WO2010054896A1 - Verfahren zur herstellung von telechelen mit einer breiten molekulkargewichtsverteilung - Google Patents
Verfahren zur herstellung von telechelen mit einer breiten molekulkargewichtsverteilung Download PDFInfo
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/001—Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
- C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/02—Neutralisation of the polymerisation mass, e.g. killing the catalyst also removal of catalyst residues
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/26—Removing halogen atoms or halogen-containing groups from the molecule
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/34—Introducing sulfur atoms or sulfur-containing groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J153/00—Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/01—Atom Transfer Radical Polymerization [ATRP] or reverse ATRP
Definitions
- the invention relates to a controlled Polymehsations Kunststoffus for producing (meth) acrylate-based telechelics, which have a broad, monomodal molecular weight distribution, and their use as binders in adhesives or sealants.
- Tailored copolymers with defined composition, chain length, molecular weight distribution, etc. are a broad field of research. One differentiates among other things between gradient and block polymers. For such materials, various applications are conceivable. In the following some of them are briefly presented.
- Polymers can be prepared for example by ionic polymerization or by polycondensation or addition. In these methods, the presentation of end phenomenonfunktionalinstrumenter products is not a problem. However, a targeted molecular weight buildup is problematic.
- Polymers obtained by a free radical polymerization process show molecularity indices well above 1, 8. Thus, it is inevitably very short-chain and long-chain polymers in the overall product in such a molecular weight distribution.
- the short-chain polymer chains show in melt or solution a reduced viscosity and in a polymer matrix increased mobility compared to long-chain components. This leads, on the one hand, to an improved processability of such polymers and, on the other hand, to an increased availability of polymer-bound functional groups in a polymer composition or coating.
- Suitable living or controlled polymerization methods are, in addition to anionic or group transfer polymerization, also modern methods of controlled free-radical polymerization, such as, for example, RAFT polymerization.
- the atom transfer radical polymerization (ATRP) method was decisively developed in the 1990s by Prof. Matyjaszewski (Matyjaszewski et al., J. Am. Chem. Soc., 1995, 117, p.5614, WO 97/18247; Science, 1996, 272, p. 866).
- Binders with a defined polymer design can be made available by a controlled polymerization method, for example in the form of atom transfer radical polymerization.
- ABA triblock copolymers are described which have an unfunctionalized B block and functionalized A outer blocks.
- EP 1 475 397 describes such polymers with OH groups, in WO 2007/033887 with olefinic, in WO 2008/012116 with amine and in the not yet published DE 102008002016 with silyl groups.
- all polymers described in these documents have an explicitly narrow molecular weight distribution.
- the so-called controlled polymerisation processes do not describe any processes with which it would be possible to produce polymers which have one or more blocks with a specifically broad molecular weight distribution.
- ATRP synthesized - e.g. Silyl-containing - (meth) acrylate copolymers having a statistical distribution and a narrow molecular weight distribution is an alternative.
- a disadvantage of such binders is a dense crosslinking.
- binder systems have neither the advantages of particularly long, nor particularly short polymer chains contained in the system.
- the object was to provide a method for the synthesis of telechelics, which in total have a polydispersity index of at least 1, 8 available.
- Molecular weight distribution of less than 1, 6 and B blocks which have a monomodal, broad molecular weight distribution having on the one hand long polymer chains and on the other hand, particularly short polymer chains composed.
- ABA triblock copolymers whose monomodal broad molecular weight distribution B blocks have a polydispersity index of at least 1.8, and ABA triblock copolymers containing these B blocks having an overall polydispersity index of at least 1.8.
- ABA triblock copolymers are equated with pentablock copolymers of the composition ACBCA or CABAC.
- the problem was solved by providing a new polymerization process based on atom transfer radical polymethylation (ATRP).
- ATRP atom transfer radical polymethylation
- a process for producing (meth) acrylate polymers characterized in that it is an atom transfer radical polymerization (ATRP) in which a bifunctional initiator is added to the polymerization solution and that the (meth) acrylate polymer has a polydispersity index greater 1, 8.
- ATRP atom transfer radical polymerization
- the initiation is started with a partial amount of the initiator, and then metered in a second amount of the initiator continuously.
- a process is provided in which the addition of suitable functional sulfur compounds causes a termination of the polymerization.
- suitable sulfur compounds By choosing suitable sulfur compounds, the respective chain ends are functionalized.
- the terminal halogen atoms are removed from the polymer and the transition metal needed for the polymerization is almost completely precipitated. This can then be easily separated by filtration.
- a process for the synthesis of telechelic ABA triblock copolymers having a polydispersity index greater than 1.8 Provided, characterized in that it is a sequentially carried out atom transfer radical polymerization (ATRP), in which a bifunctional initiator is added to the polymerization, and that the block copolymer as a whole and also the block type B has a polydispersity index greater than 1, 8.
- ATRP atom transfer radical polymerization
- the process corresponds as far as the production of polymers without block structure.
- ABA triblock or CABAC pentablock copolymers are built up.
- Both the initiation, the polymerization of the middle block B and the termination of the polymerization by adding suitable sulfur compounds take place analogously to the preparation of a polymer without a block structure. Therefore, both structures may be considered identical in view of the following description.
- the initiation is started with a partial amount of the initiator, and then a second amount of the initiator is metered in continuously.
- the block copolymers are prepared by a sequential polymerization process. This means that the monomer mixture for the synthesis of the blocks, for example A, are added to the system only after a polymerization time t 2 when the monomer mixture for the synthesis of the block, for example B, has been converted to at least 90%, preferably at least 95%. This process ensures that the B blocks are free of monomers of composition A and that the A blocks contain less than 10%, preferably less than 5% of the total amount of the monomers of composition B.
- the block boundaries are according to this definition at the respective point of the chain at which the first repeating unit of the added monomer mixture - in this example, the mixture A - is.
- a mere 95% conversion has the advantage that the remaining monomers, especially in the case of acrylates, enable a more efficient transition to the polymerization of a second monomer composition, especially of methacrylates. In this way, the yield of block copolymers is significantly improved.
- the initiator for the polymerization of the monomer mixture or for block copolymers of the monomer mixture B is only partially introduced for initiation and the remainder is added over a longer period of time to the polymer solution.
- the polymerization is started with the first batch.
- the first initiator charge is 10% to 60%, preferably 20% to 40% of the total amount of initiator. With the dosage of the remaining amount of initiator is started immediately or slightly delayed after the occurrence of an exotherm, but at the latest after 10 minutes.
- ti which can vary depending on the desired molecular weight.
- the time ti can be between 60 minutes and 6 hours, preferably between 90 minutes and 3 hours.
- t 2 may be an example of a desired molecular weight of 10,000 g / mol to 40,000 g / mol between 5 min and 6 hours, preferably between 30 min and 3 hours. For higher molecular weights quite longer polymerization times are necessary.
- the minimum molecular weight and the width of the molecular weight distribution of the B blocks can be adjusted in a targeted manner.
- the rapid start of the metering after the primary initiation further ensures that polymer blocks B having a monomodal molecular weight distribution are obtained.
- macroinitiators of composition B are formed for the sequential construction of block copolymers of composition ABA. These macroinitiators have a molecular weight distribution with a polydispersity index between 1, 8 and 3.0, preferably between 1, 9 and 2.5. After the polymerization time t 2 , finally, the monomer mixture A is added. Due to the character of the ATRP, both previously initiated polymer species of composition B are available for the polymerization at this time and the polymer blocks A are built up under the already known conditions of ATRP. Accordingly, these segments of the polymer chains show in themselves a narrow molecular weight distribution. In the case of pentablock polymers, it is also possible to construct blocks of type C or D accordingly.
- Another advantage of the present invention is the further prevention of recombination.
- the formation of particularly high molecular weights can be suppressed with this method.
- Such polymer components would contribute disproportionately to an increase in the solution or melt viscosity.
- the broadly distributed, monomodal polymer produced according to the invention has a novel polymer distribution.
- the chains are formed which are subject to the longest polymerization time and thus have the highest molecular weight in the end product.
- a polymer is obtained which, at high molecular weights, still has the characteristics of a polymer produced by controlled polymerization.
- the total molecular weight distribution of the polymers produced according to the invention has a polydispersity index greater than 1.8. According to the invention as a measure of the non-uniformity of
- Another component of the present invention is the targeted functionalization of the ABA, CABAC, ACBCA or CDBDC ⁇ Iockcopolymerymere with broad, monomodal molecular weight distribution at the chain ends.
- the object was achieved in that after completion of the ATRP by adding a suitable sulfur compound, the transition metal compound is precipitated and simultaneously the chain ends of the polymer are functionalized. In this way, the chain ends are at least 75%, preferably at least 85% functionalized.
- the reagents added according to the invention after or during the polymerization termination of the polymer solution are Compounds containing sulfur in organically bound form.
- These sulfur-containing compounds used for precipitation of transition metal ions or transition metal complexes particularly preferably have SH groups and at the same time a second functional group. Most preferably, this second functional group is a hydroxy, acid or silyl group.
- the particularly preferred compounds are commercially readily available compounds used in free-radical polymerization as regulators. The advantage of these compounds is their easy availability, their low price and the wide range of variations that allow optimal adaptation of the precipitating reagents to the respective polymerization system. However, the present invention can not be limited to these compounds.
- organic compounds are very particularly preferably functionalized
- the hydroxy-functional sulfur compounds may be, for example, organic compounds such as mercaptoethanol, mercaptopropanol, mercaptobutanol,
- the acid-functional sulfur compounds may be, for example, organic compounds such as thioglycolic acid or mercaptopropionic acid.
- the silyl-functional sulfur compounds may be, for example, commercially available compounds, e.g. as adhesion agents have great industrial significance. Advantage of these compounds is their easy
- DYNALYSAN® ® MTMO is marketed. Further available silanes are 3-
- ABCR Mercaptopropylthethoxysilane or 3-mercaptopropylmethyldimethoxysilane
- Particularly reactive are the so-called ⁇ -silanes.
- the mercapto group and the silane group are bonded to the same carbon atom (R 1 is thus usually -CH 2 -).
- R 1 is thus usually -CH 2 -.
- Corresponding silane groups of this type are particularly reactive and can thus lead to a broader range of applications in the later formulation.
- An example of such a compound would be mercaptomethylmethyldiethoxysilane (ABCR).
- the amount of regulators based on the monomers to be polymerized, usually with 0.05% by weight to 5% by weight specified.
- the amount of the sulfur compound used is not related to the monomers but to the concentration of the polymerization-active chain ends in the polymer solution.
- polymerization-active chain ends is meant the sum of dormant and active chain ends.
- the sulfur-containing precipitating agents according to the invention are used in this sense in 1, 5 molar equivalents, preferably 1, 2 molar equivalents, more preferably below 1, 1 molar equivalents and most preferably below 1.05 molar equivalents. The remaining amounts of residual sulfur can be easily removed by modification of the following filtration step.
- the mercaptans described may have no further influence on the polymers when added to the polymer solution during or after termination of the polymerization, with the exception of the substitution reaction described. This applies in particular to the breadth of the molecular weight distributions, the molecular weight, additional functionalities, glass transition temperature or melting temperature in semicrystalline polymers and polymer architectures.
- the telechelic polymers or block copolymers according to the invention may contain additional functional groups which correspond to the end groups or may differ from these. In block copolymers, these additional functional groups can be incorporated selectively in one or more blocks.
- additional functional groups can be incorporated selectively in one or more blocks.
- the following list is only an example to illustrate the invention and is not intended to limit the invention in any way.
- the telechelic polymers may have additional OH groups.
- Hydroxy-functionalized (meth) acrylates which are suitable for this purpose are preferably hydroxyalkyl (meth) acrylates of straight-chain, branched or cycloaliphatic diols having 2-36 C atoms, for example 3-hydroxypropyl (meth) acrylate, 3,4-dihydroxybutyl mono (meth ) acrylate, 2-hydroxyethyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, 2-hydroxypropyl (meth) acrylate, 2,5-dimethyl-1,6-hexanediol mono (meth) acrylate, more preferably 2-hydroxyethyl methacrylate.
- Amine groups are, for example, by the Copolymehsation of 2-dimethylaminoethyl methacrylate (DMAEMA), 2-diethylaminoethyl methacrylate (DEAEMA), 2-te / t-butylaminoethyl ⁇ ethacrylat (t-BAEMA), 2-dimethylaminoethyl acrylate (DMAEA), 2nd -Diethylaminoethyl acrylate (DEAEA), 2-t / t-butylaminoethyl acrylate (t-BAEA), 3-dimethylaminopropyl-methacrylamide (DMAPMA) and 3-dimethylaminopropyl-acrylamide (DMAPA) representable.
- DMAEMA 2-dimethylaminoethyl methacrylate
- DEAEMA 2-diethylaminoethyl methacrylate
- t-BAEMA 2-te / t-butylamino
- Polymers with allyl groups can be realized, for example, by the copolymerization of allyl (meth) acrylate.
- Polymers with epoxy groups by the copolymerization of glycidyl (meth) acrylate.
- Acid groups can be realized by the copolymerization of tert-butyl (meth) acrylate and subsequent saponification or thermal cleavage of isobutene.
- Examples of (meth) acrylate-bonded silyl radicals are -SiCl 3 , -SiMeCl 2 , -SiMe 2 Cl, -Si (OMe) 3 , -SiMe (OMe) 2 , -SiMe 2 (OMe), -Si (OPh) 3 , -SiMe (OPh) 2 , -SiMe 2 (OPh), -Si (OEt) 3 , -SiMe (OEt) 2 , -SiMe 2 (OEt), -Si (OPr) 3 , -SiMe (OPr) 2 , -SiMe 2 (OPr), -SiEt (OMe) 2 , - SiEtMe (OMe), -SiPh (OMe) 2 , -SiPhMe (OMe), -SiPh 2 (OM (OMe), -SiPh
- Me are methyl
- Ph is phenyl
- Et is ethyl
- Pr is iso or n-propyl.
- a commercially available monomer is, for example, Dynasylan ® MEMO from Evonik Degussa GmbH. These are 3-methacryloxypropyltrimethoxysilane.
- the notation (meth) acrylate stands for the esters of (meth) acrylic acid and means here both methacrylate, such as methyl methacrylate, ethyl methacrylate, etc., as well as acrylate, such as methyl acrylate, ethyl acrylate, etc., as well as mixtures of the two.
- Monomers which are polymerized both in block A and in block B are selected from the group of (meth) acrylates, for example alkyl (meth) acrylates of straight-chain, branched or cycloaliphatic alcohols having 1 to 40 carbon atoms, for example methyl ( meth) acrylate, ethyl (meth) acrylate, n-butyl (meth) acrylate, i-butyl (meth) acrylate, t-butyl (meth) acrylate, pentyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, stearyl ( meth) acrylate, lauryl (meth) acrylate, cyclohexyl (meth) acrylate, isobornyl (meth) acrylate;
- Aryl (meth) acrylates such as benzyl (meth) acrylate or phenyl (meth) acrylate which may each have
- compositions to be polymerized may also contain further unsaturated monomers which are copolymerizable with the abovementioned (meth) acrylates and with ATRP.
- further unsaturated monomers which are copolymerizable with the abovementioned (meth) acrylates and with ATRP.
- these include, inter alia, 1-alkenes such as 1-hexene, 1-heptane, branched alkenes such as vinylcyclohexane, 3,3-dimethyl-1-propene, 3-methyl-1-diisobutylene, 4-methyl-1-pentene, acrylonitrile Vinyl esters such as vinyl acetate, styrene, substituted styrenes having an alkyl substituent on the vinyl group such as ⁇ -methylstyrene and ⁇ -ethylstyrene, substituted styrenes having one or more alkyl substituents on the ring such as vinyltoluene and p
- these copolymers can also be prepared so as to have a hydroxy and / or amino and / or mercapto functionality in a substituent.
- monomers are vinylpiperidine, 1-vinylimidazole, N-vinylpyrrolidone, 2-vinylpirrolidone, N-vinylpirrolidine, 3-vinylpyrrolidine, N-vinylcaprolactam, N-vinylbutyrolactam, hydrogenated vinylthiazoles and hydrogenated vinyl oxazoles.
- Vinyl esters, vinyl ethers, fumarates, maleates, styrenes or acrylonitriles are particularly preferably copolymerized with the A blocks and / or B blocks.
- the process can be carried out in any halogen-free solvents.
- Preference is given to toluene, xylene, H 2 O; Acetates, preferably butyl acetate, ethyl acetate, propyl acetate; Ketones, preferably ethyl methyl ketone, acetone; ether; Aliphatic, preferably pentane, hexane; biodiesel; but also plasticizers such as low molecular weight polypropylene glycols or phthalates.
- the block copolymers of composition ABA are prepared by sequential polymerization.
- the ATRP can also be carried out as emulsion, miniemulsion, microemulsion, suspension or bulk polymerization.
- the polymerization can be carried out at atmospheric pressure, underpressure or overpressure.
- the polymerization temperature is not critical. In general, however, it is in the range of -20 0 C to 200 0 C, preferably from 0 ° C to 130 0 C and particularly preferably from 50 ° C to 120 ° C.
- the polymer of the invention has a number average molecular weight between 5000 g / mol and 100000 g / mol, more preferably between 7500 g / mol and 50,000 g / mol and very particularly preferably ⁇ 30,000 g / mol.
- 1, 4-butanediol di (2-bromo-2-methylpropionate), 1, 2-ethylene glycol di (2-bromo-2-methylpropionate), 2,5-dibromo-adipic acid di-ethyl ester or 2,3-dibromo-maleic acid di-ethyl ester used. From the ratio of initiator to monomer results in the later molecular weight, if the entire monomer is reacted.
- Catalysts for ATRP are described in Chem. Rev. 2001, 101, 2921. Copper complexes are predominantly described, but iron, rhodium, platinum, ruthenium or nickel compounds are also used. In general, it is possible to use all transition metal compounds which, with the initiator or the polymer chain which has a transferable atomic group, have a redox Cycle can form.
- copper can be supplied to the system starting from CU 2 O, CuBr, CuCl, CuI, CuN 3 , CuSCN, CuCN, CuNO 2 , CuNO 3 , CuBF 4 , Cu (CH 3 COO) or Cu (CF 3 COO).
- a variant of the reverse ATRP represents the additional use of metals in the oxidation state zero.
- an acceleration of the reaction rate is effected. This process is described in more detail in WO 98/40415.
- the molar ratio of transition metal to bifunctional initiator is generally in the range of 0.02: 1 to 20: 1, preferably in the range of 0.02: 1 to 6: 1 and more preferably in the range of 0.2: 1 to 4: 1, without this being a restriction.
- ligands are added to the system.
- the ligands facilitate the abstraction of the transferable atomic group by the transition metal compound.
- a list of known ligands can be found, for example, in WO 97/18247, WO 97/47661 or WO 98/40415.
- the compounds used as ligands usually have one or more nitrogen, oxygen, phosphorus and / or sulfur atoms. Particularly preferred are nitrogen-containing compounds. Very particular preference is given to nitrogen-containing chelate ligands.
- Examples are 2,2'-bipyridine, N, N, N ' , N “ , N “ - Pentamethyldiethylenetriamine (PMDETA), tris (2-aminoethyl) amine (TREN), N, N, N ', N' - Tetramethylethylendiannin or 1, 1, 4,7,10,10-hexamethyl listed. Valuable information on the selection and combination of the individual components will be found by the person skilled in the art in WO 98/40415.
- ligands can form coordination compounds in situ with the metal compounds, or they can first be prepared as coordination compounds and then added to the reaction mixture.
- the ratio of ligand (L) to transition metal is dependent on the denticity of the ligand and the coordination number of the transition metal (M). In general, the molar ratio is in the range 100: 1 to 0.1: 1, preferably 6: 1 to 0.1: 1 and more preferably 3: 1 to 1: 1, without this being a restriction.
- the transition metal compound is precipitated by adding the described sulfur compound.
- the chain-terminating halogen atom is substituted to release a hydrogen halide.
- the hydrogen halide - e.g. HBr protonates the transition metal-coordinated ligand L to an ammonium halide. This process quenches the transition metal-ligand complex and precipitates the "bare" metal, and then allows the polymer solution to be easily purified by simple filtration, with sulfur compounds preferably being SH group compounds This is a known from the free radical polymerization regulator.
- EP 1 510 550 describes a coating composition which consists, inter alia, of acrylate particles and polyurethanes.
- a polymer according to the invention resulted in an improvement in the processing and crosslinking properties in a corresponding formulation.
- Conceivable applications are, for example, powder coating formulations.
- the new binders make it possible to produce crosslinkable one-component and two-component elastomers, for example for one of the listed applications.
- Typical further constituents of a formulation are solvents, fillers, pigments, plasticizers, stabilizing additives, water scavengers, adhesion promoters, thixotropic agents, crosslinking catalysts, tackifiers, etc.
- solvents can be used, for.
- aromatic hydrocarbons such as toluene, xylene, etc.
- esters such as ethyl acetate, butyl acetate, amyl acetate, Cellosolveacetat, etc.
- ketones such as.
- the solvent can be added already in the course of radical polymerization.
- Crosslinking catalysts for hydrosilylated binders in a formulation with, for example, corresponding polyurethanes are the common organic tin, lead, mercury and bismuth catalysts, e.g. Dibutyltin dilaurate (eg from BNT Chemicals GmbH), dibutyltin diacetate, dibutyltin diketonate (eg Metatin 740 from Acima / Rohm + Haas), dibutyltin dimaleate, tin naphthenate, etc. It is also possible to use reaction products of organic tin compounds, e.g. B.
- dibutyltin dilaurate with Silica esters can be used as crosslinking catalysts.
- titanates eg, tetrabutyl titanate, tetrapropyl titanate, etc.
- zirconates eg, tetrabutyl zirconate, etc.
- amines eg, butylamine, diethanolamine, octylamine, morpholine, 1,3-diazabicyclo [5.4.6] undecene-7 (DBU), etc.
- DBU 1,3-diazabicyclo [5.4.6] undecene-7
- An advantage of the block copolymers is the colorlessness and odorlessness of the product produced.
- Another advantage of the present invention is a limited number of functionalities. A higher proportion of functional groups in the binder leads to a possible premature gelation or at least to an additional increase in the solution or melt viscosity.
- the number-average or weight-average molecular weights Mn or Mw and the polydispersity index D Mw / Mn as a measure of the molecular weight distributions are determined by gel permeation chromatography (GPC) in tetrahydrofuran versus a PMMA standard.
- the polymerization is carried out analogously to Comparative Example 1 with the addition of the amounts indicated in Table 1. Termination of the reaction is carried out with the addition of 2.0 g of thioglycolic acid.
- the polymerization is carried out analogously to Comparative Example 1 with the addition of the amounts indicated in Table 1. Termination of the reaction is carried out with the addition of 5.0 g Dynasylan MTMO.
- MMA methyl methacrylate
- n-BA n-butyl acrylate
- Comparison games 1 to 3 show that with conventional addition of initiator in a batch, polymers with relatively narrow internal blocks and polydispersity indices smaller than 1.4 are formed. After removal of the solvent, the silyl-functionalized products can be stabilized by addition of suitable drying agents. In this way, a good storage stability can be ensured without further increase in molecular weight.
- a quantity of initiator (see Table 1) 1, 4-butanediol di (2-bromo-2-methylpropionate) (BDBIB, total initiator dissolved in 26 ml of propyl acetate) was added. After 2 minutes, uniform addition of the amount of initiator 2 (see Table 1, dissolved in 20 ml of ethyl acetate) to 1,4-butanediol-di- (2-bromo-2-methylpropionate) (BDBIB) is begun. The dosage runs without interruption and with a constant dosage rate over the period ti.
- BDBIB 1,4-butanediol-di- (2-bromo-2-methylpropionate
- the polymerization solution is stirred for a period t 2 at the polymerization temperature before removing a sample for determining the average molecular weight M n (by SEC) and adding methyl methacrylate (exact amount in Table 1).
- the mixture is stirred for a further two hours at 75 0 C and then stopped by addition of 2.0 g of mercaptoethanol.
- the solution is worked up by filtration through silica gel and subsequent removal of volatiles by distillation. The average molecular weight is finally determined by SEC measurements.
- Example 3 The polymerization is carried out analogously to Example 1 with the addition of the amounts indicated in Table 2 while maintaining the times stated there. Termination of the reaction takes place with the addition of 2.3 g of thioglycolic acid.
- Example 3 The polymerization is carried out analogously to Example 1 with the addition of the amounts indicated in Table 2 while maintaining the times stated there. Termination of the reaction takes place with the addition of 2.3 g of thioglycolic acid.
- the polymerization is carried out analogously to Example 1 with the addition of the amounts indicated in Table 2 while maintaining the times stated there.
- the reaction is stopped with the addition of 4.9 g of Dynasylan MTMO.
- the molecular weight distributions of the first polymerization stages are each monomodal and have a molecular index D greater than 1.8.
- the end products have correspondingly large, although in comparison to the pure B blocks smaller molecularity indices. This effect results from the overall higher molecular weight, but also shows that the polymerization of the A blocks takes place in a controlled manner and the blocks themselves have a narrow molecular weight distribution.
- the increase in molecular index is due to partial dimerization of the polymer chains at the end groups.
- a transfer of the process to polymers without block structure can be done easily.
- the Mercaptanzugabe takes place directly after completion of the polymerization time t 2 instead of the addition of the monomer mixture A.
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- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
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Abstract
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JP2011535945A JP6099309B2 (ja) | 2008-11-12 | 2009-10-06 | 幅広い分子量分布を有するテレケリックポリマーの製造方法 |
CN200980144402.6A CN102209737B (zh) | 2008-11-12 | 2009-10-06 | 具有宽分子量分布的遥爪聚合物的制备方法 |
EP09736884A EP2350151B1 (de) | 2008-11-12 | 2009-10-06 | Verfahren zur herstellung von telechelen mit einer breiten molekulkargewichtsverteilung |
ES09736884T ES2401688T3 (es) | 2008-11-12 | 2009-10-06 | Método para la fabricación de polímeros telequélicos con una distribución amplia del peso molecular |
US13/127,533 US20110269913A1 (en) | 2008-11-12 | 2009-10-06 | Method for producing telechelics having a wide molecular weight distribution |
AU2009315875A AU2009315875A1 (en) | 2008-11-12 | 2009-10-06 | Method for producing telechelics having a wide molecular weight distribution |
BRPI0921732A BRPI0921732A2 (pt) | 2008-11-12 | 2009-10-06 | processo para a preparação de "telechelen" com ampla distribuição de peso molecular |
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DE102008043662A DE102008043662A1 (de) | 2008-11-12 | 2008-11-12 | Verfahren zur Herstellung von Telechelen mit breiter Molekulargewichtsverteilung |
DE102008043662.3 | 2008-11-12 |
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US (1) | US20110269913A1 (de) |
EP (1) | EP2350151B1 (de) |
JP (1) | JP6099309B2 (de) |
CN (1) | CN102209737B (de) |
AU (1) | AU2009315875A1 (de) |
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US9587062B2 (en) | 2014-12-15 | 2017-03-07 | Henkel IP & Holding GmbH and Henkel AG & Co. KGaA | Photocrosslinkable block copolymers for hot-melt adhesives |
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DE102008043669A1 (de) * | 2008-11-12 | 2010-05-20 | Evonik Röhm Gmbh | Verfahren zur Herstellung von ABA-Triblockcopolymeren mit einem breit verteilten B-Block |
CN103068866A (zh) * | 2010-08-03 | 2013-04-24 | 国际壳牌研究有限公司 | 制备聚合物多元醇的方法 |
CN113265018B (zh) * | 2021-06-04 | 2022-03-29 | 大连理工大学 | 一种基于锁定-解锁机理的聚合物分子量分布调控方法 |
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WO1999020659A1 (en) | 1997-10-23 | 1999-04-29 | The B.F. Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
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DE69829063T2 (de) | 1997-09-22 | 2006-03-23 | Kaneka Corp. | Polymer, verfahren zu dessen herstellung und härtbare zusammensetzung, die dieses polymer enthält |
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DE69939959D1 (de) | 1998-09-02 | 2009-01-02 | Kaneka Corp | Polymer, Verfahren zu seiner Herstellung und Zusammensetzung |
AU2003211925A1 (en) | 2002-02-13 | 2003-09-04 | Kaneka Corporation | Block copolymer |
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2008
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- 2009-10-06 WO PCT/EP2009/062931 patent/WO2010054896A1/de active Application Filing
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WO1999020659A1 (en) | 1997-10-23 | 1999-04-29 | The B.F. Goodrich Company | End-functionalized polymers by controlled free-radical polymerization process and polymers made therefrom |
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US9587062B2 (en) | 2014-12-15 | 2017-03-07 | Henkel IP & Holding GmbH and Henkel AG & Co. KGaA | Photocrosslinkable block copolymers for hot-melt adhesives |
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Publication number | Publication date |
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CN102209737B (zh) | 2013-05-29 |
ES2401688T3 (es) | 2013-04-23 |
BRPI0921732A2 (pt) | 2016-01-05 |
EP2350151A1 (de) | 2011-08-03 |
DE102008043662A1 (de) | 2010-05-20 |
EP2350151B1 (de) | 2013-02-27 |
JP2012508311A (ja) | 2012-04-05 |
US20110269913A1 (en) | 2011-11-03 |
AU2009315875A1 (en) | 2010-05-20 |
JP6099309B2 (ja) | 2017-03-22 |
CN102209737A (zh) | 2011-10-05 |
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