WO2010091116A3 - Method of forming an anode material for a lithium ion battery - Google Patents

Method of forming an anode material for a lithium ion battery Download PDF

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Publication number
WO2010091116A3
WO2010091116A3 PCT/US2010/023096 US2010023096W WO2010091116A3 WO 2010091116 A3 WO2010091116 A3 WO 2010091116A3 US 2010023096 W US2010023096 W US 2010023096W WO 2010091116 A3 WO2010091116 A3 WO 2010091116A3
Authority
WO
WIPO (PCT)
Prior art keywords
solution
forming
lithium ion
ion battery
anode material
Prior art date
Application number
PCT/US2010/023096
Other languages
French (fr)
Other versions
WO2010091116A2 (en
Inventor
Chunlei Wang
Yan Yu
Original Assignee
The Florida International University Board Of Trustees
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by The Florida International University Board Of Trustees filed Critical The Florida International University Board Of Trustees
Publication of WO2010091116A2 publication Critical patent/WO2010091116A2/en
Publication of WO2010091116A3 publication Critical patent/WO2010091116A3/en

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/0402—Methods of deposition of the material
    • H01M4/0419—Methods of deposition of the material involving spraying
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1393—Processes of manufacture of electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/139—Processes of manufacture
    • H01M4/1395—Processes of manufacture of electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/661—Metal or alloys, e.g. alloy coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/70—Carriers or collectors characterised by shape or form
    • H01M4/80—Porous plates, e.g. sintered carriers
    • H01M4/808—Foamed, spongy materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/021—Physical characteristics, e.g. porosity, surface area
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Composite Materials (AREA)
  • Inorganic Chemistry (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

A method of forming a three dimensional porous thin film can include depositing a precursor solution on a substrate through a nozzle having a voltage applied thereto. The precursor solution is deposited through the nozzle as a spray. The precursor solution includes a first solution comprising My+ ions and a second solution having a lower boiling point than the first solution The method can further includes heating the deposited precursor solution under conditions sufficient to oxidize the M'' ions of the first solution and remove the second solution, thereby forming a three dimensional porous thin film represented by the formula MxOy, w herein M is a transition metal or a semiconductor, O is oxygen, x is in a range of 1 to 3, and y is in a range of 1 to 4.
PCT/US2010/023096 2009-02-03 2010-02-03 Method of forming an anode material for a lithium ion battery WO2010091116A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US14961209P 2009-02-03 2009-02-03
US61/149,612 2009-02-03

Publications (2)

Publication Number Publication Date
WO2010091116A2 WO2010091116A2 (en) 2010-08-12
WO2010091116A3 true WO2010091116A3 (en) 2010-12-02

Family

ID=42542637

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/023096 WO2010091116A2 (en) 2009-02-03 2010-02-03 Method of forming an anode material for a lithium ion battery

Country Status (1)

Country Link
WO (1) WO2010091116A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102011088533A1 (en) * 2011-12-14 2013-06-20 Robert Bosch Gmbh Electrode, method for producing an electrode and energy storage comprising an electrode
CN102800490B (en) * 2012-08-16 2016-04-13 黑龙江大学 The melamine formaldehyde resin/polyvinyl alcohol aqueous solution directly prepares the method for nitrogenous carbon fiber electrode by high-voltage electrostatic spinning technology
KR20230052308A (en) * 2013-03-15 2023-04-19 웰스태트 바이오커탤리시스, 엘엘씨 Methods of making nanofiber electrodes for batteries
CN104021879B (en) * 2013-09-18 2017-02-01 天津工业大学 Preparation method for carbon nanotube flexible transparent conductive thin film
CN103996821A (en) * 2014-06-14 2014-08-20 哈尔滨工业大学 Negative film for lithium ion secondary battery as well as preparation method and application of negative film
CN106207108B (en) * 2016-07-09 2018-07-27 太原理工大学 Si-C composite material and the preparation method and application thereof based on macromolecule foaming microballoon
CN106654190A (en) * 2016-11-04 2017-05-10 华中科技大学 One-dimensional In<2>O<3>/C fiber composite material, and preparation method and application thereof
CN109768263A (en) * 2019-03-01 2019-05-17 江苏赛清科技有限公司 A kind of lithium battery high capacity composite negative pole material and preparation method thereof
CN112751010B (en) * 2019-10-31 2022-10-28 青岛海尔智能技术研发有限公司 Double-layer coated zinc cathode, preparation method thereof, zinc-air battery and direct current water heater
CN113552180A (en) * 2021-07-02 2021-10-26 山东大学 NiO/SnO2Composite nanowire and preparation method and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143448A (en) * 1997-10-20 2000-11-07 Mitsubishi Chemical Corporation Electrode materials having carbon particles with nano-sized inclusions therewithin and an associated electrolytic and fabrication process
US20060057463A1 (en) * 2004-04-15 2006-03-16 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
US20080274403A1 (en) * 2007-05-04 2008-11-06 Il-Doo Kim Anode for secondary battery having negative active material with nano-fiber network structure and secondary battery using the same, and fabrication method of negative active material for secondary battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6143448A (en) * 1997-10-20 2000-11-07 Mitsubishi Chemical Corporation Electrode materials having carbon particles with nano-sized inclusions therewithin and an associated electrolytic and fabrication process
US20060057463A1 (en) * 2004-04-15 2006-03-16 Fmc Corporation Composite materials of nano-dispersed silicon and tin and methods of making the same
US20080274403A1 (en) * 2007-05-04 2008-11-06 Il-Doo Kim Anode for secondary battery having negative active material with nano-fiber network structure and secondary battery using the same, and fabrication method of negative active material for secondary battery

Also Published As

Publication number Publication date
WO2010091116A2 (en) 2010-08-12

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