WO2011035715A1 - Iron removal purification device with magnetic field and its application of condensed water and water supply in power plant - Google Patents

Iron removal purification device with magnetic field and its application of condensed water and water supply in power plant Download PDF

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Publication number
WO2011035715A1
WO2011035715A1 PCT/CN2010/077206 CN2010077206W WO2011035715A1 WO 2011035715 A1 WO2011035715 A1 WO 2011035715A1 CN 2010077206 W CN2010077206 W CN 2010077206W WO 2011035715 A1 WO2011035715 A1 WO 2011035715A1
Authority
WO
WIPO (PCT)
Prior art keywords
permanent magnet
iron
sleeve
water
magnetic field
Prior art date
Application number
PCT/CN2010/077206
Other languages
French (fr)
Chinese (zh)
Inventor
张子楠
Original Assignee
Zhang Zinan
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN200910176939A external-priority patent/CN101648743A/en
Priority claimed from CN200910176938A external-priority patent/CN101648742A/en
Application filed by Zhang Zinan filed Critical Zhang Zinan
Publication of WO2011035715A1 publication Critical patent/WO2011035715A1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/58Treatment of water, waste water, or sewage by removing specified dissolved compounds
    • C02F1/62Heavy metal compounds
    • C02F1/64Heavy metal compounds of iron or manganese
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • C02F1/488Treatment of water, waste water, or sewage with magnetic or electric fields for separation of magnetic materials, e.g. magnetic flocculation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • C02F2101/203Iron or iron compound

Definitions

  • the present invention relates to a magnetic field iron removal apparatus for separating iron impurities in water, and a specific application of such apparatus in power plant steam turbine condensate and boiler (nuclear power plant steam generator) feed water.
  • Boilers in power plants or steam generators in nuclear power plants
  • the soda pipes and their associated thermal equipment are made of iron-based materials, which generate a large amount of solid iron corrosion products during operation and become the main water Harmful impurities, these solid iron impurities will deposit on the evaporation surface of the boiler (nuclear power plant steam generator) or other thermal system pipelines, which will affect the heat transfer to the pipe wall and overheat the pipe wall. It will cause corrosion under scale, overheating and corrosion are the main causes of tube explosion accidents in boilers.
  • the flow of solid impurities in the steam pipe will cause erosion damage to the pipe wall valves.
  • These solid impurities in the feed water directly affect the boiler (nuclear power plant).
  • the steam generator is safe to operate.
  • the power plant attaches great importance to the decontamination of condensate and boiler feed water.
  • there is no iron removal device in the water supply system Only various forms of chemistry can be set in the condensate system in front of the water supply system.
  • the "fine treatment" device for iron purification equipment and various types of front-mounted iron removers here, by trying to improve the quality of condensate purification, the shortage of the purification device in the water supply system is compensated.
  • all of the filter materials such as resins and fibers are used, and the adsorption and filtration of these substances are used to remove iron impurities in the water.
  • the traditional thermal cycle system of the power plant and the process of removing the iron are: After the steam works in the steam turbine, the steam is condensed into condensed water in the condenser, and the condensed water passes through the condensate pump outside the condenser to increase the pressure, and the condensate Send to the condensate purification and heating device, first enter the chemical de-ironing equipment "fine treatment" to remove the iron from the condensate, "fine treatment” in the traditional power plant thermal system becomes the only iron removal device in the condensate and water supply system Then, the condensed water enters the boiler feed water system through the low-pressure heater and the deaerator deaeration water tank, and the feed water is heated by the boiler to become steam to push the steam turbine to work, and the above-mentioned steam-water thermodynamic cycle process begins. Power Generation It is customary to say that the iron removal system managed by the chemical profession is a chemical iron removal method. It is currently widely used in the world to remove iron, but the disadvantages
  • the main purpose of water purification of power plants is to protect the heating surface of boilers (steam generators of nuclear power plants). Therefore, the iron removal purification equipment should theoretically be located in the water supply system closest to the boiler (the steam generator of the nuclear power plant).
  • the traditional iron removal technology uses a polymer material such as resin as the filter material.
  • the temperature of the filter material generally does not exceed 75 °C, so the chemical iron removal method can only be used at lower temperatures.
  • the "fine treatment" is established in the condensate system.
  • the iron removal device performs iron removal and purification on the condensed water, but the iron removal purification device cannot be established in the water supply system with the working temperature above 150 °C, but the condensed ice is "finished," After the device is cleaned, it is further polluted by the low-pressure heater and various hydrophobic pollution, so there is no purification device.
  • the contaminated condensate directly enters the water supply system and enters the boiler.
  • the critical unit requires "fine treatment”.
  • the iron content of the condensed water after treatment is less than 5ppb, and the iron content of the feed water is less than l Oppb. On the contrary, it is lower than the standard of condensate, which means that there is no iron removal device in the water supply, and it has to be relaxed.
  • the primary object of the present invention is to provide a magnetic field iron removal apparatus for separating iron impurities in water, and the present invention further provides a specific embodiment of such a device in a power plant condensate and feed water.
  • the condensed water magnetic field iron removal device is installed in the steam turbine workshop condenser of the power plant, and the power supply magnetic field iron removal purification device of the power plant is installed in the oxygen removal water tank. According to the ferromagnetic phase suction principle, the iron impurities in the water flowing through are separated, thereby realizing the iron removal purification of water.
  • the magnetic field de-iron purification device is installed in the condenser, and the condensed water is desulfurized at the source for the first time; the magnetic field iron removal purification device is installed in the deaerating water tank, and the boiler is realized for the first time (nuclear power plant) Steam generator) The iron removal of the feed water.
  • the basic constituent unit constituting the magnetic field iron-removing device of the present invention is a permanent magnet tube, which comprises a sleeve and a plurality of permanent magnets fixed in the sleeve, the sleeve is made of a non-magnetic material, and a plurality of permanent magnets are
  • the length direction of the sleeve is arranged in sequence or arranged in a ring shape along the circumference of the sleeve.
  • the polarity direction of the permanent magnets is the direction of arrangement, and the polarities of the adjacent ends of the adjacent permanent magnets are the same, so that the effective adsorption area of the iron impurities is spread over the sleeve.
  • the effective adsorption zone of the iron impurities refers to a portion where the magnetic lines of the permanent magnets on the surface of the sleeve are respectively concentrated, and the portions are respectively associated with the permanent magnets
  • the position where the magnetic pole is located corresponds.
  • the magnetic field iron removal purifying device of the invention is composed of a plurality of permanent magnet tubes through a frame, and the effective adsorption ranges of the permanent magnet tubes for the iron impurities in the water are sequentially connected in space, thereby forming a magnetic field of a plurality of permanent magnet tubes.
  • the range in which the impurity is adsorbed onto the surface thereof is a three-dimensional space surrounding the permanent magnet tube.
  • a plurality of permanent magnets By arranging a plurality of permanent magnets in the permanent magnet tube and making the adjacent ends of the adjacent permanent magnets have the same polarity, as in the permanent magnet tube, a plurality of permanent magnets whose magnetic fields are independent of each other and do not affect each other are arranged.
  • the use of several such permanent magnet tubes to construct a purification device is equivalent to constructing a large magnetic field filter required by thousands of small magnetic fields that do not affect each other. This structure ensures the magnetic field range. Covering all corners of the entire network, the entire device structure is simple and easy to implement.
  • the device When the magnetic field iron removal purifying device of the invention is used for iron removal purification of power plant condensed water, the device may be disposed above the water outlet of the steam turbine condenser hot water well, and according to the water flow direction at the water outlet, through the frame a plurality of permanent magnet tubes are combined into a hollow annular or lower end opening, and a cover shape of a permanent magnet tube is arranged around and at the top; when the water flow in the hot water well flows into the water outlet from the periphery, the water flowing into the water outlet is used by the annular purifying device
  • the cover-shaped structure purifying device In the iron removal purification, when the water flow in the hot water well flows into the water outlet from the periphery and the upper portion at the same time, the water flowing into the water outlet is subjected to iron removal purification by the cover-shaped structure purifying device with the cover buckle above the water outlet.
  • the device When the magnetic field iron removal purifying device of the invention is used for iron removal purification of a power supply boiler boiler water supply system, the device can be installed in an oxygen removal water tank, and according to the internal flow rate of the oxygen removal water tank and the direction of the water flow, a plurality of pieces are permanently passed through the frame.
  • the magnetic tube assembly is formed into a body grid structure, which is composed of a plurality of horizontally arranged planar units and a plurality of vertically disposed planar units, each of which is composed of a plurality of permanent magnet tubes through a frame.
  • a plurality of horizontally disposed planar units are disposed in parallel with each other, and a plurality of vertically disposed planar units are also disposed in parallel with each other.
  • the traditional chemical iron removal method is: using the resin and fiber as the filter material and establishing a separate and dedicated large pressure-bearing equipment to purify the water
  • the present invention is a conventional heat equipment condenser with only a single storage water function.
  • the well and the deaerating water tank skillfully increase the iron removal function, and realize the iron removal and purification of the condensed water and the feed water by using the condenser and the oxygen removal water tank respectively.
  • the potential of thermal equipment has also created a new way to remove iron from the original thermal equipment of the power plant.
  • the complementary coexistence of the two methods has promoted the improvement of water purification technology in power plants.
  • the condensate removal iron removal device installed in the condenser establishes the only condensate de-ironing device before the steam turbine generator set starts, the chemical “fine treatment” iron removal device is not put into operation, and the condensed water is realized.
  • the source is de-purified, speeding up water purification, reducing water discharge and unit start-up process; it becomes a chemical de-ironing method in the normal operation of the unit, and the front-mounted iron remover of the unit is lightened.
  • the burden of “fine treatment” prolongs the service life and replacement time of the resin, which not only improves the “fine treatment, economical operation, but also contributes to the improvement of the quality of the refined water purification”.
  • the iron removal purification device installed in the deaerator tank the iron removal purification device was established in the boiler feed water system for the first time, which realized the iron removal purification of the feed water, and ended the history of the power supply system without purification device.
  • the traditional purification method uses resin and fiber as the filter material to filter and adsorb impurities in the water.
  • the resin and fiber need to be regenerated, replaced, and discarded.
  • the cost is high and the environment is also polluted.
  • the device uses the permanent magnetic field to screen out the iron impurities in the water.
  • the use of magnetic energy to remove iron like the use of wind energy, solar energy to get the benefits of nature, and the magnetic field is a permanent magnet, can be reused and high precision in iron removal, is environmentally friendly, does not consume other energy, water purification technology.
  • the device adopts the submersible design, uses the magnetic field technology to develop the container space, and establishes the invisible iron removing device in the underwater space of the thermal container without occupying the ground of the workshop. This is a very compact power plant.
  • the contradiction between the establishment of equipment and the land occupation has been successfully solved, and it is also a typical design of compact layout and land saving.
  • the traditional chemical iron removal purification device needs to use a water pump to provide the power of the water flow in order to overcome the resistance of the filtration device, which consumes electric energy; and the demagnetization magnetic field of the device is selected to be established on the flow path of the water flow flowing from top to bottom.
  • the iron removing device does not need to establish a driving water pump; at the same time, the iron removing device installed in the container uses the casing of the original container as the casing, and is no longer
  • the special outer casing structure is provided, and the magnetic component with the iron removing function is mechanically connected with the original heat container member to form a stable iron removing device, which not only saves energy, reduces the cost, but also makes the iron removing system simpler and easy to popularize.
  • 1 is a schematic view showing a first structural type of a permanent magnet tube used in a magnetic field iron removal purifying apparatus of the present invention
  • 2 is a schematic view showing a second structure of a permanent magnet tube
  • FIG. 3 is a schematic diagram of a system for applying a magnetic field iron removal purification device to a condenser according to the present invention
  • FIG. 4 is a schematic view showing a first structural type of the magnetic field iron removal purification device used in the system shown in FIG.
  • Figure 6 is a schematic view showing a second structural type of the magnetic field iron removing apparatus used in the system shown in Figure 3;
  • Figure 7 is a schematic view showing a third structural type of the magnetic field removing iron purifying apparatus used in the system shown in Figure 3;
  • 3 is a schematic diagram of a fourth structural type of the magnetic field removing iron purifying device used in the system shown in FIG. 3;
  • FIG. 9 is a schematic view showing a system for applying the magnetic field iron removing and purifying device to the oxygen scavenging water tank according to the present invention;
  • FIG. 10 is an AA view of FIG.
  • Figure 11 is a left side view of the magnetic field iron removing apparatus shown in Figure 10;
  • Figure 12 is a top view of the state shown in Figure 11 of the magnetic field iron removal purifying device
  • Figure 13 is a schematic diagram of the wavy arrangement of the permanent magnet tube.
  • the permanent magnet tube 5 used in the magnetic field iron removal apparatus of the present invention comprises a sleeve 2 and a sleeve fixedly enclosed with a plurality of permanent magnets 3, and the sleeve 2 is a circular tube, which is made of stainless steel or aluminum alloy.
  • a plurality of cylindrical permanent magnets 3 are arranged in the longitudinal direction of the sleeve 2, the polar directions of the permanent magnets 3 are arranged in the direction of alignment, and the adjacent ends of the adjacent permanent magnets 3 have the same polarity, thereby forming an edge
  • the magnetic lines of the permanent magnets 3 at the two ends are guided through the side wall of the sleeve 2 to form a circuit.
  • the two ends of the sleeve 2 are also specially provided with a guide plate 4' made of a magnetically permeable material, and the ends of the sleeve 2 are sealed by a cover plate 1 The gas seal is blocked, and the sealing plate 1 is made of a non-magnetic material.
  • the sealing plate can be fixed to the sleeve 2 by an interference fit, or can be welded and fixed by the argon arc welding and the sleeve 2, and the permanent magnet 3 is required according to the need.
  • Figure 2 shows the first structural version of the permanent magnet tube 5, in addition to this, the permanent magnet tube 5 is also made in Figure 3.
  • the permanent magnet 3 is partially annular, and the plurality of permanent magnets 3 are circumferentially arranged in a ring shape matching the inner diameter of the sleeve 2, and the magnetic pole direction of the permanent magnet 3
  • the circumferential directions of the two adjacent permanent magnets 3 are the same, thereby forming a problem of SS-Li SS magnetic pole distribution arranged along the circumference of the sleeve, and two adjacent permanent magnets 3 in the circumferential direction.
  • a separator 4 made of a magnetically permeable material is also provided.
  • the permanent magnet 3 in the above second structure type can be manufactured in sections along the longitudinal direction of the permanent magnet tube 5 for the convenience of processing.
  • the magnetic lines of the permanent magnets 3 are individually pierced and penetrated into the side wall of the sleeve to form a loop, thereby ensuring the magnetic field of each permanent magnet 3.
  • Independence also ensures the independence of the adsorption function and range of action of each permanent magnet 3 on the ferrous material.
  • This type of structure makes the effective adsorption zone of the iron impurities corresponding to the magnetic poles of each permanent magnet 3 spread over the circumferential and full length of the casing surface, ensuring that the permanent magnet tube 5 can effectively form iron impurities throughout its length. Adsorption.
  • the magnetic pole of the magnet has the strongest adsorption force to the ferrous material. Therefore, the so-called effective impurity adsorption region of the iron impurity refers to a portion on the surface of the sleeve 1 corresponding to the position of the magnetic poles of the permanent magnets 3, and also That is, the magnetic lines of the respective permanent magnets 3 are each concentrated at a portion of the side wall of the sleeve 2.
  • the effective adsorption zone of the iron impurities on the permanent magnet tube shown in Fig. 2 is a ring surrounded by the circumferential direction of the permanent magnet tube, and the width of the ring and its distribution on the surface of the permanent magnet tube The thickness and position of the partition correspond.
  • the effective adsorption zone of the iron impurities on the permanent magnet tube shown in Fig. 3 is a plurality of strips distributed uniformly along the circumference of the sleeve 2, the strips extending along the length of the sleeve, the width of each strip and the circumference of the sleeve 2 The position corresponds to the thickness and position of the partition 4.
  • the permanent magnet tubes 5 of the above two types of structures are all round tubes, and in addition, the permanent magnet tubes 5 may also be square tubes or tubes of other cross-sectional shapes. Since each of the permanent magnet tubes 5 has a plurality of small magnetic fields formed by the permanent magnets therein, and the small magnetic fields have independent functions on the adsorption function and the range of action of the iron materials, and thus, the plurality of roots are passed through the frame.
  • the magnetic tube 5 is combined to construct a combined magnetic field formed by splicing a plurality of small magnetic fields, and the combined magnetic field can be used to perform iron removal treatment on the water flowing through.
  • the magnetic field iron removal apparatus of the present invention is proposed based on this idea.
  • the adsorption force of the magnet on the iron impurities in the water is related to the distance between the two, the farther the distance is, the smaller the adsorption force is. Therefore, in order to ensure the reliable adsorption of the iron shield in the water
  • the distance between adjacent permanent magnet tubes can be adjusted according to the specific conditions of the iron impurities in the water to be treated, the flow rate of the water flow, etc., so that The effective adsorption ranges of adjacent permanent magnet tubes are connected or partially overlapped.
  • the effective adsorption range refers to a range in which the permanent magnet tube 5 can reliably adsorb iron impurities to its surface, which is a three-dimensional space surrounding the permanent magnet tube.
  • FIG. 3 shows a specific application of the magnetic field iron removal purifying apparatus of the present invention in a power plant condenser.
  • the magnetic field iron removal purifying apparatus of the present invention is used for de-ironing purification of power plant condensed water.
  • the condensed water magnetic field iron removal device 8 is installed in the hot water well 7 of the condenser 6, and is located above the water outlet of the hot water well, and the condensed water in the hot water well 7 flows out through the ice outlet. The well is sent to the next link by the condensate pump 9.
  • the condensed water magnetic field removing iron cleaning device 8 can be made into a cofferdam type annular structure having a sufficient height as shown in Figs.
  • the front, rear, left, and right planes of the square ring can be assembled into four rectangular plane units 10 as shown in FIG. 5, and then four.
  • the rectangular planar units 10 are combined into a square ring.
  • the rectangular planar unit 10 is formed by combining a plurality of permanent magnet tubes 5 arranged in parallel with each other through a frame U, and the magnetic field effective adsorption ranges of the adjacent two permanent magnet tubes 5 are connected or partially overlapped.
  • the permanent magnet tubes 5 can be directly combined by using the upper and lower frames 1 1 .
  • the magnetic field iron removing device 8 of the annular structure After the magnetic field iron removing device 8 of the annular structure is disposed above the water outlet of the hot water well, the iron impurities in the water are adsorbed to the permanent magnet tube as the condensed water flows from the periphery through the gap between the permanent magnet tubes 5 into the water outlet. On the surface of 5, the water is purified.
  • the hot water well for the condensed water flowing from the periphery and the upper side to the water outlet can be made into a condensed water magnetic field removing iron cleaning device 8 as shown in Figs. 6 and 8 at the lower end opening, and the permanent magnet tube 5 is arranged at the periphery and the top.
  • the hood structure is arranged.
  • the structure shown in FIG. 6 has a top rectangular plane. Yuan.
  • the structure shown in Fig. 8 has a top circular planar unit.
  • the device can perform iron removal and purification treatment on the condensed water flowing into the water outlet from the periphery and the upper side.
  • the condenser hot water well it is a magnetic field iron removal device with a ring structure, or a magnetic field iron removal device with a cover structure, and the area of the concrete, depending on the shape of the water flow section in the hot water well. And condensate flow.
  • the water flow should be cleaned at full flow, that is, the magnetic field should be completely closed on the water flow section.
  • Figure 9 shows the specific application of the magnetic field iron removal purification device of the present invention in a water supply system of a power plant.
  • the magnetic field iron removal purification device is used to remove iron from the power supply of the power plant.
  • the magnetic field iron removal purifying device for de-ironing the power supply system of the power plant is installed in the deaerating water tank 14 and is located in the gas outlet of the deaerating water tank.
  • the deaerator tank is a thermal equipment with a single water space. Condensed water flows from the upper part and feed water flows out from the lower part.
  • the magnetic field iron removal device in the oxygen removal water tank 14 is a three-dimensional grid structure, and two horizontally arranged planar units 13 and four vertically disposed planar units 12 are formed to cross each other.
  • the planar units 1 3 and 14 are each formed by combining a plurality of permanent magnet tubes 5 through a frame 1 1 , and two horizontally arranged planar units 13 are arranged in parallel with each other, and the four vertically disposed planar units 12 are also mutually connected to each other. Parallel spacing settings.
  • the vertically disposed planar units 12 are perpendicular to the central axis of the oxygen scavenging water tank 14, and are spaced apart along the central axis. Since the operating water level in the deaerating water tank 14 generally has a space of 300-400 inches from the top of the water tank, the height of the vertically disposed flat unit 12 should be higher than the operating water level.
  • the flow area of the magnetic field iron removal purifying device in the deaerating water tank 14 is larger than the inlet pipe area of the feed water pump 15 to ensure that no harmful resistance is generated to the inlet of the feed water pump.
  • a magnetic field iron removal purifying device adopting a three-dimensional grid structure can purify the water flow through the magnetic field and purify the water flowing from the various directions to the lower water outlet. Moreover, it is conceivable that a multi-layer combined magnetic field can be used for multiple iron removal purifications to obtain a better purification effect.
  • the permanent magnet tubes 5 in the purification device are arranged in parallel with each other.
  • the permanent magnet tubes may be arranged alternately as needed, or the wave shape as shown in FIG. Arrangement.
  • a frame For a larger combined magnetic field, several permanent magnet tubes 5 can be combined into a smaller unit by a frame (see Fig. 5), and then several units are combined by the frame to have a desired shape and a required area.
  • the magnetic field removes the iron purifying device, and such a unit may be a single layer or a plurality of layers as needed, and may be rectangular, circular, semicircular, or the like.

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

An iron removal purification device with a magnetic field is provided, and it can be applied to treatment of condensed water and water supply for a power plant. The device is formed by permanent magnetic pipes. The permanent magnetic pipes comprise sleeve tubes, in which several permanent magnets are fixed and sealed with the same poles facing each other. A big magnetic filter net is formed in the device, so that it ensures that the whole filter net is under magnetic field. Furthermore, the device has simple structure, and is easy to implement.

Description

一种磁场除铁净化装置及其在发电厂凝结 7j和给水中的应用 技术领域  Magnetic field iron removal purifying device and application thereof in power plant condensation 7j and water supply
本发明涉及一种用于分离出水中铁质杂质的磁场除铁净化装置, 以及这 种装置在发电厂汽轮机凝结水和锅炉 (核电厂蒸汽发生器)给水中的具体应 用。 背景技术  The present invention relates to a magnetic field iron removal apparatus for separating iron impurities in water, and a specific application of such apparatus in power plant steam turbine condensate and boiler (nuclear power plant steam generator) feed water. Background technique
发电厂的锅炉 (或核电厂蒸汽发生器) 汽水管路及其相关的热力设备都 是以铁为基础的材料制成的, 它在运行中会产生大量的固态铁质腐蚀产物成 为水中主要的有害杂质, 这些固态铁质杂质会在锅炉 (核电厂蒸汽发生器) 的蒸发面或其它热力系统管路中沉积形成垢, 它既影响到管壁的传热还会使 管壁产生过热, 又会引起垢下腐蚀, 过热和腐蚀是造成锅炉受热面爆管事故 的主要原因, 同时固态杂质在汽水管路中流动会对管壁阀门产生冲刷损坏, 给水中这些固态杂质直接影响锅炉 (核电厂蒸汽发生器) 的运行安全。 所以 发电厂对凝结水和锅炉给水除铁净化非常重视, 但由于技术上的原因以前在 给水系统却没有除铁净化装置, 只能在给水系统前的凝结水系统中设有各种 形式的化学除铁净化设备 "精处理" 装置及各种形式的前置式除铁器, 在这里通过尽力提高凝结水净化质量来补偿给水系统中没有净化装置的不 足。 在这些传统净化设备中全部采用树脂、 纤维等过滤物质, 利用这些物质 的吸附和过滤 -作用除去水中的铁质杂质。 发电厂传统热力循环系统及除铁方 式的流程是: 蒸汽在汽轮机内做功后, 乏汽至凝汽器内凝结成凝结水, 而后 凝结水经过凝汽器外的凝结水泵提高压力, 将凝结水送至凝结水净化和加热 装置, 先进入化学除铁设备 "精处理" 对凝结水进行除铁净化, 在传统 发电厂热力系统中 "精处理" 成为凝结水和给水系统中唯一的除铁装置, 而 后凝结水经过低压加热器、 除氧器除氧水箱进入锅炉给水系统, 给水经锅炉 加热后变成蒸汽推动汽轮机做功, 又开始了上述的汽水热力循环过程。 发电 广习惯上称由化学专业管理的除铁净化系统为化学除铁方式, 它是目前世界 上广泛使用的除铁净化方式, 但不足之处是:  Boilers in power plants (or steam generators in nuclear power plants) The soda pipes and their associated thermal equipment are made of iron-based materials, which generate a large amount of solid iron corrosion products during operation and become the main water Harmful impurities, these solid iron impurities will deposit on the evaporation surface of the boiler (nuclear power plant steam generator) or other thermal system pipelines, which will affect the heat transfer to the pipe wall and overheat the pipe wall. It will cause corrosion under scale, overheating and corrosion are the main causes of tube explosion accidents in boilers. At the same time, the flow of solid impurities in the steam pipe will cause erosion damage to the pipe wall valves. These solid impurities in the feed water directly affect the boiler (nuclear power plant). The steam generator is safe to operate. Therefore, the power plant attaches great importance to the decontamination of condensate and boiler feed water. However, for technical reasons, there is no iron removal device in the water supply system. Only various forms of chemistry can be set in the condensate system in front of the water supply system. In addition to the "fine treatment" device for iron purification equipment and various types of front-mounted iron removers, here, by trying to improve the quality of condensate purification, the shortage of the purification device in the water supply system is compensated. In these conventional purification apparatuses, all of the filter materials such as resins and fibers are used, and the adsorption and filtration of these substances are used to remove iron impurities in the water. The traditional thermal cycle system of the power plant and the process of removing the iron are: After the steam works in the steam turbine, the steam is condensed into condensed water in the condenser, and the condensed water passes through the condensate pump outside the condenser to increase the pressure, and the condensate Send to the condensate purification and heating device, first enter the chemical de-ironing equipment "fine treatment" to remove the iron from the condensate, "fine treatment" in the traditional power plant thermal system becomes the only iron removal device in the condensate and water supply system Then, the condensed water enters the boiler feed water system through the low-pressure heater and the deaerator deaeration water tank, and the feed water is heated by the boiler to become steam to push the steam turbine to work, and the above-mentioned steam-water thermodynamic cycle process begins. Power Generation It is customary to say that the iron removal system managed by the chemical profession is a chemical iron removal method. It is currently widely used in the world to remove iron, but the disadvantages are:
1.因凝结水精处理中的树脂更换费用高, 为了防止其过早被污染,在机组 启动初期水质较差时还不能投入使用, 因此造成了启动时成为无除铁净化装 置的工况, 至使大量凝结水被排放, 也使机组启动并网发电时间不可预期。 1. Due to the high cost of resin replacement in the treatment of condensed water, in order to prevent premature contamination, it cannot be put into use when the water quality is poor at the initial stage of the unit startup, thus causing the installation to be cleaned without iron removal. The set condition, so that a large amount of condensed water is discharged, also makes the unit start-up grid-connected power generation time unpredictable.
2.发电厂水质净化最主要目的是保护锅炉(核电厂蒸汽发生器 )受热面的 安全, 因此除铁净化装置理论上应设在离锅炉 (核电厂蒸汽发生器)最近的 给水系统内才能起到更直接更有效的保护, 而传统的除铁技术是利用树脂等 高分子物质做滤材, 这种滤材的使用温度一般不超过 75 °C , 因此化学除铁方 式只能在温度较低的凝结水系统内建立 "精处理" 除铁装置对凝结水进行除 铁净化, 而不能在工作温度为 150 °C以上的给水系统内建立除铁净化装置,但 凝结氷经 "精处理,, 装置净化之后, 又受到低压加热器和各种流进的疏水污 染使水质又恶化, 因此后又没有净化装置, 被污染的凝结水直接进入了给水 系统, 也就进入了锅炉。 现发电厂亚临界机组要求 "精处理" 处理后的凝结 水含铁量要小于 5ppb,而给水含铁量要小于 l Oppb,这里给水含铁要求标准反 而低于凝结水的标准, 说明因给水中没有除铁装置, 不得不对给水放宽要求, 是一种无奈的选择。 此前给水系统一直没有建立除铁净化装置, 对给水的质 量要求则完全取决于凝结水净化装置的能力, 给水系统需要有适合自己独立 的除铁净化装置, 以保证锅炉的运行安全。 发明内容  2. The main purpose of water purification of power plants is to protect the heating surface of boilers (steam generators of nuclear power plants). Therefore, the iron removal purification equipment should theoretically be located in the water supply system closest to the boiler (the steam generator of the nuclear power plant). To the more direct and more effective protection, the traditional iron removal technology uses a polymer material such as resin as the filter material. The temperature of the filter material generally does not exceed 75 °C, so the chemical iron removal method can only be used at lower temperatures. The "fine treatment" is established in the condensate system. The iron removal device performs iron removal and purification on the condensed water, but the iron removal purification device cannot be established in the water supply system with the working temperature above 150 °C, but the condensed ice is "finished," After the device is cleaned, it is further polluted by the low-pressure heater and various hydrophobic pollution, so there is no purification device. The contaminated condensate directly enters the water supply system and enters the boiler. The critical unit requires "fine treatment". The iron content of the condensed water after treatment is less than 5ppb, and the iron content of the feed water is less than l Oppb. On the contrary, it is lower than the standard of condensate, which means that there is no iron removal device in the water supply, and it has to be relaxed. It is a helpless choice. The previous water supply system has not established a de-iron purification device, and the quality requirements for the water supply are completely dependent on The ability of the condensate purification device, the water supply system needs to have its own independent iron removal purification device to ensure the safe operation of the boiler.
为弥补上述现有技术的不足, 本发明的首要目的在于提供一种用于分离 水中铁质杂质的磁场除铁净化装置, 本发明还进一步提供这种装置在发电厂 凝结水和给水中的具体应用。 其中, 凝结水磁场除铁净化装置安装在发电厂 汽轮机车间凝汽器中, 发电厂给水磁场除铁净化装置安装在除氧水箱内。 本 发明根据铁磁相吸原理来分离出流经的水中的铁质杂质, 从而实现对水的除 铁净化。 在凝汽器内设置磁场除铁净化装置, 第一次实现了凝结水在其源头 就得到除铁净化; 在除氧水箱内设置磁场除铁净化装置, 第一次实现了对锅 炉 (核电厂蒸汽发生器)给水的除铁净化。  In order to remedy the above-mentioned deficiencies of the prior art, the primary object of the present invention is to provide a magnetic field iron removal apparatus for separating iron impurities in water, and the present invention further provides a specific embodiment of such a device in a power plant condensate and feed water. application. Among them, the condensed water magnetic field iron removal device is installed in the steam turbine workshop condenser of the power plant, and the power supply magnetic field iron removal purification device of the power plant is installed in the oxygen removal water tank. According to the ferromagnetic phase suction principle, the iron impurities in the water flowing through are separated, thereby realizing the iron removal purification of water. The magnetic field de-iron purification device is installed in the condenser, and the condensed water is desulfurized at the source for the first time; the magnetic field iron removal purification device is installed in the deaerating water tank, and the boiler is realized for the first time (nuclear power plant) Steam generator) The iron removal of the feed water.
构成本发明磁场除铁净化装置的基本构成单元为永磁管, 该永磁管包括 套管以及套管内固定封装的若干个永磁体, 套管由非导磁性材料制成, 若干 个永磁体沿套管长度方向依次排列或者沿套管周向排列成一封闭环, 永磁体 的极性方向为其排列方向, 并且相邻永磁体相邻端的极性相同, 使得铁质杂 质有效吸附区遍布套管表面的周向和全长; 所述铁质杂质有效吸附区指的是 套管表面上各永磁体的磁力线各自集中穿过的部位, 该部位分别与各永磁体 磁极所在的位置相对应。 The basic constituent unit constituting the magnetic field iron-removing device of the present invention is a permanent magnet tube, which comprises a sleeve and a plurality of permanent magnets fixed in the sleeve, the sleeve is made of a non-magnetic material, and a plurality of permanent magnets are The length direction of the sleeve is arranged in sequence or arranged in a ring shape along the circumference of the sleeve. The polarity direction of the permanent magnets is the direction of arrangement, and the polarities of the adjacent ends of the adjacent permanent magnets are the same, so that the effective adsorption area of the iron impurities is spread over the sleeve. The circumferential direction and the full length of the surface; the effective adsorption zone of the iron impurities refers to a portion where the magnetic lines of the permanent magnets on the surface of the sleeve are respectively concentrated, and the portions are respectively associated with the permanent magnets The position where the magnetic pole is located corresponds.
本发明磁场除铁净化装置由若干根永磁管通过框架组合而成, 各永磁管 对水中铁质杂质的有效吸附范围在空间上依次相接, 从而形成一由若干个永 磁管单元磁场相互拼接而成的组合磁场; 随着待净化氷穿流过该组合磁场, 水中的铁质杂质被吸附到组合磁场中的永磁管表面上; 所述有效吸附范围为 永磁管能够将铁质杂质吸附到其表面上的范围, 该范围为一围绕永磁管的立 体空间。  The magnetic field iron removal purifying device of the invention is composed of a plurality of permanent magnet tubes through a frame, and the effective adsorption ranges of the permanent magnet tubes for the iron impurities in the water are sequentially connected in space, thereby forming a magnetic field of a plurality of permanent magnet tubes. a combined magnetic field formed by splicing each other; as the ice to be purified flows through the combined magnetic field, iron impurities in the water are adsorbed onto the surface of the permanent magnet tube in the combined magnetic field; the effective adsorption range is that the permanent magnet tube can iron The range in which the impurity is adsorbed onto the surface thereof is a three-dimensional space surrounding the permanent magnet tube.
通过在永磁管中配置若干个永磁体, 并使相邻永磁体的相邻端的极性相 同, 如同沿永磁管全长布置了若干个磁场作用范围相互独立、 互不影响的永 磁体, 再利用若干根这种永磁管来构建净化装置, 则相当于用若千个互不影 响的小磁场构建了一个所需的大的磁场过滤网, 这种结构形式, 既保证了磁 场作用范围覆盖到整个网的各个角落, 又使整个装置结构简单, 实施方便。  By arranging a plurality of permanent magnets in the permanent magnet tube and making the adjacent ends of the adjacent permanent magnets have the same polarity, as in the permanent magnet tube, a plurality of permanent magnets whose magnetic fields are independent of each other and do not affect each other are arranged. The use of several such permanent magnet tubes to construct a purification device is equivalent to constructing a large magnetic field filter required by thousands of small magnetic fields that do not affect each other. This structure ensures the magnetic field range. Covering all corners of the entire network, the entire device structure is simple and easy to implement.
将本发明磁场除铁净化装置用于发电厂凝结水的除铁净化时, 可将该装 置设置在汽轮机凝汽器热水井内出水口的上方, 并根据出水口处的水流方向, 通过框架将若干根永磁管组合成一中空的环形或下端开口、 四周及顶部均设 置有永磁管的罩形; 当热水井内的水流从四周流入出水口时, 利用环形净化 装置对流入出水口的水进行除铁净化, 当热水井内的水流同时从四周和上部 流入出水口时, 则利用罩扣在出水口上方的罩形结构的净化装置对流入出水 口的水进行除铁净化。  When the magnetic field iron removal purifying device of the invention is used for iron removal purification of power plant condensed water, the device may be disposed above the water outlet of the steam turbine condenser hot water well, and according to the water flow direction at the water outlet, through the frame a plurality of permanent magnet tubes are combined into a hollow annular or lower end opening, and a cover shape of a permanent magnet tube is arranged around and at the top; when the water flow in the hot water well flows into the water outlet from the periphery, the water flowing into the water outlet is used by the annular purifying device In the iron removal purification, when the water flow in the hot water well flows into the water outlet from the periphery and the upper portion at the same time, the water flowing into the water outlet is subjected to iron removal purification by the cover-shaped structure purifying device with the cover buckle above the water outlet.
将本发明磁场除铁净化装置用于发电厂锅炉给水系统的除铁净化时, 可 将该装置安装在除氧水箱内, 并根据除氧水箱内部水流流量和水流方向, 通 过框架将若干根永磁管组合成立体网架式结构, 该网架式结构由多个水平设 置的平面单元和多个垂直设置的平面单元相互交叉构成, 每个平面单元均由 若干根永磁管通过框架组合而成, 多个水平设置的平面单元之间相互平行间 隔设置, 多个垂直设置的平面单元之间同样相互平行间隔设置。  When the magnetic field iron removal purifying device of the invention is used for iron removal purification of a power supply boiler boiler water supply system, the device can be installed in an oxygen removal water tank, and according to the internal flow rate of the oxygen removal water tank and the direction of the water flow, a plurality of pieces are permanently passed through the frame. The magnetic tube assembly is formed into a body grid structure, which is composed of a plurality of horizontally arranged planar units and a plurality of vertically disposed planar units, each of which is composed of a plurality of permanent magnet tubes through a frame. A plurality of horizontally disposed planar units are disposed in parallel with each other, and a plurality of vertically disposed planar units are also disposed in parallel with each other.
针对除氧水箱中的高温环境, 应采用能耐此高温的永磁体来制作永磁管。 本发明磁场除铁净化装置的创新点在于:  For the high temperature environment in the deaerator tank, a permanent magnet that can withstand this high temperature should be used to make the permanent magnet tube. The innovation of the magnetic field iron removal device of the invention lies in:
1、传统化学除铁方式是: 利用树脂、 纤维做滤材并建立独立专用的庞大 承压设备对水质进行除铁净化, 而本发明是将传统只有单一储存水功能的热 力设备凝汽器热水井和除氧水箱通过磁场技术, 巧妙的增加了除铁功能, 实 现了利用凝汽器和除氧水箱分别对凝结水和给水进行除铁净化, 这既挖掘了 热力设备潜力, 又创立利用发电厂原有热力设备除铁净化的新方式, 两种方 式互补共存促进了发电厂水质净化技术的提高。 1. The traditional chemical iron removal method is: using the resin and fiber as the filter material and establishing a separate and dedicated large pressure-bearing equipment to purify the water, and the present invention is a conventional heat equipment condenser with only a single storage water function. Through the magnetic field technology, the well and the deaerating water tank skillfully increase the iron removal function, and realize the iron removal and purification of the condensed water and the feed water by using the condenser and the oxygen removal water tank respectively. The potential of thermal equipment has also created a new way to remove iron from the original thermal equipment of the power plant. The complementary coexistence of the two methods has promoted the improvement of water purification technology in power plants.
1、安装在凝汽器内的凝结水除铁净化装置, 建立了在汽轮发电机组启动 时, 化学 "精处理" 除铁装置未投入前唯一的凝结水除铁装置, 实现了凝结 水在其源头就得到除铁净化, 加快了水质净化, 减少了水的排放和机组启动 进程; 在机组正常运行中它成为化学除铁方式 "精处理,, 装置的前置式除铁 器, 减轻了 "精处理" 的负担, 延长了其内树脂的使用寿命和更换时间, 这 既提高了 "精处理,, 运行的经济性, 又有利于 "精处理" 出口水质净化质量 的提高。  1. The condensate removal iron removal device installed in the condenser establishes the only condensate de-ironing device before the steam turbine generator set starts, the chemical “fine treatment” iron removal device is not put into operation, and the condensed water is realized. The source is de-purified, speeding up water purification, reducing water discharge and unit start-up process; it becomes a chemical de-ironing method in the normal operation of the unit, and the front-mounted iron remover of the unit is lightened. The burden of “fine treatment” prolongs the service life and replacement time of the resin, which not only improves the “fine treatment, economical operation, but also contributes to the improvement of the quality of the refined water purification”.
3、安装在除氧水箱中的除铁净化装置, 第一次在锅炉给水系统中建立了 除铁净化装置, 实现了对给水的除铁净化, 结束了发电厂给水系统没有净化 装置的历史。  3. The iron removal purification device installed in the deaerator tank, the iron removal purification device was established in the boiler feed water system for the first time, which realized the iron removal purification of the feed water, and ended the history of the power supply system without purification device.
4、 传统净化方式利用树脂、 纤维为滤材来过滤吸附水中杂质, 其树脂、 纤维需要再生、 更换、 废弃, 成本高, 对环境也造成污染; 本装置利用永磁 场筛选出水中铁质杂质, 充分利用了磁能除铁净化, 如同利用风能、 太阳能 一样得到大自然的优惠, 而且磁场是永磁的, 可以重复使用且除铁精度高, 是环保、 不耗其它能源、 节水的净化技术。  4. The traditional purification method uses resin and fiber as the filter material to filter and adsorb impurities in the water. The resin and fiber need to be regenerated, replaced, and discarded. The cost is high and the environment is also polluted. The device uses the permanent magnetic field to screen out the iron impurities in the water. The use of magnetic energy to remove iron, like the use of wind energy, solar energy to get the benefits of nature, and the magnetic field is a permanent magnet, can be reused and high precision in iron removal, is environmentally friendly, does not consume other energy, water purification technology.
5、 本装置采用潜入式设计, 利用磁场技术开发容器空间, 在热力容器的 水下空间内, 在不占车间地面的情况下, 建立了隐形的除铁装置, 这对地面 十分紧凑的发电厂汽轮机车间来说, 成功的解决了建立设备与占地的矛盾, 也是紧凑布置、 节地的典型设计。  5. The device adopts the submersible design, uses the magnetic field technology to develop the container space, and establishes the invisible iron removing device in the underwater space of the thermal container without occupying the ground of the workshop. This is a very compact power plant. For the steam turbine workshop, the contradiction between the establishment of equipment and the land occupation has been successfully solved, and it is also a typical design of compact layout and land saving.
6、 传统化学除铁净化装置需要利用水泵来提供水流的动力, 以便克服 过滤设备的阻力, 这要耗费电能; 而本装置的除铁磁场选择建立在水流具有 从上至下流动的流道上, 利用该处水流具有从上而下流动的势能通过磁场, 因此这种除铁装置不需要再建立驱动水泵; 同时装在容器内的除铁装置利用 原容器的壳体为壳体, 不再为此设置专用外壳结构, 将具有除铁功能的磁性 組件通过机械方式与原热力容器构件相连接组成了稳固的除铁装置, 这不仅 节能、 降低造价, 又使除铁系统更加简单, 易于推广。 附图说明  6. The traditional chemical iron removal purification device needs to use a water pump to provide the power of the water flow in order to overcome the resistance of the filtration device, which consumes electric energy; and the demagnetization magnetic field of the device is selected to be established on the flow path of the water flow flowing from top to bottom. With the water flow there is a potential energy flowing from top to bottom through the magnetic field, the iron removing device does not need to establish a driving water pump; at the same time, the iron removing device installed in the container uses the casing of the original container as the casing, and is no longer The special outer casing structure is provided, and the magnetic component with the iron removing function is mechanically connected with the original heat container member to form a stable iron removing device, which not only saves energy, reduces the cost, but also makes the iron removing system simpler and easy to popularize. DRAWINGS
图 1为本发明磁场除铁净化装置所用永磁管的第一种结构型式示意图; 图 2为永磁管第二种结构型式示意图; 1 is a schematic view showing a first structural type of a permanent magnet tube used in a magnetic field iron removal purifying apparatus of the present invention; 2 is a schematic view showing a second structure of a permanent magnet tube;
图 3为本发明磁场除铁净化装置应用于凝汽器中的系统示意图; 图 4为图 3所示系统中所用磁场除铁净化装置的第一种结构型式示意图; 图 5为构建图 4所示净化装置用矩形平面单元结构示意图;  3 is a schematic diagram of a system for applying a magnetic field iron removal purification device to a condenser according to the present invention; FIG. 4 is a schematic view showing a first structural type of the magnetic field iron removal purification device used in the system shown in FIG. A schematic diagram of a rectangular planar unit structure for a purification device;
图 6为图 3所示系统中所用磁场除铁净化装置的第二种结构型式示意图; 图 7为图 3所示系统中所用磁场除铁净化装置的第三种结构型式示意图; 图 8为图 3所示系统中所用磁场除铁净化装置的第四种结构型式示意图; 图 9为本发明磁场除铁净化装置应用于除氧水箱中的系统示意图; 图 10为图 9中 A-A视图;  Figure 6 is a schematic view showing a second structural type of the magnetic field iron removing apparatus used in the system shown in Figure 3; Figure 7 is a schematic view showing a third structural type of the magnetic field removing iron purifying apparatus used in the system shown in Figure 3; 3 is a schematic diagram of a fourth structural type of the magnetic field removing iron purifying device used in the system shown in FIG. 3; FIG. 9 is a schematic view showing a system for applying the magnetic field iron removing and purifying device to the oxygen scavenging water tank according to the present invention; FIG. 10 is an AA view of FIG.
图 11为图 10中所示磁场除铁净化装置左视图;  Figure 11 is a left side view of the magnetic field iron removing apparatus shown in Figure 10;
图 12为磁场除铁净化装置图 11所示状态俯视图;  Figure 12 is a top view of the state shown in Figure 11 of the magnetic field iron removal purifying device;
图 1 3为永磁管波浪形布置示意图。  Figure 13 is a schematic diagram of the wavy arrangement of the permanent magnet tube.
图中: 1.封板, 2.套管, 3.永磁体, 4.隔板, 5.永磁管, 6.凝汽器, Ί. 热水井, 8.凝结水磁场除铁净化装置, 9.凝结水泵, 10.矩形平面单元, 1 1. 边框, 12.垂直设置的平面单元, 13.水平设置的平面单元, 14.除氧水箱, 15. 给水泵。 具体实施方式  In the figure: 1. Sealing plate, 2. Casing, 3. Permanent magnet, 4. Separator, 5. Permanent magnet tube, 6. Condenser, Ί. Hot water well, 8. Condensed water magnetic field iron removal device 9. Condensate pump, 10. Rectangular plane unit, 1 1. Frame, 12. Vertically arranged plane unit, 13. Horizontally arranged plane unit, 14. Oxygen dehydration tank, 15. Feed water pump. detailed description
下面结合附图对本发明作进一步说明。  The invention will now be further described with reference to the accompanying drawings.
如图 2所示, 本发明磁场除铁净化装置中所用的永磁管 5包括套管 2及 套管内固定封装有若干个永磁体 3, 套管 2为圆管, 由不锈钢、 铝合金等非导 磁性材料制成, 若干个圓柱形永磁体 3沿套管 2长度方向依次排列,永磁体 3 的极性方向为其排列方向, 并且相邻永磁体 3相邻端的极性相同, 从而形成 沿套管长度方向排列的 N— SS—丽一 SS—匪一 SS… … S磁极分布形态, 套管 2 内相邻两永磁体 3之间设置有由导磁性材料制成的隔板 4 ,为了将位于两端的 永磁体 3的磁力线引导穿过套管 2侧壁形成回路, 套管 2两端还专门设置有 由导磁性材料制成的导向板 4', 套管 2两端由封板 1气密封堵, 封板 1由非 导磁性材料制成, 该封板可以采用过盈配合的方式固定到套管 2 上, 也可以 利用氩弧焊与套管 2焊接固定, 永磁体 3根据需要可选择由铝镍钴、 钕铁硼、 As shown in FIG. 2, the permanent magnet tube 5 used in the magnetic field iron removal apparatus of the present invention comprises a sleeve 2 and a sleeve fixedly enclosed with a plurality of permanent magnets 3, and the sleeve 2 is a circular tube, which is made of stainless steel or aluminum alloy. Made of a magnetic material, a plurality of cylindrical permanent magnets 3 are arranged in the longitudinal direction of the sleeve 2, the polar directions of the permanent magnets 3 are arranged in the direction of alignment, and the adjacent ends of the adjacent permanent magnets 3 have the same polarity, thereby forming an edge The N-SS-Liyi SS-匪-SS... S magnetic pole distribution pattern arranged in the longitudinal direction of the sleeve, and the partition plate 4 made of a magnetic conductive material is disposed between the adjacent two permanent magnets 3 in the sleeve 2, The magnetic lines of the permanent magnets 3 at the two ends are guided through the side wall of the sleeve 2 to form a circuit. The two ends of the sleeve 2 are also specially provided with a guide plate 4' made of a magnetically permeable material, and the ends of the sleeve 2 are sealed by a cover plate 1 The gas seal is blocked, and the sealing plate 1 is made of a non-magnetic material. The sealing plate can be fixed to the sleeve 2 by an interference fit, or can be welded and fixed by the argon arc welding and the sleeve 2, and the permanent magnet 3 is required according to the need. AlNiCo, NdFeB
4钴合金或铁氧体等永磁材料制成。 4 cobalt alloy or ferrite and other permanent magnet materials.
图 2所示为永磁管 5的第一种结构型式, 除此之外, 永磁管 5也制成图 3 所示的结构型式, 在该第二种结构型式中, 永磁体 3 为部分圓环形, 若干个 永磁体 3沿周向排列成与套管 2 内径相匹配的圆环, 永磁体 3的磁极方向为 其周向, 周向两相邻永磁体 3的极性相同, 从而形成沿套管圓周排列的題一 SS—丽 ... ... SS磁极分布, 周向两相邻永磁体 3之间同样设置有由导磁性材料 制成的隔板 4。 Figure 2 shows the first structural version of the permanent magnet tube 5, in addition to this, the permanent magnet tube 5 is also made in Figure 3. In the second type of construction, the permanent magnet 3 is partially annular, and the plurality of permanent magnets 3 are circumferentially arranged in a ring shape matching the inner diameter of the sleeve 2, and the magnetic pole direction of the permanent magnet 3 For its circumferential direction, the circumferential directions of the two adjacent permanent magnets 3 are the same, thereby forming a problem of SS-Li SS magnetic pole distribution arranged along the circumference of the sleeve, and two adjacent permanent magnets 3 in the circumferential direction. A separator 4 made of a magnetically permeable material is also provided.
由于永磁管 5通常比较长, 因而, 为了加工方便, 上述第二中结构型式 中的永磁体 3可沿永磁管 5长度方向分段制造。  Since the permanent magnet tube 5 is usually relatively long, the permanent magnet 3 in the above second structure type can be manufactured in sections along the longitudinal direction of the permanent magnet tube 5 for the convenience of processing.
通过使套管中相邻永磁体 3的相邻端极性相同, 使各永磁体 3的磁力线 均独自穿出、 穿入套管侧壁而自成回路, 因而保证了各永磁体 3磁场的独立 性, 也就保证了各永磁体 3对铁质材料吸附功能及作用范围的独立性。 这种 结构型式, 使得与各永磁体 3磁极相对应的铁质杂质有效吸附区遍布套管表 面的周向和全长, 保证了永磁管 5 在其整个长度都能够对铁质杂质形成有效 吸附。  By making the adjacent ends of the adjacent permanent magnets 3 of the same polarity of the sleeves, the magnetic lines of the permanent magnets 3 are individually pierced and penetrated into the side wall of the sleeve to form a loop, thereby ensuring the magnetic field of each permanent magnet 3. Independence also ensures the independence of the adsorption function and range of action of each permanent magnet 3 on the ferrous material. This type of structure makes the effective adsorption zone of the iron impurities corresponding to the magnetic poles of each permanent magnet 3 spread over the circumferential and full length of the casing surface, ensuring that the permanent magnet tube 5 can effectively form iron impurities throughout its length. Adsorption.
根据物理常识可知, 磁体磁极对铁质材料的吸附力最强, 因此, 上述所 谓的铁质杂质有效吸附区指的是套管 1表面上与各永磁体 3磁极所在位置相 对应的部位, 也就是各永磁体 3的磁力线各自集中穿过套管 2侧壁的部位。 图 2 所示永磁管上的铁质杂质有效吸附区为沿永磁管长度方向间隔排列的一 个个环绕永磁管周向的环, 该环宽度及其在永磁管表面的分布位置与隔板 的厚度及位置相对应。 图 3 所示永磁管上的铁质杂质有效吸附区为若干根沿 套管 2 周向均布的条带, 该条带沿套管长度方向延伸, 各条带的宽度及在套 管 2周向上的位置与隔板 4的厚度及位置相对应。  According to physical common knowledge, the magnetic pole of the magnet has the strongest adsorption force to the ferrous material. Therefore, the so-called effective impurity adsorption region of the iron impurity refers to a portion on the surface of the sleeve 1 corresponding to the position of the magnetic poles of the permanent magnets 3, and also That is, the magnetic lines of the respective permanent magnets 3 are each concentrated at a portion of the side wall of the sleeve 2. The effective adsorption zone of the iron impurities on the permanent magnet tube shown in Fig. 2 is a ring surrounded by the circumferential direction of the permanent magnet tube, and the width of the ring and its distribution on the surface of the permanent magnet tube The thickness and position of the partition correspond. The effective adsorption zone of the iron impurities on the permanent magnet tube shown in Fig. 3 is a plurality of strips distributed uniformly along the circumference of the sleeve 2, the strips extending along the length of the sleeve, the width of each strip and the circumference of the sleeve 2 The position corresponds to the thickness and position of the partition 4.
上述两种结构型式的永磁管 5均为圆管, 除此之外, 永磁管 5也可以是 方管, 或其他截面形状的管。 由于每根永磁管 5 上都有若干个由其内永磁体形成的小磁场, 并且各小 磁场对铁质材料吸附功能及作用范围相互独立、 互不影响, 因而, 通过框架 将若干根永磁管 5 进行组合, 可构建一个由若干个小磁场相互拼接而成的组 合磁场, 利用该组合磁场即可对流经的水进行除铁净化处理。 本发明磁场除 铁净化装置就是基于这一思想而提出的。  The permanent magnet tubes 5 of the above two types of structures are all round tubes, and in addition, the permanent magnet tubes 5 may also be square tubes or tubes of other cross-sectional shapes. Since each of the permanent magnet tubes 5 has a plurality of small magnetic fields formed by the permanent magnets therein, and the small magnetic fields have independent functions on the adsorption function and the range of action of the iron materials, and thus, the plurality of roots are passed through the frame. The magnetic tube 5 is combined to construct a combined magnetic field formed by splicing a plurality of small magnetic fields, and the combined magnetic field can be used to perform iron removal treatment on the water flowing through. The magnetic field iron removal apparatus of the present invention is proposed based on this idea.
需要指出的是, 由于磁体对水中铁质杂质的吸附力与二者之间的距离相 关, 距离越远, 吸附力越小, 因此, 为了保证将水中的铁质杂盾可靠吸附到 永磁管 5表面上, 在利用永磁管 5构建磁场除铁净化装置时, 可针对待处理 水中铁质杂质的大小、 水流流速等具体情况, 调整相邻永磁管之间的距离, 以便使相邻永磁管的有效吸附范围相接或部分重叠。 所谓有效吸附范围指的 是永磁管 5 能够将铁质杂质可靠吸附到其表面上的范围, 该范围为一围绕永 磁管的立体空间。 It should be pointed out that because the adsorption force of the magnet on the iron impurities in the water is related to the distance between the two, the farther the distance is, the smaller the adsorption force is. Therefore, in order to ensure the reliable adsorption of the iron shield in the water On the surface of the permanent magnet tube 5, when the magnetic field iron removal device is constructed by using the permanent magnet tube 5, the distance between adjacent permanent magnet tubes can be adjusted according to the specific conditions of the iron impurities in the water to be treated, the flow rate of the water flow, etc., so that The effective adsorption ranges of adjacent permanent magnet tubes are connected or partially overlapped. The effective adsorption range refers to a range in which the permanent magnet tube 5 can reliably adsorb iron impurities to its surface, which is a three-dimensional space surrounding the permanent magnet tube.
还需要指出的是, 为了充分发挥磁场除铁净化装置的效能, 装置中的永 磁管 5应尽可能与水流方向垂直。 图 3 所示为本发明磁场除铁净化装置在发电厂凝汽器中的具体应用, 在 此, 本发明磁场除铁净化装置用于对发电厂凝结水进行除铁净化。  It should also be noted that in order to fully utilize the performance of the magnetic field iron removal apparatus, the permanent magnet 5 in the apparatus should be as perpendicular as possible to the direction of water flow. Fig. 3 shows a specific application of the magnetic field iron removal purifying apparatus of the present invention in a power plant condenser. Here, the magnetic field iron removal purifying apparatus of the present invention is used for de-ironing purification of power plant condensed water.
如图 3所示, 凝结水磁场除铁净化装置 8安装在凝汽器 6的热水井 7中, 并位于热水井出水口的上方, 热水井 7 中的凝结水经出氷口流出热水井, 并 由凝结水泵 9送往下一环节。  As shown in Fig. 3, the condensed water magnetic field iron removal device 8 is installed in the hot water well 7 of the condenser 6, and is located above the water outlet of the hot water well, and the condensed water in the hot water well 7 flows out through the ice outlet. The well is sent to the next link by the condensate pump 9.
由于热水井 7 中凝结水的流量比较大, 因而需要大面积的組合磁场, 以 保证具有足够的通流能力, 避免因设置磁场除铁净化装置而对凝结水泵入口 产生有害阻力。  Since the flow rate of the condensed water in the hot water well 7 is relatively large, a large combined magnetic field is required to ensure sufficient flow capacity to avoid harmful resistance to the condensate pump inlet due to the provision of the magnetic field iron removal device.
当热水井 7 中的水只从四周流向出水口时, 可将凝结水磁场除铁净化装 置 8制成如图 4、 图 7所示的具有足够高度的围堰式环形结构。  When the water in the hot water well 7 flows only from the periphery to the water outlet, the condensed water magnetic field removing iron cleaning device 8 can be made into a cofferdam type annular structure having a sufficient height as shown in Figs.
对于图 4所示的方环形结构, 为了装配方便, 可先将方环的前、 后、 左、 右四个平面装配成如图 5所示的四个矩形平面单元 1 0, 然后再将四个矩形平 面单元 10组合成方环。 矩形平面单元 10由若干根相互平行排列的永磁管 5 通过边框 U组合而成,相邻两永磁管 5的磁场有效吸附范围相接或部分重叠。  For the square ring structure shown in FIG. 4, for the convenience of assembly, the front, rear, left, and right planes of the square ring can be assembled into four rectangular plane units 10 as shown in FIG. 5, and then four. The rectangular planar units 10 are combined into a square ring. The rectangular planar unit 10 is formed by combining a plurality of permanent magnet tubes 5 arranged in parallel with each other through a frame U, and the magnetic field effective adsorption ranges of the adjacent two permanent magnet tubes 5 are connected or partially overlapped.
而对于图 7所示的圆环形结构, 则可直接利用上下两道边框 1 1对永磁管 5进行组合。  For the toroidal structure shown in Fig. 7, the permanent magnet tubes 5 can be directly combined by using the upper and lower frames 1 1 .
将环形结构的磁场除铁净化装置 8设置在热水井出水口上方后, 随着凝 结水从四周穿过永磁管 5之间的空隙流入出水口, 水中的铁质杂质被吸附到 永磁管 5的表面上, 而使水得到净化。  After the magnetic field iron removing device 8 of the annular structure is disposed above the water outlet of the hot water well, the iron impurities in the water are adsorbed to the permanent magnet tube as the condensed water flows from the periphery through the gap between the permanent magnet tubes 5 into the water outlet. On the surface of 5, the water is purified.
针对凝结水从四周及上方同时流向出水口的热水井, 可将凝结水磁场除 铁净化装置 8制成如图 6、 图 8所示的下端开口、 四周及顶部均布置有永磁管 5的罩形结构。  The hot water well for the condensed water flowing from the periphery and the upper side to the water outlet can be made into a condensed water magnetic field removing iron cleaning device 8 as shown in Figs. 6 and 8 at the lower end opening, and the permanent magnet tube 5 is arranged at the periphery and the top. The hood structure.
与图 4所示的方环形结构相比, 图 6所示结构多了一个顶部矩形平面单 元。 与图 7所示的圓环形结构相比, 图 8所示结构多了一个顶部圓形平面单 元。 Compared with the square ring structure shown in FIG. 4, the structure shown in FIG. 6 has a top rectangular plane. Yuan. Compared to the toroidal structure shown in Fig. 7, the structure shown in Fig. 8 has a top circular planar unit.
将图 6和图 8所示罩形结构磁场除铁净化装置罩扣在热水井出水口上后, 该装置可对从四周和上方流入出水口的凝结水进行除铁净化处理。  After the cover type magnetic field iron removing device shown in Fig. 6 and Fig. 8 is buckled on the water outlet of the hot water well, the device can perform iron removal and purification treatment on the condensed water flowing into the water outlet from the periphery and the upper side.
在凝汽器热水井 Ί 中, 是釆用环形结构的磁场除铁净化装置, 还是采用 罩形结构的磁场除铁净化装置, 以及釆用多大面积, 取决于热水井内水流断 面的形状, 以及凝结水流量。 对于被净化的水流而言, 应对水流进行全流量 的净化, 也就是说磁场在水流断面上应做到完全封闭。 图 9 所示为本发明磁场除铁净化装置在发电厂给水系统中的具体应用, 在此 , 利用磁场除铁净化装置对发电厂给水进行除铁净化。  In the condenser hot water well, it is a magnetic field iron removal device with a ring structure, or a magnetic field iron removal device with a cover structure, and the area of the concrete, depending on the shape of the water flow section in the hot water well. And condensate flow. For the purified water stream, the water flow should be cleaned at full flow, that is, the magnetic field should be completely closed on the water flow section. Figure 9 shows the specific application of the magnetic field iron removal purification device of the present invention in a water supply system of a power plant. Here, the magnetic field iron removal purification device is used to remove iron from the power supply of the power plant.
如图 9 所示, 用于对发电厂给水系统进行除铁净化的磁场除铁净化装置 安装在除氧水箱 14中, 位于除氧水箱出水口的上访。 除氧水箱是一个具有单 一水容空间的热力设备,从上部流入的是凝结水, 从下部流出的称给水。  As shown in Fig. 9, the magnetic field iron removal purifying device for de-ironing the power supply system of the power plant is installed in the deaerating water tank 14 and is located in the gas outlet of the deaerating water tank. The deaerator tank is a thermal equipment with a single water space. Condensed water flows from the upper part and feed water flows out from the lower part.
参见图 1 0—图 1 2 , 除氧水箱 14 中的磁场除铁净化装置为立体网架式结 构, 由两个水平设置的平面单元 1 3和四个垂直设置的平面单元 12相互交叉 构成, 平面单元 1 3、 14均由若干根永磁管 5通过边框 1 1组合而成, 两个水 平设置的平面单元 1 3之间相互平行间隔设置, 四个垂直设置的平面单元 12 之间同样相互平行间隔设置。  Referring to FIG. 10 to FIG. 12, the magnetic field iron removal device in the oxygen removal water tank 14 is a three-dimensional grid structure, and two horizontally arranged planar units 13 and four vertically disposed planar units 12 are formed to cross each other. The planar units 1 3 and 14 are each formed by combining a plurality of permanent magnet tubes 5 through a frame 1 1 , and two horizontally arranged planar units 13 are arranged in parallel with each other, and the four vertically disposed planar units 12 are also mutually connected to each other. Parallel spacing settings.
针对卧式圓筒型结构的除氧水箱 14 ,垂直设置的平面单元 1 2与除氧水箱 14的中心轴垂直, 并且沿该中心轴间隔设置。 因除氧水箱 14内的运行水位一 般距离水箱顶部留有 300- 400匪空间, 故应使垂直设置的平面单元 12的高度 高过运行水位。  For the deaerating water tank 14 of the horizontal cylindrical structure, the vertically disposed planar units 12 are perpendicular to the central axis of the oxygen scavenging water tank 14, and are spaced apart along the central axis. Since the operating water level in the deaerating water tank 14 generally has a space of 300-400 inches from the top of the water tank, the height of the vertically disposed flat unit 12 should be higher than the operating water level.
除氧水箱 14 中的磁场除铁净化装置的通流面积要大于给水泵 15进口管 面积, 以保证不对给水泵 1 5入口产生有害的阻力。  The flow area of the magnetic field iron removal purifying device in the deaerating water tank 14 is larger than the inlet pipe area of the feed water pump 15 to ensure that no harmful resistance is generated to the inlet of the feed water pump.
在除氧水箱中采用立体网架式结构的磁场除铁净化装置, 可对流经该磁 场的水流进行全流量的净化, 从各个方向流到下部出水口的水流, 都会得到 除铁净化处理。 而且, 可以想象到的是, 利用多层组合磁场对流经的水流进 行多次除铁净化, 可以获得更好的净化效果。  In the deaerating water tank, a magnetic field iron removal purifying device adopting a three-dimensional grid structure can purify the water flow through the magnetic field and purify the water flowing from the various directions to the lower water outlet. Moreover, it is conceivable that a multi-layer combined magnetic field can be used for multiple iron removal purifications to obtain a better purification effect.
上述各实例中, 净化装置中的永磁管 5 均以相互平行的方式进行排列, 实际应用中, 也可以根据需要, 将永磁管交叉布置, 或如图 1 3所示的波浪形 布置。 In the above examples, the permanent magnet tubes 5 in the purification device are arranged in parallel with each other. In practical applications, the permanent magnet tubes may be arranged alternately as needed, or the wave shape as shown in FIG. Arrangement.
对于面积较大的组合磁场, 可先通过边框将若干根永磁管 5 组合成面积 较小的单元(参见图 5 ), 然后再将若干个单元通过框架组合具有所需形状和 所需面积的磁场除铁净化装置, 而这种单元, 根据需要可以是单层或多层, 可以是矩形、 圓形、 半圓形, 等等。  For a larger combined magnetic field, several permanent magnet tubes 5 can be combined into a smaller unit by a frame (see Fig. 5), and then several units are combined by the frame to have a desired shape and a required area. The magnetic field removes the iron purifying device, and such a unit may be a single layer or a plurality of layers as needed, and may be rectangular, circular, semicircular, or the like.
上迷实例只是用于说明本发明, 并不起任何限定作用, 在符合本发明思 想的情况下, 所实施的各种具体形式均在本发明保护范围之内。  The above examples are intended to be illustrative of the present invention and are not intended to limit the scope of the invention.

Claims

权利 要求 Rights request
1. 一种磁场除铁净化装置, 其特征在于, 该装置由若干根永磁管通过框架组 合而成, 各永磁管对水中铁质杂盾的有效吸附范围在空间上依次相接, 从而 形成一由若干个永磁管单元磁场相互拼接而成的組合磁场; 随着待净化水穿 流过该组合磁场, 水中的铁质杂质被吸附到组合磁场中的永磁管表面上; 所 述有效吸附范围为永磁管能够将铁质杂质吸附到其表面上的范围, 该范围为 一围绕永磁管的立体空间;所述永磁管包括套管, 套管中若干个永磁体以同极 相对的形式被固定封装在内。  A magnetic field iron removal purification device, characterized in that the device is composed of a plurality of permanent magnet tubes through a frame, and the effective adsorption ranges of the permanent magnet tubes to the iron shields in the water are sequentially connected in space, thereby Forming a combined magnetic field formed by splicing magnetic fields of a plurality of permanent magnet tube units; as the water to be purified flows through the combined magnetic field, iron impurities in the water are adsorbed onto the surface of the permanent magnet tube in the combined magnetic field; The effective adsorption range is a range in which the permanent magnet tube can adsorb the iron impurities onto the surface thereof, and the range is a three-dimensional space surrounding the permanent magnet tube; the permanent magnet tube includes a sleeve, and the plurality of permanent magnets in the sleeve are the same The extremely opposite form is fixedly packaged.
2. 如权利要求 1所述的净化装置, 其特征在于, 所述套管为圆管, 并由非导 磁性材料制成; 所述永磁体由铝镍钴、 钐钴合金、 钕铁硼或铁氧体永磁材料 制成。  2. The purification apparatus according to claim 1, wherein the sleeve is a circular tube and is made of a non-magnetic material; the permanent magnet is made of alumino-nickel-cobalt, samarium-cobalt alloy, neodymium-iron-iron or Made of ferrite permanent magnet material.
3. 如权利要求 2所述的净化装置, 其特征在于, 所述永磁体为与所述套管内 径相匹配的圓柱体段, 圆柱体段的磁极方向为其轴向, 若干个圓柱形永磁体 沿套管长度方向排列, 形成沿套管长度排列的 N (或 S ) — SS—而一 SS—丽一 SS ... ... N (或 S )磁极分布, 铁质杂质有效吸附区遍布套管表面的周向和全长, 铁质杂质有效吸附区指的是套管表面上与各永磁体磁极所在位置相对应的部 位, 也就是各永磁体的磁力线各自集中穿过套管侧壁的部位。  3. The purification apparatus according to claim 2, wherein the permanent magnet is a cylindrical section matching the inner diameter of the sleeve, and the magnetic pole direction of the cylinder section is an axial direction thereof, and a plurality of cylindrical shapes are The magnets are arranged along the length of the sleeve to form N (or S) - SS - and SS - Li - SS N (or S ) magnetic poles arranged along the length of the sleeve, and the effective adsorption area of the iron impurities The circumferential and full length of the surface of the casing, the effective adsorption zone of the iron impurities refers to the location on the surface of the casing corresponding to the position of the magnetic poles of the permanent magnets, that is, the magnetic lines of each permanent magnet are concentrated through the casing side. The part of the wall.
4. 如权利要求 3所述的净化装置, 其特征在于, 所述套管由不锈钢制成, 套 管内两相邻所述圓柱形永磁体之间设置有由导磁性材料制成的隔板, 套管两 端由非导磁性材料封堵, 封堵方式采用机械封堵或氩弧焊封堵。  4. The purification apparatus according to claim 3, wherein the sleeve is made of stainless steel, and a partition made of a magnetically permeable material is disposed between two adjacent cylindrical permanent magnets in the sleeve. Both ends of the casing are sealed by non-magnetic materials, and the sealing method is blocked by mechanical sealing or argon arc welding.
5. 如权利要求 2所述的净化装置, 其特征在于, 所述永磁体为部分圓环形, 若干个永磁体沿周向排列成与所述套管内径相匹配的圓环, 7j磁体的磁极方 向为其周向, 形成沿套管圓周排列的丽一 SS— NN ... ... SS磁极分布, 铁质杂质 有效吸附区遍布套管表面的周向和全长, 铁质杂质有效吸附区指的是套管表 面上与各永磁体磁极所在位置相对应的部位, 也就是各永磁体的磁力线各自 集中穿过套管侧壁的部位。 5. The purification apparatus according to claim 2, wherein the permanent magnet is partially annular, and the plurality of permanent magnets are circumferentially arranged in a ring shape matching the inner diameter of the sleeve, 7 j magnet The direction of the magnetic pole is its circumferential direction, forming a distribution of the Li-SS-NN SS magnetic poles arranged along the circumference of the sleeve. The effective adsorption area of the iron impurities is distributed throughout the circumference and the full length of the casing surface, and the iron impurities are effective. The adsorption zone refers to the portion of the surface of the sleeve corresponding to the position of the magnetic poles of the permanent magnets, that is, the portions of the magnetic lines of the permanent magnets that converge through the side walls of the sleeve.
6. 一种发电厂凝结水磁场除铁净化装置, 其特征在于, 该装置设置在汽轮机 凝汽器热水井内出水口的上方, 由若干根永磁管通过框架组合而成, 各永磁 管对水中铁质杂质的有效吸附范围在空间上依次相接, 从而形成一由若干个 永磁管单元磁场相互拼接而成的组合磁场; 随着水流穿过该组合磁场从热水 井流入其出水口, 水中的铁质杂质被吸附到组合磁场中的永磁管表面上; 所 述有效吸附范围为永磁管能够将铁质杂质吸附到其表面上的范围, 该范围为 一围绕永磁管的立体空间; 所述永磁管包括套管, 套管中若干个永磁体以同 极相对的形式被固定封装在内。 6. A power plant condensed water magnetic field iron removal purifying device, characterized in that the device is arranged above a water outlet of a steam turbine condenser hot water well, and is composed of a plurality of permanent magnet tubes through a frame, each permanent magnet tube The effective adsorption range of the iron impurities in the water is sequentially connected in space, thereby forming a combined magnetic field formed by merging magnetic fields of a plurality of permanent magnet tubes; the water flows through the combined magnetic field from the hot water The well flows into its water outlet, and the iron impurities in the water are adsorbed onto the surface of the permanent magnet tube in the combined magnetic field; the effective adsorption range is a range in which the permanent magnet tube can adsorb the iron impurities onto the surface thereof, and the range is one a three-dimensional space surrounding the permanent magnet tube; the permanent magnet tube includes a sleeve, and the plurality of permanent magnets in the sleeve are fixedly packaged in the opposite poles.
7. 如权利要求 6所述的净化装置, 其特征在于, 所述套管为圆管, 并由非导 磁性材料制成; 所述永磁体由铝镍钴、 钐钴合金、 钕铁硼或铁氧体永磁材料 制成。  7. The purification apparatus according to claim 6, wherein the sleeve is a circular tube and is made of a non-magnetic material; the permanent magnet is made of alumino-nickel-cobalt, samarium-cobalt alloy, neodymium-iron-iron or Made of ferrite permanent magnet material.
8. 如权利要求 7所述的净化装置, 其特征在于, 所述永磁体为与所述套管内 径相匹配的圓柱体段, 圆柱体段的磁极方向为其轴向, 若干个圓柱形永磁体 沿套管长度方向排列, 形成沿套管长度排列的 N (或 S ) — SS—題一 SS—題一 SS ... ... N (或 S )磁极分布, 铁质杂质有效吸附区遍布套管表面的周向和全长, 铁质杂质有效吸附区指的是套管表面上与各永磁体磁极所在位置相对应的部 位, 也就是各永磁体的磁力线各自集中穿过套管侧壁的部位。  8. The purification apparatus according to claim 7, wherein the permanent magnet is a cylindrical section matching the inner diameter of the sleeve, and the magnetic pole direction of the cylindrical section is an axial direction thereof, and a plurality of cylindrical shapes are The magnets are arranged along the length of the sleeve to form N (or S)-SS-----SS---S-N (or S) magnetic pole distribution arranged along the length of the sleeve, and the effective adsorption area of the iron impurities The circumferential and full length of the surface of the casing, the effective adsorption zone of the iron impurities refers to the location on the surface of the casing corresponding to the position of the magnetic poles of the permanent magnets, that is, the magnetic lines of each permanent magnet are concentrated through the casing side. The part of the wall.
9. 如权利要求 8所述的净化装置, 其特征在于, 所述套管由不锈钢制成, 套 管内两相邻所迷圓柱形永磁体之间设置有由导磁性材料制成的隔板, 套管两 端由非导磁性材料封堵, 封堵方式采用机械封堵或氩弧焊封堵。  9. The purification apparatus according to claim 8, wherein the sleeve is made of stainless steel, and a partition made of a magnetically permeable material is disposed between two adjacent cylindrical permanent magnets in the sleeve. Both ends of the casing are sealed by non-magnetic materials, and the sealing method is blocked by mechanical sealing or argon arc welding.
1 0. 如权利要求 7所述的净化装置, 其特征在于, 所述永磁体为部分圆环形, 若干个永磁体沿周向排列成与所述套管内径相匹配的圆环, 永磁体的磁极方 向为其周向, 形成沿套管圓周排列的而一 SS—題 ... ... SS磁极分布, 铁质杂质 有效吸附区遍布套管表面的周向和全长, 铁质杂质有效吸附区指的是套管表 面上与各永磁体磁极所在位置相对应的部位, 也就是各永磁体的磁力线各自 集中穿过套管侧壁的部位。  1 . The purification apparatus according to claim 7 , wherein the permanent magnet is partially annular, and the plurality of permanent magnets are circumferentially arranged in a ring matching the inner diameter of the sleeve, and the permanent magnet The direction of the magnetic pole is its circumferential direction, forming an arrangement along the circumference of the sleeve and an SS-question... SS magnetic pole distribution, the effective adsorption region of the iron impurity is distributed throughout the circumference and the full length of the casing surface, and the iron impurities The effective adsorption zone refers to the portion of the surface of the sleeve corresponding to the position of the magnetic poles of the permanent magnets, that is, the portions of the magnetic lines of the permanent magnets that converge through the side walls of the sleeve.
1 1. 如权利要求 6— 1 0任一所述的磁场除铁净化装置, 其特征在于, 所述若 干根永磁管通过框架环绕所述出水口组合成一中空的环形 , 通过该环形净化 装置对热水井内从四周流入出水口的水流进行除铁净化。  1 . The magnetic field iron removal purification device according to any one of claims 6 to 10, wherein the plurality of permanent magnet tubes are combined into a hollow ring shape around the water outlet through a frame, and the annular purification device is passed through The water flow flowing into the water outlet from the surrounding water in the hot water well is subjected to iron removal purification.
12. 如权利要求 1 1所述的磁场除铁净化装置, 其特征在于, 所述环形为方环 形, 该方环形结构由前、 后、 左、 右四个矩形平面单元拼接而成, 每个矩形 平面单元均由若干根永磁管通过框架组合而成。  12. The magnetic field iron removal apparatus according to claim 11, wherein the ring shape is a square ring shape, and the square ring structure is formed by splicing four rectangular plane units of front, rear, left, and right, each of which Rectangular planar units are assembled from a plurality of permanent magnet tubes through a frame.
1 3. 如权利要求 6— 1 0任一所述的磁场除铁净化装置, 其特征在于, 所述若 干根永磁管通过框架组合成一下端开口、 四周及顶部均布置有永磁管的罩形, 该罩形净化装置罩扣在出水口上方, 对热水井内从四周和上部流入出水口的 水流进行除铁净化。 The magnetic field iron removal purifying apparatus according to any one of claims 6 to 10, wherein The dry root permanent magnet tube is combined into a lower end opening, a circumference and a top portion are arranged with a cap shape of a permanent magnet tube, and the cover type purifying device cover is above the water outlet, and flows into the water outlet from the periphery and the upper portion in the hot water well. The water stream is subjected to iron removal purification.
14. 如权利要求 1 3所述的磁场除铁净化装置, 其特征在于, 所述罩形由前、 后、 左、 右、 上五个矩形平面单元拼接而成, 每个矩形平面单元均由若干根 永磁管通过框架组合而成。  14. The magnetic field iron removal purification apparatus according to claim 13, wherein the cover shape is formed by splicing five rectangular unit units of front, rear, left, right, and upper, each rectangular planar unit is A number of permanent magnet tubes are assembled by a frame.
15. 一种发电厂给水系统磁场除铁净化装置, 其特征在于, 该装置设置在发 电厂给水系统中的除氧水箱内, 为由多个水平设置的平面单元和多个垂直设 置的平面单元交叉构成的立体网架式结构, 多个水平设置的平面单元之间相 互平行间隔设置, 多个垂直平面单元之间同样相互平行间隔设置; 所述水平 设置的平面单元和所述垂直设置的平面单元均由若干根永磁管通过框架组合 而成, 各平面单元中的各永磁管对水中铁质杂质的有效吸附范围在空间上依 次相接, 从而形成一由若干个永磁管单元磁场相互拼接而成的平面状组合磁 场, 所述有效吸附范围为永磁管能够将铁质杂质吸附到其表面上的范围, 该 范围为一围绕永磁管的立体空间; 所述永磁管包括套管, 套管中若干个永磁 体以同极相对的形式被固定封装在内。  A magnetic field de-iron purification device for a power plant water supply system, characterized in that the device is disposed in an oxygen removal water tank in a power supply system of a power plant, and is a planar unit arranged by a plurality of horizontal units and a plurality of vertically arranged planar units a three-dimensional grid structure formed by intersecting, a plurality of horizontally disposed planar units are disposed in parallel with each other, and a plurality of vertical planar units are also disposed in parallel with each other; the horizontally disposed planar unit and the vertically disposed plane The unit is composed of a plurality of permanent magnet tubes through a frame, and the effective adsorption ranges of the permanent magnet tubes in each plane unit for the iron impurities in the water are sequentially connected in space, thereby forming a magnetic field of a plurality of permanent magnet tubes. a planar combined magnetic field formed by splicing each other, wherein the effective adsorption range is a range in which the permanent magnet tube can adsorb the iron impurities onto the surface thereof, and the range is a three-dimensional space surrounding the permanent magnet tube; The sleeve, a plurality of permanent magnets in the sleeve are fixedly packaged in the same polarity.
16. 如权利要求 15所述的净化装置, 其特征在于, 所述套管为圆管, 并由非 导磁性材料制成; 所述永磁体由铝镍钴、 钐钴合金、 钕铁硼或铁氧体永磁材 料制成。  16. The purification apparatus according to claim 15, wherein the sleeve is a circular tube and is made of a non-magnetic material; the permanent magnet is made of alumino-nickel-cobalt, samarium-cobalt alloy, neodymium-iron-iron or Made of ferrite permanent magnet material.
17. 如权利要求 1 6所述的净化装置, 其特征在于, 所述永磁体为与所述套管 内径相匹配的圓柱体段, 圆柱体段的磁极方向为其轴向, 若干个圓柱形永磁 体沿套管长度方向排列, 形成沿套管长度排列的 N (或 S ) — S S—丽一 SS—丽 -SS ... ... N (或 S )磁极分布, 铁质杂质有效吸附区遍布套管表面的周向和全 长, 铁质杂质有效吸附区指的是套管表面上与各永磁体磁极所在位置相对应 的部位, 也就是各永磁体的磁力线各自集中穿过套管侧壁的部位。  17. The purification apparatus according to claim 16, wherein the permanent magnet is a cylindrical section matching the inner diameter of the sleeve, and the magnetic pole direction of the cylindrical section is an axial direction thereof, and a plurality of cylindrical shapes. The permanent magnets are arranged along the length of the sleeve to form a N (or S)-SS-Li-SS-Li-SS N (or S) magnetic pole distribution arranged along the length of the sleeve, and the iron impurities are effectively adsorbed. The area is distributed in the circumferential direction and the full length of the surface of the casing. The effective adsorption area of the iron impurities refers to the position on the surface of the casing corresponding to the position of the magnetic poles of the permanent magnets, that is, the magnetic lines of each permanent magnet are concentrated through the casing. The part of the side wall.
18. 如权利要求 1 7所述的净化装置, 其特征在于, 所述套管由不锈钢制成, 套管内两相邻所述圓柱形永磁体之间设置有由导磁性材料制成的隔板, 套管 两端由非导磁性材料封堵, 封堵方式采用机械封堵或氩弧焊封堵。  18. The purification apparatus according to claim 17, wherein the sleeve is made of stainless steel, and a separator made of a magnetically permeable material is disposed between two adjacent cylindrical permanent magnets in the sleeve. The two ends of the casing are sealed by non-magnetic materials, and the sealing method is blocked by mechanical sealing or argon arc welding.
19. 如权利要求 16所述的净化装置, 其特征在于, 所述永磁体为部分圆环形, 若干个永磁体沿周向排列成与所述套管内径相匹配的圓环, 永磁体的磁极方 向为其周向, 形成沿套管圓周排列的皿一 SS— NN ... ... SS磁极分布, 铁质杂质 有效吸附区遍布套管表面的周向和全长, 铁质杂质有效吸附区指的是套管表 面上与各永磁体磁极所在位置相对应的部位, 也就是各永磁体的磁力线各自 集中穿过套管侧壁的部位。 19. The purification apparatus according to claim 16, wherein the permanent magnet is partially annular, and the plurality of permanent magnets are circumferentially arranged in a ring matching the inner diameter of the sleeve, and the permanent magnet Magnetic pole To its circumferential direction, a dish-SS-NN SS magnetic pole distribution is formed along the circumference of the casing. The effective adsorption zone of the iron impurities is distributed over the circumferential and full length of the casing surface, and the iron impurities are effectively adsorbed. The area refers to the part of the surface of the sleeve corresponding to the position of the magnetic poles of the permanent magnets, that is, the magnetic lines of each permanent magnet are respectively concentrated through the side wall of the sleeve.
20. 一种对发电厂锅炉 (核电厂蒸汽发生器)给水进行除铁净化的方法, 其 特征在于, 在发电厂汽轮机凝汽器的热水井内设置权利要求 6— 14任一所述 的磁场除铁净化装置, 利用该装置对从热水井流出的水进行除铁净化处理。 A method for de-ironing and purifying a feed water of a power plant boiler (a steam generator of a nuclear power plant), characterized in that a magnetic field according to any one of claims 6 to 14 is provided in a hot water well of a steam turbine condenser of a power plant In addition to the iron purification device, the water discharged from the hot water well is subjected to iron removal purification treatment.
21. 一种对发电厂锅炉 (核电厂蒸汽发生器)给水进行除铁净化的方法, 其 特征在于, 在发电厂给水系统中的除氧水箱内设置权利要求 1 5— 1 9任一所述 的磁场除铁净化装置, 利用该装置对从热水井流出的水进行除铁净化处理。A method for de-ironing and purifying a feed water of a power plant boiler (a steam generator of a nuclear power plant), characterized in that the oxygen-removing water tank in the power supply system of the power plant is provided with any one of claims 15 to 19. The magnetic field removing iron purifying device uses the device to perform iron removal purification treatment on the water flowing out of the hot water well.
22. 一种对发电厂锅炉 (核电厂蒸汽发生器)给水进行除铁净化的方法, 其 特征在于, 在发电厂汽轮机凝汽器的热水井内设置权利要求 6— 14任一所述 的磁场除铁净化装置, 利用该装置对从热水井流出的水进行除铁净化处理; 在发电厂给水系统中的除氧水箱内设置权利要求 15— 19任一所述的磁场除铁 净化装置, 利用该装置对从热水井流出的水进行除铁净化处理。 A method for de-ironing and purifying a feed water of a power plant boiler (a steam generator of a nuclear power plant), characterized in that the magnetic field according to any one of claims 6 to 14 is provided in a hot water well of a steam turbine condenser of a power plant The iron purification device is used to perform the iron removal purification treatment on the water flowing out of the hot water well; and the magnetic field iron removal purification device according to any one of claims 15 to 19 is disposed in the oxygen removal water tank in the power supply system of the power plant. The device is used to perform iron removal purification treatment on the water flowing out of the hot water well.
PCT/CN2010/077206 2009-09-25 2010-09-21 Iron removal purification device with magnetic field and its application of condensed water and water supply in power plant WO2011035715A1 (en)

Applications Claiming Priority (4)

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CN200910176939A CN101648743A (en) 2009-09-25 2009-09-25 Magnetic field deironing and purifying device of condensed water
CN200910176938.8 2009-09-25
CN200910176939.2 2009-09-25
CN200910176938A CN101648742A (en) 2009-09-25 2009-09-25 Magnetic field deironing and purifying device of water supply system

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CN105883985A (en) * 2016-05-18 2016-08-24 胡建军 Gyromagnetic electrolyzed water treatment device
CN105884066A (en) * 2016-05-26 2016-08-24 江苏兴隆防腐设备有限公司 Low-energy-consumption sewage treatment equipment

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