WO2010060702A1 - Photoinitiator mixtures - Google Patents
Photoinitiator mixtures Download PDFInfo
- Publication number
- WO2010060702A1 WO2010060702A1 PCT/EP2009/063963 EP2009063963W WO2010060702A1 WO 2010060702 A1 WO2010060702 A1 WO 2010060702A1 EP 2009063963 W EP2009063963 W EP 2009063963W WO 2010060702 A1 WO2010060702 A1 WO 2010060702A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alkyl
- phenyl
- substituted
- optionally
- halogen
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 281
- 150000001875 compounds Chemical class 0.000 claims abstract description 198
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract description 179
- 239000001257 hydrogen Substances 0.000 claims abstract description 73
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 73
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 52
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 150000001642 boronic acid derivatives Chemical class 0.000 claims abstract description 20
- WURBFLDFSFBTLW-UHFFFAOYSA-N benzil Chemical compound C=1C=CC=CC=1C(=O)C(=O)C1=CC=CC=C1 WURBFLDFSFBTLW-UHFFFAOYSA-N 0.000 claims abstract description 9
- FAQJJMHZNSSFSM-UHFFFAOYSA-N phenylglyoxylic acid Chemical class OC(=O)C(=O)C1=CC=CC=C1 FAQJJMHZNSSFSM-UHFFFAOYSA-N 0.000 claims abstract description 6
- NLGDWWCZQDIASO-UHFFFAOYSA-N 2-hydroxy-1-(7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-yl)-2-phenylethanone Chemical compound OC(C(=O)c1cccc2Oc12)c1ccccc1 NLGDWWCZQDIASO-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 N(Ci-Ci2alkyl)2 Chemical group 0.000 claims description 334
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 163
- 229910052736 halogen Inorganic materials 0.000 claims description 107
- 239000000976 ink Substances 0.000 claims description 107
- 150000002367 halogens Chemical class 0.000 claims description 106
- 239000000049 pigment Substances 0.000 claims description 88
- 238000007639 printing Methods 0.000 claims description 78
- 238000000576 coating method Methods 0.000 claims description 53
- 239000000463 material Substances 0.000 claims description 41
- 125000001624 naphthyl group Chemical group 0.000 claims description 41
- 229910052760 oxygen Inorganic materials 0.000 claims description 41
- 238000000034 method Methods 0.000 claims description 40
- 238000004519 manufacturing process Methods 0.000 claims description 36
- 239000000758 substrate Substances 0.000 claims description 36
- 239000011248 coating agent Substances 0.000 claims description 34
- 239000012965 benzophenone Substances 0.000 claims description 33
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 33
- 229920005989 resin Polymers 0.000 claims description 33
- 239000011347 resin Substances 0.000 claims description 33
- 239000000654 additive Substances 0.000 claims description 28
- 229910052740 iodine Inorganic materials 0.000 claims description 28
- 125000004432 carbon atom Chemical group C* 0.000 claims description 27
- 229910052717 sulfur Inorganic materials 0.000 claims description 27
- 239000002270 dispersing agent Substances 0.000 claims description 25
- 125000001424 substituent group Chemical group 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 22
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 21
- 239000000843 powder Substances 0.000 claims description 20
- 230000008569 process Effects 0.000 claims description 20
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 18
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- 239000000853 adhesive Substances 0.000 claims description 14
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- 239000007788 liquid Substances 0.000 claims description 13
- 150000008065 acid anhydrides Chemical class 0.000 claims description 12
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 claims description 12
- 230000003287 optical effect Effects 0.000 claims description 12
- 150000007519 polyprotic acids Polymers 0.000 claims description 10
- 229910000679 solder Inorganic materials 0.000 claims description 9
- 125000006552 (C3-C8) cycloalkyl group Chemical group 0.000 claims description 8
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- 238000007645 offset printing Methods 0.000 claims description 8
- 238000007650 screen-printing Methods 0.000 claims description 8
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 7
- 238000013500 data storage Methods 0.000 claims description 7
- 125000004957 naphthylene group Chemical group 0.000 claims description 7
- 125000006678 phenoxycarbonyl group Chemical group 0.000 claims description 7
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 claims description 7
- 125000000332 coumarinyl group Chemical group O1C(=O)C(=CC2=CC=CC=C12)* 0.000 claims description 6
- 239000003822 epoxy resin Substances 0.000 claims description 6
- 239000003365 glass fiber Substances 0.000 claims description 6
- 230000001678 irradiating effect Effects 0.000 claims description 6
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 claims description 6
- 125000006729 (C2-C5) alkenyl group Chemical group 0.000 claims description 5
- 125000004956 cyclohexylene group Chemical group 0.000 claims description 5
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- 238000009713 electroplating Methods 0.000 claims description 5
- 238000003384 imaging method Methods 0.000 claims description 5
- 239000003973 paint Substances 0.000 claims description 5
- 125000003356 phenylsulfanyl group Chemical group [*]SC1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 claims description 5
- 125000006850 spacer group Chemical group 0.000 claims description 5
- VKVJIWVUYNTBEZ-UHFFFAOYSA-N 1,3-bis(3,5-dichlorophenyl)urea Chemical compound ClC1=CC(Cl)=CC(NC(=O)NC=2C=C(Cl)C=C(Cl)C=2)=C1 VKVJIWVUYNTBEZ-UHFFFAOYSA-N 0.000 claims description 4
- YBFHILNBYXCJKD-UHFFFAOYSA-N 1-(6-methylpyridin-3-yl)-2-(4-methylsulfonylphenyl)ethanone Chemical compound C1=NC(C)=CC=C1C(=O)CC1=CC=C(S(C)(=O)=O)C=C1 YBFHILNBYXCJKD-UHFFFAOYSA-N 0.000 claims description 4
- 125000003358 C2-C20 alkenyl group Chemical group 0.000 claims description 4
- 125000000609 carbazolyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3NC12)* 0.000 claims description 4
- 238000005401 electroluminescence Methods 0.000 claims description 4
- 239000003094 microcapsule Substances 0.000 claims description 4
- 238000007747 plating Methods 0.000 claims description 4
- 239000002966 varnish Substances 0.000 claims description 4
- 125000000051 benzyloxy group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])O* 0.000 claims description 3
- 238000004377 microelectronic Methods 0.000 claims description 3
- 125000006710 (C2-C12) alkenyl group Chemical group 0.000 claims description 2
- VWBYXJRDIQCSLW-UHFFFAOYSA-N O=[P](c1ccccc1)c1ccccc1 Chemical group O=[P](c1ccccc1)c1ccccc1 VWBYXJRDIQCSLW-UHFFFAOYSA-N 0.000 claims description 2
- 238000001459 lithography Methods 0.000 claims description 2
- 239000008247 solid mixture Substances 0.000 claims description 2
- 239000000306 component Substances 0.000 claims 4
- 150000002763 monocarboxylic acids Chemical class 0.000 claims 1
- 229940048053 acrylate Drugs 0.000 description 160
- 229920001577 copolymer Polymers 0.000 description 73
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- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 49
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 46
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 44
- 239000010410 layer Substances 0.000 description 42
- 229940117913 acrylamide Drugs 0.000 description 39
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 35
- 229920005862 polyol Polymers 0.000 description 33
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 31
- 239000002904 solvent Substances 0.000 description 31
- 239000000178 monomer Substances 0.000 description 29
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- 239000011651 chromium Substances 0.000 description 28
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 27
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 27
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 26
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 25
- 150000008366 benzophenones Chemical class 0.000 description 23
- 229940044603 styrene Drugs 0.000 description 23
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 22
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 21
- 239000000975 dye Substances 0.000 description 20
- 150000002148 esters Chemical class 0.000 description 20
- 239000010408 film Substances 0.000 description 20
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 19
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 17
- 239000006185 dispersion Substances 0.000 description 17
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- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 12
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- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 12
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- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 10
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- 230000002028 premature Effects 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- QCTJRYGLPAFRMS-UHFFFAOYSA-N prop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical class OC(=O)C=C.NC1=NC(N)=NC(N)=N1 QCTJRYGLPAFRMS-UHFFFAOYSA-N 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- GVVKBARIYRBZHC-UHFFFAOYSA-N prop-2-enyl 2,2-dimethylpropanoate Chemical compound CC(C)(C)C(=O)OCC=C GVVKBARIYRBZHC-UHFFFAOYSA-N 0.000 description 1
- CYFIHPJVHCCGTF-UHFFFAOYSA-N prop-2-enyl 2-hydroxypropanoate Chemical compound CC(O)C(=O)OCC=C CYFIHPJVHCCGTF-UHFFFAOYSA-N 0.000 description 1
- AXLMPTNTPOWPLT-UHFFFAOYSA-N prop-2-enyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCC=C AXLMPTNTPOWPLT-UHFFFAOYSA-N 0.000 description 1
- HPCIWDZYMSZAEZ-UHFFFAOYSA-N prop-2-enyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC=C HPCIWDZYMSZAEZ-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000006233 propoxy propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001042 pteridinyl group Chemical group N1=C(N=CC2=NC=CN=C12)* 0.000 description 1
- 125000000561 purinyl group Chemical group N1=C(N=C2N=CNC2=C1)* 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- 125000004307 pyrazin-2-yl group Chemical group [H]C1=C([H])N=C(*)C([H])=N1 0.000 description 1
- 125000003373 pyrazinyl group Chemical group 0.000 description 1
- 125000003226 pyrazolyl group Chemical group 0.000 description 1
- PBMFSQRYOILNGV-UHFFFAOYSA-N pyridazine Chemical compound C1=CC=NN=C1 PBMFSQRYOILNGV-UHFFFAOYSA-N 0.000 description 1
- 125000002098 pyridazinyl group Chemical group 0.000 description 1
- JUJWROOIHBZHMG-UHFFFAOYSA-O pyridinium Chemical compound C1=CC=[NH+]C=C1 JUJWROOIHBZHMG-UHFFFAOYSA-O 0.000 description 1
- 125000004076 pyridyl group Chemical group 0.000 description 1
- 125000000714 pyrimidinyl group Chemical group 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 125000002294 quinazolinyl group Chemical group N1=C(N=CC2=CC=CC=C12)* 0.000 description 1
- IZMJMCDDWKSTTK-UHFFFAOYSA-N quinoline yellow Chemical compound C1=CC=CC2=NC(C3C(C4=CC=CC=C4C3=O)=O)=CC=C21 IZMJMCDDWKSTTK-UHFFFAOYSA-N 0.000 description 1
- 125000005493 quinolyl group Chemical group 0.000 description 1
- 125000001567 quinoxalinyl group Chemical group N1=C(C=NC2=CC=CC=C12)* 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000001044 red dye Substances 0.000 description 1
- 239000001054 red pigment Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000007763 reverse roll coating Methods 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- KIWUVOGUEXMXSV-UHFFFAOYSA-N rhodanine Chemical compound O=C1CSC(=S)N1 KIWUVOGUEXMXSV-UHFFFAOYSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000003335 secondary amines Chemical class 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000012312 sodium hydride Substances 0.000 description 1
- 229910000104 sodium hydride Inorganic materials 0.000 description 1
- 239000001540 sodium lactate Substances 0.000 description 1
- 235000011088 sodium lactate Nutrition 0.000 description 1
- 229940005581 sodium lactate Drugs 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 235000010339 sodium tetraborate Nutrition 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- LJFWQNJLLOFIJK-UHFFFAOYSA-N solvent violet 13 Chemical compound C1=CC(C)=CC=C1NC1=CC=C(O)C2=C1C(=O)C1=CC=CC=C1C2=O LJFWQNJLLOFIJK-UHFFFAOYSA-N 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000009788 spray lay-up Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- PMJMHCXAGMRGBZ-UHFFFAOYSA-N subphthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(=N3)N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C3=N1 PMJMHCXAGMRGBZ-UHFFFAOYSA-N 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- MUTNCGKQJGXKEM-UHFFFAOYSA-N tamibarotene Chemical compound C=1C=C2C(C)(C)CCC(C)(C)C2=CC=1NC(=O)C1=CC=C(C(O)=O)C=C1 MUTNCGKQJGXKEM-UHFFFAOYSA-N 0.000 description 1
- 238000010345 tape casting Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- UFDHBDMSHIXOKF-UHFFFAOYSA-N tetrahydrophthalic acid Natural products OC(=O)C1=C(C(O)=O)CCCC1 UFDHBDMSHIXOKF-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 125000004627 thianthrenyl group Chemical group C1(=CC=CC=2SC3=CC=CC=C3SC12)* 0.000 description 1
- 150000003549 thiazolines Chemical class 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- JADVWWSKYZXRGX-UHFFFAOYSA-M thioflavine T Chemical compound [Cl-].C1=CC(N(C)C)=CC=C1C1=[N+](C)C2=CC=C(C)C=C2S1 JADVWWSKYZXRGX-UHFFFAOYSA-M 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- AYNNSCRYTDRFCP-UHFFFAOYSA-N triazene Chemical compound NN=N AYNNSCRYTDRFCP-UHFFFAOYSA-N 0.000 description 1
- KKFOMYPMTJLQGA-UHFFFAOYSA-N tribenzyl phosphite Chemical compound C=1C=CC=CC=1COP(OCC=1C=CC=CC=1)OCC1=CC=CC=C1 KKFOMYPMTJLQGA-UHFFFAOYSA-N 0.000 description 1
- TUQOTMZNTHZOKS-UHFFFAOYSA-N tributylphosphine Chemical compound CCCCP(CCCC)CCCC TUQOTMZNTHZOKS-UHFFFAOYSA-N 0.000 description 1
- XOALFFJGWSCQEO-UHFFFAOYSA-N tridecyl prop-2-enoate Chemical compound CCCCCCCCCCCCCOC(=O)C=C XOALFFJGWSCQEO-UHFFFAOYSA-N 0.000 description 1
- 229960001124 trientine Drugs 0.000 description 1
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ODHXBMXNKOYIBV-UHFFFAOYSA-N triphenylamine Chemical compound C1=CC=CC=C1N(C=1C=CC=CC=1)C1=CC=CC=C1 ODHXBMXNKOYIBV-UHFFFAOYSA-N 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 1
- 235000019801 trisodium phosphate Nutrition 0.000 description 1
- 125000003774 valeryl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UIYCHXAGWOYNNA-UHFFFAOYSA-N vinyl sulfide Chemical class C=CSC=C UIYCHXAGWOYNNA-UHFFFAOYSA-N 0.000 description 1
- 239000011345 viscous material Substances 0.000 description 1
- 235000012431 wafers Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 125000001834 xanthenyl group Chemical group C1=CC=CC=2OC3=CC=CC=C3C(C12)* 0.000 description 1
- 150000007964 xanthones Chemical class 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 125000004933 β-carbolinyl group Chemical group C1(=NC=CC=2C3=CC=CC=C3NC12)* 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
- C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D209/00—Heterocyclic compounds containing five-membered rings, condensed with other rings, with one nitrogen atom as the only ring hetero atom
- C07D209/56—Ring systems containing three or more rings
- C07D209/80—[b, c]- or [b, d]-condensed
- C07D209/82—Carbazoles; Hydrogenated carbazoles
- C07D209/86—Carbazoles; Hydrogenated carbazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to carbon atoms of the ring system
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
- C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
- C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
- C07D333/06—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring carbon atoms
- C07D333/22—Radicals substituted by doubly bound hetero atoms, or by two hetero atoms other than halogen singly bound to the same carbon atom
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
- G03F7/028—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds with photosensitivity-increasing substances, e.g. photoinitiators
- G03F7/031—Organic compounds not covered by group G03F7/029
Definitions
- R 2 and R 2 ' are phenoxycarbonyl which is unsubstituted or substituted by CrC 6 alkyl, halogen, phenyl, OR 3 , SR 4 and/or NR 5 R 6 ; or
- R" 2 has one of the meanings as given for R 2 ;
- NR 5 R 6 wherein the substituents OR 3 , SR 4 or NR 5 R 6 optionally form 5- or 6-membered rings via the radicals R 3 , R 4 , R 5 and/or R 6 with one of the carbon atoms of the phenyl, biphenylyl, naphthyl or d-C 2 oheteroaryl ring;
- R 8 and R 9 and R' 8 and R' 9 are halogen, CN, OR 3 , SR 4 , SOR 4 , SO 2 R 4 or NR 5 R 6 , wherein the substituents OR 3 , SR 4 or NR 5 R 6 optionally form 5- or 6-membered rings via the radicals R 3 , R 4 , R 5 and/or R 6 with one of the carbon atoms of the phenyl or with the substituent R 7 or one of the carbon atoms of the naphthylene or phenylene group of M 3 ; or
- R 22 is C 2 -C 20 alkyl which is interrupted by one or more O
- R 20 or R 22 is phenyl, naphthyl, coumarinyl or Ci-C 20 heteroaryl, each of which optionally is sub- stituted by one or more Ci-Ci 2 alkyl, phenyl, halogen, Ci-C 4 haloalkyl, CN, NO 2 , SR 4 , OR 3 ,
- R 23 has one of the meanings as given for R 1 ;
- the ratio of the compound of the formula (I) or (I') and the compound of the formula (HK), (MPO), (BPO), (BP), (TX), (KS), (BK), (PG), (BT) and/or (Tl) is for example from 0.1 :99.9 to 50:50, especially 0.5:99.5 to 40:60, in particular 1 :99 to 20:80.
- R2, R'2, R7, Re and R 9 are as defined above.
- Every oxime ester group can exist in two configurations, (Z) or (E). It is possible to separate the isomers by conventional methods, but it is also possible to use the isomeric mixture as such as photoinitiating species. Therefore, the invention also relates to photoinitiator mixtures as oxime ester component comprising mixtures of configurational isomers of compounds of the formula (I) or (I').
- R 3 is for example CrC 20 alkyl, CrC 8 alkanoyl, phenyl-CrC 3 alkyl, C 3 -C 20 cycloalkyl which is uninterrupted or interrupted by O, or is phenyl, CrC 20 heteroaryl.
- R 3 is CrC 20 alkyl or C 3 -C 8 cycloalkyl which optionally is interrupted by one or more O, in particular it is CrC 8 alkyl or C 3 -C 6 cycloalkyl which is interrupted by O.
- R 4 is preferably Ci-C 2 oalkyl, Ci-C 8 alkanoyl, phenyl-CrC 3 alkyl, Ci-C 2 oheteroaryl, unsubsti-
- R 5 and R 6 are for example hydrogen, CrC 2 oalkyl, C 2 -C 4 hydroxyalkyl, C 2 -Ci 0 alkoxyalkyl, phenyl-Ci-C 3 alkyl, phenyl, or together with the N-atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring which optionally is interrupted by O, or preferably hydrogen, phenyl, CrC 20 alkyl; or together with the N-atom to which they are attached form a heteroaromatic ring system, in particular carbazolyl.
- R 4 o R 40 and R 4 i independently of one another are unsubstituted CrC 2 o-alkyl, cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl; or CrC 2 o-alkyl, cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl substituted by one or more halogen, Ci-Ci 2 -alkyl, Ci-Ci 2 -alkoxy, CrCi 2 alkylthio or NR 43 R 44 ; or are OCi-Ci 2 alkyl; R 42 is unsubstituted cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl, or cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl substituted by one or more halogen, Ci-C
- R 45 is unsubstituted Ci-C 20 -alkyl, C 2 -C 20 -alkenyl, Ci-C 20 -alkyl substituted by one or more halogen, C r Ci 2 -alkoxy, C r Ci 2 alkylthio, NR 43 R 44 Or (CO)OR 46 , or R 45 is unsubstituted cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl; or is cyclohexyl, cyclopentyl, phenyl, naphthyl or biphenylyl substituted by one or more halogen, d-
- R 42 and R' 42 independently of one another are phenyl substituted by one or more halogen, Ci-C 4 -alkyl or Ci-C 4 -alkoxy;
- R 45 is unsubstituted C r C 20 -alkyl, C r C 20 -alkyl substituted by (CO)OR 46 , or
- R 45 is unsubstituted phenyl or phenyl, substituted by one or more Ci-Ci 2 -alkoxy; and
- R 46 is Ci-C 20 -alkyl.
- R53, R5 4 and R 55 independently of one another are hydrogen or Ci-Ci 2 -alkyl; x is 1-10, in particular 1-5; y is 2-20; z is 1-6, in particular 1-2; the sum of d and e is from 10-16, in particular from 12-14, where d is greater than e; and
- R ⁇ , R59 and R 60 independently of one another are hydrogen, halogen, d-C ⁇ alkoxy,
- TX Compounds of the formula (TX) are known in the art and the compounds as well as their preparation is for example described in WO 03/033492. Many of the compounds also are commercially available for example under the trademark Omnipol from IGM.
- the ketosulfone compound in the photoinitiator mixture as described above for example is of the formula (KS),
- a specific example is the photoinitiator Esacure 1001 available from Lamberti: 1-[4-(4-benzoylphenylsulfanyl)phenyl]-2-methyl-2-(4-methylphenylsulfonyl)propan-1-one:
- KS compounds of the formula (KS) are known in the art and the compounds as well as their preparation are for example described in WO 00/031030.
- Esacure 1001 M is commercially available.
- the benzil ketal or benzoin ether compound in the photoinitiator mixture as described above for example is of the formula (BK) o M R I TM ⁇ C-C-R 72 R (BK), wherein
- R ⁇ o is hydrogen, Ci-Ci 2 -alkyl or — Y 1 - O - C - C
- C ⁇ -C ⁇ oalkyl which is interrupted by one or more O is for example interrupted 1-9, 1-5, 1-3 or once or twice by O.
- Two O-atoms are separated by at least one methylene group, prefera- bly at least two methylene groups, namely ethylene.
- the alkyl groups are linear or branched.
- CrC 18 alkoxy is CrCi 8 alkyl, which is substituted by one-O-atom.
- d-Ci 8 alkyl has the same meanings as given above for Ci-C 2 oalkyl up to the corresponding number of C-atoms.
- Cr C 4 alkoxy is linear or branched, for example, methoxy, ethoxy, propoxy, isopropoxy, n-butyl- oxy, sec-butyloxy, isobutyloxy, tert-butyloxy.
- substituents OR 3 , SR 4 or NR 5 R 6 on the phenyl group as R 8 and/or Rg optionally form 5- or 6-membered rings via the radicals R 3 , R 4 , R 5 and/or R 6 with one of the carbon atoms of the phenyl, naphthyl group or that of the substituent R 7 , for example structures comprising two or three rings (inclusive the phenyl rings) are obtained. Examples are
- R 42 as a 5- or 6-membered heterocyclic ring comprising an S atom or N atomis for example furyl, thienyl, pyrrolyl, oxinyl, dioxinyl or pyridyl.
- Said heterocyclic rings are unsubstituted or are for example substituted once or more times by for example linear or branched CrC 6 -alkyl such as methyl, ethyl, propyl, butyl, pentyl or hexyl. Examples of such rings are dimethylpyridyl, di- methylpyrrolyl or methylfuryl.
- the unsaturated compounds (a) may include one or more olefinic double bonds. They may be of low (monomeric) or high (oligomeric) molecular mass.
- monomers containing a double bond are alkyl, hydroxyalkyl, cycloalkyl (which optionally interrupted by O) or aminoalkyl (meth)acrylates, for example methyl, ethyl, propyl, butyl, hexyl, benzyl, 2- ethylhexyl, isobornyl, cyclohexyl, tetrahydrofurfuryl 2-hydroxyethyl, 2-hydroxypropyl, meth- oxyethyl, ethoxyethyl, glycerol, phenoxyethyl, methoxydiethylene glycol, ethoxydiethylene glycol, polyethylene glycol, polypropylene glycol, glycidyl, N, N-dimethylaminoethyl,
- oligomers which carry vinyl ether groups and of polymers as described in WO 90/01512.
- copolymers of vinyl ether and maleic acid-functionalized mono- mers are also suitable.
- Unsaturated oligomers of this kind can also be referred to as pre- polymers.
- unsaturated carboxylic acids are acrylic acid, methacrylic acid, crotonic acid, ita- conic acid, cinnamic acid, and unsaturated fatty acids such as linolenic acid or oleic acid.
- Acrylic and methacrylic acid are preferred.
- amides of identical or different, unsaturated carbox- ylic acids with aromatic, cycloaliphatic and aliphatic polyamines having preferably 2 to 6, especially 2 to 4, amino groups are ethylenediamine, 1 ,2- or 1 ,3-propylenediamine, 1 ,2-, 1 ,3- or 1 ,4-butylenediamine, 1 ,5-pentylenediamine, 1 ,6-hexyle- nediamine, octylenediamine, dodecylenediamine, 1 ,4-diaminocyclohexane, isophoronediami- ne, phenylenediamine, bisphenylenediamine, di- ⁇ -aminoethyl ether, diethylenetriamine, tri- ethylenetetramine, di( ⁇ -aminoethoxy)- or di( ⁇ -aminopropoxy)ethan
- Suitable polyamines are polymers and copolymers, preferably with additional amino groups in the side chain, and oligoamides having amino end groups.
- unsaturated amides are methylenebisacrylamide, 1 ,6-hexamethylenebisacrylamide, diethylenetriaminetrismethacryl- amide, bis(methacrylamidopropoxy)ethane, ⁇ -methacrylamidoethyl methacrylate and N[( ⁇ - hydroxyethoxy)ethyl]acrylamide.
- the above mentioned aminoacrylates are preferentially used as component (a).
- component (a) Specific examples are given below in the context of the application in printing inks.
- Suitable unsaturated polyesters and polyamides are derived, for example, from maleic acid and from diols or diamines. Some of the maleic acid can be replaced by other dicarboxylic acids. They can be used together with ethylenically unsaturated comonomers, for example styrene.
- the polyesters and polyamides may also be derived from dicarboxylic acids and from ethylenically unsaturated diols or diamines, especially from those with relatively long chains of, for example 6 to 20 C atoms.
- polyurethanes are those composed of saturated or unsaturated diisocyanates and of unsaturated or, respectively, saturated diols.
- Polymers with (meth)acrylate groups in the side chain are likewise known. They may, for example, be reaction products of epoxy resins based on novolaks with (meth)acrylic acid, or may be homo- or copolymers of vinyl alcohol or hydroxyalkyl derivatives thereof which are esterified with (meth)acrylic acid, or may be homo- and copolymers of (meth)acrylates which are esterified with hydroxyalkyl (meth)acrylates.
- Suitable polymers with acrylate or methacrylate groups in the side chains are, for ex- ample, solvent soluble or alkaline soluble polyimide precursors, for example poly(amic acid ester) compounds, having the photopolymerizable side groups either attached to the backbone or to the ester groups in the molecule, i.e. according to EP 624826.
- Such oligomers or polymers can be formulated with the new photoinitiators and optionally reactive diluents, like polyfunctional (meth)acrylates in order to prepare highly sensitive polyimide precursor re- sists.
- the photopolymerizable compounds can be used alone or in any desired mixtures. It is preferred to use mixtures of polyol (meth)acrylates.
- polymers or oligomers having at least two ethylenically unsaturated groups and at least one carboxyl function within the molecule structure is an addition product formed between a carboxyl group-containing resin and an unsaturated compound having an ⁇ , ⁇ -unsatu rated double bond and an epoxy group.
- the binder polymers which are resulting from the reaction of an unsaturated carboxylic acid compound with one or more polymerizable compounds, for example, copolymers of (meth)acrylic acid, benzyl (meth)acrylate, styrene and 2-hydroxyethyl (meth)acrylate, copolymers of (meth)acrylic acid, styrene and ⁇ -methystyrene, copolymers of (meth)acrylic acid, N-phenylmaleimide, styrene and benzyl (meth)acrylate, copolymers of (meth)acrylic acid and styrene, copolymers of (meth)acrylic acid and benzyl (meth)acrylate, 5 copolymers of tetrahydrofurfuryl (meth)acrylate, styrene and (meth)acrylic acid, and the like.
- R 50 is hydrogen or methyl group
- M 30 is substituted or unsubstituted alkylene having 1 to 10 carbon atoms.
- the invention also provides compositions comprising as component (a) at least one ethylenically unsaturated photopolymerizable compound which is emulsified or dissolved in water.
- component (a) at least one ethylenically unsaturated photopolymerizable compound which is emulsified or dissolved in water.
- a prepolymer dispersion is understood as being a dispersion of water and at least one prepolymer dispersed therein.
- the concentration of water in these systems is, for example, from 5 to 80% by weight, in particular from 30 to 60% by weight.
- the concentration of the radiation-curable prepolymer or prepolymer mixture is, for example, from 95 to 20% by weight, in particular from 70 to 40% by weight.
- the sum of the percentages given for water and prepolymer is in each case 100, with auxiliaries and additives being added in varying quantities depending on the intended use.
- aqueous prepolymer dispersions of mono- or polyfunctional, ethylenically unsaturated prepolymers which are known per se, can be initiated by free radicals and have for example a content of from 0.01 to 1.0 mol of polymerizable double bonds per 100 g of prepolymer and an average molecular weight of, for example, at least 400, in particular from 500 to 10O00.
- Prepolymers with higher molecular weights may also be consid- ered depending on the intended application.
- Use is made, for example, of polyesters containing polymerizable C-C double bonds and having an acid number of not more than 10, of polyethers containing polymerizable C-C double bonds, of hydroxyl-containing reaction products of a polyepoxide, containing at least two epoxide groups per molecule, with at least one ⁇ , ⁇ -ethylenically unsaturated carboxylic acid, of polyurethane (meth)acrylates and of acrylic copolymers which contain ⁇ , ⁇ -ethylenically unsaturated acrylic radicals, as are described in EP 12339. Mixtures of these prepolymers can likewise be used.
- polymerizable prepolymers described in EP 33896 which are thioether adducts of polymerizable prepolymers having an average molecular weight of at least 600, a carboxyl group content of from 0.2 to 15% and a content of from 0.01 to 0.8 mol of polymerizable C-C double bonds per 100 g of prepolymer.
- thioether adducts of polymerizable prepolymers having an average molecular weight of at least 600, a carboxyl group content of from 0.2 to 15% and a content of from 0.01 to 0.8 mol of polymerizable C-C double bonds per 100 g of prepolymer.
- Other suitable aqueous dispersions, based on specific alkyl (meth)acrylate polymers, are described in EP 41125, and suitable waterdispersible, radiation-curable prepolymers of urethane acrylates can be found in DE 2936039.
- dispersion auxiliaries emulsifiers, antioxidants, e.g. 2,2-thiobis(4-methyl-6t- butylphenol) or 2,6-di-t-butylphenol, light stabilizers, dyes, pigments, fillers, such as glass or alumina, for example talc, gypsum, silicic acid, rutile, carbon black, zinc oxide, iron oxides, reaction accelerators, levelling agents, lubricants, wetting agents, thickeners, flatting agents, antifoams and other auxiliaries customary in paint technology.
- dispersion auxiliaries e.g. 2,2-thiobis(4-methyl-6t- butylphenol) or 2,6-di-t-butylphenol
- light stabilizers e.g. 2,2-thiobis(4-methyl-6t- butylphenol) or 2,6-di-t-butylphenol
- light stabilizers e.g. 2,2-thiobis(4-methyl-6t- but
- Suitable dispersion auxiliaries are water-soluble organic compounds which are of high molecular mass and contain polar groups, examples being polyvinyl alcohols, polyvinylpyrrolidone or cellulose ethers.
- Emulsifiers which can be used are nonionic emulsifiers and, if desired, ionic emulsifiers as well.
- photoinitiators (c) of the alpha-amino ketones e.g. (4-methylthiobenzoyl)-1-methyl-1-morpholinoethane (IRGACURE® 907), (4- morpholinobenzoyl)-1-benzyl-1-dimethylaminopropane (IRGACURE® 369), (4-morpholino- benzoyl)-1-(4-methylbenzyl)-1-dimethylaminopropane (IRGACURE® 379), (4-(2-hydroxy- ethyl)aminobenzoyl)-1 -benzyl-1 -dimethylaminopropane), (3,4-dimethoxybenzoyl)-1 -benzyl-1 - dimethylaminopropane.
- photoinitiators (c) of the alpha-amino ketones e.g. (4-methylthiobenzoyl)-1-methyl-1-morpholinoethane (IRGACURE® 907)
- novel photoinitiator systems are employed in hybrid systems, use is made, in addition to the novel free-radical hardeners, of cationic photoinitiators, of peroxide compounds, such as benzoyl peroxide (other suitable peroxides are described in US 4950581 column 19, lines 17-25), of aromatic sulfonium-, phosphonium- or iodonium salts as described for example in US4950581 , column 18, line 60 to column 19, line 10 or cyclopentadienylarene-iron(ll) complex salts, for example ( ⁇ 6 -iso-propylbenzene)( ⁇ 5 -cyclopentadienyl)iron(ll) hexafluoro- phosphate, as well as oxime sulfonic acid esters, as are, for example described in EP780729. Also pyridinium and (iso)quinolinium salts as described e.g. in EP497531 and EP 441232 may be used in combination
- the photopolymerizable compositions generally comprise 0.01 to 25 % by weight, preferably 0.05 to 15 % by weight, in particular 0.05 to 10 % by weight of the photoinitiator mixture, based on the solid composition.
- the amount refers to the sum of all photoinitiators added, if additionally to the photoinitiator mixture comprising compounds of the formula (I) or (I') and (HK), (MPO), (BPO), (BP), (TX), (KS), (BK), (PG), (BT), (Tl) further initiators (c) are employed. Accordingly, the amount either refers to the photoinitiator mixture (b) or the photoini- tiators (b) +(c).
- the photopolymerizable composition may include various additives (d).
- Subject of the invention therefore also is a photopolymerizable composition as described above, additionally to the photoinitiator (b) comprising at least one further photoinitiator (c), and/or other additives (d).
- thermal inhibitors which are intended to prevent premature polymerization
- examples being hydroquinone, hydroquinone derivatives, p- methoxyphenol, ⁇ -naphthol or sterically hindered phenols, such as 2,6-di-tert-butyl-p-cresol
- cop- per compounds such as copper naphthenate, stearate or octoate
- phosphorus compounds for example triphenylphosphine, tributylphosphine, triethyl phosphite, triphenyl phosphite or tribenzyl phosphite
- quaternary ammonium compounds for example tetramethylammonium chloride or trimethylbenzylammonium chloride
- hydroxylamine derivatives for example N- diethylhydroxylamine.
- UV absorbers and light stabilisers are disclosed in WO 04/074328, page 12, line 9 to page14, line 23, said disclosure hereby is incorporated by reference.
- the curing process can be assisted by adding photosensitizers, in particular, in compositions which are pigmented (for example with titanium dioxide), and also by adding a component which under thermal conditions forms free radicals, for example an azo compound such as 2,2'-azobis(4-methoxy-2,4-dimethylvaleronitrile), a triazene, diazo sulfide, pentazadiene or a peroxy compound, for instance a hydroperoxide or peroxycarbonate, for example t-butyl hydroperoxide, as described for example in EP245639.
- azo compound such as 2,2'-azobis(4-methoxy-2,4-dimethylvaleronitrile)
- a triazene diazo sulfide
- pentazadiene for instance a hydroperoxide or peroxycarbonate, for example t-butyl hydroperoxide, as described for example in EP245639.
- Surfactants, optical brighteners, pigments, dyes, wetting agents, levelling assistants, dispersants, aggregation preventers, antioxidants or fillers are further examples for additives (d).
- additives (d) In order to cure thick and pigmented coatings it is appropriate to add glass microspheres or pulverized glass fibres, as described for example in US 5013768.
- Suitable surfactants include anionic surfactants such as alkylbenzene- or alkylnahthalene- sulfonates, alkylsulfosuccinates or naphthalene formaldehyde sulfonates; cationic surfactants including, for example, quaternary salts such as benzyl tributyl ammonium chloride; or non- ionic or amphoteric surfactants such as polyoxyethylene surfactants and alkyl- or amidopro- pyl betaines, respectively.
- anionic surfactants such as alkylbenzene- or alkylnahthalene- sulfonates, alkylsulfosuccinates or naphthalene formaldehyde sulfonates
- cationic surfactants including, for example, quaternary salts such as benzyl tributyl ammonium chloride
- non- ionic or amphoteric surfactants such
- Polymeric dispersants may also be employed. Suitable polymeric dispersants are, for example, BYK's DISPERBYK® 101 , 1 15, 130, 140, 160, 161 , 162, 163, 164, 166, 168, 169, 170, 171 , 180, 182, 2000, 2001 , 2009, 2020, 2025, 2050, 2090, 2091 , 2095, 2096, 2150, Ciba's Ciba® EFKA® 4008, 4009, 4010, 4015, 4046, 4047, 4050, 4055, 4060, 4080, 4300, 4310, 4330, 4340, 4400, 4401 , 4402, 4403, 4406, 4500, 4510, 4520, 4530, 4540, 4550, 4560, Aji- nomoto Fine Techno's PB®711 , 821 , 822, 823, 824, 827, Lubrizol's SOLSPERSE® 1320, 13940, 17000, 20000,
- Subject of the invention also is a photopolymerizable composition as described above as further additive (d) comprising a dispersant or a mixture of dispersants as well as a photopoly- merizable composition as described above as further additive (d) comprising a pigment or a mixture of pigments.
- the binder which is alkaline developable, for example, a homopolymer of a polymerizable compound having one or more acid groups and one or more polymerizable unsaturated bonds in the molecule, or a copolymer of two or more kinds thereof, and a copolymer of one or more polymerizable compounds having one or more unsaturated bonds copolymerizable with these compounds and containing no acid group, can be used.
- Such compounds can be obtained by copolymerizing one or more kinds of a low molecular compound having one or more acid groups and one or more polymerizable unsaturated bonds in the molecule with one or more polymerizable compounds having one or more unsaturated bonds copolymeriz- able with these compounds and containing no acid group.
- Examples of polymerizable compounds having one or more phenolic hydroxy groups and one or more polymerizable unsaturated bonds in a molecule include hydroxyphenyl (meth)- acrylamide, dihydroxyphenyl (meth)acrylamide, hydroxyphenyl-carbonyloxyethyl (meth)acry- late, hydroxyphenyloxyethyl (meth)acrylate, hydroxyphenylthioethyl (meth)acrylate, dihydrox- yphenylcarbonyloxyethyl (meth)acrylate, dihydroxyphenyloxyethyl (meth)acrylate, and dihydr- oxy-phenylthioethyl (meth)acrylate.
- the polymerizable compounds having one or more -CO-NH-CO- group and one or more polymerizable unsaturated bond include maleimide and N-acryloyl-acrylamide. These polymerizable compounds become the high molecular compounds comprising a -CO-NH-CO- group, in which a ring is formed together with a primary chain by polymerization. Further, a methacrylic acid derivative and an acrylic acid derivative each having a -CO-NH-CO- group can be used as well.
- polymerizable compounds having one or more polymerizable unsaturated bond and containing no acid group include a compound having a polymerizable unsaturated bond, selected from esters of (meth)acrylic acid, such as methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, butyl (meth)acrylate, tetrahydrofurfuryl (meth)acrylate, benzyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, hydroxyethyl (meth)acrylate, hydroxypro- pyl (meth)acrylate, hydroxybutyl (meth)acrylate, glycerol mono(meth)acrylate, dihydroxypro- pyl (meth)acrylate, allyl (meth)acrylate, cyclohexyl (meth)acrylate, phenyl (meth)acrylate, methoxyphenyl (meth)acryl
- hydroxystyrene homo- or co-polymers or a novolak type phenol resin for example, poly(hydroxystyrene) and poly(hydroxystyrene-co-vinylcyclohexanol), a novolak resin, a cresol novolak resin, and a halogenated phenol novolak resin.
- polymeric binder components as described e.g. in JP 10-1711 19-A, in particular for use in color filters.
- the procedure normally comprises electrostatic or tribostatic spraying of the powder onto the substrate, for example metal or wood, melting of the powder by heating, and, after a smooth film has formed, radiation-curing of the coating with ultraviolet and/or visible light, using for example medium-pressure mercury lamps, metal halide lamps or xenon lamps.
- a particular advantage of the radiation-curable powder coatings over their heat-curable counterparts is that the flow time after melting the powder particles can be delayed in order to ensure the formation of a smooth, high-gloss coating.
- radiation-curable powder coatings can be for- mulated to melt at lower temperatures without the unwanted effect of shortening their lifetime. For this reason, they are also suitable as coatings for heat-sensitive substrates, for example wood or plastics.
- the powder coating formulations may also include UV absorbers. Appropriate examples are listed above in sections 1.-8.
- novel photocurable compositions are suitable, for example, as coating materials for substrates of all kinds, for example wood, textiles, paper, ceramics, glass, plastics such as for example polyesters, polyethylene terephthalate, polyolefins or cellulose acetate, especially in the form of films, and also metals such as Al, Cu, Ni, Fe, Zn, Mg or Co and GaAs, Si or SiC> 2 to which it is for example intended to apply a protective layer or a printing ink, or by means of imagewise exposure, to generate an image.
- substrates of all kinds for example wood, textiles, paper, ceramics, glass, plastics such as for example polyesters, polyethylene terephthalate, polyolefins or cellulose acetate, especially in the form of films, and also metals such as Al, Cu, Ni, Fe, Zn, Mg or Co and GaAs, Si or SiC> 2 to which it is for example intended to apply a protective layer or a printing ink, or by means of imagewise
- the novel radiation-sensitive compositions further find application as negative resists, having a very high sensitivity to light and being able to be developed in an aqueous alkaline medium without swelling. They are suitable for the production of printing forms for relief printing, planographic printing, photogravure or of screen printing forms, for the production of relief copies, for example for the production of texts in braille, for the production of stamps, for use in chemical milling or as a microresist in the production of integrated circuits.
- the compositions further may be used as photopatternable dielectric layer or coating, encapsulating ma- terial and isolating coating in the production of computer chips, printed boards and other electric or electronic components.
- the possible layer supports, and the processing conditions of the coating substrates, are just as varied.
- the solder resist is a substance which is used during the soldering of a given part to a printed circuit board for the purpose of preventing molten solder from adhering to irrelevant portions and protecting circuits. It is, therefore, required to possess such properties as high adhesion, insulation resistance, resistance to soldering temperature, resistance to solvents, resistance to alkalis, resistance to acids, and resistance to plating.
- alkaline materials include alkali metal hydroxides (for example, sodium hydroxide and potassium hydroxide), alkali metal carbonates (for example, sodium carbonate and potassium carbonate), alkali metal bicarbonates (for example, sodium bicarbonate and potassium bicarbonate), alkali metal silicates (for example, sodium silicate and potassium silicate), alkali metal metasilicates (for example, sodium metasilicate and potassium metasili- cate), triethanolamine, diethanolamine, monoethanolamine, morpholine, tetraalkylammonium hydroxides (for example, tetramethylammonium hydroxide), or trisodium phosphate.
- the concetration of the alkaline substance is 0.01 to 30 weight %, and pH is preferably 8 to 14.
- Suitable organic solvents which are miscible with water include methanol, ethanol, 2- propanol, 1-propanol, butanol, diacetone alcohol, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-butyl ether, diethyleneglycol dimethyl ether, propyleneglycol monomethyl ether acetate, ethyl-3-ethoxypropionate, methyl-3-methoxy- propionate, n-butyl acetate, benzyl alcohol, acetone, methyl ethyl ketone, cyclopentanone, cyclohexanone, 2-heptanone, 2-pentanone, epsilon-caprolactone, gamma-butylolactone, di- methylformamide, dimethylacetoamide, hexamethylphosphoramide, ethyl lactate, methyl lac- tate, epsilon-cap
- the concentration of the surface active agent is preferably 0.001 to 10 weight %.
- a final heat treatment is preferably carried out after the development processing.
- a support having a layer which is photopolymerized by exposing (hereinafter referred to as a photocured layer) is heated in an electric furnace and a drier, or the photocured layer is irradiated with an infrared lamp or heated on a hot plate.
- the heating temperature and time depend on the composition used and the thickness of the formed layer. In general, heating is preferably applied at about 120 0 C to about 250 0 C, for about 5 to about 60 minutes.
- the pigment which can be comprised in the composition according to the present invention is preferably a processed pigment, for example a powdery or pasty product prepared by finely dispersing a pigment into at least one resin selected from the group consisting of acrylic resin, vinyl chloride-vinyl acetate copolymer, maleic acid resin and ethyl cellulose resin.
- unsaturated urethanes derived from a polyisocyanate and an unsaturated compound having a hydroxy group or from a polyisocyanate, a polyol and an unsaturated compound having a hydroxy group.
- Subject of the invention therefore also is a photopolymerizable composition as described above, which is a printing ink, in particular an offset printing ink.
- the printing inks are also suitable, for example, for use in recording systems of the kind in which a printing ink is expressed from a small opening in the form of droplets which are directed towards a substrate on which an image is formed.
- Suitable substrates are, for exam- pie, textile fibre materials, paper, plastics or aluminium foils pretreated by the process according to the invention.
- Suitable recording systems are e.g. commercially available ink-jet printers. Preference is given to printing processes in which aqueous printing inks are used.
- Examples of aliphatic and cycloaliphatic polyols include alkylenediols having preferably from 2 to 12 carbon atoms, such as ethylene glycol, 1 ,2- or 1 ,3-propanediol, 1 ,2-, 1 ,3- or 1 ,4- butanediol, pentanediol, hexanediol, octanediol, dodecanediol, diethylene glycol, triethylene glycol, polyethylene glycols having molecular weights of preferably from 200 to 1500, 1 ,3- cyclopentanediol, 1 ,2-, 1 ,3- or 1 ,4-cyclohexanediol, 1 ,4-dihydroxymethylcyclohexane, glycerol, tris( ⁇ -hydroxyethyl)amine, trimethylolethane, trimethylolpropane, pentaerythr
- the ink compositions comprising the novel photoinitiator mixture according to the present invention.
- the amount of the photopolymerizable monomer, oligomer or prepolymer in this connection is for example 10 to 80wt%, preferably 10 to 60wt%.
- compositions suitable as for example ink-jet inks are dual cure compositions, which are cured first by heat and subsequently by UV or electron irradiation, or vice versa, and whose components contain ethylenic double bonds as described above capable to react on irradia- tion with UV light in presence of a photoinitiator, in the context of the invention the novel photoinitiator mixture as described above.
- the inks preferably comprise a total content of colorant of 1 to 35% by weight, in particular 1 to 30% by weight, and preferably 1 to 20% by weight, based on the total weight of ink.
- Ink jet inks may include a variety of further additives such as for example surfactants, bio- cides, buffering agents, anti-mold agents, pH adjustment agents, electric conductivity adjustment agents, chelating agents, anti-rusting agents, polymerisation inhibitors, light stabilizers, and the like. Such additives may be included in the ink jet inks in any effective amount, as desired.
- photocuring is employed in the coating of metals, in the case, for exam- pie, of the coating of metal plates and tubes, cans or bottle caps, and the photocuring of polymer coatings, for example of floor or wall coverings based on PVC.
- photocuring of paper coatings are the colourless varnishing of labels, record sleeves and book covers.
- the pre-polymerized adhesives containing the isocyanates can for example be processed at high temperature and coated onto the substrate following the hotmelt process, afterwards full cure is achieved by an additional curing step involving the blocked isocyanates, which is realized by photoactivation of the photolatent catalyst.
- the novel photoinitiators for curing shaped articles made from composite compositions.
- the composite compound consists of a self-supporting matrix material, for example a glass fibre fabric, or alternatively, for example, plant fibres [cf. K.-P. Mieck, T. Reussmann in Kunststoffe 85 (1995), 366-370], which is impregnated with the photocuring formulation.
- Shaped parts comprising composite compounds, when produced using the novel compounds, attain a high level of mechanical stability and resistance.
- the novel compounds can also be employed as photocuring agents in moulding, impregnating and coating compositions as are described, for example, in EP7086.
- moulding, impregnating and coating compositions are UP resin gel coats for mouldings containing glass fibres (GRP), such as corrugated sheets and paper laminates.
- Paper lami- nates may be based on urea resins or melamine resins.
- the gel coat Prior to production of the laminate, the gel coat is produced on a support (for example a film).
- the novel photocurable compositions can also be used for casting resins or for embedding articles, for example electronic components, etc..
- compositions and compounds according to the invention can be used for the production of holographies, waveguides, optical switches wherein advantage is taken of the development of a difference in the index of refraction between irradiated and unirradiated areas.
- the layer (wet or dry) applied to the support is irradiated imagewise, e.g. through a photomask, with UV or visible light, and the unexposed areas of the layer are removed by treatment with a developer.
- Application of the photocurable layer to metal can also be carried out by electrodeposition.
- the exposed areas are polymeric through crosslinking and are therefore insoluble and remain on the support. Appropriate colouration produces visible images.
- the support is a metallized layer
- the metal can, following exposure and development, be etched away at the unexposed areas or reinforced by electroplating.
- the choice of solvents and the concentration depend principally on the type of composition and on the coating technique.
- the solvent should be inert, i.e. it should not undergo a chemical reaction with the components and should be able to be removed again, after coating, in the course of drying.
- imagewise exposure includes both, exposure through a photomask comprising a predetermined pattern, for example a slide, a chromium mask, a stencil mask or a reticle, as well as exposure by means of a laser or light beam, which for example is moved under com- puter control over the surface of the coated substrate and in this way produces an image.
- Suitable UV laser exposure systems for the purpose are, for example, provided by Etec and Orbotech (DP-100TM DIRECT IMAGING SYSTEM).
- the novel compositions can be developed by aqueous alkalis or organic solvents.
- Particularly suitable aqueous-alkaline developer solutions are aqueous solutions of tetraalkylammonium hydroxides or of alkali metal silicates, phosphates, hydroxides and carbonates. Minor quantities of wetting agents and/or organic solvents may also be added, if desired, to these solutions. Examples of typical organic solvents, which may be added to the developer liquids in small quantities, are cyclohexanone, 2-ethoxyethanol, toluene, acetone and mixtures of such solvents.
- the invention therefore also provides a process for the photopolymerization of compounds containing ethylenically unsaturated double bonds, i.e. monomeric, oligomeric or polymeric compounds containing at least one ethylenically unsaturated double bond, which comprises adding to these compounds at least one photoinitiator mixture as described above and irradiating the resulting composition with electromagnetic radiation, in particular light of the wavelength 150 to 600 nm, in particular 190-600 nm, with electron beam, or with X-rays.
- electromagnetic radiation in particular light of the wavelength 150 to 600 nm, in particular 190-600 nm, with electron beam, or with X-rays.
- the invention further provides a coated substrate which is coated on at least one surface with a composition as described above, and describes a process for the photographic pro- duction of relief images, in which a coated substrate is subjected to imagewise exposure and then the unexposed portions are removed with a developer.
- Imagewise exposure may be effected by irradiating through a mask or by means of a laser or electron beam as already described above.
- laser beam exposure al- ready mentioned above.
- the photoinitiator mixtures of the invention have a good thermal stability, low volatility, good storage stability and high solubility, and are also suitable for photopolymerisations in the presence of air (oxygen). Further, they cause only low yellowing in the compositions after photopolymerization, as well as an excellent resolution in resist applications, in particular color filters and high curing speeds in particular in printing ink applications.
- Example A1 mixtures with compounds of the formula (HK)
- Table A1 Cure speed measured by REL of HK-2 and blend HK-2 / oxime in the presence of HK-1 in a blue flexo ink; Gallium lamp, cold mirrors, 150 W/cm under nitrogen, white PEC foil corona treated
- Table A2 Cure speed measured by REL of HK-3 / BP-1 and a blend HK-3/BP-1 /oxime in a blue flexo ink; Hg lamp, cold mirrors , 200 W/cm under nitrogen 700 ppm O 2 , white PEC foil corona treated
- Table A3 Cure speed measured by REL and rubbing of BP-2 and blend BP-2 / oxime with 2% EDB in a blue flexo ink; Hg lamp, cold mirrors, 200 W/cm under air, white PEC foil
- Table A5 Cure speed measured by REL of MPO-1 and blend MPO-1 / oxime in a blue flexo ink; Ga lamp, cold mirrors, 150 W/cm under nitrogen, white PEC foil corona treated
- Example A6 mixture with compound of the formula (HK) and (BPO)
- Table A6 Cure speed measured by REL of BPO-1 and blend BPO-1/oxime with HK-1 in a blue flexo ink; Ga lamp, cold mirrors, 200 W/cm under inert atmosphere
- Table A7 Cure speed measured by REL of KS-1 and blend KS-1 /oxime with and without EDB in a blue flexo ink; Hg lamp, cold mirrors, 200 W/cm under air, white PEC
- Example A9 curing of an adhesive formulation
- a UV curable acrylic adhesive formulation is prepared comprising 50% aliphatic urethane acrylate (Ebecryl 270 from Cytec), 25% isobornyl acrylate (IBOA), 25% trimethylolpropane triacrylate (TMPTA), and photoinitiator as indicated in the table A9
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Abstract
Description
Claims
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CN2009801436477A CN102203136B (en) | 2008-11-03 | 2009-10-23 | Photoinitiator mixtures |
JP2011535068A JP5623416B2 (en) | 2008-11-03 | 2009-10-23 | Photoinitiator mixture |
US13/127,068 US8507726B2 (en) | 2008-11-03 | 2009-10-23 | Photoinitiator mixtures |
EP09737002.7A EP2342237B1 (en) | 2008-11-03 | 2009-10-23 | Photoinitiator mixtures |
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EP (1) | EP2342237B1 (en) |
JP (1) | JP5623416B2 (en) |
KR (1) | KR101648996B1 (en) |
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CN102471150A (en) * | 2010-06-30 | 2012-05-23 | 帝斯曼知识产权资产管理有限公司 | D1492 liquid bapo photoinitiator and its use in radiation curable compositions |
US8633258B2 (en) | 2010-06-30 | 2014-01-21 | Dsm Ip Assets B.V. | D1492 liquid BAPO photoinitiator and its use in radiation curable compositions |
CN102471150B (en) * | 2010-06-30 | 2014-05-07 | 帝斯曼知识产权资产管理有限公司 | D1492 liquid bapo photoinitiator and its use in radiation curable compositions |
JP2013042096A (en) * | 2011-08-19 | 2013-02-28 | Dainippon Printing Co Ltd | Photosensitive resin composition for optical imprint, hardened material, resist substrate, and manufacturing method of semiconductor device |
US10072173B2 (en) | 2012-03-22 | 2018-09-11 | 3M Innovative Properties Company | Polymethylmethacrylate based hardcoat composition and coated article |
WO2015036910A1 (en) | 2013-09-10 | 2015-03-19 | Basf Se | Oxime ester photoinitiators |
US9957258B2 (en) | 2013-09-10 | 2018-05-01 | Basf Se | Oxime ester photoinitiators |
US10793555B2 (en) | 2013-09-10 | 2020-10-06 | Basf Se | Oxime ester photoinitiators |
EP3232268A4 (en) * | 2014-12-10 | 2018-01-03 | Goo Chemical Co., Ltd. | Solder resist composition and covered printed wiring board |
US10317796B2 (en) | 2014-12-10 | 2019-06-11 | Goo Chemical Co., Ltd. | Solder resist composition and covered printed wiring board |
WO2017033880A1 (en) * | 2015-08-24 | 2017-03-02 | 株式会社Adeka | Oxime ester compound and polymerization initiator containing compound |
Also Published As
Publication number | Publication date |
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TWI453184B (en) | 2014-09-21 |
KR101648996B1 (en) | 2016-08-17 |
US20110218266A1 (en) | 2011-09-08 |
US8507726B2 (en) | 2013-08-13 |
JP2012507571A (en) | 2012-03-29 |
EP2342237A1 (en) | 2011-07-13 |
JP5623416B2 (en) | 2014-11-12 |
CN102203136B (en) | 2013-11-13 |
TW201033161A (en) | 2010-09-16 |
KR20110091742A (en) | 2011-08-12 |
EP2342237B1 (en) | 2014-04-23 |
CN102203136A (en) | 2011-09-28 |
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