WO2010004163A2 - Suspension colloidale generatrice d'hydrogene - Google Patents
Suspension colloidale generatrice d'hydrogene Download PDFInfo
- Publication number
- WO2010004163A2 WO2010004163A2 PCT/FR2009/051200 FR2009051200W WO2010004163A2 WO 2010004163 A2 WO2010004163 A2 WO 2010004163A2 FR 2009051200 W FR2009051200 W FR 2009051200W WO 2010004163 A2 WO2010004163 A2 WO 2010004163A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- hydrogen
- colloidal suspension
- alkali metal
- aqueous solution
- metal particles
- Prior art date
Links
- 239000000725 suspension Substances 0.000 title claims abstract description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 54
- 239000001257 hydrogen Substances 0.000 claims abstract description 51
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 51
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 22
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 22
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 16
- 239000003085 diluting agent Substances 0.000 claims abstract description 13
- 239000002923 metal particle Substances 0.000 claims abstract description 11
- 230000007935 neutral effect Effects 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 9
- 239000000203 mixture Substances 0.000 claims description 22
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000004519 manufacturing process Methods 0.000 claims description 13
- 239000007864 aqueous solution Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000000446 fuel Substances 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 239000000839 emulsion Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 3
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 3
- 230000001804 emulsifying effect Effects 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 239000012024 dehydrating agents Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000002347 injection Methods 0.000 claims description 2
- 239000007924 injection Substances 0.000 claims description 2
- 239000002480 mineral oil Substances 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000003860 storage Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 sorbitan ester Chemical class 0.000 description 2
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000008239 natural water Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 238000010944 pre-mature reactiony Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002123 temporal effect Effects 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
- H01M8/065—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants by dissolution of metals or alloys; by dehydriding metallic substances
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/08—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents with metals
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to the use of a particular composition for producing hydrogen gas.
- the invention also relates to a hydrogen generating device from this composition and to its use for supplying a fuel cell.
- the reduction of hydrocarbon stocks and the pollution problems of cities make it necessary to develop new energies that are more available and less polluting than petroleum products.
- Hydrogen is indeed a fuel vector of clean energy, its combustion with the oxygen of the air releasing a significant energy while producing only water.
- Hydrogen can also be stored in gaseous form. Nevertheless, given the low molar mass of hydrogen, the storage in compressed form can only store a small amount of hydrogen and because of the small size of the hydrogen molecules, leaks appear systematically porosity . The prolonged and secure storage of hydrogen in gaseous form is therefore very limited. It is still known that it is possible to store hydrogen in structures reversibly absorbing it. This storage method, which uses materials with a higher or lower affinity with hydrogen, allows a good storage capacity but still requires the handling of liquid or gaseous hydrogen. In addition, these storage systems in the form of hydride requires the establishment of a heating system to allow the desorption of hydrogen.
- the invention relates to a composition for the production of hydrogen in the form of a colloidal suspension comprising between 2 and 60% of alkali metal particles suspended in a hydrophobic neutral diluent.
- the invention notably covers a process for producing hydrogen from this composition. It also relates to a hydrogen production device comprising this composition and the use of this device for any application requiring hydrogen for example to supply a fuel cell or a combustion engine.
- FIG. 1 represents the diagram of a device for producing hydrogen according to the invention.
- composition for the production of hydrogen according to the invention comprises between 2 and 60% of alkali metal particles suspended in a hydrophobic neutral diluent.
- This proportion of alkali metal particles in the colloidal suspension is particularly suitable for the production of gaseous hydrogen.
- the alkali metal concentration is between 5 and 40%.
- the alkali metal may be chosen in particular from sodium or lithium.
- the suspension according to the invention comprises particles of metallic sodium.
- the alkali metal is in the form of particles of very small dimension, even nanoparticles.
- the particle size is less than 15 .mu.m. Preferably it is between 0.1 and 1 ⁇ m.
- these particles are suspended in a hydrophobic neutral diluent, such as an organic polymer selected from vegetable oils and mineral oils.
- a hydrophobic neutral diluent such as an organic polymer selected from vegetable oils and mineral oils.
- the alkali metal particles are suspended in a silicone oil.
- the composition also comprises a desiccant which makes it possible to tolerate in the suspension the presence of water in a small quantity or trace of atmospheric humidity capable of triggering premature reactions.
- a dehydrating agent is typically a composition comprising suspended inorganic compounds such as silica or phosphorus penta-oxide, or complex organic compounds such as zeolites.
- composition according to the invention can be obtained for example by the implementation of a process comprising the following steps:
- the presence of the hydrophobic diluent allows the suspension to be maintained in the liquid state without any particular precaution under the ambient storage conditions.
- the hydrophobic nature of the diluent protects the composition from accidental point contact with water that would cause unwanted chemical reactions.
- the composition is easily handled slightly viscous and stable at room temperature and pressure. It can thus easily be handled and stored in liquid form at ambient pressure.
- the composition according to the invention is useful for producing hydrogen.
- the water preferably purified and demineralized, progressively reacts with the alkali metal and generates hydrogen gas and an aqueous alkali hydroxide emulsion. for example a solution of sodium hydroxide.
- the reaction that occurs is as follows:
- M being an alkali metal, preferably sodium or lithium.
- the surfactant may be selected from any suitable ionic or anionic surfactant. It may be for example a sorbitan ester, a polyoxyethylene, a polysorbate or a lecithin.
- the content of surfactant is between 0.05 and 10%.
- composition according to the invention can be used in a simple hydrogen generating device in which the reagents can be stored without thermal limitation of low temperature or high pressure.
- FIG. 1 shows a hydrogen generating device 10 comprising in particular:
- the mixing chamber 16 into which the composition 13 and the aqueous solution 15 are introduced and from which hydrogen gas 17 can escape.
- the mixing chamber 16, or reactor may be made of stainless steel resistant to corrosion and heat and have a high-strength ceramic inner wall.
- the composition 13 and the aqueous solution 15 are preferably injected under pressure into the chamber 16 using injection systems, thus avoiding any sealing problem.
- the temporal management of the reaction in the mixing chamber 16 can be provided by self-regulating sensor and nozzle devices that allow mixing.
- the device 10 also comprises a reservoir 18 for recovering the hydrophobic oil and the aqueous alkaline hydroxide emulsion produced after reaction in the chamber 16.
- This reservoir 18 is preferably made of polymeric material or inert composite resistant to chemical attack at high pH.
- the chamber 16 may also include a system for suctioning and grinding the sodium hydroxide crystals generated by the hydrogen production reaction.
- This device is a complete portable system for supplying a fuel cell, which can be used, for example, in an electric vehicle.
- the hydrogen produced in the chamber 16 can be used to supply hydrogen gas to a fuel cell 20 to produce electricity with oxygen.
- the device according to the invention can also be used to supply hydrogen gas with a low or high power heat engine, or a fixed or mobile hydrogen distribution station, supplying hydrogen on demand and having its own autonomy. electric, in an ecological way.
- the invention overcomes the problems of the important storage of hydrogen, technically difficult and dangerous.
- the presentation in liquid form of the composition 13 allows easy handling by means of a simple pumping system for transferring / dosing the liquid.
- the water produced by the cell 20 can be reused in the aqueous solution necessary for the reaction with the alkali metal of the colloidal suspension 13.
- the device according to the invention may also include a heat exchange type heat recovery system, for generating mechanical power by a device of the Sterling motor type or equivalent, or can be directly transformed into electricity by thermocouple devices.
- a heat exchange type heat recovery system for generating mechanical power by a device of the Sterling motor type or equivalent, or can be directly transformed into electricity by thermocouple devices.
- the exothermicity of the reaction between the alkali metal and water can be exploited in embedded systems that use the device 10 to produce, for example, the heating in motor vehicle interiors or the air conditioning by means of a heating system. absorption or reheating of fuel cells whose conversion efficiency is better at higher temperature.
- the hydroxide solution produced by the reaction between the composition according to the invention and the aqueous solution can be recycled to regenerate the colloidal suspension of alkali metal.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Sustainable Development (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Sustainable Energy (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Fuel Cell (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Catalysts (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
Description
Claims
Priority Applications (9)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP09784425A EP2300358A2 (fr) | 2008-06-25 | 2009-06-23 | Suspension colloidale generatrice d'hydrogene |
JP2011515556A JP2011526572A (ja) | 2008-06-25 | 2009-06-23 | 水素を発生するコロイド懸濁液 |
US13/000,956 US20110104048A1 (en) | 2008-06-25 | 2009-06-23 | Hydrogen-generating colloidal suspension |
BRPI0910164A BRPI0910164A2 (pt) | 2008-06-25 | 2009-06-23 | uso de suspensão coloidal, processo de produção de hidrogênio, dispositivo para gerar hidrogênio e uso de dispositivo para gerar hidrogênio |
CN2009801256366A CN102076603A (zh) | 2008-06-25 | 2009-06-23 | 用于氢气发生的胶体悬浮液 |
MX2010014413A MX2010014413A (es) | 2008-06-25 | 2009-06-23 | Suspension coloidal generadora de hidrogeno. |
CA2728317A CA2728317A1 (fr) | 2008-06-25 | 2009-06-23 | Suspension colloidale generatrice d'hydrogene |
AU2009267872A AU2009267872A1 (en) | 2008-06-25 | 2009-06-23 | Hydrogen-generating colloidal suspension |
US13/859,942 US20130236393A1 (en) | 2008-06-25 | 2013-04-10 | Hydrogen-generating colloidal suspension |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0854233A FR2933087B1 (fr) | 2008-06-25 | 2008-06-25 | Suspension colloidale generatrice d'hydrogene. |
FR0854233 | 2008-06-25 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US13/859,942 Continuation-In-Part US20130236393A1 (en) | 2008-06-25 | 2013-04-10 | Hydrogen-generating colloidal suspension |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2010004163A2 true WO2010004163A2 (fr) | 2010-01-14 |
WO2010004163A3 WO2010004163A3 (fr) | 2010-03-11 |
Family
ID=40090067
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/FR2009/051200 WO2010004163A2 (fr) | 2008-06-25 | 2009-06-23 | Suspension colloidale generatrice d'hydrogene |
Country Status (10)
Country | Link |
---|---|
US (1) | US20110104048A1 (fr) |
EP (1) | EP2300358A2 (fr) |
JP (1) | JP2011526572A (fr) |
CN (1) | CN102076603A (fr) |
AU (1) | AU2009267872A1 (fr) |
BR (1) | BRPI0910164A2 (fr) |
CA (1) | CA2728317A1 (fr) |
FR (1) | FR2933087B1 (fr) |
MX (1) | MX2010014413A (fr) |
WO (1) | WO2010004163A2 (fr) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120282166A1 (en) * | 2005-06-14 | 2012-11-08 | Wallace Andrew P | Water reactive hydrogen generation system and method with separation of waste products from water reactive materials |
US20130043125A1 (en) * | 2010-08-12 | 2013-02-21 | Societe Bic | Fuels for Fuel Cells |
ITRM20130385A1 (it) * | 2013-06-28 | 2014-12-29 | Fausto Ubaldi | Procedimento ed apparecchiatura per la produzione di idrogeno |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8951312B2 (en) * | 2011-11-09 | 2015-02-10 | Alvin Gabriel Stern | Compact, safe and portable hydrogen generation apparatus for hydrogen on-demand applications |
FR3016537B1 (fr) * | 2014-01-22 | 2016-02-12 | Commissariat Energie Atomique | Procede de traitement du sodium par une solution de sel aqueux et procede de lavage d'assemblage de combustible de reacteur nucleaire utilisant ledit procede de traitement |
CA3104889A1 (fr) | 2018-07-23 | 2020-01-30 | Nutragenom, Llc | Composition et procedes pour generer et entretenir de l'hydrogene moleculaire (h2) dans des systemes aqueux |
DE102020208863A1 (de) | 2020-07-16 | 2022-01-20 | Volkswagen Aktiengesellschaft | Verfahren zum Betreiben eines mit Wasserstoffgas betreibbaren Antriebsaggregats sowie ein Fortbewegungsmittel mit einem solchen |
CN112693329B (zh) * | 2021-01-07 | 2022-04-08 | 江苏电子信息职业学院 | 一种减轻车用锂离子电池爆炸损毁的保护装置 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB202743A (en) * | 1922-05-26 | 1923-08-27 | Jinshichi Kato | A process for preparing an injection for hemorrhoids |
GB1070851A (en) * | 1963-08-14 | 1967-06-07 | Nat Distillers Chem Corp | Continuous process for sodium dispersions |
US4080179A (en) * | 1975-04-17 | 1978-03-21 | Winston Boyer | Colloidal magnesium suspension in critical low concentration in motor gasoline and method of preparation |
US4080177A (en) * | 1975-04-17 | 1978-03-21 | Winston Boyer | Colloidal magnesium suspension in critical low concentration in jet fuel |
JPS54114473A (en) * | 1978-02-27 | 1979-09-06 | Mitsubishi Atomic Power Ind | Treatment method and apparatus for stabilizing waste sodium |
JPS61126075A (ja) * | 1984-11-22 | 1986-06-13 | Koei Chem Co Ltd | 3−〔3−(1−ピペリジニルメチル)フエノキシ〕プロピルアミンの製造法 |
TWI260344B (en) * | 2001-01-12 | 2006-08-21 | Safe Hydrogen Llc | A method of operating a hydrogen-fueled device |
US6653007B2 (en) * | 2002-02-11 | 2003-11-25 | Mcwhorter Edward Milton | Hydrogen generator for fuel cell operation |
JP2004155599A (ja) * | 2002-11-05 | 2004-06-03 | Kazunari Ikuta | 水素の製造方法及び水素−酸素の製造方法並びにこれらの製造装置 |
JP2004337649A (ja) * | 2003-05-13 | 2004-12-02 | Hitachi Ltd | 有機塩素化合物処理装置 |
-
2008
- 2008-06-25 FR FR0854233A patent/FR2933087B1/fr active Active
-
2009
- 2009-06-23 WO PCT/FR2009/051200 patent/WO2010004163A2/fr active Application Filing
- 2009-06-23 US US13/000,956 patent/US20110104048A1/en not_active Abandoned
- 2009-06-23 BR BRPI0910164A patent/BRPI0910164A2/pt not_active IP Right Cessation
- 2009-06-23 JP JP2011515556A patent/JP2011526572A/ja active Pending
- 2009-06-23 AU AU2009267872A patent/AU2009267872A1/en not_active Abandoned
- 2009-06-23 EP EP09784425A patent/EP2300358A2/fr not_active Withdrawn
- 2009-06-23 CA CA2728317A patent/CA2728317A1/fr not_active Abandoned
- 2009-06-23 MX MX2010014413A patent/MX2010014413A/es not_active Application Discontinuation
- 2009-06-23 CN CN2009801256366A patent/CN102076603A/zh active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120282166A1 (en) * | 2005-06-14 | 2012-11-08 | Wallace Andrew P | Water reactive hydrogen generation system and method with separation of waste products from water reactive materials |
US9156687B2 (en) * | 2005-06-14 | 2015-10-13 | Intelligent Energy Limited | Water reactive hydrogen generation system and method with separation of waste products from water reactive materials |
US20130043125A1 (en) * | 2010-08-12 | 2013-02-21 | Societe Bic | Fuels for Fuel Cells |
ITRM20130385A1 (it) * | 2013-06-28 | 2014-12-29 | Fausto Ubaldi | Procedimento ed apparecchiatura per la produzione di idrogeno |
WO2014207539A1 (fr) | 2013-06-28 | 2014-12-31 | Ubaldi Fausto | Procédé et appareil de production d'hydrogène |
Also Published As
Publication number | Publication date |
---|---|
CN102076603A (zh) | 2011-05-25 |
US20110104048A1 (en) | 2011-05-05 |
EP2300358A2 (fr) | 2011-03-30 |
AU2009267872A1 (en) | 2010-01-14 |
WO2010004163A3 (fr) | 2010-03-11 |
BRPI0910164A2 (pt) | 2016-01-19 |
JP2011526572A (ja) | 2011-10-13 |
MX2010014413A (es) | 2011-06-01 |
CA2728317A1 (fr) | 2010-01-14 |
FR2933087A1 (fr) | 2010-01-01 |
FR2933087B1 (fr) | 2012-01-13 |
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