WO2010055236A1 - Dispositif et procede de controle d'une concentration d'un desinfectant halogene dans une piscine ou similaire. - Google Patents
Dispositif et procede de controle d'une concentration d'un desinfectant halogene dans une piscine ou similaire. Download PDFInfo
- Publication number
- WO2010055236A1 WO2010055236A1 PCT/FR2009/001323 FR2009001323W WO2010055236A1 WO 2010055236 A1 WO2010055236 A1 WO 2010055236A1 FR 2009001323 W FR2009001323 W FR 2009001323W WO 2010055236 A1 WO2010055236 A1 WO 2010055236A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- reagent
- liquid
- case
- measurement
- colored
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N31/00—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods
- G01N31/22—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators
- G01N31/223—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating presence of specific gases or aerosols
- G01N31/224—Investigating or analysing non-biological materials by the use of the chemical methods specified in the subgroup; Apparatus specially adapted for such methods using chemical indicators for investigating presence of specific gases or aerosols for investigating presence of dangerous gases
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/01—Arrangements or apparatus for facilitating the optical investigation
- G01N21/03—Cuvette constructions
- G01N21/05—Flow-through cuvettes
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N2201/00—Features of devices classified in G01N21/00
- G01N2201/06—Illumination; Optics
- G01N2201/062—LED's
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/11—Automated chemical analysis
- Y10T436/115831—Condition or time responsive
- Y10T436/116664—Condition or time responsive with automated titrator
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/19—Halogen containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T436/00—Chemistry: analytical and immunological testing
- Y10T436/19—Halogen containing
- Y10T436/193333—In aqueous solution
Definitions
- the present invention relates to a device and a method for controlling a concentration of a halogen disinfectant in a pool or the like.
- the invention will advantageously be used in the field of controlling the chlorine or bromine concentration of individual outdoor pools.
- the device and the associated method may be used in the control and treatment of pool water pools or pools of various types including Jacuzzi or aquarium.
- the chlorine or bromine doses are calculated according to the characteristics of the pool when the latter is discovered; when the pool is covered, the rate of disappearance of chlorine and bromine is considerably slowed down and, because of a lack of real-time regulation, the concentration increases rapidly and becomes too high. This too high concentration is detrimental since it makes the water aggressive for the skin and for the pelvic liner.
- Another disadvantage lies in the fact that the lack of regulation generates a high consumption of disinfectant.
- a control device has been proposed on the market for measuring, in real time, the concentration of halogen disinfectant.
- This device using a probe based on the redox effect is however not satisfactory. Indeed the measurement of the redox potential is not reliable given many external parameters parasitic measures.
- the device deduces an absence of chlorine or bromine in the absence of electrolysis, or this absence of electrolysis may be due to a small presence of microbe in the water to be analyzed. In this case the device controls the addition of a new dose of disinfectant even though the concentration of disinfectant may be higher than the maximum concentration required.
- the present invention aims to provide a device and a method for measuring in real time the concentration of halogen disinfectant, without risk of false measurement due to bleaching phenomena or a lack of reagent injection.
- control method comprises:
- a step of injecting a colored reagent into the analysis chamber a step of colorimetric measurement of the liquid / reagent mixture, a step of processing the measurement with respect to data, a step of verifying the measurement.
- colorimetric when the measurement corresponds to a case of reagent whitening or a case of absence of the reaction color.
- This last verification step makes it possible to detect, in the event of suspicious measurements detected during the treatment step, a high concentration of halogenated compounds causing bleaching or a reagent supply problem of the analysis chamber.
- This verification step is advantageously followed by a control step thus making it possible to have in real time a suitable dosage of disinfectant.
- the invention also relates to a device for implementing the aforementioned method, the device comprising an analysis chamber, a reagent reservoir, colorimetric analysis means, first and second means for respectively introducing the liquid to be analyzed and the reagent into the chamber.
- the device also comprises means for mixing the colored reagent with the water to be analyzed, said stirring means comprising at least one baffle.
- FIG. 1 there is shown a device 1 according to the invention with an analysis chamber 2, a reagent reservoir 3, colorimetric analysis means 4.
- the device 1 further comprises first introduction means 5 arranged between the arrival of the liquid to be analyzed, typically the water inlet of the swimming pool, and the analysis chamber 2 and the second introduction means 6 of the In the example of FIG. 1, these introduction means 5 and 6 share a three-way injector, however, in another embodiment, the introduction of the reagent and the liquid are independent.
- the first input means 5 comprise a peristaltic pump 7.
- the introduction of the water is effected not by a pump but by a system generating a pressure difference.
- the second introduction means 6 comprise a metering pump 8 for injecting precise volumes of reagent into the analysis chamber 2.
- stirring means 9 are fixed and consist of baffles 10 or deflectors for stirring facilitating mixing.
- the stirring means 9 will consist of moving means such as motorized propellers.
- the colorimetric analysis is carried out in the analysis chamber 2 by the colorimetric analysis means 4 comprising a set of light-emitting diodes 11 associated with receivers 12 and processing means not shown in the attached figure.
- filtration means 13 and a return of the filtered liquid are also provided in the pool circuit.
- a recovery tank for the mixture is provided, the whole being treated or recycled in a separate device.
- control method is described according to the device 1 presented above and which is particularly adapted to said method, it is however important to note that the method could be implemented in other devices.
- the first input means 5 are controlled so as to inject liquid to be analyzed into the analysis chamber 2. This step can be started at fixed or variable intervals according to a program determined.
- the method then involves injecting a colored reagent into the analysis chamber 2.
- the injection can be performed in one or more times with varying durations and injection volumes.
- a single injection is performed so as to limit the consumption of reagent.
- the method then comprises processing the colorimetric measurement of the mixture in a processing step relative to stored data. In order to perform a reliable analysis, in a preferred embodiment several measurements are carried out so as to obtain a statistical value. This value is then compared with stored data corresponding to reference values and / or historical values.
- the analysis is completed.
- the statistical value serves as a basis for controlling an electrolyser or a chlorine pump when the chlorine content analyzed is insufficient.
- the device then goes to sleep until the next analysis.
- the method comprises a verification step.
- This verification step depends on the measurement adopted in the previous step if this measurement corresponds to a reagent bleaching case, which occurs when the concentration of halogenated compound exceeds a limit, the verification step consists of injecting at least one new dose of reagent and to carry out a succession of colorimetric surveys during the injection and mixing phases of the colored reagent with the liquid to be analyzed. These different measurements make it possible to calculate the absorption speed of the colored reagent and to confirm a case of reagent whitening.
- the verification step comprises steps of injection at determined intervals of increasing doses of colored reagent.
- the treatment means make it possible to identify the bleaching case and the level of halogenated compound as a function of the reaction rate on the one hand and the volume of reagent on the other hand injected into the analysis chamber.
- the verification step consists in injecting at least one new dose of reagent and raising the brightness in the chamber of analysis 2 to distinguish a case of concentration of halogenated compound of a case of non-injection of the colored reagent. Indeed by controlling at least one additional dose of reagent is obtained, if the device actually sends the reagent in the analysis chamber an increase in the concentration of the colored reagent that results in a change in brightness, the reagent being colored.
- the verification step comprises injections of doses of colored reagent at increasing times.
- the measurement of the brightness will not vary or little over time and therefore the process makes it possible to distinguish between a lack of reaction due to zero or very low concentration.
- halogenated compound on the one hand and on the other hand a failure in the means of introduction of the reagent or a lack of reagent in the tank.
- the method thus makes it possible to avoid disinfectant dispensing control in the pool because of a misinterpretation of the colorimetric measurements and also, according to an advantageous mode, to report by means of an alert of a dysfunction of the device. .
- the process comprises at the end and / or at the beginning of each colorimetric measurement cycle a rinsing step of the analysis chamber 2.
- a filtering step is also provided for the liquid / colored reagent assembly making it possible to limit the residues due to the control of the liquid to be analyzed.
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Pathology (AREA)
- Immunology (AREA)
- General Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plasma & Fusion (AREA)
- Engineering & Computer Science (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Biophysics (AREA)
- Molecular Biology (AREA)
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/128,359 US8778692B2 (en) | 2008-11-17 | 2009-11-17 | Measurement method for measuring the level of halogen agents in swimming-pool water |
EP09768110A EP2373990A1 (fr) | 2008-11-17 | 2009-11-17 | Dispositif et procede de controle d'une concentration d'un desinfectant halogene dans une piscine ou similaire. |
CN200980146468.9A CN102216770B (zh) | 2008-11-17 | 2009-11-17 | 用于监测游泳池等中的卤代消毒剂浓度的仪器及方法 |
AU2009315505A AU2009315505B2 (en) | 2008-11-17 | 2009-11-17 | Device and method for monitoring the concentration of a halogenated disinfectant in a swimming pool or the like |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0806409 | 2008-11-17 | ||
FR0806409A FR2938653B1 (fr) | 2008-11-17 | 2008-11-17 | Dispositif et procede de controle d'une concentration d'un desinfectant halogene dans une piscine ou similaire |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2010055236A1 true WO2010055236A1 (fr) | 2010-05-20 |
Family
ID=40791649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2009/001323 WO2010055236A1 (fr) | 2008-11-17 | 2009-11-17 | Dispositif et procede de controle d'une concentration d'un desinfectant halogene dans une piscine ou similaire. |
Country Status (6)
Country | Link |
---|---|
US (1) | US8778692B2 (fr) |
EP (1) | EP2373990A1 (fr) |
CN (1) | CN102216770B (fr) |
AU (1) | AU2009315505B2 (fr) |
FR (1) | FR2938653B1 (fr) |
WO (1) | WO2010055236A1 (fr) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108181252A (zh) * | 2018-02-09 | 2018-06-19 | 广东贝特涞生物科技有限公司 | 消毒剂检测装置、添加装置及添加方法 |
DE102022121644A1 (de) * | 2022-08-26 | 2024-02-29 | Kowalytics UG (haftungsbeschränkt) | Messvorrichtung, Zusatzmodul, Messsystem und Verfahren für die Wasseranalyse |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2977199A (en) * | 1956-12-31 | 1961-03-28 | Ind Rayon Corp | Method for the continuous testing of flowing materials |
US3226195A (en) * | 1960-08-02 | 1965-12-28 | Atomic Energy Authority Uk | Testing for the presence or absence of a reagent in liquors |
US3466450A (en) * | 1966-08-04 | 1969-09-09 | William L Goodman | Swimming pool chlorine concentration controller using reference resistor in control circuit |
US3574553A (en) * | 1968-01-08 | 1971-04-13 | Howard Precision Inc | Fluid analyzer |
US4207450A (en) * | 1978-06-14 | 1980-06-10 | The United States Of America As Represented By The Secretary Of The Navy | Continuous oil concentration monitor |
CA2169248A1 (fr) * | 1996-02-09 | 1997-08-10 | Etienne Prive | Systeme pour la surveillance et la regulation automatiques des produits chimiques utilises pour l'entretien de l'eau des piscines |
US6180412B1 (en) * | 1999-03-26 | 2001-01-30 | Hach Company | Test for chlorine in water |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1960615A (en) * | 1929-06-25 | 1934-05-29 | Wallace & Tiernan Company Inc | Measuring and controlling apparatus |
US1986403A (en) * | 1932-01-25 | 1935-01-01 | Henry W Lehmkuhl | Method for testing chlorine solutions |
NL7304229A (fr) * | 1973-03-27 | 1974-10-01 | ||
CA1174833A (fr) * | 1980-06-10 | 1984-09-25 | Alan Queen | Dispositif coupe-debit |
US4865992A (en) * | 1986-08-28 | 1989-09-12 | Hach Company | System and method for quantitative analysis of a solution |
US5004696A (en) * | 1988-03-24 | 1991-04-02 | Ashland Oil, Inc. | Automatic total reducers monitoring and adjustment system |
US5098186A (en) * | 1990-10-12 | 1992-03-24 | Christopher Bull | Stopped flow spectrophotometer mixer |
JP3118552B2 (ja) * | 1991-02-27 | 2000-12-18 | ロッシュ ダイアグノスティックス コーポレイション | 体液の分析装置及び方法 |
US6180413B1 (en) * | 1999-07-13 | 2001-01-30 | Westinghouse Savannah River Company | Low level TOC measurement method |
US6881583B2 (en) * | 2002-06-16 | 2005-04-19 | Applied Spectrometry Associates Inc. | Water chloramination control system |
CN101241080B (zh) * | 2008-01-25 | 2011-06-15 | 黄晓平 | 一种检测水中多形态氯的便捷比色法及其比色仪 |
-
2008
- 2008-11-17 FR FR0806409A patent/FR2938653B1/fr active Active
-
2009
- 2009-11-17 AU AU2009315505A patent/AU2009315505B2/en not_active Ceased
- 2009-11-17 US US13/128,359 patent/US8778692B2/en not_active Expired - Fee Related
- 2009-11-17 EP EP09768110A patent/EP2373990A1/fr not_active Withdrawn
- 2009-11-17 WO PCT/FR2009/001323 patent/WO2010055236A1/fr active Application Filing
- 2009-11-17 CN CN200980146468.9A patent/CN102216770B/zh not_active Expired - Fee Related
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2977199A (en) * | 1956-12-31 | 1961-03-28 | Ind Rayon Corp | Method for the continuous testing of flowing materials |
US3226195A (en) * | 1960-08-02 | 1965-12-28 | Atomic Energy Authority Uk | Testing for the presence or absence of a reagent in liquors |
US3466450A (en) * | 1966-08-04 | 1969-09-09 | William L Goodman | Swimming pool chlorine concentration controller using reference resistor in control circuit |
US3574553A (en) * | 1968-01-08 | 1971-04-13 | Howard Precision Inc | Fluid analyzer |
US4207450A (en) * | 1978-06-14 | 1980-06-10 | The United States Of America As Represented By The Secretary Of The Navy | Continuous oil concentration monitor |
CA2169248A1 (fr) * | 1996-02-09 | 1997-08-10 | Etienne Prive | Systeme pour la surveillance et la regulation automatiques des produits chimiques utilises pour l'entretien de l'eau des piscines |
US6180412B1 (en) * | 1999-03-26 | 2001-01-30 | Hach Company | Test for chlorine in water |
Also Published As
Publication number | Publication date |
---|---|
AU2009315505B2 (en) | 2012-12-20 |
FR2938653B1 (fr) | 2011-02-11 |
CN102216770A (zh) | 2011-10-12 |
AU2009315505A1 (en) | 2010-05-20 |
EP2373990A1 (fr) | 2011-10-12 |
CN102216770B (zh) | 2014-06-04 |
US20110217788A1 (en) | 2011-09-08 |
FR2938653A1 (fr) | 2010-05-21 |
US8778692B2 (en) | 2014-07-15 |
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