WO2010120876A1

WO2010120876A1 - System and method for using super critical state carbon dioxide (co2) for hydrocarbon recovery and transport

Info

Publication number: WO2010120876A1
Application number: PCT/US2010/031026
Authority: WO
Inventors: Michael Hirl
Original assignee: Michael Hirl
Priority date: 2009-04-17
Filing date: 2010-04-14
Publication date: 2010-10-21

Abstract

A system and method for the use of super critical CO₂ as a carrying or suspension agent for transport of extracted or processed hydrocarbons. The super critical state CO₂ is then co-mingled with the extracted or processed hydrocarbons and transported in the co-mingled state to a delivery point. At the delivery point, the super critical state CO₂is allowed to return to its gaseous state allowing the separation of the hydrocarbons therefrom. The hydrocarbons may be processed and the gaseous CO₂ returned to its super critical state for future transport, use in EOR, or geologically sequestered.

Description

U. S. PATENT APPLICATION

SYSTEM AND METHOD FOR USING SUPER CRITICAL

STATE CARBON DIOXIDE (CO₂) FOR HYDROCARBON RECOVERY AND TRANSPORT

CROSS REFERENCE TO RELATED APPLICATION

[0001] This application claims the benefit of Provisional U.S. Patent Application No. 61/124,596 filed April 17, 2008.

STATEMENT REGARDING FEDERALLY FUNDED RESEARCH AND DEVELOPMENT

[0002] The invention described in this patent application was not the subject of federally sponsored research or development. FIELD

[0003] The system and method of the present invention pertains to the recovery and transport of extracted or processed hydrocarbons; more particularly, the system and method of the present invention pertains to the use of super critical state CO2 in the recovery and transport of extracted or processed hydrocarbons. BACKGROUND

[0004] Extracted or processed hydrocarbons, for example, heavy hydrocarbons, especially like bitumen or those heavy hydrocarbons mined or produced from "oil sands," require an additional element to be combined with the heavy hydrocarbon, to enable the heavy hydrocarbon to be transported via pipeline. This additional element or additive, more commonly called a "diluent," is injected into and/or otherwise combined with the heavy hydrocarbon, to form a combination known in the industry as a "dilbit."

[0005] The use of the diluents is necessary to transport heavy hydrocarbons to upgraders and other processing facilities to make usable products. However, the very high exist of diluents, as represented by the direct investment to acquire diluents and then process these diluents, as well as the opportunity cost of not marketing the diluents for sale in their own markets, directly impacts the recovery and transportation cost associated with producing heavy hydrocarbons, extracted from oil sands as well as making useful products from the heavy hydrocarbons.

[0006] Diluents currently in use in the transport of heavy hydrocarbons, include various lighted hydrocarbons such as condensate. With the growth in the production of heavy hydrocarbons from oil sands expected to both continue and grow, the demand for condensate (a high value, very light hydrocarbon product) will exceed available supply. As a result of the anticipated shortage or lack of availability of condensate, other diluents must be considered for use in the dilbit to make up for the anticipated shortfall in the supply of available condensate. Principal among the other diluents being considered are natural gas liquids or as they are more commonly called in the industry, "NGLs." NGLs, like condensate, are very valuable light end hydrocarbons which have their own value and are marketed, traded and transported in their own markets.

[0007] Accordingly, there remains a need in the art for a low cost, easily accessible diluent to be used in the transport of heavy hydrocarbons such as those heavy hydrocarbons produced from oil sands. SUMMARY

[0008] The system and method of the present invention provides a low cost, easily accessible product which can be used in the transport of extracted or processed hydrocarbons such as those heavy hydrocarbons produced from oil sands. [0009] According to the system and method of the present invention, CO₂ is compressed and transformed into a super critical state. Once in a super critical state, the CO₂ is added to a heavy hydrocarbon. The combination of the super critical state CO₂ facilitates the removal of the heavy hydrocarbon from a ground formation, such as oil sands.

[0010] Once the heavy hydrocarbon is removed from the ground formation, such as oil sands, the combination of the heavy hydrocarbon, with the super critical state CO₂ may be transported in a pressurized pipeline or tank to a predetermined delivery destination. Specifically, the super critical state CO₂ acts as a carrying or suspension agent for the heavy hydrocarbon.

[0011] At the predetermined delivery destination, the pressurized pipeline or tank containing the combination of the super critical state CO₂ and the heavy hydrocarbon is de-pressurized. Such de-pressurization of the pressurized pipeline causes the combination of the heavy hydrocarbon, and the CO₂ to return to a dual gas- liquid state. The gaseous CO₂, is then separated from the heavy hydrocarbon. The heavy hydrocarbon may then be transformed into useful products. The CO₂ may then be caused to re-enter a super critical state for re-use or storage. BRIEF DESCRIPTION OF THE DRAWING FIGURE

[0012] A still better understanding of the system and method of the present invention may be had by reference to the drawing figure wherein:

[0013] Figure 1 is a flow diagram of the system and method of the present invention. DESCRIPTION OF THE EMBODIMENTS

[0014] Technical and Historical Background [0015] Carbon dioxide, or as hereinafter referred to as CO₂, is a unique molecule. CO₂ is found in many common applications such as: an additive for soft drinks to add the "fizz"; dry ice for keeping food cold; and a component in chemical processes, for example, the urea process for making fertilizer. CO₂ is also importantly used, in a specialty sense, in the oil and gas industry as an injectant for tertiary oil recovery for what is called in the industry, COrEOR (enhanced oil recovery).

[0016] The unique application of CO₂ in the oil and gas industry began in the early 1970's. Part of this key development was the construction of an expansive and unique infrastructure for handling CO₂ at locations where naturally occurring CO₂ was discovered. These "naturally sourced" CO₂ reservoirs were predominantly at four formations or "domes" discovered in the Untied States. These four formations or domes are: McElmo Dome (SW Colorado), Sheep Mountain (SE Colorado), Bravo Dome (Eastern New Mexico), and Jackson Dome (near Jackson, Mississippi). CO₂ from these four formations or domes served as the first source from which major CO₂ transport pipelines infrastructures were built. These CO₂ transport pipelines connect natural CO₂ sources to major oil fields at which CO₂-EOR is conducted.

[0017] Overtime, additional anthropogenic sources such as CO₂ sources from man-made processes based on the separation of CH4 or methane from CO₂, also became more widely available. This increase in availability of CO₂ from anthropogenic sources resulted in both anthropogenic and naturally sourced CO₂ becoming available for use in CO₂ EOR. The designation of CO₂ from these two sources is denoted by suffix "a" or "n". CO₂a designates CO₂ from an anthropogenic source and CO₂n designates CO2 from a natural source. This nomenclature will be applied herein in all references to CO2.

[0018] It is important to note, that what is referred to as either CC^a or CO₂n is not usually pure CO₂; that is CO₂ without other gases or elemental components. Rather, CO₂X is the term to describe a somewhat "mixed" gas, or CO2 containing small amounts of nitrogen, oxygen, hydrogen, sulfide and other gases. Some CO₂n sources are 99% or greater pure CO₂. Some Cθ₂a sources contain varying amounts of H₂S gas.

[0019] In all cases herein, the terms CO₂a or CO₂n will be used to primarily indicate the distinction in source from which they are obtained. In all cases, both CO₂ and CO₂n indicate a CO₂ gas or gas mix with varying constituent component gases such as O₂, N₂, H₂S and other gases as the case may be. The CO₂ used as a diluent can either be 100% pure CO2 or be a CO2 gas mix consisting of the various gas components present as a result of the process through which the CO₂ is extracted or otherwise captured.

[0020] A unique feature of the evolved CO₂-EOR industry is the manner in which CO₂ is transported. Unlike natural gas (methane) or hydrogen gas which are transported in a gaseous state, all CO₂, be it in its relatively pure and/or in its mixed gas state, is transported differently. Specifically, the CO₂a/ CO₂n gas and/or mixed gas is first dehydrated to achieve a dryer gas with little or no water or water vapor content. This dehydration process effectively lessens the chances of the CO₂X forming carbonic acid. Such dehydration is important because carbonic acid causes corrosion to form in the pipe or tank transporting the CO₂X gas. Second, and most significantly, CO₂ is typically compressed to a pressure at which it takes on a "super critical" state for transport.

[0021] Super critical state CO₂" is the term used to describe CO₂ that is in a fluid state while also being at or above both its critical temperature and pressure. In its super critical state, CO₂ exhibits some uncommon properties. Specifically, CO₂ usually behaves as a gas in air at STP or as a solid called "dry ice" when the CO₂ gas is frozen. If the temperature and pressure are both increased from STP to be at or above the critical point for CO₂, CO₂ can adopt properties some where between a gas and a liquid. More specifically, super critical CO₂ behaves as a super critical fluid above its critical temperature (31.1⁰C) and critical pressure (73 atm), expanding to fill its container like a gas but with a density like that of a liquid.

[0022] Consequently, CO₂ (both a and n) is different from gases from a transport and infrastructure perspective. Specifically, CO₂ (a and n) in the pure or mixed gas state needs to be caused to enter a super critical state. More particularly a means for causing CO₂ to enter a super critical state such as a compressor is used to cause the CO₂ to achieve a "super critical" state. In the super critical state, CO₂ behaves like a liquid. And, like most liquids, super critical state CO₂ can be passed through a series of pumps where the pressure of the super critical state CO₂ can be increased at each pump. However, the CO2 gas must first be compressed or otherwise cooled to reach a super critical state. New process technologies are providing methods by which the amount of compression required for CO₂ to reach its super critical state is minimized through cryogenic processing. In cryogenic processing, a CO₂ gas/mix is passed through cryogenic units whereupon the density of the CO₂ gas/mix increases and less compression of the CO₂ gas is subsequently required. It is important to note that reaching the "super critical state" is the key transport attribute.

[0023] Once CO₂ in its super critical state, the CO₂ gas/mix is usually run through pumps to increase its pressure up to 2000 psi, and in some cases higher pressures, depending on the pressure rating of the transport pipe or tank. Pumps for the COa gas/mix are generally inexpensive to operate. Therefore, the movement of super critical CO₂ has comparatively lower overall transportation costs than CO₂ gas while still enabling transport and delivery to an injection point - especially for CO₂EOR use and geologic sequestration at a much higher pressure. It is this key characteristic of CO₂a and CO₂n upon which the system and method of the present invention is predicated. Once in its super critical state, the CO2 may be moved in a means for transport such as a pipeline or in tanks on a transport vehicle to the location of the heavy hydrocarbon. Heretofore, this important transportation characteristic of CO₂ in a super critical state has not been used with a heavy hydrocarbon, such as bitumen.

[0024] Disclosed System and Method

[0025] According to the system and method of the present invention, CO₂ from any source (either anthropogenic or natural), in either pure or mixed gas form, is compressed or otherwise taken to a super critical state. The super critical state CO₂ is then used as a carrying or suspension agent for the transport of bitumen and/or other heavy hydrocarbons via a pipeline or other transportation means (even including petcoke where CO₂ could serve as a carrying or suspension agent or what is more commonly referred to for petcoke to be a "slum/ mix). The super critical state CO₂ is added to the very heavy hydrocarbons, in either of the following combinations: 100% CO₂ - pure "carbonbif ; or a predetermined mixture consisting of some percentage of either condensate, NGLs, or other very light hydrocarbon or non-hydrocarbon fluids - wherein the super critical state CO₂ constitutes a minimum of 5% or greater of the total added carrying or suspension agent - either by volume or by weight. [0026] Specific processing techniques will vary depending on site, operation, and existing process facilities as to how the super critical state CO₂ and heavy hydrocarbon, such as bitumen, and possibly other chemical products are commingled and injected as a combination into the pipeline for transport. Such means for co- mingling the super critical state CO₂ and the heavy hydrocarbons are well known to those of ordinary skills in the art.

[0027] Regardless of the specific engineered process, the energy savings along with the market and economic efficiencies wilt be significant By using super critical state CO₂ as a carrying or suspension agent in the dilbit (e.g. "carbit" with CO₂ or carbon) or even as partial replacement by volume of current diluents, an inexpensive technique/process will exist by which Cθ₂a/ Cθ₂n may be transported for CO₂ EOR and/or geologic sequestration in approved aquifers and formations.

[0028] The newly constituted dilbit including CO₂a or CO₂n and a heavy hydrocarbon is then moved through a means for transport such as a pipeline or in tanks on a transport vehicle to a final delivery destination. Upon receipt at the final delivery destination, the pipe containing the combination of super critical state CO₂ and the heavy hydrocarbon will be depressurized so that the combined super critical state CO₂ and heavy hydrocarbon would return to a dual gas-liquid phase. At that point, the CO₂ would be separating from the heavy hydrocarbon. The heavy hydrocarbon would drop out of formation and be processed at the processing destination or upgrader. The separated CO₂, while in a gaseous phase, would be handled to maintain as high a pressure rating as possible. Maintaining a high pressure rating enables inexpensive recompression and/or pumping of the CO₂ back to a super critical state wherein the super critical state CO₂ would be transported via a pipeline or tank to oil and/or gas fields for EOR/EGR, coal fields for enhanced coat bed methane, or saline reservoirs/dormant oil/gas fields or other geological formations where the CO₂ can be permanently sequestered and/or stored.

[0029] The complete process would then result in a full carbon cycle from (i) initial production/mining or processing of the heavy hydrocarbon in the extraction phase to; (ii) pre-transport processing phase, to (iii) a final storage or sequestration phase.

[0030] While the system and method of the disclosed invention has been disclosed according to its preferred and alternate embodiments, those of ordinary skill in the art will understand that modifications may be made to the disclosed invention without departing form the system and method of the present invention. Such modifications shall be included within the scope and meaning of the appended claims.

Claims

Listing of Claims:

1. A method for utilizing super critical state CO₂ as a carrying or suspension agent for extracted or processed hydrocarbons, said method comprising the steps of:

causing CO₂ to enter a super critical state; transporting said super critical state CO₂ to the processed hydrocarbons; commingling the super critical state CO₂ with the processed hydrocarbons; transporting the super critical state CO₂ together with the processed hydrocarbons to a predetermined delivery destination.

2. The method as defined in claim 1 further including the step of: depressurizing the mixture of super critical state CO₂ and processed hydrocarbons at the delivery destination; recovering the gaseous phase CO₂; causing the gaseous phase CO₂ to re-enter a super critical state; transporting the super critical state CO₂ to one or more locations including but not limited to: EOR/EGR, coal fields for enhanced coal bed methane, and a sequestration location

3. A system for utilizing super critical state CO₂ as a carrying or suspension agent for extracted or processed hydrocarbons, said system comprising: means for causing CO₂ to enter a super critical state; means for transporting said super critical state CO₂ to the processed hydrocarbons; means for commingling the super critical state CO₂ with the processed hydrocarbons; means for transporting the super critical state CO₂ together with the processed hydrocarbons to a predetermined delivery destination.

4. The system as defined in claim 3 further including: means for depressurizing the mixture of super critical state CO₂ and processed hydrocarbons at the delivery destination; means for recovering the gaseous phase CO₂; means for causing the gaseous phase CO₂ to re-enter a super critical state; means for transporting the super critical state CO₂ to one or more locations including but not limited to: EOR/EGR, coal fields for enhanced coal bed methane, and a sequestration location.