WO2010095224A1 - Battery, vehicle and apparatus using battery - Google Patents

Battery, vehicle and apparatus using battery Download PDF

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Publication number
WO2010095224A1
WO2010095224A1 PCT/JP2009/052809 JP2009052809W WO2010095224A1 WO 2010095224 A1 WO2010095224 A1 WO 2010095224A1 JP 2009052809 W JP2009052809 W JP 2009052809W WO 2010095224 A1 WO2010095224 A1 WO 2010095224A1
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WO
WIPO (PCT)
Prior art keywords
battery
case lid
lid member
insulating
terminal
Prior art date
Application number
PCT/JP2009/052809
Other languages
French (fr)
Japanese (ja)
Inventor
粟野 直実
貴司 原山
秀平 石崎
彦人 山崎
正人 駒月
Original Assignee
トヨタ自動車株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by トヨタ自動車株式会社 filed Critical トヨタ自動車株式会社
Priority to PCT/JP2009/052809 priority Critical patent/WO2010095224A1/en
Publication of WO2010095224A1 publication Critical patent/WO2010095224A1/en

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/564Terminals characterised by their manufacturing process
    • H01M50/567Terminals characterised by their manufacturing process by fixing means, e.g. screws, rivets or bolts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings, jackets or wrappings of a single cell or a single battery
    • H01M50/172Arrangements of electric connectors penetrating the casing
    • H01M50/174Arrangements of electric connectors penetrating the casing adapted for the shape of the cells
    • H01M50/176Arrangements of electric connectors penetrating the casing adapted for the shape of the cells for prismatic or rectangular cells
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/531Electrode connections inside a battery casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/547Terminals characterised by the disposition of the terminals on the cells
    • H01M50/55Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/50Current conducting connections for cells or batteries
    • H01M50/543Terminals
    • H01M50/552Terminals characterised by their shape
    • H01M50/553Terminals adapted for prismatic, pouch or rectangular cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • the present invention provides a power generation element, a battery case that accommodates the power generation element, an electrode terminal member that extends to the outside of the battery case while being connected to the power generation element, and an insulation that insulates the electrode terminal member from the battery case A battery comprising the member. Moreover, it is related with a vehicle provided with this battery, and a battery using apparatus provided with this battery.
  • FIG. 10 shows a longitudinal sectional view of the vicinity of the electrode terminal member 930 of the battery 900
  • FIG. 11 shows an exploded perspective view of the electrode terminal member 930, the insulating members 950, 960, 970, and the like.
  • the battery 900 includes a battery case 910 that houses a power generation element (not shown), an electrode terminal member 930 that extends to the outside of the battery case 910 while being connected to the power generation element, and the electrode terminal member 930 and the battery case 910. And a plurality of (three) insulating members (upper insulating member 950, seal rubber 960, and lower insulating member 970) that are interposed between and insulate them.
  • the battery case 910 includes a box-shaped case main body member (not shown) that houses the power generation element, and a case lid member 913 that closes the opening of the case main body member.
  • a circular terminal insertion hole 913 h is formed in the case lid member 913, and the electrode terminal member 930 is inserted therethrough.
  • the electrode terminal member 930 includes three members, that is, an element connection member 931, an externally arranged terminal member 933, and a fastening member 935. These members 931, 933, and 935 are separated from each other.
  • the element connection member 931 includes an element connection main body portion 931e, an insertion portion 931f, and a rivet portion 931g.
  • the element connection main body 931e is located inside the battery case 910 and is connected to the power generation element.
  • the insertion portion 931f is connected to the upper end (the upper end portion in FIGS. 10 and 11) of the element connection main body portion 931e, and fixes a terminal insertion hole 913h of the case lid member 913 and an external arrangement terminal member 933 to be described later.
  • the portion 933e is inserted into the opening 933eh.
  • the rivet portion 931g is connected to the upper end of the insertion portion 931f, is exposed to the outside of the battery, is crimped, and is in contact with the fixing portion 933e of the externally arranged terminal member 933 from above.
  • the externally arranged terminal member 933 is located on the case lid member 913, and includes a fixing portion 933e, an intermediate portion 933f, and an external connection portion 933g, and has a Z shape.
  • the fixing portion 933e has an opening 933eh that passes through the fixing portion 933e, and is connected to the element connecting member 931 (rivet portion 931g) as described above.
  • the fixing portion 933e has a plate shape extending along and parallel to the case lid member 913, and is fixed to the case lid member 913 via an upper insulating member 950 described later.
  • the intermediate portion 933f is connected to the fixing portion 933e and has a plate shape extending upward (upward in FIGS. 10 and 11).
  • the external connection portion 933g is connected to the intermediate portion 933f, has a plate shape extending in parallel with the case lid member 913, and is formed with a screw insertion hole 933gh penetrating through the plate.
  • the fastening member 935 is located on the case lid member 913 and includes a male screw portion 935e and a base portion 935f.
  • the male screw portion 935e is formed with a male screw extending in a direction orthogonal to the case lid member 913, and is inserted into the screw insertion hole 933gh of the external connection portion 933g of the externally arranged terminal member 933.
  • the base portion 935f is larger in diameter than the male screw portion 935e, and is located closer to the case lid member 913 than the male screw portion 935e and the external connection portion 933g.
  • the three insulating members 950, 960, and 970 are separated from each other, and the element connecting member 931, the externally arranged terminal member 933, the fastening member 935, and the case lid member 913 that constitute the electrode terminal member 930 described above. After being formed separately, it is assembled.
  • the upper insulating member 950 is mainly located outside the battery case 910, between the fixing portion 933 e of the externally arranged terminal member 933 and the case lid member 913, and between the base portion 935 f and the case lid member 913 of the fastening member 935. Between the externally arranged terminal member 933 and the fastening member 935 and the case lid member 913.
  • the upper insulating member 950 is also interposed between the insertion portion 931f of the element connection member 931 and the inner peripheral surface of the terminal insertion hole 913h of the case cover member 913, and the insertion portion 931f of the element connection member 931 and the case.
  • the lid member 913 is insulated.
  • the seal rubber 960 has an annular shape, and the insertion portion 931f of the element connection member 931 is inserted therethrough.
  • the seal rubber 960 is located inside the battery case 910 and is sandwiched between the case lid member 913 and the element connection main body 931e of the element connection member 931. Accordingly, the element connection main body 931e of the element connection member 931 and the case lid member 913 are sealed while being insulated.
  • the lower insulating member 970 is located inside the battery case 910, and is disposed on the radially outer side of the seal rubber 960, and is disposed between the case lid member 913 and the element connection main body 931e of the element connection member 931. .
  • the element connection main body 931e of the element connection member 931 and the case lid member 913 are insulated.
  • the electrode terminal member 930 is composed of three members (the element connecting member 931, the externally arranged terminal member 933, and the fastening member 935), and the number of parts tends to be large, so that the battery manufacturing process tends to be complicated. .
  • the element connecting member 931 and the externally arranged terminal member 933 are connected by caulking by the rivet portion 931g, the caulking is loosened by long-term use, and the contact resistance between them increases. There was a fear.
  • the present invention has been made in view of such a situation, and the number of parts of the electrode terminal member is small and the manufacture is easy, and the resistance of the electrode terminal member is not easily increased even when used for a long period of time. It aims at providing a high battery, a vehicle provided with this battery, and a battery using apparatus provided with this battery.
  • one aspect of the present invention includes a power generation element, a case main body member that has an opening and accommodates the power generation element, and a case lid member that closes the opening of the case main body member.
  • a battery case an electrode terminal member connected to the power generation element, and extending on the case lid member through a terminal insertion hole formed in the case lid member, and between the electrode terminal member and the case lid member
  • An insulating member that insulates the battery, wherein the electrode terminal member has an extending member that extends from the inside of the battery case through the terminal insertion hole onto the case lid member, and the extension
  • the member is an element connection part connected to the power generation element, and is located inside the battery case, connected to the power generation element, and connected to the element connection main body part.
  • An element connecting portion including an insertion portion inserted into the terminal insertion hole of the lid member, and an externally arranged terminal portion located on the case lid member of the outside of the battery case, wherein the insertion of the element connecting portion A fixed portion fixed to the case lid member via the insulating member, an intermediate portion connected to the fixed portion and extending in a direction away from the case lid member, and An external connection terminal portion having a Z-shape including an external connection portion that is connected to the intermediate portion, extends along the case lid member, and has a screw insertion hole penetrating through the case lid member.
  • the member is a battery formed by bending a single metal plate having a predetermined shape and integrally forming the element connecting portion and the externally arranged terminal portion.
  • the electrode terminal member has an extending member including an element connecting portion and an externally arranged terminal portion, and the extending member is formed by bending a single metal plate having a predetermined shape, and the element connecting portion. And the externally arranged terminal portion is formed integrally. For this reason, an electrode terminal member has few parts compared with the conventional electrode terminal member, manufacture of a battery is easy, and can make a battery cheap. In addition, since the extending member composed of the element connecting portion and the externally arranged terminal portion is integrally formed, the resistance of the electrode terminal member is hardly increased even when used for a long time, and the reliability can be improved.
  • the “power generation element” for example, a winding type power generation element obtained by winding a positive electrode, a negative electrode, and a separator each having a long shape, and a plurality of positive electrodes, negative electrodes, and separators each having a predetermined shape are stacked. And a laminated power generation element.
  • the “battery case” include a rectangular battery case and a cylindrical battery case.
  • the “terminal insertion hole” include a circular shape, an oval shape, an elliptical shape, a rectangular shape, a polygonal shape, and a shape obtained by combining these.
  • the “insulating member” may be insulated from one electrode terminal member by using a single insulating member, or may be insulated by using a plurality of insulating members.
  • the electrode terminal member further includes a fastening member positioned on the case lid member, and the fastening member extends in a form extending in a direction orthogonal to the case lid member.
  • a male screw part that is inserted into the screw insertion hole of the member and has a male screw formed on the outer periphery thereof, and has a diameter larger than that of the male screw part, and is greater than the male screw part and the external connection part of the extension member.
  • a battery having a base portion located on the case lid member side is preferable.
  • the electrode terminal member is composed of an extending member including an element connecting portion and an externally arranged terminal portion, and a fastening member.
  • the extending member is a single metal plate having a predetermined shape.
  • the element connecting portion and the externally arranged terminal portion are integrally formed by bending.
  • the electrode terminal member is composed of two members, that is, an extension member and a fastening member.
  • the number of parts is small compared to the conventional electrode terminal member composed of three members, and the battery can be easily manufactured. Can be made cheaper.
  • the extending member composed of the element connecting portion and the externally arranged terminal portion is integrally formed, the resistance of the electrode terminal member is hardly increased even when used for a long time, and the reliability can be improved.
  • the insulating member includes at least the insertion portion of the element connection portion of the extension member and an inner peripheral surface of the terminal insertion hole of the case lid member.
  • a battery comprising a single member with respect to one electrode terminal member interposed therebetween, and insulation and sealing between the element connecting portion and the case lid member being performed only by this insulating member Good.
  • the insulating member is composed of a single member interposed between at least the insertion portion of the element connection portion of the extending member and the inner peripheral surface of the terminal insertion hole of the case lid member, Insulation and sealing between the element connecting portion and the case lid member are performed only by this insulating member. Therefore, as compared with the conventional case, the battery can be easily manufactured and the battery can be made inexpensive.
  • the insulating member is formed by insert molding using the extending member, the fastening member, and the case lid member, and at least the fixing portion of the extending member and the The insulating member, the extending member, and the fastening member are joined to the surface of the case lid member and between the base portion of the fastening member and the surface of the case lid member while being joined thereto.
  • the member and the case lid member may be a battery that can be handled as one member.
  • each member constituting the electrode terminal member 930 (element connecting member 931, externally arranged terminal member 933 and fastening member 935), a case lid member 913, and three insulating members (upper insulating member 950).
  • the seal rubber 960 and the lower insulating member 970) were separately formed, and then these seven members were assembled (see FIG. 11).
  • the insulating member is formed by insert molding using the extending member, the fastening member, and the case lid member, and the insulating member, the extending member, the fastening member, and the case lid member are 1 It can be handled as one member. For this reason, compared with the past, each component can be easily cleaned and handled, and the battery can be easily manufactured. Further, among the extension member, the fastening member, and the case lid member, since the metal exposure of the portion covered by the insulating member formed by insert molding is suppressed, metal foreign matters such as metal powder are generated during handling. Can be suppressed more than before.
  • the “insulating member” can be formed of, for example, a resin. Specifically, a material excellent in resistance to electrolytic solution is preferable.
  • the insulating member may be formed using a single material of a resin such as PPS, PE, or PP, or a composite material including a plurality of types of resins. That's fine.
  • the joining method of the extending member, the fastening member, the case lid member, and the insulating member include a joining method using a nano-level anchor effect, a joining method using a silane coupling agent or organic plating, and the like.
  • the first direction is a direction connecting the center of the terminal insertion hole and the center of the male screw portion of the fastening member in plan view of the case lid member.
  • the direction orthogonal to the first direction is the second direction
  • the terminal insertion hole has a first dimension along the first direction larger than a second dimension along the second direction. It is better to use
  • the terminal insertion hole is configured such that the first dimension along the first direction is larger than the second dimension along the second direction. For this reason, when an external connection terminal such as a bus bar is brought into contact with the external connection portion of the extending member, and the nut or the like is fastened to the male screw portion of the fastening member, the insulating member rotates relative to the case lid member. Can be effectively prevented.
  • the fixing portion of the extending member includes a fixing portion back surface facing the case lid member side, and a fixing portion surface facing the case lid member side. It is preferable that the battery has a plate shape and at least a part of the surface of the fixing portion is exposed to the outside of the battery without being covered with the insulating member.
  • the intermediate portion of the extending member has a plate shape having an intermediate portion surface continuous with the fixed portion surface of the fixed portion and an intermediate portion rear surface continuous with the fixed portion rear surface. It is preferable that the battery is formed by exposing at least a part of the surface of the intermediate portion to the outside of the battery without being covered with the insulating member.
  • the external connection portion of the extending member includes a connection portion rear surface facing the case lid member side and a connection portion facing the opposite side to the case lid member side. It is preferable that the battery has a plate shape having a surface, and the surface of the connecting portion is exposed to the outside of the battery without being covered with the insulating member.
  • connection portion of the external connection portion of the extending member is exposed to the outside of the battery without being covered with the insulating member. For this reason, when an external connection terminal such as a bus bar is brought into contact with the surface of the connection portion and a nut or the like is fastened to the male screw portion of the fastening member, an insulating member is provided between the connection portion surface and the external connection terminal. Therefore, the electrical connection between the surface of the connecting portion and the external connection terminal can be ensured.
  • another aspect of the present invention is a vehicle on which the battery according to any one of the above is mounted and electric energy generated by the battery is used for all or a part of a power source.
  • the battery described above has a small number of parts for the electrode terminal member, is easy to manufacture, and can be made inexpensive. Therefore, a vehicle equipped with this battery can be made inexpensive. In addition, since the above-described battery hardly increases resistance in the electrode terminal member even when used for a long period of time and has high reliability, the reliability of the vehicle on which the battery is mounted can be improved.
  • the “vehicle” include an electric vehicle, a hybrid vehicle, a plug-in hybrid vehicle, a hybrid railway vehicle, a forklift, an electric wheelchair, an electrically assisted bicycle, and an electric scooter.
  • another aspect of the present invention is a battery-using device that includes the battery described above and uses the battery as at least one energy source.
  • the battery described above has a small number of parts for the electrode terminal member, is easy to manufacture, and can be made inexpensive. Therefore, the battery using apparatus which mounts this battery can be made cheap.
  • the above-described battery is less likely to increase resistance in the electrode terminal member even when used for a long period of time, and has high reliability. Therefore, it is possible to improve the reliability of the battery-using device on which the battery is mounted.
  • Examples of the “battery-equipped device” include various home appliances driven by a battery such as a personal computer, a mobile phone, a battery-driven electric tool, and an uninterruptible power supply, office equipment, and industrial equipment.
  • FIG. 1 is a longitudinal sectional view of a lithium secondary battery according to Embodiment 1.
  • FIG. 3 is an exploded perspective view showing an electrode terminal member, a case lid member, and an insulating member in the lithium secondary battery according to Embodiment 1.
  • FIG. 4 is a perspective view showing an electrode terminal member, a case lid member, and an insulating member in an integrated state in the lithium secondary battery according to Embodiment 1.
  • FIG. FIG. 3 is a partially enlarged perspective view showing an enlarged vicinity of a fastening member among an electrode terminal member, a case lid member, and an insulating member in an integrated state of the lithium secondary battery according to Embodiment 1.
  • FIG. 2 is a partially enlarged perspective view showing an enlarged vicinity of a safety valve among an electrode terminal member, a case lid member, and an insulating member in an integrated state of the lithium secondary battery according to Embodiment 1. It is a graph which shows the relationship between a temperature / humidity cycle and conduction resistance. It is a graph which shows the relationship between an exposed area and the temperature of an extending member.
  • FIG. 6 is an explanatory diagram showing a vehicle according to a second embodiment. It is explanatory drawing which shows the hammer drill which concerns on Embodiment 3.
  • FIG. It is a longitudinal cross-sectional view which shows the form of the electrode terminal member vicinity of the battery which concerns on a prior art. It is a disassembled perspective view which shows the electrode terminal member of the battery which concerns on a prior art, a case cover member, and an insulating member.
  • Lithium secondary battery 110 Battery case 111 Case body member 111h Opening 113 Case lid member 113h Terminal insertion hole 120 Electrode body (power generation element) 130 Positive Electrode Terminal Member (Electrode Terminal Member) 131 Element connection portion 131e Element connection main body portion 131f Insertion portion 133 Externally arranged terminal portion 133e Fixing portion 133f Intermediate portion 133g External connection portion 133gh Screw insertion hole 135 Fastening member 135e Male screw portion 135f Base portion 137 Extension member 140 Negative electrode terminal member ( Electrode terminal member) 150 Insulating member 700 Vehicle 710 Assembly battery (battery) 800 Hammer drill (Battery-equipped equipment) 810 Battery pack (battery) A1 First dimension A2 Second dimension G1 Center G2 (of the terminal insertion hole) Center H1 (of the external thread) H1 First direction H2 Second direction
  • FIG. 1 the longitudinal cross-sectional view of the lithium secondary battery (battery) 100 of this Embodiment 1 is shown.
  • 2 to 4 show details of the positive electrode terminal member 130, the negative electrode terminal member 140, and the like constituting the lithium secondary battery 100.
  • FIG. FIG. 5 shows the vicinity of the safety valve portion 113j of the lithium secondary battery 100. 1 to 5 will be described as the upper side of the lithium secondary battery 100 and the lower side as the lower side of the lithium secondary battery 100.
  • the lithium secondary battery 100 is a prismatic battery that is mounted on a vehicle such as a hybrid car or an electric vehicle, or a battery using device such as a hammer drill.
  • the lithium secondary battery 100 includes a rectangular battery case 110, an electrode body (power generation element) 120 housed in the battery case 100, and an insulating film enclosed in the battery case 110 while surrounding the electrode body 120.
  • an electrolytic solution is injected into the battery case 110.
  • the battery case 110 is made of metal (specifically, pure aluminum) and is formed in a rectangular parallelepiped shape.
  • the battery case 110 has a box shape in which only the upper side is opened.
  • the battery case 110 has a rectangular shape that is welded in a form that closes an opening 111h of the case body member 111 and a case body member 111 that houses an electrode body 120 described later.
  • a case lid member 113 a case body member 111 includes a rectangular plate-like case bottom wall portion 111b facing the case lid member 113, and four rectangular plate-like case side wall portions 111c connecting the case lid member 113 and the case bottom wall portion 111b, 111c,...
  • terminal insertion holes 113h and 113h having predetermined shapes penetrating the case lid member 113 are formed at predetermined positions near both ends in the longitudinal direction (left and right direction in FIGS. 1 to 5).
  • a positive electrode terminal member 130 and an insulating member 150 described later are inserted into one terminal insertion hole 113h (left side in FIGS. 1 and 2), and the other terminal insertion hole 113h (right side in FIGS. 1 and 2).
  • a negative electrode terminal member 140 and an insulating member 150, which will be described later, are inserted through the electrode.
  • a direction connecting a center G1 of the terminal insertion hole 113h and a center G2 of a male screw portion 135e of the fastening member 135 described later is a first direction H1 (see FIG. 2).
  • the direction orthogonal to the first direction H1 is defined as a second direction H2.
  • the first direction H1 is the longitudinal direction of the case lid member 113
  • the second direction H2 is the short direction of the case lid member 113.
  • the terminal insertion hole 113h is configured such that the first dimension A1 along the first direction H1 is larger than the second dimension A2 along the second direction H2.
  • the terminal insertion hole 113h is a first opening 113h1 that is rectangular in plan view and is elongated in the first direction H1, and is located closer to the center side of the case lid member 113 than the first opening 113h1.
  • the second opening 113h2 is elongated in the direction H1 and has a rectangular shape in plan view that is smaller than the first opening 113h1.
  • the second dimension 7 mm.
  • a safety valve portion 113j is provided in the center of the case lid member 113 in the longitudinal direction.
  • the safety valve portion 113j is formed integrally with the case lid member 113 and forms a part of the case lid member 113.
  • the safety valve portion 113j is formed in a thin film shape (thickness 110 ⁇ 30 ⁇ m) thinner than other portions of the case lid member 113, and has a V-shaped groove on the upper side thereof, and is particularly thin as 45 ⁇ 30 ⁇ m.
  • the breaking portion 113jv is formed in a predetermined shape. As a result, the safety valve portion 113j operates when the internal pressure inside the battery case 110 reaches a predetermined pressure. That is, when the internal pressure reaches a predetermined pressure, the breaking portion 113jv breaks and releases the gas inside the battery to the outside of the battery.
  • a thin resin film 115 made of PPS resin is deposited on the safety valve portion 113j (see FIGS. 2, 3 and 5). Since the safety valve portion 113j is formed thin and the break portion 113jv is formed particularly thin, there is a risk of damage such as a hole formed by oxidation. However, since the safety valve portion 113j is protected from the outside by forming the resin film 115 on the safety valve portion 113j, it is possible to effectively prevent the safety valve portion 113j from being damaged. Since the resin film 115 is formed at the same time as the insert forming of the insulating member 150 as will be described later, the material cost and the manufacturing cost are compared with the case of attaching a protective seal or the like on the safety valve portion 113j. Can be reduced.
  • a liquid injection port portion 113 m for injecting the electrolyte into the battery case 110 is provided at a predetermined position on the negative electrode terminal member 140 side from the longitudinal center of the case lid member 113. Note that the entire surface of the case lid member 113 is subjected to organic plating in order to improve the bondability with an insulating member 150 described later formed by insert molding.
  • a wound electrode body 120 having an elliptical cross section orthogonal to its own axial direction (left and right direction in FIG. 1) is laid down.
  • the electrode body 120 is accommodated in a state in which the axial direction of the electrode body 120 is orthogonal to the two case side wall portions 111 c and 111 c of the case body member 111.
  • the element connection part 131 of the positive electrode terminal member 130 and the element connection part 131 of the negative electrode terminal member 140 are connected to both ends of the electrode body 120 in the axial direction.
  • This electrode body 120 is obtained by rolling a positive electrode sheet and a negative electrode sheet with a separator interposed between them and compressing them into a flat shape.
  • the positive electrode sheet has a positive electrode current collector made of a long aluminum foil.
  • a positive electrode active material layer containing a positive electrode active material is formed on both surfaces of the positive electrode current collector.
  • the negative electrode sheet has a negative electrode current collector made of a long copper foil.
  • a negative electrode active material layer containing a negative electrode active material is formed on both surfaces of the negative electrode current collector.
  • the separator is made of a porous polypropylene resin sheet.
  • the electrode body 120 is entirely surrounded by an insulating film envelope 125 formed by bending an insulating film into a box shape having an opening only on the upper side and welding a predetermined portion, except for the upper side.
  • the positive electrode terminal member 130 is electrically and mechanically connected to the positive electrode sheet of the electrode body 120 inside the battery case 110, while the battery is passed through the terminal insertion hole 113 h formed in the battery case 110 (case lid member 113). It extends outside the case 110 (on the case lid member 113).
  • the negative electrode terminal member 140 is electrically and mechanically connected to the negative electrode sheet of the electrode body 120 inside the battery case 110, while passing through a terminal insertion hole 113 h formed in the battery case 110 (case lid member 113).
  • the battery case 110 extends outside (on the case lid member 113).
  • Each of these electrode terminal members 130 and 140 extends from the inside of the battery case 110 through the terminal insertion hole 113h onto the case lid member 113, and includes an extending member 137 including an element connecting portion 131 and an externally arranged terminal portion 133,
  • the fastening member 135 is disposed on the case lid member 113 so as to be connectable (contactable) to the extending member 137.
  • Both the extending member 137 and the fastening member 135 are made of metal.
  • the extending member 137 of the positive electrode terminal member 130 is made of pure aluminum in consideration of welding with the positive electrode sheet (aluminum foil) of the electrode body 120, and the extending member 137 of the negative electrode terminal member 140. Is formed of pure copper in consideration of welding of the electrode body 120 to the negative electrode sheet (copper foil). In addition, the entire surface of these extending members 137 and 137 is subjected to organic plating in order to improve the bonding property with an insulating member 150 described later formed by insert molding.
  • the element connecting portion 131 is located inside the battery case 110, and is connected to the element connecting main body portion 131e that is electrically and mechanically connected to the electrode body 120, and the element connecting main body portion 131e.
  • the insertion portion 131 f is inserted into the terminal insertion hole 113 h of the case lid member 113.
  • the element connection main body 131e has a predetermined shape obtained by bending a metal plate material, and is welded to the electrode body 120.
  • the insertion portion 131f is continuous with the upper end 131es of the element connection main body portion 131e on the lower side of the insertion portion 131f, and is connected with the fixing portion 133e of the external arrangement terminal portion 133 described later on the upper side of the insertion portion 131f.
  • the insertion portion 131f penetrates the terminal insertion hole 113h of the case lid member 113 and penetrates the insulating member 150 further radially inward of the terminal insertion hole 113h.
  • the insertion portion 131f has a predetermined shape obtained by bending a metal plate material.
  • the insertion portion 131f is a first plate insertion portion that extends from the upper end 131es of the element connection main body portion 131e and extends in a plate shape along the case lid member 113 and in the lateral direction of the case lid member 113.
  • 131f1 and a second plate insertion portion 131f2 which is continuous from the first plate insertion portion 131f1 and extends upward in a direction perpendicular to the case lid member 113, and has an L shape.
  • the externally arranged terminal portion 133 is located on the case lid member 113, and includes a fixed portion 133e, an intermediate portion 133f, and an external connection portion 133g, and has a Z shape (stepped shape).
  • the fixing part 133e has a plate shape having a fixing part surface 133ea facing the side opposite to the case lid member 113 (upper side) and a fixing part rear surface 113eb facing the case lid member 113 side (lower side).
  • the fixing portion 133e is connected to the insertion portion 131f of the element connecting portion 131 described above, extends along and parallel to the case lid member 113, and is fixed to the case lid member 113 via an insulating member 150 described later. .
  • the entire surface of the fixing portion surface 133ea of the fixing portion 133e is exposed to the outside of the battery without being covered with the insulating member 150.
  • the intermediate part 133f has a plate shape having an intermediate part surface 133fa continuous with the fixed part surface 133ea of the fixed part 133e and an intermediate part back surface 133fb continuous with the fixed part back surface 133eb.
  • the intermediate portion 133f is connected to the fixing portion 133e, and extends in a direction away from the case lid member 113 in the direction away from the case lid member 113, in the first embodiment, in the direction perpendicular to the case lid member 113 (upper side). Yes.
  • the entire surface of the intermediate portion 133fa of the intermediate portion 133f is exposed to the outside of the battery without being covered with an insulating member 150 described later.
  • the external connection portion 133g has a plate shape having a connection portion surface 133ga facing the side opposite to the case lid member 113 (upper side) and a connection portion rear surface 133gb facing the case lid member 113 side (lower side).
  • the external connection portion 133g is connected to the intermediate portion 133f, extends along and parallel to the case lid member 113, and is formed with a circular screw insertion hole 133gh passing therethrough.
  • the entire external connection portion 133g is exposed outside the battery without being covered with an insulating member 150 described later.
  • the connection portion surface 133ga of the external connection portion 133g is used for electrical connection with an external connection terminal such as a bus bar.
  • the element connection member 931 and the externally arranged terminal member 933 are separate members (see FIGS. 10 and 11).
  • the above-described element connecting portion 131 and the externally arranged terminal portion 133 are integrally formed by bending a single metal plate having a predetermined shape, and extending from one member.
  • the member 137 is used.
  • the fastening member 135 includes a male screw portion 135e having a male screw formed on its outer periphery and a base portion 135f having a larger diameter than this.
  • the male screw portion 135e is inserted into the screw insertion hole 133gh of the external connection portion 133g of the extending member 137 in a form extending in a direction (vertical direction) orthogonal to the case lid member 113, and is formed on the outer periphery as described above.
  • a male screw is formed. In FIGS. 1 to 4, the description of the male screw is omitted.
  • the base portion 135f is a disc-shaped disc portion 135f1 and is located on the case lid member 113 side of the disc portion 153f1, and has a columnar portion 135f2 that is slightly smaller in diameter than the disc portion 135f1 and has a cylindrical outer shape. (See FIG. 2).
  • the base portion 135f is located closer to the case lid member 113 than the external threaded portion 135e and the external connection portion 133g of the extending member 137.
  • the base surface 135fa facing the side opposite to the case lid member 113 (upper side) abuts on the connection portion back surface 133gb of the external connection portion 133g of the extension member 137, and the fastening member 135 extends.
  • the lead member 137 is electrically connected.
  • the base portion 135f is formed with a concave portion 135fc having a hexagonal shape in plan view, which is recessed on the side (upper side) opposite to the case lid member 113 side and opened on the base rear surface 135fb facing the case lid member 113 side (lower side).
  • a protruding portion 150fn of an insulating member 150 described later is filled in the recess 135fc.
  • the insulating member 150 is disposed between the electrode terminal members 130 and 140 and the case lid member 113 to prevent the electrode terminal members 130 and 140 and the case lid member 113 from contacting and short-circuiting.
  • the insulating member 150 is made of resin (specifically, PPS), and is formed by insert molding using the electrode terminal members 130 and 140 (the extending member 137 and the fastening member 135) and the case lid member 113. Thereby, the insulating member 150, the extending member 137, the fastening member 135, and the case lid member 113 can be handled as one member as shown in FIG.
  • the insulating member 150 is positioned inside the battery case 110 and inside the terminal insertion hole 113h of the case lid member 113, and outside the battery case 110 (on the case lid member 113). And an external insulating portion 150f.
  • the internal insulating portion 150e is interposed between the insertion portion 131f of the element connection portion 131 of the extending member 137 and the inner peripheral surface 113ha of the terminal insertion hole 113h of the case lid member 113, and is joined to these, and the electrode body 120 is also provided.
  • the back surface 113b of the case lid member 113 Accordingly, the insertion portion 131f of the element connection portion 131 of the extending member 137 and the case lid member 113 are insulated, and the electrode body 120 and the case lid member 113 are insulated.
  • the insulation and sealing between the element connecting portion 131 and the case lid member 113 are performed only by the insulating member 150 (specifically, the internal insulating portion 150e). That is, in the conventional battery 900 (FIGS. 10 and 11), three insulating members (an upper insulating member 950, a seal rubber 960, and a lower insulating member 970) are used for insulation and sealing between the element connecting member 931 and the case lid member 113. ) Is used. On the other hand, in the first embodiment, only one insulating member 150 is used for insulation and sealing between the element connecting portion 131 and the case lid member 113.
  • the external insulating portion 150f is formed between the fixing portion 133e of the externally arranged terminal portion 133 of the extending member 137 and the surface 113a of the case lid member 113, and between the base portion 135f of the fastening member 135 and the surface 113a of the case lid member 113. These are joined to each other.
  • the externally arranged terminal portion 133 of the extending member 137 and the case lid member 113 are insulated
  • the base portion 135f of the fastening member 135 and the case lid member 113 are insulated.
  • the external insulating portion 150f is formed with a recess 150fm that is recessed on the case lid member 113 side (lower side) and that opens on the opposite side (upper side) of the case lid member 113 (see FIG. 2).
  • positioning terminal part 133 of the extending member 137 is settled in this recessed part 150fm, and the external insulation part 150f and the fixing
  • the external insulating portion 150f is provided with a hexagonal columnar protruding portion 150fn that protrudes on the opposite side (upper side) from the case lid member 113.
  • the projecting portion 150fn is accommodated in the recess 135fc of the base portion 135f of the fastening member 135, and the external insulating portion 150f and the base portion 135f are joined to each other.
  • the fixing portion of the fixing portion 133e of the extending member 137 is fixed. It does not cover the surface 133ea. Further, the insulating member 150 does not cover the intermediate portion surface 133fa of the intermediate portion 133f of the extending member 137. Further, the insulating member 150 does not cover the connection portion surface 133ga of the external connection portion 133g of the extending member 137.
  • the electrode terminal members 130 and 140 include the extending member 137 including the element connecting portion 131 and the externally arranged terminal portion 133, and the fastening member 135.
  • the extending member 137 is formed by bending a single metal plate having a predetermined shape, and the element connecting portion 131 and the externally arranged terminal portion 133 are integrally formed.
  • the electrode terminal members 130 and 140 are each composed of two members, that is, an extending member 137 and a fastening member 135, and the number of parts is smaller than that of the conventional electrode terminal member 930 composed of three members, and the lithium secondary battery 100 is easy to manufacture, and the lithium secondary battery 100 can be made inexpensive.
  • the extending member 137 including the element connecting portion 131 and the externally arranged terminal portion 133 is integrally formed, the resistance of the electrode terminal members 130 and 140 hardly increases even when used for a long period of time, and the reliability is improved. Can be made.
  • the insulating member 150 is interposed between the insertion portion 131f of the element connection portion 131 of the extending member 137 and the inner peripheral surface 113ha of the terminal insertion hole 113h of the case lid member 113, so that the element Insulation and sealing between the connecting portion 131 and the case lid member 113 are performed only by the insulating member 150. Therefore, the lithium secondary battery 100 can be easily manufactured as compared with the conventional case, and the lithium secondary battery 100 can be made inexpensive.
  • the insulating member 150 is formed by insert molding using the extending member 137, the fastening member 135, and the case lid member 113, and the insulating member 150, the extending member 137, the fastening member 135, and the like.
  • the case lid member 113 can be handled as one member. For this reason, compared with the conventional case in which the seven members 931, 933, 935, 913, 950, 960, and 970 are handled separately, the parts can be easily cleaned and handled, and the lithium secondary battery 100 Is easy to manufacture.
  • the metal exposure is suppressed about the part covered with the insulating member 150 formed by insert molding among the extending member 137, the fastening member 135, and the case lid member 113, metal powder or the like is used during handling.
  • the occurrence of metallic foreign matter can be suppressed more than before.
  • the terminal insertion hole 113h formed in the case lid member 113 is configured such that the first dimension A1 along the first direction H1 is larger than the second dimension A2 along the second direction H2. ing. Therefore, when an external connection terminal such as a bus bar is brought into contact with the external connection portion 133g of the extending member 137 and a nut or the like is fastened to the male screw portion 135e of the fastening member 135, the base portion 135f of the fastening member 135 is fixed.
  • the insulating member 150 thus made can be effectively prevented from rotating with respect to the case lid member 113.
  • the entire surface of the fixing portion surface 133ea of the fixing portion 133e of the extending member 137 is covered with the insulating member 150, although the insulating member 150 is formed by insert molding. Not exposed to the outside of the battery. For this reason, heat is generated from the fixed portion surface 133ea by the heat of the electrode terminal members 130 and 140 (for example, heat generated inside the battery and transmitted to the electrode terminal members 130 and 140, and resistance generated in the electrode terminal members 130 and 140 themselves). Heat, etc.) can be dissipated, so that it is possible to suppress problems that occur when the temperature of the electrode terminal members 130 and 140 rises (for example, the insulating member 150 deteriorates due to heat and the sealing performance decreases).
  • the entire surface of the intermediate portion 133fa of the intermediate portion 133f of the extending member 137 is covered with the insulating member 150 even though the insulating member 150 is formed by insert molding. Not exposed to the outside of the battery. For this reason, since the heat of the electrode terminal members 130 and 140 can be radiated not only from the fixed portion surface 133ea but also from the intermediate portion surface 133fa, the problem caused by the temperature rise of the electrode terminal members 130 and 140 is further effective. Can be suppressed.
  • connection portion surface 133ga of the external connection portion 133g of the extending member 137 is not covered with the insulating member 150, and the battery Exposed outside. For this reason, when connecting an external connection terminal such as a bus bar to the connection portion surface 133ga and fastening a nut or the like to the male screw portion 135e of the fastening member 135, the connection portion surface 133ga and the external connection terminal are connected to each other. Since the insulating member 150 is not sandwiched between them, the electrical connection between the connection portion surface 133ga and the external connection terminal can be ensured.
  • An extending member 137 is prepared by bending a single metal plate having a predetermined shape. Further, a fastening member 135 and a case lid member 113 are prepared. Then, the insulating member 150 is formed by resin insert molding using these members 137, 135, and 113. Specifically, the extending member 137, the fastening member 135, and the case lid member 113 are set in a mold, and the molten molding resin is injected into the mold to form the insulating member 150. Thereby, as shown in FIG.
  • the sub-assay which can handle the insulation members 150 and 150, the extension members 137 and 137, the fastening members 135 and 135, and the case cover member 113 as one member can be performed.
  • the resin film 115 is simultaneously formed on the safety valve portion 113j of the case lid member 113.
  • the electrode body 120 is prepared, and the element connection portion 131 of the positive electrode terminal member 130 and the element connection portion 131 of the negative electrode terminal member 140 are welded to both ends in the axial direction. Thereafter, the electrode body 120 is inserted into the insulating film enclosure 125.
  • the case lid member 113 is disposed on the opening 111 h of the case body member 111 such that the electrode body 120 and the insulating film enclosure 125 are accommodated in the case body member 111. Then, the peripheral portion of the case lid member 113 and the peripheral edge of the opening 111h of the case main body member 111 are laser-welded. Thereafter, an electrolytic solution is injected into the battery case 110 from the liquid inlet portion 113m of the case lid member 113, and the liquid inlet portion 113m is sealed. Thus, the lithium secondary battery 100 is completed.
  • the lithium secondary battery 100 of Embodiment 1 was prepared. Further, as a comparative example, a lithium secondary battery 900 according to the related art shown in FIGS. 10 and 11 was prepared. And about each test sample, the temperature / humidity cycle test was done. Specifically, each test sample was held at 65 ° C. for 15.5 hours and then held at 40 ° C. for 7.5 hours. Then, after holding at 65 ° C. and 95% RH for 17.5 hours, it was held at 40 ° C. for 7.5 hours. The temperature / humidity condition was set to 1 cycle, and a total of 10 cycles were performed. For each test sample, the conduction resistance of the electrode terminal members 130 and 930 was measured before the start of the test, after 4 cycles, and after 10 cycles. The result is shown in the graph of FIG.
  • the lithium secondary battery 900 of the comparative example has already increased the conduction resistance at the stage where the temperature and humidity cycle test was performed for four cycles, and the conduction resistance has increased further after 10 cycles.
  • the conduction resistance does not change (does not increase) even when the temperature and humidity cycle test is performed 10 cycles.
  • the reason why the conduction resistance increases in the lithium secondary battery 900 of the comparative example is that the element connecting member 931 and the externally arranged terminal member 933 are connected by caulking by the rivet portion 931g, so that caulking is performed by the temperature and humidity cycle test. This is probably because the conduction resistance increases due to loosening.
  • the lithium secondary battery 100 of the example since the element connection portion 131 and the externally arranged terminal portion 133 are integrally formed, it is considered that resistance increase does not occur even when the temperature and humidity cycle test is performed. . From this, it can be seen that by forming the element connecting portion 131 and the externally arranged terminal portion 133 integrally, resistance increase does not easily occur in the electrode terminal members 130 and 140 even when used for a long period of time, and the reliability is improved.
  • the lithium secondary battery 100 of Embodiment 1 was prepared.
  • the lithium secondary battery 100 according to the first embodiment includes the entire surface of the fixing portion surface 133ea of the fixing portion 133e of the extending member 137 and the intermediate portion surface of the intermediate portion 133f among the electrode terminal members 130 and 140.
  • the entire surface of 133fa is exposed to the outside of the battery, and the exposed area of the fixed portion 133e and the intermediate portion 133f combined with each other is 140 mm 2 .
  • a lithium secondary battery in which the intermediate surface 133fa of the intermediate part 133f of the lithium secondary battery 100 of Embodiment 1 was covered with an insulating member 150 was prepared.
  • the exposed area of the fixing portion 133e and the intermediate portion 133f (only the total area of the fixing portion surface 133ea in the second embodiment) is 100 mm 2 .
  • Example 3 based on the lithium secondary battery 100 of Embodiment 1 described above, the entire intermediate surface 133fa of the intermediate portion 133f and half of the fixed portion surface 133ea of the fixing portion 133e are connected to the insulating member 150.
  • a lithium secondary battery covered with was prepared. In this lithium secondary battery, the exposed area of the fixed portion 133e and the intermediate portion 133f (in the third embodiment, half the area of the fixed portion surface 133ea) is 50 mm 2 .
  • Example 4 based on the lithium secondary battery 100 of Embodiment 1 described above, the entire intermediate surface 133fa of the intermediate portion 133f and the entire fixed portion surface 133ea of the fixing portion 133e are connected to the insulating member 150.
  • a lithium secondary battery covered with was prepared. In this lithium secondary battery, the exposed areas of the fixed portion 133e and the intermediate portion 133f are 0 mm 2 .
  • the temperature of the extending member 137 decreases as the exposed area of the fixed portion 133e and the intermediate portion 133f increases. It is considered that the larger the exposed area, the more efficiently the heat of the extending member 137 can be dissipated. When the extending member 137 reaches a high temperature, there is a possibility that a defect such as deterioration of the sealing performance due to deterioration of the insulating member 150 due to this heat may occur. Therefore, it is preferable to increase the exposed areas of the fixed portion 133e and the intermediate portion 133f to keep the temperature of the extending member 137 low.
  • a vehicle 700 according to the second embodiment includes a plurality of lithium secondary batteries (batteries) 100 according to the first embodiment.
  • the vehicle 700 is a hybrid vehicle that is driven by using an engine 740, a front motor 720, and a rear motor 730 in combination.
  • the vehicle 700 includes a vehicle body 790, an engine 740, a front motor 720, a rear motor 730, a cable 750, and an inverter 760 attached thereto.
  • the vehicle 700 includes an assembled battery 710 having a plurality of lithium secondary batteries 100 therein, and electric energy from the assembled battery 710 is used to drive the front motor 720 and the rear motor 730.
  • the lithium secondary battery 100 has a small number of parts for the electrode terminal members 130 and 140, the lithium secondary battery 100 can be easily manufactured, and the lithium secondary battery 100 can be made inexpensive. . Therefore, the vehicle 700 equipped with the lithium secondary battery 100 can be made inexpensive. Further, the lithium secondary battery 100 is less likely to increase resistance in the electrode terminal members 130 and 140 even when used for a long period of time, and has high reliability. Therefore, the reliability of the vehicle 700 on which the lithium secondary battery 100 is mounted can be improved.
  • a hammer drill 800 according to the third embodiment is a battery using device on which a battery pack 810 including the lithium secondary battery (battery) 100 according to the first embodiment is mounted. As shown in FIG. 9, this hammer drill 800 has a battery pack 810 accommodated in a bottom 821 of a main body 820, and this battery pack 810 is used as an energy source for driving the drill.
  • the lithium secondary battery 100 has a small number of parts for the electrode terminal members 130 and 140, the lithium secondary battery 100 can be easily manufactured, and the lithium secondary battery 100 can be made inexpensive. . Therefore, the hammer drill 800 on which the lithium secondary battery 100 is mounted can be made inexpensive. In addition, since the lithium secondary battery 100 is less likely to increase resistance in the electrode terminal members 130 and 140 even when used for a long period of time and has high reliability, the reliability of the hammer drill 800 on which the lithium secondary battery 100 is mounted can be improved. .
  • the present invention has been described with reference to the embodiments.
  • the present invention is not limited to the above-described first to third embodiments, and it is needless to say that the present invention can be appropriately modified and applied without departing from the gist thereof.
  • the lithium secondary battery 100 is exemplified as the battery.
  • the present invention can be applied to other types of secondary batteries such as a nickel metal hydride battery and a nickel cadmium battery.
  • the battery 100 having the wound type power generation element is illustrated, but the present invention can also be applied to a battery having a stacked type power generation element.

Abstract

Provided is a highly reliable battery which can be manufactured easily because the number of components of an electrode terminal member is small and wherein the resistance of the electrode terminal member does not increase easily even after long term use. Also provided is a vehicle equipped with the battery, and an apparatus using this battery. A battery comprises electrode terminal members (130, 140) each having an extension member (137) consisting of an element joint (131) and an externally arranged terminal (133), and a fastening member (135), wherein the element joint (131) consists of an element joint body (131e) and an inserting portion (131f), the externally arranged terminal (133) consists of a fixed portion (133e), an intermediate portion (133f) and an external joint (133g) arranged in Z-shape, the extension member (137) is formed by bending a metal plate material of a predetermined shape, and the element joint (131) and the externally arranged terminal (133) are formed integrally.

Description

電池、車両及び電池使用機器Batteries, vehicles, and equipment using batteries
 本発明は、発電要素と、これを収容する電池ケースと、発電要素に接続する一方、電池ケースの外部に延出する電極端子部材と、この電極端子部材と電池ケースとの間を絶縁する絶縁部材とを備える電池に関する。また、この電池を備える車両、及び、この電池を備える電池使用機器に関する。 The present invention provides a power generation element, a battery case that accommodates the power generation element, an electrode terminal member that extends to the outside of the battery case while being connected to the power generation element, and an insulation that insulates the electrode terminal member from the battery case A battery comprising the member. Moreover, it is related with a vehicle provided with this battery, and a battery using apparatus provided with this battery.
 従来より、発電要素と、これを収容する電池ケースと、発電要素に接続する一方、電池ケースの外部に延出して外部の接続端子との接続に利用される電極端子部材と、この電極端子部材と電池ケースとの間を絶縁する絶縁部材とを備える電池が知られている。例えば特許文献1に、このような電池が開示されている。図10に、この電池900の電極端子部材930近傍の縦断面図を示し、また、図11に、電極端子部材930、絶縁部材950,960,970等の分解斜視図を示す。 Conventionally, a power generation element, a battery case that accommodates the power generation element, an electrode terminal member that is connected to the power generation element and extends to the outside of the battery case and used for connection to an external connection terminal, and the electrode terminal member A battery including an insulating member that insulates the battery case from the battery case is known. For example, Patent Document 1 discloses such a battery. FIG. 10 shows a longitudinal sectional view of the vicinity of the electrode terminal member 930 of the battery 900, and FIG. 11 shows an exploded perspective view of the electrode terminal member 930, the insulating members 950, 960, 970, and the like.
 この電池900は、発電要素(図示外)を収容する電池ケース910と、発電要素に接続する一方、電池ケース910の外部に延出する電極端子部材930と、この電極端子部材930と電池ケース910との間に介在してこれらを絶縁する複数(3つ)の絶縁部材(上部絶縁部材950、シールゴム960及び下部絶縁部材970)とを備える。
 このうち電池ケース910は、発電要素を収容する箱状のケース本体部材(図示外)と、このケース本体部材の開口を閉塞するケース蓋部材913とから構成されている。ケース蓋部材913には、円状の端子挿通孔913hが形成され、電極端子部材930が挿通されている。
The battery 900 includes a battery case 910 that houses a power generation element (not shown), an electrode terminal member 930 that extends to the outside of the battery case 910 while being connected to the power generation element, and the electrode terminal member 930 and the battery case 910. And a plurality of (three) insulating members (upper insulating member 950, seal rubber 960, and lower insulating member 970) that are interposed between and insulate them.
Among these, the battery case 910 includes a box-shaped case main body member (not shown) that houses the power generation element, and a case lid member 913 that closes the opening of the case main body member. A circular terminal insertion hole 913 h is formed in the case lid member 913, and the electrode terminal member 930 is inserted therethrough.
 電極端子部材930は、要素接続部材931と外部配置端子部材933と締結部材935の3部材からなり、これらの部材931,933,935は、互いに別体とされている。
 このうち要素接続部材931は、要素接続本体部931eと挿通部931fとリベット部931gとからなる。要素接続本体部931eは、電池ケース910の内部に位置し、発電要素に接続している。また、挿通部931fは、この要素接続本体部931eの上端(図10及び図11中、上方の端部)に連なり、ケース蓋部材913の端子挿通孔913h及び後述する外部配置端子部材933の固定部933eの開口933ehに挿通されている。また、リベット部931gは、挿通部931fの上端に連なり、電池外部に露出し、加締められて外部配置端子部材933の固定部933eに上側から当接している。
The electrode terminal member 930 includes three members, that is, an element connection member 931, an externally arranged terminal member 933, and a fastening member 935. These members 931, 933, and 935 are separated from each other.
Among these, the element connection member 931 includes an element connection main body portion 931e, an insertion portion 931f, and a rivet portion 931g. The element connection main body 931e is located inside the battery case 910 and is connected to the power generation element. The insertion portion 931f is connected to the upper end (the upper end portion in FIGS. 10 and 11) of the element connection main body portion 931e, and fixes a terminal insertion hole 913h of the case lid member 913 and an external arrangement terminal member 933 to be described later. The portion 933e is inserted into the opening 933eh. The rivet portion 931g is connected to the upper end of the insertion portion 931f, is exposed to the outside of the battery, is crimped, and is in contact with the fixing portion 933e of the externally arranged terminal member 933 from above.
 外部配置端子部材933は、ケース蓋部材913上に位置し、固定部933eと中間部933fと外部接続部933gとからなり、Z字状をなす。固定部933eは、自身を貫通する開口933ehを有し、上述のように要素接続部材931(リベット部931g)に接続している。この固定部933eは、ケース蓋部材913に沿ってこれに平行に延びる板状をなし、後述する上部絶縁部材950を介してケース蓋部材913に固定されている。中間部933fは、この固定部933eに連なり、上方(図10及び図11中、上方)に延びる板状をなす。外部接続部933gは、この中間部933fに連なり、ケース蓋部材913に沿ってこれに平行に延びる板状をなし、自身を貫通するネジ挿通孔933ghが形成されている。 The externally arranged terminal member 933 is located on the case lid member 913, and includes a fixing portion 933e, an intermediate portion 933f, and an external connection portion 933g, and has a Z shape. The fixing portion 933e has an opening 933eh that passes through the fixing portion 933e, and is connected to the element connecting member 931 (rivet portion 931g) as described above. The fixing portion 933e has a plate shape extending along and parallel to the case lid member 913, and is fixed to the case lid member 913 via an upper insulating member 950 described later. The intermediate portion 933f is connected to the fixing portion 933e and has a plate shape extending upward (upward in FIGS. 10 and 11). The external connection portion 933g is connected to the intermediate portion 933f, has a plate shape extending in parallel with the case lid member 913, and is formed with a screw insertion hole 933gh penetrating through the plate.
 締結部材935は、ケース蓋部材913上に位置し、雄ネジ部935eと基部935fとからなる。雄ネジ部935eは、ケース蓋部材913に直交する方向に延びる雄ネジが形成され、外部配置端子部材933の外部接続部933gのネジ挿通孔933ghに挿通されている。基部935fは、この雄ネジ部935eよりも径大で、この雄ネジ部935e及び外部接続部933gよりもケース蓋部材913側に位置している。 The fastening member 935 is located on the case lid member 913 and includes a male screw portion 935e and a base portion 935f. The male screw portion 935e is formed with a male screw extending in a direction orthogonal to the case lid member 913, and is inserted into the screw insertion hole 933gh of the external connection portion 933g of the externally arranged terminal member 933. The base portion 935f is larger in diameter than the male screw portion 935e, and is located closer to the case lid member 913 than the male screw portion 935e and the external connection portion 933g.
 3つの絶縁部材950,960,970は、互いに別体とされており、また、上述の電極端子部材930を構成する要素接続部材931、外部配置端子部材933及び締結部材935や、ケース蓋部材913とは別に形成された後に、組み付けられている。
 このうち上部絶縁部材950は、主として電池ケース910の外部に位置し、外部配置端子部材933の固定部933eとケース蓋部材913との間、及び、締結部材935の基部935fとケース蓋部材913との間に介在して、外部配置端子部材933及び締結部材935とケース蓋部材913との間を絶縁している。また、この上部絶縁部材950は、要素接続部材931の挿通部931fとケース蓋部材913の端子挿通孔913hの内周面との間にも介在して、要素接続部材931の挿通部931fとケース蓋部材913との間を絶縁している。
The three insulating members 950, 960, and 970 are separated from each other, and the element connecting member 931, the externally arranged terminal member 933, the fastening member 935, and the case lid member 913 that constitute the electrode terminal member 930 described above. After being formed separately, it is assembled.
Of these, the upper insulating member 950 is mainly located outside the battery case 910, between the fixing portion 933 e of the externally arranged terminal member 933 and the case lid member 913, and between the base portion 935 f and the case lid member 913 of the fastening member 935. Between the externally arranged terminal member 933 and the fastening member 935 and the case lid member 913. The upper insulating member 950 is also interposed between the insertion portion 931f of the element connection member 931 and the inner peripheral surface of the terminal insertion hole 913h of the case cover member 913, and the insertion portion 931f of the element connection member 931 and the case. The lid member 913 is insulated.
 シールゴム960は、円環状をなし、要素接続部材931の挿通部931fが挿通されている。このシールゴム960は、電池ケース910の内部に位置し、ケース蓋部材913と要素接続部材931の要素接続本体部931eとの間に狭持されている。これにより、要素接続部材931の要素接続本体部931eとケース蓋部材913との間を絶縁しつつシールしている。
 下部絶縁部材970は、電池ケース910の内部に位置し、シールゴム960の径方向外側に配置されると共に、ケース蓋部材913と要素接続部材931の要素接続本体部931eとの間に配置されている。これにより、要素接続部材931の要素接続本体部931eとケース蓋部材913との間を絶縁している。
The seal rubber 960 has an annular shape, and the insertion portion 931f of the element connection member 931 is inserted therethrough. The seal rubber 960 is located inside the battery case 910 and is sandwiched between the case lid member 913 and the element connection main body 931e of the element connection member 931. Accordingly, the element connection main body 931e of the element connection member 931 and the case lid member 913 are sealed while being insulated.
The lower insulating member 970 is located inside the battery case 910, and is disposed on the radially outer side of the seal rubber 960, and is disposed between the case lid member 913 and the element connection main body 931e of the element connection member 931. . Thus, the element connection main body 931e of the element connection member 931 and the case lid member 913 are insulated.
特開2008-192595号公報JP 2008-192595 A
 上述の電池900では、電極端子部材930が3部材(要素接続部材931、外部配置端子部材933及び締結部材935)からなり、部品点数が多いため、電池の製造工程が複雑になりがちであった。また、要素接続部材931と外部配置端子部材933とを、リベット部931gによる加締めにより接続しているため、長期間に渡る使用により加締めが緩むなどして、両者間の接触抵抗が増加するおそれがあった。 In the battery 900 described above, the electrode terminal member 930 is composed of three members (the element connecting member 931, the externally arranged terminal member 933, and the fastening member 935), and the number of parts tends to be large, so that the battery manufacturing process tends to be complicated. . In addition, since the element connecting member 931 and the externally arranged terminal member 933 are connected by caulking by the rivet portion 931g, the caulking is loosened by long-term use, and the contact resistance between them increases. There was a fear.
 本発明は、かかる現状に鑑みてなされたものであって、電極端子部材の部品点数が少なく製造が容易であり、また、長期間に渡る使用でも電極端子部材に抵抗増加が生じ難く信頼性の高い電池、この電池を備える車両、及び、この電池を備える電池使用機器を提供することを目的とする。 The present invention has been made in view of such a situation, and the number of parts of the electrode terminal member is small and the manufacture is easy, and the resistance of the electrode terminal member is not easily increased even when used for a long period of time. It aims at providing a high battery, a vehicle provided with this battery, and a battery using apparatus provided with this battery.
 上記目的を達成するための、本発明の一態様は、発電要素と、開口をなし、前記発電要素を収容するケース本体部材、及び、このケース本体部材の前記開口を閉塞するケース蓋部材を有する電池ケースと、前記発電要素に接続する一方、前記ケース蓋部材に形成された端子挿通孔を通じて前記ケース蓋部材上に延出する電極端子部材と、前記電極端子部材と前記ケース蓋部材との間を絶縁する絶縁部材と、を備える電池であって、前記電極端子部材は、前記電池ケースの内部から前記端子挿通孔を通じて前記ケース蓋部材上に延出する延出部材を有し、前記延出部材は、前記発電要素に接続する要素接続部であって、前記電池ケースの内部に位置し、前記発電要素に接続する要素接続本体部、及び、この要素接続本体部に連なり、前記ケース蓋部材の前記端子挿通孔に挿通された挿通部、を含む要素接続部と、電池ケースの外部のうち前記ケース蓋部材上に位置する外部配置端子部であって、前記要素接続部の前記挿通部に連なり、前記ケース蓋部材に沿って延び、前記絶縁部材を介して前記ケース蓋部材に固定された固定部、この固定部に連なり、前記ケース蓋部材から離れる方向に延びる中間部、及び、この中間部に連なり、前記ケース蓋部材に沿って延び、自身を貫通するネジ挿通孔が形成された外部接続部、を含みZ字状をなす外部配置端子部と、を有し、前記延出部材は、所定形状の1枚の金属板材を屈曲成形して、前記要素接続部及び前記外部配置端子部を一体に形成してなる電池である。 In order to achieve the above object, one aspect of the present invention includes a power generation element, a case main body member that has an opening and accommodates the power generation element, and a case lid member that closes the opening of the case main body member. A battery case, an electrode terminal member connected to the power generation element, and extending on the case lid member through a terminal insertion hole formed in the case lid member, and between the electrode terminal member and the case lid member An insulating member that insulates the battery, wherein the electrode terminal member has an extending member that extends from the inside of the battery case through the terminal insertion hole onto the case lid member, and the extension The member is an element connection part connected to the power generation element, and is located inside the battery case, connected to the power generation element, and connected to the element connection main body part. An element connecting portion including an insertion portion inserted into the terminal insertion hole of the lid member, and an externally arranged terminal portion located on the case lid member of the outside of the battery case, wherein the insertion of the element connecting portion A fixed portion fixed to the case lid member via the insulating member, an intermediate portion connected to the fixed portion and extending in a direction away from the case lid member, and An external connection terminal portion having a Z-shape including an external connection portion that is connected to the intermediate portion, extends along the case lid member, and has a screw insertion hole penetrating through the case lid member. The member is a battery formed by bending a single metal plate having a predetermined shape and integrally forming the element connecting portion and the externally arranged terminal portion.
 上述の電池では、電極端子部材が、要素接続部及び外部配置端子部を含む延出部材を有し、この延出部材は、所定形状の1枚の金属板材を屈曲成形して、要素接続部及び外部配置端子部を一体に形成されている。このため、電極端子部材は、従来の電極端子部材に比して、部品点数が少なく、電池の製造が容易であり、また、電池を安価にすることができる。しかも、要素接続部及び外部配置端子部からなる延出部材は一体に成形されているため、長期間に渡る使用でも電極端子部材に抵抗増加が生じ難く、信頼性を向上させることができる。 In the battery described above, the electrode terminal member has an extending member including an element connecting portion and an externally arranged terminal portion, and the extending member is formed by bending a single metal plate having a predetermined shape, and the element connecting portion. And the externally arranged terminal portion is formed integrally. For this reason, an electrode terminal member has few parts compared with the conventional electrode terminal member, manufacture of a battery is easy, and can make a battery cheap. In addition, since the extending member composed of the element connecting portion and the externally arranged terminal portion is integrally formed, the resistance of the electrode terminal member is hardly increased even when used for a long time, and the reliability can be improved.
 なお、「発電要素」としては、例えば、各々長尺状をなす正極、負極及びセパレータを重ねて捲回してなる捲回型の発電要素や、各々所定形状をなす正極、負極及びセパレータを多数積層してなる積層型の発電要素などが挙げられる。
 「電池ケース」としては、角型の電池ケースや円筒型の電池ケースが挙げられる。また、「端子挿通孔」の形態としては、例えば、円状、長円状、楕円状、矩形状、多角形状や、これらを組み合わせた形状などが挙げられる。
 「絶縁部材」は、1つの電極端子部材に対して、単一の絶縁部材を用いて絶縁してもよいし、複数の絶縁部材を用いて絶縁してもよい。
In addition, as the “power generation element”, for example, a winding type power generation element obtained by winding a positive electrode, a negative electrode, and a separator each having a long shape, and a plurality of positive electrodes, negative electrodes, and separators each having a predetermined shape are stacked. And a laminated power generation element.
Examples of the “battery case” include a rectangular battery case and a cylindrical battery case. Examples of the “terminal insertion hole” include a circular shape, an oval shape, an elliptical shape, a rectangular shape, a polygonal shape, and a shape obtained by combining these.
The “insulating member” may be insulated from one electrode terminal member by using a single insulating member, or may be insulated by using a plurality of insulating members.
 更に、上記の電池であって、前記電極端子部材は、前記ケース蓋部材上に位置する締結部材を更に有し、前記締結部材は、前記ケース蓋部材に直交する方向に延びる形態に前記延出部材の前記ネジ挿通孔に挿通され、外周に雄ネジが形成された雄ネジ部と、この雄ネジ部よりも径大で、この雄ネジ部及び前記延出部材の前記外部接続部よりも前記ケース蓋部材側に位置する基部と、を有する電池とすると良い。 Further, in the battery described above, the electrode terminal member further includes a fastening member positioned on the case lid member, and the fastening member extends in a form extending in a direction orthogonal to the case lid member. A male screw part that is inserted into the screw insertion hole of the member and has a male screw formed on the outer periphery thereof, and has a diameter larger than that of the male screw part, and is greater than the male screw part and the external connection part of the extension member. A battery having a base portion located on the case lid member side is preferable.
 上述の電池では、電極端子部材が、要素接続部及び外部配置端子部を含む延出部材と、締結部材とから構成されており、このうち延出部材は、所定形状の1枚の金属板材を屈曲成形して、要素接続部及び外部配置端子部を一体に形成されている。このため、電極端子部材は、延出部材と締結部材の2部材からなり、従来の3部材からなる電極端子部材に比して、部品点数が少なく、電池の製造が容易であり、また、電池を安価にすることができる。しかも、要素接続部及び外部配置端子部からなる延出部材は一体に成形されているため、長期間に渡る使用でも電極端子部材に抵抗増加が生じ難く、信頼性を向上させることができる。 In the battery described above, the electrode terminal member is composed of an extending member including an element connecting portion and an externally arranged terminal portion, and a fastening member. Among these members, the extending member is a single metal plate having a predetermined shape. The element connecting portion and the externally arranged terminal portion are integrally formed by bending. For this reason, the electrode terminal member is composed of two members, that is, an extension member and a fastening member. The number of parts is small compared to the conventional electrode terminal member composed of three members, and the battery can be easily manufactured. Can be made cheaper. In addition, since the extending member composed of the element connecting portion and the externally arranged terminal portion is integrally formed, the resistance of the electrode terminal member is hardly increased even when used for a long time, and the reliability can be improved.
 更に、上記のいずれかに記載の電池であって、前記絶縁部材は、少なくとも、前記延出部材の前記要素接続部の前記挿通部と前記ケース蓋部材の前記端子挿通孔の内周面との間に介在し、1つの前記電極端子部材に対して単一の部材からなり、前記要素接続部と前記ケース蓋部材との間の絶縁及びシールが、この絶縁部材のみで行われてなる電池とすると良い。 Furthermore, in the battery according to any one of the above, the insulating member includes at least the insertion portion of the element connection portion of the extension member and an inner peripheral surface of the terminal insertion hole of the case lid member. A battery comprising a single member with respect to one electrode terminal member interposed therebetween, and insulation and sealing between the element connecting portion and the case lid member being performed only by this insulating member Good.
 前述した従来の電池900では、要素接続部材931とケース蓋部材913との間の絶縁及びシールを、3つの絶縁部材(上部絶縁部材950、シールゴム960及び下部絶縁部材970)を用いて行っている。このため、絶縁部材950,960,970の部品点数が多いので、電池900の製造工程が複雑になりがちであり、電池900が高価になりがちであった。
 これに対し、上述の電池では、絶縁部材が、少なくとも延出部材の要素接続部の挿通部とケース蓋部材の端子挿通孔の内周面との間にも介在する単一の部材からなり、要素接続部とケース蓋部材との間の絶縁及びシールを、この絶縁部材のみで行っている。従って、従来に比して、電池の製造が容易であり、また、電池を安価にすることができる。
In the conventional battery 900 described above, insulation and sealing between the element connecting member 931 and the case lid member 913 are performed using three insulating members (upper insulating member 950, seal rubber 960, and lower insulating member 970). . For this reason, since the number of parts of the insulating members 950, 960, and 970 is large, the manufacturing process of the battery 900 tends to be complicated, and the battery 900 tends to be expensive.
On the other hand, in the battery described above, the insulating member is composed of a single member interposed between at least the insertion portion of the element connection portion of the extending member and the inner peripheral surface of the terminal insertion hole of the case lid member, Insulation and sealing between the element connecting portion and the case lid member are performed only by this insulating member. Therefore, as compared with the conventional case, the battery can be easily manufactured and the battery can be made inexpensive.
 更に、上記の電池であって、前記絶縁部材は、前記延出部材、前記締結部材及び前記ケース蓋部材を用いたインサート成形によって成形されてなり、少なくとも、前記延出部材の前記固定部と前記ケース蓋部材の表面との間、及び、前記締結部材の前記基部と前記ケース蓋部材の前記表面との間に介在しつつこれらに接合しており、前記絶縁部材、前記延出部材、前記締結部材及び前記ケース蓋部材が、1つの部材として取り扱い可能な形態とされてなる電池とすると良い。 Further, in the above battery, the insulating member is formed by insert molding using the extending member, the fastening member, and the case lid member, and at least the fixing portion of the extending member and the The insulating member, the extending member, and the fastening member are joined to the surface of the case lid member and between the base portion of the fastening member and the surface of the case lid member while being joined thereto. The member and the case lid member may be a battery that can be handled as one member.
 前述した従来の電池900では、電極端子部材930を構成する各部材(要素接続部材931、外部配置端子部材933及び締結部材935)と、ケース蓋部材913と、3つの絶縁部材(上部絶縁部材950、シールゴム960及び下部絶縁部材970)をそれぞれ別に形成した後に、これら7部材を組み付けていた(図11参照)。 In the conventional battery 900 described above, each member constituting the electrode terminal member 930 (element connecting member 931, externally arranged terminal member 933 and fastening member 935), a case lid member 913, and three insulating members (upper insulating member 950). The seal rubber 960 and the lower insulating member 970) were separately formed, and then these seven members were assembled (see FIG. 11).
 これに対し、上述の電池では、絶縁部材が、延出部材、締結部材及びケース蓋部材を用いたインサート成形によって成形されており、絶縁部材、延出部材、締結部材及びケース蓋部材が、1つの部材として取り扱い可能な形態とされている。このため、従来に比して、各部品の洗浄や取り扱いが容易であり、また、電池の製造も容易である。
 また、延出部材、締結部材及びケース蓋部材のうち、インサート成形により形成した絶縁部材に覆われている部分については、金属の露出が抑制されるので、取り扱い時に金属粉など金属異物が生じるのを従来よりも抑制できる。
In contrast, in the battery described above, the insulating member is formed by insert molding using the extending member, the fastening member, and the case lid member, and the insulating member, the extending member, the fastening member, and the case lid member are 1 It can be handled as one member. For this reason, compared with the past, each component can be easily cleaned and handled, and the battery can be easily manufactured.
Further, among the extension member, the fastening member, and the case lid member, since the metal exposure of the portion covered by the insulating member formed by insert molding is suppressed, metal foreign matters such as metal powder are generated during handling. Can be suppressed more than before.
 「絶縁部材」は、例えば樹脂により形成できる。具体的には、耐電解液性に優れた材料が好ましく、例えば、PPSやPE、PPなどの樹脂の単一材料、或いは、複数種の樹脂を含む複合材料を用いて、絶縁部材を形成すればよい。
 延出部材、締結部材及びケース蓋部材と絶縁部材との接合方法としては、ナノレベルのアンカー効果を利用した接合方法、シランカップリング剤や有機めっきを利用した接合方法などが挙げられる。
The “insulating member” can be formed of, for example, a resin. Specifically, a material excellent in resistance to electrolytic solution is preferable. For example, the insulating member may be formed using a single material of a resin such as PPS, PE, or PP, or a composite material including a plurality of types of resins. That's fine.
Examples of the joining method of the extending member, the fastening member, the case lid member, and the insulating member include a joining method using a nano-level anchor effect, a joining method using a silane coupling agent or organic plating, and the like.
 更に、上記のいずれかに記載の電池であって、前記ケース蓋部材を平面視して、前記端子挿通孔の中心と前記締結部材の前記雄ネジ部の中心とを結ぶ方向を第1方向とし、この第1方向に直交する方向を第2方向としたとき、前記端子挿通孔は、前記第1方向に沿う第1寸法が、前記第2方向に沿う第2寸法よりも大きい形態とされてなる電池とすると良い。 Furthermore, in the battery according to any one of the above, the first direction is a direction connecting the center of the terminal insertion hole and the center of the male screw portion of the fastening member in plan view of the case lid member. When the direction orthogonal to the first direction is the second direction, the terminal insertion hole has a first dimension along the first direction larger than a second dimension along the second direction. It is better to use
 上述の電池では、この端子挿通孔が、その第1方向に沿う第1寸法が第2方向に沿う第2寸法よりも大きい形態とされている。このため、延出部材の外部接続部にバスバー等の外部の接続端子を当接させ、締結部材の雄ネジ部にナット等を締結する際に、絶縁部材がケース蓋部材に対して回転することを効果的に防止できる。 In the battery described above, the terminal insertion hole is configured such that the first dimension along the first direction is larger than the second dimension along the second direction. For this reason, when an external connection terminal such as a bus bar is brought into contact with the external connection portion of the extending member, and the nut or the like is fastened to the male screw portion of the fastening member, the insulating member rotates relative to the case lid member. Can be effectively prevented.
 更に、上記のいずれかに記載の電池であって、前記延出部材の前記固定部は、前記ケース蓋部材側を向く固定部裏面と、前記ケース蓋部材側とは逆側を向く固定部表面とを有する板状をなし、前記固定部表面の少なくとも一部が、前記絶縁部材に覆われることなく、電池外部に露出してなる電池とすると良い。 Furthermore, in the battery according to any one of the above, the fixing portion of the extending member includes a fixing portion back surface facing the case lid member side, and a fixing portion surface facing the case lid member side. It is preferable that the battery has a plate shape and at least a part of the surface of the fixing portion is exposed to the outside of the battery without being covered with the insulating member.
 上述の電池では、延出部材の固定部のうち、固定部表面の少なくとも一部が、絶縁部材に覆われることなく、電池外部に露出している。このため、この固定部表面の露出部分から、電極端子部材の熱(例えば、電池内部で生じて電極端子部材に伝わった熱や、電極端子部材自身に生じる抵抗で生じた熱など)を放熱できるので、電極端子部材の温度が上昇することにより生じる不具合(例えば、絶縁部材が熱により劣化してシール性が低下するなど)を抑制できる。
 なお、上記の放熱性の点から、固定部表面の全面が、絶縁部材に覆われることなく、電池外部に露出してなるのが特に好ましい。
In the battery described above, at least a part of the surface of the fixed portion of the extending portion of the extending member is exposed to the outside of the battery without being covered with the insulating member. For this reason, heat of the electrode terminal member (for example, heat generated inside the battery and transmitted to the electrode terminal member, heat generated by resistance generated in the electrode terminal member itself, etc.) can be radiated from the exposed portion of the surface of the fixed portion. Therefore, it is possible to suppress problems caused by an increase in the temperature of the electrode terminal member (for example, the insulating member is deteriorated by heat and the sealing performance is lowered).
In addition, it is particularly preferable that the entire surface of the fixed portion is exposed to the outside of the battery without being covered with the insulating member, from the viewpoint of heat dissipation.
 更に、上記の電池であって、前記延出部材の前記中間部は、前記固定部の前記固定部表面に連なる中間部表面と、前記固定部裏面に連なる中間部裏面とを有する板状をなし、前記中間部表面の少なくとも一部が、前記絶縁部材に覆われることなく、電池外部に露出してなる電池とすると良い。 Further, in the battery described above, the intermediate portion of the extending member has a plate shape having an intermediate portion surface continuous with the fixed portion surface of the fixed portion and an intermediate portion rear surface continuous with the fixed portion rear surface. It is preferable that the battery is formed by exposing at least a part of the surface of the intermediate portion to the outside of the battery without being covered with the insulating member.
 上述の電池では、延出部材の中間部のうち、中間部表面の少なくとも一部が、絶縁部材に覆われることなく、電池外部に露出している。このため、前述の固定部表面の露出部分だけでなく、この中間部表面の露出部分からも、電極端子部材の熱を放熱できるので、電極端子部材の温度が上昇することにより生じる不具合を更に効果的に抑制できる。
 なお、上記の放熱性の点から、中間部表面の全面が、絶縁部材に覆われることなく、電池外部に露出してなるのが特に好ましい。
In the battery described above, at least a part of the surface of the intermediate portion of the intermediate portion of the extending member is exposed to the outside of the battery without being covered with the insulating member. For this reason, since the heat of the electrode terminal member can be dissipated not only from the exposed portion of the surface of the fixed portion described above but also from the exposed portion of the surface of the intermediate portion, the problem caused by the temperature rise of the electrode terminal member is further effective. Can be suppressed.
In addition, it is particularly preferable that the entire surface of the intermediate portion is exposed to the outside of the battery without being covered with the insulating member, from the viewpoint of heat dissipation.
 更に、上記のいずれかに記載の電池であって、前記延出部材の前記外部接続部は、前記ケース蓋部材側を向く接続部裏面と、前記ケース蓋部材側とは逆側を向く接続部表面とを有する板状をなし、前記接続部表面が、前記絶縁部材に覆われることなく、電池外部に露出してなる電池とすると良い。 Furthermore, in the battery according to any one of the above, the external connection portion of the extending member includes a connection portion rear surface facing the case lid member side and a connection portion facing the opposite side to the case lid member side. It is preferable that the battery has a plate shape having a surface, and the surface of the connecting portion is exposed to the outside of the battery without being covered with the insulating member.
 上述の電池では、延出部材の外部接続部のうち、接続部表面は、絶縁部材に覆われることなく、電池外部に露出している。このため、この接続部表面に、バスバー等の外部の接続端子を当接させ、締結部材の雄ネジ部にナット等を締結する際に、接続部表面と外部の接続端子との間に絶縁部材が挟まることがないので、接続部表面と外部の接続端子との電気的接続を確実なものとすることができる。 In the battery described above, the surface of the connection portion of the external connection portion of the extending member is exposed to the outside of the battery without being covered with the insulating member. For this reason, when an external connection terminal such as a bus bar is brought into contact with the surface of the connection portion and a nut or the like is fastened to the male screw portion of the fastening member, an insulating member is provided between the connection portion surface and the external connection terminal. Therefore, the electrical connection between the surface of the connecting portion and the external connection terminal can be ensured.
 また、本発明の他の態様は、上記のいずれかに記載の前記電池を搭載し、この電池による電気エネルギーを動力源の全部または一部に使用する車両である。 Further, another aspect of the present invention is a vehicle on which the battery according to any one of the above is mounted and electric energy generated by the battery is used for all or a part of a power source.
 前述の電池は、電極端子部材の部品点数が少なく、電池の製造が容易であり、また、電池を安価にすることができる。従って、この電池を搭載する車両を安価にすることができる。また、前述の電池は、長期間に渡る使用でも電極端子部材に抵抗増加が生じ難く、信頼性が高いので、この電池を搭載する車両の信頼性を向上させることができる。
 なお、「車両」としては、例えば、電気自動車、ハイブリッド自動車、プラグインハイブリッド自動車、ハイブリッド鉄道車両、フォークリフト、電気車いす、電動アシスト自転車、電動スクータなどが挙げられる。
The battery described above has a small number of parts for the electrode terminal member, is easy to manufacture, and can be made inexpensive. Therefore, a vehicle equipped with this battery can be made inexpensive. In addition, since the above-described battery hardly increases resistance in the electrode terminal member even when used for a long period of time and has high reliability, the reliability of the vehicle on which the battery is mounted can be improved.
Examples of the “vehicle” include an electric vehicle, a hybrid vehicle, a plug-in hybrid vehicle, a hybrid railway vehicle, a forklift, an electric wheelchair, an electrically assisted bicycle, and an electric scooter.
 また、本発明の他の態様は、上記のいずれかに記載の前記電池を搭載し、この電池をエネルギー源の少なくとも1つとして使用する電池使用機器である。 Further, another aspect of the present invention is a battery-using device that includes the battery described above and uses the battery as at least one energy source.
 前述の電池は、電極端子部材の部品点数が少なく、電池の製造が容易であり、また、電池を安価にすることができる。従って、この電池を搭載する電池使用機器を安価にすることができる。また、前述の電池は、長期間に渡る使用でも電極端子部材に抵抗増加が生じ難く、信頼性が高いので、この電池を搭載する電池使用機器の信頼性を向上させることができる。
 なお、「電池搭載機器」としては、例えば、パーソナルコンピュータ、携帯電話、電池駆動の電動工具、無停電電源装置など、電池で駆動される各種の家電製品、オフィス機器、産業機器などが挙げられる。
The battery described above has a small number of parts for the electrode terminal member, is easy to manufacture, and can be made inexpensive. Therefore, the battery using apparatus which mounts this battery can be made cheap. In addition, the above-described battery is less likely to increase resistance in the electrode terminal member even when used for a long period of time, and has high reliability. Therefore, it is possible to improve the reliability of the battery-using device on which the battery is mounted.
Examples of the “battery-equipped device” include various home appliances driven by a battery such as a personal computer, a mobile phone, a battery-driven electric tool, and an uninterruptible power supply, office equipment, and industrial equipment.
実施形態1に係るリチウム二次電池の縦断面図である。1 is a longitudinal sectional view of a lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池のうち、電極端子部材、ケース蓋部材及び絶縁部材を示す分解斜視図である。3 is an exploded perspective view showing an electrode terminal member, a case lid member, and an insulating member in the lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池のうち、一体化された状態の電極端子部材、ケース蓋部材及び絶縁部材を示す斜視図である。4 is a perspective view showing an electrode terminal member, a case lid member, and an insulating member in an integrated state in the lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池の一体化された状態の電極端子部材、ケース蓋部材及び絶縁部材のうち、締結部材近傍を拡大して示す部分拡大斜視図である。FIG. 3 is a partially enlarged perspective view showing an enlarged vicinity of a fastening member among an electrode terminal member, a case lid member, and an insulating member in an integrated state of the lithium secondary battery according to Embodiment 1. 実施形態1に係るリチウム二次電池の一体化された状態の電極端子部材、ケース蓋部材及び絶縁部材のうち、安全弁近傍を拡大して示す部分拡大斜視図である。FIG. 2 is a partially enlarged perspective view showing an enlarged vicinity of a safety valve among an electrode terminal member, a case lid member, and an insulating member in an integrated state of the lithium secondary battery according to Embodiment 1. 温湿度サイクルと導通抵抗との関係を示すグラフである。It is a graph which shows the relationship between a temperature / humidity cycle and conduction resistance. 露出面積と延出部材の温度との関係を示すグラフである。It is a graph which shows the relationship between an exposed area and the temperature of an extending member. 実施形態2に係る車両を示す説明図である。FIG. 6 is an explanatory diagram showing a vehicle according to a second embodiment. 実施形態3に係るハンマードリルを示す説明図である。It is explanatory drawing which shows the hammer drill which concerns on Embodiment 3. FIG. 従来技術に係る電池の電極端子部材近傍の形態を示す縦断面図である。It is a longitudinal cross-sectional view which shows the form of the electrode terminal member vicinity of the battery which concerns on a prior art. 従来技術に係る電池の電極端子部材、ケース蓋部材及び絶縁部材を示す分解斜視図である。It is a disassembled perspective view which shows the electrode terminal member of the battery which concerns on a prior art, a case cover member, and an insulating member.
符号の説明Explanation of symbols
100 リチウム二次電池(電池)
110 電池ケース
111 ケース本体部材
111h 開口
113 ケース蓋部材
113h 端子挿通孔
120 電極体(発電要素)
130 正極電極端子部材(電極端子部材)
131 要素接続部
131e 要素接続本体部
131f 挿通部
133 外部配置端子部
133e 固定部
133f 中間部
133g 外部接続部
133gh ネジ挿通孔
135 締結部材
135e 雄ネジ部
135f 基部
137 延出部材
140 負極電極端子部材(電極端子部材)
150 絶縁部材
700 車両
710 組電池(電池)
800 ハンマードリル(電池搭載機器)
810 バッテリパック(電池)
A1 第1寸法
A2 第2寸法
G1 (端子挿通孔の)中心
G2 (雄ネジ部の)中心
H1 第1方向
H2 第2方向
100 Lithium secondary battery (battery)
110 Battery case 111 Case body member 111h Opening 113 Case lid member 113h Terminal insertion hole 120 Electrode body (power generation element)
130 Positive Electrode Terminal Member (Electrode Terminal Member)
131 Element connection portion 131e Element connection main body portion 131f Insertion portion 133 Externally arranged terminal portion 133e Fixing portion 133f Intermediate portion 133g External connection portion 133gh Screw insertion hole 135 Fastening member 135e Male screw portion 135f Base portion 137 Extension member 140 Negative electrode terminal member ( Electrode terminal member)
150 Insulating member 700 Vehicle 710 Assembly battery (battery)
800 Hammer drill (Battery-equipped equipment)
810 Battery pack (battery)
A1 First dimension A2 Second dimension G1 Center G2 (of the terminal insertion hole) Center H1 (of the external thread) H1 First direction H2 Second direction
(実施形態1)
 以下、本発明の実施の形態を、図面を参照しつつ説明する。図1に、本実施形態1のリチウム二次電池(電池)100の縦断面図を示す。また、図2~図4に、このリチウム二次電池100を構成する正極電極端子部材130及び負極電極端子部材140等の詳細を示す。また、図5に、このリチウム二次電池100の安全弁部113j近傍を示す。なお、これら図1~図5における上方をリチウム二次電池100の上側、下方をリチウム二次電池100の下側として説明する。
(Embodiment 1)
Hereinafter, embodiments of the present invention will be described with reference to the drawings. In FIG. 1, the longitudinal cross-sectional view of the lithium secondary battery (battery) 100 of this Embodiment 1 is shown. 2 to 4 show details of the positive electrode terminal member 130, the negative electrode terminal member 140, and the like constituting the lithium secondary battery 100. FIG. FIG. 5 shows the vicinity of the safety valve portion 113j of the lithium secondary battery 100. 1 to 5 will be described as the upper side of the lithium secondary battery 100 and the lower side as the lower side of the lithium secondary battery 100.
 このリチウム二次電池100は、ハイブリッドカー、電気自動車等の車両や、ハンマードリル等の電池使用機器に搭載される角型電池である。リチウム二次電池100は、角型の電池ケース110、この電池ケース100内に収容された電極体(発電要素)120、この電極体120を包囲しつつ電池ケース110内に収容された絶縁フィルム包囲体125、電池ケース110に支持された2つの電極端子部材130,140、電池ケース110と電極端子部材130,140との間を絶縁する絶縁部材150等から構成されている。また、電池ケース110の内部には、電解液が注入されている。 The lithium secondary battery 100 is a prismatic battery that is mounted on a vehicle such as a hybrid car or an electric vehicle, or a battery using device such as a hammer drill. The lithium secondary battery 100 includes a rectangular battery case 110, an electrode body (power generation element) 120 housed in the battery case 100, and an insulating film enclosed in the battery case 110 while surrounding the electrode body 120. The body 125, two electrode terminal members 130 and 140 supported by the battery case 110, an insulating member 150 for insulating between the battery case 110 and the electrode terminal members 130 and 140, and the like. In addition, an electrolytic solution is injected into the battery case 110.
 このうち、電池ケース110は、金属(具体的には純アルミニウム)からなり、直方体状に形成されている。この電池ケース110は、上側のみが開口した箱状をなし、後述する電極体120を収容するケース本体部材111と、このケース本体部材111の開口111hを閉塞する形態で溶接された矩形板状のケース蓋部材113とから構成されている。
 ケース本体部材111は、ケース蓋部材113に対向する矩形板状のケース底壁部111bと、ケース蓋部材113とケース底壁部111bとの間を結ぶ矩形板状の4つのケース側壁部111c,111c,…とからなる。
Among these, the battery case 110 is made of metal (specifically, pure aluminum) and is formed in a rectangular parallelepiped shape. The battery case 110 has a box shape in which only the upper side is opened. The battery case 110 has a rectangular shape that is welded in a form that closes an opening 111h of the case body member 111 and a case body member 111 that houses an electrode body 120 described later. And a case lid member 113.
The case body member 111 includes a rectangular plate-like case bottom wall portion 111b facing the case lid member 113, and four rectangular plate-like case side wall portions 111c connecting the case lid member 113 and the case bottom wall portion 111b, 111c,...
 ケース蓋部材113のうち、その長手方向(図1~図5中、左右方向)の両端近傍の所定位置には、このケース蓋部材113を貫通する所定形状の端子挿通孔113h,113hがそれぞれ形成されている。一方の端子挿通孔113h(図1及び図2中、左側)には、後述する正極電極端子部材130及び絶縁部材150が挿通され、他方の端子挿通孔113h(図1及び図2中、右側)には、後述する負極電極端子部材140及び絶縁部材150が挿通されている。 In the case lid member 113, terminal insertion holes 113h and 113h having predetermined shapes penetrating the case lid member 113 are formed at predetermined positions near both ends in the longitudinal direction (left and right direction in FIGS. 1 to 5). Has been. A positive electrode terminal member 130 and an insulating member 150 described later are inserted into one terminal insertion hole 113h (left side in FIGS. 1 and 2), and the other terminal insertion hole 113h (right side in FIGS. 1 and 2). A negative electrode terminal member 140 and an insulating member 150, which will be described later, are inserted through the electrode.
 ここで、ケース蓋部材113を平面視して、端子挿通孔113hの中心G1と、後述する締結部材135の雄ネジ部135eの中心G2とを結ぶ方向を第1方向H1とし(図2参照)、この第1方向H1に直交する方向を第2方向H2とする。本実施形態1では、この第1方向H1はケース蓋部材113の長手方向であり、第2方向H2はケース蓋部材113の短手方向である。すると、この端子挿通孔113hは、その第1方向H1に沿う第1寸法A1が第2方向H2に沿う第2寸法A2よりも大きい形態とされている。 Here, in a plan view of the case lid member 113, a direction connecting a center G1 of the terminal insertion hole 113h and a center G2 of a male screw portion 135e of the fastening member 135 described later is a first direction H1 (see FIG. 2). The direction orthogonal to the first direction H1 is defined as a second direction H2. In the first embodiment, the first direction H1 is the longitudinal direction of the case lid member 113, and the second direction H2 is the short direction of the case lid member 113. Then, the terminal insertion hole 113h is configured such that the first dimension A1 along the first direction H1 is larger than the second dimension A2 along the second direction H2.
 具体的には、この端子挿通孔113hは、第1方向H1に細長い平面視矩形状の第1開口部113h1と、この第1開口部113h1よりケース蓋部材113の中央側に位置し、第1方向H1に細長く、第1開口部113h1よりも小さい平面視矩形状の第2開口部113h2とからなる。本実施形態1では、この端子挿通孔113hの第1寸法はA1=22mmであり、第2寸法はA2=7mmである。 Specifically, the terminal insertion hole 113h is a first opening 113h1 that is rectangular in plan view and is elongated in the first direction H1, and is located closer to the center side of the case lid member 113 than the first opening 113h1. The second opening 113h2 is elongated in the direction H1 and has a rectangular shape in plan view that is smaller than the first opening 113h1. In the first embodiment, the first dimension of the terminal insertion hole 113h is A1 = 22 mm, and the second dimension is A2 = 7 mm.
 ケース蓋部材113の長手方向中央には、安全弁部113jが設けられている。この安全弁部113jは、ケース蓋部材113と一体的に形成されてケース蓋部材113の一部をなす。安全弁部113jは、ケース蓋部材113の他の部分よりも薄く薄膜状(厚み110±30μm)に形成されると共に、その上側にはV字溝を有し、厚み45±30μmと特に薄くされた破断部113jvが所定形状に形成されている。これにより、安全弁部113jは、電池ケース110内部の内圧が所定圧力に達した際に作動する。即ち、内圧が所定圧力に達したときに破断部113jvが破断して、電池内部のガスを電池外部に放出する。 A safety valve portion 113j is provided in the center of the case lid member 113 in the longitudinal direction. The safety valve portion 113j is formed integrally with the case lid member 113 and forms a part of the case lid member 113. The safety valve portion 113j is formed in a thin film shape (thickness 110 ± 30 μm) thinner than other portions of the case lid member 113, and has a V-shaped groove on the upper side thereof, and is particularly thin as 45 ± 30 μm. The breaking portion 113jv is formed in a predetermined shape. As a result, the safety valve portion 113j operates when the internal pressure inside the battery case 110 reaches a predetermined pressure. That is, when the internal pressure reaches a predetermined pressure, the breaking portion 113jv breaks and releases the gas inside the battery to the outside of the battery.
 また、この安全弁部113j上には、PPS樹脂からなる薄膜状の樹脂膜115が被着形成されている(図2、図3及び図5参照)。安全弁部113jは薄く形成され、破断部113jvは特に薄く形成されているので、酸化により穴が生じるなど破損するおそれがある。しかし、安全弁部113j上に樹脂膜115を形成することにより、安全弁部113jが外部から保護されるので、安全弁部113jに破損が生じることを効果的に防止できる。なお、この樹脂膜115は、後述するように絶縁部材150をインサート形成する際に同時に形成しているので、安全弁部113j上に保護シールなどを貼り付ける場合に比して、材料費や製造コストを削減できる。 In addition, a thin resin film 115 made of PPS resin is deposited on the safety valve portion 113j (see FIGS. 2, 3 and 5). Since the safety valve portion 113j is formed thin and the break portion 113jv is formed particularly thin, there is a risk of damage such as a hole formed by oxidation. However, since the safety valve portion 113j is protected from the outside by forming the resin film 115 on the safety valve portion 113j, it is possible to effectively prevent the safety valve portion 113j from being damaged. Since the resin film 115 is formed at the same time as the insert forming of the insulating member 150 as will be described later, the material cost and the manufacturing cost are compared with the case of attaching a protective seal or the like on the safety valve portion 113j. Can be reduced.
  また、ケース蓋部材113の長手方向中央よりも負極電極端子部材140側の所定位置には、電解液を電池ケース110内に注入する為の注液口部113mが設けられている。
 なお、ケース蓋部材113の全面には、インサート成形により形成される後述する絶縁部材150との接合性を向上させるために、有機めっきが施されている。
In addition, a liquid injection port portion 113 m for injecting the electrolyte into the battery case 110 is provided at a predetermined position on the negative electrode terminal member 140 side from the longitudinal center of the case lid member 113.
Note that the entire surface of the case lid member 113 is subjected to organic plating in order to improve the bondability with an insulating member 150 described later formed by insert molding.
 図1に示すように、電池ケース110の内部には、自身の軸方向に(図1中、左右方向)に直交する横断面が長円形状をなす捲回型の電極体120が、横倒しにした状態で、即ち、電極体120の軸方向が、ケース本体部材111の2つのケース側壁部111c,111cと直交する状態で、収容されている。この電極体120の軸方向の両端には、正極電極端子部材130の要素接続部131及び負極電極端子部材140の要素接続部131が接続されている。 As shown in FIG. 1, in the battery case 110, a wound electrode body 120 having an elliptical cross section orthogonal to its own axial direction (left and right direction in FIG. 1) is laid down. In other words, the electrode body 120 is accommodated in a state in which the axial direction of the electrode body 120 is orthogonal to the two case side wall portions 111 c and 111 c of the case body member 111. The element connection part 131 of the positive electrode terminal member 130 and the element connection part 131 of the negative electrode terminal member 140 are connected to both ends of the electrode body 120 in the axial direction.
 この電極体120は、正極シートと負極シートとをセパレータを介して重ねて捲回し、扁平状に圧縮したものである。正極シートは、長尺状アルミニウム箔からなる正極集電体を有する。この正極集電体の両面には、正極活物質を含む正極活物質層が形成されている。また、負極シートは、長尺状銅箔からなる負極集電体を有する。この負極集電体の両面には、負極活物質を含む負極活物質層が形成されている。セパレータは、多孔質のポリプロピレン樹脂シートからなる。
 この電極体120は、絶縁フィルムを上側のみが開口した箱状に折り曲げ、所定部位を溶着して形成した絶縁フィルム包囲体125に、自身の上側を除いて全体的に包囲されている。
This electrode body 120 is obtained by rolling a positive electrode sheet and a negative electrode sheet with a separator interposed between them and compressing them into a flat shape. The positive electrode sheet has a positive electrode current collector made of a long aluminum foil. A positive electrode active material layer containing a positive electrode active material is formed on both surfaces of the positive electrode current collector. The negative electrode sheet has a negative electrode current collector made of a long copper foil. A negative electrode active material layer containing a negative electrode active material is formed on both surfaces of the negative electrode current collector. The separator is made of a porous polypropylene resin sheet.
The electrode body 120 is entirely surrounded by an insulating film envelope 125 formed by bending an insulating film into a box shape having an opening only on the upper side and welding a predetermined portion, except for the upper side.
 次に、正極電極端子部材130及び負極電極端子部材140について説明する(図1~図4参照)。正極電極端子部材130と負極電極端子部材140は、基本的に同様な構成であるので、これらを構成する各部材には、正極電極端子部材130と負極電極端子部材140とで同一の符号を付して説明する。
 正極電極端子部材130は、電池ケース110の内部において電極体120の正極シートと電気的かつ機械的に接続する一方、電池ケース110(ケース蓋部材113)に形成された端子挿通孔113hを通じて、電池ケース110の外部(ケース蓋部材113上)に延出している。また、負極電極端子部材140は、電池ケース110の内部において電極体120の負極シートと電気的かつ機械的に接続する一方、電池ケース110(ケース蓋部材113)に形成された端子挿通孔113hを通じて、電池ケース110の外部(ケース蓋部材113上)に延出している。
Next, the positive electrode terminal member 130 and the negative electrode terminal member 140 will be described (see FIGS. 1 to 4). Since the positive electrode terminal member 130 and the negative electrode terminal member 140 have basically the same configuration, the same reference numerals are given to the respective members constituting the positive electrode terminal member 130 and the negative electrode terminal member 140. To explain.
The positive electrode terminal member 130 is electrically and mechanically connected to the positive electrode sheet of the electrode body 120 inside the battery case 110, while the battery is passed through the terminal insertion hole 113 h formed in the battery case 110 (case lid member 113). It extends outside the case 110 (on the case lid member 113). Further, the negative electrode terminal member 140 is electrically and mechanically connected to the negative electrode sheet of the electrode body 120 inside the battery case 110, while passing through a terminal insertion hole 113 h formed in the battery case 110 (case lid member 113). The battery case 110 extends outside (on the case lid member 113).
 これらの電極端子部材130,140は、それぞれ、電池ケース110の内部から端子挿通孔113hを通じてケース蓋部材113上に延出し、要素接続部131及び外部配置端子部133からなる延出部材137と、この延出部材137に接続可能(当接可能)にケース蓋部材113上に配置された締結部材135とからなる。これら延出部材137及び締結部材135は、いずれも金属から形成されている。 Each of these electrode terminal members 130 and 140 extends from the inside of the battery case 110 through the terminal insertion hole 113h onto the case lid member 113, and includes an extending member 137 including an element connecting portion 131 and an externally arranged terminal portion 133, The fastening member 135 is disposed on the case lid member 113 so as to be connectable (contactable) to the extending member 137. Both the extending member 137 and the fastening member 135 are made of metal.
 なお、正極電極端子部材130の延出部材137は、電極体120の正極シート(アルミニウム箔)との溶接を考慮して、純アルミニウムにより形成されており、負極電極端子部材140の延出部材137は、電極体120の負極シート(銅箔)との溶接を考慮して、純銅により形成されている。また、これらの延出部材137,137の全面には、インサート成形により形成される後述する絶縁部材150との接合性を向上させるために、有機めっきが施されている。 The extending member 137 of the positive electrode terminal member 130 is made of pure aluminum in consideration of welding with the positive electrode sheet (aluminum foil) of the electrode body 120, and the extending member 137 of the negative electrode terminal member 140. Is formed of pure copper in consideration of welding of the electrode body 120 to the negative electrode sheet (copper foil). In addition, the entire surface of these extending members 137 and 137 is subjected to organic plating in order to improve the bonding property with an insulating member 150 described later formed by insert molding.
 延出部材137のうち、要素接続部131は、電池ケース110の内部に位置し、電極体120に電気的かつ機械的に接続する要素接続本体部131eと、この要素接続本体部131eに連なり、ケース蓋部材113の端子挿通孔113hに挿通された挿通部131fとからなる。
 要素接続本体部131eは、金属板材を屈曲加工した所定形状を有し、電極体120に溶接されている。
Of the extending member 137, the element connecting portion 131 is located inside the battery case 110, and is connected to the element connecting main body portion 131e that is electrically and mechanically connected to the electrode body 120, and the element connecting main body portion 131e. The insertion portion 131 f is inserted into the terminal insertion hole 113 h of the case lid member 113.
The element connection main body 131e has a predetermined shape obtained by bending a metal plate material, and is welded to the electrode body 120.
 挿通部131fは、自身の下側で要素接続本体部131eの上端131esに連なると共に、自身の上側で後述する外部配置端子部133の固定部133eに連なっている。この挿通部131fは、ケース蓋部材113の端子挿通孔113hを貫通すると共に、端子挿通孔113hの更に径方向内側において絶縁部材150を貫通している。この挿通部131fは、金属板材を屈曲加工した所定形状を有する。具体的には、挿通部131fは、要素接続本体部131eの上端131esから連なり、ケース蓋部材113に沿って、かつ、ケース蓋部材113の短手方向に板状に延びる第1板状挿通部131f1と、この第1板状挿通部131f1から連なり、ケース蓋部材113に直交する方向に沿って上方に板状に延びる第2板状挿通部131f2とからなり、L字状をなす。 The insertion portion 131f is continuous with the upper end 131es of the element connection main body portion 131e on the lower side of the insertion portion 131f, and is connected with the fixing portion 133e of the external arrangement terminal portion 133 described later on the upper side of the insertion portion 131f. The insertion portion 131f penetrates the terminal insertion hole 113h of the case lid member 113 and penetrates the insulating member 150 further radially inward of the terminal insertion hole 113h. The insertion portion 131f has a predetermined shape obtained by bending a metal plate material. Specifically, the insertion portion 131f is a first plate insertion portion that extends from the upper end 131es of the element connection main body portion 131e and extends in a plate shape along the case lid member 113 and in the lateral direction of the case lid member 113. 131f1 and a second plate insertion portion 131f2 which is continuous from the first plate insertion portion 131f1 and extends upward in a direction perpendicular to the case lid member 113, and has an L shape.
 延出部材137のうち、外部配置端子部133は、ケース蓋部材113上に位置し、固定部133eと中間部133fと外部接続部133gとからなり、Z字状(段状)をなす。
 固定部133eは、ケース蓋部材113側とは逆側(上側)を向く固定部表面133eaと、ケース蓋部材113側(下側)を向く固定部裏面113ebとを有する板状をなす。この固定部133eは、上述の要素接続部131の挿通部131fに連なり、ケース蓋部材113に沿ってかつこれに平行に延び、後述する絶縁部材150を介してケース蓋部材113に固定されている。固定部133eの固定部表面133eaは、その全面が、絶縁部材150に覆われることなく、電池外部に露出している。
Of the extending member 137, the externally arranged terminal portion 133 is located on the case lid member 113, and includes a fixed portion 133e, an intermediate portion 133f, and an external connection portion 133g, and has a Z shape (stepped shape).
The fixing part 133e has a plate shape having a fixing part surface 133ea facing the side opposite to the case lid member 113 (upper side) and a fixing part rear surface 113eb facing the case lid member 113 side (lower side). The fixing portion 133e is connected to the insertion portion 131f of the element connecting portion 131 described above, extends along and parallel to the case lid member 113, and is fixed to the case lid member 113 via an insulating member 150 described later. . The entire surface of the fixing portion surface 133ea of the fixing portion 133e is exposed to the outside of the battery without being covered with the insulating member 150.
 中間部133fは、固定部133eの固定部表面133eaに連なる中間部表面133faと、固定部裏面133ebに連なる中間部裏面133fbとを有する板状をなす。この中間部133fは、固定部133eに連なり、ケース蓋部材113から離れる方向、本実施形態1では、ケース蓋部材113に直交する方向のうち、ケース蓋部材113から離れる方向(上側)に延びている。中間部133fの中間部表面133faは、その全面が、後述する絶縁部材150に覆われることなく、電池外部に露出している。 The intermediate part 133f has a plate shape having an intermediate part surface 133fa continuous with the fixed part surface 133ea of the fixed part 133e and an intermediate part back surface 133fb continuous with the fixed part back surface 133eb. The intermediate portion 133f is connected to the fixing portion 133e, and extends in a direction away from the case lid member 113 in the direction away from the case lid member 113, in the first embodiment, in the direction perpendicular to the case lid member 113 (upper side). Yes. The entire surface of the intermediate portion 133fa of the intermediate portion 133f is exposed to the outside of the battery without being covered with an insulating member 150 described later.
 外部接続部133gは、ケース蓋部材113側とは逆側(上側)を向く接続部表面133gaと、ケース蓋部材113側(下側)を向く接続部裏面133gbとを有する板状をなす。この外部接続部133gは、中間部133fに連なり、ケース蓋部材113に沿ってかつこれに平行に延び、自身を貫通する円状のネジ挿通孔133ghが形成されている。この外部接続部133gは、その全体が、後述する絶縁部材150に覆われることなく、電池外部に露出している。この外部接続部133gの接続部表面133gaは、バスバーなどの外部の接続端子との電気的接続に利用される。 The external connection portion 133g has a plate shape having a connection portion surface 133ga facing the side opposite to the case lid member 113 (upper side) and a connection portion rear surface 133gb facing the case lid member 113 side (lower side). The external connection portion 133g is connected to the intermediate portion 133f, extends along and parallel to the case lid member 113, and is formed with a circular screw insertion hole 133gh passing therethrough. The entire external connection portion 133g is exposed outside the battery without being covered with an insulating member 150 described later. The connection portion surface 133ga of the external connection portion 133g is used for electrical connection with an external connection terminal such as a bus bar.
 従来の電池900では、前述のように、要素接続部材931と外部配置端子部材933とが別部材とされていた(図10及び図11参照)。これに対し、本実施形態1では、所定形状の1枚の金属板材を屈曲成形することにより、前述の要素接続部131及び外部配置端子部133を一体に形成して、1部材からなる延出部材137としている。 In the conventional battery 900, as described above, the element connection member 931 and the externally arranged terminal member 933 are separate members (see FIGS. 10 and 11). On the other hand, in the first embodiment, the above-described element connecting portion 131 and the externally arranged terminal portion 133 are integrally formed by bending a single metal plate having a predetermined shape, and extending from one member. The member 137 is used.
 次に、締結部材135について説明する。締結部材135は、自身の外周に雄ネジが形成された雄ネジ部135eと、これよりも径大な基部135fとからなる。
 このうち雄ネジ部135eは、ケース蓋部材113に直交する方向(上下方向)に延びる形態に延出部材137の外部接続部133gのネジ挿通孔133ghに挿通されており、上記のように外周に雄ネジが形成されている。なお、図1~図4の各図においては、雄ネジの記載を省略してある。
Next, the fastening member 135 will be described. The fastening member 135 includes a male screw portion 135e having a male screw formed on its outer periphery and a base portion 135f having a larger diameter than this.
Among these, the male screw portion 135e is inserted into the screw insertion hole 133gh of the external connection portion 133g of the extending member 137 in a form extending in a direction (vertical direction) orthogonal to the case lid member 113, and is formed on the outer periphery as described above. A male screw is formed. In FIGS. 1 to 4, the description of the male screw is omitted.
 基部135fは、円板状をなす円板部135f1と、この円板部153f1のケース蓋部材113側に位置し、円板部135f1よりも若干径小で、外形が円柱状をなす円柱部135f2とからなる(図2参照)。この基部135fは、雄ネジ部135e及び延出部材137の外部接続部133gよりもケース蓋部材113側に位置している。そして、基部135fのうち、ケース蓋部材113側とは逆側(上側)を向く基部表面135faが、延出部材137の外部接続部133gの接続部裏面133gbに当接して、締結部材135が延出部材137に電気的に接続している。 The base portion 135f is a disc-shaped disc portion 135f1 and is located on the case lid member 113 side of the disc portion 153f1, and has a columnar portion 135f2 that is slightly smaller in diameter than the disc portion 135f1 and has a cylindrical outer shape. (See FIG. 2). The base portion 135f is located closer to the case lid member 113 than the external threaded portion 135e and the external connection portion 133g of the extending member 137. Of the base portion 135f, the base surface 135fa facing the side opposite to the case lid member 113 (upper side) abuts on the connection portion back surface 133gb of the external connection portion 133g of the extension member 137, and the fastening member 135 extends. The lead member 137 is electrically connected.
 また、この基部135fには、ケース蓋部材113側とは逆側(上側)に凹み、ケース蓋部材113側(下側)を向く基部裏面135fbに開口する、平面視六角形状の凹部135fcが形成されている。そして、この凹部135fc内には、後述する絶縁部材150の突出部150fnが充填形成されている。これにより、締結部材135がその軸線周りに回転不能に、基部135fと絶縁部材150とが互いに接合している。 Further, the base portion 135f is formed with a concave portion 135fc having a hexagonal shape in plan view, which is recessed on the side (upper side) opposite to the case lid member 113 side and opened on the base rear surface 135fb facing the case lid member 113 side (lower side). Has been. In the recess 135fc, a protruding portion 150fn of an insulating member 150 described later is filled. Thereby, the base 135f and the insulating member 150 are joined to each other so that the fastening member 135 cannot rotate around the axis thereof.
 次に、電極端子部材130,140と共にケース蓋部材113に固定された絶縁部材150,150について説明する(図1~図4参照)。絶縁部材150は、電極端子部材130,140とケース蓋部材113との間に配置されて、電極端子部材130,140とケース蓋部材113とが接触して短絡することを防止している。この絶縁部材150は、樹脂(具体的にはPPS)からなり、電極端子部材130,140(延出部材137及び締結部材135)並びにケース蓋部材113を用いたインサート成形によって成形されている。これにより、絶縁部材150、延出部材137、締結部材135及びケース蓋部材113は、図3に示すように、1つの部材として取り扱いが可能となっている。 Next, the insulating members 150 and 150 fixed to the case lid member 113 together with the electrode terminal members 130 and 140 will be described (see FIGS. 1 to 4). The insulating member 150 is disposed between the electrode terminal members 130 and 140 and the case lid member 113 to prevent the electrode terminal members 130 and 140 and the case lid member 113 from contacting and short-circuiting. The insulating member 150 is made of resin (specifically, PPS), and is formed by insert molding using the electrode terminal members 130 and 140 (the extending member 137 and the fastening member 135) and the case lid member 113. Thereby, the insulating member 150, the extending member 137, the fastening member 135, and the case lid member 113 can be handled as one member as shown in FIG.
 具体的には、この絶縁部材150は、電池ケース110の内部及びケース蓋部材113の端子挿通孔113h内に位置する内部絶縁部150eと、電池ケース110の外部(ケース蓋部材113上)に位置する外部絶縁部150fとからなる。
 内部絶縁部150eは、延出部材137の要素接続部131の挿通部131fとケース蓋部材113の端子挿通孔113hの内周面113haとの間に介在してこれらに接合すると共に、電極体120とケース蓋部材113の裏面113bとの間に介在している。これにより、延出部材137の要素接続部131の挿通部131fとケース蓋部材113との間が絶縁されると共に、電極体120とケース蓋部材113との間が絶縁されている。
Specifically, the insulating member 150 is positioned inside the battery case 110 and inside the terminal insertion hole 113h of the case lid member 113, and outside the battery case 110 (on the case lid member 113). And an external insulating portion 150f.
The internal insulating portion 150e is interposed between the insertion portion 131f of the element connection portion 131 of the extending member 137 and the inner peripheral surface 113ha of the terminal insertion hole 113h of the case lid member 113, and is joined to these, and the electrode body 120 is also provided. And the back surface 113b of the case lid member 113. Accordingly, the insertion portion 131f of the element connection portion 131 of the extending member 137 and the case lid member 113 are insulated, and the electrode body 120 and the case lid member 113 are insulated.
 本実施形態1では、要素接続部131とケース蓋部材113との間の絶縁及びシールが、この絶縁部材150(具体的には内部絶縁部150e)のみで行われてなる。即ち、従来の電池900(図10及び図11)では、要素接続部材931とケース蓋部材113との間の絶縁及びシールに、3つの絶縁部材(上部絶縁部材950、シールゴム960及び下部絶縁部材970)が用いられている。これに対し、本実施形態1では、要素接続部131とケース蓋部材113との間の絶縁及びシールに、1つの絶縁部材150のみが用いられている。 In the first embodiment, the insulation and sealing between the element connecting portion 131 and the case lid member 113 are performed only by the insulating member 150 (specifically, the internal insulating portion 150e). That is, in the conventional battery 900 (FIGS. 10 and 11), three insulating members (an upper insulating member 950, a seal rubber 960, and a lower insulating member 970) are used for insulation and sealing between the element connecting member 931 and the case lid member 113. ) Is used. On the other hand, in the first embodiment, only one insulating member 150 is used for insulation and sealing between the element connecting portion 131 and the case lid member 113.
 外部絶縁部150fは、延出部材137の外部配置端子部133の固定部133eとケース蓋部材113の表面113aとの間、及び、締結部材135の基部135fとケース蓋部材113の表面113aとの間に介在してこれらに接合している。これにより、延出部材137の外部配置端子部133とケース蓋部材113との間が絶縁されると共に、締結部材135の基部135fとケース蓋部材113との間が絶縁されている。 The external insulating portion 150f is formed between the fixing portion 133e of the externally arranged terminal portion 133 of the extending member 137 and the surface 113a of the case lid member 113, and between the base portion 135f of the fastening member 135 and the surface 113a of the case lid member 113. These are joined to each other. Thus, the externally arranged terminal portion 133 of the extending member 137 and the case lid member 113 are insulated, and the base portion 135f of the fastening member 135 and the case lid member 113 are insulated.
 詳細には、外部絶縁部150fには、ケース蓋部材113側(下側)に凹み、ケース蓋部材113とは逆側(上側)に開口する凹部150fmが形成されている(図2参照)。そして、この凹部150fm内に、延出部材137の外部配置端子部133の固定部133eが収まって、外部絶縁部150fと固定部133eとが互いに接合している。また、外部絶縁部150fには、ケース蓋部材113とは逆側(上側)に突出する六角柱状の突出部150fnが設けられている。そして、この突出部150fnが、前述のように、締結部材135の基部135fの凹部135fc内に収まって、外部絶縁部150fと基部135fとが互いに接合している。 Specifically, the external insulating portion 150f is formed with a recess 150fm that is recessed on the case lid member 113 side (lower side) and that opens on the opposite side (upper side) of the case lid member 113 (see FIG. 2). And the fixing | fixed part 133e of the external arrangement | positioning terminal part 133 of the extending member 137 is settled in this recessed part 150fm, and the external insulation part 150f and the fixing | fixed part 133e are mutually joined. Further, the external insulating portion 150f is provided with a hexagonal columnar protruding portion 150fn that protrudes on the opposite side (upper side) from the case lid member 113. As described above, the projecting portion 150fn is accommodated in the recess 135fc of the base portion 135f of the fastening member 135, and the external insulating portion 150f and the base portion 135f are joined to each other.
 この絶縁部材150は、延出部材137、締結部材135及びケース蓋部材113を用いたインサート成形によって成形されているにも拘わらず、前述したように、延出部材137の固定部133eの固定部表面133eaを覆っていない。また、絶縁部材150は、延出部材137の中間部133fの中間部表面133faも覆っていない。更に、絶縁部材150は、延出部材137の外部接続部133gの接続部表面133gaも覆っていない。 Although the insulating member 150 is formed by insert molding using the extending member 137, the fastening member 135, and the case lid member 113, as described above, the fixing portion of the fixing portion 133e of the extending member 137 is fixed. It does not cover the surface 133ea. Further, the insulating member 150 does not cover the intermediate portion surface 133fa of the intermediate portion 133f of the extending member 137. Further, the insulating member 150 does not cover the connection portion surface 133ga of the external connection portion 133g of the extending member 137.
 以上で説明したように、本実施形態1のリチウム二次電池100は、電極端子部材130,140が、要素接続部131及び外部配置端子部133を含む延出部材137と、締結部材135とから構成されており、このうち延出部材137は、所定形状の1枚の金属板材を屈曲成形して、要素接続部131及び外部配置端子部133を一体に形成されている。このため、電極端子部材130,140は、それぞれ延出部材137と締結部材135の2部材からなり、従来の3部材からなる電極端子部材930に比して、部品点数が少なく、リチウム二次電池100の製造が容易であり、また、リチウム二次電池100を安価にすることができる。しかも、要素接続部131及び外部配置端子部133からなる延出部材137は一体に成形されているため、長期間に渡る使用でも電極端子部材130,140に抵抗増加が生じ難く、信頼性を向上させることができる。 As described above, in the lithium secondary battery 100 according to the first embodiment, the electrode terminal members 130 and 140 include the extending member 137 including the element connecting portion 131 and the externally arranged terminal portion 133, and the fastening member 135. Among them, the extending member 137 is formed by bending a single metal plate having a predetermined shape, and the element connecting portion 131 and the externally arranged terminal portion 133 are integrally formed. For this reason, the electrode terminal members 130 and 140 are each composed of two members, that is, an extending member 137 and a fastening member 135, and the number of parts is smaller than that of the conventional electrode terminal member 930 composed of three members, and the lithium secondary battery 100 is easy to manufacture, and the lithium secondary battery 100 can be made inexpensive. In addition, since the extending member 137 including the element connecting portion 131 and the externally arranged terminal portion 133 is integrally formed, the resistance of the electrode terminal members 130 and 140 hardly increases even when used for a long period of time, and the reliability is improved. Can be made.
 更に、本実施形態1では、絶縁部材150が、延出部材137の要素接続部131の挿通部131fとケース蓋部材113の端子挿通孔113hの内周面113haとの間に介在して、要素接続部131とケース蓋部材113との間の絶縁及びシールを、この絶縁部材150のみで行っている。従って、従来に比して、リチウム二次電池100の製造が容易であり、また、リチウム二次電池100を安価にすることができる。 Furthermore, in the first embodiment, the insulating member 150 is interposed between the insertion portion 131f of the element connection portion 131 of the extending member 137 and the inner peripheral surface 113ha of the terminal insertion hole 113h of the case lid member 113, so that the element Insulation and sealing between the connecting portion 131 and the case lid member 113 are performed only by the insulating member 150. Therefore, the lithium secondary battery 100 can be easily manufactured as compared with the conventional case, and the lithium secondary battery 100 can be made inexpensive.
 また、本実施形態1では、絶縁部材150が、延出部材137、締結部材135及びケース蓋部材113を用いたインサート成形によって形成されており、絶縁部材150、延出部材137、締結部材135及びケース蓋部材113が、1つの部材として取り扱い可能となっている。このため、7つの部材931,933,935,913,950,960,970を別個に取り扱っていた従来に比して、また、部品の洗浄や取り扱いが容易であり、また、リチウム二次電池100の製造が容易である。
 また、延出部材137、締結部材135及びケース蓋部材113のうち、インサート成形により形成した絶縁部材150に覆われている部分については、金属の露出が抑制されるので、取り扱い時に金属粉などの金属異物が生じるのを従来よりも抑制できる。
In the first embodiment, the insulating member 150 is formed by insert molding using the extending member 137, the fastening member 135, and the case lid member 113, and the insulating member 150, the extending member 137, the fastening member 135, and the like. The case lid member 113 can be handled as one member. For this reason, compared with the conventional case in which the seven members 931, 933, 935, 913, 950, 960, and 970 are handled separately, the parts can be easily cleaned and handled, and the lithium secondary battery 100 Is easy to manufacture.
Moreover, since the metal exposure is suppressed about the part covered with the insulating member 150 formed by insert molding among the extending member 137, the fastening member 135, and the case lid member 113, metal powder or the like is used during handling. The occurrence of metallic foreign matter can be suppressed more than before.
 また、本実施形態1では、ケース蓋部材113に形成された端子挿通孔113hが、その第1方向H1に沿う第1寸法A1が第2方向H2に沿う第2寸法A2よりも大きい形態とされている。このため、延出部材137の外部接続部133gにバスバー等の外部の接続端子を当接させ、締結部材135の雄ネジ部135eにナット等を締結する際に、締結部材135の基部135fと固定された絶縁部材150が、ケース蓋部材113に対して回転することを効果的に防止できる。 In the first embodiment, the terminal insertion hole 113h formed in the case lid member 113 is configured such that the first dimension A1 along the first direction H1 is larger than the second dimension A2 along the second direction H2. ing. Therefore, when an external connection terminal such as a bus bar is brought into contact with the external connection portion 133g of the extending member 137 and a nut or the like is fastened to the male screw portion 135e of the fastening member 135, the base portion 135f of the fastening member 135 is fixed. The insulating member 150 thus made can be effectively prevented from rotating with respect to the case lid member 113.
 また、本実施形態1では、絶縁部材150がインサート成形により形成されているにも拘わらず、延出部材137の固定部133eの固定部表面133eaは、その全面が、絶縁部材150に覆われることなく、電池外部に露出している。このため、この固定部表面133eaから、電極端子部材130,140の熱(例えば、電池内部で生じて電極端子部材130,140に伝わった熱や、電極端子部材130,140自身に生じる抵抗で生じた熱など)を放熱できるので、電極端子部材130,140の温度が上昇することにより生じる不具合(例えば、絶縁部材150が熱により劣化してシール性が低下するなど)を抑制できる。 In the first embodiment, the entire surface of the fixing portion surface 133ea of the fixing portion 133e of the extending member 137 is covered with the insulating member 150, although the insulating member 150 is formed by insert molding. Not exposed to the outside of the battery. For this reason, heat is generated from the fixed portion surface 133ea by the heat of the electrode terminal members 130 and 140 (for example, heat generated inside the battery and transmitted to the electrode terminal members 130 and 140, and resistance generated in the electrode terminal members 130 and 140 themselves). Heat, etc.) can be dissipated, so that it is possible to suppress problems that occur when the temperature of the electrode terminal members 130 and 140 rises (for example, the insulating member 150 deteriorates due to heat and the sealing performance decreases).
 また、本実施形態1では、絶縁部材150がインサート成形により形成されているにも拘わらず、延出部材137の中間部133fの中間部表面133faも、その全面が、絶縁部材150に覆われることなく、電池外部に露出している。このため、固定部表面133eaだけでなく、この中間部表面133faからも、電極端子部材130,140の熱を放熱できるので、電極端子部材130,140の温度が上昇することにより生じる不具合を更に効果的に抑制できる。 In the first embodiment, the entire surface of the intermediate portion 133fa of the intermediate portion 133f of the extending member 137 is covered with the insulating member 150 even though the insulating member 150 is formed by insert molding. Not exposed to the outside of the battery. For this reason, since the heat of the electrode terminal members 130 and 140 can be radiated not only from the fixed portion surface 133ea but also from the intermediate portion surface 133fa, the problem caused by the temperature rise of the electrode terminal members 130 and 140 is further effective. Can be suppressed.
 また、本実施形態1では、絶縁部材150がインサート成形により形成されているにも拘わらず、延出部材137の外部接続部133gの接続部表面133gaは、絶縁部材150に覆われることなく、電池外部に露出している。このため、この接続部表面133gaに、バスバー等の外部の接続端子を当接させ、締結部材135の雄ネジ部135eにナット等を締結する際に、接続部表面133gaと外部の接続端子との間に絶縁部材150が挟まることがないので、接続部表面133gaと外部の接続端子との電気的接続を確実なものとすることができる。 Further, in the first embodiment, although the insulating member 150 is formed by insert molding, the connection portion surface 133ga of the external connection portion 133g of the extending member 137 is not covered with the insulating member 150, and the battery Exposed outside. For this reason, when connecting an external connection terminal such as a bus bar to the connection portion surface 133ga and fastening a nut or the like to the male screw portion 135e of the fastening member 135, the connection portion surface 133ga and the external connection terminal are connected to each other. Since the insulating member 150 is not sandwiched between them, the electrical connection between the connection portion surface 133ga and the external connection terminal can be ensured.
 次いで、上記リチウム二次電池100の製造方法について説明する。
 所定形状の1枚の金属板材を屈曲成形した延出部材137を用意する。また、締結部材135及びケース蓋部材113を用意する。そして、これらの部材137,135,113を用いた樹脂インサート成形により、絶縁部材150を形成する。具体的には、延出部材137、締結部材135及びケース蓋部材113を金型にセットし、溶融した成形樹脂をこの金型内に射出して、絶縁部材150を形成する。これにより、図3に示すように、絶縁部材150,150、延出部材137,137、締結部材135,135及びケース蓋部材113が、1つの部材として取り扱い可能なサブアッセイができる。なお、このインサート成形の際に、ケース蓋部材113の安全弁部113j上に樹脂膜115を同時に形成する。
Next, a method for manufacturing the lithium secondary battery 100 will be described.
An extending member 137 is prepared by bending a single metal plate having a predetermined shape. Further, a fastening member 135 and a case lid member 113 are prepared. Then, the insulating member 150 is formed by resin insert molding using these members 137, 135, and 113. Specifically, the extending member 137, the fastening member 135, and the case lid member 113 are set in a mold, and the molten molding resin is injected into the mold to form the insulating member 150. Thereby, as shown in FIG. 3, the sub-assay which can handle the insulation members 150 and 150, the extension members 137 and 137, the fastening members 135 and 135, and the case cover member 113 as one member can be performed. During the insert molding, the resin film 115 is simultaneously formed on the safety valve portion 113j of the case lid member 113.
 次に、電極体120を用意し、その軸方向の両端に、正極電極端子部材130の要素接続部131と負極電極端子部材140の要素接続部131を溶接する。その後、電極体120を絶縁フィルム包囲体125内に挿入する。次に、電極体120及び絶縁フィルム包囲体125がケース本体部材111内に収容されるようにして、ケース蓋部材113をケース本体部材111の開口111h上に配置する。そして、ケース蓋部材113の周縁部分とケース本体部材111の開口111h周縁とをレーザ溶接する。その後、ケース蓋部材113の注液口部113mから電池ケース110内に電解液を注入し、この注液口部113mを封止する。かくして、リチウム二次電池100が完成する。 Next, the electrode body 120 is prepared, and the element connection portion 131 of the positive electrode terminal member 130 and the element connection portion 131 of the negative electrode terminal member 140 are welded to both ends in the axial direction. Thereafter, the electrode body 120 is inserted into the insulating film enclosure 125. Next, the case lid member 113 is disposed on the opening 111 h of the case body member 111 such that the electrode body 120 and the insulating film enclosure 125 are accommodated in the case body member 111. Then, the peripheral portion of the case lid member 113 and the peripheral edge of the opening 111h of the case main body member 111 are laser-welded. Thereafter, an electrolytic solution is injected into the battery case 110 from the liquid inlet portion 113m of the case lid member 113, and the liquid inlet portion 113m is sealed. Thus, the lithium secondary battery 100 is completed.
(実施例)
 次いで、本発明の効果を検証するために行った試験の結果について説明する。
(試験1)
 本発明の実施例として、上記実施形態1のリチウム二次電池100を用意した。また、比較例として、図10及び図11に示した従来技術に係るリチウム二次電池900を用意した。
 そして、各試験サンプルについて、温湿度サイクル試験を行った。具体的には、各試験サンプルを、65℃で15.5時間保持した後、40℃で7.5時間保持した。その後、65℃、95%RHで17.5時間保持した後、40℃で7.5時間保持した。そして、この温度・湿度条件を1サイクルとして、合計10サイクル行った。
 各試験サンプルについて、試験開始前と、4サイクル後と、10サイクル後に、電極端子部材130,930の導通抵抗を測定した。その結果を図6のグラフに示す。
(Example)
Subsequently, the result of the test conducted in order to verify the effect of this invention is demonstrated.
(Test 1)
As an example of the present invention, the lithium secondary battery 100 of Embodiment 1 was prepared. Further, as a comparative example, a lithium secondary battery 900 according to the related art shown in FIGS. 10 and 11 was prepared.
And about each test sample, the temperature / humidity cycle test was done. Specifically, each test sample was held at 65 ° C. for 15.5 hours and then held at 40 ° C. for 7.5 hours. Then, after holding at 65 ° C. and 95% RH for 17.5 hours, it was held at 40 ° C. for 7.5 hours. The temperature / humidity condition was set to 1 cycle, and a total of 10 cycles were performed.
For each test sample, the conduction resistance of the electrode terminal members 130 and 930 was measured before the start of the test, after 4 cycles, and after 10 cycles. The result is shown in the graph of FIG.
 図6のグラフより、比較例のリチウム二次電池900は、温湿度サイクル試験を4サイクル行った段階で既に導通抵抗が増加し、10サイクル後には、更に大きく導通抵抗が増加している。これに対し、実施例のリチウム二次電池100は、温湿度サイクル試験を10サイクル行っても導通抵抗が変化しない(増加しない)ことが判る。 From the graph of FIG. 6, the lithium secondary battery 900 of the comparative example has already increased the conduction resistance at the stage where the temperature and humidity cycle test was performed for four cycles, and the conduction resistance has increased further after 10 cycles. In contrast, in the lithium secondary battery 100 of the example, it can be seen that the conduction resistance does not change (does not increase) even when the temperature and humidity cycle test is performed 10 cycles.
 比較例のリチウム二次電池900で導通抵抗が増加するのは、要素接続部材931と外部配置端子部材933とをリベット部931gによる加締めにより接続しているため、温湿度サイクル試験により加締めが緩むなどして、導通抵抗が増加するためと考えられる。これに対し、実施例のリチウム二次電池100は、要素接続部131と外部配置端子部133とが一体に形成されているため、温湿度サイクル試験を行っても抵抗増加が生じないと考えられる。このことから、要素接続部131と外部配置端子部133を一体に形成することにより、長期間に渡る使用でも電極端子部材130,140に抵抗増加が生じ難く、信頼性を向上させることが判る。 The reason why the conduction resistance increases in the lithium secondary battery 900 of the comparative example is that the element connecting member 931 and the externally arranged terminal member 933 are connected by caulking by the rivet portion 931g, so that caulking is performed by the temperature and humidity cycle test. This is probably because the conduction resistance increases due to loosening. On the other hand, in the lithium secondary battery 100 of the example, since the element connection portion 131 and the externally arranged terminal portion 133 are integrally formed, it is considered that resistance increase does not occur even when the temperature and humidity cycle test is performed. . From this, it can be seen that by forming the element connecting portion 131 and the externally arranged terminal portion 133 integrally, resistance increase does not easily occur in the electrode terminal members 130 and 140 even when used for a long period of time, and the reliability is improved.
(試験2)
 次に、本発明の実施例1として、上記実施形態1のリチウム二次電池100を用意した。この実施例1のリチウム二次電池100は、前述のように、電極端子部材130,140のうち、延出部材137の固定部133eの固定部表面133eaの全面と、中間部133fの中間部表面133faの全面が電池外部に露出しており、これらを合わせた固定部133eと中間部133fの露出面積が140mm2 である。
 また、実施例2として、上記実施形態1のリチウム二次電池100を基本に、これの中間部133fの中間部表面133faを絶縁部材150で覆ったリチウム二次電池を用意した。このリチウム二次電池では、固定部133e及び中間部133fの露出面積(本実施例2では固定部表面133eaの全面積のみ)が100mm2 である。
(Test 2)
Next, as Example 1 of the present invention, the lithium secondary battery 100 of Embodiment 1 was prepared. As described above, the lithium secondary battery 100 according to the first embodiment includes the entire surface of the fixing portion surface 133ea of the fixing portion 133e of the extending member 137 and the intermediate portion surface of the intermediate portion 133f among the electrode terminal members 130 and 140. The entire surface of 133fa is exposed to the outside of the battery, and the exposed area of the fixed portion 133e and the intermediate portion 133f combined with each other is 140 mm 2 .
As Example 2, a lithium secondary battery in which the intermediate surface 133fa of the intermediate part 133f of the lithium secondary battery 100 of Embodiment 1 was covered with an insulating member 150 was prepared. In this lithium secondary battery, the exposed area of the fixing portion 133e and the intermediate portion 133f (only the total area of the fixing portion surface 133ea in the second embodiment) is 100 mm 2 .
 また、実施例3として、上記実施形態1のリチウム二次電池100を基本に、これの中間部133fの中間部表面133faの全面と、固定部133eの固定部表面133eaの半分とを絶縁部材150で覆ったリチウム二次電池を用意した。このリチウム二次電池では、固定部133e及び中間部133fの露出面積(本実施例3では固定部表面133eaの半分の面積)が50mm2 である。
 また、実施例4として、上記実施形態1のリチウム二次電池100を基本に、これの中間部133fの中間部表面133faの全面と、固定部133eの固定部表面133eaの全面とを絶縁部材150で覆ったリチウム二次電池を用意した。このリチウム二次電池では、固定部133e及び中間部133fの露出面積が0mm2 である。
Further, as Example 3, based on the lithium secondary battery 100 of Embodiment 1 described above, the entire intermediate surface 133fa of the intermediate portion 133f and half of the fixed portion surface 133ea of the fixing portion 133e are connected to the insulating member 150. A lithium secondary battery covered with was prepared. In this lithium secondary battery, the exposed area of the fixed portion 133e and the intermediate portion 133f (in the third embodiment, half the area of the fixed portion surface 133ea) is 50 mm 2 .
Further, as Example 4, based on the lithium secondary battery 100 of Embodiment 1 described above, the entire intermediate surface 133fa of the intermediate portion 133f and the entire fixed portion surface 133ea of the fixing portion 133e are connected to the insulating member 150. A lithium secondary battery covered with was prepared. In this lithium secondary battery, the exposed areas of the fixed portion 133e and the intermediate portion 133f are 0 mm 2 .
 そして、上記の各試験サンプルについて、放熱性試験を行った。具体的には、WOT走行パターン(I2 =15000,90秒間)を下記の条件で行った。即ち、通電電流204Aで2秒間、その後、通電電流138Aで9秒間、更に、通電電流97Aで4秒間を1セットとし、これを6セット繰り返し行った。そして、延出部材137の温度を測定した。その結果を図7のグラフに示す。 And about each said test sample, the heat dissipation test was done. Specifically, the WOT running pattern (I 2 = 15000, 90 seconds) was performed under the following conditions. That is, one set of energizing current 204A for 2 seconds, then energizing current 138A for 9 seconds, and further energizing current 97A for 4 seconds was repeated 6 times. And the temperature of the extending member 137 was measured. The result is shown in the graph of FIG.
 図7のグラフより、固定部133e及び中間部133fの露出面積が大きくなるほど、延出部材137の温度が低くなることが判る。この露出面積が大きいほど、延出部材137の熱を効率よく放熱できるためと考えられる。延出部材137が高温になると、例えば絶縁部材150がこの熱により劣化してシール性が低下するなどの不具合が生じるおそれがある。従って、固定部133e及び中間部133fの露出面積を大きくして、延出部材137の温度を低く抑えることが好適である。 7 that the temperature of the extending member 137 decreases as the exposed area of the fixed portion 133e and the intermediate portion 133f increases. It is considered that the larger the exposed area, the more efficiently the heat of the extending member 137 can be dissipated. When the extending member 137 reaches a high temperature, there is a possibility that a defect such as deterioration of the sealing performance due to deterioration of the insulating member 150 due to this heat may occur. Therefore, it is preferable to increase the exposed areas of the fixed portion 133e and the intermediate portion 133f to keep the temperature of the extending member 137 low.
  (実施形態2)
 次いで、第2の実施の形態について説明する。本実施形態2に係る車両700は、上記実施形態1のリチウム二次電池(電池)100を複数搭載したものである。具体的には、図8に示すように、この車両700は、エンジン740、フロントモータ720及びリアモータ730を併用して駆動するハイブリッド自動車である。この車両700は、車体790、エンジン740、これに取り付けられたフロントモータ720、リアモータ730、ケーブル750、インバータ760を備える。更に、この車両700は、複数のリチウム二次電池100を自身の内部に有する組電池710を備え、この組電池710による電気エネルギーを、フロントモータ720及びリアモータ730の駆動に利用している。
(Embodiment 2)
Next, a second embodiment will be described. A vehicle 700 according to the second embodiment includes a plurality of lithium secondary batteries (batteries) 100 according to the first embodiment. Specifically, as shown in FIG. 8, the vehicle 700 is a hybrid vehicle that is driven by using an engine 740, a front motor 720, and a rear motor 730 in combination. The vehicle 700 includes a vehicle body 790, an engine 740, a front motor 720, a rear motor 730, a cable 750, and an inverter 760 attached thereto. Further, the vehicle 700 includes an assembled battery 710 having a plurality of lithium secondary batteries 100 therein, and electric energy from the assembled battery 710 is used to drive the front motor 720 and the rear motor 730.
 前述したように、リチウム二次電池100は、電極端子部材130,140の部品点数が少なく、リチウム二次電池100の製造が容易であり、また、リチウム二次電池100を安価にすることができる。従って、このリチウム二次電池100を搭載する車両700を安価にすることができる。また、リチウム二次電池100は、長期間に渡る使用でも電極端子部材130,140に抵抗増加が生じ難く、信頼性が高いので、これを搭載する車両700の信頼性を向上させることができる。 As described above, the lithium secondary battery 100 has a small number of parts for the electrode terminal members 130 and 140, the lithium secondary battery 100 can be easily manufactured, and the lithium secondary battery 100 can be made inexpensive. . Therefore, the vehicle 700 equipped with the lithium secondary battery 100 can be made inexpensive. Further, the lithium secondary battery 100 is less likely to increase resistance in the electrode terminal members 130 and 140 even when used for a long period of time, and has high reliability. Therefore, the reliability of the vehicle 700 on which the lithium secondary battery 100 is mounted can be improved.
 (実施形態3)
 次いで、第3の実施の形態について説明する。本実施形態3のハンマードリル800は、上記実施形態1のリチウム二次電池(電池)100を含むバッテリパック810を搭載した電池使用機器である。図9に示すように、このハンマードリル800は、本体820の底部821に、バッテリパック810が収容されており、このバッテリパック810を、ドリルを駆動するためのエネルギー源として利用している。
(Embodiment 3)
Next, a third embodiment will be described. A hammer drill 800 according to the third embodiment is a battery using device on which a battery pack 810 including the lithium secondary battery (battery) 100 according to the first embodiment is mounted. As shown in FIG. 9, this hammer drill 800 has a battery pack 810 accommodated in a bottom 821 of a main body 820, and this battery pack 810 is used as an energy source for driving the drill.
 前述したように、リチウム二次電池100は、電極端子部材130,140の部品点数が少なく、リチウム二次電池100の製造が容易であり、また、リチウム二次電池100を安価にすることができる。従って、このリチウム二次電池100を搭載するハンマードリル800を安価にすることができる。また、リチウム二次電池100は、長期間に渡る使用でも電極端子部材130,140に抵抗増加が生じ難く、信頼性が高いので、これを搭載するハンマードリル800の信頼性を向上させることができる。 As described above, the lithium secondary battery 100 has a small number of parts for the electrode terminal members 130 and 140, the lithium secondary battery 100 can be easily manufactured, and the lithium secondary battery 100 can be made inexpensive. . Therefore, the hammer drill 800 on which the lithium secondary battery 100 is mounted can be made inexpensive. In addition, since the lithium secondary battery 100 is less likely to increase resistance in the electrode terminal members 130 and 140 even when used for a long period of time and has high reliability, the reliability of the hammer drill 800 on which the lithium secondary battery 100 is mounted can be improved. .
 以上において、本発明を実施形態に即して説明したが、本発明は上述の実施形態1~3に限定されるものではなく、その要旨を逸脱しない範囲で、適宜変更して適用できることは言うまでもない。
 例えば、上記実施形態1~3では、電池として、リチウム二次電池100を例示したが、例えばニッケル水素電池、ニッケルカドミウム電池等の他の種類の二次電池などにも、本発明を適用できる。
 また、上記実施形態1~3では、捲回型の発電要素(電極体120)を有する電池100を例示したが、積層型の発電要素を有する電池などにも、本発明を適用できる。
In the above, the present invention has been described with reference to the embodiments. However, the present invention is not limited to the above-described first to third embodiments, and it is needless to say that the present invention can be appropriately modified and applied without departing from the gist thereof. Yes.
For example, in the first to third embodiments, the lithium secondary battery 100 is exemplified as the battery. However, the present invention can be applied to other types of secondary batteries such as a nickel metal hydride battery and a nickel cadmium battery.
In the first to third embodiments, the battery 100 having the wound type power generation element (electrode body 120) is illustrated, but the present invention can also be applied to a battery having a stacked type power generation element.

Claims (11)

  1.  発電要素と、
     開口をなし、前記発電要素を収容するケース本体部材、及び、このケース本体部材の前記開口を閉塞するケース蓋部材を有する電池ケースと、
     前記発電要素に接続する一方、前記ケース蓋部材に形成された端子挿通孔を通じて前記ケース蓋部材上に延出する電極端子部材と、
     前記電極端子部材と前記ケース蓋部材との間を絶縁する絶縁部材と、を備える
    電池であって、
     前記電極端子部材は、
      前記電池ケースの内部から前記端子挿通孔を通じて前記ケース蓋部材上に延出する延出部材を有し、
     前記延出部材は、
      前記発電要素に接続する要素接続部であって、
       前記電池ケースの内部に位置し、前記発電要素に接続する要素接続本体部、及び、
       この要素接続本体部に連なり、前記ケース蓋部材の前記端子挿通孔に挿通された挿通部、を含む
      要素接続部と、
      電池ケースの外部のうち前記ケース蓋部材上に位置する外部配置端子部であって、
       前記要素接続部の前記挿通部に連なり、前記ケース蓋部材に沿って延び、前記絶縁部材を介して前記ケース蓋部材に固定された固定部、
       この固定部に連なり、前記ケース蓋部材から離れる方向に延びる中間部、及び、
       この中間部に連なり、前記ケース蓋部材に沿って延び、自身を貫通するネジ挿通孔が形成された外部接続部、を含みZ字状をなす
      外部配置端子部と、を有し、
     前記延出部材は、
      所定形状の1枚の金属板材を屈曲成形して、前記要素接続部及び前記外部配置端子部を一体に形成してなる
    電池。
    A power generation element;
    A battery case having an opening and housing the power generation element, and a case lid member that closes the opening of the case body member;
    While connecting to the power generation element, an electrode terminal member extending on the case lid member through a terminal insertion hole formed in the case lid member;
    An insulating member for insulating between the electrode terminal member and the case lid member,
    The electrode terminal member is
    An extension member extending from the inside of the battery case onto the case lid member through the terminal insertion hole;
    The extending member is
    An element connection for connecting to the power generation element,
    An element connection main body located inside the battery case and connected to the power generation element; and
    An element connection portion that includes the insertion portion that is connected to the element connection main body portion and is inserted into the terminal insertion hole of the case lid member.
    An externally arranged terminal portion located on the case lid member of the outside of the battery case,
    A fixed portion that is connected to the insertion portion of the element connecting portion, extends along the case lid member, and is fixed to the case lid member via the insulating member,
    An intermediate portion that continues to the fixed portion and extends away from the case lid member, and
    An external connection terminal portion that is continuous with the intermediate portion, extends along the case lid member, and includes an external connection portion formed with a screw insertion hole that penetrates the intermediate portion, and has a Z-shape, and
    The extending member is
    A battery formed by bending a single metal plate having a predetermined shape and integrally forming the element connecting portion and the externally arranged terminal portion.
  2. 請求項1に記載の電池であって、
     前記電極端子部材は、
      前記ケース蓋部材上に位置する締結部材を更に有し、
     前記締結部材は、
      前記ケース蓋部材に直交する方向に延びる形態に前記延出部材の前記ネジ挿通孔に挿通され、外周に雄ネジが形成された雄ネジ部と、
      この雄ネジ部よりも径大で、この雄ネジ部及び前記延出部材の前記外部接続部よりも前記ケース蓋部材側に位置する基部と、を有する
    電池。
    The battery according to claim 1,
    The electrode terminal member is
    A fastening member located on the case lid member;
    The fastening member is
    A male screw part inserted into the screw insertion hole of the extension member in a form extending in a direction orthogonal to the case lid member, and a male screw formed on the outer periphery;
    A battery having a diameter larger than that of the male screw portion and a base portion located on the case lid member side with respect to the male screw portion and the external connection portion of the extending member.
  3. 請求項1に記載の電池であって、
     前記絶縁部材は、
      少なくとも、前記延出部材の前記要素接続部の前記挿通部と前記ケース蓋部材の前記端子挿通孔の内周面との間に介在し、1つの前記電極端子部材に対して単一の部材からなり、
     前記要素接続部と前記ケース蓋部材との間の絶縁及びシールが、この絶縁部材のみで行われてなる
    電池。
    The battery according to claim 1,
    The insulating member is
    At least interposed between the insertion portion of the element connection portion of the extension member and the inner peripheral surface of the terminal insertion hole of the case lid member, from a single member to one electrode terminal member Become
    A battery in which insulation and sealing between the element connecting portion and the case lid member are performed only by the insulating member.
  4. 請求項2に記載の電池であって、
     前記絶縁部材は、
      少なくとも、前記延出部材の前記要素接続部の前記挿通部と前記ケース蓋部材の前記端子挿通孔の内周面との間に介在し、1つの前記電極端子部材に対して単一の部材からなり、
     前記要素接続部と前記ケース蓋部材との間の絶縁及びシールが、この絶縁部材のみで行われてなる
    電池。
    The battery according to claim 2,
    The insulating member is
    At least interposed between the insertion portion of the element connection portion of the extension member and the inner peripheral surface of the terminal insertion hole of the case lid member, from a single member to one electrode terminal member Become
    A battery in which insulation and sealing between the element connecting portion and the case lid member are performed only by the insulating member.
  5. 請求項4に記載の電池であって、
     前記絶縁部材は、
      前記延出部材、前記締結部材及び前記ケース蓋部材を用いたインサート成形によって成形されてなり、
      少なくとも、前記延出部材の前記固定部と前記ケース蓋部材の表面との間、及び、前記締結部材の前記基部と前記ケース蓋部材の前記表面との間に介在しつつこれらに接合しており、
     前記絶縁部材、前記延出部材、前記締結部材及び前記ケース蓋部材が、1つの部材として取り扱い可能な形態とされてなる
    電池。
    The battery according to claim 4,
    The insulating member is
    Molded by insert molding using the extension member, the fastening member and the case lid member,
    At least, between the fixed portion of the extending member and the surface of the case lid member, and between the base portion of the fastening member and the surface of the case lid member, and joined to these ,
    A battery in which the insulating member, the extending member, the fastening member, and the case lid member can be handled as one member.
  6. 請求項4または請求項5に記載の電池であって、
     前記ケース蓋部材を平面視して、前記端子挿通孔の中心と前記締結部材の前記雄ネジ部の中心とを結ぶ方向を第1方向とし、この第1方向に直交する方向を第2方向としたとき、
     前記端子挿通孔は、
      前記第1方向に沿う第1寸法が、前記第2方向に沿う第2寸法よりも大きい形態とされてなる
    電池。
    The battery according to claim 4 or 5, wherein
    When the case lid member is viewed in plan, a direction connecting the center of the terminal insertion hole and the center of the male screw portion of the fastening member is defined as a first direction, and a direction orthogonal to the first direction is defined as a second direction. When
    The terminal insertion hole is
    A battery in which a first dimension along the first direction is larger than a second dimension along the second direction.
  7. 請求項3~請求項6のいずれか一項に記載の電池であって、
     前記延出部材の前記固定部は、
      前記ケース蓋部材側を向く固定部裏面と、前記ケース蓋部材側とは逆側を向く固定部表面とを有する板状をなし、
      前記固定部表面の少なくとも一部が、前記絶縁部材に覆われることなく、電池外部に露出してなる
    電池。
    The battery according to any one of claims 3 to 6,
    The fixing portion of the extending member is
    A plate having a fixing part back surface facing the case lid member side and a fixing part surface facing the opposite side to the case lid member side,
    A battery in which at least a part of the surface of the fixed part is exposed to the outside of the battery without being covered with the insulating member.
  8. 請求項7に記載の電池であって、
     前記延出部材の前記中間部は、
      前記固定部の前記固定部表面に連なる中間部表面と、前記固定部裏面に連なる中間部裏面とを有する板状をなし、
      前記中間部表面の少なくとも一部が、前記絶縁部材に覆われることなく、電池外部に露出してなる
    電池。
    The battery according to claim 7,
    The intermediate portion of the extending member is
    A plate having an intermediate portion surface continuous with the fixed portion surface of the fixed portion and an intermediate portion rear surface continuous with the fixed portion back surface,
    A battery in which at least a part of the surface of the intermediate part is exposed to the outside of the battery without being covered with the insulating member.
  9. 請求項3~請求項8のいずれか一項に記載の電池であって、
     前記延出部材の前記外部接続部は、
      前記ケース蓋部材側を向く接続部裏面と、前記ケース蓋部材側とは逆側を向く接続部表面とを有する板状をなし、
      前記接続部表面が、前記絶縁部材に覆われることなく、電池外部に露出してなる
    電池。
    A battery according to any one of claims 3 to 8,
    The external connection portion of the extending member is
    The connection part back surface facing the case lid member side and the connection part surface facing the opposite side to the case lid member side has a plate shape,
    A battery formed by exposing the surface of the connecting portion to the outside of the battery without being covered by the insulating member.
  10. 請求項1~請求項9のいずれか一項に記載の前記電池を搭載し、この電池による電気エネルギーを動力源の全部または一部に使用する車両。 A vehicle on which the battery according to any one of claims 1 to 9 is mounted and electric energy generated by the battery is used for all or part of a power source.
  11. 請求項1~請求項9のいずれか一項に記載の前記電池を搭載し、この電池をエネルギー源の少なくとも1つとして使用する電池使用機器。 A battery-operated device equipped with the battery according to any one of claims 1 to 9 and using the battery as at least one energy source.
PCT/JP2009/052809 2009-02-18 2009-02-18 Battery, vehicle and apparatus using battery WO2010095224A1 (en)

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US10177364B2 (en) 2015-07-16 2019-01-08 Johnson Controls Technology Company System and method of overmolded terminal posts of a battery module
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