WO2009117479A2 - Reduction of aldehydes in amines - Google Patents
Reduction of aldehydes in amines Download PDFInfo
- Publication number
- WO2009117479A2 WO2009117479A2 PCT/US2009/037499 US2009037499W WO2009117479A2 WO 2009117479 A2 WO2009117479 A2 WO 2009117479A2 US 2009037499 W US2009037499 W US 2009037499W WO 2009117479 A2 WO2009117479 A2 WO 2009117479A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tertiary amine
- formaldehyde
- amine catalyst
- tertiary
- primary
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1833—Catalysts containing secondary or tertiary amines or salts thereof having ether, acetal, or orthoester groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/18—Catalysts containing secondary or tertiary amines or salts thereof
- C08G18/1825—Catalysts containing secondary or tertiary amines or salts thereof having hydroxy or primary amino groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2290/00—Compositions for creating anti-fogging
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
Claims
Priority Applications (7)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/919,817 US20110009512A1 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
EP09721708.7A EP2257592A4 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
CN200980109711XA CN101977977A (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
CA2717573A CA2717573A1 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
MX2010010101A MX2010010101A (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines. |
JP2011500919A JP5583112B2 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines. |
AU2009225611A AU2009225611A1 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US3816708P | 2008-03-20 | 2008-03-20 | |
US61/038,167 | 2008-03-20 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009117479A2 true WO2009117479A2 (en) | 2009-09-24 |
WO2009117479A3 WO2009117479A3 (en) | 2010-03-18 |
Family
ID=41091512
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2009/037499 WO2009117479A2 (en) | 2008-03-20 | 2009-03-18 | Reduction of aldehydes in amines |
Country Status (9)
Country | Link |
---|---|
US (1) | US20110009512A1 (en) |
EP (1) | EP2257592A4 (en) |
JP (1) | JP5583112B2 (en) |
CN (2) | CN102924675B (en) |
AU (1) | AU2009225611A1 (en) |
CA (1) | CA2717573A1 (en) |
MX (1) | MX2010010101A (en) |
TW (1) | TWI438214B (en) |
WO (1) | WO2009117479A2 (en) |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012072441A1 (en) * | 2010-11-29 | 2012-06-07 | Huntsman Corporation Hungary Zrt. | Blowing catalyst |
US20120184639A1 (en) * | 2009-09-30 | 2012-07-19 | Bayer Materialscience Ag | Method for lowering emissions of a polyurethane foam |
DE102012206193A1 (en) | 2012-04-16 | 2013-10-17 | Evonik Industries Ag | Guanidinruppen containing compounds and their use as additives in the production of polyurethane systems |
WO2014026802A1 (en) | 2012-08-16 | 2014-02-20 | Huntsman Petrochemical Llc | A composition |
DE102013223441A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of pentaethylenehexamine in the preparation of polyurethane systems |
DE102013223444A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of guanidine reaction products in the preparation of polyurethane systems |
WO2016166100A1 (en) * | 2015-04-13 | 2016-10-20 | Ask Chemicals Gmbh | Coated granular material |
CN109312042A (en) * | 2016-06-14 | 2019-02-05 | 株式会社普利司通 | The manufacturing method of polyurethane aldehyde scavenger, polyurethane and polyurethane |
EP3459983A1 (en) | 2017-09-25 | 2019-03-27 | Evonik Degussa GmbH | Manufacture of polyurethane systems |
US10472456B2 (en) | 2014-07-10 | 2019-11-12 | Huntsman Petrochemical Llc | Composition to reduce the amount of aldehydes emitted from polyurethane foams |
WO2021013607A1 (en) | 2019-07-24 | 2021-01-28 | Evonik Operations Gmbh | Preparation of polyurethane systems |
US11548997B2 (en) | 2016-02-05 | 2023-01-10 | Huntsman International Llc | Method for the reduction of aldehyde emission in polyurethane foam |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9273175B2 (en) | 2011-10-03 | 2016-03-01 | Air Products And Chemicals, Inc. | Tertiary amine composition and method for making the composition |
JP6556137B2 (en) * | 2013-08-26 | 2019-08-07 | ハンツマン ペトロケミカル エルエルシーHuntsman Petrochemical LLC | Reduction of aldehydes in amine catalysts. |
JP6509236B2 (en) | 2013-10-01 | 2019-05-08 | ハンツマン ペトロケミカル エルエルシーHuntsman Petrochemical LLC | Aldehyde reduction in amine catalysts |
CN107148434A (en) * | 2014-09-12 | 2017-09-08 | 赢创德固赛有限公司 | With low emission polyurethane foam made from isocyanate-reactive amine crystal |
CN107108829B (en) * | 2014-12-31 | 2020-05-12 | 亨斯迈石油化学有限责任公司 | Aldehyde reduction in amine catalysts |
US10696777B2 (en) | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
CA2989370C (en) | 2015-06-16 | 2022-11-01 | Evonik Degussa Gmbh | Aldehyde scavengers for polyurethane foams |
WO2018210217A1 (en) * | 2017-05-15 | 2018-11-22 | Rhodia Operations | Method for Scavenging Airborne Formaldehyde |
CN112292412A (en) * | 2018-06-26 | 2021-01-29 | 株式会社普利司通 | Polyol composition for producing low-odor polyurethane foam |
CN114031739B (en) * | 2021-11-24 | 2023-03-28 | 杨骏 | Aldehyde compound foamed environment-friendly polyurethane foam plastic and manufacturing method and application thereof |
Family Cites Families (23)
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US3330782A (en) * | 1963-11-12 | 1967-07-11 | Union Carbide Corp | Beta-(n, n-dimethylamino)alkyl ethers as catalysts for isocyanate reactions |
US4194069A (en) * | 1978-10-16 | 1980-03-18 | Texaco Development Corporation | Urea derivative and use as polyurethane catalyst |
US4585804A (en) * | 1981-03-25 | 1986-04-29 | The Dow Chemical Company | Rigid foam with improved "K" factor by reacting a polyol, a polyisocyanate and at least one compound having at least one primary aliphatic amine group |
US4644015A (en) * | 1986-05-08 | 1987-02-17 | Ashland Oil, Inc. | Stable polyol-melamine blend for use in the manufacture of fire retardant flexible urethane foam |
US5006569A (en) * | 1989-08-16 | 1991-04-09 | Pmc, Inc. | Density reduction in flexible polyurethane foams |
US5086082A (en) * | 1989-09-27 | 1992-02-04 | Pmc, Inc. | Ignition resistant polyurethane foams with melamine |
US5700846A (en) * | 1994-06-15 | 1997-12-23 | Huntsman Petrochemical Corporation | Polyurea foam made from a partially aminated polyether polyamine |
CN1197890C (en) * | 1999-12-17 | 2005-04-20 | 花王株式会社 | Process for producing polyurethane |
JP3860694B2 (en) * | 1999-12-17 | 2006-12-20 | 花王株式会社 | Production method of polyurethane foam |
US6540936B1 (en) * | 2000-06-19 | 2003-04-01 | Toagosei Co., Ltd. | Aldehyde gas absorbent and process for absorbing aldehyde gas |
US6699916B2 (en) * | 2001-10-29 | 2004-03-02 | Dow Global Technologies Inc. | Rigid hybrid polyurethane foams |
HUP0402499A3 (en) * | 2001-12-21 | 2006-06-28 | Dow Global Technologies Inc Mi | Tertiary amine modified polyols and polyurethane products made therefrom |
US7169268B2 (en) * | 2002-06-26 | 2007-01-30 | Huntsman Petrochemical Corporation | Color stabilization of amines |
US20040153040A1 (en) * | 2003-02-05 | 2004-08-05 | Lucie Martineau | Multi-layer synthetic dressing with cooling characteristics |
US6858654B1 (en) * | 2003-10-27 | 2005-02-22 | Air Products And Chemicals, Inc. | Catalyst blends for producing low thermal desorption polyurethane foams |
JP3959092B2 (en) * | 2004-12-27 | 2007-08-15 | 住化バイエルウレタン株式会社 | Polyurethane molded product and method for producing the same |
JP4948853B2 (en) * | 2006-03-06 | 2012-06-06 | 花王株式会社 | Manufacturing method of rigid polyurethane foam |
JP4724149B2 (en) * | 2007-05-09 | 2011-07-13 | 住化バイエルウレタン株式会社 | Method for producing polyurethane resin and polyurethane molded product thereof |
US8563676B2 (en) * | 2007-06-19 | 2013-10-22 | Huntsman Petrochemical Llc | Reactive amine catalysts for polyurethane foam |
US20090227758A1 (en) * | 2008-03-07 | 2009-09-10 | Yoshiaki Miyazaki | Polyurethanes having low levels of aldehyde emissions |
US9243103B2 (en) * | 2008-06-25 | 2016-01-26 | Inoac Corporation | Polyurethane foam for flame-laminating |
DE102008030763A1 (en) * | 2008-06-28 | 2009-12-31 | Bayer Materialscience Ag | Process for reducing emissions of a polyurethane foam |
MX2010005069A (en) * | 2009-05-27 | 2010-11-26 | Bayer Materialscience Ag | Method for manufacturing polyurethane soft foam material with low emissions. |
-
2009
- 2009-03-18 US US12/919,817 patent/US20110009512A1/en not_active Abandoned
- 2009-03-18 CA CA2717573A patent/CA2717573A1/en not_active Abandoned
- 2009-03-18 EP EP09721708.7A patent/EP2257592A4/en not_active Ceased
- 2009-03-18 MX MX2010010101A patent/MX2010010101A/en active IP Right Grant
- 2009-03-18 JP JP2011500919A patent/JP5583112B2/en active Active
- 2009-03-18 CN CN201210395555.1A patent/CN102924675B/en active Active
- 2009-03-18 AU AU2009225611A patent/AU2009225611A1/en not_active Abandoned
- 2009-03-18 CN CN200980109711XA patent/CN101977977A/en active Pending
- 2009-03-18 WO PCT/US2009/037499 patent/WO2009117479A2/en active Application Filing
- 2009-03-20 TW TW098109229A patent/TWI438214B/en not_active IP Right Cessation
Non-Patent Citations (1)
Title |
---|
See references of EP2257592A4 * |
Cited By (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120184639A1 (en) * | 2009-09-30 | 2012-07-19 | Bayer Materialscience Ag | Method for lowering emissions of a polyurethane foam |
US9382397B2 (en) | 2010-11-29 | 2016-07-05 | Huntsman Corporation Hungary ZRt | Blowing catalyst |
JP2013544933A (en) * | 2010-11-29 | 2013-12-19 | ハンツマン・コーポレーション・ハンガリー・ゼーエルテー | Foam catalyst |
WO2012072441A1 (en) * | 2010-11-29 | 2012-06-07 | Huntsman Corporation Hungary Zrt. | Blowing catalyst |
DE102012206193A1 (en) | 2012-04-16 | 2013-10-17 | Evonik Industries Ag | Guanidinruppen containing compounds and their use as additives in the production of polyurethane systems |
WO2013156237A2 (en) | 2012-04-16 | 2013-10-24 | Evonik Industries Ag | Compounds having guanidine groups and use thereof as additives in the production of polyurethane systems |
WO2013156237A3 (en) * | 2012-04-16 | 2014-01-23 | Evonik Industries Ag | Compounds having guanidine groups and use thereof as additives in the production of polyurethane systems |
WO2014026802A1 (en) | 2012-08-16 | 2014-02-20 | Huntsman Petrochemical Llc | A composition |
US10308754B2 (en) | 2012-08-16 | 2019-06-04 | Huntsman Petrochemical Llc | Composition |
EP2703421A1 (en) * | 2012-08-28 | 2014-03-05 | Huntsman Petrochemical LLC | A composition for making foams with reduced aldehyde emission |
US10100148B2 (en) | 2013-11-18 | 2018-10-16 | Evonik Degussa Gmbh | Use of guanidine reaction products in the production of polyurethane systems |
WO2015071065A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of pentaethylene hexamine in the production of polyurethane systems |
WO2015071063A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of guanidine reaction products in the production of polyurethane systems |
DE102013223441A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of pentaethylenehexamine in the preparation of polyurethane systems |
DE102013223444A1 (en) | 2013-11-18 | 2015-05-21 | Evonik Industries Ag | Use of guanidine reaction products in the preparation of polyurethane systems |
US10472456B2 (en) | 2014-07-10 | 2019-11-12 | Huntsman Petrochemical Llc | Composition to reduce the amount of aldehydes emitted from polyurethane foams |
WO2016166100A1 (en) * | 2015-04-13 | 2016-10-20 | Ask Chemicals Gmbh | Coated granular material |
US10947410B2 (en) | 2015-04-13 | 2021-03-16 | Ask Chemicals Gmbh | Coated granular material |
US11548997B2 (en) | 2016-02-05 | 2023-01-10 | Huntsman International Llc | Method for the reduction of aldehyde emission in polyurethane foam |
CN109312042A (en) * | 2016-06-14 | 2019-02-05 | 株式会社普利司通 | The manufacturing method of polyurethane aldehyde scavenger, polyurethane and polyurethane |
EP3470445A4 (en) * | 2016-06-14 | 2019-05-15 | Bridgestone Corporation | Aldehyde scavenger for polyurethanes, polyurethane and method for producing polyurethane |
EP3459983A1 (en) | 2017-09-25 | 2019-03-27 | Evonik Degussa GmbH | Manufacture of polyurethane systems |
US10995174B2 (en) | 2017-09-25 | 2021-05-04 | Evonik Operations Gmbh | Production of polyurethane systems |
WO2021013607A1 (en) | 2019-07-24 | 2021-01-28 | Evonik Operations Gmbh | Preparation of polyurethane systems |
Also Published As
Publication number | Publication date |
---|---|
TW201011051A (en) | 2010-03-16 |
JP5583112B2 (en) | 2014-09-03 |
CN102924675A (en) | 2013-02-13 |
WO2009117479A3 (en) | 2010-03-18 |
CN101977977A (en) | 2011-02-16 |
JP2011515540A (en) | 2011-05-19 |
TWI438214B (en) | 2014-05-21 |
CN102924675B (en) | 2015-07-29 |
EP2257592A4 (en) | 2013-06-05 |
AU2009225611A1 (en) | 2009-09-24 |
MX2010010101A (en) | 2011-03-03 |
US20110009512A1 (en) | 2011-01-13 |
EP2257592A2 (en) | 2010-12-08 |
CA2717573A1 (en) | 2009-09-24 |
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