JP5369900B2 - Batteries, vehicles, and equipment using batteries - Google Patents

Batteries, vehicles, and equipment using batteries Download PDF

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JP5369900B2
JP5369900B2 JP2009128316A JP2009128316A JP5369900B2 JP 5369900 B2 JP5369900 B2 JP 5369900B2 JP 2009128316 A JP2009128316 A JP 2009128316A JP 2009128316 A JP2009128316 A JP 2009128316A JP 5369900 B2 JP5369900 B2 JP 5369900B2
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battery
fixing
outer end
caulking
case lid
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JP2010277797A (en
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裕喜 永井
忠伸 太田
智浩 松浦
高広 左右木
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Toyota Motor Corp
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a battery or the like which sufficiently secures connection strength and connection reliability of a caulking part of an element connection member and a fixing part of an externally arranged terminal member in an electrode terminal member. <P>SOLUTION: A lithium secondary battery 100 has a form where a fixing hole 133eh of the fixing part 133e of the externally arranged terminal member 133 includes an outside end part 133eh2 enlarged to an external of the battery. The caulking part 131g of the element connection member 131 is welded to the fixing part 133e. The welded part 132 is formed only on a caulking outer circumference part 131gd of the caulking part 131g positioned on a radially outer side than the outside end part 133eh2, and a fixing part outer circumference part 133ed of the fixing part 133e positioned on a radially outer side than the outside end part 133eh2. <P>COPYRIGHT: (C)2011,JPO&amp;INPIT

Description

本発明は、発電要素と、これを収容する電池ケースと、電池ケース内で発電要素に接続すると共に、電池ケースの外部に延出する電極端子部材とを備える電池に関する。また、この電池を備える車両、及び、この電池を備える電池使用機器に関する。   The present invention relates to a battery including a power generation element, a battery case that accommodates the power generation element, and an electrode terminal member that is connected to the power generation element in the battery case and extends to the outside of the battery case. Moreover, it is related with a vehicle provided with this battery, and a battery using apparatus provided with this battery.

従来より、発電要素と、これを収容する電池ケースと、電池ケース内で発電要素に接続すると共に、電池ケースの外部に延出して外部の接続端子との接続に利用される電極端子部材とを備える電池が知られている。例えば特許文献1に、このような電池が開示されている。図13に、この電池900のうち、電極端子部材930の固定部933e近傍の縦断面図を示し、また、図14に、図13に対応した分解斜視図を示す。   Conventionally, a power generation element, a battery case that accommodates the power generation element, and an electrode terminal member that is connected to the power generation element in the battery case and extends to the outside of the battery case and used for connection to an external connection terminal A battery is known. For example, Patent Document 1 discloses such a battery. FIG. 13 shows a longitudinal sectional view of the vicinity of the fixing portion 933e of the electrode terminal member 930 in the battery 900, and FIG. 14 shows an exploded perspective view corresponding to FIG.

この電池900は、発電要素(図示外)を収容する電池ケース910と、電池ケース910内で発電要素に接続する一方、電池ケース910の外部に延出する電極端子部材930と、この電極端子部材930と電池ケース910との間に介在してこれらを絶縁する2種類の絶縁部材(外部絶縁部材950及びシールゴム960)とを備える。
このうち電池ケース910は、発電要素を収容する箱状のケース本体部材(図示外)と、このケース本体部材の開口を閉塞するケース蓋部材913とから構成されている。ケース蓋部材913には、端子挿通孔913hが形成され、電極端子部材930が挿通されている。
The battery 900 includes a battery case 910 that houses a power generation element (not shown), an electrode terminal member 930 that is connected to the power generation element in the battery case 910 and extends outside the battery case 910, and the electrode terminal member Two types of insulating members (an external insulating member 950 and a seal rubber 960) are provided between the battery case 930 and the battery case 910 to insulate them.
Among these, the battery case 910 includes a box-shaped case main body member (not shown) that houses the power generation element, and a case lid member 913 that closes the opening of the case main body member. A terminal insertion hole 913 h is formed in the case lid member 913, and the electrode terminal member 930 is inserted therethrough.

電極端子部材930は、要素接続部材931と外部配置端子部材933と図示外の締結部材の3部材からなる。
このうち要素接続部材931は、要素接続本体部931eと挿通部931fと加締部931gとからなる。要素接続本体部931eは、電池ケース910の内部に位置し、発電要素に接続している。また、挿通部931fは、この要素接続本体部931eの上端(図13及び図14中、上方の端部)に連なり、ケース蓋部材913の端子挿通孔913h及び後述する外部接続端子材933の固定部933eの固定孔933ehに挿通されている。また、加締部931gは、挿通部931fの上端に連なり、電池外部に露出し、加締められ拡径されて傘状をなし、外部接続端子933の固定部933eに上側から当接している。
The electrode terminal member 930 is composed of three members: an element connecting member 931, an externally arranged terminal member 933, and a fastening member not shown.
Among these, the element connection member 931 includes an element connection main body portion 931e, an insertion portion 931f, and a caulking portion 931g. The element connection main body 931e is located inside the battery case 910 and is connected to the power generation element. The insertion portion 931f is connected to the upper end (the upper end in FIGS. 13 and 14) of the element connection main body portion 931e, and fixes a terminal insertion hole 913h of the case lid member 913 and an external connection terminal member 933 to be described later. The fixing hole 933eh of the portion 933e is inserted. The caulking portion 931g is connected to the upper end of the insertion portion 931f, is exposed to the outside of the battery, is caulked and enlarged in diameter to form an umbrella shape, and is in contact with the fixing portion 933e of the external connection terminal 933 from above.

外部配置端子部材933は、ケース蓋部材913上に位置し、固定部933eと中間部933fと図示外の外部接続部とからなり、Z字状をなす。固定部933eは、自身を貫通し、電池外部に(上側に)向かって拡大するテーパ状の固定孔933ehを有し、上述のように要素接続部931(加締部931g)に接続している。この固定部933eは、ケース蓋部材913に沿ってこれに平行に延びる板状をなし、後述する外部絶縁部材950を介してケース蓋部材913に固定されている。中間部933fは、この固定部933eに連なり、上方(図13及び図14中、上方)に延びる板状をなす。   The externally arranged terminal member 933 is located on the case lid member 913, and includes a fixing portion 933e, an intermediate portion 933f, and an external connection portion (not shown), and has a Z shape. The fixing portion 933e has a tapered fixing hole 933eh that penetrates itself and expands toward the outside of the battery (upward), and is connected to the element connection portion 931 (caulking portion 931g) as described above. . The fixing portion 933e has a plate shape extending along and parallel to the case lid member 913, and is fixed to the case lid member 913 via an external insulating member 950 described later. The intermediate portion 933f is connected to the fixing portion 933e and has a plate shape extending upward (upward in FIGS. 13 and 14).

特開2008−192552号公報JP 2008-192552 A

上述の電池900では、前述のように、要素接続部材931の加締部931gの加締めにより、要素接続部材931の加締部931gと外部配置端子部材933の固定部933eとを接続している。このため、接続強度を十分に確保することが困難であり、また、長期間に渡る使用により加締めが緩むなどして、接触抵抗が増加するおそれがある。そこで、本発明者は、要素接続部材931の加締部931gと外部配置端子部材933の固定部933eとを加締め固定した上で、更に、これら加締部931g及び固定部933eを溶接することを考えた。   In the battery 900 described above, the caulking portion 931g of the element connecting member 931 and the fixing portion 933e of the externally arranged terminal member 933 are connected by caulking the caulking portion 931g of the element connecting member 931 as described above. . For this reason, it is difficult to ensure sufficient connection strength, and contact resistance may increase due to loosening of caulking due to long-term use. Therefore, the inventor fixes the caulking portion 931g of the element connecting member 931 and the fixing portion 933e of the externally arranged terminal member 933, and further welds the caulking portion 931g and the fixing portion 933e. Thought.

しかしながら、加締部931gと固定部933eとを溶接すると、その溶接部にブローホールが発生することがある。ブローホールが発生すると、溶接面積が減少するために、接続信頼性が低下する。本発明者が鋭意検討した結果、ブローホールが発生する原因は、溶接が固定部933eの固定孔933ehのテーパ部分にかかると、加締部931gとテーパ部分とは加締めにより密着しているために、溶接の際に生じるガスの逃げ道がなくなり、ブローホールの発生に繋がると考えられた。   However, when the caulking portion 931g and the fixing portion 933e are welded, a blow hole may occur in the welded portion. When blowholes are generated, the welding area is reduced and connection reliability is lowered. As a result of intensive studies by the inventor, the cause of blowholes is that when welding is applied to the tapered portion of the fixing hole 933eh of the fixing portion 933e, the caulking portion 931g and the taper portion are in close contact by caulking. In addition, it was thought that there was no escape route for gas generated during welding, leading to the generation of blowholes.

本発明は、かかる現状に鑑みてなされたものであって、電極端子部材がその要素接続部材の加締部と外部配置端子部材の固定部とを加締め固定する形態とされた電池において、これら加締部と固定部との接続強度及び接続信頼性を十分に確保できる電池を提供することを目的とする。また、この電池を備える車両、及び、この電池を備える電池使用機器を提供することを目的とする。   The present invention has been made in view of such a situation, and in the battery in which the electrode terminal member is configured to crimp and fix the crimping portion of the element connection member and the fixing portion of the externally arranged terminal member, It is an object of the present invention to provide a battery that can sufficiently secure the connection strength and connection reliability between a crimped portion and a fixed portion. Moreover, it aims at providing the vehicle provided with this battery, and the battery use apparatus provided with this battery.

その解決手段は、発電要素と、開口をなし、前記発電要素を収容するケース本体部材、及び、このケース本体部材の前記開口を閉塞するケース蓋部材を有する電池ケースと、前記電池ケースの内部で前記発電要素に接続すると共に、前記ケース蓋部材に形成された端子挿通孔を通じて前記ケース蓋部材上に延出する電極端子部材と、を備える電池であって、前記電極端子部材は、前記電池ケースの内部で前記発電要素に接続すると共に、前記ケース蓋部材の前記端子挿通孔に挿通された要素接続部材と、前記要素接続部材に接続し、前記電池ケースの外部のうち前記ケース蓋部材上に位置する外部配置端子部材と、を有し、前記要素接続部材は、前記電池ケースの内部に位置し、前記発電要素に接続する要素接続本体部と、この要素接続本体部に連なり、前記ケース蓋部材の前記端子挿通孔に挿通された挿通部と、この挿通部に連なり、電池外部に露出し、加締められ拡径されて傘状をなし、前記外部配置端子部材に係合する加締部と、を含み、前記外部配置端子部材は、前記ケース蓋部材に沿って延び、前記ケース蓋部材に固定された固定部であって、自身を貫通する固定孔に前記要素接続部材の前記挿通部が挿通されると共に、前記要素接続部材の前記加締部が係合する固定部を含み、前記固定部の前記固定孔は、少なくとも自身の外側端部が電池外部に向かって拡大するテーパ形状をなし、前記加締部と前記固定部とは、前記加締部のうち、前記固定孔の前記外側端部よりも径方向外側に位置する加締外周部、及び、前記固定部のうち、前記固定孔の前記外側端部よりも径方向外側に位置する固定部外周部においてのみ、互いに溶接されてなる電池である。   The solution includes a power generation element, a battery case having an opening and housing the power generation element, a battery case having a case lid member closing the opening of the case main body member, and the battery case. An electrode terminal member connected to the power generation element and extending onto the case lid member through a terminal insertion hole formed in the case lid member, wherein the electrode terminal member is the battery case Connected to the power generation element inside the element, and connected to the element connection member inserted into the terminal insertion hole of the case lid member, and to the element connection member, on the case lid member of the outside of the battery case An external connection terminal member, and the element connection member is located inside the battery case and connected to the power generation element, and the element connection body An insertion portion that is inserted into the terminal insertion hole of the case lid member, is connected to the insertion portion, is exposed to the outside of the battery, is crimped and expanded in diameter to form an umbrella shape, and the external placement terminal member The externally arranged terminal member extending along the case lid member, and being fixed to the case lid member, the fixing member penetrating through the element. The insertion portion of the connection member is inserted, and includes a fixing portion with which the caulking portion of the element connection member is engaged. At least the outer end portion of the fixing portion faces the outside of the battery. The caulking portion and the fixing portion are, among the caulking portions, a caulking outer peripheral portion positioned radially outward from the outer end portion of the fixing hole, and the Of the fixed part, it is more radial than the outer end of the fixed hole. Only in the fixed outer peripheral portion that is located outside a cell formed by welded together.

本発明の電池では、要素接続部材の加締部を外部配置端子部材の固定部に加締め固定した上、更にこれらを溶接している。このため、これら加締部と固定部との接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。
しかも、本発明では、加締部と固定部との溶接が、加締部のうち、固定孔の外側端部よりも径方向外側に位置する加締外周部、及び、固定部のうち、固定孔の前記外側端部よりも径方向外側に位置する固定部外周部においてのみ、行われている。加締部を変形させて固定部に加締め固定する際、加締部は固定孔の外側端部に隙間なく密着する。一方、通常、加締部の加締外周部を固定部の固定部外周部に押し付けるように変形してもスプリングバックが生じるので、これらの間には僅かに隙間が生じる。このため、加締部と固定部との溶接を加締外周部及び固定部外周部で行えば、溶接の際に生じるガスが上記隙間を通じて径方向外側に移動し外部に放出されやすいので、溶接時にブローホールが発生し溶接不良が生じるのを効果的に抑制できる。従って、加締部と固定部との溶接を確実に行うことができるので、両者の接続信頼性を特に向上させることができる。
In the battery of the present invention, the caulking portion of the element connecting member is caulked and fixed to the fixing portion of the externally arranged terminal member, and these are further welded. For this reason, it is possible to sufficiently secure the connection strength between the caulking portion and the fixing portion, and it is possible to prevent the contact resistance from increasing even when used for a long period of time.
Moreover, in the present invention, the welding between the caulking portion and the fixing portion is the fixing portion among the caulking portion, the caulking outer peripheral portion located radially outside the outer end portion of the fixing hole, and the fixing portion. This is performed only at the outer peripheral portion of the fixed portion located radially outside the outer end portion of the hole. When the caulking portion is deformed and fixed to the fixing portion by caulking, the caulking portion closely contacts the outer end portion of the fixing hole without any gap. On the other hand, since the spring back is generated even if the crimping outer peripheral portion of the crimping portion is deformed so as to be pressed against the fixing portion outer peripheral portion of the fixing portion, a slight gap is generated between them. For this reason, if welding between the caulking portion and the fixing portion is performed at the caulking outer peripheral portion and the fixing portion outer peripheral portion, the gas generated during welding easily moves to the outside in the radial direction through the gap and is easily released to the outside. It is possible to effectively suppress the occurrence of blow holes and sometimes poor welding. Therefore, since it is possible to reliably weld the caulking portion and the fixing portion, it is possible to particularly improve the connection reliability between them.

なお、「発電要素」としては、例えば、各々長尺状をなす正極、負極及びセパレータを重ねて捲回してなる捲回型の発電要素や、各々所定形状をなす正極、負極及びセパレータを多数積層してなる積層型の発電要素などが挙げられる。
「電池ケース」としては、角型の電池ケースや円筒型の電池ケースが挙げられる。
「固定孔」の形態としては、例えば、外側端部を含む孔全体が電池外部に向かって拡大するテーパ形状をなすものでもよいし、外側端部のみが電池外部に向かって拡大するテーパ形状をなすものでもよい。
In addition, as the “power generation element”, for example, a winding type power generation element obtained by winding a positive electrode, a negative electrode, and a separator each having a long shape, and a plurality of positive electrodes, negative electrodes, and separators each having a predetermined shape are stacked. And a laminated power generation element.
Examples of the “battery case” include a rectangular battery case and a cylindrical battery case.
As the form of the “fixed hole”, for example, the whole hole including the outer end portion may have a tapered shape that expands toward the outside of the battery, or the tapered shape in which only the outer end portion expands toward the outside of the battery. An eggplant may be used.

更に、上記の電池であって、前記固定孔の前記外側端部は、この固定孔の中心軸とのなす角が20度〜45度とされてなる電池とすると良い。   Furthermore, in the battery described above, it is preferable that the outer end portion of the fixing hole is a battery in which an angle with the central axis of the fixing hole is 20 degrees to 45 degrees.

固定孔の外側端部の中心軸とのなす角(以下、傾斜角とも言う。)を小さくし過ぎると、具体的には傾斜角を20度より小さくすると、加締めによる接続強度が小さくなり、要素接続部材の加締部が外部配置端子部材の固定部から抜けやすくなる。一方、固定孔の外側端部の傾斜角を大きくし過ぎると、具体的には傾斜角を45度より大きくすると、固定孔の開口径が大きくなるため、加締部の加締外周部と固定部の固定部外周部との溶接可能な面積が小さくなる。このため、加締部を固定部に溶接する際に制約を受けやすくなる。   If the angle (hereinafter also referred to as the inclination angle) formed with the central axis of the outer end portion of the fixing hole is made too small, specifically, if the inclination angle is made smaller than 20 degrees, the connection strength by caulking becomes small, The caulking portion of the element connecting member is easily detached from the fixing portion of the externally arranged terminal member. On the other hand, if the inclination angle of the outer end portion of the fixing hole is too large, specifically, if the inclination angle is larger than 45 degrees, the opening diameter of the fixing hole becomes large. The area that can be welded to the outer peripheral portion of the fixed portion of the portion is reduced. For this reason, it becomes easy to receive restrictions when welding a caulking part to a fixed part.

これに対し本発明の電池では、固定孔の外側端部の中心軸とのなす角(傾斜角)を20度以上としているので、加締めによる接続強度を十分に確保できる。また一方で、固定孔の外側端部の傾斜角を45度以下としているので、開口径を適切な大きさに収めることができ、加締部の加締外周部と固定部の固定部外周部との溶接可能な面積を十分に確保できる。このため、加締部を固定部に溶接する際に、加締部のうちの加締外周部と固定部のうちの固定部外周部とを確実に溶接できる。従って、固定孔の外側端部の傾斜角を20度〜45度とすることで、要素接続部材の加締部と外部配置端子部材の固定部との接続信頼性を更に向上させることができる。なお、固定孔の外側端部の傾斜角を30度〜45度とすると更に好適である。   On the other hand, in the battery of the present invention, since the angle (inclination angle) formed with the central axis of the outer end portion of the fixing hole is 20 degrees or more, the connection strength by caulking can be sufficiently secured. On the other hand, since the inclination angle of the outer end portion of the fixing hole is 45 degrees or less, the opening diameter can be kept to an appropriate size, and the caulking outer peripheral portion of the caulking portion and the fixing portion outer peripheral portion of the fixing portion It is possible to secure a sufficient area for welding. For this reason, when welding a crimping part to a fixing | fixed part, the crimping outer peripheral part of a crimping part and the fixing | fixed part outer peripheral part of a fixing part can be welded reliably. Therefore, the connection reliability between the crimping portion of the element connection member and the fixing portion of the externally arranged terminal member can be further improved by setting the inclination angle of the outer end portion of the fixing hole to 20 degrees to 45 degrees. It is more preferable that the inclination angle of the outer end portion of the fixing hole is 30 degrees to 45 degrees.

更に、上記の電池であって、前記加締部の前記加締外周部は、前記径方向の寸法が0.5mm以上とされてなる電池とすると良い。   Further, in the battery described above, the caulking outer peripheral portion of the caulking portion may be a battery having a radial dimension of 0.5 mm or more.

加締部の加締外周部の径方向の寸法(以下、径方向寸法とも言う。)を0.5mmよりも小さくすると、要素接続部材の加締部を外部配置端子部材の固定部に溶接する際に、加締部の加締外周部と固定部の固定部外周部との溶接可能な面積が小さくなる。このため、加締部を固定部に溶接する際に制約を受けやすくなる。
これに対し本発明の電池では、加締外周部の径方向寸法を0.5mm以上としているので、加締部の加締外周部と固定部の固定部外周部との溶接可能な面積を十分に確保できる。このため、加締部を固定部に溶接する際に、加締部のうちの加締外周部と固定部のうちの固定部外周部とを確実に溶接できる。従って、要素接続部材の加締部と外部配置端子部材の固定部との接続信頼性を更に向上させることができる。なお、加締外周部の径方向寸法を1.0mm以上とすると更に好適である。
When the radial dimension (hereinafter also referred to as radial dimension) of the crimping outer peripheral portion of the crimping portion is smaller than 0.5 mm, the crimping portion of the element connection member is welded to the fixed portion of the externally arranged terminal member. In this case, the weldable area between the caulking outer peripheral portion of the caulking portion and the fixing portion outer peripheral portion of the fixing portion is reduced. For this reason, it becomes easy to receive restrictions when welding a caulking part to a fixed part.
On the other hand, in the battery of the present invention, since the radial dimension of the crimping outer peripheral portion is 0.5 mm or more, a sufficient weldable area between the crimping outer peripheral portion of the crimping portion and the fixing portion outer peripheral portion of the fixing portion is sufficient. Can be secured. For this reason, when welding a crimping part to a fixing | fixed part, the crimping outer peripheral part of a crimping part and the fixing | fixed part outer peripheral part of a fixing part can be welded reliably. Therefore, it is possible to further improve the connection reliability between the caulking portion of the element connecting member and the fixing portion of the externally arranged terminal member. It is more preferable that the radial dimension of the caulking outer peripheral portion is 1.0 mm or more.

更に、上記のいずれかに記載の電池であって、前記固定孔の前記外側端部は、自身の周方向に配置された第1外側端部及び第2外側端部であって、前記第1外側端部と前記固定孔の中心軸とのなす角が、前記第2外側端部と前記固定孔の中心軸とのなす角よりも大きくされた第1外側端部及び第2外側端部を有する電池とすると良い。   Furthermore, in the battery according to any one of the above, the outer end portion of the fixing hole is a first outer end portion and a second outer end portion arranged in a circumferential direction of the fixing hole, and the first end portion is the first outer end portion. A first outer end portion and a second outer end portion, wherein an angle formed between the outer end portion and the central axis of the fixing hole is larger than an angle formed between the second outer end portion and the central axis of the fixing hole; It is preferable to have a battery.

本発明の電池では、固定孔の外側端部が、中心軸とのなす角(傾斜角)が互いに異なる第1外側端部及び第2外側端部を周方向に配置した形態とされている。このように固定孔の外側端部が周方向に方向性を有することにより、要素接続部材の加締部と外部配置端子部材の固定部とが相対的に回転することを効果的に防止できる。   In the battery of the present invention, the outer end portion of the fixing hole is configured such that the first outer end portion and the second outer end portion, which are different in angle (inclination angle) with the central axis, are arranged in the circumferential direction. As described above, since the outer end portion of the fixing hole has a directivity in the circumferential direction, the caulking portion of the element connecting member and the fixing portion of the externally arranged terminal member can be effectively prevented from rotating relatively.

上記の電池であって、前記加締部と前記固定部とは、前記固定孔の前記第2外側端部の径方向外側においてのみ、互いに溶接されてなる電池とすると良い。   In the battery described above, the caulking portion and the fixing portion may be batteries that are welded to each other only on the radially outer side of the second outer end portion of the fixing hole.

前述のように、第2外側端部の中心軸とのなす角(傾斜角)は、第1外側端部の傾斜角よりも小さいため、第2外側端部の外径も小さい。このため、第2外側端部の径方向外側においては、加締部の加締外周部と固定部の固定部外周部との溶接可能な面積を十分に確保できるので、加締部を固定部に溶接する際に、加締部のうちの加締外周部と固定部のうちの固定部外周部とを確実に溶接できる。従って、要素接続部材の加締部と外部配置端子部材の固定部とが相対的に回転することを効果的に防止できる上に、加締部と固定部との接続信頼性を更に向上させることができる。   As described above, since the angle (inclination angle) formed with the central axis of the second outer end portion is smaller than the inclination angle of the first outer end portion, the outer diameter of the second outer end portion is also small. For this reason, since the area that can be welded between the caulking outer peripheral portion of the caulking portion and the fixing portion outer peripheral portion of the fixing portion can be sufficiently secured on the outer side in the radial direction of the second outer end, During welding, the caulking outer peripheral portion of the caulking portion and the fixed portion outer peripheral portion of the fixing portion can be reliably welded. Therefore, it is possible to effectively prevent the caulking portion of the element connecting member and the fixing portion of the externally arranged terminal member from rotating relatively, and to further improve the connection reliability between the caulking portion and the fixing portion. Can do.

また、他の解決手段は、上記のいずれかに記載の前記電池を搭載し、この電池による電気エネルギーを動力源の全部または一部に使用する車両である。   Another solution is a vehicle on which the battery according to any one of the above is mounted and electric energy generated by the battery is used for all or part of a power source.

前述の電池は、従来の電池900に比して、要素接続部材の加締部を外部配置端子部材の固定部に加締め固定した上でこれらを溶接しているので、両者の接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。その上、加締部と固定部との溶接の際に溶接不良が生じるのを抑制できるので、両者の接続信頼性を特に向上させることができる。従って、この電池を搭載する車両の信頼性を向上させることができる。
なお、「車両」としては、例えば、電気自動車、ハイブリッド自動車、プラグインハイブリッド自動車、ハイブリッド鉄道車両、フォークリフト、電気車いす、電動アシスト自転車、電動スクータなどが挙げられる。
Compared with the conventional battery 900, the above-mentioned battery is welded after the crimping portion of the element connecting member is crimped and fixed to the fixing portion of the externally arranged terminal member. The contact resistance can be prevented from increasing even when used for a long period of time. In addition, since welding failure can be suppressed during welding of the crimped portion and the fixed portion, the connection reliability between them can be particularly improved. Therefore, the reliability of a vehicle equipped with this battery can be improved.
Examples of the “vehicle” include an electric vehicle, a hybrid vehicle, a plug-in hybrid vehicle, a hybrid railway vehicle, a forklift, an electric wheelchair, an electrically assisted bicycle, and an electric scooter.

また、他の解決手段は、上記のいずれかに記載の前記電池を搭載し、この電池をエネルギー源の少なくとも1つとして使用する電池使用機器である。   Another solution is a battery-using device in which the battery according to any one of the above is mounted and the battery is used as at least one energy source.

前述の電池は、従来の電池900に比して、要素接続部材の加締部を外部配置端子部材の固定部に加締め固定した上でこれらを溶接しているので、両者の接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。その上、加締部と固定部との溶接の際に溶接不良が生じるのを抑制できるので、両者の接続信頼性を特に向上させることができる。従って、この電池を搭載する電池使用機器の信頼性を向上させることができる。
なお、「電池搭載機器」としては、例えば、パーソナルコンピュータ、携帯電話、電池駆動の電動工具、無停電電源装置など、電池で駆動される各種の家電製品、オフィス機器、産業機器などが挙げられる。
Compared with the conventional battery 900, the above-mentioned battery is welded after the crimping portion of the element connecting member is crimped and fixed to the fixing portion of the externally arranged terminal member. The contact resistance can be prevented from increasing even when used for a long period of time. In addition, since welding failure can be suppressed during welding of the crimped portion and the fixed portion, the connection reliability between them can be particularly improved. Accordingly, it is possible to improve the reliability of a battery-using device equipped with this battery.
Examples of the “battery-equipped device” include various home appliances driven by a battery such as a personal computer, a mobile phone, a battery-driven electric tool, and an uninterruptible power supply, office equipment, and industrial equipment.

実施形態1に係るリチウム二次電池の縦断面図である。1 is a longitudinal sectional view of a lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池のうち、電極端子部材、ケース蓋部材及び各絶縁部材を示す分解斜視図である。4 is an exploded perspective view showing an electrode terminal member, a case lid member, and each insulating member in the lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池に関し、外部配置端子部材の側面図である。4 is a side view of an externally arranged terminal member for the lithium secondary battery according to Embodiment 1. FIG. 実施形態1に係るリチウム二次電池のうち、電極端子部材の固定部及び加締部近傍を示す縦断面図である。FIG. 3 is a longitudinal sectional view showing the vicinity of a fixing part and a caulking part of an electrode terminal member in the lithium secondary battery according to Embodiment 1. 実施形態1に係るリチウム二次電池のうち、電極端子部材の固定部と加締部との溶接部近傍を拡大して示す縦断面図である。FIG. 3 is a longitudinal sectional view showing, in an enlarged manner, a vicinity of a welded portion between a fixing portion of an electrode terminal member and a caulking portion in the lithium secondary battery according to Embodiment 1. 実施形態2に係るリチウム二次電池に関し、外部配置端子部材の上方から見た平面図である。FIG. 6 is a plan view of a lithium secondary battery according to Embodiment 2 as viewed from above an externally arranged terminal member. 実施形態2に係るリチウム二次電池に関し、外部配置端子部材の図6におけるA−A断面図である。FIG. 7 is a cross-sectional view taken along line AA in FIG. 6 of the externally arranged terminal member for the lithium secondary battery according to the second embodiment. 実施形態2に係るリチウム二次電池に関し、外部配置端子部材の図6におけるB−B断面図である。FIG. 7 is a cross-sectional view of the externally arranged terminal member taken along the line BB in FIG. 6 regarding the lithium secondary battery according to the second embodiment. 実施形態3に係るリチウム二次電池に関し、外部配置端子部材の上方から見た平面図である。FIG. 6 is a plan view of a lithium secondary battery according to Embodiment 3 as viewed from above an externally arranged terminal member. 実施形態3に係るリチウム二次電池に関し、外部配置端子部材の外部接続部側から見た側面図である。FIG. 5 is a side view of the lithium secondary battery according to Embodiment 3 as viewed from the external connection portion side of the externally arranged terminal member. 実施形態4に係る車両を示す説明図である。It is explanatory drawing which shows the vehicle which concerns on Embodiment 4. FIG. 実施形態5に係るハンマードリルを示す説明図である。It is explanatory drawing which shows the hammer drill which concerns on Embodiment 5. FIG. 従来技術に係る電池の電極端子部材の固定部近傍を拡大して示す縦断面図である。It is a longitudinal cross-sectional view which expands and shows the fixing | fixed part vicinity of the electrode terminal member of the battery which concerns on a prior art. 従来技術に係る電池の電極端子部材、ケース蓋部材及び各絶縁部材を示す分解斜視図である。It is a disassembled perspective view which shows the electrode terminal member of a battery which concerns on a prior art, a case cover member, and each insulation member.

(実施形態1)
以下、本発明の実施の形態を、図面を参照しつつ説明する。図1に、本実施形態1のリチウム二次電池(電池)100の縦断面図を示す。また、図2〜図5に、このリチウム二次電池100を構成する正極電極端子部材130及び負極電極端子部材140等の詳細を示す。なお、図1〜図5における上方をリチウム二次電池100の上側、下方をリチウム二次電池100の下側として説明する。
(Embodiment 1)
Hereinafter, embodiments of the present invention will be described with reference to the drawings. In FIG. 1, the longitudinal cross-sectional view of the lithium secondary battery (battery) 100 of this Embodiment 1 is shown. 2 to 5 show details of the positive electrode terminal member 130, the negative electrode terminal member 140, and the like constituting the lithium secondary battery 100. 1 to 5 will be described as the upper side of the lithium secondary battery 100 and the lower side as the lower side of the lithium secondary battery 100.

このリチウム二次電池100は、ハイブリッドカー、電気自動車等の車両や、ハンマードリル等の電池使用機器に搭載される角型電池である。リチウム二次電池100は、角型の電池ケース110、この電池ケース100内に収容された電極体(発電要素)120、この電極体120を包囲しつつ電池ケース110内に収容された絶縁フィルム包囲体125、電池ケース110に支持された2つの電極端子部材130,140、電池ケース110と電極端子部材130,140との間を絶縁する3種類の絶縁部材150,160,170等から構成されている。また、電池ケース110の内部には、電解液が注入されている。   The lithium secondary battery 100 is a prismatic battery that is mounted on a vehicle such as a hybrid car or an electric vehicle, or a battery-powered device such as a hammer drill. The lithium secondary battery 100 includes a rectangular battery case 110, an electrode body (power generation element) 120 housed in the battery case 100, and an insulating film enclosed in the battery case 110 while surrounding the electrode body 120. Body 125, two electrode terminal members 130, 140 supported by battery case 110, and three types of insulating members 150, 160, 170 that insulate between battery case 110 and electrode terminal members 130, 140. Yes. In addition, an electrolytic solution is injected into the battery case 110.

このうち、電池ケース110は、金属(具体的には純アルミニウム)からなり、直方体状に形成されている。この電池ケース110は、上側のみが開口した箱状をなし、後述する電極体120を収容するケース本体部材111と、このケース本体部材111の開口111hを閉塞する形態で溶接された矩形板状のケース蓋部材113とから構成されている。
ケース本体部材111は、ケース蓋部材113に対向する矩形板状のケース底壁部111bと、ケース蓋部材113とケース底壁部111bとの間を結ぶ矩形板状の4つのケース側壁部111c,111c,…とからなる。
Among these, the battery case 110 is made of metal (specifically, pure aluminum) and is formed in a rectangular parallelepiped shape. The battery case 110 has a box shape in which only the upper side is opened. The battery case 110 has a rectangular shape that is welded in a form that closes an opening 111h of the case body member 111 and a case body member 111 that houses an electrode body 120 described later. And a case lid member 113.
The case body member 111 includes a rectangular plate-like case bottom wall portion 111b facing the case lid member 113, and four rectangular plate-like case side wall portions 111c connecting the case lid member 113 and the case bottom wall portion 111b, 111c,...

ケース蓋部材113は、表面113a及び裏面113bを有する矩形板状をなし、その長手方向(図1及び図2中、左右方向)の両端近傍の所定位置には、このケース蓋部材113を貫通する円孔の端子挿通孔113h,113hがそれぞれ形成されている。一方の端子挿通孔113h(図1及び図2中、左側)には、後述する正極電極端子部材130が挿通され、他方の端子挿通孔113h(図1及び図2中、右側)には、後述する負極電極端子部材140が挿通されている。   The case lid member 113 has a rectangular plate shape having a front surface 113a and a back surface 113b, and penetrates the case lid member 113 at predetermined positions near both ends in the longitudinal direction (left and right directions in FIGS. 1 and 2). Circular terminal insertion holes 113h and 113h are formed, respectively. A positive electrode terminal member 130 (described later) is inserted into one terminal insertion hole 113h (left side in FIGS. 1 and 2), and the other terminal insertion hole 113h (right side in FIGS. 1 and 2) is described later. The negative electrode terminal member 140 to be inserted is inserted.

ケース蓋部材113の長手方向中央には、安全弁部113jが設けられている。この安全弁部113jは、ケース蓋部材113と一体的に形成されてケース蓋部材113の一部をなす。安全弁部113jは、ケース蓋部材113の他の部分よりも薄く薄膜状(厚み110±30μm)に形成されると共に、その上側にはV字溝を有し、厚み45±30μmと特に薄くされた破断部113jvが所定形状に形成されている。これにより、安全弁部113jは、電池ケース110内部の内圧が所定圧力に達した際に作動する。即ち、内圧が所定圧力に達したときに破断部113jvが破断して、電池内部のガスを電池外部に放出する。   A safety valve portion 113j is provided at the center of the case lid member 113 in the longitudinal direction. The safety valve portion 113j is formed integrally with the case lid member 113 and forms a part of the case lid member 113. The safety valve portion 113j is formed in a thin film shape (thickness 110 ± 30 μm) thinner than other portions of the case lid member 113, and has a V-shaped groove on the upper side thereof, and is particularly thin with a thickness of 45 ± 30 μm. The breaking portion 113jv is formed in a predetermined shape. As a result, the safety valve portion 113j operates when the internal pressure inside the battery case 110 reaches a predetermined pressure. That is, when the internal pressure reaches a predetermined pressure, the breaking portion 113jv breaks and releases the gas inside the battery to the outside of the battery.

また、この安全弁部113j上には、PPS樹脂からなる薄膜状の樹脂膜115が被着形成されている。安全弁部113jは薄く形成され、破断部113jvは特に薄く形成されているので、酸化により穴が生じるなど破損するおそれがある。しかし、安全弁部113j上に樹脂膜115を形成することにより、安全弁部113jが外部から保護されるので、安全弁部113jに破損が生じることを効果的に防止できる。
また、ケース蓋部材113の長手方向中央よりも負極電極端子部材140側の所定位置には、電解液を電池ケース110内に注入する為の注液口部113mが設けられている。
A thin resin film 115 made of PPS resin is deposited on the safety valve portion 113j. Since the safety valve portion 113j is formed thin and the break portion 113jv is formed particularly thin, there is a risk of damage such as a hole formed by oxidation. However, since the safety valve portion 113j is protected from the outside by forming the resin film 115 on the safety valve portion 113j, it is possible to effectively prevent the safety valve portion 113j from being damaged.
In addition, a liquid injection port portion 113 m for injecting the electrolyte into the battery case 110 is provided at a predetermined position on the negative electrode terminal member 140 side from the longitudinal center of the case lid member 113.

図1に示すように、電池ケース110の内部には、自身の軸方向に(図1中、左右方向)に直交する横断面が長円形状をなす捲回型の電極体120が、横倒しにした状態で、即ち、電極体120の軸方向が、ケース本体部材111の2つのケース側壁部111c,111cと直交する状態で、収容されている。この電極体120の軸方向の両端には、正極電極端子部材130の要素接続部材131及び負極電極端子部材140の要素接続部材131が接続されている。   As shown in FIG. 1, in the battery case 110, a wound electrode body 120 having an elliptical cross section orthogonal to its own axial direction (left and right direction in FIG. 1) is laid down. In other words, the electrode body 120 is accommodated in a state in which the axial direction of the electrode body 120 is orthogonal to the two case side wall portions 111 c and 111 c of the case body member 111. The element connection member 131 of the positive electrode terminal member 130 and the element connection member 131 of the negative electrode terminal member 140 are connected to both ends of the electrode body 120 in the axial direction.

この電極体120は、正極シートと負極シートとをセパレータを介して重ねて捲回し、扁平状に圧縮したものである。正極シートは、長尺状アルミニウム箔からなる正極集電体を有する。この正極集電体の両面には、正極活物質を含む正極活物質層が形成されている。また、負極シートは、長尺状銅箔からなる負極集電体を有する。この負極集電体の両面には、負極活物質を含む負極活物質層が形成されている。セパレータは、多孔質のポリプロピレン樹脂シートからなる。
この電極体120は、絶縁フィルムを上側のみが開口した箱状に折り曲げて、所定部位を溶着して形成した絶縁フィルム包囲体125に、自身の上側を除いて全体的に包囲されている。
This electrode body 120 is obtained by rolling a positive electrode sheet and a negative electrode sheet with a separator interposed between them and compressing them into a flat shape. The positive electrode sheet has a positive electrode current collector made of a long aluminum foil. A positive electrode active material layer containing a positive electrode active material is formed on both surfaces of the positive electrode current collector. The negative electrode sheet has a negative electrode current collector made of a long copper foil. A negative electrode active material layer containing a negative electrode active material is formed on both surfaces of the negative electrode current collector. The separator is made of a porous polypropylene resin sheet.
The electrode body 120 is entirely surrounded by an insulating film enclosure 125 formed by bending an insulating film into a box shape having an opening only on the upper side and welding a predetermined portion, except for its upper side.

次に、正極他電極端子部材130及び負極電極端子部材140について説明する(図1〜図5参照)。正極電極端子部材130と負極電極端子部材140は、基本的に同様な構成であるため、これらを構成する各部材には、正極電極端子部材130と負極電極端子部材140とで同一の符号を付して説明する。
正極電極端子部材130は、電池ケース110の内部において電極体120の正極シートと電気的かつ機械的に接続する一方、電池ケース110(ケース蓋部材113)に形成された端子挿通孔113hを通じて、電池ケース110の外部(ケース蓋部材113上)に延出している。また、負極電極端子部材140は、電池ケース110の内部において電極体120の負極シートと電気的かつ機械的に接続する一方、電池ケース110(ケース蓋部材113)に形成された端子挿通孔113hを通じて、電池ケース110の外部(ケース蓋部材113上)に延出している。
Next, the positive electrode other electrode terminal member 130 and the negative electrode terminal member 140 will be described (see FIGS. 1 to 5). Since the positive electrode terminal member 130 and the negative electrode terminal member 140 have basically the same configuration, the same reference numerals are given to the respective members constituting the positive electrode terminal member 130 and the negative electrode terminal member 140. To explain.
The positive electrode terminal member 130 is electrically and mechanically connected to the positive electrode sheet of the electrode body 120 inside the battery case 110, while the battery is passed through the terminal insertion hole 113 h formed in the battery case 110 (case lid member 113). It extends outside the case 110 (on the case lid member 113). Further, the negative electrode terminal member 140 is electrically and mechanically connected to the negative electrode sheet of the electrode body 120 inside the battery case 110, while passing through a terminal insertion hole 113 h formed in the battery case 110 (case lid member 113). The battery case 110 extends outside (on the case lid member 113).

これらの電極端子部材130,140は、それぞれ、電池ケース110の内部から端子挿通孔113hを通じてケース蓋部材113上に延出する要素接続部材131と、この要素接続部材131に接続し、ケース蓋部材113上に位置する外部配置端子部材133と、この外部配置端子部材133に接続し、ケース蓋部材113上に配置された締結部材135とからなる。これら要素接続部材131、外部配置端子部材133及び締結部材135は、いずれも金属から形成されている。なお、正極電極端子部材130の要素接続部材131は、電極体120の正極シート(アルミニウム箔)との溶接を考慮して、純アルミニウムにより形成されており、負極電極端子部材140の要素接続部材131は、電極体120の負極シート(銅箔)との溶接を考慮して、純銅により形成されている。   These electrode terminal members 130 and 140 are connected to the element connecting member 131 extending from the inside of the battery case 110 through the terminal insertion hole 113h onto the case lid member 113, and to the element connecting member 131, respectively. The external arrangement terminal member 133 located on the 113 and the fastening member 135 connected to the external arrangement terminal member 133 and arranged on the case lid member 113. The element connecting member 131, the externally arranged terminal member 133, and the fastening member 135 are all made of metal. The element connection member 131 of the positive electrode terminal member 130 is made of pure aluminum in consideration of welding with the positive electrode sheet (aluminum foil) of the electrode body 120, and the element connection member 131 of the negative electrode terminal member 140. Is formed of pure copper in consideration of welding of the electrode body 120 to the negative electrode sheet (copper foil).

このうち要素接続部材131は、要素接続本体部131eと挿通部131fと加締部131gとからなる。
要素接続本体部131eは、金属板材を屈曲加工した所定形状を有し、電池ケース110の内部に位置し、電極体120に溶接されている。これにより、要素接続部材131と電極体120とが電気的かつ機械的に接続されている。
挿通部131fは、円柱状をなし、自身の下端で要素接続本体部131eの上端131esに連なると共に、自身の上端で加締部131gに連なっている。この挿通部131fは、ケース蓋部材113の端子挿通孔113h及び後述する外部配置端子部材133の固定部133eの固定孔133ehに挿通されている。
Among these, the element connection member 131 includes an element connection main body 131e, an insertion portion 131f, and a caulking portion 131g.
The element connection main body 131e has a predetermined shape obtained by bending a metal plate material, is located inside the battery case 110, and is welded to the electrode body 120. Thereby, the element connection member 131 and the electrode body 120 are electrically and mechanically connected.
The insertion portion 131f has a cylindrical shape, and is continuous with the upper end 131es of the element connection main body portion 131e at its lower end, and is continuous with the crimping portion 131g at its upper end. The insertion portion 131f is inserted into a terminal insertion hole 113h of the case lid member 113 and a fixing hole 133eh of a fixing portion 133e of the externally arranged terminal member 133 described later.

加締部131gは、電池外部に露出し、加締められ拡径されて傘状をなして、後述する外部配置端子部材133の固定部133eに上側から係合している。この加締部131gは、後述する固定孔133ehの外側端部133eh2よりも径方向外側に位置する円環状の加締外周部131gdと、これよりも径方向内側に位置する加締中央部131gcとからなる(図4及び図5参照)。このうち加締外周部131gdは、径方向に沿った寸法(径方向寸法)LAが0.5mm以上(本実施形態1では、径方向寸法LA=1.0mm)とされている。   The caulking portion 131g is exposed to the outside of the battery, is caulked and enlarged in diameter to form an umbrella shape, and engages with a fixing portion 133e of the externally arranged terminal member 133 described later from above. The caulking portion 131g includes an annular caulking outer peripheral portion 131gd that is located radially outside the outer end portion 133eh2 of the fixing hole 133eh, which will be described later, and a caulking central portion 131gc that is located radially inward of the caulking portion 131g. (See FIGS. 4 and 5). Of these, the caulking outer peripheral portion 131gd has a radial dimension (radial dimension) LA of 0.5 mm or more (in the first embodiment, the radial dimension LA = 1.0 mm).

また、この加締部131gは、外部配置端子部材133の固定部133eに溶接されている。具体的には、加締部131gのうち、加締外周部131gdのみが外部配置端子部材133の固定部133eに溶接されている。即ち、加締部131gのうちで、溶接部132が形成されている部位は、加締外周部131gdのみである。この溶接部132は、加締外周部131gd及び後述する固定部133eの固定部外周部133edに、周方向に等間隔に複数(4つ)形成されている。   The caulking portion 131g is welded to the fixing portion 133e of the externally arranged terminal member 133. Specifically, only the caulking outer peripheral portion 131gd of the caulking portion 131g is welded to the fixing portion 133e of the externally arranged terminal member 133. That is, in the crimped portion 131g, the portion where the welded portion 132 is formed is only the crimped outer peripheral portion 131gd. A plurality (four) of the welded portions 132 are formed at equal intervals in the circumferential direction on the caulking outer peripheral portion 131gd and a fixing portion outer peripheral portion 133ed of the fixing portion 133e described later.

外部配置端子部材133は、電池ケース110の外部のうちケース蓋部材113上に位置し、固定部133eと中間部133fと外部接続部133gとからなり、Z字状(段状)をなす。
このうち固定部133eは、ケース蓋部材113側とは逆側(上側)を向く固定部表面133eaと、ケース蓋部材113側(下側)を向く固定部裏面113ebとを有する板状をなす。この固定部133eは、ケース蓋部材113に沿ってかつこれに平行に延び、後述する外部絶縁部材150を介してケース蓋部材113に固定されている。具体的には、この固定部133eは、外部絶縁部材150の固定部用凹部150fm内に配置されている。また、固定部表面133eaは、外部絶縁部材150に覆われることなく、電池外部に露出している。
The externally arranged terminal member 133 is located on the case lid member 113 in the outside of the battery case 110, and includes a fixed portion 133e, an intermediate portion 133f, and an external connection portion 133g, and has a Z shape (step shape).
Among these, the fixing portion 133e has a plate shape having a fixing portion surface 133ea facing the side opposite to the case lid member 113 (upper side) and a fixing portion rear surface 113eb facing the case lid member 113 side (lower side). The fixing portion 133e extends along and parallel to the case lid member 113, and is fixed to the case lid member 113 via an external insulating member 150 described later. Specifically, the fixing portion 133e is disposed in the fixing portion recess 150fm of the external insulating member 150. Further, the fixed portion surface 133ea is exposed to the outside of the battery without being covered by the external insulating member 150.

また、この固定部133eには、自身を貫通する固定孔133ehが形成され、前述のように要素接続部材131の挿通部133fが挿通されている。この固定孔133ehは、ケース蓋部材113側(下側)に位置し、開口径が一定の円孔とされた円孔部133eh1と、ケース蓋部材113側とは逆側(上側)に位置し、電池外部に(上側に)向かって直線的に拡大するテーパ孔とされた外側端部133eh2とからなる。このうち外側端部133eh2は、この固定孔133ehの中心軸AXとのなす角(傾斜角)θ1が20度〜45度(本実施形態では傾斜角θ1=30度)とされている(図4参照)。   The fixing portion 133e is formed with a fixing hole 133eh that passes through the fixing portion 133e, and the insertion portion 133f of the element connection member 131 is inserted as described above. The fixing hole 133eh is located on the case lid member 113 side (lower side), and is located on the opposite side (upper side) of the circular hole portion 133eh1 having a constant opening diameter and the case lid member 113 side. The outer end portion 133eh2 is a tapered hole that linearly expands outward (upward) from the battery. Of these, the outer end 133eh2 has an angle (inclination angle) θ1 formed with the central axis AX of the fixing hole 133eh of 20 to 45 degrees (in this embodiment, the inclination angle θ1 = 30 degrees) (FIG. 4). reference).

また、この固定部133eには、前述のように、要素接続部材131の加締部131gが接続している。具体的には、加締部131gの加締中央部131gcが、固定孔133ehの外側端部133eh2に隙間なく当接すると共に、加締部131gの加締外周部131gdが、固定部133eのうち、固定孔133ehの外側端部133eh2よりも径方向外側に位置する固定部外周部133ed上に位置している。前述のように加締部131gと固定部133eとは互いに溶接されており、その溶接部132は、加締部131gのうちの加締外周部131gd、及び、固定部133eのうちの固定部外周部133edにのみ形成されている。   Further, as described above, the caulking portion 131g of the element connecting member 131 is connected to the fixing portion 133e. Specifically, the crimping central portion 131gc of the crimping portion 131g contacts the outer end portion 133eh2 of the fixing hole 133eh without a gap, and the crimping outer peripheral portion 131gd of the crimping portion 131g is included in the fixing portion 133e. The fixing hole 133eh is positioned on the fixing portion outer peripheral portion 133ed that is positioned radially outward from the outer end portion 133eh2. As described above, the caulking portion 131g and the fixing portion 133e are welded to each other, and the welding portion 132 includes the caulking outer peripheral portion 131gd of the caulking portion 131g and the fixing portion outer periphery of the fixing portion 133e. It is formed only on the portion 133ed.

中間部133fは、固定部133eの固定部表面133eaに連なる中間部表面133faと、固定部裏面133ebに連なる中間部裏面133fbとを有する板状をなす。この中間部133fは、固定部133eに連なり、ケース蓋部材113から離れる方向、本実施形態1では、ケース蓋部材113に直交する方向のうち、ケース蓋部材113から離れる方向(上側)に延びている。中間部表面133faは、外部絶縁部材150に覆われることなく、電池外部に露出している。   The intermediate part 133f has a plate shape having an intermediate part surface 133fa continuous with the fixed part surface 133ea of the fixed part 133e and an intermediate part back surface 133fb continuous with the fixed part back surface 133eb. The intermediate portion 133f is connected to the fixing portion 133e, and extends in a direction away from the case lid member 113 in the direction away from the case lid member 113, in the first embodiment, in the direction perpendicular to the case lid member 113 (upper side). Yes. The intermediate portion surface 133fa is exposed to the outside of the battery without being covered by the external insulating member 150.

外部接続部133gは、ケース蓋部材113側とは逆側(上側)を向く接続部表面133gaと、ケース蓋部材113側(下側)を向く接続部裏面133gbとを有する板状をなす。この外部接続部133gは、中間部133fに連なり、ケース蓋部材113に沿って延び、自身を貫通する円孔のネジ挿通孔133ghが形成されている。この外部接続部133gのうち、接続部表面133gaの全体は、後述する外部絶縁部材150に覆われることなく、電池外部に露出している。この接続部表面133gaは、バスバーなどの外部の接続端子との電気的接続に利用される。   The external connection portion 133g has a plate shape having a connection portion surface 133ga facing the opposite side (upper side) to the case lid member 113 side and a connection portion rear surface 133gb facing the case lid member 113 side (lower side). The external connection portion 133g is connected to the intermediate portion 133f, extends along the case lid member 113, and is formed with a circular screw insertion hole 133gh that passes through the external connection portion 133g. Of the external connection portion 133g, the entire connection portion surface 133ga is exposed to the outside of the battery without being covered by the external insulating member 150 described later. The connection portion surface 133ga is used for electrical connection with an external connection terminal such as a bus bar.

また、この外部接続部133gは、図3に示すように、ケース蓋部材113に対して、角θ2=10度だけケース蓋部材113側に傾いている。この角θ2は、1度〜30度とするのが好ましい。このように外部接続部133gに角θ2を持たせることにより、接続部表面133gaにバスバーなどの外部の接続端子を当接させて、後述する締結部材135の雄ネジ部135eにナット等を締結した場合に、ナット等の緩みを防止できる。その結果、外部接続部133gと外部の接続端子との接触抵抗の増加を抑えることができ、リチウム二次電池100の異常発熱等の不具合を確実に防止できるので、リチウム二次電池100の信頼性及び安全性を向上させることができる。   Further, as shown in FIG. 3, the external connection portion 133g is inclined toward the case lid member 113 by an angle θ2 = 10 degrees with respect to the case lid member 113. This angle θ2 is preferably 1 to 30 degrees. By providing the external connection portion 133g with the angle θ2 in this manner, an external connection terminal such as a bus bar is brought into contact with the connection portion surface 133ga, and a nut or the like is fastened to the male screw portion 135e of the fastening member 135 described later. In such a case, it is possible to prevent loosening of the nut or the like. As a result, an increase in contact resistance between the external connection portion 133g and the external connection terminal can be suppressed, and problems such as abnormal heat generation of the lithium secondary battery 100 can be surely prevented. And safety can be improved.

次に、締結部材135について説明する(図1及び図2参照)。締結部材135は、締結部材135は、自身の外周に雄ネジが形成された雄ネジ部135eと、これよりも径大な基部135fとからなる。
このうち雄ネジ部135eは、ケース蓋部材113に直交する方向(上下方向)に延びる形態に外部接続部113gのネジ挿通孔133ghに挿通されており、上記のように外周に雄ネジが形成されている。なお、図1及び図2においては、雄ネジの記載を省略してある。
Next, the fastening member 135 will be described (see FIGS. 1 and 2). The fastening member 135 includes a male screw portion 135e having a male screw formed on the outer periphery thereof, and a base portion 135f having a larger diameter than that.
Among these, the male screw portion 135e is inserted into the screw insertion hole 133gh of the external connection portion 113g in a form extending in a direction (vertical direction) orthogonal to the case lid member 113, and the male screw is formed on the outer periphery as described above. ing. In FIG. 1 and FIG. 2, the description of the male screw is omitted.

基部135fは、円板状をなす円板部135f1と、この円板部153f1のケース蓋部材113側に位置し、円板部135f1よりも若干径小で、外形が六角柱状をなす六角部135f2とからなる。この基部135fは、雄ネジ部135e及び外部配置端子部材133の外部接続部133gよりもケース蓋部材113側に位置している。そして、基部135fのうち、ケース蓋部材113側とは逆側(上側)を向く基部表面135faが、外部接続部133gの接続部裏面133gbに当接して、締結部材135が外部端子部材133に電気的に接続している。また、この基部135fの六角部135f2は、後述する外部絶縁部材150の基部用凹部151fnに嵌合しており、これにより、締結部材135がその軸線周りに回転不能な状態とされている。   The base portion 135f is a disc-shaped disc portion 135f1 and is located on the case lid member 113 side of the disc portion 153f1, and is slightly smaller in diameter than the disc portion 135f1 and has an outer shape of a hexagonal column 135f2. It consists of. The base part 135f is located closer to the case lid member 113 than the external threaded part 135e and the external connection part 133g of the externally arranged terminal member 133. Of the base portion 135f, the base surface 135fa facing the side opposite to the case lid member 113 (upper side) abuts on the connection portion back surface 133gb of the external connection portion 133g, and the fastening member 135 is electrically connected to the external terminal member 133. Connected. In addition, the hexagonal portion 135f2 of the base portion 135f is fitted into a base recess portion 151fn of the external insulating member 150 described later, whereby the fastening member 135 is in a state in which the fastening member 135 cannot rotate about its axis.

次に、電極端子部材130,140と共にケース蓋部材113に固定された外部絶縁部材150,150について説明する(図1,図2及び図4参照)。この外部絶縁部材150は、電極端子部材130,140とケース蓋部材113との間に配置されて、電極端子部材130,140とケース蓋部材113とが接触して短絡することを防止している。この外部絶縁部材150は、樹脂(具体的には100%PPS)から形成されている。   Next, the external insulating members 150 and 150 fixed to the case lid member 113 together with the electrode terminal members 130 and 140 will be described (see FIGS. 1, 2 and 4). The external insulating member 150 is disposed between the electrode terminal members 130 and 140 and the case lid member 113 to prevent the electrode terminal members 130 and 140 and the case lid member 113 from contacting and short-circuiting. . The external insulating member 150 is made of resin (specifically, 100% PPS).

この外部絶縁部材150は、電池ケース110の外部(ケース蓋部材113上)に配置されると共に、ケース蓋部材113の端子挿通孔113h内に配置されている。即ち、この外部絶縁部材150は、外部配置端子部材133とケース蓋部材113の表面113aとの間、及び、締結部材135とケース蓋部材113の表面113aとの間に介在している。これにより、外部配置端子部材133とケース蓋部材113との間が絶縁されると共に、締結部材135とケース蓋部材113との間が絶縁されている。また、この外部絶縁部材150は、要素接続部材131の挿通部131fとケース蓋部材113の端子挿通孔113hの内周面113haとの間に介在している。これにより、要素接続部材131の挿通部131fとケース蓋部材113との間が絶縁されている。   The external insulating member 150 is disposed outside the battery case 110 (on the case lid member 113) and is disposed in the terminal insertion hole 113h of the case lid member 113. That is, the external insulating member 150 is interposed between the externally arranged terminal member 133 and the surface 113a of the case lid member 113, and between the fastening member 135 and the surface 113a of the case lid member 113. Accordingly, the externally arranged terminal member 133 and the case lid member 113 are insulated from each other, and the fastening member 135 and the case lid member 113 are insulated from each other. The external insulating member 150 is interposed between the insertion portion 131 f of the element connection member 131 and the inner peripheral surface 113 ha of the terminal insertion hole 113 h of the case lid member 113. Thereby, the insertion portion 131f of the element connection member 131 and the case lid member 113 are insulated.

詳細には、外部絶縁部材150は、外部配置端子部材133の固定部133eの固定部裏面133ebとケース蓋部材113の表面113aとの間に介在している。即ち、外部絶縁部材150には、ケース蓋部材113側(下側)に凹み、ケース蓋部材113とは逆側(上側)に開口する平面視矩形状の固定部用凹部150fmが形成されている。そして、この固定部用凹部150fm内に外部配置端子部材133の固定部133eが収まっている。   Specifically, the external insulating member 150 is interposed between the fixed portion back surface 133 eb of the fixed portion 133 e of the externally arranged terminal member 133 and the front surface 113 a of the case lid member 113. That is, the external insulating member 150 is formed with a recess 150fm for a fixing portion that is recessed in the case lid member 113 (lower side) and has a rectangular shape in plan view that opens on the opposite side (upper side) of the case lid member 113. . And the fixing | fixed part 133e of the external arrangement | positioning terminal member 133 is settled in this recessed part 150fm for fixing | fixed parts.

また、外部絶縁部材150は、締結部材135の基部135fとケース蓋部材113の表面113aとの間に介在している。即ち、外部絶縁部材150には、ケース蓋部材113側(下側)に凹み、ケース蓋部材113とは逆側(上側)に開口する平面視六角形状の基部用凹部150fnが形成されている。そして、この基部用凹部150fm内に締結部材135の基部135fの六角部135f2が収まっている。これにより、締結部材135が、その軸線周りに回転不能な状態となっている。   The external insulating member 150 is interposed between the base portion 135 f of the fastening member 135 and the surface 113 a of the case lid member 113. In other words, the external insulating member 150 is formed with a base recess 150fn that is recessed on the case lid member 113 side (lower side) and opened on the opposite side (upper side) of the case lid member 113 in a plan view. The hexagonal portion 135f2 of the base portion 135f of the fastening member 135 is accommodated in the base recess portion 150fm. As a result, the fastening member 135 is in a state in which it cannot rotate around its axis.

次に、電極端子部材130,140と共にケース蓋部材113に固定されたシールゴム160,160について説明する。このシールゴム160は、樹脂からなり、ケース蓋部材113と要素接続部材131の要素接続本体部131eとの間に、厚み方向に圧縮された状態で狭持されている。このシールゴム160は、円環板状をなし、その内側には、要素接続部材131の挿通部131fが挿通されている。このシールゴム160により、ケース蓋部材113と要素接続部材131の要素接続本体部131eとの間の絶縁及びシールが行われている。   Next, the seal rubbers 160 and 160 fixed to the case lid member 113 together with the electrode terminal members 130 and 140 will be described. The seal rubber 160 is made of resin, and is sandwiched between the case lid member 113 and the element connection main body 131e of the element connection member 131 in a compressed state in the thickness direction. The seal rubber 160 has an annular plate shape, and an insertion portion 131f of the element connection member 131 is inserted inside the seal rubber 160. The seal rubber 160 provides insulation and sealing between the case lid member 113 and the element connection main body 131e of the element connection member 131.

次に、電極端子部材130,140と共にケース蓋部材113に固定された内部絶縁部材170,170について説明する。この内部絶縁部材170は、介在部170eと側壁部170fと側方部170gとから構成されている。この内部絶縁部材170は、樹脂製、具体的には、PPS樹脂から形成されている。
介在部170eは、シールゴム160の径方向外側に配置されると共に、ケース蓋部材113と要素接続部材131の要素接続本体部131eとの間に配置されている。これにより、ケース蓋部材113と要素接続部材131の要素接続本体部131eとの間を絶縁できると共に、シールゴム160の厚みを所定の厚みに規制できる。
側壁部170fは、この介在部170eの径方向外側に位置し、この介在部170eからケース蓋部材113側とは逆側(下側)に延びている。
Next, the internal insulating members 170 and 170 fixed to the case lid member 113 together with the electrode terminal members 130 and 140 will be described. The internal insulating member 170 includes an interposition part 170e, a side wall part 170f, and a side part 170g. The internal insulating member 170 is made of resin, specifically, PPS resin.
The interposition part 170e is disposed on the outer side in the radial direction of the seal rubber 160, and is disposed between the case lid member 113 and the element connection main body part 131e of the element connection member 131. Thereby, it is possible to insulate between the case lid member 113 and the element connection main body 131e of the element connection member 131, and to regulate the thickness of the seal rubber 160 to a predetermined thickness.
The side wall portion 170f is located on the radially outer side of the interposition portion 170e, and extends from the interposition portion 170e to the opposite side (lower side) to the case lid member 113 side.

側方部170gは、介在部170e及び側壁部170fの側方に連なって、ケース蓋部材113と電極体120との間に配置されている。これにより、ケース蓋部材113と電極体120とが接触することを確実に防止している。また、この側方部170gが存在することにより、電極体120がケース蓋部材113側に移動することを防止できるので、電極体120と、ケース蓋部材113の中央に設けられた安全弁部113jとが、常に所定距離以上離間された状態を維持できる。これにより、電極体120が安全弁部113jを塞いでしまうことを防止できる。   The side portion 170g is arranged between the case lid member 113 and the electrode body 120 so as to continue to the sides of the interposition portion 170e and the side wall portion 170f. This reliably prevents the case lid member 113 and the electrode body 120 from contacting each other. Further, since the electrode body 120 can be prevented from moving toward the case lid member 113 due to the presence of the side portion 170g, the electrode body 120 and the safety valve portion 113j provided at the center of the case lid member 113 are provided. However, it is possible to always maintain a state where they are separated by a predetermined distance or more. Thereby, it can prevent that the electrode body 120 block | closes the safety valve part 113j.

以上で説明したように、本実施形態1のリチウム二次電池100は、要素接続部材131の加締部131gを外部配置端子部材133の固定部133eに加締め固定した上で、更にこれらを溶接している。このため、これら加締部131gと固定部133eとの接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。   As described above, in the lithium secondary battery 100 according to the first embodiment, the caulking portion 131g of the element connection member 131 is caulked and fixed to the fixing portion 133e of the externally arranged terminal member 133, and these are further welded. doing. For this reason, it is possible to sufficiently secure the connection strength between the caulking portion 131g and the fixing portion 133e, and to prevent the contact resistance from increasing even when used for a long period of time.

しかも、加締部131gと固定部133eとの溶接が、加締部131gのうちの加締外周部131gd、及び、固定部133eのうちの固定部外周部133edにおいてのみ、行われている。加締部131gを変形させて固定部133eに加締め固定する際、加締部131gは固定孔133ehの外側端部133eh2に隙間なく密着する。一方、加締部131gの加締外周部131gdを固定部133eの固定部外周部133edに押し付けるように変形してもスプリングバックが生じるので、これらの間には僅かに隙間が生じる。このため、加締部131gと固定部133eとの溶接を加締外周部131gd及び固定部外周部133edで行えば、溶接の際に生じるガスが上記隙間を通じて径方向外側に移動し外部に放出されやすいので、溶接時にブローホールが発生し溶接不良が生じるのを効果的に抑制できる。従って、加締部131gと固定部131eとの溶接を確実に行うことができるので、両者の接続信頼性を特に向上させることができる。   In addition, welding of the crimped portion 131g and the fixed portion 133e is performed only at the crimped outer peripheral portion 131gd of the crimped portion 131g and the fixed portion outer peripheral portion 133ed of the fixed portion 133e. When the caulking portion 131g is deformed and is caulked and fixed to the fixing portion 133e, the caulking portion 131g closely contacts the outer end portion 133eh2 of the fixing hole 133eh without any gap. On the other hand, even if the crimping outer peripheral portion 131gd of the crimping portion 131g is deformed so as to be pressed against the fixing portion outer peripheral portion 133ed of the fixing portion 133e, a springback is generated, so that a slight gap is generated between them. For this reason, if welding of the caulking portion 131g and the fixing portion 133e is performed at the caulking outer peripheral portion 131gd and the fixing portion outer peripheral portion 133ed, the gas generated during welding moves radially outward through the gap and is released to the outside. Since it is easy, it can suppress effectively that a blowhole generate | occur | produces at the time of welding and a welding defect arises. Therefore, since the welding of the caulking portion 131g and the fixing portion 131e can be reliably performed, the connection reliability between them can be particularly improved.

更に、本実施形態1では、固定孔133ehの外側端部133eh2の中心軸AXとのなす角(傾斜角)θ1を20度以上(具体的には傾斜角θ1=30度)としているので、加締めによる接続強度を十分に確保できる。一方、固定孔133ehの外側端部133eh2の傾斜角θ1を45度以下としているので、開口径を適切な大きさに収めることができ、加締部131gの加締外周部131gdと固定部133eの固定部外周部133edとの溶接可能な面積を十分に確保できる。このため、加締部131gを固定部133eに溶接する際に、加締部131gのうちの加締外周部131gdと固定部133eのうちの固定部外周部133edとを確実に溶接できる。従って、固定孔133ehの外側端部133eh2の傾斜角θ1を20度〜45度とすることで、加締部131gと固定部133eとの接続信頼性を更に向上させることができる。   Furthermore, in the first embodiment, the angle (inclination angle) θ1 formed with the central axis AX of the outer end portion 133eh2 of the fixing hole 133eh is set to 20 degrees or more (specifically, the inclination angle θ1 = 30 degrees). Connection strength by tightening can be sufficiently secured. On the other hand, since the inclination angle θ1 of the outer end portion 133eh2 of the fixing hole 133eh is set to 45 degrees or less, the opening diameter can be set to an appropriate size, and the crimping outer peripheral portion 131gd of the crimping portion 131g and the fixing portion 133e An area that can be welded to the outer peripheral portion 133ed of the fixed portion can be sufficiently secured. For this reason, when welding the crimping part 131g to the fixing | fixed part 133e, the crimping outer peripheral part 131gd of the crimping part 131g and the fixing | fixed part outer peripheral part 133ed of the fixing | fixed part 133e can be welded reliably. Therefore, the connection reliability between the caulking portion 131g and the fixing portion 133e can be further improved by setting the inclination angle θ1 of the outer end portion 133eh2 of the fixing hole 133eh to 20 ° to 45 °.

また、本実施形態1では、加締部131gの加締外周部131gdの径方向寸法LA を0.5mm以上(具体的には径方向寸法LA=1.0mm)と大きくしているので、加締部131gの加締外周部131gdと固定部133eの固定部外周部133edとの溶接可能な面積を十分に確保できる。このため、加締部131gを固定部133eに溶接する際に、加締部131gの加締外周部131gdと固定部133eの固定部外周部133edとを確実に溶接できる。従って、加締部131gと固定部133eとの接続信頼性を更に向上させることができる。   In Embodiment 1, the radial dimension LA of the crimping outer peripheral part 131gd of the crimping part 131g is increased to 0.5 mm or more (specifically, the radial dimension LA = 1.0 mm). It is possible to secure a sufficient weldable area between the caulking outer peripheral portion 131gd of the tightening portion 131g and the fixing portion outer peripheral portion 133ed of the fixing portion 133e. For this reason, when welding the crimping part 131g to the fixing | fixed part 133e, the crimping outer peripheral part 131gd of the crimping part 131g and the fixing | fixed part outer peripheral part 133ed of the fixing | fixed part 133e can be welded reliably. Therefore, the connection reliability between the caulking portion 131g and the fixing portion 133e can be further improved.

次いで、上記リチウム二次電池100の製造方法について説明する。
電極体120と要素接続部材131,131をそれぞれ用意する。そして、電極体120の軸方向の両端に、正極用の要素接続部材131と負極用の要素接続部材131を溶接する。その後、各要素接続部材131,131の挿通部131f,131fにそれぞれシールゴム160,160を配置する。また、各シールゴム160,160の径方向外側にそれぞれ内部絶縁部材170,170を配置する。更に、各内部絶縁部材170,170の上に、ケース蓋部材113を配置し、ケース蓋部材113の端子挿通孔113h,113hに、各要素接続部材131,131の挿通部131f,131fを挿入する。
Next, a method for manufacturing the lithium secondary battery 100 will be described.
An electrode body 120 and element connecting members 131 and 131 are prepared. Then, the positive electrode element connecting member 131 and the negative electrode element connecting member 131 are welded to both ends of the electrode body 120 in the axial direction. Thereafter, the seal rubbers 160 and 160 are disposed in the insertion portions 131f and 131f of the element connection members 131 and 131, respectively. In addition, internal insulating members 170 and 170 are disposed on the radially outer sides of the seal rubbers 160 and 160, respectively. Furthermore, the case lid member 113 is disposed on each internal insulating member 170, 170, and the insertion portions 131 f and 131 f of the element connection members 131 and 131 are inserted into the terminal insertion holes 113 h and 113 h of the case lid member 113. .

次に、このうちのケース蓋部材113上に、外部絶縁部材150を配置し、更にその上に、外部配置端子部材133と締結部材135を配置する。その際、各外部配置端子部材133,133の固定部133e,133eの固定孔133eh,133ehに、各要素接続部材131,131の挿通部131f,131fを挿入する。その後、各要素接続部材131,131のうち、固定孔133eh,133ehから突出した部分を加締めて拡大し、加締部131g,131gを形成する。   Next, the external insulating member 150 is disposed on the case lid member 113, and the externally disposed terminal member 133 and the fastening member 135 are further disposed thereon. At that time, the insertion portions 131f and 131f of the element connection members 131 and 131 are inserted into the fixing holes 133eh and 133eh of the fixing portions 133e and 133e of the externally arranged terminal members 133 and 133, respectively. Thereafter, portions of the element connection members 131 and 131 that protrude from the fixing holes 133eh and 133eh are swaged and enlarged to form swaged portions 131g and 131g.

その後、要素接続部材131の加締部131gを外部配置端子部材133,133の固定部133eに溶接する。具体的には、加締部131gのうちの加締外周部131gdと固定部133eのうちの固定部外周部133edとを溶接し、溶接部132を形成する。この溶接は、レーザ溶接や電子ビーム溶接などにより行えばよい。その際、前述のようにブローホールが発生し溶接不良が生じるのを効果的に抑制できるので、加締部131gと固定部133eとの溶接を確実に行うことができ、両者の接続信頼性を特に向上させることができる。   Thereafter, the caulking portion 131g of the element connecting member 131 is welded to the fixing portion 133e of the externally arranged terminal members 133 and 133. Specifically, the caulking outer peripheral portion 131gd of the caulking portion 131g and the fixed portion outer peripheral portion 133ed of the fixing portion 133e are welded to form the welded portion 132. This welding may be performed by laser welding or electron beam welding. At that time, it is possible to effectively suppress the occurrence of poor welding due to the occurrence of blowholes as described above, so that the crimping portion 131g and the fixing portion 133e can be reliably welded, and the connection reliability between them can be improved. In particular, it can be improved.

次に、このうちの電極体120を、別途用意した絶縁フィルム包囲体125内に挿入する。その後、電極体120及び絶縁フィルム包囲体125がケース本体部材111内に収容されるようにして、ケース蓋部材113をケース本体部材111の開口111h上に配置する。そして、ケース蓋部材113の周縁部分とケース本体部材111の開口111h周縁とをレーザ溶接する。その後、ケース蓋部材113の注液口部113mから電池ケース110内に電解液を注入し、この注液口部113mを封止する。かくして、リチウム二次電池100が完成する。   Next, the electrode body 120 is inserted into the separately prepared insulating film enclosure 125. Thereafter, the case lid member 113 is disposed on the opening 111 h of the case body member 111 such that the electrode body 120 and the insulating film enclosure 125 are accommodated in the case body member 111. Then, the peripheral portion of the case lid member 113 and the peripheral edge of the opening 111h of the case main body member 111 are laser-welded. Thereafter, an electrolytic solution is injected into the battery case 110 from the liquid inlet portion 113m of the case lid member 113, and the liquid inlet portion 113m is sealed. Thus, the lithium secondary battery 100 is completed.

(実施形態2)
次いで、第2の実施の形態について説明する。本実施形態2のリチウム二次電池200は、外部配置端子部材233の固定部233eの固定孔233ehの形態が、上記実施形態1の外部配置端子部材133の固定部133eの固定孔133ehの形態と異なる。それ以外は、基本的に上記実施形態1と同様であるので、上記実施形態1と同様な部分の説明は、省略または簡略化する。図6〜図8に、本実施形態2に係る外部配置端子部材233を示す。
(Embodiment 2)
Next, a second embodiment will be described. In the lithium secondary battery 200 of the second embodiment, the form of the fixing hole 233eh of the fixing part 233e of the externally arranged terminal member 233 is different from the form of the fixing hole 133eh of the fixing part 133e of the externally arranged terminal member 133 of the first embodiment. Different. Other than that, it is basically the same as in the first embodiment, and therefore the description of the same parts as in the first embodiment is omitted or simplified. 6 to 8 show an externally arranged terminal member 233 according to the second embodiment.

本実施形態2の外部配置端子部材233は、固定部233eと中間部133fと外部接続部133gとからなり、Z字状(段状)をなす。このうち、中間部133fと外部接続部133gの形態は、上記実施形態1と同様である。
一方、固定部233eは、ケース蓋部材113側とは逆側(上側)を向く固定部表面233eaと、ケース蓋部材113側(下側)を向く固定部裏面213ebとを有する板状をなす。この固定部233eには、自身を貫通する固定孔233ehが形成され、上記実施形態1と同様に、要素接続部材131の挿通部131fが挿通されている。
The externally arranged terminal member 233 of the second embodiment includes a fixed portion 233e, an intermediate portion 133f, and an external connection portion 133g, and has a Z shape (step shape). Among these, the form of the intermediate part 133f and the external connection part 133g is the same as that of the first embodiment.
On the other hand, the fixing portion 233e has a plate shape having a fixing portion surface 233ea facing the side opposite to the case lid member 113 (upper side) and a fixing portion rear surface 213eb facing the case lid member 113 side (lower side). The fixing portion 233e is formed with a fixing hole 233eh that passes through the fixing portion 233e, and the insertion portion 131f of the element connection member 131 is inserted in the same manner as in the first embodiment.

この固定孔233ehは、ケース蓋部材113側(下側)に位置し、開口径が一定の円孔とされた円孔部233eh1と、ケース蓋部材113側とは逆側(上側)に位置し、電池外部に(上側に)向かって直線的に拡大するテーパ形状をなす外側端部233eh2とからなる。
このうち外側端部233eh2は、自身の周方向に交互に配置された2つの第1外側端部233eh21,233eh21と2つの第2外側端部233eh22,233eh22を有する。第1外側端部233eh1と固定孔233ehの中心軸AXとのなす角(傾斜角)θ11は、第2外側端部233eh2と固定孔233ehの中心軸AXとのなす角(傾斜角)θ12よりも大きくされている。具体的には、第1外側端部233eh21の傾斜角はθ11=45度とされ、第2外側端部233eh22の傾斜角はθ12=30度とされている。
The fixing hole 233eh is located on the case lid member 113 side (lower side), and is located on the opposite side (upper side) of the circular hole portion 233eh1 having a constant opening diameter and the case lid member 113 side. And an outer end portion 233eh2 having a tapered shape that linearly expands toward the outside of the battery (upward).
Of these, the outer end portion 233eh2 has two first outer end portions 233eh21 and 233eh21 and two second outer end portions 233eh22 and 233eh22 that are alternately arranged in the circumferential direction of the outer end portion 233eh2. An angle (inclination angle) θ11 formed between the first outer end portion 233eh1 and the central axis AX of the fixing hole 233eh is larger than an angle (inclination angle) θ12 formed between the second outer end portion 233eh2 and the central axis AX of the fixing hole 233eh. It has been enlarged. Specifically, the inclination angle of the first outer end portion 233eh21 is θ11 = 45 degrees, and the inclination angle of the second outer end portion 233eh22 is θ12 = 30 degrees.

また、この固定部233eには、要素接続部材131の加締部131gが加締め及び溶接により接続している。具体的には、加締部131gの加締中央部131gcが、固定部233eの固定孔233ehの外側端部233eh2に加締めにより隙間なく当接すると共に、加締部131gの加締外周部131gdが、固定部233eのうち、固定孔233ehの外側端部233eh2よりも径方向外側に位置する固定部外周部233ed上に位置している。そして、加締部131gのうちの加締外周部131gdが、固定部233eの固定部外周部233edに溶接されている。本実施形態2では、溶接部232は、固定部外周部233edのうち、固定孔233ehの2つの第2外側端部233eh22,233eh22の径方向外側にそれぞれ(合計2つ)形成されている。   Further, a caulking portion 131g of the element connecting member 131 is connected to the fixing portion 233e by caulking and welding. Specifically, the caulking central portion 131gc of the caulking portion 131g abuts the outer end portion 233eh2 of the fixing hole 233eh of the fixing portion 233e without any gap by caulking, and the caulking outer peripheral portion 131gd of the caulking portion 131g Of the fixing portion 233e, the fixing portion 233e is positioned on the outer peripheral portion 233ed of the fixing portion that is positioned radially outward from the outer end portion 233eh2 of the fixing hole 233eh. And the crimping outer peripheral part 131gd of the crimping part 131g is welded to the fixing | fixed part outer peripheral part 233ed of the fixing | fixed part 233e. In the second embodiment, the welded portion 232 is formed on the radially outer side of the two second outer end portions 233eh22 and 233eh22 of the fixed hole 233eh in the fixed portion outer peripheral portion 233ed (two in total).

本実施形態2のリチウム二次電池200も、要素接続部材131の加締部131gを外部配置端子部材233の固定部233eに加締め固定した上で、更にこれらを溶接しているので、これらの接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。
しかも、加締部131gと固定部233eとは、加締部131gのうちの加締外周部131gd、及び、固定部233eのうちの固定部外周部233edにおいてのみ、互いに溶接されている(図5参照)。このため、加締部131gと固定部233eとの溶接を加締外周部131gd及び固定部外周部233edの部分で行う際に、溶接の際に生じるガスが両者の隙間を通じて径方向外側に移動し外部に放出されやすいので、溶接時にブローホールが発生し溶接不良が生じるのを抑制できる。従って、加締部131gと固定部233eとの溶接を確実に行うことができるので、両者の接続信頼性を特に向上させることができる。
In the lithium secondary battery 200 of the second embodiment, the caulking portion 131g of the element connection member 131 is caulked and fixed to the fixing portion 233e of the externally arranged terminal member 233, and these are further welded. A sufficient connection strength can be secured, and an increase in these contact resistances can be prevented even when used for a long period of time.
Moreover, the caulking portion 131g and the fixing portion 233e are welded to each other only at the caulking outer peripheral portion 131gd of the caulking portion 131g and the fixing portion outer peripheral portion 233ed of the fixing portion 233e (FIG. 5). reference). For this reason, when welding the caulking portion 131g and the fixing portion 233e at the caulking outer peripheral portion 131gd and the fixing portion outer peripheral portion 233ed, the gas generated during welding moves radially outward through the gap between the two. Since it is easy to discharge | release outside, it can suppress that a blow hole generate | occur | produces at the time of welding and a welding defect arises. Therefore, since it is possible to reliably weld the caulking portion 131g and the fixing portion 233e, it is possible to particularly improve the connection reliability between them.

更に、本実施形態2では、固定孔233ehの外側端部233eh2を、傾斜角θ11,θ12が互いに異なる第1外側端部233eh21,233eh21及び第2外側端部233eh22,233eh22を周方向に配置した形態とし、周方向に方向性を持たせている。このため、要素接続部材131の加締部131gと外部配置端子部材233の固定部233eとが相対的に回転することを効果的に防止できる。   Further, in the second embodiment, the outer end 233eh2 of the fixing hole 233eh is arranged in the circumferential direction with the first outer end 233eh21, 233eh21 and the second outer end 233eh22, 233eh22 having different inclination angles θ11, θ12. The directionality is given to the circumferential direction. For this reason, it can prevent effectively that the crimping part 131g of the element connection member 131 and the fixing | fixed part 233e of the external arrangement | positioning terminal member 233 rotate relatively.

また、本実施形態2では、第2外側端部233eh22の傾斜角θ12(具体的にはθ12=30度)が第1外側端部233eh21の傾斜角θ11(具体的にはθ11=45度)よりも小さいため、第2外側端部233eh22の外径が小さい。このため、第2外側端部233eh22の径方向外側においては、加締部131gの加締外周部131gdと固定部233eの固定部外周部233edとの溶接可能な面積を十分に確保できるので、加締部131gを固定部233eに溶接する際に、加締部131gのうちの加締外周部131gdと固定部233eのうちの固定部外周部233edとを確実に溶接できる。従って、加締部131gと固定部233eとが相対的に回転することを効果的に防止できる上に、加締部131gと固定部233eとの接続信頼性を更に向上させることができる。その他、上記実施形態1と同様な部分は、同様な作用効果を奏する。   In the second embodiment, the inclination angle θ12 (specifically θ12 = 30 degrees) of the second outer end portion 233eh22 is greater than the inclination angle θ11 (specifically θ11 = 45 degrees) of the first outer end portion 233eh21. Therefore, the outer diameter of the second outer end 233eh22 is small. For this reason, on the outer side in the radial direction of the second outer end portion 233eh22, a sufficient weldable area can be secured between the caulking outer peripheral portion 131gd of the caulking portion 131g and the fixing portion outer peripheral portion 233ed of the fixing portion 233e. When welding the tightening portion 131g to the fixing portion 233e, the crimping outer peripheral portion 131gd of the crimping portion 131g and the fixing portion outer peripheral portion 233ed of the fixing portion 233e can be reliably welded. Therefore, the caulking part 131g and the fixing part 233e can be effectively prevented from rotating relatively, and the connection reliability between the caulking part 131g and the fixing part 233e can be further improved. In addition, the same parts as those of the first embodiment have the same effects.

(実施形態3)
次いで、第3の実施の形態について説明する。本実施形態3のリチウム二次電池300は、外部配置端子部材333の外部接続部333gの形態が、上記実施形態1,2の外部配置端子部材133,233の外部接続部133gの形態と異なる。それ以外は、基本的に上記実施形態1等と同様であるので、上記実施形態1等と同様な部分の説明は、省略または簡略化する。図9及び図10に、本実施形態3に係る外部配置端子部材333を示す。
(Embodiment 3)
Next, a third embodiment will be described. In the lithium secondary battery 300 of Embodiment 3, the form of the external connection portion 333g of the external placement terminal member 333 is different from the form of the external connection portion 133g of the external placement terminal member 133, 233 of Embodiments 1 and 2. Other than that, it is basically the same as in the first embodiment, and therefore, the description of the same parts as in the first embodiment is omitted or simplified. 9 and 10 show an externally arranged terminal member 333 according to the third embodiment.

本実施形態3の外部配置端子部材333は、固定部133eと中間部133fと外部接続部333gとからなり、Z字状(段状)をなす。このうち、固定部133eと中間部133fの形態は、上記実施形態1と同様である。
一方、外部接続部333gは、ケース蓋部材113側とは逆側(上側)を向く接続部表面333gaと、ケース蓋部材113側(下側)を向く接続部裏面333gbとを有する板状をなす。この外部接続部333gは、中間部133fに連なり、ケース蓋部材113に沿って延び、自身を貫通するネジ挿通孔333ghが形成されている。
The externally arranged terminal member 333 according to the third embodiment includes a fixed portion 133e, an intermediate portion 133f, and an external connection portion 333g, and has a Z shape (step shape). Among these, the form of the fixing | fixed part 133e and the intermediate part 133f is the same as that of the said Embodiment 1. FIG.
On the other hand, the external connection portion 333g has a plate shape having a connection portion surface 333ga facing the side opposite to the case lid member 113 (upper side) and a connection portion rear surface 333gb facing the case lid member 113 side (lower side). . The external connection portion 333g is connected to the intermediate portion 133f, extends along the case lid member 113, and is formed with a screw insertion hole 333gh penetrating through the external connection portion 333g.

本実施形態3では、外部接続部333gには、固定部133e側とは反対側に位置する先端部333gsに切れ込み部333gjが形成され、外部接続部333gが平面視C字状とされている。そして、切れ込み部333gjにより2つに分割された先端部333gs,333gsは、ケース蓋部材113に直交する方向(上下方向)において、段違い(高さ違い)となるように加工されている。即ち、分割された2つの先端部333gs,333gsの一方(図10中、左側)は、ケース蓋部材113側(下側)に位置し、他方(図10中、左側)は、これよりもケース蓋部材113側とは逆側(上側)に位置している。   In the third embodiment, the external connection portion 333g is formed with a notch 333gj at a tip portion 333gs located on the side opposite to the fixed portion 133e side, and the external connection portion 333g is C-shaped in a plan view. And the front-end | tip parts 333gs and 333gs divided | segmented into two by the notch | incision part 333gj are processed so that it may become a level | step difference (height difference) in the direction (up-down direction) orthogonal to the case cover member 113. That is, one of the two divided tip portions 333gs and 333gs (left side in FIG. 10) is located on the case lid member 113 side (lower side), and the other (left side in FIG. 10) is the case. It is located on the opposite side (upper side) from the lid member 113 side.

このように外部接続部333gの2つの先端部333gs,333gsを段違いとすることにより、接続部表面333gaにバスバーなどの外部の接続端子を当接させて、締結部材135の雄ネジ部135eにナット等を締結した場合に、ナット等の緩みを防止できる。その結果、外部接続部333gと外部の接続端子との接触抵抗の増加を抑えることができ、リチウム二次電池300の異常発熱等の不具合を確実に防止できるので、リチウム二次電池300の信頼性及び安全性を向上させることができる。その他、上記実施形態1等と同様な部分は、上記実施形態1等と同様な作用効果を奏する。   In this way, the two front end portions 333gs and 333gs of the external connection portion 333g are stepped so that an external connection terminal such as a bus bar is brought into contact with the connection portion surface 333ga, and a nut is attached to the male screw portion 135e of the fastening member 135. Etc., the nuts can be prevented from loosening. As a result, an increase in contact resistance between the external connection portion 333g and an external connection terminal can be suppressed, and problems such as abnormal heat generation of the lithium secondary battery 300 can be reliably prevented. And safety can be improved. In addition, the same parts as those in the first embodiment have the same effects as those in the first embodiment.

(実施形態4)
次いで、第4の実施の形態について説明する。本実施形態4に係る車両700は、上記実施形態1のリチウム二次電池(電池)100を複数搭載したものである。具体的には、図11に示すように、この車両700は、エンジン740、フロントモータ720及びリアモータ730を併用して駆動するハイブリッド自動車である。この車両700は、車体790、エンジン740、これに取り付けられたフロントモータ720、リアモータ730、ケーブル750、インバータ760を備える。更に、この車両700は、複数のリチウム二次電池100を自身の内部に有する組電池710を備え、この組電池710による電気エネルギーを、フロントモータ720及びリアモータ730の駆動に利用している。
(Embodiment 4)
Next, a fourth embodiment will be described. A vehicle 700 according to the fourth embodiment includes a plurality of lithium secondary batteries (batteries) 100 according to the first embodiment. Specifically, as shown in FIG. 11, the vehicle 700 is a hybrid vehicle that is driven by using an engine 740, a front motor 720, and a rear motor 730 in combination. The vehicle 700 includes a vehicle body 790, an engine 740, a front motor 720, a rear motor 730, a cable 750, and an inverter 760 attached thereto. Further, the vehicle 700 includes an assembled battery 710 having a plurality of lithium secondary batteries 100 therein, and electric energy from the assembled battery 710 is used to drive the front motor 720 and the rear motor 730.

前述したように、リチウム二次電池100は、従来に比して、要素接続部材131の加締部131gと外部配置端子部材133の固定部133eとの接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。また、これら加締部131gと固定部133eとの溶接を確実に行うことができるので、両者の接続信頼性を特に向上させることができる。従って、このリチウム二次電池100を搭載する車両700の信頼性を向上させることができる。   As described above, the lithium secondary battery 100 can sufficiently secure the connection strength between the crimped portion 131g of the element connecting member 131 and the fixing portion 133e of the externally arranged terminal member 133, compared to the conventional case, and can be used for a long time. These contact resistances can be prevented from increasing even when used over a wide range. In addition, since the crimping portion 131g and the fixing portion 133e can be reliably welded, the connection reliability between them can be particularly improved. Therefore, the reliability of the vehicle 700 equipped with the lithium secondary battery 100 can be improved.

(実施形態5)
次いで、第5の実施の形態について説明する。本実施形態5のハンマードリル800は、上記実施形態1のリチウム二次電池(電池)100を含むバッテリパック810を搭載した電池使用機器である。図12に示すように、このハンマードリル800は、本体820の底部821に、バッテリパック810が収容されており、このバッテリパック810を、ドリルを駆動するためのエネルギー源として利用している。
(Embodiment 5)
Next, a fifth embodiment will be described. The hammer drill 800 according to the fifth embodiment is a battery-operated device on which the battery pack 810 including the lithium secondary battery (battery) 100 according to the first embodiment is mounted. As shown in FIG. 12, this hammer drill 800 has a battery pack 810 accommodated in a bottom 821 of a main body 820, and this battery pack 810 is used as an energy source for driving the drill.

前述したように、リチウム二次電池100は、従来に比して、要素接続部材131の加締部131gと外部配置端子部材133の固定部133eとの接続強度を十分に確保でき、長期間に渡る使用でもこれらの接触抵抗が増加するのを防止できる。また、これら加締部131gと固定部133eとの溶接を確実に行うことができるので、両者の接続信頼性を特に向上させることができる。従って、このリチウム二次電池100を搭載するハンマードリル800の信頼性を向上させることができる。   As described above, the lithium secondary battery 100 can sufficiently secure the connection strength between the crimped portion 131g of the element connecting member 131 and the fixing portion 133e of the externally arranged terminal member 133, compared to the conventional case, and can be used for a long time. These contact resistances can be prevented from increasing even when used over a wide range. In addition, since the crimping portion 131g and the fixing portion 133e can be reliably welded, the connection reliability between them can be particularly improved. Therefore, the reliability of the hammer drill 800 on which the lithium secondary battery 100 is mounted can be improved.

以上において、本発明を実施形態に即して説明したが、本発明は上述の実施形態1〜5に限定されるものではなく、その要旨を逸脱しない範囲で、適宜変更して適用できることは言うまでもない。
例えば、上記実施形態1〜5では、電池として、リチウム二次電池100,200,300を例示したが、例えばニッケル水素電池、ニッケルカドミウム電池等の他の種類の二次電池などにも、本発明を適用できる。
また、上記実施形態1〜5では、捲回型の発電要素(電極体120)を有する電池100,200,300を例示したが、積層型の発電要素を有する電池などにも、本発明を適用できる。
In the above, the present invention has been described with reference to the embodiments. However, the present invention is not limited to the above-described first to fifth embodiments, and it is needless to say that the present invention can be appropriately modified and applied without departing from the gist thereof. Yes.
For example, in the first to fifth embodiments, the lithium secondary batteries 100, 200, and 300 are exemplified as the battery. However, the present invention is applicable to other types of secondary batteries such as a nickel hydrogen battery and a nickel cadmium battery. Can be applied.
In the first to fifth embodiments, the batteries 100, 200, and 300 having the wound type power generation element (electrode body 120) are exemplified. However, the present invention is also applied to a battery having a stacked type power generation element. it can.

100,200,300 リチウム二次電池(電池)
110 電池ケース
111 ケース本体部材
111h 開口
113 ケース蓋部材
113h 端子挿通孔
120 電極体(発電要素)
130 正極電極端子部材(電極端子部材)
131 要素接続部材
131e 要素接続本体部
131f 挿通部
131g 加締部
131gc 加締中央部
131gd 加締外周部
132,232 溶接部
133,233,333 外部配置端子部材
133e,233e 固定部
133ed,233ed 固定部外周部
133eh,233eh 固定孔
133eh1,233eh1 円孔部
133eh2,233eh2 外側端部
233eh21 第1外側端部
233eh22 第2外側端部
133f 中間部
133g,333g 外部接続部
133gh,333gh ネジ挿通孔
135 締結部材
135e 雄ネジ部
135f 基部
140 負極電極端子部材(電極端子部材)
150 外部絶縁部材
160 シールゴム
170 内部絶縁部材
700 車両
710 組電池(電池)
800 ハンマードリル(電池搭載機器)
810 バッテリパック(電池)
AX 中心軸
θ1,θ11,θ12 傾斜角
100, 200, 300 Lithium secondary battery (battery)
110 Battery case 111 Case body member 111h Opening 113 Case lid member 113h Terminal insertion hole 120 Electrode body (power generation element)
130 Positive Electrode Terminal Member (Electrode Terminal Member)
131 Element connection member 131e Element connection body 131f Insertion part 131g Clamping part 131gc Clamping center part 131gd Clamping outer peripheral part 132,232 Welding parts 133,233,333 Externally arranged terminal members 133e, 233e Fixing part 133ed, 233ed Fixing part Outer peripheral portion 133eh, 233eh Fixing hole 133eh1, 233eh1 Circular hole portion 133eh2, 233eh2 Outer end portion 233eh21 First outer end portion 233eh22 Second outer end portion 133f Intermediate portion 133g, 333g External connection portion 133gh, 333gh Screw insertion hole 135 Fastening member 135e Male screw part 135f Base part 140 Negative electrode terminal member (electrode terminal member)
150 External insulating member 160 Seal rubber 170 Internal insulating member 700 Vehicle 710 Battery assembly (battery)
800 Hammer drill (Battery-equipped equipment)
810 Battery pack (battery)
AX Center axis θ1, θ11, θ12 Inclination angle

Claims (7)

発電要素と、
開口をなし、前記発電要素を収容するケース本体部材、及び、このケース本体部材の前記開口を閉塞するケース蓋部材を有する電池ケースと、
前記電池ケースの内部で前記発電要素に接続すると共に、前記ケース蓋部材に形成された端子挿通孔を通じて前記ケース蓋部材上に延出する電極端子部材と、を備える
電池であって、
前記電極端子部材は、
前記電池ケースの内部で前記発電要素に接続すると共に、前記ケース蓋部材の前記端子挿通孔に挿通された要素接続部材と、
前記要素接続部材に接続し、前記電池ケースの外部のうち前記ケース蓋部材上に位置する外部配置端子部材と、を有し、
前記要素接続部材は、
前記電池ケースの内部に位置し、前記発電要素に接続する要素接続本体部と、
この要素接続本体部に連なり、前記ケース蓋部材の前記端子挿通孔に挿通された挿通部と、
この挿通部に連なり、電池外部に露出し、加締められ拡径されて傘状をなし、前記外部配置端子部材に係合する加締部と、を含み、
前記外部配置端子部材は、
前記ケース蓋部材に沿って延び、前記ケース蓋部材に固定された固定部であって、自身を貫通する固定孔に前記要素接続部材の前記挿通部が挿通されると共に、前記要素接続部材の前記加締部が係合する固定部を含み、
前記固定部の前記固定孔は、
少なくとも自身の外側端部が電池外部に向かって拡大するテーパ形状をなし、
前記加締部と前記固定部とは、
前記加締部のうち、前記固定孔の前記外側端部よりも径方向外側に位置する加締外周部、及び、前記固定部のうち、前記固定孔の前記外側端部よりも径方向外側に位置する固定部外周部においてのみ、互いに溶接されてなる
電池。
Power generation elements,
A battery case having an opening and housing the power generation element, and a case lid member that closes the opening of the case body member;
An electrode terminal member connected to the power generation element inside the battery case and extending onto the case lid member through a terminal insertion hole formed in the case lid member, and a battery comprising:
The electrode terminal member is
While connecting to the power generation element inside the battery case, an element connection member inserted through the terminal insertion hole of the case lid member,
An externally arranged terminal member connected to the element connecting member and positioned on the case lid member of the outside of the battery case;
The element connecting member is
An element connection main body located inside the battery case and connected to the power generation element;
The element connecting main body portion, the insertion portion inserted through the terminal insertion hole of the case lid member,
A caulking portion that is connected to the insertion portion, exposed to the outside of the battery, caulked and expanded in diameter to form an umbrella shape, and engages with the externally arranged terminal member,
The externally arranged terminal member is
A fixing portion that extends along the case lid member and is fixed to the case lid member, wherein the insertion portion of the element connection member is inserted into a fixing hole that penetrates the case lid member, and the element connection member Including a fixing portion with which the crimping portion is engaged,
The fixing hole of the fixing part is
A taper shape in which at least the outer end portion of the self expands toward the outside of the battery,
The caulking portion and the fixing portion are
Of the caulking portion, a caulking outer peripheral portion positioned radially outward from the outer end portion of the fixing hole, and of the fixing portion, radially outward from the outer end portion of the fixing hole. Batteries that are welded to each other only at the outer periphery of the fixed portion.
請求項1に記載の電池であって、
前記固定孔の前記外側端部は、
この固定孔の中心軸とのなす角が20度〜45度とされてなる
電池。
The battery according to claim 1,
The outer end of the fixing hole is
A battery in which the angle formed with the central axis of the fixing hole is 20 to 45 degrees.
請求項1または請求項2に記載の電池であって、
前記加締部の前記加締外周部は、
前記径方向の寸法が0.5mm以上とされてなる
電池。
The battery according to claim 1 or 2,
The caulking outer peripheral portion of the caulking portion is
A battery in which the radial dimension is 0.5 mm or more.
請求項1〜請求項3のいずれか一項に記載の電池であって、
前記固定孔の前記外側端部は、
自身の周方向に配置された第1外側端部及び第2外側端部であって、前記第1外側端部と前記固定孔の中心軸とのなす角が、前記第2外側端部と前記固定孔の中心軸とのなす角よりも大きくされた第1外側端部及び第2外側端部を有する
電池。
The battery according to any one of claims 1 to 3,
The outer end of the fixing hole is
A first outer end portion and a second outer end portion arranged in a circumferential direction of the first outer end portion, and an angle formed by the first outer end portion and a central axis of the fixing hole is an angle between the second outer end portion and the second outer end portion; A battery having a first outer end and a second outer end that are made larger than an angle formed by the central axis of the fixing hole.
請求項4に記載の電池であって、
前記加締部と前記固定部とは、
前記固定孔の前記第2外側端部の径方向外側においてのみ、互いに溶接されてなる
電池。
The battery according to claim 4,
The caulking portion and the fixing portion are
A battery which is welded to each other only on the radially outer side of the second outer end portion of the fixing hole.
請求項1〜請求項5のいずれか一項に記載の前記電池を搭載し、この電池による電気エネルギーを動力源の全部または一部に使用する車両。 A vehicle on which the battery according to any one of claims 1 to 5 is mounted and electric energy generated by the battery is used for all or part of a power source. 請求項1〜請求項5のいずれか一項に記載の前記電池を搭載し、この電池をエネルギー源の少なくとも1つとして使用する電池使用機器。 A battery-operated device equipped with the battery according to any one of claims 1 to 5 and using the battery as at least one energy source.
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