WO2009121283A1 - A conductive cleaning drawing template and a laser imaging device - Google Patents

A conductive cleaning drawing template and a laser imaging device Download PDF

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Publication number
WO2009121283A1
WO2009121283A1 PCT/CN2009/071039 CN2009071039W WO2009121283A1 WO 2009121283 A1 WO2009121283 A1 WO 2009121283A1 CN 2009071039 W CN2009071039 W CN 2009071039W WO 2009121283 A1 WO2009121283 A1 WO 2009121283A1
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WO
WIPO (PCT)
Prior art keywords
conductive
polyol
polyurethane
cleaning blade
photosensitive drum
Prior art date
Application number
PCT/CN2009/071039
Other languages
French (fr)
Chinese (zh)
Inventor
周小平
Original Assignee
兰光明
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Publication date
Application filed by 兰光明 filed Critical 兰光明
Publication of WO2009121283A1 publication Critical patent/WO2009121283A1/en

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Classifications

    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G21/00Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge
    • G03G21/0005Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge for removing solid developer or debris from the electrographic recording medium
    • G03G21/0011Arrangements not provided for by groups G03G13/00 - G03G19/00, e.g. cleaning, elimination of residual charge for removing solid developer or debris from the electrographic recording medium using a blade; Details of cleaning blades, e.g. blade shape, layer forming
    • G03G21/0017Details relating to the internal structure or chemical composition of the blades
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03GELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
    • G03G2221/00Processes not provided for by group G03G2215/00, e.g. cleaning or residual charge elimination
    • G03G2221/0005Cleaning of residual toner

Definitions

  • the present invention relates to the field of laser image forming technology, and in particular to a toner cartridge cleaning blade of a laser printer, a laser facsimile machine, a laser copier, a laser photographer, and the like, and a laser image forming apparatus including the same.
  • the working principle of laser imaging is to first convert the printed signal from the computer into a pulse signal and send it to the laser.
  • the charging roller uniformly charges the surface of the photosensitive drum core.
  • the laser emits laser light to cancel the charge on the image part of the drum core, and then the magnetic roller is placed on the magnetic roller.
  • the toner is adsorbed onto the drum core by electrostatic principle and then transferred by the transfer roller. Since the voltage on the transfer roller is higher than the voltage on the drum core, the toner on the drum core is pulled onto the paper. After warming and pressing, the carbon powder is melted and penetrated into the fibers of the paper to complete the entire imaging process.
  • the molding structure is as shown in FIG.
  • the structure of the existing charging roller 5 comprises a roller core made of a metal conductive material, the roller core is coated with a conductive adhesive layer, and the conductive adhesive layer is provided with a conductive rubber having a certain thickness and containing carbon micropowder.
  • the rubber elastic layer, the outer surface of the conductive rubber elastic layer is covered with a conductive coating.
  • the charging roller is relatively complicated in process and seriously pollutes the environment.
  • the conductive coating of the charging roller is damaged or unclean and the operation process
  • the consumption of the medium voltage causes the photosensitive drum to be charged and discharged insufficiently, causing the bottom ash or affecting the print quality.
  • the cleaning blade is generally formed by bonding a transparent polyurethane sheet to a metal sheet material.
  • the polyurethane material mainly has high abrasion resistance and does not damage the photosensitive drum.
  • the cleaning blade does not have electrical conductivity because its polyurethane material is an insulating material.
  • the technical problem to be solved by the present invention is to overcome the above drawbacks of the prior art, and provide an electrically conductive cleaning blade which can replace the existing charging roller and the cleaning blade, and can clean the photosensitive drum core and the surface of the photosensitive drum core. Charging to reduce manufacturing costs.
  • the present invention also provides a laser imaging apparatus including the above-described cleaning blade.
  • An electrically conductive cleaning blade which is composed of a metal bottom knife and a blade, and is characterized in that: the blade is made of a conductive polyurethane material, and the polyurethane material is an unsaturated polyol and one or more
  • the isocyanate is a polyurethane conductive composition produced by crosslinking reaction to form a polyurethane resin and then mixing with an ion conductive type donor.
  • the polyurethane resin formed by crosslinking the polyol with one or more polyisocyanates is mixed with an ion conductive type donor in a ratio of 100: 5 to 20.
  • the polyurethane conductive composition has a resistivity of 10 5 to 10 9 ohms/cm.
  • the polyol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol or a polyester polyol.
  • the polyisocyanate is one or more of a high molecular polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and a modified mixture thereof.
  • the ion conductive type administering agent is: metal anion, cationic conductive material, non-detached Sub-conductive material.
  • the present invention also provides a laser image forming apparatus comprising a powder silo, a powder feeding roller, a developing roller, a transfer roller and a photosensitive drum core, wherein: a photosensitive drum core is disposed at a position in front of the photosensitive drum core An electrically conductive cleaning blade that is in contact with the outer surface, the electrically conductive cleaning blade being composed of a metal base knife and a blade made of a conductive polyurethane material, the polyurethane material being an unsaturated polyol and one or one
  • the above polyisocyanate is subjected to a crosslinking reaction to form a polyurethane resin, and then a polyurethane conductive composition prepared by mixing with an ion conductive type donor.
  • the polyol is crosslinked with one or more polyisocyanates to form a polyurethane resin and an ion conductive type donor in a mixing ratio of 100: 5 to 20.
  • the polyurethane conductive composition has a resistivity of from 10 5 to 10 9 ohms/cm.
  • the polyol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol or a polyester polyol.
  • the polyisocyanate is one or more of a high molecular polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and a modified mixture thereof.
  • the ion conductive type administering agent is: a metal anion, a cationic conductive material, and a nonionic conductive material.
  • the present invention can combine the charging roller and the cleaning blade of the prior art by using an electrically conductive cleaning blade, which can save the trouble of manufacturing the charging roller, reduce pollution, and save.
  • the material calculated by the number of toner cartridges used in the world every year, can save the material cost and processing cost of 250 million charging rollers, which can be reduced by 3,250 tons per year based on an average of 130 grams per charging roller. Solid waste, saving 3.75 billion yuan, and this number is increasing by 15% every year. [Description of the Drawings]
  • Figure 1 is a schematic view showing the structure of a cleaning blade of the present invention
  • FIG. 2 is a schematic structural view of a prior art laser imaging device
  • FIG. 3 is a schematic structural view of a laser imaging apparatus of the present invention.
  • the present invention first provides an electrically conductive cleaning blade.
  • the conductive cleaning blade 8a is composed of a metal base knife 81 and a blade 82.
  • the blade 82 of the present invention is made of a conductive polyurethane material, and the polyurethane material is unsaturation.
  • a polyurethane conductive composition prepared by mixing a polyol with one or more polyisocyanates to form a polyurethane resin and then mixing with an ion conductive type donor.
  • the volume resistivity of the polyurethane squeegee having a thickness of from 1.0 to 1.00 ⁇ is from 10 5 to 10 9 ohm.cm.
  • the cleaning blade 8 By connecting the cleaning blade 8 to the power source, when the power is turned on, the photosensitive drum core can be charged as a conductor, and the residual potential after imaging can be cleared to achieve the effect of acting as a charging roller; Residual toner that can be used as an insulator to leave a pattern on the photosensitive drum Scrape off to achieve the function of cleaning the scraper.
  • the charging roller and the cleaning blade of the prior art can be combined into one, which can save the trouble of manufacturing the charging roller, thereby reducing pollution and saving material cost.
  • the polyol used includes a polymer polyol such as a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol, a polyester polyol, etc.;
  • the polyisocyanate is a polymer One or more of the polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI and a modified mixture thereof, the molar ratio of the NC0 to the hydroxyl group 0H of the polyol and the polyisocyanate is in the range of 0. Between 9 and 2. 0.
  • the polyurethane resin formed by crosslinking the polyol with one or more polyisocyanates is mixed with an ion conductive type donor in a ratio of 100: 5 to 20.
  • the ion conductive type injecting agent may be a metal anion or a cationic conductive material, and a nonionic conductive material, wherein the metal anion conductive material may be selected from the group consisting of a mercaptosulfonate, a sulfate, a phosphoric acid derivative, a higher fatty acid salt, a carboxylate, etc.
  • Metal cation conductive materials are selected from amine salts, quaternary ammonium salts, sulfonium amino acid salts, etc.
  • Non-ionic conductive materials are selected from polyethylene glycol esters or ethers, polyol fatty acid esters, fatty acid sterol amides, fatty amine ethoxylated ethers. Wait.
  • the present invention also provides a laser image forming apparatus comprising the above cleaning blade.
  • the present invention comprises: a container for accommodating toner, a powder hopper 1, a powder feeding roller 2 placed in the powder hopper 1, and a developing roller 3, and the outer surface of the developing roller 3 is provided with a touch
  • the powder discharging knives 4 are provided, before the developing roller 3, a photosensitive drum core 7 tangential thereto is provided, and the photosensitive drum core 7 is simultaneously tangential to the transfer roller 6, in front of the photosensitive drum core 7
  • the position is provided with an electrically conductive cleaning blade 8a.
  • the cleaning blade 8a can be in contact with the outer surface of the photosensitive drum core 7.
  • the conductive cleaning blade 8a is made of a conductive polyurethane material which is an unsaturated polyol and a polyisocyanate and an ion conductive type.
  • the agent is mixed to form a polyurethane conductive composition having a resistivity of 10 3 to 10 9 ohm.cm.
  • the cleaning blade 8a made of the above-mentioned conductive polyurethane material can save the processing material and reduce the material cost because the charging roller can be omitted, and at the same time, the cumbersome process and environmental pollution in the processing can be avoided by using the charging roller. There is no problem that the voltage consumption during operation due to breakage or uncleanness of the conductive coating of the charging roller may cause the bottom of the photosensitive drum to be insufficiently charged or discharged, which may affect the print quality.

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Cleaning In Electrography (AREA)

Abstract

There is provided a conductive cleaning drawing template (8a) comprising a metal dead knife (81) and a blade (82). The blade (82) is made of conductive polyurethane which is a conductive composition of ion conductive donor and polyurethane formed by crosslinking unsaturated polyol and one or more types of polyisocryanate. In addition, there is also provided a laser imaging device with the conductive cleaning drawing template (8a), which combines the charging roller (5) and the cleaning scraper (8) in the prior art, so as to avoid the trouble of producing the charging roller, and thus reduce pollution and cost.

Description

一种可导电清洁刮板及激光成像装置  Conductive cleaning blade and laser imaging device
【技术领域】 [Technical Field]
本发明涉及激光影像成型技术领域, 尤其涉及激光打印机、 激光传真 机、 激光复印机、 激光晒图仪等设备之硒鼓部分清洁刮板及含有该清洁刮 板的激光成像装置。  The present invention relates to the field of laser image forming technology, and in particular to a toner cartridge cleaning blade of a laser printer, a laser facsimile machine, a laser copier, a laser photographer, and the like, and a laser image forming apparatus including the same.
【背景技术】 【Background technique】
激光成像的工作原理是首先把电脑传来的打印信号转化为脉冲信号传 送到激光器, 由充电棍对感光鼓芯表面均匀充电, 激光器射出激光抵消鼓 芯上图像部位的电荷, 然后将磁辊上的碳粉通过静电原理吸附到鼓芯上, 再通过转印辊进行转印, 由于转印辊上所带的电压高于鼓芯上的电压, 使 鼓芯上的碳粉被拉到纸张上, 加温加压后使碳粉熔化渗入纸张的纤维中, 完成整个成像过程。 其成型结构如图 1所示, 包括送粉器 2、 显影辊 3、 出粉刀 4、 感光鼓芯 7、 充电辊 5、 清洁刮刀 8等, 一次影像完成后, 清洁 刮刀 8必须把感光鼓芯 7上之上一幅图案遗留下来的残余碳粉刮掉, 存入 废粉仓中。 然后充电辊 5再一次对感光鼓芯 7表面充电, 清除一次成像后 的残余电位, 然后才能进行第二次影像工作。 目前现有充电辊 5结构包括 以金属导电材料做基体的辊芯, 所述辊芯上包覆有导电粘合层, 导电粘合 层上设有具有一定厚度、 含有炭微粉的导电橡胶构成的橡胶弹性层, 导电 橡胶弹性层外表面覆盖有导电涂层。 上述充电辊在制造中, 工艺相对较为 复杂, 且严重污染环境。 同时, 充电辊导电涂层破损或不洁以及运作过程 中电压的消耗会引起感光鼓充、 放电不足, 造成底灰或对打印质量产生影 响。 清洁刮刀一般是在金属片材料上粘接一块透明的聚氨脂片材组合而 成, 采用聚氨脂材料主要是其具有较高的耐磨性能, 且不会伤及感光鼓, 而这种清洁刮刀由于其聚氨酯材料为绝缘材料, 不具有导电性能。 The working principle of laser imaging is to first convert the printed signal from the computer into a pulse signal and send it to the laser. The charging roller uniformly charges the surface of the photosensitive drum core. The laser emits laser light to cancel the charge on the image part of the drum core, and then the magnetic roller is placed on the magnetic roller. The toner is adsorbed onto the drum core by electrostatic principle and then transferred by the transfer roller. Since the voltage on the transfer roller is higher than the voltage on the drum core, the toner on the drum core is pulled onto the paper. After warming and pressing, the carbon powder is melted and penetrated into the fibers of the paper to complete the entire imaging process. The molding structure is as shown in FIG. 1, and includes a powder feeder 2, a developing roller 3, a powder discharging knife 4, a photosensitive drum core 7, a charging roller 5, a cleaning blade 8, and the like. After one image is completed, the cleaning blade 8 must have a photosensitive drum The residual toner left over from the pattern on the core 7 is scraped off and stored in the waste toner box. Then, the charging roller 5 charges the surface of the photosensitive drum core 7 again, and removes the residual potential after imaging once, and then performs the second image operation. At present, the structure of the existing charging roller 5 comprises a roller core made of a metal conductive material, the roller core is coated with a conductive adhesive layer, and the conductive adhesive layer is provided with a conductive rubber having a certain thickness and containing carbon micropowder. The rubber elastic layer, the outer surface of the conductive rubber elastic layer is covered with a conductive coating. In the above manufacturing, the charging roller is relatively complicated in process and seriously pollutes the environment. At the same time, the conductive coating of the charging roller is damaged or unclean and the operation process The consumption of the medium voltage causes the photosensitive drum to be charged and discharged insufficiently, causing the bottom ash or affecting the print quality. The cleaning blade is generally formed by bonding a transparent polyurethane sheet to a metal sheet material. The polyurethane material mainly has high abrasion resistance and does not damage the photosensitive drum. The cleaning blade does not have electrical conductivity because its polyurethane material is an insulating material.
【发明内容】 [Summary of the Invention]
本发明所要解决的技术问题是克服上述现有技术的缺陷, 提供一种可 导电的清洁刮板, 可取代现有充电辊和清洁刮刀, 既可以清洁感光鼓芯, 又可对感光鼓芯表面充电, 以降低制造成本。  The technical problem to be solved by the present invention is to overcome the above drawbacks of the prior art, and provide an electrically conductive cleaning blade which can replace the existing charging roller and the cleaning blade, and can clean the photosensitive drum core and the surface of the photosensitive drum core. Charging to reduce manufacturing costs.
本发明还提供了一种含有上述清洁刮板的激光成像装置。  The present invention also provides a laser imaging apparatus including the above-described cleaning blade.
为达到上述发明目的, 本发明提出以下的技术方案:  In order to achieve the above object, the present invention proposes the following technical solutions:
一种可导电清洁刮板, 由金属底刀和刀片组合而成, 其特征在于: 所 述刀片采用导电聚氨酯材料制成, 该聚氨酯材料为不饱和度的多元醇与一 种或一种以上多异氰酸酯产生交联反应形成聚氨酯树脂后再与离子导电 型给予剂混合制成的聚氨酯导电性组合物。  An electrically conductive cleaning blade, which is composed of a metal bottom knife and a blade, and is characterized in that: the blade is made of a conductive polyurethane material, and the polyurethane material is an unsaturated polyol and one or more The isocyanate is a polyurethane conductive composition produced by crosslinking reaction to form a polyurethane resin and then mixing with an ion conductive type donor.
优选地, 所述多元醇与一种或一种以上多异氰酸酯交联反应形成的聚 氨酯树脂与离子导电型给予剂混合配比为 100: 5〜20。  Preferably, the polyurethane resin formed by crosslinking the polyol with one or more polyisocyanates is mixed with an ion conductive type donor in a ratio of 100: 5 to 20.
优选地, 所述聚氨酯导电性组合物电阻率为 105〜109欧姆 /厘米。 优选地, 所述多元醇为聚醚型多元醇、 聚氧化丙烯醚多元醇、 聚四氢 呋喃多元醇、 聚已内酯多元醇或聚酯多元醇。 Preferably, the polyurethane conductive composition has a resistivity of 10 5 to 10 9 ohms/cm. Preferably, the polyol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol or a polyester polyol.
优选地, 所述多异氰酸酯为高分子聚合物 MDI、 甲苯二异氰酸酯 IDI、 六亚甲基二异氰酸酯 HDI及其改性混合物中的一种或多种。  Preferably, the polyisocyanate is one or more of a high molecular polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and a modified mixture thereof.
优选地, 所述离子导电型给予剂为: 金属阴、 阳离子导电材料, 非离 子导电材料。 Preferably, the ion conductive type administering agent is: metal anion, cationic conductive material, non-detached Sub-conductive material.
本发明还提供了一种激光成像装置, 包括粉仓、 送粉辊、 显影辊、 转 影辊和感光鼓芯, 其特征在于: 在所述感光鼓芯前面位置, 设有一可与感 光鼓芯外表面触接之可导电清洁刮板, 所述可导电清洁刮板由金属底刀和 可导电聚氨酯材料制成的刀片构成, 所述聚氨酯材料为不饱和度的多元醇 与一种或一种以上多异氰酸酯产生交联反应形成聚氨酯树脂后再与与离 子导电型给予剂混合制成的聚氨酯导电性组合物。  The present invention also provides a laser image forming apparatus comprising a powder silo, a powder feeding roller, a developing roller, a transfer roller and a photosensitive drum core, wherein: a photosensitive drum core is disposed at a position in front of the photosensitive drum core An electrically conductive cleaning blade that is in contact with the outer surface, the electrically conductive cleaning blade being composed of a metal base knife and a blade made of a conductive polyurethane material, the polyurethane material being an unsaturated polyol and one or one The above polyisocyanate is subjected to a crosslinking reaction to form a polyurethane resin, and then a polyurethane conductive composition prepared by mixing with an ion conductive type donor.
优选地, 所述多元醇与一种或一种以上多异氰酸酯交联反应形成聚氨 酯树脂与离子导电型给予剂混合配比为 100: 5〜20。  Preferably, the polyol is crosslinked with one or more polyisocyanates to form a polyurethane resin and an ion conductive type donor in a mixing ratio of 100: 5 to 20.
优选地, 所述聚氨酯导电性的组合物电阻率为 105〜109欧姆 /厘米。 优选地, 所述多元醇为聚醚型多元醇、 聚氧化丙烯醚多元醇、 聚四氢 呋喃多元醇、 聚已内酯多元醇或聚酯多元醇。 Preferably, the polyurethane conductive composition has a resistivity of from 10 5 to 10 9 ohms/cm. Preferably, the polyol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol or a polyester polyol.
优选地, 所述多异氰酸酯为高分子聚合物 MDI、 甲苯二异氰酸酯 IDI、 六亚甲基二异氰酸酯 HDI及其改性混合物中的一种或多种。  Preferably, the polyisocyanate is one or more of a high molecular polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and a modified mixture thereof.
优选地, 所述离子导电型给予剂为: 金属阴、 阳离子导电材料, 非离 子导电材料。 从以上技术方案可以看出, 本发明由于采用可导电的清洁刮板, 可将 现有技术中充电辊和清洁刮刀合二为一, 可省去充电辊制造上的麻烦, 减 少了污染, 节约了材料, 以全世界每年硒鼓使用的数量两亿五千万计算, 可节省两亿五千万个充电辊的材料成本和加工成本, 按平均每支充电辊 130克计算, 每年可减少 3250吨固体垃圾, 节约资金三十七亿五千万元, 而且这个数量每年按 15%递增。 【附图说明】 Preferably, the ion conductive type administering agent is: a metal anion, a cationic conductive material, and a nonionic conductive material. It can be seen from the above technical solution that the present invention can combine the charging roller and the cleaning blade of the prior art by using an electrically conductive cleaning blade, which can save the trouble of manufacturing the charging roller, reduce pollution, and save. The material, calculated by the number of toner cartridges used in the world every year, can save the material cost and processing cost of 250 million charging rollers, which can be reduced by 3,250 tons per year based on an average of 130 grams per charging roller. Solid waste, saving 3.75 billion yuan, and this number is increasing by 15% every year. [Description of the Drawings]
图 1为本发明清洁刮板结构示意图;  Figure 1 is a schematic view showing the structure of a cleaning blade of the present invention;
图 2为现有技术激光成像装置结构示意图;  2 is a schematic structural view of a prior art laser imaging device;
图 3为本发明激光成像装置结构示意图。  3 is a schematic structural view of a laser imaging apparatus of the present invention.
图中:  In the picture:
1一粉仓; 2—送粉辊;  1 a powder bin; 2 - powder feeding roller;
3—显影辊; 4一出粉刀;  3—developing roller; 4 a powder knife;
5—充电辊; 6—转影辊;  5—charging roller; 6—shadow roller;
7—感光鼓芯; 8—清洁刮刀:  7—photosensitive drum core; 8—cleaning scraper:
8a—清洁刮板; 81—底刀;  8a—cleaning scraper; 81—bottom knife;
82—刀片。  82—blade.
【具体实施方式】 【detailed description】
本发明首先提供了一种可导电清洁刮板。 如图 3所示, 所述可导电清 洁刮板 8a是由金属底刀 81和刀片 82组合而成, 本发明所述刀片 82是采 用可导电聚氨酯材料制成, 所述聚氨酯材料为不饱和度的多元醇与一种或 一种以上多异氰酸酯产生的交联反应形成聚氨酯树脂后, 再与离子导电型 给予剂混合制成的聚氨酯导电性组合物。 将上述组合物用公知的方法制成 1. 0〜5. 0匪厚度的聚氨酯刮板材, 其体积电阻率达到 105〜109欧姆.厘米。 通过将清洁刮板 8与电源连接, 在电源接通时, 可使其作为导体对感光鼓 芯进行充电, 清除一次成像后的残余电位, 便能达到充当充电辊的效果; 断电时, 其可作为绝缘体将感光鼓芯上之上一幅图案遗留下来的残余碳粉 刮掉, 实现清洁刮刀的功能。 这样, 可将现有技术中充电辊和清洁刮刀合 二为一, 可省去充电辊制造上的麻烦, 从而减少了污染, 节约了材料成本。 The present invention first provides an electrically conductive cleaning blade. As shown in FIG. 3, the conductive cleaning blade 8a is composed of a metal base knife 81 and a blade 82. The blade 82 of the present invention is made of a conductive polyurethane material, and the polyurethane material is unsaturation. A polyurethane conductive composition prepared by mixing a polyol with one or more polyisocyanates to form a polyurethane resin and then mixing with an ion conductive type donor. The volume resistivity of the polyurethane squeegee having a thickness of from 1.0 to 1.00 Å is from 10 5 to 10 9 ohm.cm. By connecting the cleaning blade 8 to the power source, when the power is turned on, the photosensitive drum core can be charged as a conductor, and the residual potential after imaging can be cleared to achieve the effect of acting as a charging roller; Residual toner that can be used as an insulator to leave a pattern on the photosensitive drum Scrape off to achieve the function of cleaning the scraper. In this way, the charging roller and the cleaning blade of the prior art can be combined into one, which can save the trouble of manufacturing the charging roller, thereby reducing pollution and saving material cost.
本发明中, 所用多元醇包括聚醚型多元醇、 聚氧化丙烯醚多元醇、 聚 四氢呋喃多元醇、 聚已内酯多元醇、 聚酯多元醇等聚合物多元醇; 所述多 异氰酸酯为高分子聚合物 MDI、 甲苯二异氰酸酯 IDI、 六亚甲基二异氰酸 酯 HDI及其改性混合物中的一种或多种, 多元醇与多异氰酸酯的基因 NC0 与羟基 0H的摩尔比 NC0/0H范围在 0. 9〜2. 0之间。  In the present invention, the polyol used includes a polymer polyol such as a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, a polycaprolactone polyol, a polyester polyol, etc.; the polyisocyanate is a polymer One or more of the polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI and a modified mixture thereof, the molar ratio of the NC0 to the hydroxyl group 0H of the polyol and the polyisocyanate is in the range of 0. Between 9 and 2. 0.
所述多元醇与一种或一种以上多异氰酸酯交联反应形成的聚氨酯树 脂与离子导电型给予剂混合配比为 100: 5〜20。  The polyurethane resin formed by crosslinking the polyol with one or more polyisocyanates is mixed with an ion conductive type donor in a ratio of 100: 5 to 20.
所述离子导电型给予剂可为金属阴、 阳离子导电材料, 非离子导电材 料, 其中金属阴离子导电材料可选用垸基磺酸盐、 硫酸盐、 磷酸衍生物、 高级脂肪酸盐、 羧酸盐等, 金属阳离子导电材料选用胺盐、 季铵盐、 垸基 氨基酸盐等, 非离子导电材料选用聚乙二醇酯或醚类, 多元醇脂肪酸酯、 脂肪酸垸醇酰胺、 脂肪胺乙氧基醚等。  The ion conductive type injecting agent may be a metal anion or a cationic conductive material, and a nonionic conductive material, wherein the metal anion conductive material may be selected from the group consisting of a mercaptosulfonate, a sulfate, a phosphoric acid derivative, a higher fatty acid salt, a carboxylate, etc. Metal cation conductive materials are selected from amine salts, quaternary ammonium salts, sulfonium amino acid salts, etc. Non-ionic conductive materials are selected from polyethylene glycol esters or ethers, polyol fatty acid esters, fatty acid sterol amides, fatty amine ethoxylated ethers. Wait.
本发明还提供了一种含有上述清洁刮板之激光成像装置。如图 2所示, 本发明包括: 可容纳碳粉的容器一一粉仓 1、 置于粉仓 1内之送粉辊 2和 显影辊 3, 所述显影辊 3外表面设有与之触接的出粉刀 4, 在所述显影辊 3 之前方, 设有一与之相切的感光鼓芯 7, 该感光鼓芯 7同时与转影辊 6相 切, 在所述感光鼓芯 7前面位置, 设有一可导电清洁刮板 8a, 所述清洁刮 板 8a可与感光鼓芯 7外表面触接, 充电后, 即可代替现有技术中的充电 辊 , 作为导体对感光鼓芯 7表面充电, 从而将感光鼓芯 7上之上一幅图 案遗留下来的残余碳粉刮掉。 所述可导电清洁刮板 8a采用可导电聚氨酯 材料制成, 该聚氨酯材料为不饱和度的多元醇与多异氰酸酯及离子导电型 给予剂混合制成聚氨酯导电性的组合物, 该聚氨酯导电性的组合物电阻率 为 103〜109欧姆.厘米。 The present invention also provides a laser image forming apparatus comprising the above cleaning blade. As shown in FIG. 2, the present invention comprises: a container for accommodating toner, a powder hopper 1, a powder feeding roller 2 placed in the powder hopper 1, and a developing roller 3, and the outer surface of the developing roller 3 is provided with a touch The powder discharging knives 4 are provided, before the developing roller 3, a photosensitive drum core 7 tangential thereto is provided, and the photosensitive drum core 7 is simultaneously tangential to the transfer roller 6, in front of the photosensitive drum core 7 The position is provided with an electrically conductive cleaning blade 8a. The cleaning blade 8a can be in contact with the outer surface of the photosensitive drum core 7. After charging, it can replace the charging roller of the prior art as a conductor to the surface of the photosensitive drum core 7. Charging, thereby scraping off residual toner left over from the pattern on the photosensitive drum core 7. The conductive cleaning blade 8a is made of a conductive polyurethane material which is an unsaturated polyol and a polyisocyanate and an ion conductive type. The agent is mixed to form a polyurethane conductive composition having a resistivity of 10 3 to 10 9 ohm.cm.
采用上述可导电聚氨酯材料做成的清洁刮板 8a, 由于可省去充电辊, 故而可大大节约加工材料, 降低材料成本, 同时, 可避免采用充电辊而带 来加工中的繁琐工艺和环境污染问题, 也不存在由于充电辊导电涂层破损 或不洁导致运作过程中电压的消耗会引起感光鼓芯充、 放电不足而造成底 灰或对打印质量产生的影响。  The cleaning blade 8a made of the above-mentioned conductive polyurethane material can save the processing material and reduce the material cost because the charging roller can be omitted, and at the same time, the cumbersome process and environmental pollution in the processing can be avoided by using the charging roller. There is no problem that the voltage consumption during operation due to breakage or uncleanness of the conductive coating of the charging roller may cause the bottom of the photosensitive drum to be insufficiently charged or discharged, which may affect the print quality.
以上所述实施例仅表达了本发明的一种实施方式, 其描述较为具体和 详细, 但并不能因此而理解为对本发明专利范围的限制。 应当指出的是, 对于本领域的普通技术人员来说, 在不脱离本发明构思的前提下, 还可以 做出若干变形和改进, 这些都属于本发明的保护范围。 因此, 本发明专利 的保护范围应以所附权利要求为准。  The above-mentioned embodiments are merely illustrative of one embodiment of the present invention, and the description thereof is more specific and detailed, but is not to be construed as limiting the scope of the invention. It should be noted that a number of variations and modifications may be made by those skilled in the art without departing from the spirit and scope of the invention. Therefore, the scope of the invention should be determined by the appended claims.

Claims

权利要求书 Claim
1、 一种可导电清洁刮板, 由金属底刀和刀片组合而成, 其特征在于: 所述刀片采用导电聚氨酯材料制成, 该聚氨酯材料为不饱和度的多元醇与 一种或一种以上多异氰酸酯产生交联反应形成聚氨酯树脂后再与离子导 电型给予剂混合制成的聚氨酯导电性组合物。  1. An electrically conductive cleaning blade, which is composed of a metal base knife and a blade, wherein: the blade is made of a conductive polyurethane material, the polyurethane material is an unsaturated polyol and one or a kind The above polyisocyanate is produced by a crosslinking reaction to form a polyurethane resin, and then mixed with an ion conductive type donor to prepare a polyurethane conductive composition.
2、 根据权利要求 1 所述的可导电清洁刮板, 其特征在于: 所述多元 醇与一种或一种以上多异氰酸酯交联反应形成的聚氨酯树脂与离子导电 型给予剂混合配比为 100: 5〜20。  2. The conductive cleaning blade according to claim 1, wherein: the polyurethane resin formed by crosslinking the polyol with one or more polyisocyanates is mixed with an ion conductive type donor. : 5~20.
3、 根据权利要求 1 所述的可导电清洁刮板, 其特征在于: 所述聚氨 酯导电性组合物电阻率为 105〜109欧姆 /厘米。 3. The conductive cleaning blade according to claim 1, wherein: the polyurethane conductive composition has a resistivity of 10 5 to 10 9 ohms/cm.
4、 根据权利要求 1〜3任一项所述的可导电清洁刮板, 其特征在于: 所述多元醇为聚醚型多元醇、 聚氧化丙烯醚多元醇、 聚四氢呋喃多元醇、 聚已内酯多元醇或聚酯多元醇。  The conductive cleaning blade according to any one of claims 1 to 3, wherein the polyhydric alcohol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, or a poly Ester polyol or polyester polyol.
5、 根据权利要求 1〜3任一项所述的可导电清洁刮板, 其特征在于: 所述多异氰酸酯为高分子聚合物 MDI、 甲苯二异氰酸酯 IDI、 六亚甲基二 异氰酸酯 HDI及其改性混合物中的一种或多种。  The conductive cleaning blade according to any one of claims 1 to 3, wherein the polyisocyanate is a polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and the like. One or more of the sexual mixtures.
6、 根据权利要求 1〜3任一项所述的可导电清洁刮板, 其特征在于: 所述离子导电型给予剂为: 金属阴、 阳离子导电材料, 非离子导电材料。  The conductive cleaning blade according to any one of claims 1 to 3, wherein the ion conductive type donor is: a metal anion, a cationic conductive material, and a nonionic conductive material.
7、 一种激光成像装置, 包括粉仓、 送粉辊、 显影辊、 转影辊和感光 鼓芯, 其特征在于: 在所述感光鼓芯前面位置, 设有一可与感光鼓芯外表 面触接之可导电清洁刮板, 所述可导电清洁刮板由金属底刀和可导电聚氨 酯材料制成的刀片构成, 所述聚氨酯材料为不饱和度的多元醇与一种或一 种以上多异氰酸酯产生交联反应形成聚氨酯树脂后再与与离子导电型给 予剂混合制成的聚氨酯导电性组合物。 7. A laser image forming apparatus comprising: a powder silo, a powder feeding roller, a developing roller, a transfer roller and a photosensitive drum core, wherein: a position in front of the photosensitive drum core is provided to be in contact with an outer surface of the photosensitive drum core An electrically conductive cleaning blade is formed, the conductive cleaning blade being composed of a metal base knife and a blade made of a conductive polyurethane material, the polyurethane material being an unsaturated polyol and one or more polyisocyanates Producing a cross-linking reaction to form a polyurethane resin and then giving it with an ion-conducting type A polyurethane conductive composition prepared by mixing the prepolymers.
8、 根据权利要求 Ί 所述的激光成像装置, 其特征在于: 所述多元醇 与一种或一种以上多异氰酸酯交联反应形成聚氨酯树脂与离子导电型给 予剂混合配比为 100: 5〜20。  8. The laser image forming apparatus according to claim ,, wherein: the polyol is crosslinked with one or more polyisocyanates to form a polyurethane resin and an ion conductive type donor, and the mixing ratio is 100: 5~ 20.
9、 根据权利要求 Ί 所述的激光成像装置, 其特征在于: 所述聚氨酯 导电性的组合物电阻率为 105〜109欧姆 /厘米。 9. The laser image forming apparatus according to claim 1, wherein the polyurethane conductive composition has a resistivity of from 10 5 to 10 9 ohms/cm.
10、 根据权利要求 7〜9 任一项所述的激光成像装置, 其特征在于: 所述多元醇为聚醚型多元醇、 聚氧化丙烯醚多元醇、 聚四氢呋喃多元醇、 聚已内酯多元醇或聚酯多元醇。  The laser image forming apparatus according to any one of claims 7 to 9, wherein the polyhydric alcohol is a polyether polyol, a polyoxypropylene ether polyol, a polytetrahydrofuran polyol, or a polycaprolactone polyol. Alcohol or polyester polyol.
11、 根据权利要求 7〜9 任一项所述的激光成像装置, 其特征在于: 所述多异氰酸酯为高分子聚合物 MDI、 甲苯二异氰酸酯 IDI、 六亚甲基二 异氰酸酯 HDI及其改性混合物中的一种或多种。  The laser image forming apparatus according to any one of claims 7 to 9, wherein the polyisocyanate is a polymer MDI, toluene diisocyanate IDI, hexamethylene diisocyanate HDI, and a modified mixture thereof. One or more of them.
12、 根据权利要求 7〜9任一项所述的可导电清洁刮板, 其特征在于: 所述离子导电型给予剂为: 金属阴、 阳离子导电材料, 非离子导电材料。  The conductive cleaning blade according to any one of claims 7 to 9, wherein the ion conductive type donor is: a metal anion, a cationic conductive material, and a nonionic conductive material.
PCT/CN2009/071039 2008-04-03 2009-03-27 A conductive cleaning drawing template and a laser imaging device WO2009121283A1 (en)

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CN101261488A (en) * 2008-04-03 2008-09-10 周小平 Conductive cleaning blade and laser image forming apparatus
CN102591169A (en) * 2011-01-13 2012-07-18 李华容 Developing unit based on display module and electronic photograph imaging device
CN105372976A (en) * 2015-12-18 2016-03-02 珠海市拓佳科技有限公司 Selenium drum without charging roller
CN114815556B (en) * 2022-04-13 2023-05-16 珠海市新意造科技有限公司 Photosensitive drum core charger

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JP2003307897A (en) * 2001-10-16 2003-10-31 Hokushin Ind Inc Conductive blade
JP2005010809A (en) * 2004-09-17 2005-01-13 Ricoh Co Ltd Image forming apparatus
CN101261488A (en) * 2008-04-03 2008-09-10 周小平 Conductive cleaning blade and laser image forming apparatus

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JPS5748766A (en) * 1980-09-08 1982-03-20 Bando Chem Ind Ltd Blade for removing static electricity
JP2003307897A (en) * 2001-10-16 2003-10-31 Hokushin Ind Inc Conductive blade
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CN101261488A (en) * 2008-04-03 2008-09-10 周小平 Conductive cleaning blade and laser image forming apparatus

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