WO2010094926A1 - Composition - Google Patents

Composition Download PDF

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Publication number
WO2010094926A1
WO2010094926A1 PCT/GB2010/000294 GB2010000294W WO2010094926A1 WO 2010094926 A1 WO2010094926 A1 WO 2010094926A1 GB 2010000294 W GB2010000294 W GB 2010000294W WO 2010094926 A1 WO2010094926 A1 WO 2010094926A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
moles
ether
glycol
optical brightener
Prior art date
Application number
PCT/GB2010/000294
Other languages
English (en)
Inventor
Fabio Corradini
Fabio D'amico
Ralf Wiedemann
Original Assignee
Reckitt Benckiser N.V.
Reckitt Benckiser (Uk) Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reckitt Benckiser N.V., Reckitt Benckiser (Uk) Limited filed Critical Reckitt Benckiser N.V.
Priority to EP10707632A priority Critical patent/EP2398883A1/fr
Publication of WO2010094926A1 publication Critical patent/WO2010094926A1/fr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/39—Organic or inorganic per-compounds
    • C11D3/3947—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043—For use with aerosol devices
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
    • C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
    • C11D17/046—Insoluble free body dispenser
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/395—Bleaching agents
    • C11D3/3956—Liquid compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40—Dyes ; Pigments
    • C11D3/42—Brightening agents ; Blueing agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10—Objects to be cleaned
    • C11D2111/12—Soft surfaces, e.g. textile

Definitions

  • the present invention relates to an aqueous cleaning composition comprising an optical brightener and a bleach.
  • Optical brighteners are common ingredients in fabric / laundry washing or cleaning agents. They are used to prevent / disguise discoloration of items being cleaned. This discoloration is commonly exhibited as a yellowing / graying of the item being cleaned and is particularly prevalent in light / white colored items.
  • Optical brighteners operate by acting as a radiation absorber / emitter. Natural day light is adsorbed and then emitted with a blue-ish hue. This emitted light aids the overcoming of the discoloration issues.
  • an aqueous composition comprising a bleach and an optical brightener.
  • an aqueous composition comprising a bleach and an optical brightener as a pre-treatment composition in a laundry / fabric washing operation.
  • composition and use of the present invention have improved performance in stain treatment when used in a fabric / laundry cleaning operation. Furthermore this is achieved whilst avoiding the problem of "white halos/spotting" which typically occurs with local applications of optical brighteners on items being cleaned resulting in areas of the item having a different shade of white. Without wishing to be bound by theory it is postulated that this enhanced performance arises due to the ability of the optical brightener to camouflage any remnants of the stain in the stain treatment step.
  • the optical brightener is present in an amount of 0.01 to lwt%, e.g. 0.08wt%.
  • the optical brightener is selected from the substance class of 4, 4 ' -diamino-2, 2 ' - stilbenedisulfonic acids (flavonic acids), 4 , 4 ' -distyryl- biphenylene, methylumbelliferones, coumarins, dihydroquino- linones, 1, 3-diaryl-pyrazolines, naphthalic acid imides, benzoxazole, benzisoxazole and benzimidazole systems as well as pyrene derivatives with heterocycle substituents .
  • the optical brightener is selected from the substance class of 4, 4 ' -diamino-2, 2 ' - stilbenedisulfonic acids (flavonic acids), 4 , 4 ' -distyryl- biphenylene, methylumbelliferones, coumarins, dihydroquino- linones, 1, 3-diaryl-pyrazolines, naphthalic acid imides,
  • the fabric treatment composition comprises a bleach.
  • the composition comprises from 0.001% to 99.99%, preferably 0.001% to 7%, preferably 2% to 6%, most preferably about 7%, by weight, of bleach.
  • the bleach is preferably peroxide bleach, most preferably hydrogen peroxide. Peroxide sources other than H 2 O 2 can be used.
  • the fabric treatment composition comprises a surfactant.
  • the composition comprises from 0.001% to 99.99%, preferably 0.05% to 15%, e.g. about 10%, by weight of surfactants.
  • the surfactant is, for example, an anionic or nonionic surfactant or mixture thereof.
  • the nonionic surfactant is preferably a surfactant having a formula RO(CH 2 CH 2 O) n H wherein R is a mixture of linear, even carbon-number hydrocarbon chains ranging from Ci 2 H 2 S to Ci 6 H 33 and n represents the number of repeating units and is a number of from about 1 to about 12.
  • R is a mixture of linear, even carbon-number hydrocarbon chains ranging from Ci 2 H 2 S to Ci 6 H 33
  • n represents the number of repeating units and is a number of from about 1 to about 12.
  • examples of other non-ionic surfactants include higher aliphatic primary alcohol containing about twelve to about 16 carbon atoms which are condensed with about three to thirteen moles of ethylene oxide.
  • nonionic surfactants include primary alcohol ethoxylates (available under the Neodol trade name from Shell Co.), such as Cn alkanol condensed with 9 moles of ethylene oxide (Neodol 1-9) , C 12 -i 3 alkanol condensed with 6.5 moles ethylene oxide (Neodol 23-6.5), C 1 2-1 3 alkanol with 9 moles of ethylene oxide (Neodol 23-9) , C12-15 alkanol condensed with 7 or 3 moles ethylene oxide (Neodol 25-7 or Neodol 25-3) , Ci 4 - 15 alkanol condensed with 13 moles ethylene oxide (Neodol 45-13) , C 9 -u linear ethoxylated alcohol, averaging 2.5 moles of ethylene oxide per mole of alcohol (Neodol 91-2.5), and the like.
  • primary alcohol ethoxylates available under the Neodol trade name
  • nonionic surfactants suitable for use in the present invention include ethylene oxide condensate products of secondary aliphatic alcohols containing 11 to 18 carbon atoms in a straight or branched chain configuration condensed with 5 to 30 moles of ethylene oxide.
  • examples of commercially available non-ionic detergents of the foregoing type are Cn-is secondary alkanol condensed with either 9 moles of ethylene oxide (Tergitol 15-S-9) or 12 moles of ethylene oxide (Tergitol 15-S-12) marketed by Union Carbide, a subsidiary of Dow Chemical.
  • Octylphenoxy polyethoxyethanol type nonionic surfactants for example, Triton X-IOO, as well as amine oxides can also be used as a nonionic surfactant in the present invention.
  • linear primary alcohol ethoxylates are available under the Tomadol trade name such as, for example, Tomadol 1-7, a Cu linear primary alcohol ethoxylate with 7 moles EO; Tomadol 25-7, a Ci 2 -Ci S linear primary alcohol ethoxylate with 7 moles EO; Tomadol 45-7, a Ci 4 -Ci 5 linear primary alcohol ethoxylate with 7 moles EO; and Tomadol 91- 6, a C 9 -Ci I linear alcohol ethoxylate with 6 moles EO.
  • Tomadol 1-7 a Cu linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 25-7 a Ci 2 -Ci S linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 45-7 a Ci 4 -Ci 5 linear primary alcohol ethoxylate with 7 moles EO
  • linear primary alcohol ethoxylates are available under the Lutensol trade name such as, for example, Lutensol A3N, a C1 3 - 15 linear primary alcohol ethoxylate with 3 moles EO; Lutensol LA60, a C13- 1 5 linear primary alcohol ethoxylate with 7 moles EO.
  • Genapol such as, for example, Genapol LA3, a C 13 - 15 linear primary alcohol ethoxylate with 3 moles EO; Genapol LA070, a Ci 3 _i 5 linear primary alcohol ethoxylate with 7 moles EO
  • Tomadol 45-7 a C14-C 15 linear primary alcohol ethoxylate with 7 moles EO; and Tomadol 91-6, a C 9 -Cn linear alcohol ethoxylate with 6 moles EO.
  • nonionic surfactants are amine oxides, alkyl amide oxide surfactants.
  • Preferred anionic surfactants are frequently provided as alkali metal salts, ammonium salts, amine salts, aminoalco- hol salts or magnesium salts.
  • sulfate or sulfonate compounds including: alkyl benzene sulfates, alkyl sulfates, alkyl ether sulfates, al- kylamidoether sulfates, alkylaryl polyether sulfates, monoglyceride sulfates, alkylsulfonates, alkylamide sulfonates, alkylarylsulfonates, olefinsulfonates, paraffin sulfonates, alkyl sulfosuccinates, alkyl ether sulfosucci- nates, alkylamide sulfosuccinates, alkyl sulfosuccinamate, alkyl sulfoacetates, alkyl phosphates, alkyl ether phosphates, acyl sarconsinates, acyl isethionates, and N-acy
  • surfactants which may be used are alkyl naphthalene sulfonates and acyl / oleoyl sarcosinates and mixtures thereof.
  • the fabric treatment composition comprises a solvent.
  • the composition comprises from 0% to 99.99% preferably from 0% to 10% by weight, of solvent.
  • the solvent constituent may comprise one or more alcohol, glycol, acetate, ether acetate or glycol ether.
  • exemplary alcohols useful in the compositions of the invention include C 2 -Cs primary and secondary alcohols which may be straight chained or branched, preferably pentanol and hexa- nol. More preferably the solvent is a glycol ether.
  • Preferred examples of glycol ethers include glycol ethers hav- ing the general structure Ra-O-Rb-OH, wherein Ra is an alkoxy of 1 to 20 carbon atoms, or aryloxy of at least 6 carbon atoms, and Rb is an ether condensate of propylene glycol and/or ethylene glycol having from 1 to 10 glycol monomer units.
  • Specific and preferred solvents are selected from propylene glycol methyl ether, dipropylene glycol methyl ether, dipropylene glycol propyl ether, dipropylene glycol butyl ether, tripropylene glycol methyl ether, propylene glycol n-propyl ether, ethylene glycol n-butyl ether, diethylene glycol n-butyl ether, diethylene glycol methyl ether, propylene glycol, ethylene glycol, isopropanol, ethanol, methanol, diethylene glycol monoethyl ether acetate, and particularly useful are, propylene glycol phenyl ether, ethylene glycol hexyl ether and diethylene glycol hexyl ether .
  • the solvent or mixture of solvent is from the propanol series (Dowanol P-series) and among these Dipropylene Glycol n-Propyl Ether, Dipropylene Glycol n- Butyl Ether and Propylene Glycol Phenyl Ether. These are commercially available from Dow Chemicals as Dowanol DPnP, Dowanol DPnB and Dowanol PPH respectively.
  • the fabric treatment composition comprises a builder. Where present the composition comprises from 0% to 99.99% preferably from 0% to 10% by weight, of builder.
  • the fabric treatment composition may comprise minor amounts of various optional ingredients, including enzymes, dye transfer inhibition agents, dye catchers, preservatives, anti-static agents, fragrances, odour absorbing components.
  • the pH range of the fabric treatment composition is typically from about 3 to about 8, preferably about 3.5.
  • a most preferred composition is below: -
  • Non Ionic Surfactant 0.05% to 15% Anionic Surfactant: 0.05% to 5% IDS 30%: 1.0wt% H 2 O 2 50%: 0.05% to 10% Propylene glycol: 2.0wt% Fragrance: 0.1 - 0.5wt% Sulphuric Acid 93%: 0.1 - 0.5wt% Optical Brightener: 0.1 - 1.0wt% Water: Rest
  • the composition is most preferably suitable for discharge / application onto an item being cleaned using a spray device. Indeed in a preferred embodiment of the second aspect of the invention a spray device is employed. Such application typically occurs before the item is washed in an automatic washing machine, i.e. the composition is used as pre-treater. In this application it is most noticeable that the problem of white halos/spotting is avoided.
  • the spray device may comprise a propellent and thus be in the form of an aerosol type device, wherein the pressure of the propellant is used to aid the discharge of the contents of the spray device when the spray device is activated.
  • the spray device may be manually operated and thus be in the form of a trigger spray device. In these device application of pressure to an operating lever causes the operation of a pump which brings about dispense of the contents of the spray device.
  • wash parameters were set to large load (86° F, 120 ppm, cold rinse, 4 lbs ballast) detergent was added and agitated for 30 seconds-lminute . Ballast was added. Test cloths were set up on bench top. These were sprayed and rubbed for the stain pre-treatment . 2 ml of pre-treat product was applied to the stains on cloth; the product was rubbed 5 times backward and forward.
  • the reflectance (L*a*b*) of residual stains was measured using the Datacolor 650 colorimeter (photoelectric colorimeter) or the equivalent with the UV filter. Background readings were taken on the white background that did not come into contact with stain or pre-treat material. All readings were taken after the washing and drying cycles are completed.
  • composition A in accordance with the invention showed better cleaning than composition B (comparative) .
  • Composi- tion A was found statistically superior than Formula B on stain removal of 5 out of 20 stains (with the remainder being parity performance) .

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)

Abstract

La présente invention concerne l'utilisation d'une composition aqueuse. La composition comprend un agent de blanchiment et un azurant optique. Il s'agit d'une composition de prétraitement destinée à être utilisée dans une opération de blanchisserie/lavage de vêtements.
PCT/GB2010/000294 2009-02-20 2010-02-19 Composition WO2010094926A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP10707632A EP2398883A1 (fr) 2009-02-20 2010-02-19 Composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0902917.4 2009-02-20
GBGB0902917.4A GB0902917D0 (en) 2009-02-20 2009-02-20 Composition

Publications (1)

Publication Number Publication Date
WO2010094926A1 true WO2010094926A1 (fr) 2010-08-26

Family

ID=40565475

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2010/000294 WO2010094926A1 (fr) 2009-02-20 2010-02-19 Composition

Country Status (3)

Country Link
EP (1) EP2398883A1 (fr)
GB (1) GB0902917D0 (fr)
WO (1) WO2010094926A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2551487A (en) * 2016-06-15 2017-12-27 Reckitt Benckiser Vanish Bv Composition
US10640903B2 (en) 2017-06-13 2020-05-05 The Procter & Gamble Company Process for treating at least one garment

Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430236A (en) * 1981-06-22 1984-02-07 Texize, Division Of Mortonthiokol Liquid detergent composition containing bleach
EP0404293A2 (fr) * 1989-04-21 1990-12-27 The Clorox Company Composition liquide acide épaissie avec des azurants optiques sulfonatés
US5234617A (en) * 1992-04-20 1993-08-10 Kathleen B. Hunter Aqueous liquid bleach compositions with fluorescent whitening agent and polyvinyl pyrrolidone or polyvinyl alcohol
WO1997045518A1 (fr) * 1996-05-28 1997-12-04 Warwick International Group Limited Liquide detergent, isotrope, alcalin et concentre comportant un agent de blanchiment
WO1998017771A1 (fr) * 1996-10-25 1998-04-30 The Procter & Gamble Company Detachage au peroxyde
US5776878A (en) * 1994-01-13 1998-07-07 The Procter & Gamble Company Liquid detergent compositions containing brighteners and polymers for preventing fabric spotting
DE19750455C1 (de) * 1997-11-14 1999-04-29 Henkel Kgaa Verwendung von peroxidhaltigen Zubereitungen
US6010994A (en) * 1995-06-07 2000-01-04 The Clorox Company Liquid compositions containing N-alkyl ammonium acetonitrile salts
EP1001014A1 (fr) * 1998-11-10 2000-05-17 The Procter & Gamble Company Compositions de blanchiment
WO2000027960A2 (fr) * 1998-11-10 2000-05-18 The Procter & Gamble Company Compositions de blanchiment
EP1118656A1 (fr) * 2000-01-20 2001-07-25 The Procter & Gamble Company Procédé de traitement de tapis avec une composition contenant un azurant optique
US6921985B2 (en) 2003-01-24 2005-07-26 General Electric Company Low voltage ride through for wind turbine generators
EP1614742A1 (fr) * 2004-07-08 2006-01-11 The Procter & Gamble Company Composition de blanchissement comprenant une amine cyclique à empèchement stérique
EP1780260A1 (fr) * 2005-10-26 2007-05-02 The Procter & Gamble Company Procédé de traitement de textiles
EP1865051A1 (fr) * 2006-06-08 2007-12-12 The Procter and Gamble Company Compositions de blanchiment
DE102007012581A1 (de) * 2006-06-07 2007-12-27 Klaus Scheuermann Flüssigwaschmittel mit Bleichwirkung
US7411309B2 (en) 2003-05-02 2008-08-12 Xantrex Technology Inc. Control system for doubly fed induction generator
US20080221005A1 (en) * 2005-01-13 2008-09-11 Kaaret Thomas W Stable Bleaches With Coloring Agents
US20080305980A1 (en) * 2005-12-30 2008-12-11 Carlos Malet Stability of detergents containing hypochlorite

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4430236A (en) * 1981-06-22 1984-02-07 Texize, Division Of Mortonthiokol Liquid detergent composition containing bleach
EP0404293A2 (fr) * 1989-04-21 1990-12-27 The Clorox Company Composition liquide acide épaissie avec des azurants optiques sulfonatés
US5234617A (en) * 1992-04-20 1993-08-10 Kathleen B. Hunter Aqueous liquid bleach compositions with fluorescent whitening agent and polyvinyl pyrrolidone or polyvinyl alcohol
US5776878A (en) * 1994-01-13 1998-07-07 The Procter & Gamble Company Liquid detergent compositions containing brighteners and polymers for preventing fabric spotting
US6010994A (en) * 1995-06-07 2000-01-04 The Clorox Company Liquid compositions containing N-alkyl ammonium acetonitrile salts
WO1997045518A1 (fr) * 1996-05-28 1997-12-04 Warwick International Group Limited Liquide detergent, isotrope, alcalin et concentre comportant un agent de blanchiment
WO1998017771A1 (fr) * 1996-10-25 1998-04-30 The Procter & Gamble Company Detachage au peroxyde
DE19750455C1 (de) * 1997-11-14 1999-04-29 Henkel Kgaa Verwendung von peroxidhaltigen Zubereitungen
EP1001014A1 (fr) * 1998-11-10 2000-05-17 The Procter & Gamble Company Compositions de blanchiment
WO2000027960A2 (fr) * 1998-11-10 2000-05-18 The Procter & Gamble Company Compositions de blanchiment
EP1118656A1 (fr) * 2000-01-20 2001-07-25 The Procter & Gamble Company Procédé de traitement de tapis avec une composition contenant un azurant optique
US6921985B2 (en) 2003-01-24 2005-07-26 General Electric Company Low voltage ride through for wind turbine generators
US7411309B2 (en) 2003-05-02 2008-08-12 Xantrex Technology Inc. Control system for doubly fed induction generator
EP1614742A1 (fr) * 2004-07-08 2006-01-11 The Procter & Gamble Company Composition de blanchissement comprenant une amine cyclique à empèchement stérique
US20080221005A1 (en) * 2005-01-13 2008-09-11 Kaaret Thomas W Stable Bleaches With Coloring Agents
EP1780260A1 (fr) * 2005-10-26 2007-05-02 The Procter & Gamble Company Procédé de traitement de textiles
US20080305980A1 (en) * 2005-12-30 2008-12-11 Carlos Malet Stability of detergents containing hypochlorite
DE102007012581A1 (de) * 2006-06-07 2007-12-27 Klaus Scheuermann Flüssigwaschmittel mit Bleichwirkung
EP1865051A1 (fr) * 2006-06-08 2007-12-12 The Procter and Gamble Company Compositions de blanchiment

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2551487A (en) * 2016-06-15 2017-12-27 Reckitt Benckiser Vanish Bv Composition
US10640903B2 (en) 2017-06-13 2020-05-05 The Procter & Gamble Company Process for treating at least one garment

Also Published As

Publication number Publication date
GB0902917D0 (en) 2009-04-08
EP2398883A1 (fr) 2011-12-28

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