WO2011005725A2 - Method and system for enhanced oil recovery - Google Patents
Method and system for enhanced oil recovery Download PDFInfo
- Publication number
- WO2011005725A2 WO2011005725A2 PCT/US2010/041014 US2010041014W WO2011005725A2 WO 2011005725 A2 WO2011005725 A2 WO 2011005725A2 US 2010041014 W US2010041014 W US 2010041014W WO 2011005725 A2 WO2011005725 A2 WO 2011005725A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- output stream
- combustion chamber
- oxygen
- gas injection
- injection method
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 36
- 238000011084 recovery Methods 0.000 title claims abstract description 22
- 238000002485 combustion reaction Methods 0.000 claims abstract description 56
- 239000004449 solid propellant Substances 0.000 claims abstract description 32
- 239000007924 injection Substances 0.000 claims abstract description 28
- 238000002347 injection Methods 0.000 claims abstract description 28
- 239000012530 fluid Substances 0.000 claims abstract description 22
- 230000037361 pathway Effects 0.000 claims abstract description 16
- 239000007789 gas Substances 0.000 claims description 48
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 39
- 229910052760 oxygen Inorganic materials 0.000 claims description 39
- 239000001301 oxygen Substances 0.000 claims description 39
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 230000008878 coupling Effects 0.000 claims 1
- 238000010168 coupling process Methods 0.000 claims 1
- 238000005859 coupling reaction Methods 0.000 claims 1
- 239000013529 heat transfer fluid Substances 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 claims 1
- 239000003921 oil Substances 0.000 description 30
- 239000003245 coal Substances 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000001569 carbon dioxide Substances 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 230000005540 biological transmission Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 238000010795 Steam Flooding Methods 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- QGJOPFRUJISHPQ-NJFSPNSNSA-N carbon disulfide-14c Chemical compound S=[14C]=S QGJOPFRUJISHPQ-NJFSPNSNSA-N 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
Definitions
- the invention relates to a gas injection method for enhanced oil recovery.
- Enhanced oil recovery is a term for techniques applied to increase the amount of crude oil that can be extracted from an oil field. Through enhanced oil recovery techniques, 30-60% or more of the reservoir's original oil can be extracted compared with 20-40% using primary and secondary recovery methods. Enhanced oil recovery is also referred to as improved oil recovery or tertiary recovery. Enhanced oil recovery is achieved by gas injection, chemical injection, ultrasonic stimulation, microbial injection, or thermal recovery such as cyclic steam, steamflooding, and fireflooding. Gas injection is presently the most-commonly used approach to enhanced oil recovery. A gas, such as carbon dioxide or natural gas or nitrogen, is injected into the oil-bearing stratum under high pressure. The pressure of the gas pushes the oil toward the production well and assists in driving the oil up to the surface. In addition to providing a source of driving-pressure, the gas can also mix with the oil and thereby reduce the viscosity of the oil.
- a gas such as carbon dioxide or natural gas or nitrogen
- the invention is a system and method for gas injection enhanced oil recovery.
- the method includes the step of burning solid fuel and an oxygen-bearing gas in a combustion chamber.
- the method also includes the step directing an output stream of the burning step through a fluid pathway extending from the combustion chamber and underground to push oil toward a well.
- the method includes the step maintaining the pressure in the combustion chamber above ambient during the burning step.
- Figure 1 is a simplified schematic of a system according to an exemplary embodiment of the invention.
- a system 10 includes a combustion chamber 12 operable to contain solid fuel and an oxygen-bearing gas while burning at a pressure maintained above ambient.
- the system 10 also includes a fluid pathway 14 extending from the combustion chamber 12 and underground 16 for directing an output stream of the combustion chamber 12 to push underground oil toward a well 18.
- the exemplary system 10 can also include a sub-system for power generation.
- a thermal fluid such as water can travel along a closed-loop fluid circuit 20.
- a condenser 22, a pump 24, a heat exchanger 26, and a steam turbine 28 can be positioned along the fluid circuit 20.
- Thermal fluid in liquid state can be pumped by the pump 24 to the heat exchanger 26.
- the thermal fluid can extract thermal energy from the output stream of the combustion chamber 12 to change to vapor state.
- a portion 30 of the fluid pathway 14 can pass through the heat exchanger 26.
- the thermal fluid in vapor state, such as steam can move from the heat exchanger 26 and pass across the steam turbine 28. The energy of the thermal fluid can be extracted and converted to rotation by the steam turbine 28.
- the steam turbine 28 can transmit rotational power to other components, such as a rotor of a generator 32.
- the generator 32 can generate electricity in response to the input of rotational power from the steam turbine 28. It is noted that rotational power can be transmitted directly from the steam turbine 28 or through intermediary structures, such as a transmission or clutch. It is also noted that the steam turbine 28 can transmit rotational power to structures other than the generator 32. After passing across the steam turbine 28, the thermal fluid can pass through the condenser 22 and return to liquid state.
- the solid fuel can be coal.
- Any kind of coal can be used in practicing various embodiments of the broader invention.
- the coal can be of relatively high or relatively low carbon content.
- the coal can be of relatively high or relatively low sulfur content. Burning coal having a higher sulfur content can result in the production of carbon disulfide, which can be helpful in thinning the underground oil. Thinning the oil can be helpful in promoting oil recovery.
- the solid fuel can be directed to the combustion chamber 12 with a solid fuel handler 34, shown schematically.
- the solid fuel handler 12 can be a device, or a plurality of devices working together, operable to receive the solid fuel and deliver the solid fuel to the combustion chamber 12 in a desired form.
- the solid fuel handler 34 can be operable to deliver coal to the combustion chamber 12 in powder form.
- the solid fuel handler 34 can include a pulverizer to reduce the size of individual pieces of solid fuel.
- the solid fuel handler 34 can also include devices for containing the solid fuel such as hoppers and/or also include devices for moving the solid fuel such as conveyors from a railroad receiving station and/or injectors projecting into the combustion chamber 12.
- the device or devices of the solid fuel handler 34 can be supplied with rotational or mechanical power directly or indirectly from the steam turbine 28, or can be supplied with electrical power from the generator 32. It is noted that the dashed lines in Figure 1 represent paths for the transmission of electrical power.
- the oxygen-bearing gas delivered to the combustion chamber 12 can be pure oxygen or air.
- the nature of the output stream will be affected by the properties of the solid fuel and the properties of the oxygen-bearing gas.
- the output stream can be substantially pure carbon dioxide. Carbon dioxide is miscible in oil and can therefore be helpful in promoting oil recovery.
- carbon disulfide can be a component of the output stream.
- the output stream can include carbon dioxide, nitrogen, water, ash, as well as trace amounts of other gases. All of these components can be directed underground. Alternatively, one or more of these components can be separated from the rest of the output stream before the remainder of the output stream is directed underground.
- the system 10 can include an oxygen separator 36 on site with the combustion chamber 12 for separating oxygen from air and delivering substantially pure oxygen to the combustion chamber 12.
- the oxygen separator 36 can apply any process for oxygen separation.
- cryogenic air separation can be applied.
- U.S. Pat. No. 6,279,344 is hereby incorporated by reference as one example of a cryogenic air separation method in which a stream of oxygen is generated.
- Another process for separating oxygen from air or generating an oxygen stream occurs in a solid oxide fuel cell. Air can be pressurized to around 300 p.s.i. and injected into a fuel cell. Electric current can be passed through the cell to generate a stream of oxygen.
- 7,531,260 is hereby incorporated by reference as one example of a solid oxide fuel cell that can be applied in embodiments of the invention.
- the oxygen separator 36 can be supplied with rotational or mechanical power directly or indirectly from the steam turbine 28, or can be supplied with electrical power from the generator 32.
- the oxygen generated by the oxygen separator 36, or any other oxygen-bearing gas directed into the combustion chamber 12, can be compressed by a compressor 38.
- the compressor 38 can also compress air directed to the oxygen separator 36.
- the compressor 38 can be operable to compress the oxygen-bearing gas to between 200 p.s.i. and 3000 p.s.i. in various embodiments of the invention. Some embodiments of the broader invention can be practiced wherein the range of pressure is 1500 - 2500 p.s.i. Other embodiments of the broader invention can be practiced over different ranges.
- the combustion chamber 12 is operable to contain the solid fuel and the oxygen-bearing gas while the combination is burned at a predetermined pressure above ambient or while burning over a pressure range.
- the compressor 38 can be supplied with rotational or mechanical power directly or indirectly from the steam turbine 28, or can be supplied with electrical power from the generator 32.
- the combined solid fuel and oxygen-bearing gas can be burned in the combustion chamber at a pressure of between 200 - 3000 p.s.i. and at a peak temperature of between 4500 0 F - 6000 0 F, outlet temperatures will be between 100 and 4000F .
- the combustor chamber 12 can be about 1/100 of the size of a combustion chamber currently used in enhanced oil recovery systems. This benefit can be enjoyed because, generally, a heat transfer coefficient of the output stream changes with changes in pressure. As the pressure during combustion increases, the heat transfer coefficient increases so that more energy can be extracted at the heat exchanger 26. Another benefit that can be enjoyed from higher-than-
- the heat exchanger can be about 1/40 of the size of a heat exchanger currently used in coal fired power plants.
- ash can be a portion of the output stream of combustion. If the ash does not clog the fluid pathway 14 or otherwise hinder oil recovery, the ash can be directed underground with the gases generated by combustion.
- the system 10 can also include ash handling equipment, represented schematically at 40 in Figure 1.
- the ash handling equipment 40 is shown positioned between portions 42, 44 of the fluid pathway 14, but the ash handling equipment 40 could be positioned at another location in alternative embodiments of the invention.
- the ash handling equipment 40 could be an electrostatic precipitator or could remove ash by another process.
- the ash handling equipment 40 can be supplied with rotational or mechanical power directly or indirectly from the steam turbine 28, or can be supplied with electrical power from the generator 32.
- the system 10 can include a recirculation pathway 46.
- a portion of the output stream of combustion can be returned to the combustion chamber 12 after the output stream has passed the ash handling equipment 40 and the heat exchanger 26.
- seventy-five percent (if nearly pure 02 is the oxidizing stream input to the coal combustor, or approx 0-30% if the oxidizing stream is air) of the output stream can be directed back to the combustion chamber.
- the recirculation pathway 46 can be omitted and all of the output stream can be directed underground.
- the recirculation pathway 46 is shown extending from a portion 52 of the fluid pathway 14, but the recirculation pathway 46 could extend from another position along the fluid pathway 14 in alternative embodiments of the invention.
- the system can include a compressor 48 downstream of the combustion chamber 12.
- compression of the output stream can be desirable. For example, if the output stream is compressed, the oxygen-bearing gas can be directed into the combustion chamber 12 at a lower pressure and the combustion chamber 12 can be less robust.
- the compressor 48 can be supplied with rotational or mechanical power directly or indirectly from the steam turbine 28, or can be supplied with electrical power from the generator 32.
- Another basis for compressing the output stream can be that more energy can be extracted from the output stream at the heat exchanger 26.
- the output stream can enter the heat exchanger 28 at a temperature of between 4500 0 F - 6000 0 F and a pressure of between 200 - 3000 p.s.i.
- the output stream can exit the heat exchanger 26 at a temperature of between 200 0 F - 1000 0 F (approximately 3% - 25% of the combustion temperature in the exemplary embodiment) and a pressure of between 160 - 2400 p.s.i. (approximately 80% - 100% of the combustion pressure in the exemplary embodiment).
- the amount of energy extracted, or the rate of energy extraction, from the output stream can be selected based on the power needs of the system 10.
- the system 10 can include the compressor 48.
- the amount of energy extracted can be greater than the amount of power needed to power the system 10.
- the operator of the system 10 can choose to generate power in excess of the needs of the system 10 and can then sell the excess power to a customer, referenced at 50 in Figure 1.
- embodiments of the invention can be practiced wherein the operator of the system is a power supplier rather than a purchaser of power.
- Another aspect of the operation of the system 10 is the temperature of the output stream at entry into the ground.
- the operator of the system 10 can direct the output stream into the ground at relatively higher temperatures or at relatively lower temperatures.
- a higher temperature will exacerbate thinning of the oil and thereby promote oil recovery.
- higher temperatures could increase the cost of injection piping since larger and more robust piping may be required.
- a portion 54 of the exemplary fluid pathway 14 extends from the compressor 48 and extends underground.
- the output stream of combustion can be injected underground at one or more locations in embodiments of the invention. It is noted that U.S. Pub. No. 2008087425 and U.S. Pat. Nos. 5,065,821 and 5,803,171 are incorporated by reference as exemplary teachings of how the output stream, or a portion of the output stream, can be applied to move oil. Other injection schemes can be applied in embodiments of the invention.
- system 10 can include a central controller to control the operation of the individual components of the system.
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Mining & Mineral Resources (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Fluid Mechanics (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Engine Equipment That Uses Special Cycles (AREA)
- Incineration Of Waste (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2010800402673A CN102648331A (zh) | 2009-07-10 | 2010-07-06 | 用于强化采油的方法和系统 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/500,966 US20110005747A1 (en) | 2009-07-10 | 2009-07-10 | Method and system for enhanced oil recovery |
US12/500,966 | 2009-07-10 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2011005725A2 true WO2011005725A2 (en) | 2011-01-13 |
WO2011005725A3 WO2011005725A3 (en) | 2011-04-21 |
Family
ID=43426611
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2010/041014 WO2011005725A2 (en) | 2009-07-10 | 2010-07-06 | Method and system for enhanced oil recovery |
Country Status (3)
Country | Link |
---|---|
US (1) | US20110005747A1 (zh) |
CN (1) | CN102648331A (zh) |
WO (1) | WO2011005725A2 (zh) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104594862A (zh) * | 2015-01-05 | 2015-05-06 | 西南石油大学 | 一种采用膜生物反应器系统用于微生物采油的方法 |
CN105986788B (zh) * | 2016-06-24 | 2018-09-04 | 中国石油天然气股份有限公司 | 空气驱产出井的安全控制装置和方法以及空气驱注采系统 |
CN107542442A (zh) * | 2017-09-26 | 2018-01-05 | 碧海舟(北京)节能环保装备有限公司 | 一种高效节能低污染强力火驱采油系统 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330038A (en) * | 1980-05-14 | 1982-05-18 | Zimpro-Aec Ltd. | Oil reclamation process |
US4546829A (en) * | 1981-03-10 | 1985-10-15 | Mason & Hanger-Silas Mason Co., Inc. | Enhanced oil recovery process |
US6279344B1 (en) * | 2000-06-01 | 2001-08-28 | Praxair Technology, Inc. | Cryogenic air separation system for producing oxygen |
US20080283249A1 (en) * | 2007-05-19 | 2008-11-20 | Zubrin Robert M | Apparatus, methods, and systems for extracting petroleum using a portable coal reformer |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4499946A (en) * | 1981-03-10 | 1985-02-19 | Mason & Hanger-Silas Mason Co., Inc. | Enhanced oil recovery process and apparatus |
US5065821A (en) * | 1990-01-11 | 1991-11-19 | Texaco Inc. | Gas flooding with horizontal and vertical wells |
JP2733188B2 (ja) * | 1993-06-18 | 1998-03-30 | 川崎重工業株式会社 | 加圧型ガス化炉による石炭直接燃焼ガスタービン複合発電システム |
US5469699A (en) * | 1994-10-14 | 1995-11-28 | Foster Wheeler Development Corporation | Method and apparatus for generating electrical energy utilizing a boiler and a gas turbine powered by a carbonizer |
US5803171A (en) * | 1995-09-29 | 1998-09-08 | Amoco Corporation | Modified continuous drive drainage process |
SE507116C2 (sv) * | 1995-12-11 | 1998-03-30 | Abb Carbon Ab | Förgasningsanordning och kraftanläggning |
US5918466A (en) * | 1997-02-27 | 1999-07-06 | Siemens Westinghouse Power Corporation | Coal fuel gas turbine system |
US6033447A (en) * | 1997-06-25 | 2000-03-07 | Eastman Chemical Company | Start-up process for a gasification reactor |
JP3621809B2 (ja) * | 1997-06-27 | 2005-02-16 | 三菱重工業株式会社 | 複合発電システムにおけるガスタービン出力増加方法 |
US6101983A (en) * | 1999-08-11 | 2000-08-15 | General Electric Co. | Modified gas turbine system with advanced pressurized fluidized bed combustor cycle |
US6911058B2 (en) * | 2001-07-09 | 2005-06-28 | Calderon Syngas Company | Method for producing clean energy from coal |
US7666251B2 (en) * | 2006-04-03 | 2010-02-23 | Praxair Technology, Inc. | Carbon dioxide purification method |
RU2435024C2 (ru) * | 2006-08-10 | 2011-11-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Способ добычи нефти и/или газа (варианты) |
-
2009
- 2009-07-10 US US12/500,966 patent/US20110005747A1/en not_active Abandoned
-
2010
- 2010-07-06 CN CN2010800402673A patent/CN102648331A/zh active Pending
- 2010-07-06 WO PCT/US2010/041014 patent/WO2011005725A2/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330038A (en) * | 1980-05-14 | 1982-05-18 | Zimpro-Aec Ltd. | Oil reclamation process |
US4546829A (en) * | 1981-03-10 | 1985-10-15 | Mason & Hanger-Silas Mason Co., Inc. | Enhanced oil recovery process |
US6279344B1 (en) * | 2000-06-01 | 2001-08-28 | Praxair Technology, Inc. | Cryogenic air separation system for producing oxygen |
US20080283249A1 (en) * | 2007-05-19 | 2008-11-20 | Zubrin Robert M | Apparatus, methods, and systems for extracting petroleum using a portable coal reformer |
Also Published As
Publication number | Publication date |
---|---|
US20110005747A1 (en) | 2011-01-13 |
WO2011005725A3 (en) | 2011-04-21 |
CN102648331A (zh) | 2012-08-22 |
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