WO2010038943A3 - Resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier - Google Patents

Resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier Download PDF

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Publication number
WO2010038943A3
WO2010038943A3 PCT/KR2009/004615 KR2009004615W WO2010038943A3 WO 2010038943 A3 WO2010038943 A3 WO 2010038943A3 KR 2009004615 W KR2009004615 W KR 2009004615W WO 2010038943 A3 WO2010038943 A3 WO 2010038943A3
Authority
WO
WIPO (PCT)
Prior art keywords
resin composition
compounds
present
electrodeposition paint
cation electrodeposition
Prior art date
Application number
PCT/KR2009/004615
Other languages
French (fr)
Korean (ko)
Other versions
WO2010038943A2 (en
Inventor
김재효
오일석
김광선
정하택
송윤석
Original Assignee
주식회사 케이씨씨
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 주식회사 케이씨씨 filed Critical 주식회사 케이씨씨
Priority to TR2011/03855T priority Critical patent/TR201103855T1/en
Priority to CN2009801412862A priority patent/CN102186934B/en
Publication of WO2010038943A2 publication Critical patent/WO2010038943A2/en
Publication of WO2010038943A3 publication Critical patent/WO2010038943A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443Polyepoxides
    • C09D5/4453Polyepoxides characterised by the nature of the curing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/182Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing using pre-adducts of epoxy compounds with curing agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/4419Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications with polymers obtained otherwise than by polymerisation reactions only involving carbon-to-carbon unsaturated bonds
    • C09D5/443Polyepoxides
    • C09D5/4434Polyepoxides characterised by the nature of the epoxy binder
    • C09D5/4438Binder based on epoxy/amine adducts, i.e. reaction products of polyepoxides with compounds containing amino groups only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/44Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications
    • C09D5/448Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for electrophoretic applications characterised by the additives used

Abstract

The present invention relates to a resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier, and to a use thereof. More particularly, the present invention relates to a resin composition for cation electrodeposition paint, comprising (1) a base resin containing reaction products of polysulfide compounds and epoxy compounds and reaction products of amine compounds and epoxy compounds; (2) a curing agent resin containing reaction products of modified polyol compounds derived from analogous-Mannich reaction products of phenol compounds, aliphatic or aromatic amine compounds and formalin, and blocked polyisocyanate compounds; (3) aromatic sulfonic acid; and (4) a rheology modifier having an urethane function group. The resin composition of the present invention is specially suitable as a primer for vehicle and industrial use as the resin composition of the present invention is excellent in water-dispersion stability, inner permeability, and anti-bacterial property, exhibits superior flexibility, anti-corrosion property, and coating property of the film of paint, and exhibits improved anti-corrosion property at the edge of the film of paint. The present invention also relates to a cation electrodeposition paint comprising the resin composition.
PCT/KR2009/004615 2008-09-30 2009-08-19 Resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier WO2010038943A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
TR2011/03855T TR201103855T1 (en) 2008-09-30 2009-08-19 Resin composition for cation electric coating paint with superior internal permeability including aromatic sulfonic acid and urethane functional rheology modifier.
CN2009801412862A CN102186934B (en) 2008-09-30 2009-08-19 Resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1020080096062A KR101005297B1 (en) 2008-09-30 2008-09-30 Resin composition for cathodic electrodeposition coating with good throw power comprising aromatic sulfonic acid and urethane-fuctional rheology control agent
KR10-2008-0096062 2008-09-30

Publications (2)

Publication Number Publication Date
WO2010038943A2 WO2010038943A2 (en) 2010-04-08
WO2010038943A3 true WO2010038943A3 (en) 2010-07-01

Family

ID=42073984

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2009/004615 WO2010038943A2 (en) 2008-09-30 2009-08-19 Resin composition for cation electrodeposition paint with excellent inner permeability, containing aromatic sulfonic acid and urethane functional rheology modifier

Country Status (5)

Country Link
KR (1) KR101005297B1 (en)
CN (1) CN102186934B (en)
RU (1) RU2467043C1 (en)
TR (1) TR201103855T1 (en)
WO (1) WO2010038943A2 (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101029660B1 (en) 2011-01-25 2011-04-15 (주)새론테크 Polyurea paint composition having excellent workability and superior toughness and method using the same
KR101863369B1 (en) * 2011-12-30 2018-06-01 주식회사 케이씨씨 Paint composition having polysilazane modified epoxy for chemical tank
US9068089B2 (en) * 2013-03-15 2015-06-30 Ppg Industries Ohio, Inc. Phenolic admix for electrodepositable coating composition containing a cyclic guanidine
JP6402199B2 (en) * 2013-12-20 2018-10-10 ビーエイエスエフ・コーティングス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBASF Coatings GmbH Aqueous primary dispersion, process for its production and use thereof
JP6419212B2 (en) * 2013-12-20 2018-11-07 ビーエイエスエフ・コーティングス・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツングBASF Coatings GmbH Aqueous primary dispersion, process for its production and use thereof
KR102341535B1 (en) * 2017-03-10 2021-12-22 주식회사 케이씨씨 Coating composition for cationic electrodeposition
KR102042239B1 (en) * 2017-08-08 2019-11-08 주식회사 케이씨씨 Cationic urethane curing agent and electro-deposition paint composition comprising the same

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000355795A (en) * 1999-06-15 2000-12-26 Aisin Seiki Co Ltd Surface treatment of aluminum and aluminum alloy
JP2002356646A (en) * 2001-05-31 2002-12-13 Nippon Paint Co Ltd Lead-less cationic-electrodeposition paint composition containing crosslinked resin particle
US20040026248A1 (en) * 2002-03-26 2004-02-12 Satoru Uchidoi Electrodeposition coating method using lead-free cationic electrodeposition coating composition
KR20040091647A (en) * 2002-02-20 2004-10-28 이 아이 듀폰 디 네모아 앤드 캄파니 Amine Acid Zwitterion Additive for a Cathodic Electrocoating Composition
KR20050013623A (en) * 2002-06-27 2005-02-04 피피지 인더스트리즈 오하이오 인코포레이티드 Electrodepositable dielectric coating compositions to coat a substrate and methods to form dielectric coating
KR100831205B1 (en) * 2006-12-31 2008-05-21 주식회사 케이씨씨 A cathodic electrodeposition coating compositions having improved appearance, anti-corrosion resistance and flexibility

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8918086D0 (en) * 1989-08-08 1989-09-20 Ciba Geigy Coating compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000355795A (en) * 1999-06-15 2000-12-26 Aisin Seiki Co Ltd Surface treatment of aluminum and aluminum alloy
JP2002356646A (en) * 2001-05-31 2002-12-13 Nippon Paint Co Ltd Lead-less cationic-electrodeposition paint composition containing crosslinked resin particle
KR20040091647A (en) * 2002-02-20 2004-10-28 이 아이 듀폰 디 네모아 앤드 캄파니 Amine Acid Zwitterion Additive for a Cathodic Electrocoating Composition
US20040026248A1 (en) * 2002-03-26 2004-02-12 Satoru Uchidoi Electrodeposition coating method using lead-free cationic electrodeposition coating composition
KR20050013623A (en) * 2002-06-27 2005-02-04 피피지 인더스트리즈 오하이오 인코포레이티드 Electrodepositable dielectric coating compositions to coat a substrate and methods to form dielectric coating
KR100831205B1 (en) * 2006-12-31 2008-05-21 주식회사 케이씨씨 A cathodic electrodeposition coating compositions having improved appearance, anti-corrosion resistance and flexibility

Also Published As

Publication number Publication date
WO2010038943A2 (en) 2010-04-08
KR101005297B1 (en) 2011-01-04
TR201103855T1 (en) 2011-10-21
KR20100036708A (en) 2010-04-08
CN102186934A (en) 2011-09-14
CN102186934B (en) 2013-09-11
RU2467043C1 (en) 2012-11-20

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