WO2010117156A2

WO2010117156A2 - Method for manufacturing y-type ferrite, and y-type ferrite manufactured by same

Info

Publication number: WO2010117156A2
Application number: PCT/KR2010/001864
Authority: WO
Inventors: 유병훈; 성원모; 금준식
Original assignee: 주식회사 이엠따블유
Priority date: 2009-04-06
Filing date: 2010-03-26
Publication date: 2010-10-14
Also published as: KR20100110929A; WO2010117156A3; KR101161625B1

Abstract

The present invention relates to a method for manufacturing Y-type ferrite, and to Y-type ferrite manufactured by same. The method for manufacturing Y-type ferrite according to the present invention comprises a heat treatment step performed at least once, wherein said heat treatment step includes a primary heat treatment step performed at a temperature of 300°C to 500°C , and a secondary heat treatment step performed at a temperature of 1100°C to 1250°C. The method of the present invention is capable of manufacturing Y-type ferrite with a low permittivity, a high magnetic permeability, a low dielectric loss, and a low permeation loss, simply by controlling the heat treatment temperature without substituting a portion of initial materials or without using any additives. Therefore, the Y-type ferrite of the present invention can be used as an element for high frequency (3GHz or lower) devices, and processes for manufacturing the Y-type ferrite can be simplified, and the costs of manufacturing Y-type ferrite can be reduced.

Description

Y-type ferrite manufacturing method and thereby-type ferrite

The present invention relates to a method for producing a wire type ferrite and a wire type ferrite produced thereby. More particularly, the present invention relates to a method for producing a wire type ferrite having a low dielectric constant and a high permeability, a low dielectric loss value and a low permeability loss value, and a wire type ferrite manufactured thereby.

Ferrite is a solid solution in which alloying elements or impurities are dissolved in iron of a body-centered cubic crystal which is stable at 900 ° C. or lower. In other words, ferrite is a metallographic term for steel, which is also called silicon ferrite or silicon iron by the name of solid solution or dissolved element based on α iron.

Such a ferrite is a single phase when viewed under a microscope. The ferrite has a characteristic of mixing a white portion of ferrite with a slightly dissolved carbon and a black portion of perlite, and is used for magnetic heads such as high frequency transformers, pickups, and tape recorders.

Meanwhile, among ferrites as described above, Y-type ferrite, which is a kind of hexagonal ferrite, is a material for high frequency devices that can be used from several hundred MHz to several GHz, and has a dielectric constant of 8 to 10 and a permeability of 2 to 3. .

When the permittivity, dielectric loss, and investment loss of the w-type ferrite are low and the permeability is high, the efficiency of the high-frequency device (for example, the antenna, etc.) using the w-type ferrite can be improved.

Conventionally, by replacing a part of the initial raw material for the production of the wire type ferrite or by mixing an additive in the initial raw material, the wire type ferrite having a high permittivity while having a low permittivity, low dielectric loss and low investment loss was produced.

However, as described above, the conventional method for manufacturing a w-type ferrite in which a part of the initial raw material is replaced or an additive is added to the initial raw material is a wire type as the additional troublesome or additive to perform a part of the initial raw material needs to be performed. There is a problem that the manufacturing cost of ferrite increases.

Accordingly, an object of the present invention is to manufacture a wire type ferrite having low dielectric constant, high permeability and low loss value by controlling heat treatment temperature without replacing a part of the initial raw material or adding an additive in order to apply the electronic component material at high frequency. The present invention provides a method and a wire type ferrite produced thereby.

The Y-type ferrite manufacturing method according to the present invention includes a heat treatment step of heat treatment one or more times. The heat treatment step includes performing a first heat treatment at 300 ° C to 500 ° C and performing a second heat treatment at 1100 ° C to 1250 ° C.

Wye type ferrite manufacturing method according to the present invention, before the heat treatment step, providing a raw material for producing a wire type ferrite, a mixing step of mixing the initial raw material, a first made by mixing the initial raw material A coprecipitation step of coprecipitating the mixed solution and a drying step of washing filtration and drying of the coprecipitated material.

The initial raw material includes a barium (Ba) compound, a cobalt (Co) compound and an iron (Fe) compound, wherein the barium compound is any one of barium chloride, barium nitrate and barium sulfide, and the cobalt compound is cobalt chloride, Cobalt nitrate, and cobalt sulfide, and the iron compound is any one of iron chloride, iron nitrate, and iron sulfide.

The providing step includes providing the barium compound, the nitric acid compound and the iron compound in a molar ratio of 1.7 to 2.3: 1.7 to 2.3: 10 to 14.

The coprecipitation step includes a step of coprecipitation by adding a second mixed solution of sodium hydroxide (NaOH) and hydrogen peroxide (H ₂ O ₂ ) water to the first mixed solution.

In addition, the wire-type ferrite according to the invention is characterized in that it is produced by the above production method.

As described above, according to the present invention, a wire type ferrite having low dielectric constant, high permeability, low dielectric loss and low permeability loss can be manufactured by controlling only the heat treatment temperature without replacing a part of the initial raw material or adding an additive. have. Therefore, it can be applied as a device for high frequency (3 GHz or less), and the manufacturing process of the wire type ferrite is not only simplified, and the manufacturing cost of the wire type ferrite can be reduced.

1 is a flow chart showing a manufacturing process of the w-type ferrite in accordance with an embodiment of the present invention,

FIG. 2 is a diagram showing antenna efficiency for each loss in the case of permittivity 4 and permeability 2. FIG.

DETAILED DESCRIPTION The following detailed description of the invention refers to the accompanying drawings that show, by way of illustration, specific embodiments in which the invention may be practiced. These embodiments are described in sufficient detail to enable those skilled in the art to practice the invention. It should be understood that the various embodiments of the present invention are different but need not be mutually exclusive. For example, certain shapes, structures, and characteristics described herein may be embodied in other embodiments without departing from the spirit and scope of the invention with respect to one embodiment. In addition, it is to be understood that the location or arrangement of individual components within each disclosed embodiment may be changed without departing from the spirit and scope of the invention. The following detailed description, therefore, is not to be taken in a limiting sense, and the scope of the present invention, if properly described, is defined only by the appended claims, along with the full range of equivalents to which such claims are entitled. Like reference numerals in the drawings refer to the same or similar functions throughout the several aspects.

DETAILED DESCRIPTION Hereinafter, exemplary embodiments of the present invention will be described in detail with reference to the accompanying drawings so that those skilled in the art can easily implement the present invention.

[본 발명의 실시예]Embodiment of the Invention

Y (Y) type ferrite manufacturing method

1 is a flow chart showing a manufacturing method of the w-type ferrite according to the present invention.

In the present invention, the w-type ferrite is a hexagonal soft ferrite generally represented by a chemical formula of Ba ₂ Co ₂ Fe ₁₂ O ₂₂ , and is excellent in high frequency characteristics such that the permeability hardly decreases to a frequency range of 10 Hz or more.

An initial raw material for producing such a type ferrite includes a barium (Ba) compound, cobalt (Co) compound and iron (Fe) compound, the barium compound is any one of barium chloride, barium nitrate and barium sulfide, The cobalt compound is any one of cobalt chloride, cobalt nitrate and cobalt sulfide, and the iron compound is any of iron chloride, iron nitrate and iron sulfide.

Here, barium may be replaced with strontium (Sr), and the cobalt may be replaced with any one of nickel (Ni), manganese (Mn), zinc (Zn), magnesium (Mg), and copper (Cu).

In an embodiment of the present invention, for convenience of explanation, the barium compound is limited to barium nitrate (Ba (No ₃ ) ₂ ) and the cobalt compound is cobalt nitrate hexahydrate (Co (No ₃ ) ₂ .6H ₂ O), which is a cobalt nitrate. The iron compound is limited to ferric nitrate hexahydrate (Fe (No ₃ ) ₃ .9H ₂ 0), which is an iron nitrate. However, it is a matter of course that the present invention is not limited thereto.

Referring to FIG. 1, the method for producing the w-type ferrite of the present invention includes barium nitrate {barium nitrate (Ba (No ₃ ) ₂ )}, cobalt nitrate {cobalt nitrate hexahydrate (Co (No ₃ ) ₂ ㆍ 6H) which is an initial raw material. ₂ O)} and iron nitrate {ferric nitrate hexahydrate (Fe (No ₃ ) ₃ ㆍ 9H ₂ 0)}, dissolving and mixing the initial raw material, coprecipitation of the mixed solution made by mixing the initial raw material Washing, filtering and drying the co-precipitated material and heat treating the dried material one or more times. Here, the coprecipitation method is a method of precipitating the target ion in the mixed solution by adding a precipitant (solution) containing other ions to the mixed solution to precipitate the target ion and the other ions together. ), And the initial raw material is co-precipitated using a precipitant mixed with hydrogen peroxide (H ₂ O ₂ ) dissolved in water.

Detailed description thereof is as follows.

In order to manufacture the wire-type ferrite according to the present invention, barium nitrate, cobalt nitrate hexahydrate and ferric nitrate hexahydrate are provided (S110). Here, it is preferable to provide barium nitrate, cobalt nitrate hexahydrate and ferric nitrate hexahydrate, i.e., barium compound, nitrate compound and iron compound in a molar ratio of 2: 2: 12.

By completely dissolving the barium nitrate, cobalt nitrate hexahydrate and ferric nitrate hexahydrate in water in the air, a mixed solution of barium nitrate, cobalt nitrate hexahydrate and ferric nitrate hexahydrate was prepared, and a precipitant was added to the mixed solution. The mixed solution is co-precipitated (S120, S130). Here, the precipitant is preferably a sodium hydroxide-hydrogen peroxide mixed solution in which a sodium peroxide solution of 1 to 4 times the stoichiometric amount capable of oxidizing 2 to 4 equivalents of sodium hydroxide and iron divalent ions.

The material precipitated through the step S130, that is, by adding a precipitant to the mixed solution to wash and filter the coprecipitated metal hydroxide (S140).

This dried metal hydroxide is first heat-treated at a temperature of 300 ℃ to 500 ℃ (S150). Here, it is preferable that a primary heat processing temperature is 400 degreeC.

The first heat-treated metal hydroxide is second heat treatment at a temperature of 1100 ℃ to 1250 ℃ (S160). Here, it is preferable that secondary heat processing temperature is 1200 degreeC.

Through the above process, barium nitrate, cobalt nitrate hexahydrate and ferric nitrate hexahydrate are synthesized as a w-type ferrite.

Heat treatment condition

Meanwhile, according to one embodiment of the present invention, the first type of heat treatment may be performed on a metal hydroxide at a temperature of 300 ° C. to 500 ° C., and a second heat treatment at a temperature of 1100 ° C. to 1250 ° C. to manufacture a wire type ferrite. have.

Table 1

Secondary heat treatment condition (when primary heat treatment condition is 400 ℃)	permittivity		Dielectric loss		Permeability		Investment loss
	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz
800 ℃	3.2	3.2	0.012	0.007	1.1	1.1	0.01	0.01
1000 ℃	4.6	4.6	0.004	0.001	1.3	1.3	0.02	0.05
1200 ℃	4.2	4.2	0.002	0.001	2.0	1.9	0.05	0.16
1250 ℃	4.0	4.0	0.001	0.001	1.9	1.8	0.07	0.17
1300 ℃	4.5	4.5	0.021	0.034	1.9	1.4	0.23	0.39

Table 1 is a table showing the dielectric constant, dielectric loss, permeability and investment loss according to the secondary heat treatment temperature when the primary heat treatment temperature is fixed to about 400 ℃. Referring to Table 1, the high permeability appears when the secondary heat treatment temperature is about 1200 ℃, and when the temperature is raised above, the permeability does not increase, but the dielectric constant, dielectric loss value, and permeation loss value increase. Therefore, it can be seen that the material having a high permeability, low permittivity, low dielectric loss value, and low permeability loss value can be developed by setting the secondary heat treatment temperature at about 1200 ° C. under the conditions of Table 1. Specifically, it is possible to develop a material having a high permeability of 2 or more, a low permittivity of 5 or less, a low dielectric loss value of 0.01 or less, and a low permeability loss value of 0.16 or less.

In addition, as shown in Table 2 and Table 3 below, even when the primary heat treatment temperature is fixed to about 800 ℃ and 1000 ℃, as shown in the results of Table 1 has a high permeability value when the secondary heat treatment temperature is about 1200 ℃ Able to know.

TABLE 2

Secondary heat treatment condition (when primary heat treatment condition is 800 ℃)	permittivity		Dielectric loss		Permeability		Investment loss
	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz
800 ℃	4.5	4.5	0.009	0.008	1.2	1.2	0.005	0.009
1000 ℃	4.9	4.8	0.007	0.005	1.2	1.2	0.012	0.05
1100 ℃	7.9	7.8	0.002	0.001	1.8	1.8	0.04	0.15
1200 ℃	7.0	7.0	0.008	0.001	2.5	2.3	0.21	0.56

TABLE 3

Secondary heat treatment condition (when primary heat treatment condition is 1000 ℃)	permittivity		Dielectric loss		Permeability		Investment loss
	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz
1200 ℃	9.8	8.8	0.005	0.001	2.1	2.0	0.14	0.21

Table 4

Primary heat treatment condition (when secondary heat treatment condition is 1200 ℃)	permittivity		Dielectric loss		Permeability		Investment loss
	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz	1 GHz	2.4 GHz
400 ℃	4.2	4.2	0.002	0.001	2.0	1.9	0.05	0.16
800 ℃	7.0	7.0	0.008	0.001	2.5	2.3	0.21	0.56
1000 ℃	9.8	8.8	0.005	0.001	2.1	2.0	0.14	0.21

On the other hand, when the secondary heat treatment temperature is fixed to about 1200 ℃ as shown in Table 4, when the primary heat treatment temperature is about 400 ℃ high permeability of 2 or more, low dielectric constant of 5 or less, low dielectric loss value of 0.01 or less and 0.16 It can be seen that the w-type ferrite having a low investment loss value as follows can be produced.

In conclusion, when the first heat treatment temperature is 300 ° C to 500 ° C (preferably 400 ° C) and the second heat treatment temperature is 1100 ° C to 1250 ° C (preferably 1200 ° C), It will be able to manufacture the type of ferrite.

Y type ferrite application example

FIG. 2 is a table showing the operating gains of the antennas for the dielectric loss and the investment loss when a carrier having a permittivity of 4 and a permeability of 2 is applied to an antenna system having an operating frequency of 2.35 GHz.

As can be seen in Figure 2, the lower the dielectric loss and the investment loss of the carrier, the higher the operational gain of the antenna. Therefore, it can be seen that the antenna system having a high gain can be manufactured when the wire type ferrite manufactured for the purpose of the present invention is applied to the carrier.

The present invention has been described above with reference to specific embodiments of the present invention, but this is only illustrative and does not limit the scope of the present invention. Those skilled in the art can change or modify the described embodiments without departing from the scope of the present invention. Each of the functional blocks or means described in the present specification may be implemented by various well-known elements such as an electronic circuit, an integrated circuit, an application specific integrated circuit (ASIC), and the like. Can be. Components such as means described as separate in the specification and claims may be simply functionally distinct and may be physically implemented as one means, and components such as means described as a single element may be It can be made in combination. In addition, each method step described herein may be changed in order without departing from the scope of the present invention, and other steps may be added. In addition, the various embodiments described herein may be implemented independently as well as in any combination. Therefore, the scope of the invention should be defined by the appended claims and their equivalents, rather than by the described embodiments.

Claims

In the Y-type Ferrite manufacturing method comprising a heat treatment step of heat treatment one or more times,

The heat treatment step,

Performing a first heat treatment at 300 ° C. to 500 ° C .; And

Performing a second heat treatment at 1100 ° C. to 1250 ° C .;

Y type ferrite manufacturing method comprising a.
According to claim 1, Before the heat treatment step,

Providing an initial raw material for producing the Y type ferrite;

A mixing step of mixing the initial raw materials;

A co-precipitation step of coprecipitating the first mixed solution made by mixing the initial raw materials; And

A drying step of washing, filtering, and drying the coprecipitated material;

Y type ferrite manufacturing method comprising a.
The method of claim 2, wherein the initial raw material,

A barium (Ba) compound, a cobalt (Co) compound, and an iron (Fe) compound, wherein the barium compound is any one of barium chloride, barium nitrate, and barium sulfide, and the cobalt compound is cobalt chloride, cobalt nitrate, and cobalt Any one of the sulfides, the iron compound is a ferrite manufacturing method, characterized in that any one of iron chloride, iron nitrate and iron sulfide.
The method of claim 3, wherein the providing step,

And providing the barium compound, the nitrate compound and the iron compound in a molar ratio of 1.7 to 2.3: 1.7 to 2.3: 10 to 14.
The method of claim 2, wherein the co-precipitation step,

A method of manufacturing a w-type ferrite, comprising: co-precipitation by adding a second mixed solution of sodium hydroxide (NaOH) and hydrogen peroxide (H 2 O 2 ) water to the first mixed solution.
W-type ferrite prepared by the method of any one of claims 1 to 5.