WO2009157267A1 - Shoe in piston type compressor - Google Patents

Shoe in piston type compressor Download PDF

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Publication number
WO2009157267A1
WO2009157267A1 PCT/JP2009/059645 JP2009059645W WO2009157267A1 WO 2009157267 A1 WO2009157267 A1 WO 2009157267A1 JP 2009059645 W JP2009059645 W JP 2009059645W WO 2009157267 A1 WO2009157267 A1 WO 2009157267A1
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WO
WIPO (PCT)
Prior art keywords
coating layer
shoe
piston
swash plate
plating
Prior art date
Application number
PCT/JP2009/059645
Other languages
French (fr)
Japanese (ja)
Inventor
淳志 斉藤
隆弘 杉岡
崇行 加藤
Original Assignee
株式会社 豊田自動織機
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Application filed by 株式会社 豊田自動織機 filed Critical 株式会社 豊田自動織機
Publication of WO2009157267A1 publication Critical patent/WO2009157267A1/en

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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • F04B27/0873Component parts, e.g. sealings; Manufacturing or assembly thereof
    • F04B27/0878Pistons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • F04B27/0873Component parts, e.g. sealings; Manufacturing or assembly thereof
    • F04B27/0878Pistons
    • F04B27/0886Piston shoes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F04POSITIVE - DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS FOR LIQUIDS OR ELASTIC FLUIDS
    • F04BPOSITIVE-DISPLACEMENT MACHINES FOR LIQUIDS; PUMPS
    • F04B27/00Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders
    • F04B27/08Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis
    • F04B27/10Multi-cylinder pumps specially adapted for elastic fluids and characterised by number or arrangement of cylinders having cylinders coaxial with, or parallel or inclined to, main shaft axis having stationary cylinders
    • F04B27/1036Component parts, details, e.g. sealings, lubrication
    • F04B27/1054Actuating elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2251/00Material properties
    • F05C2251/14Self lubricating materials; Solid lubricants
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F05INDEXING SCHEMES RELATING TO ENGINES OR PUMPS IN VARIOUS SUBCLASSES OF CLASSES F01-F04
    • F05CINDEXING SCHEME RELATING TO MATERIALS, MATERIAL PROPERTIES OR MATERIAL CHARACTERISTICS FOR MACHINES, ENGINES OR PUMPS OTHER THAN NON-POSITIVE-DISPLACEMENT MACHINES OR ENGINES
    • F05C2253/00Other material characteristics; Treatment of material
    • F05C2253/12Coating

Definitions

  • the present invention relates to a shoe in a piston type compressor.
  • a coating layer having excellent slidability may be provided on the surface of the shoe (see, for example, FIG. 5 of Patent Document 2).
  • Ni-P plating nickel-phosphorous plating
  • a coating layer is provided on the concave seating surface of the piston that fits the convex surface of the shoe
  • the concave seating surface of the piston is made of a material different from Ni-P plating.
  • a coating layer for example tin plating, is provided.
  • Ni-P plating is provided on the surface of the shoe and a coating layer is provided on the sliding surface of the swash plate that is in sliding contact with the flat surface portion of the shoe, the Ni-P plating is applied to the sliding surface of the swash plate.
  • a coating layer of a different material for example, a resin layer containing a solid lubricant (such as molybdenum disulfide or graphite) is provided.
  • lubricating oil flowing together with the refrigerant lubricates the sliding contact portion in the compressor. Since the shoe slides with the rotation of the swash plate against the annular sliding surface of the swash plate that goes around the axis of the rotation shaft, the sliding between the sliding surface of the swash plate and the flat surface portion of the shoe. The contact part is easily lubricated by the lubricating oil.
  • the relative movement that occurs between the convex part of the shoe and the concave seating surface of the piston is slight and the speed of the relative movement is slow, so that the lubricating oil hardly enters between the convex part and the concave seating surface. Therefore, the sliding contact portion between the convex surface portion and the concave seat surface is not easily lubricated.
  • the wear powder of the Ni—P plating adheres to the concave seating surface of the piston. Then, the wear powder of the Ni—P plating adhering to the concave seat surface and the Ni—P plating on the convex portion adhere to each other, thereby causing abnormal wear.
  • Patent Documents 1 and 2 disclose using diamond-like carbon (amorphous hard carbon film) as a coating layer provided on the surface of the shoe.
  • Diamond-like carbon is a high-hardness carbon film having excellent slidability even when not sufficiently lubricated.
  • Patent Document 3 discloses that Ni—P plating is provided on the surface of a shoe base material, and diamond-like carbon is provided on the Ni—P plating.
  • the difference between the hardness of the Ni-P plating and the hardness of diamond-like carbon is smaller than the difference between the hardness of the base material of the shoe and the hardness of diamond-like carbon, so the diamond-like carbon is removed from the shoe. It becomes difficult to peel.
  • the diamond-like carbon with high hardness provided on the flat surface portion of the shoe may wear the coating layer on the sliding surface of the swash plate that slides at high speed with respect to the shoe at an early stage.
  • An object of the present invention is to provide a shoe excellent in wear suppression.
  • a shoe provided in a piston compressor including a swash plate and a piston that reciprocates by rotation of the swash plate.
  • the shoe includes a convex surface portion and a flat surface portion.
  • the convex portion fits into a concave seat surface formed on the piston.
  • the flat surface portion faces the sliding surface of the swash plate.
  • the shoe includes a first coating layer and a second coating layer.
  • the first coating layer is formed on the flat surface portion and the convex surface portion.
  • the second coating layer is provided on the first coating layer on the convex surface portion.
  • the second coating layer is formed of diamond-like carbon.
  • the first coating layer on the flat surface portion is the outermost coating layer.
  • FIG. 1 is a side sectional view of a variable capacity piston type compressor provided with a shoe concerning one embodiment which materialized the present invention, and (b) is a partial expanded sectional view of Drawing 1 (a).
  • (A), (b) is a figure which shows the result of the sliding test of the shoes of FIG.
  • the housing of the variable displacement piston compressor 10 is joined to a cylinder block 11, a front housing member 12 joined to the front end of the cylinder block 11, and a rear end of the cylinder block 11.
  • the rear housing member 17 is provided.
  • the front housing member 12 and the cylinder block 11 form a control pressure chamber 121 between them.
  • the front housing member 12 and the cylinder block 11 support the rotating shaft 13 in a rotatable manner.
  • the rotating shaft 13 rotates by obtaining a driving force from an external driving source (for example, a vehicle engine).
  • a rotary support 14 is fixed to the rotary shaft 13, and a swash plate 15 is supported so as to be movable and tiltable in the axial direction of the rotary shaft 13.
  • the base material (metal) of the swash plate 15 is iron-based.
  • the swash plate 15 includes an annular substrate portion 20 and an annular sliding plate portion 21 provided on the radially outer side of the substrate portion 20.
  • the swash plate 15 is movable in the axial direction of the rotary shaft 13 while being tilted by the linkage between the guide hole 141 formed in the rotary support 14 and the guide pin 16 provided in the substrate portion 20 of the swash plate 15. And it can rotate integrally with the rotating shaft 13.
  • the inclination angle of the swash plate 15 changes according to the pressure in the control pressure chamber 121.
  • the maximum inclination angle of the swash plate 15 is defined by the contact between the swash plate 15 and the rotary support 14.
  • the swash plate 15 indicated by a chain line in FIG. 1A is at a position where the minimum inclination angle is obtained.
  • Pistons 18 are accommodated in a plurality of cylinder bores 111 (only two are shown in FIG. 1A) penetrating the cylinder block 11.
  • the piston 18 has a head portion 181 and a neck portion 182, and the head portion 181 fitted in the cylinder bore 111 defines a compression chamber 112 in the cylinder bore 111.
  • the piston 18 is made of an aluminum-based material containing silicon.
  • a recess 19 is formed in the neck 182, and a sliding plate portion 21 of the swash plate 15 is inserted in the recess 19.
  • the sliding plate portion 21 has a first sliding surface 22A and a second sliding surface 22B.
  • the pair of inner wall surfaces 23 and 24 forming the recess 19 face each other and have a concave first spherical seat surface 25A and a second concave seat surface 25B, respectively.
  • the hemispherical first shoe 26A is fitted to the first concave seat surface 25A, and the hemispherical second shoe 26B is fitted to the second concave seat surface 25B.
  • the base material (base metal) of the first shoe 26A and the second shoe 26B is an aluminum-based material containing silicon.
  • the first shoe 26A and the second shoe 26B have a spherical convex surface portion 27 and a planar flat surface portion 28, respectively.
  • the flat surface portion 28 is strictly composed of a plurality of curved surfaces having a large curvature.
  • the convex surface portion 27 of the first shoe 26A can slide on the first concave seat surface 25A, and the convex surface portion 27 of the second shoe 26B can slide on the second concave seat surface 25B.
  • the flat surface portion 28 of the first shoe 26 ⁇ / b> A can be slidably contacted with the first sliding surface 22 ⁇ / b> A of the sliding plate portion 21, and the flat surface portion 28 of the second shoe 26 ⁇ / b> B is the second sliding surface of the sliding plate portion 21. 22B can be slidably contacted.
  • first shoe 26A is disposed between the first sliding surface 22A and the first concave seating surface 25A
  • second shoe 26B is provided between the second sliding surface 22B and the second concave seating surface 25B. It is arranged between.
  • the rotational movement of the swash plate 15 is converted into the reciprocating movement of the piston 18 via the first shoe 26A and the second shoe 26B, and the piston 18 reciprocates in the cylinder bore 111.
  • a coating layer 33A is provided on the flat surface portion 211 of the base material (base metal) of the sliding plate portion 21 of the swash plate 15, and the surface of the coating layer 33A is the first surface.
  • a sliding surface 22A is formed.
  • a coating layer 33B is provided on the flat surface portion 212 of the base material of the sliding plate portion 21, and the surface of the coating layer 33B forms the second sliding surface 22B.
  • the coating layers 33A and 33B are each made of a resin material containing a solid lubricant.
  • the solid lubricant is, for example, molybdenum disulfide or graphite.
  • a coating layer 34 is provided on the entire surface of the base material (metal) of the piston 18.
  • the base material of the piston 18 is an aluminum-based material containing silicon, and the coating layer 34 is tin-plated.
  • the first coating layer 35 is provided on the entire surface of the base material of the first shoe 26A.
  • the first coating layer 35 is nickel-phosphorous plating (hereinafter referred to as Ni-P plating).
  • a second coating layer 36 is provided on the first coating layer 35 on the convex surface portion 27 of the first shoe 26A.
  • the second coating layer 36 is diamond-like carbon (hereinafter referred to as DLC). That is, the outermost coating layer on the convex surface portion 27 of the first shoe 26A is the second coating layer 36, and the outermost coating layer on the flat surface portion 28 of the first shoe 26A is the first coating layer 35. is there.
  • the second shoe 26B is provided with a first coating layer 35 and a second coating layer 36 in the same manner as the first shoe 26A.
  • the first coating layer 35 made of Ni—P plating is formed by electroless plating.
  • the weight% of P (phosphorus) in the first coating layer 35 (Ni—P plating) is 5% by weight or less, and the thickness of the first coating layer 35 is 40 ⁇ m.
  • the second coating layer 36 that is DLC is formed by a vapor deposition method such as a CVD method or a PVD method.
  • the thickness of the second coating layer 36 is 3 ⁇ m.
  • the first coating layer 35 on the flat surface portion 28 of the first shoe 26A comes into sliding contact with the first sliding surface 22A of the swash plate 15, and the second on the convex surface portion 27 of the first shoe 26A.
  • the coating layer 36 and the coating layer 34 on the first concave seat surface 25A of the piston 18 are in sliding contact.
  • the first coating layer 35 on the flat surface portion 28 of the second shoe 26B and the second sliding surface 22B of the swash plate 15 are in sliding contact, and the second coating layer 36 on the convex surface portion 27 of the second shoe 26B and the piston.
  • the coating layer 34 on the 18th second concave seat surface 25B comes into sliding contact.
  • FIG. 2 (a) shows the results of a reciprocating sliding test on the shoes 26A and 26B.
  • the reciprocating sliding test was performed as follows. That is, the predetermined portion of the test member (a member corresponding to a piston) formed of an aluminum-based material containing silicon is fitted to the concave surface of the shoe, and the shoe is pressed against the concave surface. A weight (for example, 10 kg) was connected to the shoe. The entire surface of the test member (member corresponding to the piston) is provided with tin plating. Then, in a non-lubricated state, the shoe was slid against the concave seat surface by reciprocating the weight while pressing the shoe against the concave seat surface.
  • a weight for example, 10 kg
  • FIG. 2 (b) shows the result of the rotational sliding test on the shoes 26A and 26B.
  • the lubricating oil is applied in a state where the flat surface portions of a plurality of shoes (same as the number of pistons 18) are pressed against a coating layer provided on a rotating flat plate made of the same material as the swash plate 15. While spraying, the rotating plate was rotated while pressing the shoe against the coating layer of the rotating plate. At this time, the pressing load of the shoe against the rotating flat plate was gradually increased.
  • the coating layer provided on the rotating flat plate is the same as the coating layers 33A and 33B.
  • the pressing load started from 0.4 kN and increased stepwise by 0.4 kN every 5 minutes. Lubricating oil was sprayed at 25 mg per minute. The number of rotations of the rotating plate was 2000 rpm. The rotary sliding test was performed twice.
  • the seizure occurs when the pressing load is 4.8 kN in the first test. In the second test, seizure occurred when the pressing load reached 4.4 kN.
  • the above embodiment has the following advantages.
  • (1) The second coating layer 36 (DLC) provided on the first coating layer 35 (Ni—P plating) is worn by the first coating layer 35 (Ni—P plating) provided on the convex portion 27. Therefore, abnormal wear of the convex portion 27 and the concave seat surfaces 25A and 25B that are difficult to be lubricated is avoided.
  • the sliding surfaces 22A and 22B of the swash plate 15 are easily worn due to the presence of DLC. The problem is avoided. Further, since an oil film is likely to be formed on the flat surface portion 28, that is, it is easily lubricated, only the first coating layer 35 (Ni-P plating) is provided between the sliding surfaces 22A, 22B and the first coating layer 35. Abnormal wear does not occur as in the prior art.
  • the hardness of the first coating layer 35 (Ni-P plating) interposed between the high hardness second coating layer 36 (DLC) and the base material of the shoes 26A and 26B is lower than the hardness of DLC.
  • the hardness of aluminum containing silicon which is a base material of the shoes 26A and 26B is higher. That is, the 1st coating layer 35 relieves the malfunction resulting from the difference of the hardness of DLC and the hardness of the member coated with this DLC. Therefore, the stress generated in the DLC is relaxed, and the second coating layer 36 is prevented from being peeled off from the shoes 26A and 26B.
  • the second coating layer 36 is provided only on the convex surface portion 27 of the shoes 26A and 26B, when forming the second coating layer 36, the flat surface portion 28 is placed on the flat seat so as to contact the flat seat.
  • the second coating layer 36 can be formed on the convex portion 27 in a state where the shoes 26A and 26B are placed. Such a method of forming the second coating layer 36 eliminates the need for a complicated jig for supporting the shoes 26A and 26B.
  • Ni—P plating as the first coating layer 35 is Ni-based plating formed by electroless plating, and can be formed by simply immersing the base material of the shoes 26A and 26B in the plating solution. Therefore, Ni—P plating is suitable as the first coating layer 35 that covers the entire surface of the base material of the shoes 26A and 26B.
  • the flat surface portion 28 may be a complete plane.
  • the base material of the shoes 26A and 26B may be titanium or iron.
  • the first coating layer 35 may be copper-based plating formed by electroless plating.
  • the present invention may be applied to a compressor in which a coating layer is not provided on an iron-based swash plate.
  • the present invention may be applied to a compressor in which a coating layer is not provided on an iron-based piston.
  • a large discharge reaction force in the discharge stroke is applied only to the second shoe 26B and not to the first shoe 26A. Therefore, when there is no fear of abnormal wear on the convex portion 27 of the first shoe 26A, the first shoe Only the first coating layer 35 may be provided on 26A.

Abstract

Disclosed is a shoe provided in a piston-type compressor, which is equipped with a cam plate and a piston that moves in reciprocating fashion due to the rotation of said cam plate. Said shoe is equipped with a convex surface part and a flat surface part. The convex surface part fits into a concave seating surface formed on said piston. Said flat surface part faces the sliding surface of said cam plate. Said shoe has a first coating layer and a second coating layer. Said first coating layer is formed on said flat surface part and said convex surface part. Said second coating layer is provided on the first coating layer on said convex surface part. Said second coating layer is formed from diamond‑like carbon. The first coating layer on said flat surface part is the outermost coating layer.

Description

ピストン式圧縮機におけるシューShoe in piston type compressor
 本発明は、ピストン式圧縮機におけるシューに関する。 The present invention relates to a shoe in a piston type compressor.
 回転する斜板の摺動面とピストンとの間に半球形状のシューが配置されたピストン式圧縮機では、斜板とシューとの摺接部位の摩耗、及び、ピストンとシューとの摺接部位の摩耗を防止するために、シューの表面に優れた摺動性を有するコーティング層を設ける場合がある(例えば、特許文献2の図5参照)。 In a piston compressor in which a hemispherical shoe is arranged between the sliding surface of the rotating swash plate and the piston, the wear of the sliding contact portion between the swash plate and the shoe and the sliding contact portion between the piston and the shoe In order to prevent wear, a coating layer having excellent slidability may be provided on the surface of the shoe (see, for example, FIG. 5 of Patent Document 2).
 コーティング層の代表的な材料としては、例えばニッケル-リンメッキ(以下、Ni-Pメッキと記すこともある)がある。シューの表面にNi-Pメッキを設け、かつシューの凸面部に嵌合するピストンの凹座面にコーティング層を設ける場合には、ピストンの凹座面にはNi-Pメッキとは異なる材料のコーティング層、例えば錫メッキが設けられる。又、シューの表面にNi-Pメッキを設け、かつシューの平坦面部に摺接する斜板の摺動面にコーティング層を設ける場合には、斜板の摺動面にはNi-Pメッキとは異なる材料のコーティング層、例えば、固体潤滑材(二硫化モリブデン、グラファイト等)を含む樹脂層が設けられる。 As a typical material for the coating layer, for example, there is nickel-phosphorous plating (hereinafter sometimes referred to as Ni-P plating). When Ni-P plating is provided on the surface of the shoe and a coating layer is provided on the concave seating surface of the piston that fits the convex surface of the shoe, the concave seating surface of the piston is made of a material different from Ni-P plating. A coating layer, for example tin plating, is provided. When Ni-P plating is provided on the surface of the shoe and a coating layer is provided on the sliding surface of the swash plate that is in sliding contact with the flat surface portion of the shoe, the Ni-P plating is applied to the sliding surface of the swash plate. A coating layer of a different material, for example, a resin layer containing a solid lubricant (such as molybdenum disulfide or graphite) is provided.
 前記圧縮機では、冷媒と共に流動する潤滑油が圧縮機内の摺接部位を潤滑する。シューは、回転軸の軸線の周りを一周する斜板の環状の摺動面に対し、斜板の回転に伴い摺動するので、斜板の摺動面とシューの平坦面部との間の摺接部位は、潤滑油によって潤滑されやすい。 In the compressor, lubricating oil flowing together with the refrigerant lubricates the sliding contact portion in the compressor. Since the shoe slides with the rotation of the swash plate against the annular sliding surface of the swash plate that goes around the axis of the rotation shaft, the sliding between the sliding surface of the swash plate and the flat surface portion of the shoe. The contact part is easily lubricated by the lubricating oil.
 しかし、シューの凸面部とピストンの凹座面との間で生じる相対移動は僅かであるとともに、その相対移動の速度は遅いため、潤滑油が凸面部と凹座面との間に入り難い。そのため、凸面部と凹座面との摺接部位は、潤滑されにくい。前記摺接部位が十分に潤滑されていない状態でシューの凸面部に設けられたNi-Pメッキが摩耗すると、該Ni-Pメッキの摩耗粉がピストンの凹座面に付着する。すると、凹座面に付着したNi-Pメッキの摩耗粉と凸面部上のNi-Pメッキとが凝着し、それにより異常な摩耗が生じる。 However, the relative movement that occurs between the convex part of the shoe and the concave seating surface of the piston is slight and the speed of the relative movement is slow, so that the lubricating oil hardly enters between the convex part and the concave seating surface. Therefore, the sliding contact portion between the convex surface portion and the concave seat surface is not easily lubricated. When the Ni—P plating provided on the convex surface portion of the shoe is worn while the sliding contact portion is not sufficiently lubricated, the wear powder of the Ni—P plating adheres to the concave seating surface of the piston. Then, the wear powder of the Ni—P plating adhering to the concave seat surface and the Ni—P plating on the convex portion adhere to each other, thereby causing abnormal wear.
 この異常な摩耗を防止するため、特許文献1,2は、シューの表面に設けられるコーティング層としてダイヤモンド・ライク・カーボン(非晶質硬質炭素膜)を用いることを開示している。ダイヤモンド・ライク・カーボンは、十分に潤滑されていない状態でも優れた摺動性を有する高硬度の炭素膜である。 In order to prevent this abnormal wear, Patent Documents 1 and 2 disclose using diamond-like carbon (amorphous hard carbon film) as a coating layer provided on the surface of the shoe. Diamond-like carbon is a high-hardness carbon film having excellent slidability even when not sufficiently lubricated.
 しかし、シューの母材(地金)として、例えばアルミニウムのような低硬度の材料を用い、かつシューの表面に高硬度のダイヤモンド・ライク・カーボンを直接設けた場合には、シューの母材の硬度とダイヤモンド・ライク・カーボンの硬度との大きな差に起因してダイヤモンド・ライク・カーボンがシューから剥離し易い。 However, when using a low hardness material such as aluminum as the shoe base material (base metal) and providing high hardness diamond-like carbon directly on the shoe surface, the shoe base material Due to the large difference between the hardness and the hardness of diamond-like carbon, diamond-like carbon tends to peel off from the shoe.
 特許文献3は、シューの母材の表面にNi-Pメッキを設け、このNi-Pメッキの上にダイヤモンド・ライク・カーボンを設けることを開示している。Ni-Pメッキの硬度とダイヤモンド・ライク・カーボンの硬度との差は、シューの母材の硬度とダイヤモンド・ライク・カーボンの硬度との差に比べて小さいため、ダイヤモンド・ライク・カーボンがシューから剥離されにくくなる。 Patent Document 3 discloses that Ni—P plating is provided on the surface of a shoe base material, and diamond-like carbon is provided on the Ni—P plating. The difference between the hardness of the Ni-P plating and the hardness of diamond-like carbon is smaller than the difference between the hardness of the base material of the shoe and the hardness of diamond-like carbon, so the diamond-like carbon is removed from the shoe. It becomes difficult to peel.
特開平6-346074号公報JP-A-6-346074 特開2002-5013号公報JP 2002-5013 A 特開2002-194565号公報JP 2002-194565 A
 しかし、シューの平坦面部に設けた高硬度のダイヤモンド・ライク・カーボンは、シューに対して高速で摺動する斜板の摺動面上のコーティング層を早期に摩耗させるおそれがある。 However, the diamond-like carbon with high hardness provided on the flat surface portion of the shoe may wear the coating layer on the sliding surface of the swash plate that slides at high speed with respect to the shoe at an early stage.
 本発明の目的は、摩耗抑制に優れたシューを提供することである。 An object of the present invention is to provide a shoe excellent in wear suppression.
 上記目的を達成するために、本発明の態様に従い、斜板と、該斜板の回転によって往復動するピストンとを備えるピストン式圧縮機に設けられるシューが提供される。前記シューは、凸面部と平坦面部とを備える。凸面部は、前記ピストンに形成された凹座面に嵌合する。前記平坦面部は、前記斜板の摺動面に対向する。前記シューは、第1コーティング層と第2コーティング層とを備える。前記第1コーティング層は、前記平坦面部及び前記凸面部上に形成される。前記第2コーティング層は、前記凸面部上の第1コーティング層上に設けられている。前記第2コーティング層はダイヤモンド・ライク・カーボンで形成される。前記平坦面部上の第1コーティング層は最外のコーティング層である。 In order to achieve the above object, according to an aspect of the present invention, there is provided a shoe provided in a piston compressor including a swash plate and a piston that reciprocates by rotation of the swash plate. The shoe includes a convex surface portion and a flat surface portion. The convex portion fits into a concave seat surface formed on the piston. The flat surface portion faces the sliding surface of the swash plate. The shoe includes a first coating layer and a second coating layer. The first coating layer is formed on the flat surface portion and the convex surface portion. The second coating layer is provided on the first coating layer on the convex surface portion. The second coating layer is formed of diamond-like carbon. The first coating layer on the flat surface portion is the outermost coating layer.
(a)は、本発明を具体化した一実施形態に係るシューを備えた可変容量型ピストン式圧縮機の側断面図、(b)は図1(a)の部分拡大断面図。(A) is a side sectional view of a variable capacity piston type compressor provided with a shoe concerning one embodiment which materialized the present invention, and (b) is a partial expanded sectional view of Drawing 1 (a). (a),(b)は、図1のシューの摺動試験の結果を示す図。(A), (b) is a figure which shows the result of the sliding test of the shoes of FIG.
 以下、本発明を具体化した一実施形態を図1及び図2に基づいて説明する。
 図1(a)に示すように、可変容量型ピストン式圧縮機10のハウジングは、シリンダブロック11と、シリンダブロック11の前端に接合されたフロントハウジング部材12と、シリンダブロック11の後端に接合されたリヤハウジング部材17とを備えている。フロントハウジング部材12及びシリンダブロック11は、両者の間に制御圧室121を形成する。フロントハウジング部材12及びシリンダブロック11は回転軸13を回転可能に支持する。回転軸13は、外部駆動源(例えば車両エンジン)から駆動力を得て回転する。回転軸13には、回転支持体14が止着されるとともに、斜板15が回転軸13の軸方向に移動可能かつ傾動可能に支持されている。斜板15の母材(地金)は、鉄系である。斜板15は、環状の基板部20と、基板部20の径方向外側に設けられた環状の摺動板部21とを備えている。斜板15は、回転支持体14に形成されたガイド孔141と、斜板15の基板部20に設けられたガイドピン16との連係により、傾動を伴いながら回転軸13の軸方向へ移動可能かつ回転軸13と一体的に回転可能である。
Hereinafter, an embodiment embodying the present invention will be described with reference to FIGS. 1 and 2.
As shown in FIG. 1A, the housing of the variable displacement piston compressor 10 is joined to a cylinder block 11, a front housing member 12 joined to the front end of the cylinder block 11, and a rear end of the cylinder block 11. The rear housing member 17 is provided. The front housing member 12 and the cylinder block 11 form a control pressure chamber 121 between them. The front housing member 12 and the cylinder block 11 support the rotating shaft 13 in a rotatable manner. The rotating shaft 13 rotates by obtaining a driving force from an external driving source (for example, a vehicle engine). A rotary support 14 is fixed to the rotary shaft 13, and a swash plate 15 is supported so as to be movable and tiltable in the axial direction of the rotary shaft 13. The base material (metal) of the swash plate 15 is iron-based. The swash plate 15 includes an annular substrate portion 20 and an annular sliding plate portion 21 provided on the radially outer side of the substrate portion 20. The swash plate 15 is movable in the axial direction of the rotary shaft 13 while being tilted by the linkage between the guide hole 141 formed in the rotary support 14 and the guide pin 16 provided in the substrate portion 20 of the swash plate 15. And it can rotate integrally with the rotating shaft 13.
 斜板15の傾角は、制御圧室121内の圧力に応じて変化する。斜板15の最大傾角は、斜板15と回転支持体14との当接によって規定される。図1(a)に鎖線で示す斜板15は、最小傾角となる位置にある。 The inclination angle of the swash plate 15 changes according to the pressure in the control pressure chamber 121. The maximum inclination angle of the swash plate 15 is defined by the contact between the swash plate 15 and the rotary support 14. The swash plate 15 indicated by a chain line in FIG. 1A is at a position where the minimum inclination angle is obtained.
 シリンダブロック11に貫設された複数のシリンダボア111(図1(a)では2つのみ示す)内にはピストン18が収容されている。ピストン18は、頭部181と首部182とを有し、シリンダボア111内に嵌入された頭部181は、シリンダボア111内に圧縮室112を区画する。ピストン18は、シリコンを含有するアルミニウム系の材料で形成されている。 Pistons 18 are accommodated in a plurality of cylinder bores 111 (only two are shown in FIG. 1A) penetrating the cylinder block 11. The piston 18 has a head portion 181 and a neck portion 182, and the head portion 181 fitted in the cylinder bore 111 defines a compression chamber 112 in the cylinder bore 111. The piston 18 is made of an aluminum-based material containing silicon.
 図1(b)に示すように、首部182には凹部19が形成されており、凹部19には斜板15の摺動板部21が挿入されている。摺動板部21は第1摺動面22A及び第2摺動面22Bを有している。凹部19を形成する一対の内側壁面23,24は互いに対向するとともに、凹んだ球面形状の第1凹座面25A及び第2凹座面25Bをそれぞれ有する。 As shown in FIG. 1B, a recess 19 is formed in the neck 182, and a sliding plate portion 21 of the swash plate 15 is inserted in the recess 19. The sliding plate portion 21 has a first sliding surface 22A and a second sliding surface 22B. The pair of inner wall surfaces 23 and 24 forming the recess 19 face each other and have a concave first spherical seat surface 25A and a second concave seat surface 25B, respectively.
 第1凹座面25Aには半球形状の第1シュー26Aが嵌合されており、第2凹座面25Bには半球形状の第2シュー26Bが嵌合されている。第1シュー26A及び第2シュー26Bの母材(地金)は、シリコンを含有するアルミニウム系の材料である。 The hemispherical first shoe 26A is fitted to the first concave seat surface 25A, and the hemispherical second shoe 26B is fitted to the second concave seat surface 25B. The base material (base metal) of the first shoe 26A and the second shoe 26B is an aluminum-based material containing silicon.
 第1シュー26A及び第2シュー26Bは、それぞれ球面形状の凸面部27と平面形状の平坦面部28とを有している。本実施形態では、平坦面部28は、厳密には曲率の大きい複数の曲面からなる。第1シュー26Aの凸面部27は、第1凹座面25Aに摺接可能であり、第2シュー26Bの凸面部27は、第2凹座面25Bに摺接可能である。第1シュー26Aの平坦面部28は、摺動板部21の第1摺動面22Aに摺接可能であり、第2シュー26Bの平坦面部28は、摺動板部21の第2摺動面22Bに摺接可能である。 The first shoe 26A and the second shoe 26B have a spherical convex surface portion 27 and a planar flat surface portion 28, respectively. In the present embodiment, the flat surface portion 28 is strictly composed of a plurality of curved surfaces having a large curvature. The convex surface portion 27 of the first shoe 26A can slide on the first concave seat surface 25A, and the convex surface portion 27 of the second shoe 26B can slide on the second concave seat surface 25B. The flat surface portion 28 of the first shoe 26 </ b> A can be slidably contacted with the first sliding surface 22 </ b> A of the sliding plate portion 21, and the flat surface portion 28 of the second shoe 26 </ b> B is the second sliding surface of the sliding plate portion 21. 22B can be slidably contacted.
 つまり、第1シュー26Aは、第1摺動面22Aと第1凹座面25Aとの間に配置しており、第2シュー26Bは、第2摺動面22Bと第2凹座面25Bとの間に配置されている。斜板15の回転運動は、第1シュー26A及び第2シュー26Bを介してピストン18の往復運動に変換され、ピストン18がシリンダボア111内を往復動する。 That is, the first shoe 26A is disposed between the first sliding surface 22A and the first concave seating surface 25A, and the second shoe 26B is provided between the second sliding surface 22B and the second concave seating surface 25B. It is arranged between. The rotational movement of the swash plate 15 is converted into the reciprocating movement of the piston 18 via the first shoe 26A and the second shoe 26B, and the piston 18 reciprocates in the cylinder bore 111.
 ピストン18がシリンダボア111内を上死点から下死点へ向かって移動(図1(a)において右側から左側への移動)すると、リヤハウジング部材17に形成された吸入室29内の冷媒が吸入ポート30を経由して圧縮室112へ吸入される。ピストン18がシリンダボア111内を下死点から上死点へ向かって移動(図1(a)において左側から右側への移動)すると、圧縮室112内の冷媒が吐出ポート31を経由してリヤハウジング部材17に形成された吐出室32内へ吐出される。 When the piston 18 moves from the top dead center to the bottom dead center in the cylinder bore 111 (moving from the right side to the left side in FIG. 1A), the refrigerant in the suction chamber 29 formed in the rear housing member 17 is sucked. The air is sucked into the compression chamber 112 through the port 30. When the piston 18 moves in the cylinder bore 111 from the bottom dead center to the top dead center (from the left side to the right side in FIG. 1A), the refrigerant in the compression chamber 112 passes through the discharge port 31 and the rear housing. The ink is discharged into the discharge chamber 32 formed in the member 17.
 図1(b)に示すように、斜板15の摺動板部21の母材(地金)の平面部211にはコーティング層33Aが設けられており、コーティング層33Aの表面が前記第1摺動面22Aを形成している。同様に、摺動板部21の母材の平面部212にはコーティング層33Bが設けられており、コーティング層33Bの表面が前記第2摺動面22Bを形成している。本実施形態では、コーティング層33A,33Bは、いずれも固体潤滑材を含有する樹脂材料よりなる。固体潤滑材は、例えば二硫化モリブデン、グラファイトである。 As shown in FIG. 1B, a coating layer 33A is provided on the flat surface portion 211 of the base material (base metal) of the sliding plate portion 21 of the swash plate 15, and the surface of the coating layer 33A is the first surface. A sliding surface 22A is formed. Similarly, a coating layer 33B is provided on the flat surface portion 212 of the base material of the sliding plate portion 21, and the surface of the coating layer 33B forms the second sliding surface 22B. In the present embodiment, the coating layers 33A and 33B are each made of a resin material containing a solid lubricant. The solid lubricant is, for example, molybdenum disulfide or graphite.
 ピストン18の母材(地金)の表面全体にはコーティング層34が設けられている。本実施形態では、ピストン18の母材は、シリコンを含有するアルミニウム系の材料であり、コーティング層34は、錫メッキである。 A coating layer 34 is provided on the entire surface of the base material (metal) of the piston 18. In the present embodiment, the base material of the piston 18 is an aluminum-based material containing silicon, and the coating layer 34 is tin-plated.
 第1シュー26Aの母材の表面全体には第1コーティング層35が設けられている。本実施形態では、第1コーティング層35は、ニッケル-リンメッキ(以下においてはNi-Pメッキと記す)である。第1シュー26Aの凸面部27上の第1コーティング層35上には第2コーティング層36が設けられている。第2コーティング層36は、ダイヤモンド・ライク・カーボン(以下においてはDLCと記す)である。即ち、第1シュー26Aの凸面部27上の最外のコーティング層は、第2コーティング層36であり、第1シュー26Aの平坦面部28上の最外のコーティング層は、第1コーティング層35である。 The first coating layer 35 is provided on the entire surface of the base material of the first shoe 26A. In the present embodiment, the first coating layer 35 is nickel-phosphorous plating (hereinafter referred to as Ni-P plating). A second coating layer 36 is provided on the first coating layer 35 on the convex surface portion 27 of the first shoe 26A. The second coating layer 36 is diamond-like carbon (hereinafter referred to as DLC). That is, the outermost coating layer on the convex surface portion 27 of the first shoe 26A is the second coating layer 36, and the outermost coating layer on the flat surface portion 28 of the first shoe 26A is the first coating layer 35. is there.
 第2シュー26Bには、第1シュー26Aと同様の態様で、第1コーティング層35及び第2コーティング層36が設けられている。
 Ni-Pメッキである第1コーティング層35は、無電解メッキで形成されている。本実施形態では、第1コーティング層35(Ni-Pメッキ)におけるP(リン)の重量%は、5重量%以下であり、第1コーティング層35の厚みは、40μmである。DLCである第2コーティング層36は、CVD法あるいはPVD法等の蒸着方法で形成されている。本実施形態では、第2コーティング層36の厚みは、3μmである。
The second shoe 26B is provided with a first coating layer 35 and a second coating layer 36 in the same manner as the first shoe 26A.
The first coating layer 35 made of Ni—P plating is formed by electroless plating. In the present embodiment, the weight% of P (phosphorus) in the first coating layer 35 (Ni—P plating) is 5% by weight or less, and the thickness of the first coating layer 35 is 40 μm. The second coating layer 36 that is DLC is formed by a vapor deposition method such as a CVD method or a PVD method. In the present embodiment, the thickness of the second coating layer 36 is 3 μm.
 斜板15が回転すると、第1シュー26Aの平坦面部28上の第1コーティング層35と斜板15の第1摺動面22Aとが摺接し、第1シュー26Aの凸面部27上の第2コーティング層36とピストン18の第1凹座面25A上のコーティング層34とが摺接する。又、第2シュー26Bの平坦面部28上の第1コーティング層35と斜板15の第2摺動面22Bとが摺接し、第2シュー26Bの凸面部27上の第2コーティング層36とピストン18の第2凹座面25B上のコーティング層34とが摺接する。 When the swash plate 15 rotates, the first coating layer 35 on the flat surface portion 28 of the first shoe 26A comes into sliding contact with the first sliding surface 22A of the swash plate 15, and the second on the convex surface portion 27 of the first shoe 26A. The coating layer 36 and the coating layer 34 on the first concave seat surface 25A of the piston 18 are in sliding contact. Further, the first coating layer 35 on the flat surface portion 28 of the second shoe 26B and the second sliding surface 22B of the swash plate 15 are in sliding contact, and the second coating layer 36 on the convex surface portion 27 of the second shoe 26B and the piston. The coating layer 34 on the 18th second concave seat surface 25B comes into sliding contact.
 図2(a)は、シュー26A,26Bに関する往復摺動試験の結果を示す。往復摺動試験は以下のようにして行われた。すなわち、シリコンを含有するアルミニウム系の材料で形成された試験部材(ピストンに相当する部材)の凹座面にシューの凸面部を嵌合し、且つ、シューを前記凹座面に押し付けるように所定重量(例えば10kg)の錘をシューに繋いだ。この試験部材(ピストンに相当する部材)の表面全体には錫メッキが設けられている。そして、無潤滑の状態で、シューを前記凹座面に押し付けながら錘を往復動させて、凹座面に対してシューを摺動させた。 FIG. 2 (a) shows the results of a reciprocating sliding test on the shoes 26A and 26B. The reciprocating sliding test was performed as follows. That is, the predetermined portion of the test member (a member corresponding to a piston) formed of an aluminum-based material containing silicon is fitted to the concave surface of the shoe, and the shoe is pressed against the concave surface. A weight (for example, 10 kg) was connected to the shoe. The entire surface of the test member (member corresponding to the piston) is provided with tin plating. Then, in a non-lubricated state, the shoe was slid against the concave seat surface by reciprocating the weight while pressing the shoe against the concave seat surface.
 シューの凸面部に第1コーティング層(Ni-Pメッキ)が設けられていない場合には、錘が6~8回往復動した時点で凝着が生じた。
 シューの凸面部に第1コーティング層(Ni-Pメッキ)が設けられている場合には、錘が10~12回往復動した時点で凝着が生じた。
In the case where the first coating layer (Ni—P plating) was not provided on the convex portion of the shoe, adhesion occurred when the weight reciprocated 6 to 8 times.
When the first coating layer (Ni—P plating) was provided on the convex surface portion of the shoe, adhesion occurred when the weight reciprocated 10 to 12 times.
 シューの凸面部に、第1コーティング層(Ni-Pメッキ)及び第2コーティング層(DLC)が設けられている場合には、錘が15~20回往復動した時点でも凝着は生じなかった。 When the first coating layer (Ni-P plating) and the second coating layer (DLC) were provided on the convex surface of the shoe, no adhesion occurred even when the weight reciprocated 15 to 20 times. .
 シューの凸面部に、第1コーティング層無しで、第2コーティング層(DLC)が直接設けられている場合にも、錘が15~20回往復動した時点でも凝着は生じなかった。
 図2(b)は、シュー26A,26Bに関する回転摺動試験の結果を示す。回転摺動試験では、斜板15と同じ材料で形成された回転平板上に設けられたコーティング層に、複数のシュー(ピストン18の個数と同じ)の平坦面部を押接した状態で、潤滑油を噴霧しつつ、シューを回転平板のコーティング層に押し付けながら回転平板を回転させた。この際、回転平板に対するシューの押し付け荷重を徐々に増やしていった。この回転平板上に設けられたコーティング層は前記コーティング層33A,33Bと同じである。押し付け荷重は、0.4kNから開始して5分毎に0.4kNずつ段階的に増やした。潤滑油は、1分当たり25mgを噴霧した。回転平板の回転数は、2000rpmであった。回転摺動試験は、2回行なった。
Even when the second coating layer (DLC) was directly provided on the convex portion of the shoe without the first coating layer, adhesion did not occur even when the weight reciprocated 15 to 20 times.
FIG. 2 (b) shows the result of the rotational sliding test on the shoes 26A and 26B. In the rotational sliding test, the lubricating oil is applied in a state where the flat surface portions of a plurality of shoes (same as the number of pistons 18) are pressed against a coating layer provided on a rotating flat plate made of the same material as the swash plate 15. While spraying, the rotating plate was rotated while pressing the shoe against the coating layer of the rotating plate. At this time, the pressing load of the shoe against the rotating flat plate was gradually increased. The coating layer provided on the rotating flat plate is the same as the coating layers 33A and 33B. The pressing load started from 0.4 kN and increased stepwise by 0.4 kN every 5 minutes. Lubricating oil was sprayed at 25 mg per minute. The number of rotations of the rotating plate was 2000 rpm. The rotary sliding test was performed twice.
 本実施形態のシュー26A,26Bのように、シューの平坦面部に   Ni-Pメッキのコーティング層のみが設けられている場合、1回目の試験では、押し付け荷重が4.8kNになったときに焼き付きが生じ、2回目の試験では、押し付け荷重が4.4kNになったときに焼き付きが生じた。 When only the heel Ni—P plating coating layer is provided on the flat surface portion of the shoe as in the shoes 26A and 26B of the present embodiment, the seizure occurs when the pressing load is 4.8 kN in the first test. In the second test, seizure occurred when the pressing load reached 4.4 kN.
 シューの平坦面部にDLCのコーティング層のみが設けられている場合、1回目の試験では、押し付け荷重が3.2kNになったときに焼き付きが生じ、2回目の試験では、押し付け荷重が2.8kNになったときに焼き付きが生じた。 When only the DLC coating layer is provided on the flat surface portion of the shoe, seizure occurs when the pressing load is 3.2 kN in the first test, and the pressing load is 2.8 kN in the second test. Burning occurred when
 図2(b)の試験結果は、斜板15の摺動面22A,22Bに摺接するシューの平坦面部28にDLCのコーティング層を設けると、斜板15の摺動面22A,22BがDLCのコーティング層の存在によって摩耗し易くなることを示す。 2B shows that when a DLC coating layer is provided on the flat surface portion 28 of the shoe that is in sliding contact with the sliding surfaces 22A and 22B of the swash plate 15, the sliding surfaces 22A and 22B of the swash plate 15 are DLC. It shows that it becomes easy to wear due to the presence of the coating layer.
 上記実施形態は、以下の利点を有する。
 (1)第1コーティング層35(Ni-Pメッキ)上に設けられた第2コーティング層36(DLC)は、凸面部27上に設けられた第1コーティング層35(Ni-Pメッキ)の摩耗を防止するので、潤滑されにくい凸面部27及び凹座面25A,25Bの異常摩耗が回避される。
The above embodiment has the following advantages.
(1) The second coating layer 36 (DLC) provided on the first coating layer 35 (Ni—P plating) is worn by the first coating layer 35 (Ni—P plating) provided on the convex portion 27. Therefore, abnormal wear of the convex portion 27 and the concave seat surfaces 25A and 25B that are difficult to be lubricated is avoided.
 平坦面部28上には第1コーティング層35(Ni-Pメッキ)のみが設けられ、DLCのコーティング層はないため、斜板15の摺動面22A,22BがDLCの存在によって摩耗され易くなるという問題は回避される。又、平坦面部28上では油膜が生じやすい、つまり十分に潤滑され易いため、第1コーティング層35(Ni-Pメッキ)のみでも、摺動面22A,22Bと第1コーティング層35との間で異常摩耗は、従来と同様に生じない。 Since only the first coating layer 35 (Ni—P plating) is provided on the flat surface portion 28 and there is no DLC coating layer, the sliding surfaces 22A and 22B of the swash plate 15 are easily worn due to the presence of DLC. The problem is avoided. Further, since an oil film is likely to be formed on the flat surface portion 28, that is, it is easily lubricated, only the first coating layer 35 (Ni-P plating) is provided between the sliding surfaces 22A, 22B and the first coating layer 35. Abnormal wear does not occur as in the prior art.
 (2)高硬度の第2コーティング層36(DLC)とシュー26A,26Bの母材との間に介在する第1コーティング層35(Ni-Pメッキ)の硬度は、DLCの硬度に比べて低く、シュー26A,26Bの母材であるシリコンを含有するアルミニウムの硬度よりも高い。つまり、第1コーティング層35は、DLCの硬度と該DLCでコーティングされる部材の硬度との差に起因する不具合を緩和する。よって、DLCに生じる応力が緩和されて、第2コーティング層36がシュー26A,26Bから剥離されることが防止される。 (2) The hardness of the first coating layer 35 (Ni-P plating) interposed between the high hardness second coating layer 36 (DLC) and the base material of the shoes 26A and 26B is lower than the hardness of DLC. The hardness of aluminum containing silicon which is a base material of the shoes 26A and 26B is higher. That is, the 1st coating layer 35 relieves the malfunction resulting from the difference of the hardness of DLC and the hardness of the member coated with this DLC. Therefore, the stress generated in the DLC is relaxed, and the second coating layer 36 is prevented from being peeled off from the shoes 26A and 26B.
 (3)第2コーティング層36は、シュー26A,26Bの凸面部27にのみ設けられるため、第2コーティング層36を形成するときには、平坦面部28を平面座上に接触させるように平面座上にシュー26A,26Bを載置した状態で、凸面部27に第2コーティング層36を形成することができる。このような第2コーティング層36の形成方法は、シュー26A,26Bを支持するための複雑な治具を不要にする。 (3) Since the second coating layer 36 is provided only on the convex surface portion 27 of the shoes 26A and 26B, when forming the second coating layer 36, the flat surface portion 28 is placed on the flat seat so as to contact the flat seat. The second coating layer 36 can be formed on the convex portion 27 in a state where the shoes 26A and 26B are placed. Such a method of forming the second coating layer 36 eliminates the need for a complicated jig for supporting the shoes 26A and 26B.
 (4)第1コーティング層35としてのNi-Pメッキは、無電解メッキで形成されるNi系メッキであり、シュー26A,26Bの母材をメッキ液に浸すだけで形成することができる。よって、Ni-Pメッキは、シュー26A,26Bの母材の表面全体を被覆する第1コーティング層35として好適である。 (4) Ni—P plating as the first coating layer 35 is Ni-based plating formed by electroless plating, and can be formed by simply immersing the base material of the shoes 26A and 26B in the plating solution. Therefore, Ni—P plating is suitable as the first coating layer 35 that covers the entire surface of the base material of the shoes 26A and 26B.
 本発明では以下のような実施形態も可能である。
 平坦面部28は、完全な平面であってもよい。
 シュー26A,26Bの母材は、チタン系、鉄系であってもよい。
In the present invention, the following embodiments are also possible.
The flat surface portion 28 may be a complete plane.
The base material of the shoes 26A and 26B may be titanium or iron.
 第1コーティング層35は、無電解メッキで形成される銅系メッキであってもよい。
 鉄系の斜板にコーティング層が設けられていない圧縮機に本発明を適用してもよい。
 鉄系のピストンにコーティング層が設けられていない圧縮機に本発明を適用してもよい。
The first coating layer 35 may be copper-based plating formed by electroless plating.
The present invention may be applied to a compressor in which a coating layer is not provided on an iron-based swash plate.
The present invention may be applied to a compressor in which a coating layer is not provided on an iron-based piston.
 吐出行程における大きな吐出反力は、第2シュー26Bにのみ加わって第1シュー26Aには加わらないので、第1シュー26Aの凸面部27での異常摩耗のおそれがない場合には、第1シュー26Aには第1コーティング層35のみを設けてもよい。 A large discharge reaction force in the discharge stroke is applied only to the second shoe 26B and not to the first shoe 26A. Therefore, when there is no fear of abnormal wear on the convex portion 27 of the first shoe 26A, the first shoe Only the first coating layer 35 may be provided on 26A.
 15…斜板、18…ピストン、22A,22B…摺動面、25A,25B…凹座面、26A,26B…シュー、27…凸面部、28…平坦面図、35…第1コーティング層、36…第2コーティング層。 DESCRIPTION OF SYMBOLS 15 ... Swash plate, 18 ... Piston, 22A, 22B ... Sliding surface, 25A, 25B ... Concave seat surface, 26A, 26B ... Shoe, 27 ... Convex part, 28 ... Flat view, 35 ... 1st coating layer, 36 ... second coating layer.

Claims (8)

  1.  斜板と、該斜板の回転によって往復動するピストンとを備えるピストン式圧縮機に設けられるシューであって、該シューは、前記ピストンに形成された凹座面に嵌合する凸面部と、前記斜板の摺動面に対向する平坦面部とを備え、前記シューは、
     前記平坦面部及び前記凸面部上に形成された第1コーティング層と、
     前記凸面部上の第1コーティング層上に設けられた第2コーティング層と、を備え、
     前記第2コーティング層はダイヤモンド・ライク・カーボンで形成され、
     前記平坦面部上の第1コーティング層は最外のコーティング層であることを特徴とするシュー。
    A shoe provided in a piston-type compressor including a swash plate and a piston that reciprocates by rotation of the swash plate, wherein the shoe includes a convex surface portion that fits into a concave seat surface formed on the piston, A flat surface portion facing the sliding surface of the swash plate, the shoe,
    A first coating layer formed on the flat surface portion and the convex surface portion;
    A second coating layer provided on the first coating layer on the convex surface part,
    The second coating layer is formed of diamond-like carbon,
    The shoe according to claim 1, wherein the first coating layer on the flat surface portion is an outermost coating layer.
  2.  第1コーティング層はダイヤモンド・ライク・カーボン以外の材料で形成されることを特徴とする請求項1に記載のシュー。 The shoe according to claim 1, wherein the first coating layer is formed of a material other than diamond-like carbon.
  3.  前記第1コーティング層の硬度は、前記シューの母材の硬度よりも高く、前記ダイヤモンド・ライク・カーボンの硬度よりも低いことを特徴とする請求項1又は請求項2に記載のシュー。 The shoe according to claim 1 or 2, wherein the hardness of the first coating layer is higher than the hardness of the base material of the shoe and lower than the hardness of the diamond-like carbon.
  4.  前記第1コーティング層は、ニッケル系メッキであることを特徴とする請求項1~請求項3のうちのいずれか一項に記載のシュー。 The shoe according to any one of claims 1 to 3, wherein the first coating layer is nickel-based plating.
  5.  前記ニッケル系メッキは、ニッケル-リンメッキであることを特徴とする請求項4に記載のシュー。 The shoe according to claim 4, wherein the nickel-based plating is nickel-phosphorus plating.
  6.  前記第1コーティング層は無電解メッキで形成され、前記第2コーティング層はCVD法あるいはPVD法を含む蒸着方法で形成されることを特徴とする請求項4又は請求項5に記載のシュー。 The shoe according to claim 4 or 5, wherein the first coating layer is formed by electroless plating, and the second coating layer is formed by a vapor deposition method including a CVD method or a PVD method.
  7.  前記斜板の摺動面上には、固体潤滑材を含有する樹脂で構成されたコーティング層が形成されることを特徴とする請求項4又は請求項5に記載のシュー。 6. The shoe according to claim 4, wherein a coating layer made of a resin containing a solid lubricant is formed on the sliding surface of the swash plate.
  8.  前記固体潤滑材は、二硫化モリブデン又はグラファイトであることを特徴とする請求項7に記載のシュー。 The shoe according to claim 7, wherein the solid lubricant is molybdenum disulfide or graphite.
PCT/JP2009/059645 2008-06-25 2009-05-27 Shoe in piston type compressor WO2009157267A1 (en)

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