mounting rim of a wheel of a vehicle and having a predetermined direction of mounting on the vehicle, comprising a tread having a mean radial height HB, comprising a rolling surface designed to come into contact with a ground when the tyre is rolling on the ground, the tread having an outer edge and an inner edge, the outer edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle, the inner edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle, the axial distance between the outer edge and the inner edge defining the axial width L of the tread.
[0012] The tread comprises a first portion made of at least one first rubber compound, the first portion extending, in any radial section, from the outer edge to a first axial position, the axial distance of the first axial position from the outer edge being greater or equal to 20% and smaller or equal than 40% of the axial width L of the tread. [0013] The tread also comprises a second portion made of at least one second rubber compound, the second portion extending, in any radial section, from said first axial position to a second axial position, the axial distance of the second axial position from the outer edge being greater or equal to 50% and smaller or equal than 60% of the axial width L of the tread.
[0014] The tread also comprises a third portion made of at least one third rubber compound, the third portion extending, in any radial section, from said second axial position to a third axial position, the axial distance of the third axial position from the outer edge being greater or equal to 80% and smaller or equal than 90% of the axial width L of the tread.
[0015] Finally, the tread comprises a fourth portion made of at least one fourth rubber compound, the fourth portion extending, in any radial section, from said third axial position to the inner edge of the tread.
[0016] Said first, second, third and fourth portions extend over the entire circumference of the tyre and have an intersection with the rolling surface when the tyre is new or, at the latest, after at most 10% of the height HB has been worn away,
[0017] Said at least one first rubber compound and said at least one third rubber compound contain at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler, and wherein said at least one second rubber compound and said at least one fourth rubber compound contain at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler.
[0018] Said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 0°C, at a stress of 0.7 MPa, that is lower (preferably lower by at least 0.05) than that of said at least one second rubber compound and said at least one fourth rubber compound.
[0019] According to one advantageous embodiment, said portions made of said at least one first, second, third and fourth rubber compounds all have an intersection with the rolling surface when the tyre is new. Thus, the tyre is able to develop its full potential right from first use. [0020] According to another advantageous embodiment, said at least one third rubber compound is identical to said at least one first rubber compound and said at least one fourth rubber compound is identical to said at least one second rubber compound. This embodiment has the notable advantage of simplifying the manufacture of the tyre and the control of stocks of rubber compound at the factory.
[0021 ] According to a third advantageous embodiment, said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 10°C, at a stress of 0.7 MPa, that is higher (preferably higher by at least 0.05) than that of said at least one second rubber compound and said at least one fourth rubber compound. As a matter of fact, the value tan5 of the rubber compound at 10°C, at a stress of 0.7 MPa, neatly characterizes the grip on dry ground.
[0022] According to another advantageous embodiment, the difference between the value of tan5 for said at least one first rubber compound and said at least one second rubber compound is greater than or equal to 0.05, wherein the difference between the value of tan5 for said at least one second rubber compound and said at least one third rubber compound is greater than or equal to 0.05, and wherein the difference between the value of tan5 for said at least one third rubber compound and said at least one fourth rubber compound is also greater than or equal to 0.05. This applies to both the tan5 values at 0°C and the tan5 values at 10°C, as the case may be.
[0023] Of course, it is possible, and even desirable to combine two or more of the embodiments described.
BRIEF DESCRIPTION OF THE DRAWINGS
[0024] Figure 1 depicts a tyre according to the prior art.
[0025] Figure 2 depicts a partial perspective view of a tyre according to the prior art.
[0026] Figure 3 depicts, in radial cross section, a quarter of a tyre according to the prior art.
[0027] Figures 4 and 5 illustrate how the axial edge of a tread is determined.
[0028] Figure 6 illustrates the terms "inner edge" and "outer edge" of a tread. [0029] Figure 7 schematically depicts the crown of a tyre according to the prior art.
[0030] Figure 8 schematically depicts the deformation of a tyre according to the prior art when it experiences substantial transverse stresses.
[0031 ] Figure 9 illustrates the trapezoidal distortion of the contact area of such a tyre.
[0032] Figures 10 and 1 1 illustrate the trapezoidal distortion of the contact area of two tyres mounted on one and the same axle of a vehicle, depending on the direction in which the vehicle is cornering.
[0033] Figures 12 to 14 schematically depict the crown of a tyre according to an embodiment of the invention.
DETAILED DESCRIPTION OF THE DRAWINGS
[0034] When using the term "radial" it is appropriate to make a distinction between various different uses that the person skilled in the art makes of this word. Firstly, the expression refers to a radius of the tyre. It is in that sense that a point P1 is said to be "radially inside" a point P2 (or "radially on the inside of" the point P2) if it is closer to the axis of rotation of the tyre than is the point P2. Conversely, a point P3 is said to be "radially outside" a point P4 (or "radially on the outside of" the point P4) if it is further from the axis of rotation of the tyre than is the point P4. Progress "radially inward (or outward)" will mean progress toward smaller (or larger) radii. In terms of radial distances, it is this sense of the word that applies also.
[0035] By contrast, a thread or a reinforcement is said to be "radial" when the thread or the reinforcing elements of the reinforcement make an angle greater than or equal to 80° and less than or equal to 90° with the circumferential direction. Let us specify that in this document, the term "thread" is to be understood in a very general sense of the word and encompasses threads in the form of monofilaments, multifilaments, a cord, a yarn or an equivalent assembly, irrespective of the material of which the thread is made or of the surface treatment it has undergone to enhance its bonding with the rubber.
[0036] Finally, a "radial cross section" or "radial section" here means a cross section or a section on a plane which contains the axis of rotation of the tyre. [0037] An "axial" direction is a direction parallel to the axis of rotation of the tyre. A point P5 is said to be "axially inside" a point P6 (or "axially on the inside of" the point P6) if it is closer to the median plane of the tyre than is the point P6. Conversely, a point P7 is said to be "axially outside" a point P8 (or "axially on the outside of" the point P8) if it is further from the median plane of the tyre than is the point P8. The "median plane" of the tyre is the plane which is perpendicular to the axis of rotation of the tyre and which lies equal distances from the annular reinforcing structures of each bead.
[0038] A "circumferential" direction is a direction perpendicular both to a radius of the tyre and to the axial direction. A "circumferential section" is a section on a plane perpendicular to the axis of rotation of the tyre.
[0039] Two reinforcing elements are said to be "parallel" in this document when the angle formed between the two elements is less than or equal to 20°.
[0040] What is meant here by "rolling surface" is all the points on the tread of a tyre that come into contact with the ground when the tyre is rolling.
[0041 ] The expression "rubber compound" denotes a compound of rubber containing at least one elastomer and one filler.
[0042] To make the description of the variants shown with the figures easier to read, the same references are used to denote elements that have identical structures.
[0043] Figure 1 schematically depicts a tyre 10 according to the prior art. The tyre 10 comprises a crown comprising a crown reinforcement (not visible in Figure 1 ) surmounted by a tread 40, two sidewalls 30 extending the crown radially inward, and two beads 20 radially inside of the sidewalls 30.
[0044] Figure 2 schematically depicts a partial perspective view of a tyre 10 according to the prior art and illustrates the various components of the tyre. The tyre 10 comprises a carcass reinforcement 60 made up of threads 61 coated with rubber compound, and two beads 20 each comprising annular reinforcing structures 70 which hold the tyre 10 on the rim (not depicted). The carcass reinforcement 60 is anchored in each of the beads 20. The tyre 10 further comprises a crown reinforcement comprising two plies 80 and 90. Each of the plies 80 and 90 is reinforced with thread-like reinforcing elements 81 and 91 which are parallel within each layer and cross from one layer to the next, making angles ranging between 10° and 70° with the circumferential direction. The tyre further comprises a hooping reinforcement 100, arranged radially on the outside of the crown reinforcement, this hooping reinforcement being formed of circumferentially directed spiral-wound reinforcing elements 101 . A tread 40 is laid on the hooping reinforcement; it is this tread 40 that provides contact between the tyre 10 and the road surface. The tyre 10 depicted is a "tubeless" tyre: it comprises an "inner liner" 50 made of a rubber compound impervious to the inflation gas, covering the interior surface of the tyre.
[0045] Figure 3 schematically depicts, in radial cross section, one quarter of a reference tyre 10 of the "Pilot Sport 2" type commercialised by Michelin. The tyre 10 comprises two beads 20 designed to come into contact with a mounting rim (not depicted), each bead 20 comprising a plurality of annular reinforcing structures 70. Two sidewalls 30 extend the beads 20 radially outward and meet in a crown 25 comprising a crown reinforcement formed of a first layer of reinforcing elements 80 and of a second layer of reinforcing elements 90, and radially surmounted by a hooping reinforcement 100, which is itself radially surmounted by a tread 40. The median plane 130 of the tyre is also indicated.
[0046] The way in which the axial edges of a tread are determined is illustrated in Figures 4 and 5 each of which shows the profile of a portion of the tread 40 and of that part of the sidewall 30 that is adjacent to it. In some tyre designs, the transition from tread to sidewall is clear-cut, as in the case depicted in Figure 4, and determining the axial edge 45 of the tread 40 is straightforward. However, there are tyre designs in which the transition between tread and sidewall is continuous. An example is given in Figure 5. The edge of the tread is then determined as follows. The tangent to the rolling surface of the tyre at any point on the rolling surface in the region of transition toward the sidewall is drawn onto a radial cross section of the tyre. The axial edge is the point at which the angle a (alpha) between said tangent and an axial direction is equal to 30°. When there are several points at which the angle a (alpha) between said tangent and an axial direction is equal to 30°, it is the radially outmost point that is adopted. In the case of the tyre depicted in Figure 3, the axial edge 45 has been determined in this way.
[0047] Each layer of reinforcing elements 80 and 90 comprises thread-like reinforcing elements, coated in a matrix formed of rubber compound. The reinforcing elements of each layer are substantially mutually parallel; the reinforcing elements of the two layers cross from one layer to the next at an angle of about 20°, as is well known to those skilled in the art for tyres known as radial tyres.
[0048] The tyre 10 further comprises a carcass reinforcement 60 which extends from the beads 20 through the sidewalls 30 as far as the crown 25. This carcass reinforcement 60 here comprises thread-like reinforcing elements that are directed substantially radially, that is to say that make an angle greater than or equal to 80° and less than or equal to 90° with the circumferential direction.
[0049] The carcass reinforcement 60 comprises a plurality of carcass reinforcing elements; it is anchored in the two beads 20 between the annular reinforcing structures 70.
[0050] Figure 7 schematically depicts the crown of a tyre according to the prior art, designed to be mounted on a mounting rim of a wheel of a vehicle and having a predetermined direction of mounting on the vehicle. This crown notably comprises a tread having a mean radial height HB. The tread comprises a rolling surface 47 designed to come into contact with the ground when the tyre is rolling on the ground.
[0051 ] The tread has an outer edge 45 and an inner edge 46, the outer edge 45 being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle (see Fig. 6), the inner edge 46 being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle (see Fig.6). The axial distance between the outer edge 45 and the inner edge 46 defines the axial width L of the tread,
[0052] The tread comprises a first portion 41 1 made of a first rubber compound. The first portion 41 1 extends, in any radial section, from the outer edge 45 to a first axial position 41 , the axial distance L1 of the first axial position from the outer edge 45 being equal to 40% of the axial width L of the tread. The first portion 41 1 extends around the entire circumference of the tyre and has an intersection with the rolling surface when the tyre is new (unworn).
[0053] The tread also comprises a second portion 412 made of a second rubber compound. The second portion 412 extends, in any radial section, from said first axial position 41 to the inner edge 46 of the tread, The second rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound and a grip on dry ground that is inferior to the grip on dry ground of the first rubber compound. This portion extends over the entire circumference of the tyre and has an intersection with the rolling surface when the tyre is new (unworn).
[0054] Figures 8 and 9 schematically depict the deformation of a tyre 10 according to the prior art, inflated to 3 bar and heavily loaded (load of 7100 N) when it experiences substantial transverse stresses (camber: -4.4°, rate of sideslip: 3 m/s). Figure 8 corresponds to a view in the direction of forward travel of the tyre. The reference 2 indicates the axis of rotation of the tyre 10 and the reference 3 the ground on which the tyre 10 is rolling.
[0055] Figure 9 depicts the footprint of the tyre 10 on the ground 3. To a first approximation, this footprint is in the shape of a trapezium 4 the long side 5 of which is the side furthest from the centre of the bend being taken by the vehicle on which the tyre 10 is mounted. Because the grip of the tyre is greater on dry ground than on wet ground, the transverse forces that the tyre may experience are also greater on dry ground and the trapezoidal deformation is more pronounced. It is, therefore, advantageous to ensure that the portion of rubber compound with better grip on dry ground is on that side of the contact area that is furthest from the centre of the bend, as is the case in the tyre depicted in Figure 7. By providing a portion made of rubber compound with better grip on wet ground on that side of the contact area that is closest to the centre of the bend, an advantageous compromise can be reached between the grip of the tyre on dry ground and on wet ground.
[0056] In defining a tyre according to the invention, a distinction has been made between that side of the tyre which, when the tyre is mounted on the vehicle in its predetermined direction of mounting, faces toward the outside of the vehicle, and that side of the tyre that faces toward the vehicle when the tyre is mounted on the vehicle in its predetermined direction of mounting. In the previous paragraph, by contrast, the physical effects have been explained with reference to the sides furthest from and closest to the centre of the bend. Of course, these distinctions do not correspond to one another, because reference to the centre of the bend depends on the direction of the bend (whether the vehicle is cornering to the left or to the right) whereas the side facing toward the outside of the vehicle and the side facing in toward the vehicle do not depend on this. This apparent difficulty may be explained using Figures 10 and 1 1 . [0057] Figure 10 illustrates the trapezoidal deformation of the contact area of two tyres 1 1 and 12 mounted on one and the same axle 7 of a vehicle, viewed upward from the ground on which the tyres are rolling. The case being considered is a left-hand bend (when considered from the point of view of the driver of the vehicle), that is to say a bend in the direction indicated using the arrow 151 . The tyres 1 1 and 12 have been mounted in their predetermined directions of mounting: the inner edges 46 of their treads are on the side facing in toward the body of the vehicle (the body is not depicted), and the outer edges 45 facing toward the outside of the vehicle. Strictly speaking, the situation is optimized only for the tyre 1 1 because the rubber compound with better grip on dry ground, which is on the outer edge 45 side, is on the side furthest from the centre of the bend. By contrast, for the tyre 12, the rubber compound with better grip on dry ground is on the side closest to the centre of the bend. As has been depicted in Figure 1 1 , the situation reverses when the driver corners to the right (from his point of view) that is to say in the direction indicated using the arrow 152. In Fig. 1 1 it is the tyre 12 that is best suited. Whatever the direction of the bend, there is always one tyre that "does not suit". Because an ordinary vehicle corners as often to the left as to the right, it is none the less preferable to favour the tyre that is on the side furthest from the centre of the bend, because it is that tyre which bears more load and has the greater contact area. It is that tyre which, therefore, plays a dominant part in the overall grip of the vehicle. Therefore, such an arrangement corresponds to an advantageous compromise for vehicles that corner as often to the right as to the left. In the infrequent case of a vehicle that turns always in the same direction (for example a vehicle that is exclusively used to cover a circular circuit in just one direction), it would be possible to optimize the mounting of the tyres to ensure that the rubber compound with the better grip on dry ground is always on the side furthest from the centre of the bend.
[0058] An embodiment of the invention provides a way to improve the overall grip performance still further and, more particularly, to improve the compromise between grip on dry ground and grip on wet ground. This objective is achieved using a tyre that has a predetermined direction of mounting, in which a portion of that part of the tread that is traditionally reserved for the rubber compounds that have better grip on wet ground is made of a rubber compound that has better grip on dry ground. In other words, a portion of that part of the tread that is situated on that side of the vehicle which faces toward the vehicle when the tyre is mounted on the vehicle in the predetermined direction of mounting (that is to say on the "inside" of the tyre; the corresponding sidewall commonly bearing the inscription "inside" and/or the opposite sidewall commonly bearing the inscription "outside") is made of a rubber compound that has better grip on dry ground.
[0059] Figure 12 schematically depicts the crown of a tyre according to an embodiment of the invention. This crown notably comprises a tread of axial width L and mean radial height HB. The tread comprises a rolling surface 47 designed to make contact with the ground when the tyre is rolling on the ground.
[0060] The tread has an outer edge 45 and an inner edge 46, the outer edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle (see figure 6), the inner edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle (see figure 6). What has been said above on the determination of the exact position of the outer edge 45 and the inner edge 46 also applies to a tyre according to an embodiment of the invention. The axial distance between the outer edge 45 and the inner edge 46 defining the axial width L of the tread.
[0061 ] The tread comprises a first portion 41 1 made of a first rubber compound, the first portion extending, in any radial section, from the outer edge 45 to a first axial position 41 . The axial distance L1 of the first axial position 41 from the outer edge 45 is equal to 40% of the axial width L of the tread, The first rubber compound is a compound that has good grip on dry ground : it contains at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler.
[0062] The tread comprises a second portion 412 made of a second rubber compound, the second portion 412 extending, in any radial section, from said first axial position 41 to a second axial position 42. The axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 60% of the axial width L of the tread, The second rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound : it contains at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler. [0063] The tread also comprises a third portion 413 made of a third rubber compound, the third portion 413 extending, in any radial section, from said second axial position 42 to a third axial position 43. The axial distance L3 of the second axial position 43 from the outer edge 45 is equal to 80% of the axial width L of the tread, The third rubber compound contains at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN 1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler. In the present embodiment, the first and third rubber compounds have the same composition, which is advantageous from the manufacturing point of view. None the less, it is possible to have a third rubber compound that differs from the first rubber compound.
[0064] Finally, the tread also comprises a fourth portion 414 made of a fourth rubber compound, the fourth portion 414 extending, in any radial section, from said third axial position 43 to the inner edge 46 of the tread. The fourth rubber compound has a grip on wet ground that is superior to the grip on wet ground of the first rubber compound : it contains at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler. In the present embodiment, the second and fourth rubber compounds have the same composition, which is advantageous from the manufacturing point of view. None the less, it is possible to have a fourth rubber compound that differs from the second rubber compound.
[0065] Said first, second, third and fourth portions extend over the entire circumference of the tyre and have an intersection with the rolling surface 47 when the tyre is new (unworn).
[0066] The first and third rubber compound have a value for tan5 at 0°C, at a stress of 0.7 MPa, that is lower than that of the second and fourth rubber compounds.
[0067] Figure 13 schematically depicts the crown of a tyre according to another embodiment of the invention. Unlike the case of the tyre depicted in Figure 12, the axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 50% of the axial width L of the tread and the axial distance L3 of the third axial position 43 from the outer edge 45 is equal to 90% of the axial width L. This figure also illustrates that in a tyre according to an embodiment of the invention, the transitions between the various compounds do not necessarily lie at a circumferential groove. [0068] Figure 14 schematically depicts the crown of a tyre according to another embodiment of the invention. Here, the axial distance L1 of the first axial position 41 from the outer edge 45 is equal to 30% of the axial width L, the axial distance L2 of the second axial position 42 from the outer edge 45 is equal to 55% of the axial width L, and the axial distance L3 of the third axial position 43 from the outer edge 45 is equal to 85% of the axial width L.
[0069] Table 1 gives, by way of example, the composition of rubber compounds that can be used. The composition is given in pee ("per cent elastomer") that is to say in parts by weight for 100 parts by weight of elastomer.
Figure imgf000015_0001
Table I [0070] Notes for Table I:
[1 ] SSBR with 40% styrene, 48% 1 -4 trans polybutadiene groups
[2] Carbon black series 230 (ASTM)
[3] TDAE ("treated distillate aromatic extract") oil
[4] N-(1 ,3-dimethylbutyl)-N'-phenyl-p-phenylenediamine
[0071 ] The rubber compounds are preferably based on at least one diene elastomer, one reinforcing filler and a crosslinking system.
[0072] What is meant by a "diene" elastomer (or interchangeably rubber) is, in the known way, an elastomer derived at least in part from (i.e. a homopolymer or a copolymer of) diene monomers, that is to say monomers bearing two carbon-carbon double bonds, conjugated or otherwise. The diene elastomer used is preferably chosen from the group consisting of polybutadienes (BR), natural rubber (NR), synthetic polyisoprenes (IR), styrene butadiene copolymers (SBR), isoprene-butadiene copolymers (BIR), isoprene-styrene copolymers (SIR), butadiene-styrene-isoprene copolymers (SBIR) and blends of these elastomers.
[0073] One preferred embodiment is to use an "isoprene" elastomer, that is to say a homopolymer or copolymer of isoprene, or in other words, a diene elastomer chosen from the group consisting of natural rubber (NR), synthetic polyisoprenes (IR), the various copolymers of isoprene and blends of these elastomers.
[0074] The isoprene elastomer is preferably natural rubber or a synthetic polyisoprene of the cis-1 ,4 type. Of these synthetic polyisoprenes, use is preferably made of polyisoprenes that have a cis-1 ,4 bond content (mol%) in excess of 90%, or more preferably still, in excess of 98%. According to other preferred embodiments, the diene elastomer may consist, in full or in part, of another diene elastomer such as, for example, an SBR (E-SBR or S-SBR) elastomer used in combination or otherwise with another elastomer for example of the BR type.
[0075] The rubber composition may also contain all or some of the additives conventionally employed in the rubber matrices used for the manufacture of tyres, such as, for example, reinforcing fillers such as carbon black or inorganic fillers such silica, coupling agents for inorganic fillers, anti-aging agents, antioxidants, plasticizers or extender oils, whether the latter are of aromatic or non-aromatic nature (notably oils that are only very slightly aromatic or non-aromatic, for example of the naphthene or paraffin type, with a high or preferably low viscosity, MES or TDAE oils, plasticizing resins with a high Tg in excess of 30°C), agents that improve the processability of the compositions in the green state, tackifying resins, a crosslinking system based either on sulphur or sulphur donors and/or peroxides, accelerators, vulcanization activators or retarders, anti-reversion agents, methylene acceptors and donors such as, for example, HMT (hexamethylenetetramine) or H3M (hexamethoxymethylmelamine), reinforcing resins (such as resorcinol or bismaleimide), known adhesion promoting systems of the metal salt type, for example, notably cobalt or nickel salts.
[0076] The compositions are manufactured in appropriate mills, using two successive phases of preparation well known to those skilled in the art, namely a first phase of thermomechanical work or kneading (the so-called "non-productive" phase) at high temperature, up to a maximum temperature of between 1 10°C and 190°C, preferably between 130°C and 180°C, followed by a second phase of mechanical work (the so- called "productive" phase) down to a lower temperature, typically of less than 1 10°C, during which finishing stage the crosslinking system is incorporated.
[0077] By way of example, the non-productive phase is conducted in a single thermomechanical step lasting a few minutes (for example between 2 and 10 min) during which all the required basic ingredients and other additives, apart from the crosslinking or vulcanizing system, are introduced into an appropriate mixer such as a conventional internal mixer. Once the compound thus obtained has cooled, the vulcanizing system is then incorporated with it in an external mixer such as an open mill kept at a low temperature (for example between 30°C and 100°C). This is then blended (productive phase) for a few minutes (for example for between 5 and 15 min).
[0078] Vulcanizing (or curing) may be performed in the known way at a temperature generally between 130°C and 200°C, preferably under pressure, for a sufficient length of time which may vary, for example, between 5 and 90 min depending in particular on the curing temperature, on the vulcanizing system adopted and on the vulcanization dynamics of the composition considered.
[0079] Table II gives the properties of the rubber compounds the composition of which is given in Table I Compound with better Compound with better
grip on dry ground grip on wet ground tan5 at O°C, at 0.7 MPa 0.76 0.88 tan5 at 10°C, at 0.7 MPa 0.69 0.58
Table II
[0080] These properties are measured with a viscoanalyser (Metravib VA4000), in accordance with standard ASTM D 5992-96. The response of a test specimen of vulcanized composition (a cylindrical test specimen 4 mm thick and 400 mm2 in section) subjected to simple alternating sinusoidal shear stresses at a frequency of 10 Hz, during a temperature sweep between 0° and 100°C, under a fixed stress of 0.7 MPa, is recorded, particularly the value of tan5 observed at 0°C and the values of tan5 observed at 10°C.
[0081 ] It will be recalled that, as is well known to those skilled in the art, the value of tan5 at 0°C is representative of the potential to grip on wet ground: the higher tan5 at 0°C, the better the grip. The values of tan5 at temperatures higher than 10°C are representative of the hysteresis of the material and of the potential to grip on dry ground.
[0082] To return to the compounds the composition of which is given in Table I, it may be seen that the second composition has a value of tan5 at 0°C (imposed stress 0.7 MPa) that is higher by comparison with the first composition, indicating that its grip on wet ground will be superior; and has a value of tan5 at 10°C that is lower by comparison with the first composition, indicating that the grip on dry ground would be inferior.
[0083] Tests were carried out using a Porsche 997 fitted with Pilot Super Sport tyres, size 245/35 R20 (on the front) and 295/30 R20 (on the rear). A tyre equipped with a tread as depicted in Figure 12 was compared against a reference tyre equipped with a tread as depicted in Figure 7. The rubber compounds of Table I were used. The tyres according to the invention saved an average of 1 second per lap (on the Nardo (Italy) "handling" circuit with a circuit length of 6.2 km) on dry ground, at the expense of just 0.2 seconds per lap on wet ground. These improved times were backed by the subjective assessment of the drivers who reported better grip on dry ground and substantially unchanged grip on wet ground. The invention therefore provides a better compromise between grip on dry ground and grip on wet ground.

Claims

1 . Tyre (10) designed to be mounted on a mounting rim of a wheel of a vehicle (200) and having a predetermined direction of mounting on the vehicle, comprising: a tread (40) having a mean radial height HB, comprising a rolling surface (47) designed to come into contact with a ground (3) when the tyre is rolling on the ground, the tread having an outer edge (45) and an inner edge (46), the outer edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the outside of the vehicle, the inner edge being situated on that side of the tyre which, when the tyre is mounted on the vehicle in said predetermined direction of mounting, faces toward the vehicle, the axial distance between the outer edge (45) and the inner edge (46) defining the axial width L of the tread,
the tread comprising a first portion (41 1 ) made of at least one first rubber compound, the first portion extending, in any radial section, from the outer edge (45) to a first axial position, the axial distance of the first axial position from the outer edge being greater or equal to 20% and smaller or equal than 40% of the axial width L of the tread,
the tread comprising a second portion (412) made of at least one second rubber compound, the second portion extending, in any radial section, from said first axial position to a second axial position, the axial distance of the second axial position from the outer edge being greater or equal to 50% and smaller or equal than 60% of the axial width L of the tread,
the tread comprising a third portion (413) made of at least one third rubber compound, the third portion extending, in any radial section, from said second axial position to a third axial position, the axial distance of the third axial position from the outer edge being greater or equal to 80% and smaller or equal than 90% of the axial width L of the tread,
the tread comprising a fourth portion (414) made of at least one fourth rubber compound, the fourth portion extending, in any radial section, from said third axial position to the inner edge (46) of the tread, wherein said first, second, third and fourth portions extend over the entire circumference of the tyre and have an intersection with the rolling surface when the tyre is new or, at the latest, after at most 10% of the height HB has been worn away, wherein said at least one first rubber compound and said at least one third rubber compound contain at least one elastomer and at least one reinforcing filler containing a carbon black, the carbon black representing a percentage PN 1 greater than or equal to 50% and less than or equal to 100% of the weight of all of the reinforcing filler, and wherein said at least one second rubber compound and said at least one fourth rubber compound contain at least one elastomer and at least one reinforcing filler, possibly including a carbon black, the carbon black representing a percentage PN2 greater than or equal to 0% and less than or equal to 50% of the weight of all of the reinforcing filler, and wherein said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 0°C, at a stress of 0.7 MPa, that is lower than that of said at least one second rubber compound and said at least one fourth rubber compound.
2. Tyre according to Claim 1 , wherein said portions (41 1 , 412, 413, 414) made of said at least one first, second, third and fourth rubber compounds all have an intersection with the rolling surface when the tyre is new.
3. Tyre according to one of Claims 1 and 2, wherein said at least one third rubber compound is identical to said at least one first rubber compound and wherein said at least one fourth rubber compound is identical to said at least one second rubber compound.
4. Tyre according to any one of Claims 1 to 3, wherein said at least one first rubber compound and said at least one third rubber compound have a value for tan5 at 10°C, at a stress of 0.7 MPa, that is higher than that of said at least one second rubber compound and said at least one fourth rubber compound.
5. Tyre according to any one of Claims 1 to 4, wherein the difference between the value of tan5 for said at least one first rubber compound and said at least one second rubber compound is greater than or equal to 0.05, wherein the difference between the value of tan5 for said at least one second rubber compound and said at least one third rubber compound is greater than or equal to 0.05, and wherein the difference between the value of tan5 for said at least one third rubber compound and said at least one fourth rubber compound is also greater than or equal to 0.05.
PCT/EP2010/070054 2009-12-22 2010-12-17 Tyre with improved tread WO2011076680A1 (en)

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US13/518,795 US9302546B2 (en) 2009-12-22 2010-12-17 Tire with improved tread
CN201080058559.XA CN102686413B (en) 2009-12-22 2010-12-17 Tyre with improved tread
BR112012015426A BR112012015426A8 (en) 2009-12-22 2010-12-17 PNEUMATIC WITH IMPROVED TREAD.
JP2012545254A JP5655092B2 (en) 2009-12-22 2010-12-17 Tire with improved tread
EP10794989.3A EP2516180B1 (en) 2009-12-22 2010-12-17 Tire with improved tread
RU2012131172/11A RU2529041C2 (en) 2009-12-22 2010-12-17 Tire with perfected tread

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