WO2011028617A2 - Apparatus and methods for enhanced fluid delivery on bevel etch applications - Google Patents
Apparatus and methods for enhanced fluid delivery on bevel etch applications Download PDFInfo
- Publication number
- WO2011028617A2 WO2011028617A2 PCT/US2010/046848 US2010046848W WO2011028617A2 WO 2011028617 A2 WO2011028617 A2 WO 2011028617A2 US 2010046848 W US2010046848 W US 2010046848W WO 2011028617 A2 WO2011028617 A2 WO 2011028617A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- supply
- fluid
- network
- valve
- edge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/04—Apparatus for manufacture or treatment
- H10P72/0402—Apparatus for fluid treatment
- H10P72/0418—Apparatus for fluid treatment for etching
- H10P72/0422—Apparatus for fluid treatment for etching for wet etching
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/04—Apparatus for manufacture or treatment
- H10P72/0402—Apparatus for fluid treatment
- H10P72/0418—Apparatus for fluid treatment for etching
- H10P72/0422—Apparatus for fluid treatment for etching for wet etching
- H10P72/0424—Apparatus for fluid treatment for etching for wet etching using mainly spraying means, e.g. nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
- B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
- B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
- B05C11/1026—Valves
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10P—GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10P72/00—Handling or holding of wafers, substrates or devices during manufacture or treatment thereof
- H10P72/04—Apparatus for manufacture or treatment
- H10P72/0402—Apparatus for fluid treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T137/00—Fluid handling
- Y10T137/0318—Processes
Definitions
- an apparatus to supply a plurality of process fluids for processing a substrate in a semiconductor processing chamber includes a plurality of process fluid supply valves and a fluid supply network that is defined between a crossover valve and a tuning supply valve.
- the apparatus further includes a tuning fluid supply being connected to the fluid supply network through the tuning supply valve.
- a plurality of process fluids that are connected to the fluid supply network through the plurality of process fluid supply valves.
- a process chamber that has a substrate support is also included in the apparatus.
- the process chamber further including an edge fluid supply and a center fluid supply.
- the edge fluid supply is connected to the fluid supply network through an edge enable valve and the center supply is connected to the fluid supply network through a center enable valve.
- the crossover valve, edge enable valve, and center enable valve allow one of tuning fluid or process fluids to flow to one of the edge fluid supply or the center fluid supply.
- a method to provide flexible application of a tuning fluid and a process fluid to a substrate includes operations that enable flow of the tuning fluid to a center supply through a first supply network.
- the first supply network is coupled to a cross-flow network that includes a closed crossflow valve.
- process fluid flow is enabled to the edge supply through a second supply network, where the second supply network is coupled to the cross-flow network.
- flow of the tuning fluid and the process fluid is disabled.
- the first supply network, the second supply network, the cross-flow network, the center supply and the edge supply are purged through a purge network that is connected between the cross-flow network and the center supply and edge supply.
- flow of the process fluid is enabled, wherein a open cross-flow valve routes the process fluid to the center supply.
- Figure 1 shows a simplified exemplary schematic of a fluid supply system for a processing chamber for use in semiconductor fabrication, in accordance with one embodiment of the present invention.
- Figure 2 is an exemplary cross-section view of a chamber, in accordance with one embodiment of the present invention.
- Figure 3 is an exemplary illustration of a close up of a cross-section of an edge feed within the chamber in accordance with one embodiment of the present invention.
- Figure 4 is an exemplary illustration of a cross-section of a center feed within the chamber, in accordance with one embodiment of the present invention.
- Figure 5 is an exemplary illustration of valve positions for routing the tuning fluid to the center of the substrate and the process fluids to the edge of the substrate, in accordance with one embodiment of the present invention.
- Figure 6A is an exemplary illustration of valve positions for purging the input supply network, the crossover supply network and the chamber supply network, in accordance with one embodiment of the present invention.
- Figure 6B illustrates an embodiment for the purge of a single process gas in accordance with one embodiment of the invention.
- Figure 6C illustrates an embodiment for the valve positions for the purging of the supply and tuning lines in accordance with one embodiment of the invention.
- Figure 6D is a simplified schematic diagram illustrating the valve positions for a chamber vent process in accordance with one embodiment of the invention.
- Figure 7A is an exemplary illustration of valve positions for routing the process fluid to the center of the substrate, in accordance with one embodiment of the present invention.
- Figure 7B illustrates the valve positions for delivering tuning and process fluids to an edge of the edge region of a substrate disposed in the chamber.
- FIG. 8 is flow chart with exemplary illustrations for modifying the flow of a tuning fluid and process fluids in accordance with one embodiment of the present invention.
- An invention for providing flexible configuration for semiconductor processing equipment.
- the ability to rapidly reconfigure a processing chamber provides manufacturers with flexibility regarding they type of processes that can be performed. This can lead to faster production times and decreased tool downtime for reconfiguration.
- a supply network is disclosed that enables edge etching process fluids to be routed and dispensed near the center of a substrate.
- tuning fluids normally distributed near the center of the substrate may be routed to and dispensed near the edge of the substrate.
- the process fluids can be routed toward the center of the substrate, or the process fluids can be routed to both the center of the substrate and the edge of the substrate.
- FIG. 1 illustrates a simplified exemplary schematic of a fluid supply system for a processing chamber 100 for use in semiconductor fabrication, in accordance with one embodiment of the present invention.
- the processing chamber 100 is configured with a chamber supply network 126 that includes an edge supply 126a and a center supply 126b. Coupled to the chamber supply network 126 is a crossover network 124. Within the crossover network 124, there is a crossflow valve 116, an edge enable valve 108 and a center enable valve 110. The edge enable valve 108 and the center enable valve 110 are optional for this embodiment and should be considered exemplary. Other embodiments may include additional valves within the crossover network 124.
- the source network 122 includes five fluid sources Gl - G5 although more or fewer fluid sources may be used.
- Gl is a tuning fluid such as nitrogen.
- Gl can be another fluid such as any suitable inert gas or even a mixture of inert gases, such as argon, helium, neon, xenon, etc.
- the other four fluid sources G2 - G5 are process fluids that can be combined in various ratios depending on the processing being performed within the chamber 100.
- fluid sources G2-G5 can include processing fluids for use in an etching process such as, but not limited to, oxygen (0 2 ), carbon dioxide (C0 2 ), tetrafluoromethane (CF 4 ), sulfur tetrafluoride (SF 4 ) and SF 6 , etc., or mixtures thereof.
- processing fluids for use in an etching process such as, but not limited to, oxygen (0 2 ), carbon dioxide (C0 2 ), tetrafluoromethane (CF 4 ), sulfur tetrafluoride (SF 4 ) and SF 6 , etc., or mixtures thereof.
- the individual fluids G1-G5 can be dispensed individually through respective valves V1-V5.
- the tuning fluid is connected to the center supply 126b through the crossover network 124.
- the fluid sources G2-G5 are connected to the edge supply 126a.
- the crossover network 124 allows the chamber to change configurations, thereby allowing process fluids G2-G5 to be sent to the center supply 126b.
- the crossover network 124 can further allow the tuning fluid to be routed to the edge supply 126a.
- purge valves 112, 114, 118 and 120 Coupled to both the source network 122 and the chamber supply network 126 are purge valves 112, 114, 118 and 120.
- the purging valves may be omitted in order to simplify fabrication and reduce fabrication costs.
- pump 101 is in fluid communication with valves 112 and 114.
- pump 101 is in fluid communication with chamber 100 through valve 103 for purging the chamber.
- valve 103 represents a throttle control valve that opens and closes to maintain a certain chamber pressure, i.e., the throttle control valve does not seal.
- the crossover network 124 allows fluid that was sent to the edge supply 126a to be sent to the center supply 126b.
- One advantage of including the purge valves is the potential to reduce fluid transition times and improved control over pressure transients during fluid switching processing.
- the purge valves allow fluids within the supplies to be quickly evacuated before switching the crossover valve. Thus, the purge valves can allow for faster transitions times when altering the flow of fluids to the process chamber.
- a separate purge fluid can be used to clear the respective supplies.
- the ability to have a separate purge fluid from the tuning fluid allows enhanced process control while reducing potential contamination issues by means of introducing alternative chemistries to the center or the edge supplies.
- the ability to easily change the configuration of the fluid supplies can provide flexibility during the processing of semiconductor substrates. For example, the ability to split the flow such that the tuning fluid is delivered to the center supply 126b and the process fluid is delivered to the edge supply 126a, allows for increased process performance and a reduction in potential contamination issues. Furthermore, the ability to change the configuration of the fluid supplies can reduce the total number of processing chambers required to process a semiconductor substrate. Additionally, the ability to route all fluids to the edge supply 126a or the center supply 126b provides flexibility in developing new processes with enhanced process performance and reduced contamination issues.
- Figure 2 is an exemplary cross-section view of a chamber 100, in accordance with one embodiment of the present invention.
- the cross-section illustrates both a center feed 202 and an edge feed 200 within the chamber 100.
- the edge feed 200 is connected to the edge supply from Figure 1.
- the center feed 202 is connected to the center supply from Figure 1.
- fluids routed to the edge supply of Figure 1 are distributed within the chamber 100 by the edge feed 200.
- fluids routed to the center supply of Figure 1 are distributed within the chamber 100 by the center feed 202.
- a plate 204 and a top plate 206 are visible. Additionally, the chamber liner 208 is visible.
- the center feed 202 and the edge feed 200 enter through the top of the chamber 100. Visible on top of the chamber 100 are center isolation valve 106 and edge isolation valve 104. As illustrated, the center feed 202 obstructs the view the edge feed 200. In the embodiment shown, the edge feed 200 is located behind the center feed 202.
- the edge feed 200 includes a manifold that distributes the edge feed 200 to a plurality of branches that extend radially toward the edge of a substrate. This allows the edge feed 200 to distribute fluid to multiple points around the edge of a substrate within the chamber.
- fluid supplied to the center feed is dispensed through a plurality of ports in order to promote even distribution of the fluid around the center of the substrate.
- FIG. 3 is an exemplary illustration of a close up of a cross-section of an edge feed 200 within the chamber 100 in accordance with one embodiment of the present invention.
- the chamber 100 is shown in a closed position with a bottom surface of the top plate 206 proximate to a top surface of substrate 300. Also visible is the cross-section of an edge feed 200.
- the edge feed 200 allows fluid supplied to the edge supply to flow toward the edge of the substrate 300. Recall that similar edge feeds are distributed around the perimeter of the substrate 300. Such a configuration allows process fluids or a tuning fluid to be distributed evenly around the substrate.
- process fluids for an etch operation are directed to the edge feed 200.
- the processing chamber may be reconfigured so the edge feed 200 supplies a tuning fluid to the edge of a substrate.
- FIG 4 is an exemplary illustration of a cross-section of a center feed 202 within the chamber 100, in accordance with one embodiment of the present invention. Fluids are supplied to the center feed 202 through the center supply.
- a manifold within the chamber distributes the fluid from the center feed 202 over the center of the substrate 300.
- the number of distribution ports from the manifold should not be considered limiting and other embodiments can have fewer or more distribution ports coupled to the center feed 202.
- FIG. 5 is an exemplary illustration of valve positions for routing the tuning fluid to the center of the substrate and the process fluids to the edge of the substrate, in accordance with one embodiment of the present invention.
- flow of the tuning fluid is illustrated with a diagonal fill pattern.
- the tuning fluid is shown flowing through VI from the supply Gl.
- fluid from supplies G2, G3, G4 and G5 flow through their respective valves V2, V3, V4 and V5.
- purge valves 118 and 120 are closed to promote flow of the tuning fluid and process fluid to the crossover network 124.
- crossover valve 116 being closed and the edge enable valve 110 being open, the tuning fluid enters into the chamber supply 126.
- the edge enable valve 108 is open and the process fluid enters into the chamber supply 126.
- Both the edge pumpout valve 112 and the center pumpout valve 114 are shown as closed in order to enable fluid flow to the chamber.
- edge isolation valve 104 and center isolation valve 106 are in an open position to allow fluid to flow into the chamber. It should be appreciated that if valve VI is closed then process fluids are supplied to the edge and the tuning fluid is not delivered to the center region of chamber 100.
- FIG. 6A is an exemplary illustration of valve positions for purging the input supply network, the crossover supply network and the chamber supply network, in accordance with one embodiment of the present invention.
- Purging the entire fluid supply network can be performed to evacuate any residual process fluid or tuning fluid and in the instance where all the mass flow controllers are to be changed.
- the edge pumpout valve 112, the center pumpout valve 114, the center purge valve 118 and the edge purge valve 120 are open.
- the edge enable valve 108, the center enable valve 110, and the crossover valve 116 are shown as closed. This allows the center purge valve 118 and the edge purge valve 120 to evacuate any remaining fluid from the combined input supply network and the crossover supply network.
- the open edge pumpout 112 and center pumpout 114 along with the open edge isolation valve 104 and center isolation valve 106 allow fluid within the chamber supply 126 to be evacuated.
- the edge isolation valve 104 and the center isolation valve 106 are closed when the edge pumpout valve 112 and center pumpout valve 114 are open. This can assist in preventing and particulate or particulates trapped within the filters 102 from becoming dislodged and being pulled into the respective chamber supply lines.
- the edge enable valve 108 and center enable can be left open thereby allowing both the purge valves 118 and 120 to function in conjunction with the pumpout valves 112 and 114.
- the embodiment illustrated in Figure 6A should be construed as exemplary.
- Other embodiments may include additional valves to enable or disable fluid flow.
- hand valves (HV) 1-5 are provided to isolate the process fluid supplies G1-G5 in this embodiment.
- additional valve, pumps, recycling lines and supply lines may be necessary to effectuate proper flow within the system. For the sake of simplicity, such items have been omitted from the drawings.
- FIG. 6B illustrates an embodiment for the purge of a single process gas in accordance with one embodiment of the invention.
- valve 120 is open, as well as valves V3 108, and 104 to enable the purging of G3 and the corresponding line. It should be appreciated that valve 120 is open and valve 103 is closed for the purge process and when the pumpout of chamber 100 occurs valve 120 closes and valve 103 opens.
- this embodiment may be employed for changing a single mass flow controller along the corresponding line.
- FIG. 6C illustrates an embodiment for the valve positions for the purging of the supply and tuning lines in accordance with one embodiment of the invention.
- valves 118 and 120 are open for the purge process, while valve 103 is closed.
- valve 103 is open while valves 118 and 120 are closed.
- Figure 6D is a simplified schematic diagram illustrating the valve positions for a chamber vent process in accordance with one embodiment of the invention.
- Valves 118, 110 and 106 are initially open to purge and in one embodiment, when the chamber pressure reaches a certain pressure valves 118, 110 and 106 close. In one exemplary embodiment, when the chamber pressure is greater than or equal to one atmosphere, valves 118, 110, and 106 close.
- FIG. 7A is an exemplary illustration of valve positions for routing the process fluid to the center of the substrate, in accordance with one embodiment of the present invention.
- the process fluid is shown with a diagonal hatch pattern flowing to both the center of the substrate.
- the process fluid is supplied through fluid supplies G2, G3, G4 and G4. Opening the crossover valve 116 allows the process fluid to crossover from the edge supply 126a to the center supply 126b.
- the center enable valve 110 is in the open position. It should be appreciated that if VI is open then tuning and process fluid is delivered to the center region.
- Figure 7B illustrates the valve positions for delivering tuning and process fluids to an edge of the edge region of a substrate disposed in chamber 100.
- valves 104, 108 and 116 are open to enable the tuning and process fluids access to the edge region.
- FIG. 8 is an exemplary flow chart illustrating procedural operations to modify the flow of process fluids in accordance with one embodiment of the present invention.
- the procedure is initiated by operation 800, where flow of a tuning fluid to a process chamber is initiated.
- the tuning fluid flows through an input supply, a crossover network, and a chamber supply before being dispensed within the process chamber.
- Operation 802 initiates fluid flow of process fluids to the process chamber.
- the process fluids are supplied to the process chamber through an input supply, the crossover network, and the chamber supply.
- the chamber supply includes an edge supply and a center supply that are both connected to the crossover network.
- the input supply may include a plurality of supplies.
- the input supply has a first supply for the tuning fluid and a second supply for the process fluid.
- each of the respective supplies for the tuning fluid and process fluids are connected to the crossover network.
- Operation 804 flow of both the tuning fluid and the process fluid is stopped.
- Operation 806 purges the input supply, the crossover network and the chamber supply.
- Operation 808 flows one of either the process fluid or the tuning fluid to both the center supply and the edge supply through an open crossover valve within the crossover network.
- operation 800 can flow process fluid rather than tuning fluid.
- operation 802 can flow tuning fluid rather than process fluid.
- the purge operation can include flowing of non-reactive fluids within the input supplies, the crossover network and the chamber supply. Such an operation can be used to minimize potential contamination from residual process or tuning fluid within a supply.
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Abstract
Description
Claims
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SG2012013629A SG178585A1 (en) | 2009-09-04 | 2010-08-26 | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
| KR1020127005731A KR101741283B1 (en) | 2009-09-04 | 2010-08-26 | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
| CN201080039169.8A CN102484064B (en) | 2009-09-04 | 2010-08-26 | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
| JP2012527921A JP5763076B2 (en) | 2009-09-04 | 2010-08-26 | Apparatus and method for facilitating fluid delivery for bevel etching |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/554,871 | 2009-09-04 | ||
| US12/554,871 US8328980B2 (en) | 2009-09-04 | 2009-09-04 | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2011028617A2 true WO2011028617A2 (en) | 2011-03-10 |
| WO2011028617A3 WO2011028617A3 (en) | 2011-06-09 |
Family
ID=43648118
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/US2010/046848 Ceased WO2011028617A2 (en) | 2009-09-04 | 2010-08-26 | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
Country Status (7)
| Country | Link |
|---|---|
| US (2) | US8328980B2 (en) |
| JP (1) | JP5763076B2 (en) |
| KR (1) | KR101741283B1 (en) |
| CN (1) | CN102484064B (en) |
| SG (1) | SG178585A1 (en) |
| TW (1) | TWI501337B (en) |
| WO (1) | WO2011028617A2 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8328980B2 (en) * | 2009-09-04 | 2012-12-11 | Lam Research Corporation | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
| US10937634B2 (en) | 2013-10-04 | 2021-03-02 | Lam Research Corporation | Tunable upper plasma-exclusion-zone ring for a bevel etcher |
| JP2016134569A (en) * | 2015-01-21 | 2016-07-25 | 株式会社東芝 | Semiconductor manufacturing equipment |
| US20240203695A1 (en) * | 2022-12-16 | 2024-06-20 | Applied Materials, Inc. | Fast gas switching |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4487338B2 (en) | 1999-08-31 | 2010-06-23 | 東京エレクトロン株式会社 | Film forming apparatus and film forming method |
| JP4550507B2 (en) | 2004-07-26 | 2010-09-22 | 株式会社日立ハイテクノロジーズ | Plasma processing equipment |
| US8083890B2 (en) | 2005-09-27 | 2011-12-27 | Lam Research Corporation | Gas modulation to control edge exclusion in a bevel edge etching plasma chamber |
| US8088248B2 (en) * | 2006-01-11 | 2012-01-03 | Lam Research Corporation | Gas switching section including valves having different flow coefficients for gas distribution system |
| US7540971B2 (en) | 2006-04-28 | 2009-06-02 | Applied Materials, Inc. | Plasma etch process using polymerizing etch gases across a wafer surface and additional polymer managing or controlling gases in independently fed gas zones with time and spatial modulation of gas content |
| JP5005268B2 (en) * | 2006-06-12 | 2012-08-22 | 株式会社日立ハイテクノロジーズ | Plasma processing equipment |
| US8074677B2 (en) * | 2007-02-26 | 2011-12-13 | Applied Materials, Inc. | Method and apparatus for controlling gas flow to a processing chamber |
| US7981307B2 (en) | 2007-10-02 | 2011-07-19 | Lam Research Corporation | Method and apparatus for shaping gas profile near bevel edge |
| JP5192214B2 (en) * | 2007-11-02 | 2013-05-08 | 東京エレクトロン株式会社 | Gas supply apparatus, substrate processing apparatus, and substrate processing method |
| US8328980B2 (en) * | 2009-09-04 | 2012-12-11 | Lam Research Corporation | Apparatus and methods for enhanced fluid delivery on bevel etch applications |
-
2009
- 2009-09-04 US US12/554,871 patent/US8328980B2/en active Active
-
2010
- 2010-08-26 JP JP2012527921A patent/JP5763076B2/en active Active
- 2010-08-26 KR KR1020127005731A patent/KR101741283B1/en active Active
- 2010-08-26 SG SG2012013629A patent/SG178585A1/en unknown
- 2010-08-26 CN CN201080039169.8A patent/CN102484064B/en active Active
- 2010-08-26 WO PCT/US2010/046848 patent/WO2011028617A2/en not_active Ceased
- 2010-09-02 TW TW099129649A patent/TWI501337B/en active
-
2012
- 2012-11-05 US US13/668,741 patent/US8671965B2/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| TWI501337B (en) | 2015-09-21 |
| US20110059614A1 (en) | 2011-03-10 |
| KR101741283B1 (en) | 2017-06-15 |
| US20130056078A1 (en) | 2013-03-07 |
| CN102484064B (en) | 2014-12-03 |
| JP2013504204A (en) | 2013-02-04 |
| WO2011028617A3 (en) | 2011-06-09 |
| SG178585A1 (en) | 2012-03-29 |
| US8328980B2 (en) | 2012-12-11 |
| JP5763076B2 (en) | 2015-08-12 |
| US8671965B2 (en) | 2014-03-18 |
| TW201120982A (en) | 2011-06-16 |
| CN102484064A (en) | 2012-05-30 |
| KR20120060837A (en) | 2012-06-12 |
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