WO2010131553A1

WO2010131553A1 - Drip sheet and method for producing same

Info

Publication number: WO2010131553A1
Application number: PCT/JP2010/057020
Authority: WO
Inventors: 彰柴田; 直人竹内
Original assignee: ユニ・チャーム株式会社
Priority date: 2009-05-15
Filing date: 2010-04-20
Publication date: 2010-11-18
Also published as: TW201039790A; JP2010265012A; JP5414101B2

Abstract

Provided is a soft drip sheet having a comparatively low bending stiffness, but maintaining a required drip absorption performance and wrapping operability. A drip sheet (10) comprises a top surface (10A), a bottom surface (10B), a liquid permeable upper layer sheet (11), and a liquid absorbent lower layer sheet (12) bonded to the bottom surface of the upper layer sheet (11), wherein the upper layer sheet (11) is formed from a thermoplastic plastic film having liquid conducting portions (14, 16) which extend in the thickness direction of the upper layer sheet (11) so as to move the drip leaching from a food placed on the top surface of the upper layer sheet (11) to the lower layer sheet (12), and the lower layer sheet (12) is crepe paper subjected to a wet-crepe process.

Description

Drip sheet and manufacturing method thereof

The present invention relates to a drip sheet having liquid absorbency, and more particularly to a drip sheet suitable for absorbing a drip exuding from meat or the like and a method for producing the drip sheet.

Conventionally, a sheet for absorbing drip oozing from a fish fillet or beef piece placed in a tray made of polystyrene foam or the like is generally known. For example, Patent Document 1 discloses a drip sheet having a two-layer structure in which an upper layer sheet includes a liquid-permeable thermoplastic film having a plurality of openings, and a lower layer sheet includes a liquid-absorbing fiber nonwoven fabric. .

Japanese Unexamined Patent Publication No. 09-40026

In the drip sheet disclosed in Patent Document 1, a slit is formed on the upper surface of the upper layer sheet by a slit blade, so that a step-shaped opening is formed and the drip can be absorbed in a relatively short time. At the same time, the absorbed drip can be covered so as not to be visually recognized from the outside.

However, in order to stably perform slit processing on the upper surface of the upper layer sheet, the upper layer sheet has a relatively high rigidity, and the lower layer sheet is formed of a fiber nonwoven fabric, so that it does not easily become wrinkles. Since it is difficult to bend, it is difficult to handle when the whole food is encapsulated with a drip sheet, and the encapsulated shape cannot be maintained.

In order to solve such a problem, it is conceivable to use a sheet member having a relatively low rigidity for the upper layer sheet. In this case, however, the rewetting prevention function is lowered or the drip sheet is likely to curl. For example, drip absorption performance and packaging operability may be reduced.

Therefore, in the present invention, it is an object to provide a flexible drip sheet having relatively low bending rigidity while maintaining required drip absorption performance and packaging operability.

In order to solve the above problems, the present invention is directed to an upper surface and a lower surface, a liquid-permeable upper layer sheet, and a liquid-absorbing lower layer sheet joined to the lower surface of the upper layer sheet. A drip sheet containing

A feature of the present invention is that the upper layer sheet has a liquid guide extending in the thickness direction of the upper layer sheet for moving a drip oozing from the food material placed on the upper surface of the upper layer sheet to the lower layer sheet. The lower layer sheet is a crepe paper that has been wet creped.

The present invention includes the following preferred embodiments in addition to the features described above.
(1) The liquid introduction part of the upper layer sheet is a plurality of apertures regularly arranged adjacent to each other in the planar direction of the upper layer sheet.
(2) The liquid introduction part of the upper layer sheet is a plurality of slits regularly arranged adjacent to each other in the planar direction of the upper layer sheet.
(3) The liquid introduction part has a tubular part whose diameter decreases from the upper surface toward the lower surface.
(4) The lower layer sheet has a crepe rate of 10 to 30% and a mass of 25 to 80 g / m ² .
(5) The wet elongation in the machine direction during the production of the lower layer sheet is 10% or less.
(6) A rewetting amount of the drip sheet is 0.2 g or less.
(7) A step of joining the lower layer sheet and the upper layer sheet in a state where the lower layer sheet is formed by wet creping and the tensile force applied in the machine direction when the lower layer sheet is unwound is applied. A method for producing a drip sheet.

The drip sheet according to the present invention has a multilayer structure in which an upper layer is formed from a thermoplastic film and a lower layer is formed from crepe paper by wet creping, and is relatively low in rigidity and flexible. When the whole food is encapsulated, it can be easily bent and the shape in that state can be maintained. Further, by using crepe paper for the lower layer, liquid diffusibility and liquid absorbency can be improved, and the rewet phenomenon can be suppressed. Further, by performing wet creping instead of dry creping, even if the drip is absorbed, the dimensions before absorbing the drip can be maintained, so that the drip sheet can be prevented from curling.

The partially broken top view of the drip sheet in 1st Embodiment. II-II sectional view taken on the line of FIG. FIG. 3 is a partially enlarged view of FIG. 2. The partially broken top view of the drip sheet in 2nd Embodiment. FIG. 5 is a sectional view taken along line VV in FIG. 4. The figure which shows a part of manufacturing process of wet crepe paper.

<First Embodiment>
1 is a plan view of the drip sheet 10, and FIG. 2 is a cross-sectional view taken along the line II-II of FIG. In FIG. 1, the machine direction at the time of manufacture is indicated by an MD arrow, and the direction perpendicular thereto is indicated by a CD double-headed arrow.

As shown in FIGS. 1 and 2, the drip sheet 10 has an upper surface 10A and a lower surface 10B, and is a thermoplastic film, more preferably a thickness of 0.3 to 0.35 mm, and a mass of 10 to 30 g / m ^2. An upper sheet 11 formed from a polyolefin-based thermoplastic film such as low density polyethylene having a density of 0.03 to 0.10 g / cm ³ , a thickness of 0.25 to 0.30 mm, and a mass of 45 to 100 g / m ^2. a lower layer sheet 12 made of crepe paper having a density of 0.15 to 0.40 g / cm ³ , and an intermediate layer 13 formed of a hot melt adhesive that joins the upper layer sheet 11 and the lower layer sheet 12.

The upper sheet 11 has a plurality of air-permeable and liquid-permeable holes (liquid introduction) that are regularly arranged adjacent to each other in the planar direction (XY direction) and penetrate the upper sheet 11 from the upper surface 10A toward the lower surface 10B. Part) 14 is formed. The opening 14 has a circular shape with substantially the same cross-sectional shape. By placing fresh food such as meat and vegetables on the upper surface 10A of the drip sheet 10, that is, the upper surface 10A of the upper layer sheet 11, or by wrapping the entire food with the drip sheet 10, the drip that exudes from the food is opened. It moves to the lower layer sheet 12 through the hole 14 by capillary action. The openings 14 may have various cross-sectional shapes such as a rectangle and a triangle in addition to a circle, and may have various array patterns such as a wavy shape and a staggered shape as well as a lattice shape and a decorative effect. Therefore, it may represent a character or a pattern that is visible from the outside.

The lower layer sheet 12 is for absorbing and holding a drip that exudes from the food, and is formed from crepe paper that has been wet creped. As a raw material of the crepe paper forming the lower layer sheet 12, a general pulp fiber raw material can be used. In addition to hardwood and coniferous wood fibers, plant fibers other than wood, synthetic fibers, and the like can be combined. However, softwood pulp fibers are preferred in view of the tensile strength of the crepe paper. Moreover, in order to improve the absorption performance of a crepe paper, you may perform a hydrophilization enhancement process.

The lower layer sheet 12 is thinner and denser than the upper layer sheet 11 and is formed of a crepe paper having excellent water absorption, so that a drip that oozes from the food material instantaneously due to capillary action is transferred from the upper layer sheet 11 to the lower layer sheet. 12 can be moved.

The crepe paper forming the lower layer sheet 12 is formed with a plurality of crepes 15 extending in a direction (CD direction) perpendicular to the machine direction (MD direction) during manufacture by wet creping. Since the lower layer sheet 12 is made of a crepe paper that is more flexible than other sheet members such as an airlaid nonwoven fabric, the bending rigidity of the entire drip sheet 10 can be made relatively low, and the entire food can be wrapped. Sometimes it becomes easy to bend and the restorability after the bending is low. In addition, the crepe 15 serves as an absorption groove, further improving the drip diffusibility and water absorption, and preventing the absorbed drip from returning (rewetting).

Here, wet creping refers to creping when the paper material is in a wet state in the manufacturing process of crepe paper.

The crepe paper for forming the lower layer sheet 12 is preferably wet crepe paper, not dry crepe paper. From the viewpoint of the absorbency and softness of the drip sheet, dry crepe paper is usually preferable. However, when dry crepe paper is used, the dimensional change after absorbing the drip is large, so the drip sheet 10 curls when wrapping food. It becomes difficult to wrap food. On the other hand, if it is wet crepe paper and dry crepe paper having the same basis weight and crepe rate, dry crepe is preferable only from the viewpoint of absorbency and softness, but in the case of wrapping food as mentioned above Curing after absorption is preferably wet crepe paper from the viewpoint of operability of wrapping food.

That is, when dry crepe paper is used for the lower layer sheet 12, when the drip is absorbed, the crepe 15 is fully extended in the MD direction, and the entire drip sheet 10 is curled carelessly. When the drip is used, even if the drip is absorbed by the lower layer sheet 12, the crepe 15 does not extend in the MD direction, and the product dimensions do not change before and after the drip is absorbed. Will not curl easily. Therefore, even when the lower layer sheet 12 absorbs the drip that exudes from the food material when encapsulated by the drip sheet 10 so as to wrap the entire food material, the drip sheet 10 can maintain the shape of the encapsulated state. . On the other hand, when dry crepe paper is used, the shape recovery when absorbing the drip in a folded state is high, so the state where the food is wrapped cannot be maintained and the drip leaks to the outside. There is a fear.

Further, the advantages in the manufacturing process are described. In the case of wet creping, since the moisture content is high, when the lower layer sheet 12 is cut in the manufacturing process, the fibers and pulp on the cut end face become powdery. Never go outside. On the other hand, in the case of dry creping, the fibers and pulp on the cut end face are powdered and spilled to the outside, so that the removal, management and inspection of the cutting process in the manufacturing process are troublesome.

In order for the lower layer sheet 12 to have appropriate water absorption and flexibility, the crepe rate is preferably 10 to 30%. If it is 10% or less, the flexibility is low and it is difficult to bend, and it is difficult to handle when wrapping food. If it is 30% or more, it becomes bulky more than necessary and difficult to handle, and the strength of the lower sheet 12 is high. This is because there is a possibility that the liquid may be lowered and sufficient liquid holding ability cannot be exhibited.

In the intermediate layer 13, a hot melt adhesive for joining the upper layer sheet 11 and the lower layer sheet 12 is used at a mass ratio of 1 to 5 g / m ² . The hot melt adhesive can be intermittently applied in various application patterns such as spiral and dot shapes, but in order not to impede the air permeability of the opening 14 of the upper layer sheet 11. The coating is preferably performed with a width smaller than the diameter of the opening 14. In the present invention, the upper layer sheet 11 and the lower layer sheet 12 are bonded by a hot melt adhesive, but may be bonded by various heat welding means such as heat sealing and ultrasonic sealing.

FIG. 3 is a partially enlarged view of FIG.

The opening 14 has a tubular portion 16 that extends from the peripheral edge 14 a of the opening 14 in the thickness direction of the upper layer sheet 11. The tubular portion 16 has an upper end opening diameter D <b> 1 composed of the peripheral edge 14 a of the opening 14 and a lower end opening diameter D <b> 2 facing the lower layer sheet 12. The tubular portion 16 has a funnel shape with a diameter decreasing downward, and the upper end opening diameter D1 is larger than the lower end opening diameter D2. In this way, when the tubular portion 16 is reduced in diameter toward the lower side, the capillary phenomenon becomes more prominent as it approaches the lower layer sheet 12, so that the drip that has entered the opening 14 is quickly removed from the lower layer sheet. 12 can be moved. In addition, since the diameter of the tubular portion 16 decreases as it goes downward, and the upper layer sheet 11 is thicker than the lower layer sheet 12, the food material is placed on the upper surface 10A of the upper layer sheet 11, and the entire drip sheet 10 is formed. Even if the pressure is applied, the drip absorbed by the lower layer sheet 12 can be prevented from returning to the upper layer sheet 11 side.

In order to achieve the above effects, specifically, the upper end opening diameter D1 is preferably 0.5 to 2.0 mm, and the lower end opening diameter D2 is preferably 0.1 to 1.5 mm. Although not shown, the upper and lower end opening diameters D1 and D2 may be the same size.

Second Embodiment
FIG. 4 is a plan view of a drip sheet 10 similar to FIG. 1, showing another embodiment, and FIG. 5 is a cross-sectional view taken along line VV in FIG. Since the basic configuration of the drip sheet 10 in the present embodiment is the same as that of the first embodiment, only differences will be described below.

In this embodiment, a plurality of slits 17 (liquid introduction portions) arranged in a staggered manner are formed in the upper layer sheet 11 instead of the openings of the first embodiment. Since the slit 17 extends in the thickness direction of the upper layer sheet 11 and penetrates the upper layer sheet 11, the drip that has oozed out from the food placed on the upper surface 10 </ b> A side of the upper layer sheet 11 passes through the slit 17 and lower layer sheet 12. It quickly moves to the point where it is absorbed and held by the lower layer sheet. Moreover, the slit 17 is formed so that it becomes narrow as it goes downward like the opening 14 of the first embodiment, and has the same effect as the opening 14. Although not shown, a slit 17 may be formed in the upper sheet 11 having a plurality of apertures 14 in order to further improve the drip absorption rate.

FIG. 6 is a diagram showing a part of a process for producing wet crepe paper for forming the lower layer sheet 12.

One end of the sheet-like crepe base paper 20 formed by the forming process is wound and fixed with a winding roll (not shown), and the other end side is continuously conveyed along the lower felt 21 flowing in the machine direction, Pressing and dewatering while passing between the upper roller 22 and the first lower roller 23 rotating in opposite directions. After dehydration, the wet crepe base paper 20 is pressed against the surface of the upper roller 22 while the doctor blade 24 is applied to the upper surface of the upper roller 22 and pulled along the upper felt 25 located above. A regular crepe pattern is given to the crepe base paper 20 by conveying.

The crepe rate of the crepe base paper 20 can be determined by the difference between the peripheral speed of the lower felt 21 and the peripheral speed of the upper felt 25 which are the rotational speeds of the upper and

lower rollers

22 and 23 in the pressing process. The crepe base paper 20 conveyed along the upper felt 25 passes between the cylindrical dryer 26 and the second lower roller 27 while being blown with hot air, and is wound in a completely dry state.

Since the wet crepe paper formed by such a manufacturing process is creped and dried in a wet state, the wrinkles of the crepe 15 are less likely to be stretched than the dry crepe paper. This is considered to be because the hydrogen bond in the crepe 15 is stronger in wet creping than in dry creping.

The wound crepe base paper 20 (lower layer sheet 12) is unwound by applying a tensile force applied in the MD direction, and the lower layer sheet 12 has the upper layer sheet 11 attached thereto via a hot melt adhesive forming the intermediate layer 13. Bonded with the thermoplastic film to be formed. As described above, the tensile force applied in the MD direction when the lower layer sheet 12 is unwound acts on the lower layer sheet 12, but the crepe 15 is unraveled because the wrinkles are difficult to extend by wet creping. There is no. Therefore, after the upper and

lower layer sheets

11 and 12 are joined to form the drip sheet 10, the crepe restoring force, that is, the force to return to the original creped state acts, so that the entire drip sheet is curled. It is not.

On the other hand, when the crepe base paper 20 is formed by dry creping, the entire crepe is extended by the tensile force applied in the MD direction when the crepe base paper 20 is unwound. Therefore, since the lower layer sheet 12 is joined to the upper layer sheet 11 while the crepe 15 is stretched, the crepe 15 tends to return to the original state in the lower layer sheet 12 after joining both the

sheets

11 and 12. The force may act and the entire drip sheet 10 may be easily curled even in the dry state.

Table 1 shows the evaluation of characteristics and performance in order to produce a plurality of wet crepe papers under various conditions and to compare with conventional products.

[Measuring method]
<Sheet thickness>
Based on the standard of JISL1096.6.5, it is measured using a desk thickness meter (manufactured by MITUTOYO, measurement surface φ50.5 mm, measurement pressure 3 g / cm ² ). First, a 100 mm × 100 mm sample is cut from each sheet, and the center of the sample is gently sandwiched between the upper and lower disks, and the value of the measuring instrument at that time is obtained (N = 10).

<KES (bending) value>
A 100 × 100 mm sample was cut out from each sheet, and the sample was placed in accordance with the guideline of the measuring table of an automated pure bending tester (manufactured by Kato Tech Co., Ltd.), and fixed to the center of the chuck for measurement. Measurement was performed 5 times for each of the MD direction and the CD direction.

<Water absorption and water retention>
A 140 mm × 60 mm sample is cut from each sheet, and the mass (Ag) of each sample is measured. After measuring the weight, the sample is placed on a 10-mesh wire net, and the entire sample is immersed in a test solution (tap water, physiological saline, cooking oil) placed in a tray. After soaking in the test solution for 3 minutes, the sample is taken out of the tray together with the wire mesh, drained lightly, and allowed to stand for 5 minutes. Thereafter, the mass (Bg) of the wire mesh and the sample is measured, the sample is removed, and the mass (Cg) of only the wire mesh is measured. Then, the sample is placed on the sample table, a 420 g weight is placed on the sample, and left as it is for 3 minutes. Measure the mass of the sample after 3 minutes (Dg). Using the values (A to D) obtained by the above measurement method, the water absorption amount and the water retention amount are obtained by the following calculation method. The measurement was performed three times, and the average value was taken as the water absorption amount / water retention amount of each sheet.
Water absorption (g / m ² ) = (B−C−A) /0.06/0.14
Water retention amount (g / m ² ) = (DA) /0.06/0.14

<Diffusion>
A 65 × 100 mm sample is cut from each sheet and set in an automatic injector. Under the condition of 1.0 ml / 3 sec, physiological saline is dropped from the upper position 10 mm away from the sample to the center of the sample. Three minutes after dropping, the diffusion width (mm) of the upper surface of the drip sheet, the upper surface of the lower layer sheet, and the lower surface of the lower layer sheet was measured (N = 5).

<Freshness determination>
As a freshness retention test, a K value measurement method using a freshness tester (manufactured by QS-SOLUTION) was performed. The K value is an index of freshness and indicates the degree to which ATP of food is decomposed and inosine and hypoxanthine are produced and accumulated. Specifically, raw tuna fillet is placed on a sample sheet, 4 It was stored in a refrigerator set at ° C., and the freshness (K value) of the tuna fillet after 0, 1, or 2 days was determined.

<Evaluation method for maintaining freshness>
As a result of the above test, it was found that when the rewet of the lower layer sheet was 2.0 g or less, the freshness (K value) deteriorated after 1 to 2 days. Therefore, when the rewetting of the lower layer sheet was 2.0 g or less, it was judged as good (◯), and when it was 2.0 g or more, it was judged as defective (x).

<Wet elongation rate>
A 150 mm × 25 mm sample is cut from each sheet, marked with an oil pen at a location 25 mm from both ends of the sample, and the entire sample is immersed in tap water in a tray. After soaking in tap water for 1 minute, the sample was taken out of the tray, the separation distance (dimension E) of the mark was measured (N = 3), and the wet elongation (%) was obtained by the following calculation.
Wet elongation = (E-100) / 100 × 100

<Curl judgment>
The ratio of curling when the drip sheet was pulled with a stress of 0.1 N / 25 mm was determined.

<Curl evaluation method>
The ratio of curling of each drip sheet 10 was determined by the above method. When the elongation percentage of the lower layer sheet 12 of each drip sheet 10 is 10% or less, it is difficult to curl. I found it easier to do. Therefore, when the wet elongation rate of the lower layer sheet 12 was 10% or less, it was judged as good (◯), and when it was 10% or more, it was judged as defective (x).

<Example 1>
As the upper layer sheet 11, an open plastic film made of LDPE (low density polyethylene) is used, and as the lower layer sheet 12, NBKP (conifer craft method bleached pulp) is used as a raw material, and the mass is 48 g / m ² and the crepe rate is 10%. Crepe paper was used.

<Example 2>
The upper layer sheet 11 similar to Example 1 was used, and the lower layer sheet 12 was a wet crepe paper having a mass of 48 g / m ² and a crepe rate of 20%, using NBKP as a raw material.

<Example 3>
The upper layer sheet 11 similar to Example 1 was used, and the lower layer sheet 12 was a wet crepe paper having a mass of 48 g / m ² and a crepe rate of 30%, using NBKP as a raw material.

<Example 4>
An upper layer sheet 11 similar to that in Example 1 was used, and a wet / dry crepe paper having a mass of 48 g / m ² and a crepe rate of 20%, using NBKP as a raw material, was used as the lower layer sheet 12.

<Example 5>
The upper layer sheet 11 similar to Example 1 was used, and the lower layer sheet 12 was a wet crepe paper having a mass of 25 g / m ² and a crepe rate of 20%, using NBKP as a raw material.

<Example 6>
The upper layer sheet 11 similar to Example 1 was used, and as the lower layer sheet 12, a wet crepe paper having a mass of 25 g / m ² and a crepe rate of 20%, using NBKP as a raw material, was used.

<Comparative Example 1>
The same upper layer sheet 11 as in Example 1 was used, and as the lower layer sheet 12, dry crepe paper having a mass of 48 g / m ² and a crepe rate of 20%, using NBKP as a raw material, was used.

<Comparative example 2>
The upper layer sheet 11 similar to that of Example 1 was used, and the lower layer sheet 12 was a wet paper that had a mass of 48 g / m ² and was not creped, using NBKP as a raw material.

<Comparative Example 3>
An air-laid nonwoven fabric with a mass of 48 g / m ² in which synthetic fibers and NBKP were mixed as the lower layer sheet 12 was used as the upper layer sheet 11 using an apertured plastic film made of HDPE (high density polyethylene).

<Evaluation>
As shown in the results of Table 1, in Examples 1 to 6, if the mass of the lower layer sheet 12 is 25 to 48 g / m ² and the crepe rate is between 10 to 30%, the ease of winding, maintaining the freshness, Each determination result was good (◯). Further, as apparent from the determination result of Example 4, the same determination result as the wet crepe paper could be obtained even with the wet / dry crepe paper.

In Comparative Example 1, the determination result was good (◯) in terms of ease of winding and maintaining freshness. However, in the case of dry wet paper, the crepe of the lower layer sheet 12 stretched in the MD direction in a wet state and curled. Since it becomes easy, in curl determination, it was bad (x).

In Comparative Examples 2 and 3, since the lower sheet 12 is made of wet or airlaid nonwoven fabric that is not creped, the rigidity of the entire drip sheet is relatively high, and the rollability is poor (x). It was.

10 drip sheet 10A upper surface 10B lower surface 11 upper layer sheet 12 lower layer sheet 14 opening 16 tubular part 17 slit MD machine direction

Claims

A drip sheet comprising an upper surface and a lower surface, a liquid-permeable upper layer sheet, and a liquid-absorbing lower layer sheet bonded to the lower surface of the upper layer sheet,
From the thermoplastic film having the liquid guiding portion extending in the thickness direction of the upper layer sheet, the upper layer sheet moving a drip oozing from the food material placed on the upper surface of the upper layer sheet to the lower layer sheet Formed,
The drip sheet, wherein the lower layer sheet is crepe paper that has been wet creped.
2. The drip sheet according to claim 1, wherein the liquid introduction part of the upper layer sheet is a plurality of apertures regularly arranged adjacent to each other in a planar direction of the upper layer sheet.
2. The drip sheet according to claim 1, wherein the liquid introduction part of the upper layer sheet is a plurality of slits regularly arranged adjacent to each other in a planar direction of the upper layer sheet.
The drip sheet according to any one of claims 1 to 3, wherein the liquid introduction portion has a tubular portion having a diameter that decreases from the upper surface toward the lower surface.
The drip sheet according to any one of claims 1 to 4, wherein the lower layer sheet has a crepe rate of 10 to 30% and a mass of 25 to 80 g / m 2 .
The drip sheet according to any one of claims 1 to 5, wherein a wet elongation in the machine direction during the production of the lower layer sheet is 10% or less.
The drip sheet according to any one of claims 1 to 6, wherein a rewetting amount of the drip sheet is 0.2 g or less.
The method includes forming the lower layer sheet by wet creping, and joining the lower layer sheet and the upper layer sheet in a state where a tensile force applied in the machine direction when the lower layer sheet is unwound is applied. 8. A method for producing a drip sheet according to any one of 1 to 7.