WO2010041817A2 - Waste tire recycling system - Google Patents
Waste tire recycling system Download PDFInfo
- Publication number
- WO2010041817A2 WO2010041817A2 PCT/KR2009/004839 KR2009004839W WO2010041817A2 WO 2010041817 A2 WO2010041817 A2 WO 2010041817A2 KR 2009004839 W KR2009004839 W KR 2009004839W WO 2010041817 A2 WO2010041817 A2 WO 2010041817A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carrier gas
- gas circulation
- circulation line
- recycling system
- waste tire
- Prior art date
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- 239000010920 waste tyre Substances 0.000 title claims abstract description 62
- 238000004064 recycling Methods 0.000 title claims abstract description 38
- 239000012159 carrier gas Substances 0.000 claims abstract description 170
- 238000000197 pyrolysis Methods 0.000 claims abstract description 51
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 31
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims abstract description 28
- 238000010438 heat treatment Methods 0.000 claims abstract description 26
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 16
- 239000001273 butane Substances 0.000 claims abstract description 11
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims abstract description 11
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract description 10
- 239000001294 propane Substances 0.000 claims abstract description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000007789 gas Substances 0.000 claims description 84
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 40
- 239000001301 oxygen Substances 0.000 claims description 40
- 229910052760 oxygen Inorganic materials 0.000 claims description 40
- 238000005979 thermal decomposition reaction Methods 0.000 claims description 13
- 238000000354 decomposition reaction Methods 0.000 claims description 6
- 238000004227 thermal cracking Methods 0.000 claims description 4
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 239000002912 waste gas Substances 0.000 claims 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 30
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 25
- 229910052799 carbon Inorganic materials 0.000 description 25
- 239000001569 carbon dioxide Substances 0.000 description 15
- 229910002092 carbon dioxide Inorganic materials 0.000 description 15
- 238000002485 combustion reaction Methods 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- 229930195733 hydrocarbon Natural products 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- QRSFFHRCBYCWBS-UHFFFAOYSA-N [O].[O] Chemical compound [O].[O] QRSFFHRCBYCWBS-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- -1 artificial reefs Substances 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- TXKMVPPZCYKFAC-UHFFFAOYSA-N disulfur monoxide Inorganic materials O=S=S TXKMVPPZCYKFAC-UHFFFAOYSA-N 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000004071 soot Substances 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 1
- 229910052815 sulfur oxide Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/02—Separating plastics from other materials
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B49/00—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated
- C10B49/02—Destructive distillation of solid carbonaceous materials by direct heating with heat-carrying agents including the partial combustion of the solid material to be treated with hot gases or vapours, e.g. hot gases obtained by partial combustion of the charge
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/07—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form of solid raw materials consisting of synthetic polymeric materials, e.g. tyres
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/10—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal from rubber or rubber waste
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B17/00—Recovery of plastics or other constituents of waste material containing plastics
- B29B17/04—Disintegrating plastics, e.g. by milling
- B29B2017/0424—Specific disintegrating techniques; devices therefor
- B29B2017/0496—Pyrolysing the materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1003—Waste materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/143—Feedstock the feedstock being recycled material, e.g. plastics
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/62—Plastics recycling; Rubber recycling
Definitions
- the present invention relates to a waste tire recycling system in which waste tires, which are industrial wastes, are thermally decomposed by a heating method using a carrier gas to separate and extract and recycle various energy sources.
- the present invention relates to a waste tire recycling system for supplying gas carrier gas to improve the convenience of operation.
- the waste tire is mainly a synthetic polymer compound, and the calorific value is about 34 MJ / kg, which is higher than the reference calorific value of coal of 29 MJ / kg.
- the average composition of tire pieces is 43.5 wt% of SBR polymer (styrene-butadiene copolymer), 32.6 wt% of carbon black, 21.7 wt% of oil, 2.2 wt% of additives such as sulfur and zinc oxide, except for fabrics such as iron core and nylon. %to be.
- waste tires in addition to combustion is being studied, and recycling products such as sidewalk blocks, recycled tires, recycled rubber, artificial reefs, and buffers for various structures are being commercialized, but their application scope is limited. Waste and pollution occur in the molding process for the products, as well as environmental pollution caused by the waste when these products are disposed of.
- a method for fuelization is being attempted without recycling the waste tires, and a thermal cracking furnace for thermally decomposing waste tires is used for fueling the waste tires, and according to the heating method of the thermal cracking furnace directly It is divided into heating type and indirect heating type.
- the direct heating pyrolysis furnace has a risk of explosion due to chemical reaction with the flame generated when heat is applied to the waste tire and oxygen contained in the air in the heating furnace.
- the free carbon is contained, there is a problem that the quality of the extracted oil is degraded.
- the indirect heating type has no risk of explosion compared to the direct heating type described above, but because of the low thermal efficiency, most of the oil obtained as a by-product must be used as a fuel. There was a difficulty.
- the applicant's application for waste tire recycling system includes: thermal decomposition means for thermally decomposing the injected waste tire in a pyrolysis furnace by direct heating using carbon dioxide (CO 2) or nitrogen (N 2) as a carrier gas; Carbon treatment means for pulverizing the decomposition residue separated by thermal decomposition in the pyrolysis furnace to separate carbon and iron core; Oil collecting means for separating the oil component by cooling and condensing the exhaust gas separated by thermal decomposition in the pyrolysis furnace; Carbon treatment means for producing high-pressure steam using high-temperature exhaust gas generated by incineration of the carbon separated by the carbon treatment means, and then operating steam turbines and absorption chillers to produce electricity and cold water; The exhaust gas treatment means used for cleaning the exhaust gas discharged by the carbon treatment means to discharge the pollution-free gas, and the exhaust gas treatment means for separating and recovering a part of CO2 or N2.
- the waste tire recycling system having such a configuration enables the extraction of high purity oil containing no water and free carbon while preventing the decomposition of the pyrolysis furnace by using a pyrolysis furnace of a direct heating method using a carrier gas.
- the pre-applied waste tire recycling system thermally decomposes by direct heating, but uses additional carbon dioxide (CO2) or nitrogen (N2) as a carrier gas.
- CO2 carbon dioxide
- N2 nitrogen
- this not only adds to the cost of initial capital investment, but also increases the cost of these carbon dioxide (CO2) or nitrogen (N2)
- the carrier gas consisting of carbon dioxide (CO2) or nitrogen (N2)
- the applicant of the present application is included in the oxygen by the air (oxygen) is introduced when the waste tire is introduced into the pyrolysis furnace during the initial operation of the system.
- oxygen oxygen
- the oxygen requires a process of continuously supplying the carrier gas to exhaust the oxygen. Since the oxygen exhaust process consumes a considerable amount of carrier gas over a long period of time, the economic efficiency is greatly reduced, and the time required for the normal operation of the system is long, resulting in a poor operation efficiency.
- the waste tire recycling system which is filed by the applicant, is a thermal decomposition furnace which circulates the used waste tires as a carrier gas and decomposes them by a direct heating method, and an oil that collects oil by cooling and condensing high-temperature steam generated in the thermal decomposition furnace.
- a thermal decomposition furnace which circulates the used waste tires as a carrier gas and decomposes them by a direct heating method, and an oil that collects oil by cooling and condensing high-temperature steam generated in the thermal decomposition furnace.
- a carrier gas circulation line circulated back to the pyrolysis furnace via the pyrolysis furnace and the oil collecting means, and connected to the carrier gas circulation line, the temperature in the pyrolysis furnace and the pressure in the carrier gas circulation line. It comprises a sensing element for measuring the, and collects and stores the non-condensable gas generated in the pyrolysis furnace, and selectively supply it to the pyrolysis furnace side to use as a carrier gas circulation supply device .
- the conventional waste tire recycling system configured as described above can be economically operated because it does not require the supply of a separate carrier gas by utilizing the non-condensable gas generated in the combustion process of the waste tire as a carrier gas.
- an object of the present invention is to provide a carrier gas of various components from the outside to ensure the convenience of the initial operation of the system, and also to use a carrier gas during use of the non-condensable gas generated during the combustion of waste tires as a carrier gas. If the gas supply is unstable, it is possible to provide an alternative supply to provide a waste tire recycling system that can increase the operating reliability of the system.
- a thermal decomposition furnace which circulates the used waste tires as a carrier gas and decomposes them by a direct heating method, and oil collecting means for capturing oil by cooling and condensing high-temperature steam generated in the thermal decomposition furnace and thermal decomposition
- a waste tire recycling system comprising a carrier gas circulation line circulated back to a pyrolysis furnace via a furnace and an oil collecting means, the carrier tire recycling line being connected to one end of the carrier gas circulation line and selectively supplying carrier gas by valve control.
- a carrier gas supply device having a charging element filled with a carrier gas obtained by mixing at least one or more components of methane, ethane, propane, butane, pentane, hexane, and ammonia series. do.
- An oxygen detector for detecting oxygen present in the carrier gas circulation line; It is connected to the oxygen detector is selectively operated by receiving the sensing information is installed on the carrier gas circulation line is configured to include an oxygen combustor for burning and removing the oxygen present in the carrier gas circulation line.
- the non-condensable gas generated in the pyrolysis furnace includes a sensing element that is connected to the carrier gas circulation line and measures a temperature in the pyrolysis furnace and a pressure in the carrier gas circulation line. It is to be configured to further include a carrier gas circulation supply device for collecting and storing, optionally supplying it to the pyrolysis furnace side to use as a carrier gas.
- the carrier gas circulation supply device is connected to the carrier gas supply device and is selectively piped to receive the carrier gas and supply the carrier gas circulation line.
- the carrier gas circulation supply device includes a pressure measuring device for measuring an internal pressure of the carrier gas circulation line as a sensing element and a temperature measuring device for measuring a temperature in the pyrolysis furnace.
- the carrier gas circulation supply device is connected to the carrier gas circulation line, a non-condensable gas storage tank for selectively receiving and storing a non-condensable gas, the non-condensable gas storage tank and the An intermittent valve installed in a conduit connecting the carrier gas circulation line to selectively supply the non-condensable gas in the carrier gas circulation line to the non-condensable gas storage tank or vice versa to supply the stored non-condensable gas to the carrier gas circulation line It is to be configured.
- the carrier gas circulation supply device is non-condensing in the carrier gas circulation line when the pressure in the carrier gas circulation line is 100 mmAq or more and the decomposition temperature in the thermal cracking furnace is 200 ° C. or more. Storage of stored gas in a non-condensable gas storage tank.
- the carrier gas circulation line is provided with an oxygen combustor having a heating wire that generates heat selectively by a power supply to combust oxygen contained in the gas.
- FIG. 1 is a schematic diagram showing a schematic configuration of a waste tire recycling system according to the prior art
- FIG. 2 is a schematic diagram showing a schematic configuration of a waste tire recycling system according to the present invention.
- FIG. 3 is a schematic diagram showing another embodiment of FIG.
- FIG. 4 is a block diagram showing the waste tire recycling system of FIG.
- carrier gas circulation supply device 50 carrier gas supply device
- FIG. 2 is a schematic diagram showing a schematic configuration of a waste tire recycling system according to the present invention.
- Reference numeral 1 denotes a pyrolysis furnace 1, which is an element that thermally decomposes by direct heating using a gas such as carbon dioxide (CO2) or nitrogen (N2) as a carrier gas, and such a pyrolysis furnace (1) is the upper one side.
- An inlet for injecting waste tires is provided at one side thereof, and at one side thereof, an outlet for circulating high-temperature steam generated by pyrolysis and an air outlet for discharging air during initial operation are provided, and at the lower portion, pyrolyzed decomposition residues are discharged.
- a discharge port is provided.
- Reference numeral 2 is a crusher provided under the discharge port of the pyrolysis furnace 1 to pulverize pyrolysis residues
- 3 is a chain conveyor separating pulverized carbon and iron core
- 4 is the chain.
- Reference numeral 6 denotes a condenser for cooling and condensing high temperature steam discharged through the outlet of the pyrolysis furnace 1
- reference numeral 7 denotes an oil tank for collecting oil separated in the course of cooling condensation.
- 8) is a cyclone that collects oil components that move like gas together with the carrier gas without being collected during the cooling condensation process.
- reference numeral 9 denotes a tertiary separation tank for recovering (capturing) the oil mist not collected in the cyclone 8 by directly contacting the liquid oil in aeration manner.
- Reference numeral 10 denotes a carbon incinerator in which carbon stored in the carbon storage tank 4 is transported and incinerated by self-heating, and reference numeral 11 receives the high temperature exhaust gas generated in the carbon incinerator 10 and cools it.
- Secondary heat exchanger for making a high pressure steam, and 13 is a steam turbine for producing electricity using high pressure steam.
- Reference numeral 14 is a refrigerator for supplying low pressure steam (about 5 Kg / cm2) discharged from the steam turbine 13 to produce cold water and condensation, and reference numeral 15 denotes the secondary heat exchanger by pumping condensed water. It refers to a high pressure pump circulated to (12).
- Reference numeral 16 denotes a washing tower for washing exhaust gas discharged from the secondary heat exchanger 12
- reference numeral 18 denotes a blower.
- Figure 3 is a schematic diagram showing another embodiment of Figure 2
- Figure 4 is a block diagram showing the waste tire recycling system of Figure 3, as shown therein, this embodiment is the embodiment of FIG.
- Carrier gas circulation supply device 20 is installed to collect the non-condensable gas that is naturally generated during the combustion process of the waste tire and to circulate and supply it to the carrier gas.
- the carrier gas circulation supply device 20 improves the economics and the yield of the extracted oil by using the gas component naturally generated in the combustion process of the waste tire as the carrier gas.
- the pyrolysis furnace 1 is an element for thermally decomposing waste tires by direct heating using non-condensable gas through a carrier gas circulation supply device 20 which will be described later, and using it as a carrier gas.
- An outlet for discharging pyrolyzed residues is provided, and an outlet for discharging high-temperature steam due to thermal decomposition.
- the air inside thereof is discharged to the outside by the injection of a carrier gas, and the non-condensable gas generated in the combustion process of the waste tire is circulated by opening the circulation outlet in a state where the air discharge is completed.
- the circulation path of the non-condensable gas corresponds to (cl) in the figure.
- the heating steam generated in the combustion process of the waste tire introduced into the pyrolysis furnace 1 is blower 18 and the primary heat exchange via the condenser 6, the cyclone 8 and the tertiary separation tank 9. It is circulated to the pyrolysis furnace 1 via the group 11.
- the pyrolysis residue treatment means consists of a pair of rollers in which a pulverizer (2) for pulverizing the residue put between them and a chain conveyor (3) and a chain conveyor (3) for separating the pulverized carbon and iron cores during conveyor movement. It consists of a carbon storage path 4 and an iron core storage path 5 for storing the separated carbon and iron core, respectively.
- the oil collecting means is an element that separates and extracts oil from the high-temperature steam generated in the pyrolysis furnace 1, and is primarily separated by the condenser 6 for cooling and condensing the high-temperature steam and the cooling condensation of the condenser 6.
- Oil tank (7) storing the stored oil and the cyclone (8) and the cyclone (8) which collects the secondary gaseous components of the gaseous state in a strong vortex and transfers them to the oil tank (7). It consists of a tertiary separation tank 9 which collects and collects the oil powder by directly contacting the liquid oil in an aerated manner.
- the carbon treatment means incinerates the carbon supplied from the carbon storage tank 4 to produce a high temperature exhaust gas, a carbon incinerator 10 and a first and second heat exchangers 11 and 12 that heat the exhaust gas at a high temperature, and a second heat exchanger.
- Steam turbine 13 for generating electricity by receiving the high pressure steam produced in the machine and the absorption type refrigeration unit 14 for generating condensate by receiving steam of low pressure and high pressure pump circulating the condensate to the secondary heat exchanger 12 ( 15).
- the carrier gas circulation supply device 20 is connected to the carrier gas circulation line cl.
- the carrier gas circulation line cl refers to a path circulated back to the pyrolysis furnace 1 via the pyrolysis furnace 1 and the oil collecting means.
- the carrier gas circulation supply device 20 installed in the carrier gas circulation line cl has a sensing element for measuring the temperature in the pyrolysis furnace 1 and the pressure in the carrier gas circulation line cl. The non-condensable gas produced in the pyrolysis furnace 1 is collected and stored, and then it is selectively circulated and supplied to the pyrolysis furnace 1 side.
- the carrier gas circulation supply device 20 is a sensing element, a pressure gauge 21 for measuring the internal pressure of the carrier gas circulation line (cl), and a temperature for measuring the temperature in the thermal decomposition furnace (1)
- the measuring device 23 is configured to include the pressure measuring device 21 and the temperature measuring device 23 may be implemented by a known mechanical or electronic sensor, and thus a detailed description thereof will be omitted.
- the carrier gas circulation supply device 20 is connected to the carrier gas circulation line (cl) and the non-condensable gas storage tank 27 for selectively receiving and storing the non-condensable gas and the non-condensable gas storage tank 27 ) Is installed in a conduit connecting the carrier gas circulation line (cl) to selectively supply and store the non-condensable gas to the non-condensable gas storage tank 27 or the non-condensed gas stored in the non-condensable gas storage tank 27 It is configured to include an intermittent valve (25, 29) that can be supplied to the pyrolysis furnace (1) by transferring the layering gas to the carrier gas circulation line (cl).
- the pressure measuring device (21) installed in the carrier gas circulation line (cl) to measure the internal pressure of the temperature measuring device 23 for measuring the temperature in the thermal decomposition furnace (1) while the set value is 100mmAq or more.
- Is measured at a set value of 200 ° C. or higher it is determined that the non-condensable gas is generated in the pyrolysis furnace 1, and the intermittent valve 25 of FIG. 3 is opened in the intermittent valves 25 and 29.
- the carrier gas circulation line cl and the non-condensable gas storage tank 27 are connected to each other, and a compressor (unsigned) of one side thereof is operated to draw the non-condensable gas flowing inside the carrier gas circulation line cl.
- the non-condensable gas storage tank (27) It can be supplied and stored in the non-condensable gas storage tank (27).
- the control valve corresponding to the reference sign 25 is turned off, and the control valve corresponding to the reference sign 29 is opened to open the non-condensable gas.
- the non-condensable gas stored in the storage tank 27 is transferred to the carrier gas circulation line cl to be supplied to the pyrolysis furnace 1.
- Such a configuration is similar to the configuration of the applicant's previous application waste tire recycling system.
- the present invention provides a carrier gas circulation line comprising a carrier gas composed of a gas obtained by mixing at least one or more components of methane, ethane, propane, butane, pentane, hexane, and ammonia series at the initial startup of the system, as shown in FIG.
- a carrier gas circulation line comprising a carrier gas composed of a gas obtained by mixing at least one or more components of methane, ethane, propane, butane, pentane, hexane, and ammonia series at the initial startup of the system, as shown in FIG.
- the carrier gas supply device 50 for supplying to (cl) is constituted or when the non-condensable gas is stably produced in a system using non-condensable gas as the carrier gas as shown in FIGS.
- the technical feature is to provide a carrier gas supply device 50 used as an auxiliary supply source of carrier gas.
- the carrier gas supply device 50 of the present invention is connected to the carrier gas circulation line (cl) through which the carrier gas is circulated and the carrier gas tank 51 filled with the carrier gas therein, and the carrier gas circulation line (cl) is connected to the oxygen detector 52 and the oxygen detector 52 for detecting the oxygen present in the sensing information, and based on the applied sensing information selectively in the carrier gas circulation line (cl) It consists of the oxygen combustor 30 removed by combustion.
- the carrier gas supply device 50 is connected to the carrier gas circulation line (cl) directly as shown in Figure 2 is applied to a system for supplying a carrier gas, or in Figures 3 and 4 As shown, it can be applied to a system equipped with a carrier gas supply device 50 for circulating and using the non-condensable gas generated during the combustion of waste tires as carrier gas.
- the carrier gas circulation supply device 20 and the carrier gas circulation line may be configured to be interrupted by a valve interruption. Since the configuration by the valve control can be carried out in various ways by known techniques, detailed description thereof will be omitted.
- the carrier gas circulation is performed.
- the carrier gas tank 51 is filled with a gas obtained by mixing at least one or more components of methane, ethane, propane, butane, pentane, hexane and ammonia series.
- the carrier gas tank 51 may be configured to inject gas of methane, ethane, propane, butane, pentane, hexane, ammonia series from the outside, or may be configured to replace the tank itself, and the carrier gas circulation line ( It is preferred to be piped so that it can be easily separated or connected from cl).
- Oxygen detector 52 is installed in the carrier gas circulation line (cl) to measure the concentration of oxygen contained in the flowing carrier gas, oxygen oxygen in the carrier gas is detected by detecting the oxygen combustor 30 to be described later Apply sensing information with.
- the oxygen detector 52 may be installed at equal intervals in the carrier gas circulation line cl to increase the reliability of detection.
- the oxygen combustor 30 is installed in the carrier gas circulation line cl to remove oxygen in the carrier gas by combustion.
- the oxygen combustor 30 receives oxygen sensing information from the oxygen detector 52, the oxygen combustor 30 is provided with a heating wire that generates heat by receiving power from the outside, and burns oxygen in the carrier gas using the heating wire.
- the oxygen combustor 30 in the present invention has been described an example having a heating wire as an embodiment, but not limited to the heating wire is a structural that can burn the oxygen in the carrier gas circulation line (cl) by combustion If it has a feature, it may be modified by various known techniques.
- Hydrocarbon gas consisting of methane, ethane, propane, butane, pentane and hexane series has a larger heat capacity than nitrogen or carbon dioxide, so when the same amount of gas is sent through a blower, the hydrocarbon gas (methane, ethane, propane, butane, pentane) Hexane-based) can transfer more heat. Therefore, it is possible to decompose waste tires in the pyrolysis furnace more quickly, so that more waste tires can be treated than using nitrogen or carbon dioxide in the same capacity of the pyrolysis furnace.
- Table 1 shows the transfer heat of hydrocarbon gas (methane, ethane, propane, butane, pentane, hexane series), nitrogen gas and carbon dioxide.
- oxygen in the carrier gas circulation line (cl) when the temperature of the waste tire is 250 °C or more, oxygen is first reacted with the rubber of the waste tire to generate free carbon (C) and water to product oil By mixing with, the quality is not only degraded but also the yield is greatly reduced.
- the hydrocarbon gas when used as a carrier gas, oxygen present in the system can be removed by reacting with the hydrocarbon gas in the high temperature primary heat exchanger before the temperature of the waste tire rises to 250 ° C.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Processing Of Solid Wastes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Tires In General (AREA)
Abstract
Description
Claims (8)
- 투입된 폐타이어를 캐리어가스로 순환 사용하고 직접 가열 방식에 의해 분해시키는 열 분해로 및 이 열 분해로에서 발생되는 고열의 증기를 냉각 응축시켜 오일을 포집하는 오일 포집수단 그리고 열 분해로와 오일 포집수단을 경유하여 다시 열 분해로로 순환되는 캐리어가스 순환라인을 포함하는 폐타이어 재활용 시스템에 있어서,Pyrolysis furnace that uses recycled spent tire as carrier gas and decomposes by direct heating method, and oil collecting means for collecting oil by cooling and condensing high-temperature steam generated from this pyrolysis furnace, and pyrolysis furnace and oil collecting means In the waste tire recycling system comprising a carrier gas circulation line circulated back to the pyrolysis furnace via상기 캐리어가스 순환라인(cl)의 일단에 연결되어 밸브(53) 단속에 의해 선택적으로 캐리어가스를 공급하는 것으로 메탄·에탄·프로판·부탄·펜탄·헥산·암모니아 계열의 성분을 적어도 하나 또는 하나 이상 혼합하여 된 캐리어가스를 충전한 충전요소를 구비한 캐리어가스 공급장치(50)를 더 포함하여 구성되는 것을 특징으로 하는 폐타이어 재활용 시스템.At least one or more components of methane, ethane, propane, butane, pentane, hexane, and ammonia-based components are selectively connected to one end of the carrier gas circulation line (cl) to supply the carrier gas by the control of the valve 53. A waste tire recycling system, characterized in that it further comprises a carrier gas supply device (50) having a filling element filled with the carrier gas mixed.
- 제 1항에 있어서, 상기 캐리어가스 공급장치(50)는,The method of claim 1, wherein the carrier gas supply device 50,상기 캐리어가스 순환라인(cl)과 배관으로 연결되고 내부에 캐리어가스가 충전된 캐리어가스 탱크(51)와;A carrier gas tank 51 connected to the carrier gas circulation line cl and filled with a carrier gas therein;상기 캐리어가스 순환라인(cl)에 존재하는 산소를 검출하는 산소 검출기(52)와;An oxygen detector (52) for detecting oxygen present in the carrier gas circulation line (cl);상기 산소 검출기(52)에 연결되어 감지정보를 인가 받아 선택적으로 작동되는 것으로 상기 캐리어가스 순환라인(cl) 상에 설치되어 캐리어가스 순환라인(cl)내에 존재하는 산소를 연소시켜 제거하는 산소 연소기(30);An oxygen combustor connected to the oxygen detector 52 and selectively operated by receiving sensing information and installed on the carrier gas circulation line cl to burn and remove oxygen existing in the carrier gas circulation line cl; 30);를 포함하여 구성되는 것을 특징으로 하는 폐타이어 재활용 시스템.Waste tire recycling system, characterized in that comprises a.
- 제 1항에 있어서, 상기 캐리어가스 순환라인(cl)에 연결 설치되는 것으로 상기 열 분해로(1) 내의 온도와 캐리어가스 순환라인(cl) 내의 압력을 측정하는 감지요소를 구비하고, 상기 열 분해로(1)에서 생성된 비응축성 가스를 포집하여 저장하고, 이를 선택적으로 열 분해로(1)측으로 공급하여 캐리어가스로 사용하도록 하는 캐리어가스 순환 공급장치(20)를 더 포함하여 구성되는 것을 특징으로 하는 폐타이어 재활용 시스템.According to claim 1, It is connected to the carrier gas circulation line (cl) is provided with a sensing element for measuring the temperature in the thermal decomposition furnace (1) and the pressure in the carrier gas circulation line (cl), the thermal decomposition And a carrier gas circulation supply device 20 for collecting and storing the non-condensable gas generated in the furnace 1 and selectively supplying the non-condensable gas to the pyrolysis furnace 1 to be used as a carrier gas. Waste tire recycling system.
- 제 3항에 있어서, 상기 캐리어가스 순환 공급장치(20)는 상기 캐리어가스 공급장치(50)와 연결되어 선택적으로 캐리어가스를 공급받아 캐리어가스 순환라인(cl)으로 공급하도록 배관되는 것을 특징으로 하는 폐타이어 재활용 시스템.According to claim 3, The carrier gas circulation supply device 20 is connected to the carrier gas supply device 50 is selectively piped to receive the carrier gas to supply to the carrier gas circulation line (cl) Waste tire recycling system.
- 제 3항에 있어서, 상기 캐리어가스 순환 공급장치(20)는 감지요소로 상기 캐리어가스 순환라인(cl)의 내부 압력을 측정하는 압력측정기(21) 및 상기 열 분해로(1)내의 온도를 측정하는 온도측정기(23)를 구비하는 것을 특징으로 하는 폐타이어 재활용 시스템.4. The carrier gas circulation supply device 20 according to claim 3, wherein the carrier gas circulation supply device 20 measures a temperature in the pyrolysis furnace 1 and a pressure gauge 21 for measuring the internal pressure of the carrier gas circulation line cl as a sensing element. Waste tire recycling system characterized in that it comprises a temperature measuring instrument (23).
- 제 3항에 있어서, 상기 캐리어가스 순환 공급장치(20)는,According to claim 3, The carrier gas circulation supply device 20,상기 캐리어가스 순환라인(cl)에 연결되어 선택적으로 비응축성 가스를 공급받아 저장하는 비응축성 가스 저장탱크(27)와;A non-condensable gas storage tank 27 connected to the carrier gas circulation line cl to selectively receive and store a non-condensable gas;상기 비응축성 가스 저장탱크(27)와 상기 캐리어가스 순환라인(cl)을 연결하는 관로에 설치되어 선택적으로 상기 캐리어가스 순환라인(cl)내의 비응축성 가스를 비응축성 가스 저장탱크(27)로 공급하거나 또는 반대로 저장된 비응축성 가스를 캐리어가스 순환라인(cl)으로 공급하기 위한 단속밸브(25,29);Installed in a conduit connecting the non-condensable gas storage tank 27 and the carrier gas circulation line cl to selectively supply non-condensable gas in the carrier gas circulation line cl to the non-condensable gas storage tank 27. Intermittent valves 25 and 29 for supplying the stored non-condensable gas to the carrier gas circulation line cl;를 포함하여 구성되는 것을 특징으로 하는 폐타이어 재활용 시스템.Waste tire recycling system, characterized in that comprises a.
- 제 3항에 있어서, 상기 캐리어가스 순환 공급장치(20)는, According to claim 3, The carrier gas circulation supply device 20,상기 캐리어가스 순환라인(cl)내의 압력이 100mmAq 이상이고, 상기 열 분해로(1)내의 분해 온도가 200℃ 이상인 경우 상기 캐리어가스 순환라인(cl)내에 유동중인 비응축성 가스를 비응축성 가스 저장탱크(27)에 저장하는 것을 특징으로 하는 폐타이어 재활용 시스템.When the pressure in the carrier gas circulation line (cl) is 100mmAq or more and the decomposition temperature in the thermal cracking furnace (1) is 200 ° C or more, the non-condensable gas flowing in the carrier gas circulation line (cl) is a non-condensable gas storage tank. The waste tire recycling system characterized by the above-mentioned.
- 제 1항에 있어서, 상기 캐리어가스 순환라인(cl)에는 가스에 포함된 산소를 연소시키도록 전원공급에 의해 선택적으로 발열을 하는 전열선을 구비한 산소 연소기(30)가 설치되는 것을 특징으로 하는 폐타이어 재활용 시스템.The waste gas according to claim 1, wherein the carrier gas circulation line (cl) is provided with an oxygen combustor (30) having a heating wire that generates heat selectively by a power supply to burn oxygen contained in the gas. Tire recycling system.
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/123,404 US20110303525A1 (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system |
MX2011003771A MX2011003771A (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system. |
CA 2739816 CA2739816C (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system |
CN2009801402381A CN102176982A (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system |
BRPI0914058-1A BRPI0914058A2 (en) | 2008-10-08 | 2009-08-28 | system for recycling tire waste |
JP2011530927A JP2012505286A (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system |
IL212145A IL212145A0 (en) | 2008-10-08 | 2011-04-05 | Waste tire recycling system |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR20080098653A KR100937214B1 (en) | 2008-10-08 | 2008-10-08 | Waste tire recycling system |
KR10-2008-0098653 | 2008-10-08 |
Publications (2)
Publication Number | Publication Date |
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WO2010041817A2 true WO2010041817A2 (en) | 2010-04-15 |
WO2010041817A3 WO2010041817A3 (en) | 2010-06-17 |
Family
ID=41809898
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/KR2009/004839 WO2010041817A2 (en) | 2008-10-08 | 2009-08-28 | Waste tire recycling system |
Country Status (11)
Country | Link |
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US (1) | US20110303525A1 (en) |
JP (1) | JP2012505286A (en) |
KR (1) | KR100937214B1 (en) |
CN (1) | CN102176982A (en) |
BR (1) | BRPI0914058A2 (en) |
CA (1) | CA2739816C (en) |
CL (1) | CL2011000745A1 (en) |
IL (1) | IL212145A0 (en) |
MX (1) | MX2011003771A (en) |
PE (1) | PE20120096A1 (en) |
WO (1) | WO2010041817A2 (en) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
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KR101026859B1 (en) * | 2008-12-01 | 2011-04-06 | 전영민 | Waste tire recycling system |
CZ306376B6 (en) * | 2014-07-15 | 2016-12-28 | Alpajar Group S.R.O. | Process for continuously preparing liquid and gaseous fuels form fraction of organic substances in wastes |
KR101857012B1 (en) * | 2017-03-27 | 2018-05-14 | 곽재경 | Continuous waste plastic emulsification system using gas circulation |
CN108829156B (en) * | 2018-06-08 | 2021-02-23 | 国宏中晶集团有限公司 | Mixed carrier gas control device and method for waste tire cracking |
EP3858950A1 (en) * | 2020-01-31 | 2021-08-04 | Danmarks Tekniske Universitet | A pyrolysis system, a method for producing purified pyrolysis gas and pyrolysis liquids and use of a pyrolysis system |
JP7050258B1 (en) * | 2021-11-30 | 2022-04-08 | 株式会社ナフサ | Waste recycling system |
CN114540067B (en) * | 2022-01-12 | 2023-12-26 | 青岛科技大学 | System for improving yield of organic compound pyrolysis liquid-phase product and working method thereof |
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DE2658371C2 (en) * | 1976-12-23 | 1983-03-03 | Carl Robert Eckelmann AG, 2000 Hamburg | Process for pyrolyzing old tires |
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DE3442506A1 (en) * | 1984-11-22 | 1986-05-22 | Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln | METHOD FOR PROCESSING CARBON-CONTAINING WASTE AND BIOMASS |
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-
2008
- 2008-10-08 KR KR20080098653A patent/KR100937214B1/en not_active IP Right Cessation
-
2009
- 2009-08-28 WO PCT/KR2009/004839 patent/WO2010041817A2/en active Application Filing
- 2009-08-28 BR BRPI0914058-1A patent/BRPI0914058A2/en not_active IP Right Cessation
- 2009-08-28 MX MX2011003771A patent/MX2011003771A/en not_active Application Discontinuation
- 2009-08-28 US US13/123,404 patent/US20110303525A1/en not_active Abandoned
- 2009-08-28 PE PE2011000859A patent/PE20120096A1/en not_active Application Discontinuation
- 2009-08-28 CA CA 2739816 patent/CA2739816C/en not_active Expired - Fee Related
- 2009-08-28 JP JP2011530927A patent/JP2012505286A/en active Pending
- 2009-08-28 CN CN2009801402381A patent/CN102176982A/en active Pending
-
2011
- 2011-04-04 CL CL2011000745A patent/CL2011000745A1/en unknown
- 2011-04-05 IL IL212145A patent/IL212145A0/en unknown
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JPH06200256A (en) * | 1992-10-06 | 1994-07-19 | Formex Trading Gmbh | Method and equipment for processing ground organic waste |
KR100561802B1 (en) * | 1998-08-21 | 2006-03-21 | 벵트-스투레 에르스하그 | Method for recovery of carbon and combinations of hydrocarbons from disposed tyres or similar polymeric material, by pyrolysis in a pyrolysis reactor |
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Also Published As
Publication number | Publication date |
---|---|
CA2739816A1 (en) | 2010-04-15 |
KR100937214B1 (en) | 2010-01-20 |
JP2012505286A (en) | 2012-03-01 |
MX2011003771A (en) | 2011-08-15 |
IL212145A0 (en) | 2011-06-30 |
BRPI0914058A2 (en) | 2018-06-26 |
CN102176982A (en) | 2011-09-07 |
PE20120096A1 (en) | 2012-03-14 |
CL2011000745A1 (en) | 2011-11-18 |
WO2010041817A3 (en) | 2010-06-17 |
CA2739816C (en) | 2014-05-13 |
US20110303525A1 (en) | 2011-12-15 |
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