WO2009111711A3 - Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins - Google Patents

Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins Download PDF

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Publication number
WO2009111711A3
WO2009111711A3 PCT/US2009/036353 US2009036353W WO2009111711A3 WO 2009111711 A3 WO2009111711 A3 WO 2009111711A3 US 2009036353 W US2009036353 W US 2009036353W WO 2009111711 A3 WO2009111711 A3 WO 2009111711A3
Authority
WO
WIPO (PCT)
Prior art keywords
particularly defined
hds
selective hydrodesulfurization
hydrodesulfurization
fractions
Prior art date
Application number
PCT/US2009/036353
Other languages
French (fr)
Other versions
WO2009111711A2 (en
Inventor
Opinder Kishan Bhan
Original Assignee
Shell Oil Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/043,841 external-priority patent/US20090223864A1/en
Priority claimed from US12/043,847 external-priority patent/US20090223865A1/en
Priority claimed from US12/398,009 external-priority patent/US20090223867A1/en
Priority claimed from US12/397,980 external-priority patent/US20090223866A1/en
Priority claimed from US12/398,022 external-priority patent/US20090223868A1/en
Application filed by Shell Oil Company filed Critical Shell Oil Company
Publication of WO2009111711A2 publication Critical patent/WO2009111711A2/en
Publication of WO2009111711A3 publication Critical patent/WO2009111711A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/882—Molybdenum and cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/12—Silica and alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0203—Impregnation the impregnation liquid containing organic compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A process for selective hydrodesulfurization of a sulfur and olef in-containing hydrocarbon feedstock boiling in the naphtha or gasoline boiling range utilizing a particularly defined high activity hydrodesulfurization (HDS) catalyst composition comprising a cobalt component, a molybdenum component and little or no phosphorus, prepared on a special alumina support containing a low concentration of silica and having a high surface area of at least 280 m2/g. In another aspect the process involves separating the feedstock into a light and a heavy fraction, followed by selectively hydrodesulfurizing the heavy fraction using a particularly defined high activity HDS catalyst and hydrodesulfurizing the light fraction with a particularly defined high selectivity HDS catalyst. The process also includes performing the separation into fractions and the selective hydrodesulfurization of the fractions in a distillation column reactor utilizing different particularly defined HDS catalysts.
PCT/US2009/036353 2008-03-06 2009-03-06 Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins WO2009111711A2 (en)

Applications Claiming Priority (16)

Application Number Priority Date Filing Date Title
US12/043,847 2008-03-06
US12/043,841 US20090223864A1 (en) 2008-03-06 2008-03-06 Process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US12/043,841 2008-03-06
US12/043,847 US20090223865A1 (en) 2008-03-06 2008-03-06 Catalyst and process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US5127808P 2008-05-07 2008-05-07
US5129408P 2008-05-07 2008-05-07
US5130008P 2008-05-07 2008-05-07
US61/051,294 2008-05-07
US61/051,300 2008-05-07
US61/051,278 2008-05-07
US12/398,009 US20090223867A1 (en) 2008-03-06 2009-03-04 Catalyst and process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US12/397,980 US20090223866A1 (en) 2008-03-06 2009-03-04 Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins
US12/398,022 US20090223868A1 (en) 2008-03-06 2009-03-04 Catalyst and process for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US12/398,022 2009-03-04
US12/397,980 2009-03-04
US12/398,009 2009-03-04

Publications (2)

Publication Number Publication Date
WO2009111711A2 WO2009111711A2 (en) 2009-09-11
WO2009111711A3 true WO2009111711A3 (en) 2009-11-26

Family

ID=41056669

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/036353 WO2009111711A2 (en) 2008-03-06 2009-03-06 Process for the selective hydrodesulfurization of a gasoline feedstock containing high levels of olefins

Country Status (1)

Country Link
WO (1) WO2009111711A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103386327B (en) * 2012-05-10 2015-09-23 中国石油化工股份有限公司 A kind of catalyst for selectively hydrodesulfurizing and Synthesis and applications thereof
CN104588055B (en) * 2014-12-18 2017-04-19 东北石油大学 Method for preparing high-activity oil hydrodesulfurization catalyst under mild conditions
CN112371141B (en) * 2020-12-10 2022-05-13 福州大学 Catalytic gasoline hydrodesulfurization catalyst and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030183556A1 (en) * 2002-04-02 2003-10-02 Halbert Thomas R. Selective hydrodesulfurization of naphtha streams
US20050109674A1 (en) * 2003-11-20 2005-05-26 Advanced Refining Technologies Llc Hydroconversion catalysts and methods of making and using same
US20060237345A1 (en) * 2005-04-26 2006-10-26 Bhan Opinder K Method for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock
US20070084753A1 (en) * 2004-06-07 2007-04-19 Nippon Oil Corporation Hydrogenation catalyst for hydrocarbon oil and process for hydrogenation using the catalyst

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030183556A1 (en) * 2002-04-02 2003-10-02 Halbert Thomas R. Selective hydrodesulfurization of naphtha streams
US20050109674A1 (en) * 2003-11-20 2005-05-26 Advanced Refining Technologies Llc Hydroconversion catalysts and methods of making and using same
US20070084753A1 (en) * 2004-06-07 2007-04-19 Nippon Oil Corporation Hydrogenation catalyst for hydrocarbon oil and process for hydrogenation using the catalyst
US20060237345A1 (en) * 2005-04-26 2006-10-26 Bhan Opinder K Method for the selective hydrodesulfurization of an olefin containing hydrocarbon feedstock

Also Published As

Publication number Publication date
WO2009111711A2 (en) 2009-09-11

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