WO2010006163A1 - Deinking a cellulosic substrate using magnesium hydroxine - Google Patents

Deinking a cellulosic substrate using magnesium hydroxine Download PDF

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Publication number
WO2010006163A1
WO2010006163A1 PCT/US2009/050095 US2009050095W WO2010006163A1 WO 2010006163 A1 WO2010006163 A1 WO 2010006163A1 US 2009050095 W US2009050095 W US 2009050095W WO 2010006163 A1 WO2010006163 A1 WO 2010006163A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
optionally
magnesium hydroxide
emulsifier
fatty acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/050095
Other languages
English (en)
French (fr)
Inventor
Prasad Y. Duggirala
Michael J. Murcia
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ChampionX LLC
Original Assignee
Nalco Co LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nalco Co LLC filed Critical Nalco Co LLC
Priority to CA2728650A priority Critical patent/CA2728650C/en
Priority to KR1020117000517A priority patent/KR101678698B1/ko
Priority to JP2011517620A priority patent/JP5520294B2/ja
Priority to MX2011000288A priority patent/MX2011000288A/es
Priority to CN2009801260018A priority patent/CN102084057A/zh
Priority to EP20090790219 priority patent/EP2315870A1/en
Publication of WO2010006163A1 publication Critical patent/WO2010006163A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C3/00—Pulping cellulose-containing materials
    • D21C3/02—Pulping cellulose-containing materials with inorganic bases or alkaline reacting compounds, e.g. sulfate processes
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02—Working-up waste paper
    • D21C5/025—De-inking
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00—Technologies for solid waste management
    • Y02W30/50—Reuse, recycling or recovery technologies
    • Y02W30/64—Paper recycling

Definitions

  • the invention pertains to compositions and methods for deinking a cellulosic substrate.
  • Efficiently removing ink from secondary fiber without impacting fiber quality is one of the major challenges in paper recycling.
  • the most widespread method of removing ink from secondary fiber is an alkaline process that uses sodium hydroxide, sodium silicate, hydrogen peroxide, surfactants and chelants.
  • the caustic is used to elevate the pH in the repulper causing the fiber to swell, which assists in ink detachment, but also yellows the fiber due to interaction with lignin in mechanical grades, resulting in a brightness loss.
  • Peroxide is added to reduce fiber yellowing, and chelant is added to prevent peroxide degradation by metals.
  • Surfactants are used to manage the detached ink and prevent redeposition onto the fiber.
  • the present invention provides for a composition comprising: (a) activated magnesium hydroxide; (b) optionally a suspending agent for said activated magnesium hydroxide; (c) water; (d) optionally an emulsifier; (e) optionally excluding caustic soda; and (f) optionally excluding hydrogen peroxide.
  • the present invention also provides for a composition comprising: (a) magnesium hydroxide; (b) a suspending agent for said magnesium hydroxide; (c) water; (d) optionally an emulsifier; (e) optionally excluding caustic soda; and (f) optionally excluding hydrogen peroxide.
  • the present invention also provides for a method of removing ink from a cellulosic containing substance comprising: (a) adding to the substance a composition comprising: (1) activated magnesium hydroxide, (2) water, (3) optionally a suspending agent for said activated magnesium hydroxide, and (4) optionally an emulsifier; (b) optionally excluding adding caustic soda to the cellulosic containing substance; and (c) optionally excluding adding hydrogen peroxide to the cellulosic containing substance.
  • the present invention further provides for a method of removing ink from a cellulosic containing substance comprising: (a) adding to the substance a composition comprising: (1) magnesium hydroxide, (2) a suspending agent for said magnesium hydroxide, (3) water, and (4) optionally an emulsifier; (b) optionally excluding adding caustic soda to the cellulosic containing substance; and (c) optionally excluding adding hydrogen peroxide to the cellulosic containing substance.
  • Figure 1 shows residual ink data after the application of an activated magnesium hydroxide and emulsified TOFA formulation to fiber.
  • Figure 2 shows ISO brightness after the application of an activated magnesium hydroxide and emulsified TOFA formulation to fiber.
  • Figure 3 shows sheet yellowness after the application of an activated magnesium hydroxide and emulsified TOFA formulation to fiber.
  • Figure 4 shows fiber whiteness after the application of an activated magnesium hydroxide and emulsified TOFA formulation to fiber.
  • Suspending agent means one or more agents that prevents precipitation of a stabilized dispersion of colloidal particles in solution.
  • Activated magnesium hydroxide means a formulation that includes magnesium hydroxide plus one or more components that provides additional deinking performance over the magnesium hydroxide alone, e.g. oil added as formulation with magnesium hydroxide. For example, if the magnesium hydroxide is mixed with an oil and that oil meets the requirements of providing additional deinking performance, then the magnesium hydroxide is an activated magnesium hydroxide.
  • Recycling process means any process that involves the handling of secondary fibers.
  • TOFA tall oil fatty acid
  • % means percent by weight of the composition.
  • the present invention provides for a composition comprising: (a) activated magnesium hydroxide; (b) optionally a suspending agent for said activated magnesium hydroxide; (c) water; (d) optionally an emulsifier; (e) optionally excluding adding caustic soda; and (f) optionally excluding hydrogen peroxide.
  • the present invention also provides for a composition comprising: (a) magnesium hydroxide; (b) a suspending agent for said magnesium hydroxide; (c) water; (d) optionally an emulsifier; (e) optionally excluding caustic soda; and (f) optionally excluding hydrogen peroxide .
  • the suspending agent is a thickening agent
  • the thickening agent is selected from the group consisting of: galactomannans; guar gum; locust bean gum; xanthan gum; para gum; cellulosics; hydroxypropyl methylcellulose; hydroxypropyl cellulose; carrageean; alginates; sodium alginates; potassium alginates; ammonium salt alginates; and a combination thereof.
  • the composition contains from about 5% to about 70% of said activated magnesium hydroxide/magnesium hydroxide, based upon weight of the composition.
  • the composition contains about 47% of said activated magnesium hydroxide/magnesium hydroxide, based upon weight of the composition. In another embodiment, the composition contains from about 0.05% to about 20% of said suspending agent, based upon weight of the composition.
  • the composition contains about 0.4% of said suspending agent, based upon weight of the composition.
  • the composition comprises an oil. In another embodiment, the composition contains from about 2% to about 55% of said oil based upon the weight of the composition.
  • the composition contains about 30% of said oil based upon the weight of the composition.
  • the oil contains a fatty acid. In another embodiment, the oil is used to form an oil and water emulsion. In another embodiment, the composition contains from about 0.5% to about 20% of said emulsifier.
  • composition contains about 3% of said emulsifier.
  • emulsifier is a surfactant
  • the fatty acid contains a tall oil fatty acid.
  • the emulsifier is selected from the group consisting of: sorbitol derivatives; polysorbate 80; sorbitan monolaurate; polysorbate 20; ethoxylated alcohols; sodium laureth sulfate; polyethylene glycol; sulfate esters; sodium lauryl sulfate; and a combination thereof.
  • the composition comprises: (a) activated magnesium hydroxide/magnesium hydroxide; (b) xanthan gum; (c) tall oil fatty acid; (d) sodium lauryl sulfate; and (e) water.
  • the composition is comprised of about 47% of said activated magnesium hydroxide/magnesium hydroxide; about 0.395% xanthan gum; about 30% tall oil fatty acid; and about 3% sodium lauryl sulfate.
  • the composition excludes caustic soda, optionally comprising rosin wherein the content of rosin in the composition is from greater than 0% to about 30% based upon weight of the fatty acid.
  • caustic soda optionally comprising rosin wherein the content of rosin in the composition is from greater than 0% to about 30% based upon weight of the fatty acid.
  • the present invention provides for a method of removing ink from a cellulosic containing substance comprising: (a) adding to the substance a composition comprising: (1) activated magnesium hydroxide, (2) water, (3) optionally a suspending agent for said activated magnesium hydroxide, and (4) optionally an emulsifier; (b) optionally excluding adding caustic soda to the cellulosic containing substance; and (c) optionally excluding adding hydrogen peroxide to the cellulosic containing substance.
  • the present invention also provides for a method of removing ink from a cellulosic containing substance comprising: (a) adding to the substance a composition comprising: (1) magnesium hydroxide, (2) a suspending agent for said magnesium hydroxide, (3) water, and (4) optionally an emulsifier; (b) optionally excluding adding caustic soda to the cellulosic containing substance; and (c) optionally excluding adding hydrogen peroxide to the cellulosic containing substance.
  • the performance of a deinking process can be measured in a variety of ways. Typically, optical properties such as brightness (B), whiteness (L), red/green color balance (a) and yellow/blue color balance (b*) are measured on a sheet formed from the resulting deinked fiber.
  • Residual ink can be expressed in terms of specks/unit area, percent coverage of ink specks on an area, or effective residual ink concentration (ERIC), which is commonly expressed in ppm.
  • ERIC effective residual ink concentration
  • the cellulosic substance is located anywhere in a recycling process up through one or more flotation accepts.
  • the emulsifier is added separately to the cellulosic containing substance.
  • the suspending agent is a thickening agent.
  • the thickening agent is selected from the group consisting of: galactomannans; guar gum; locust bean gum; xanthan gum; para gum; cellulosics; hydroxypropyl methylcellulose; hydroxypropyl cellulose; carrageean; alginates; sodium alginates; potassium alginates; ammonium salt alginates; and a combination thereof,
  • the composition contains from about 5% to about 70% of said activated magnesium hydroxide/magnesium hydroxide, based upon weight of the composition.
  • the composition contains about 47% of said activated magnesium hydroxide/magnesium hydroxide, based upon weight of the composition.
  • the composition contains from 0.05% to about 20% of said suspending agent, based upon weight of the composition.
  • the composition contains about 0.4% of said suspending agent, based upon weight of the composition.
  • the composition further comprises: an oil.
  • the composition contains from about 2% to about 55% of said oil based upon the weight of the composition.
  • the composition contains about 30% of said oil based upon the weight of the composition. In another embodiment, the composition contains from about 0.5% to about 20% of said emulsifier.
  • the composition contains about 3% of said emulsifier.
  • the oil contains a fatty acid.
  • the oil is used to form an oil and water emulsion.
  • the emulsifier is a surfactant.
  • the fatty acid contains a tall oil fatty acid.
  • the emulsifier is selected from the group consisting of: sorbitol derivatives; polysorbate 80; sorbitan monolaurate; polysorbate 20; ethoxylated alcohols; sodium laureth sulfate; polyethylene glycol; sulfate esters; sodium lauryl sulfate; and a combination thereof.
  • the composition excludes caustic soda.
  • the composition further comprises rosin, optionally wherein the content of rosin in the composition is from greater than 0% to about 30% based upon weight of the fatty acid.
  • the method of removing ink from a cellulosic containing substance comprises: (a) adding to the substance a composition comprising: (1) activated magnesium hydroxide/magnesium hydroxide, (2) xanthan gum, (3) tall oil fatty acid, (4) sodium lauryl sulfate, and (5) water; (b) optionally excluding the addition of caustic soda to the cellulosic containing substance; and (c) optionally excluding the addition of hydrogen peroxide to the cellulosic containing substance.
  • the composition is comprised of about 47% of said activated magnesium hydroxide/magnesium hydroxide; about 0.395% xanthan gum; about 30% tall oil fatty acid; and about 3% sodium lauryl sulfate.
  • the methodologies of the present invention can be applied to a paper recycling process, when deinking is desired.
  • the composition is added to a paper recycling process in at least one of the following locations: a pulper; dilution stage; flotation cell thickening stage; and a kneader.
  • the composition is added in a pulper of a paper recycling process. In another embodiment, the composition is added at a dilution stage of a paper recycling process.
  • the composition is added at a thickening stage of a paper recycling process.
  • the composition is added in a flotation cell of a paper recycling process.
  • the composition is added in a kneader of a paper recycling process.
  • the substance contains one or more paper fibers.
  • the paper fibers are secondary fibers in a paper recycling process.
  • the following examples are not meant to be limiting.
  • a formulation for the removal of ink from secondary fiber using under reduced alkalinity conditions can best be realized by thickening a sample of deionized (“DI") water with xanthan gum at 2.0% by weight with gentle stirring. Adding a 50/50 mixture of polysorbate 80 and polysorbate 20 at 2.5% by weight for the combined surfactant to the xanthan gum enables the emulsification of tall oil fatty acid at 5.15% by weight with mixing of the solution. While mixing, magnesium hydroxide particles with 1 micron particle size were added to the emulsion at a concentration of 5.15% by weight. To achieve a stable formulation while maintaining a fluid viscosity capable of being pumped, the overall solids in the formulation were in the range of 15%, but can be increased to higher solids percentages.
  • DI deionized
  • xanthan gum was added to 20 ml of DI water with gentle stirring to assist in dissolving the powder.
  • 0.25g of polysorbate 20 and 0.25g of polysorbate 80 were added to the xanthan gum solution.
  • 1.2g of TOFA was added and emulsified with gentle stirring, along with 1.2g of magnesium hydroxide, resulting in a stable emulsified slurry of activated magnesium hydroxide and TOFA.
  • the prepared sample was suitable to remove ink from 12Og of secondary fiber.
  • the deinking treatment can then be added to secondary fiber in the repulping process at a high consistency of fiber and an elevated temperature ( ⁇ 35-60°C) where the sheets were disintegrated into fiber.
  • peroxide was added to the pulper upon the addition of the disclosed formulation.
  • hydrogen peroxide was added to the pulper in caustic deinking at a ratio of 0.6: 1 caustic to hydrogen peroxide.
  • the replacement ratio is 1.0:0.73 NaOH:Mg(OH) 2
  • hydrogen peroxide was added at a ratio of 2.28:1.0 hydrogen peroxide to activated magnesium hydroxide.
  • the disintegrated secondary fiber was diluted and placed into a floation cell where detached ink was separated from the fiber using an agitator and air bubbles passing from the bottom to the top of the cell, collecting dislodged ink particles. This creates a froth that carries the ink and was removed from the top of the floatation cell. Typical floatation temperatures range from 35-6O 0 C.
  • the deinked fiber was collected and residual ink and optical measurements are made. Measurement Methods: For this study, optical properties of deinked fiber were measured using a Technidyne Colortouch 2 on handsheets prepared according to TAPPI method T218. In the interest of reducing effects of sample preparation, ink speck counts were performed using a PAPRICAN Ink Scanner by Op-Test on the same sheets used for optical characterization.
  • the ISO brightness was measured on handsheets made from deinked fiber.
  • the data shows that the disclosed deinking formulation is capable of outperforming the conventional caustic deinking treatment in brightness gain.
  • the sheet yellowness as measured on handsheets prepared from deinked fiber, is slightly higher for the disclosed formulation, but is not too high to overshadow the benefits of the formulation has for ink removal and the other optical properties.
  • the fiber whiteness was measured on fiber deinked with the experimental formulations. Similar to the trend observed in the brightness measurements, the proposed invention outperforms the conventional caustic deinking treatment.

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Paper (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Food Preservation Except Freezing, Refrigeration, And Drying (AREA)
PCT/US2009/050095 2008-07-09 2009-07-09 Deinking a cellulosic substrate using magnesium hydroxine Ceased WO2010006163A1 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA2728650A CA2728650C (en) 2008-07-09 2009-07-09 Deinking a cellulosic substrate using magnesium hydroxide
KR1020117000517A KR101678698B1 (ko) 2008-07-09 2009-07-09 수산화마그네슘을 이용한 셀룰로오스성 기재의 잉크 제거 방법
JP2011517620A JP5520294B2 (ja) 2008-07-09 2009-07-09 水酸化マグネシウムを用いるセルロース性基材の脱インクのための組成物及び方法
MX2011000288A MX2011000288A (es) 2008-07-09 2009-07-09 Destintado de un sustrato celulosico utilizando hidroxido de magnesio.
CN2009801260018A CN102084057A (zh) 2008-07-09 2009-07-09 使用氢氧化镁将纤维质基质脱墨
EP20090790219 EP2315870A1 (en) 2008-07-09 2009-07-09 Deinking a cellulosic substrate using magnesium hydroxine

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US12/169,900 2008-07-09
US12/169,900 US8133351B2 (en) 2008-07-09 2008-07-09 Deinking a cellulosic substrate using magnesium hydroxide

Publications (1)

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WO2010006163A1 true WO2010006163A1 (en) 2010-01-14

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PCT/US2009/050095 Ceased WO2010006163A1 (en) 2008-07-09 2009-07-09 Deinking a cellulosic substrate using magnesium hydroxine

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US (3) US8133351B2 (https=)
EP (1) EP2315870A1 (https=)
JP (1) JP5520294B2 (https=)
KR (1) KR101678698B1 (https=)
CN (1) CN102084057A (https=)
AR (1) AR072493A1 (https=)
CA (1) CA2728650C (https=)
CO (1) CO6341493A2 (https=)
MX (1) MX2011000288A (https=)
TW (1) TWI486500B (https=)
WO (1) WO2010006163A1 (https=)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106283796A (zh) * 2016-08-22 2017-01-04 湖北宝塔沛博循环科技有限公司 废报纸生产牛皮纸的生产方法
US12247348B2 (en) * 2021-03-04 2025-03-11 Södra Skogsägarna Ekonomisk Förening Method for decoloring of a textile material

Families Citing this family (7)

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Publication number Priority date Publication date Assignee Title
US8133351B2 (en) * 2008-07-09 2012-03-13 Nalco Company Deinking a cellulosic substrate using magnesium hydroxide
US8088250B2 (en) 2008-11-26 2012-01-03 Nalco Company Method of increasing filler content in papermaking
US9752283B2 (en) 2007-09-12 2017-09-05 Ecolab Usa Inc. Anionic preflocculation of fillers used in papermaking
WO2016065422A1 (en) * 2014-10-31 2016-05-06 Ixom Operations Pty Ltd Method of treatment
CN105735025A (zh) * 2014-12-11 2016-07-06 广东轻工职业技术学院 一种使用镁碱的废纸脱墨浆过氧化氢漂白方法
JP7035533B2 (ja) * 2017-12-28 2022-03-15 セイコーエプソン株式会社 処理装置、シート製造装置および処理方法
FR3095819B1 (fr) * 2019-05-10 2021-06-18 Inst De Rech Tech Jules Verne Procédé de fabrication d’une fibre de carbone à partir d’un produit en papier

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Publication number Priority date Publication date Assignee Title
CN106283796A (zh) * 2016-08-22 2017-01-04 湖北宝塔沛博循环科技有限公司 废报纸生产牛皮纸的生产方法
US12247348B2 (en) * 2021-03-04 2025-03-11 Södra Skogsägarna Ekonomisk Förening Method for decoloring of a textile material

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JP2011527733A (ja) 2011-11-04
AR072493A1 (es) 2010-09-01
CA2728650A1 (en) 2010-01-14
US8317974B2 (en) 2012-11-27
US8133351B2 (en) 2012-03-13
MX2011000288A (es) 2011-03-02
CO6341493A2 (es) 2011-11-21
TWI486500B (zh) 2015-06-01
CN102084057A (zh) 2011-06-01
CA2728650C (en) 2016-02-16
US8466204B2 (en) 2013-06-18
KR101678698B1 (ko) 2016-11-22
US20120135907A1 (en) 2012-05-31
US20100006243A1 (en) 2010-01-14
US20120135908A1 (en) 2012-05-31
KR20110027774A (ko) 2011-03-16
JP5520294B2 (ja) 2014-06-11
TW201013013A (en) 2010-04-01
EP2315870A1 (en) 2011-05-04

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