WO2009085957A1 - Universal synthetic gasoline fuel conditioner additive, method and product-by-process - Google Patents

Universal synthetic gasoline fuel conditioner additive, method and product-by-process Download PDF

Info

Publication number
WO2009085957A1
WO2009085957A1 PCT/US2008/087433 US2008087433W WO2009085957A1 WO 2009085957 A1 WO2009085957 A1 WO 2009085957A1 US 2008087433 W US2008087433 W US 2008087433W WO 2009085957 A1 WO2009085957 A1 WO 2009085957A1
Authority
WO
WIPO (PCT)
Prior art keywords
blend
weight
percent
primary
producing
Prior art date
Application number
PCT/US2008/087433
Other languages
French (fr)
Inventor
Ronald J. Sloan
Original Assignee
Bestline International Research, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from PCT/US2007/088252 external-priority patent/WO2009078882A1/en
Application filed by Bestline International Research, Inc. filed Critical Bestline International Research, Inc.
Priority to US12/747,230 priority Critical patent/US7931704B2/en
Priority to EP08867084A priority patent/EP2242821A1/en
Priority to CA2710403A priority patent/CA2710403C/en
Publication of WO2009085957A1 publication Critical patent/WO2009085957A1/en
Priority to US13/093,223 priority patent/US8268022B2/en
Priority to US13/309,648 priority patent/US8415280B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M111/00Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
    • C10M111/04Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential at least one of them being a macromolecular organic compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/08Use of additives to fuels or fires for particular purposes for improving lubricity; for reducing wear
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M141/00Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential
    • C10M141/08Lubricating compositions characterised by the additive being a mixture of two or more compounds covered by more than one of the main groups C10M125/00 - C10M139/00, each of these compounds being essential at least one of them being an organic sulfur-, selenium- or tellurium-containing compound
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/042Mixtures of base-materials and additives the additives being compounds of unknown or incompletely defined constitution only
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04Mixtures of base-materials and additives
    • C10M169/045Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1616Hydrocarbons fractions, e.g. lubricants, solvents, naphta, bitumen, tars, terpentine
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/20Organic compounds containing halogen
    • C10L1/206Organic compounds containing halogen macromolecular compounds
    • C10L1/209Organic compounds containing halogen macromolecular compounds halogenated waxes or paraffines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/24Organic compounds containing sulfur, selenium and/or tellurium
    • C10L1/2431Organic compounds containing sulfur, selenium and/or tellurium sulfur bond to oxygen, e.g. sulfones, sulfoxides
    • C10L1/2437Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2300/00Mixture of two or more additives covered by the same group of C10L1/00 - C10L1/308
    • C10L2300/20Mixture of two components
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/02Well-defined aliphatic compounds
    • C10M2203/022Well-defined aliphatic compounds saturated
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/1006Petroleum or coal fractions, e.g. tars, solvents, bitumen used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • C10M2203/1025Aliphatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • C10M2203/1045Aromatic fractions used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/028Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms
    • C10M2205/0285Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers containing aliphatic monomers having more than four carbon atoms used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/08Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2211/00Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2211/08Halogenated waxes
    • C10M2211/083Halogenated waxes used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06Perfluoro polymers
    • C10M2213/062Polytetrafluoroethylene [PTFE]
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2213/00Organic macromolecular compounds containing halogen as ingredients in lubricant compositions
    • C10M2213/06Perfluoro polymers
    • C10M2213/062Polytetrafluoroethylene [PTFE]
    • C10M2213/0623Polytetrafluoroethylene [PTFE] used as base material
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046Overbasedsulfonic acid salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01Physico-chemical properties
    • C10N2020/02Viscosity; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02Pour-point; Viscosity index
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/34Fragrance or deodorizing properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/60Electro rheological properties
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/16Dielectric; Insulating oil or insulators
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/14Electric or magnetic purposes
    • C10N2040/17Electric or magnetic purposes for electric contacts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00Specified use or application for which the lubricating composition is intended
    • C10N2040/25Internal-combustion engines
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00Specific manufacturing methods for lubricant compositions

Definitions

  • the field of invention relates to the latest technology in the development of a synthetic gasoline conditioner to clean and lubricate the fuel pump, injectors and valves.
  • the oxygenates dries the fuel creating premature wear between the moving components and in such component as injectors where premature wear can allow excess fuel to discharge causing unburned fuel to be exhausted into the atmosphere.
  • the results are twofold: (1) the environmental effect and (2) the cost to the operators for fuel loss or poor fuel mileage.
  • the invention disclosed herein has been extensively tested experimentally. These test show that it meets is its primary purpose which is to lubricate the fuel system to reduce wear of the mechanical components, which over time will restore injectors' impulse movement required to maintain the greatest fuel efficiencies. The invention will not, however, restore broken components or components that have suffered severe wear.
  • the invention incorporates a strong element of extreme pressure lubrication, octane booster, detergent, dicing agent and cleaner that cleans and restores the valve surface. In-house testing on stationary engines under load have demonstrated increased run time as high as 12% on fuel treated with the invention.
  • a synthetic gasoline conditioner additive with strong lubrication characteristics to reduce premature mechanical wear and failure, increased octane, while cleaning and restoring the valves face to a more efficient operation.
  • This lubricant comprises alpha-olefins; low odor aromatic solvents; and at least one a base oil selected from the base oil group consisting of hydrolsomerized high base oils and HT Severe Hydro-cracked Base Oils; as well as other ingredients.
  • a method for producing this fuel conditioner and lubricant additive is also disclosed.
  • this universal synthetic gasoline conditioner additive for improving lubrication comprises: alpha-olefins comprising from 5 to 30 percent thereof, by weight; low odor aromatic solvents comprising from 3 to 27 percent thereof, by weight; 2-Propanol comprising of 3 to 30 percent thereof, by weight; and at least one a base oil comprising from .50 to 15 percent thereof, by weight; wherein: the percentages by weight are specified in relative proportion to one another.
  • the invention relates to the use of a synthetic gasoline conditioner additive containing a lubricant which that can be added to gasoline fuels stocks to replace the dramatic loss of lubrication generally associated with oxygenated enhanced fuels.
  • the product will have utility in all forms and grades of gasoline, gasoline engines, naturally aspirated or turbo-charged where oxygenated fuels will result in premature wear to the integral components of internal combustion engine.
  • the invention has been submitted by confidential disclosure to the EPA and has received registration under 40CFR 79.23 in October 2007.
  • the finished product (preferred embodiment of the invention) is a combination of:
  • PAO Alpha-Olefins
  • PAO is a primary ingredient also known as Alkenes, Polymerized, Chlorowax Liquids, and Chlorinated Paraffins whose carbon chain length are 12 to 24 with chloric weight percentage from 21.4 to 70%, an HCI of 4 to 10 ppm and molecular weight of 273.5 to 650 and Wt.
  • Cl (2) from 20 to 70% with specific gravity at 25 degrees centigrade of 1.050 to 1.50 and a JQD weight percentage of HCL being 0.20 to 0.60 maximum.
  • the primary use is for the above ingredient is for lubricant formulations, lubricant additive compounds, extreme-pressure additive formulations and for metal working compounds.
  • alpha-olefins or associated products reduce the growth of algae in fuel as aging or excessive moisture accumulates and stabilize the fuel over time while providing extreme lubrication to the fuel system and the firing chamber of the engine. This provides the lubrication lacking in ultra low sulfur diesel.
  • Aromatic Solvents This is a primary ingredient which is a highly-refined, low toxic, low- odor solvent ideal for paints, varnishes, food grade coatings, adhesives, diluents, thinners, agrochemicals, household pesticides, spray oils and specialty chemicals.
  • Aromatic percentage is 5 to 40% (EC-A-G04), a flash point of 20 to 80 degrees centigrade (ASTM D-93) and a density at 30 degrees centigrade (plus/minus) 0.600 to 0.900 (ASTM D- 4052).
  • Hydrolsomerized High-Base Oils or HT Severe Hydro-cracked Base Oils This primary ingredient is a severe hydro-cracked or hydroisomerized base oil with low or no aromatics and impurities achieved by chemically reacting the feed stock with hydrogen to reduce or remove polar compounds containing sulphur, nitrogen and oxygen and to convert aromatic hydrocarbons to saturated cyclic hydrocarbons breaking up the heavy polycyclo-paraffin molecules to light saturated hydrocarbons.
  • This may include fractionated oils that have been hydro-finished or hydro-polished.
  • the base oils can be used in a host of lubricating oils, motor oils, cutting oils, food processing, pharmaceutical, industry, agriculture lubricants and extreme pressure additives. These add to the lubrication of ultra synthetic gasoline conditioner.
  • 2-F 1 TOPaHoI This known as Isopropanol Alcohol (IPA) or industrial alcohol 2-Propanol and is a colorless, flammable chemical compound with a chemical formula of C3 H8 O.
  • the compound has a Molar Mass of 60.10g/mol; density of 0.785 g/cm3, liquid; dipole moment of 1.66D(gas); viscosity of
  • Octane Booster and Detergent Blend In accordance with this invention, this is a blend comprising: hydrocarbon solvents, CAS 64741-86-2; petroleum naphtha, CAS 64742-94-5; polyester amine; and said naphthalene, CAS 91-20-3.
  • 2-Ethylhexyl Nitrate with suggested percentage of 10 to 30% by weight, particularly where calcium sulfonates are restricted, see below. This group of compounds when blended together will clean and maintain the firing chamber of the engine, increase the octane while neutralizing any acids within the fuel system and firing chamber.
  • Synthetic Calcium Sulfonates An over-based synthetic calcium sulfonate with a TBN of 100 to 600 whose primary purpose is for extreme pressure additive formulations offering corrosion protection, dispersants and detergency in oil soluble additives for ferrous and non-ferrous metals with a minimum calcium weight of 10.00 to 20.00%, a total base number, mg KOH/g (ASTM D-2896) of 200 to 600 and an average molecular weight (ASTM d-3712) of 800 to 1200.
  • TBN 100 to 600
  • ASTM D-2896 mg KOH/g
  • ASTM d-3712 average molecular weight
  • Solvent activated dyes These are commonly used to identify grades or designated uses of fuels and lubricants. They are produced in both powder and liquid form and when introduced to the product are stable and leave an identifiable color to the product.
  • Pour Point Depressants or Cloud Point Depressants are used to reduce agglomeration or massing together of wax crystals in paraffin compounds such as lubricants and diesel fuel.
  • Isomer Reformate also referred to as a Solvent, Toluene, Toluol, Methylbenzene and Phenylmethane with a chemical formula of C7H8 (C6H5CH3) and a CAS No. 108-88-3, a molecular weight of 90.00 to 95.00 g/mole and a specific gravity of 0.800 to 0.900 (water being 1).
  • the chemical is an aromatic hydrocarbon that is widely used as an industrial feedstock and as a solvent for cleaning the fuel systems, holding tanks and the combustion chamber of the engine.
  • Dimethyl Ketones Also referred to as Acetone or 2-propanone with molecular structure of CH3COCH3. It is colorless, has low boiling point, and is miscible in proportions with water, alcohols, most hydrocarbons and other organic liquids including diesel fuel stocks to help clean and reduce carbon build up on valves and piston tops.
  • Preferred Blending Ratios Preferred Blending Ratios
  • the preferred blending Ratios for each component are shown as below. It is important to maintain a blend of component that fall within the following percentages. These percentages by weight are specified in relative proportion to one another. Therefore, in the event one or more of the ingredients shown below is omitted from the synthetic gasoline conditioner additive, the percentages by weight of the remaining ingredients are proportionately increased:
  • Alpha-Olefins 5 to 30% by weight and preferably 7.0 to 25% by weight and more preferably 9.0 to 18% by weight. Most preferable is 10.45% by weight.
  • Low Odor Aromatic Solvents 3.0 to 27% by weight and preferably 5.0 to 22% by weight and more preferably is 7.0 to 18% by weight. Most preferable is 7.50 % by weight.
  • Hydrolsomerized High-Base Oils or HT Severe Hydro-cracked Base Oils .50 to 15 percent by weight and preferably 0.75 to 8 % by weight and more preferably 1.0 to 4.0% by weight. Most preferable is 1.52 % by weight.
  • 2-Proponal 5-40% by weight and preferably 7-30% by weight and more preferably 12 to 24% by weight. Most preferable is 18.5%
  • Octane Booster, Detergent and Acid Neutralizer Blend 0.30 to 7.5 % by weight and preferably 0.50 to 5.0 % by weight and more preferably 0.75 to 2.5 % by weight. Most preferable is 1.0 % by weight.
  • Synthetic Calcium Sulfonates 0.05 to 0.25% by weight, preferably 0.07 to 0.20% by weight and more preferably 0.10 to 0.18% by weight. Most preferable is 0.125 % by weight.
  • Low Flash Mineral Spirits 15 to 50% by weight and preferably 20 to 45% by weight and more preferably 25 - 39% by weight. Most preferable is 33.5% by weight.
  • Solvent Activated Dyes 0.002 to 0.005 percent by weight and preferably 0.0025 to 0.004% by weight and more preferably 0.027 to 0.035% by weight. Most preferable is 0.003 percent by weight.
  • Isomer Reformate 0.50 to 15.0% by weight and preferably 1.50 to 10 % by weight and more preferably 2.5 to 7.0 % by weight. Most preferable is 4.0% by weight.
  • Dimethyl Ketones 10 to 50% by weight and preferably 17 to 40% by weight and more preferably 24 to 28% by weight. Most preferable is 23.4%.
  • Preferred Sequence of Blending Components 10 to 50% by weight and preferably 17 to 40% by weight and more preferably 24 to 28% by weight. Most preferable is 23.4%.
  • the initial blend (primary blend) will require the Poly Alpha Olefins, the Low Aromatic Solvent and the Base Oil being blended until the liquid is a consistent amalgamation without any appearance of separation. Blending is based on speed of the agitator and temperature will dictate the amount of time for the blend to complete. The blending time range may vary from 2 to 4 hours. The ideal temperature for each component is between 22 to 30 degrees centigrade for ideal blending. While this is blending, a secondary blend for the Octane Booster, Detergent and Acid Neutralizer, 2-Propanol and said Dimethyl Ketones at 25/75 ratio can be prepared in a smaller high speed enclosed blender, and then added to the main blend.
  • Blend Equipment The Process sequence involves a series of blending and holding tanks where the product can be weighed and then pumped through control valves to maintain consistent flow and pressure.
  • Blending should be performed in a enclosed tank to reduce product evaporation (loss) and prevent exposure to open spark.
  • Blending equipment can be by a combination of high or low speed blending apparatus. Size or volume of tank is not critical to the blend. Universal Use of Invention
  • the engines were run measuring fuel which was both treated and untreated, and the results analyzed.
  • the engines were engines without an OB computer system so accurate reading of fuel consumption was measured.
  • the resulted demonstrated that the treated fuel ran for an average consistently of 12 % longer over the untreated fuel.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

A process of producing a universal synthetic based gasoline fuel additive that cleans the fuel system including valves surface, lubricates the fuel pump, injectors and valves while allowing for a clean and more efficient burn. A major portion will consist of (a) Alfa-Olefins, (b) 2-propanol (c) Hydrolsomerized High VI HT Base Oils, (d) Dimethyl Ketones, (e) Low Flash Mineral Spirits, (f) Low Aromatic Solvent, (g) Isomer Reformate, (h) Solvent Activated Dye. In a preferred embodiment, this universal synthetic gasoline conditioner additive for improving lubrication comprises: alpha-olefins comprising from 5 to 30 percent thereof, by weight; low odor aromatic solvents comprising from 3 to 27 percent thereof, by weight; 2-Propanol comprising of 3 to 30 percent thereof, by weight; and at least one a base oil comprising from. 50 to 15 percent thereof, by weight; wherein: the percentages by weight are specified in relative proportion to one another.

Description

Universal Synthetic Gasoline Fuel Conditioner Additive, Method and Product-by-Process
Field of the Invention
The field of invention relates to the latest technology in the development of a synthetic gasoline conditioner to clean and lubricate the fuel pump, injectors and valves.
Background of the Invention
Over the years, gasoline has been subject to environmental pressures to reduce emissions from the exhaust pipe. Various chemicals such as MTBE (Methyl Tertiary Butyl Ether) have been introduced to gasoline, only to discover later that the residue was showing potential long-term harmful effects on the ground water system. Grain alcohol, ethanol is now the latest ingredient to be added to gasoline. Unfortunately, unlike MTBE, ethanol when added to gasoline to satisfy the oxygen content required, raises the Reid vapor pressure (RVP) of the blend by lpsi, making it difficult for ethanol blends to meet VOC performance standards. With introduction of oxygenates such as MTBE and ethanol, many vehicles have experienced premature wear in high pressure fuel pumps required for fuel injections systems, injectors and valve guides. The oxygenates dries the fuel creating premature wear between the moving components and in such component as injectors where premature wear can allow excess fuel to discharge causing unburned fuel to be exhausted into the atmosphere. The results are twofold: (1) the environmental effect and (2) the cost to the operators for fuel loss or poor fuel mileage. The invention disclosed herein has been extensively tested experimentally. These test show that it meets is its primary purpose which is to lubricate the fuel system to reduce wear of the mechanical components, which over time will restore injectors' impulse movement required to maintain the greatest fuel efficiencies. The invention will not, however, restore broken components or components that have suffered severe wear. The invention incorporates a strong element of extreme pressure lubrication, octane booster, detergent, dicing agent and cleaner that cleans and restores the valve surface. In-house testing on stationary engines under load have demonstrated increased run time as high as 12% on fuel treated with the invention.
As of December 2007, United States requires that fuel mileage per gallon must be increased while emissions must be reduced. The challenge will fall upon the manufacture of the fuel supply, automakers and the engine lubricants. The invention will have a beneficial impact on meeting these requirements put forward by the United States government.
Ecological tests were run in California to test the fuel with an Environmental Protection Agency (EPA) designed and approved test protocol. The tests were to demonstrate that the lubricant within the invention, which has been offset by other chemical components, would not have a negative effect on the emissions.
The results of the EPA approved tests demonstrated that the invention, when added to gasoline, did not alter or have a negative effect upon the readings previously registered when tested with gasoline untreated.
These tests included readings for; non methane organic gas (NMHC); nitrogen oxide (NOX); carbon monoxide (CO2); total hydro carbons (THC) and carbon dioxide (CO). The concern of the EPA has always been that adding a lubricant to any kind of gasoline would have a serious negative upon the emissions, and these tests have demonstrated that this invention does not. Summary of the Invention
Disclosed herein is a synthetic gasoline conditioner additive with strong lubrication characteristics to reduce premature mechanical wear and failure, increased octane, while cleaning and restoring the valves face to a more efficient operation., the process for producing said lubricant, and the method of using said lubricant. This lubricant comprises alpha-olefins; low odor aromatic solvents; and at least one a base oil selected from the base oil group consisting of hydrolsomerized high base oils and HT Severe Hydro-cracked Base Oils; as well as other ingredients. Also disclosed is a method for producing this fuel conditioner and lubricant additive.
In a preferred embodiment, this universal synthetic gasoline conditioner additive for improving lubrication comprises: alpha-olefins comprising from 5 to 30 percent thereof, by weight; low odor aromatic solvents comprising from 3 to 27 percent thereof, by weight; 2-Propanol comprising of 3 to 30 percent thereof, by weight; and at least one a base oil comprising from .50 to 15 percent thereof, by weight; wherein: the percentages by weight are specified in relative proportion to one another.
Detailed Description The invention relates to the use of a synthetic gasoline conditioner additive containing a lubricant which that can be added to gasoline fuels stocks to replace the dramatic loss of lubrication generally associated with oxygenated enhanced fuels. The product will have utility in all forms and grades of gasoline, gasoline engines, naturally aspirated or turbo-charged where oxygenated fuels will result in premature wear to the integral components of internal combustion engine. The invention has been submitted by confidential disclosure to the EPA and has received registration under 40CFR 79.23 in October 2007.
Previous gasoline stocks relied upon lead to offer lubrication to mechanical components and valve facings, which is now highly restricted by the United States Environmental Protection Agency and various foreign governments. With the new universal environmental standards, oxygenated compounds will become widely used throughout the world to hopefully have a positive impact on the environment and greenhouse gasses.
Primary Ingredients
The finished product (preferred embodiment of the invention) is a combination of:
• Alpha-Olefins (PAO): PAO is a primary ingredient also known as Alkenes, Polymerized, Chlorowax Liquids, and Chlorinated Paraffins whose carbon chain length are 12 to 24 with chloric weight percentage from 21.4 to 70%, an HCI of 4 to 10 ppm and molecular weight of 273.5 to 650 and Wt. Cl (2) from 20 to 70% with specific gravity at 25 degrees centigrade of 1.050 to 1.50 and a JQD weight percentage of HCL being 0.20 to 0.60 maximum. The primary use is for the above ingredient is for lubricant formulations, lubricant additive compounds, extreme-pressure additive formulations and for metal working compounds. Further, alpha-olefins or associated products reduce the growth of algae in fuel as aging or excessive moisture accumulates and stabilize the fuel over time while providing extreme lubrication to the fuel system and the firing chamber of the engine. This provides the lubrication lacking in ultra low sulfur diesel.
• Low Odor Aromatic Solvents: This is a primary ingredient which is a highly-refined, low toxic, low- odor solvent ideal for paints, varnishes, food grade coatings, adhesives, diluents, thinners, agrochemicals, household pesticides, spray oils and specialty chemicals. Aromatic percentage is 5 to 40% (EC-A-G04), a flash point of 20 to 80 degrees centigrade (ASTM D-93) and a density at 30 degrees centigrade (plus/minus) 0.600 to 0.900 (ASTM D- 4052).
• Hydrolsomerized High-Base Oils or HT Severe Hydro-cracked Base Oils: This primary ingredient is a severe hydro-cracked or hydroisomerized base oil with low or no aromatics and impurities achieved by chemically reacting the feed stock with hydrogen to reduce or remove polar compounds containing sulphur, nitrogen and oxygen and to convert aromatic hydrocarbons to saturated cyclic hydrocarbons breaking up the heavy polycyclo-paraffin molecules to light saturated hydrocarbons. This may include fractionated oils that have been hydro-finished or hydro-polished. The base oils can be used in a host of lubricating oils, motor oils, cutting oils, food processing, pharmaceutical, industry, agriculture lubricants and extreme pressure additives. These add to the lubrication of ultra synthetic gasoline conditioner.
• 2-F1TOPaHoI: This known as Isopropanol Alcohol (IPA) or industrial alcohol 2-Propanol and is a colorless, flammable chemical compound with a chemical formula of C3 H8 O. The compound has a Molar Mass of 60.10g/mol; density of 0.785 g/cm3, liquid; dipole moment of 1.66D(gas); viscosity of
2.86 cP at 15 degrees centigrade and 1.77 cP at 30 degrees centigrade and related to 1-propanol and ethanol. Isopropanol is known to solubilize water and as an insoluble water, it will no long freeze. Being a secondary alcohol, isopropanol can be oxidized within the ketone acetone of the invention. Other Ingredients • Octane Booster and Detergent Blend: In accordance with this invention, this is a blend comprising: hydrocarbon solvents, CAS 64741-86-2; petroleum naphtha, CAS 64742-94-5; polyester amine; and said naphthalene, CAS 91-20-3. It may also contain 2-Ethylhexyl Nitrate with suggested percentage of 10 to 30% by weight, particularly where calcium sulfonates are restricted, see below. This group of compounds when blended together will clean and maintain the firing chamber of the engine, increase the octane while neutralizing any acids within the fuel system and firing chamber.
• Synthetic Calcium Sulfonates: An over-based synthetic calcium sulfonate with a TBN of 100 to 600 whose primary purpose is for extreme pressure additive formulations offering corrosion protection, dispersants and detergency in oil soluble additives for ferrous and non-ferrous metals with a minimum calcium weight of 10.00 to 20.00%, a total base number, mg KOH/g (ASTM D-2896) of 200 to 600 and an average molecular weight (ASTM d-3712) of 800 to 1200. Important note: in December 2007, a new United States law was enacted which may restrict the future use of calcium sulfonates in fuel additives, and so at least the United States, it may become necessary to omit this ingredient from the invention. This is possible, because the 2-Ethylhexyl Nitrate above serves a similar corrosion protection, dispersant and detergency function. • Low Flash Mineral Spirits: Referred to as Stoddard Solvent and / or White's Spirits, this is commonly used as an extraction solvent, cleaning solvent, solvent in aerosols, paints, lacquers, varnishes and paint thinners for household and commercial use and has been subjected to hydrodesulfurization solvent extraction with a mixture of saturated aliphatic and alicyclic C7-C12 with a maximum of 40%. The flash point ranges from 15 to 40 degrees centigrade, aniline point of 50 to 80 degrees centigrade, vapor density of 3.5 to 6.0 (air be 1) and viscosity (cps. 25 degrees centigrade) 0.70 to 1.75. As a cleaning solvent it cleans components within the fuel system.
• Solvent activated dyes: These are commonly used to identify grades or designated uses of fuels and lubricants. They are produced in both powder and liquid form and when introduced to the product are stable and leave an identifiable color to the product.
• Pour Point Depressants or Cloud Point Depressants: These are used to reduce agglomeration or massing together of wax crystals in paraffin compounds such as lubricants and diesel fuel.
• Isomer Reformate: Also referred to as a Solvent, Toluene, Toluol, Methylbenzene and Phenylmethane with a chemical formula of C7H8 (C6H5CH3) and a CAS No. 108-88-3, a molecular weight of 90.00 to 95.00 g/mole and a specific gravity of 0.800 to 0.900 (water being 1). The chemical is an aromatic hydrocarbon that is widely used as an industrial feedstock and as a solvent for cleaning the fuel systems, holding tanks and the combustion chamber of the engine.
• Dimethyl Ketones: Also referred to as Acetone or 2-propanone with molecular structure of CH3COCH3. It is colorless, has low boiling point, and is miscible in proportions with water, alcohols, most hydrocarbons and other organic liquids including diesel fuel stocks to help clean and reduce carbon build up on valves and piston tops. Preferred Blending Ratios
The preferred blending Ratios for each component are shown as below. It is important to maintain a blend of component that fall within the following percentages. These percentages by weight are specified in relative proportion to one another. Therefore, in the event one or more of the ingredients shown below is omitted from the synthetic gasoline conditioner additive, the percentages by weight of the remaining ingredients are proportionately increased:
Alpha-Olefins: 5 to 30% by weight and preferably 7.0 to 25% by weight and more preferably 9.0 to 18% by weight. Most preferable is 10.45% by weight. Low Odor Aromatic Solvents: 3.0 to 27% by weight and preferably 5.0 to 22% by weight and more preferably is 7.0 to 18% by weight. Most preferable is 7.50 % by weight.
Hydrolsomerized High-Base Oils or HT Severe Hydro-cracked Base Oils: .50 to 15 percent by weight and preferably 0.75 to 8 % by weight and more preferably 1.0 to 4.0% by weight. Most preferable is 1.52 % by weight. 2-Proponal: 5-40% by weight and preferably 7-30% by weight and more preferably 12 to 24% by weight. Most preferable is 18.5%
Octane Booster, Detergent and Acid Neutralizer Blend: 0.30 to 7.5 % by weight and preferably 0.50 to 5.0 % by weight and more preferably 0.75 to 2.5 % by weight. Most preferable is 1.0 % by weight.
Synthetic Calcium Sulfonates: 0.05 to 0.25% by weight, preferably 0.07 to 0.20% by weight and more preferably 0.10 to 0.18% by weight. Most preferable is 0.125 % by weight.
Low Flash Mineral Spirits: 15 to 50% by weight and preferably 20 to 45% by weight and more preferably 25 - 39% by weight. Most preferable is 33.5% by weight.
Solvent Activated Dyes: 0.002 to 0.005 percent by weight and preferably 0.0025 to 0.004% by weight and more preferably 0.027 to 0.035% by weight. Most preferable is 0.003 percent by weight. Isomer Reformate: 0.50 to 15.0% by weight and preferably 1.50 to 10 % by weight and more preferably 2.5 to 7.0 % by weight. Most preferable is 4.0% by weight.
Dimethyl Ketones: 10 to 50% by weight and preferably 17 to 40% by weight and more preferably 24 to 28% by weight. Most preferable is 23.4%. Preferred Sequence of Blending Components
The initial blend (primary blend) will require the Poly Alpha Olefins, the Low Aromatic Solvent and the Base Oil being blended until the liquid is a consistent amalgamation without any appearance of separation. Blending is based on speed of the agitator and temperature will dictate the amount of time for the blend to complete. The blending time range may vary from 2 to 4 hours. The ideal temperature for each component is between 22 to 30 degrees centigrade for ideal blending. While this is blending, a secondary blend for the Octane Booster, Detergent and Acid Neutralizer, 2-Propanol and said Dimethyl Ketones at 25/75 ratio can be prepared in a smaller high speed enclosed blender, and then added to the main blend.
If the synthetic calcium sulfonates are employed (noting the recent US law which could restrict their use in the US), blending will require that the synthetic calcium sulfonates be blended with the mineral spirits in an approximate 50/50 ratio in the initial stage of the blend to produce a tertiary blend. (The mineral spirits used will be from the preferred percentage set forth earlier.) This tertiary blend, or the mineral spirits alone absent the synthetic calcium sulfonates, together with the balance of the ingredients, can be then added to the main blend and the agitator is run until the components appear to have thoroughly blended into a consistent liquid. Preferred Blend Equipment The Process sequence involves a series of blending and holding tanks where the product can be weighed and then pumped through control valves to maintain consistent flow and pressure. The blending should be performed in a enclosed tank to reduce product evaporation (loss) and prevent exposure to open spark. Blending equipment can be by a combination of high or low speed blending apparatus. Size or volume of tank is not critical to the blend. Universal Use of Invention
The product has been put to experimental test in various on-road, off -road vehicles, marine and industrial engines have demonstrated that when added at 2 to 3 ounces per 10 gallons with all grades of gasoline including those containing grain alcohol, reduced wear, increased mileage and reduced emissions have been experienced, as summarized below. Testing Procedures
The only protocol for testing fuel /mileage is in the hands of the US EPA and is being revamped at the time of the filing of this application. The current tests are completed under conditions that the average person would find it nearly impossible to replicate in either city or highway driving. The main criteria, was to measure the emission from the exhaust system to establish if the invention has a negative impact on the emission standards as set by the EPA. The Inventor subjected the invention to the EPA approved and registered test in 2007. The resulting tests displayed no negative impact on THC, CO, NOX, CO, Co2 and NMNC. Further the invention was registered in October of 2007 with the EPA under 40CFR 79.21(f). Further tests were conducted on stationary generators with controlled load factors. The engines were run measuring fuel which was both treated and untreated, and the results analyzed. The engines were engines without an OB computer system so accurate reading of fuel consumption was measured. The resulted demonstrated that the treated fuel ran for an average consistently of 12 % longer over the untreated fuel.
While only certain preferred features of the invention have been illustrated and described, many modifications, changes and substitutions will occur to those skilled in the art. It is, therefore, to be understood that the appended claims are intended to cover all such modifications and changes as fall within the true spirit of the invention.

Claims

I claim: 1. A universal synthetic gasoline conditioner additive for improving lubrication, comprising: alpha-olefins comprising from 5 to 30 percent thereof, by weight; low odor aromatic solvents comprising from 3 to 27 percent thereof, by weight; 2-Propanol comprising of 3 to 30 percent thereof, by weight; and at least one a base oil comprising from .50 to 15 percent thereof, by weight; wherein: said percentages by weight are specified in relative proportion to one another.
2. The universal synthetic gasoline conditioner additive of claim 1, further comprising: a octane booster, detergent, acid neutralizer blend.
3. The universal synthetic gasoline conditioner additive of claim 2, said octane booster, detergent, acid neutralizer blend comprising: polyether amine.
4. The universal synthetic gasoline conditioner additive of claim 3, said octane booster, detergent, acid neutralizer blend further comprising: petroleum naphtha; naphthalene; and hydrocarbon solvent.
5. The universal synthetic gasoline conditioner additive of claim 2, further comprising: low flash mineral spirits that have been subjected to hydrodesulfurization.
6. The universal synthetic gasoline conditioner additive of claim 5, further comprising: synthetic calcium sulfonates.
7. The universal synthetic gasoline conditioner additive of claim 5, further comprising: at least one depressant selected form the group consisting of pour point depressants and cloud point depressants; isomer reformate; and dimethyl ketones.
8. The universal synthetic gasoline conditioner additive of claim 6, further comprising: at least one depressant selected form the group consisting of pour point depressants and cloud point depressants; isomer reformate; and dimethyl ketones.
9. The universal synthetic gasoline conditioner additive of claim 7, further comprising: solvent activated dyes.
10. The universal synthetic gasoline conditioner additive of claim 8, further comprising: solvent activated dyes.
11. The universal synthetic gasoline conditioner additive of claim 2, wherein: said octane booster, detergent, acid neutralizer blend comprise from 0.30 to 7.50 percent thereof, by weight.
12. The universal synthetic gasoline conditioner additive of claim 5, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight.
13. The universal synthetic gasoline conditioner additive of claim 6, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight; and said synthetic calcium sulfonates comprise from 0.05 to 0.25 percent thereof, by weight.
14. The universal synthetic gasoline conditioner additive of claim 7, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight; said at least one depressant comprises from 0.50 to 2 percent thereof, by weight; said isomer reformate comprises from 0.50 to 15.0 percent thereof, by weight; and said dimethyl ketones comprise from 10 to 50 percent thereof, by weight.
15. The universal synthetic gasoline conditioner additive of claim 8, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight; said synthetic calcium sulfonates comprise from 0.05 to 0.25 percent thereof, by weight; said at least one depressant comprises from 0.50 to 2 percent thereof, by weight; said isomer reformate comprises from 0.50 to 15.0 percent thereof, by weight; and said dimethyl ketones comprise from 10 to 50 percent thereof, by weight.
16. The universal synthetic gasoline conditioner additive of claim 9, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight said at least one depressant comprises from 0.50 to 2 percent thereof, by weight; said isomer reformate comprises from 0.50 to 15.0 percent thereof, by weight; and said dimethyl ketones comprise from 10 to 50 percent thereof, by weight; and said solvent activated dyes comprise from 0.002 to 0.005 percent thereof, by weight.
17. The universal synthetic gasoline conditioner additive of claim 10, wherein: said octane booster, detergent, acid neutralizer blend comprises from 0.30 to 7.50 percent thereof, by weight; said synthetic calcium sulfonates comprise from 0.05 to 0.25 percent thereof, by weight; said low flash mineral spirits comprise from 15 to 50 percent thereof, by weight said at least one depressant comprises from 0.50 to 2 percent thereof, by weight; said isomer reformate comprises from 0.50 to 15.0 percent thereof, by weight; and said dimethyl ketones comprise from 10 to 50 percent thereof, by weight; and said solvent activated dyes comprise from 0.002 to 0.005 percent thereof, by weight.
18. The universal synthetic gasoline conditioner additive of claim 3, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; and adding said polyether amine to said primary blend.
19. The universal synthetic gasoline conditioner additive of claim 4, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending said polyether amine; said petroleum naphtha; said naphthalene; and said hydrocarbon solvent, thereby producing a secondary blend; and adding said secondary blend to said primary blend.
20. The universal synthetic gasoline conditioner additive of claim 5, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately, blending said octane booster, detergent, acid neutralizer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; and adding said low flash mineral spirits to said primary and secondary blend.
21. The universal synthetic gasoline conditioner additive of claim 6, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately, blending said octane booster, detergent, acid neutralizer reducer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; separately blending said synthetic calcium sulfonates and said low flash mineral spirits, thereby producing a tertiary blend; and adding said tertiary blend to said primary and secondary blend.
22. The universal synthetic gasoline conditioner additive of claim 7, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending said octane booster, detergent, acid neutralizer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; adding said low flash mineral spirits to said primary and secondary blend; and adding said at least one depressant; said isomer reformate; and said dimethyl ketones to said blend of primary and secondary blends, and said low flash mineral spirits.
23. The universal synthetic gasoline conditioner additive of claim 8, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending said octane booster, detergent, acid neutralizer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; separately blending said synthetic calcium sulfonates and said low flash mineral spirits, thereby producing a tertiary blend; adding said tertiary blend to said primary and secondary blend; and adding said at least one depressant; said isomer reformate; and said dimethyl ketones to said primary, secondary, and tertiary blends.
24. The universal synthetic gasoline conditioner additive of claim 9, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending said octane booster, detergent, acid neutralizer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; separately blending said and said low flash mineral spirits, thereby producing a tertiary blend; adding said tertiary blend to said primary and secondary blend; and adding said solvent activated dyes; said at least one depressant; said isomer reformate; and said dimethyl ketones to said primary, secondary, and tertiary blends.
25. The universal synthetic gasoline conditioner additive of claim 10, produced by a method comprising: blending said alpha-olefins, said low odor aromatic solvents, 2-Propanol and said at least one base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending said ...octane booster, detergent, acid neutralizer blend, thereby producing a secondary blend; adding said secondary blend to said primary blend; separately blending said synthetic calcium sulfonates and said low flash mineral spirits, thereby producing a tertiary blend; adding said tertiary blend to said primary and secondary blend; and adding said solvent activated dyes; said at least one depressant; said isomer reformate; and said dimethyl ketones to said primary, secondary, and tertiary blends.
26. A method of producing a universal synthetic gasoline conditioner additive, comprising: blending alpha-olefins, low odor aromatic solvents, 2-Propanol and at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; and adding polyether amine to said primary blend.
27. The method of claim 26, further comprising: blending alpha-olefins, low odor aromatic solvents, 2-Propanol and at least one a base oil until the blend is a consistent amalgamation without any appearance of separation, thereby producing a primary blend; separately blending 2-ethylhexyl nitrate; petroleum naphtha; naphthalene; and hydrocarbon solvent, thereby producing a secondary blend; and adding said secondary blend to said primary blend.
28. The method of claim 27, further comprising: adding low flash mineral spirits to said primary and secondary blend.
29. The method of claim 27, further comprising: separately blending synthetic calcium sulfonates and low flash mineral spirits, thereby producing a tertiary blend; and adding said tertiary blend to said primary and secondary blend.
30. The method of claim 28, further comprising: adding solvent activated dyes; at least one depressant selected form the group consisting of pour point depressants and cloud point depressants; isomer reformate; and dimethyl ketones, to said blend of primary and secondary blends, and said low flash mineral spirits.
31. The method of claim 29, further comprising: adding solvent activated dyes; at least one depressant selected form the group consisting of pour point depressants and cloud point depressants; isomer reformate; and dimethyl ketones, to said primary, secondary, and tertiary blends.
PCT/US2008/087433 2005-01-18 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process WO2009085957A1 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US12/747,230 US7931704B2 (en) 2005-01-18 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
EP08867084A EP2242821A1 (en) 2007-12-19 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
CA2710403A CA2710403C (en) 2007-12-19 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US13/093,223 US8268022B2 (en) 2005-01-18 2011-04-25 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US13/309,648 US8415280B2 (en) 2005-01-18 2011-12-02 Universal synthetic penetrating lubricant, method and product-by-process

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
USPCT/US2007/088252 2007-12-19
PCT/US2007/088252 WO2009078882A1 (en) 2007-12-19 2007-12-19 Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
PCT/US2008/050951 WO2009079020A1 (en) 2007-12-19 2008-01-13 Universal synthetic golf club cleaner and protectant, method and product-by- process to clean, protect golf club faces and rejuvenate golf clubs grips
USPCT/US2008/050951 2008-01-13
US12/060,637 2008-04-01
US12/060,637 US8022020B2 (en) 2005-01-18 2008-04-01 Universal synthetic penetrating lubricant, method and product-by-process

Related Parent Applications (5)

Application Number Title Priority Date Filing Date
US11/290,596 Continuation-In-Part US7745382B2 (en) 2005-01-18 2005-12-01 Synthetic lubricant additive with micro lubrication technology to be used with a broad range of synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US12/808,495 Continuation-In-Part US8071522B2 (en) 2005-01-18 2008-01-13 Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
PCT/US2008/050951 Continuation-In-Part WO2009079020A1 (en) 2005-01-18 2008-01-13 Universal synthetic golf club cleaner and protectant, method and product-by- process to clean, protect golf club faces and rejuvenate golf clubs grips
US12/060,637 Continuation US8022020B2 (en) 2005-01-18 2008-04-01 Universal synthetic penetrating lubricant, method and product-by-process
US80849510A Continuation-In-Part 2005-01-18 2010-06-16

Related Child Applications (4)

Application Number Title Priority Date Filing Date
US12/747,236 A-371-Of-International US8071513B2 (en) 2005-01-18 2008-12-18 Universal synthetic penetrating lubricant, method and product-by-process
US12/747,230 A-371-Of-International US7931704B2 (en) 2005-01-18 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US13/093,223 Continuation US8268022B2 (en) 2005-01-18 2011-04-25 Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US13/309,648 Continuation US8415280B2 (en) 2005-01-18 2011-12-02 Universal synthetic penetrating lubricant, method and product-by-process

Publications (1)

Publication Number Publication Date
WO2009085957A1 true WO2009085957A1 (en) 2009-07-09

Family

ID=40824662

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US2008/087449 WO2009085967A1 (en) 2005-01-18 2008-12-18 Universal synthetic penetrating lubricant, method and product-by-process
PCT/US2008/087433 WO2009085957A1 (en) 2005-01-18 2008-12-18 Universal synthetic gasoline fuel conditioner additive, method and product-by-process

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2008/087449 WO2009085967A1 (en) 2005-01-18 2008-12-18 Universal synthetic penetrating lubricant, method and product-by-process

Country Status (7)

Country Link
US (2) US8022020B2 (en)
EP (2) EP2242821A1 (en)
JP (1) JP2011508022A (en)
CN (2) CN103865609B (en)
CA (2) CA2710403C (en)
HK (2) HK1153498A1 (en)
WO (2) WO2009085967A1 (en)

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7745382B2 (en) 2005-01-18 2010-06-29 Bestline International Research Inc. Synthetic lubricant additive with micro lubrication technology to be used with a broad range of synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US7931704B2 (en) 2005-01-18 2011-04-26 Bestline International Research Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8022020B2 (en) 2005-01-18 2011-09-20 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US8062388B2 (en) 2005-01-18 2011-11-22 Bestline International Research, Inc. Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US8071522B2 (en) 2005-01-18 2011-12-06 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US8268022B2 (en) 2005-01-18 2012-09-18 Bestline International Research, Inc. Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8334244B2 (en) 2005-01-18 2012-12-18 Bestline International Research, Inc. Universal synthetic water displacement multi-purpose penetrating lubricant, method and product-by-process
US8377861B2 (en) 2005-01-18 2013-02-19 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US8415280B2 (en) 2005-01-18 2013-04-09 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US10400192B2 (en) 2017-05-17 2019-09-03 Bestline International Research, Inc. Synthetic lubricant, cleaner and preservative composition, method and product-by-process for weapons and weapon systems
US11377616B2 (en) 2015-01-29 2022-07-05 Bestline International Research Inc. Motor oil blend and method for reducing wear on steel and eliminating ZDDP in motor oils by modifying the plastic response of steel

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101243110B1 (en) * 2010-10-11 2013-03-12 조선대학교산학협력단 photobioreactor
CN103666699B (en) * 2013-12-06 2014-11-26 华阳新兴科技(天津)集团有限公司 High-efficient rust cleaning lubricant, and preparation method thereof
PE20171535A1 (en) * 2015-01-29 2017-10-27 Bestline International Res Inc ENGINE OIL BLENDING AND METHOD TO REDUCE WEAR ON STEEL AND ELIMINATE ZDDP IN ENGINE OILS BY MODIFYING THE PLASTIC RESPONSE OF STEEL
US20180000706A1 (en) 2016-06-30 2018-01-04 The Procter & Gamble Company Conditioner Composition Comprising a Chelant
US20180000705A1 (en) 2016-06-30 2018-01-04 The Procter & Gamble Company Shampoo Compositions Comprising a Chelant
US11786447B2 (en) 2016-06-30 2023-10-17 The Procter & Gamble Company Conditioner composition comprising a chelant
US11246816B2 (en) 2016-06-30 2022-02-15 The Procter And Gamble Company Shampoo compositions comprising a chelant
US20180000715A1 (en) 2016-06-30 2018-01-04 The Procter & Gamble Company Hair Care Compositions For Calcium Chelation

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07233001A (en) * 1994-02-22 1995-09-05 Takeda Chem Ind Ltd Aerosol composition
EP1203803A1 (en) * 2000-10-24 2002-05-08 Oil Invest Ltd. Premium/Eurosuper leadfree gasoline
WO2007004789A1 (en) * 2005-07-01 2007-01-11 Pure Life Co Ltd Fuel composition containing bioethanol and biodiesel for internal combustion engine

Family Cites Families (65)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3406419A (en) * 1966-08-30 1968-10-22 Chester W. Young Self-polishing cover for golf club heads
FR2193080A1 (en) 1972-07-24 1974-02-15 Oleotechnique Sa Pentrating/lubricating oils - contg lipid mixt, low-viscosity petroleum hydrocarbon and wetting agent/solvent aid
US3984599A (en) * 1973-10-30 1976-10-05 Exxon Research And Engineering Company Lubricant coating compositions for use in metal drawing operations
GB1488922A (en) * 1974-12-17 1977-10-19 Exxon Research Engineering Co Halogen containing disulphides
US4127491A (en) * 1976-07-23 1978-11-28 Michael Ebert Hybrid lubricant including halocarbon oil
US4131551A (en) * 1977-08-15 1978-12-26 Standard Oil Company Railway lubricating oil
US4224173A (en) * 1978-06-12 1980-09-23 Michael Ebert Lubricant oil containing polytetrafluoroethylene and fluorochemical surfactant
US4218330A (en) * 1978-06-26 1980-08-19 Ethyl Corporation Lubricant
AU531818B2 (en) * 1978-11-20 1983-09-08 Procter & Gamble Company, The Detergent compositions having textile softening properties
GB2108149B (en) * 1981-08-20 1984-08-08 Ciba Geigy Ag Lubricant compositions containing chlorinated organic compounds
US4375417A (en) 1981-10-27 1983-03-01 Texaco Inc. Cylinder lubricating oil composition
US4375418A (en) * 1981-10-28 1983-03-01 Texaco Inc. Lubricating oil composition
US4956122A (en) * 1982-03-10 1990-09-11 Uniroyal Chemical Company, Inc. Lubricating composition
US4595395A (en) * 1982-05-06 1986-06-17 Smith Earl J Lubricating and additive mixtures for alcohol fuels and their method of preparation
US4443348A (en) * 1982-07-13 1984-04-17 General Electric Company Protective lubricant composition
JPS59204700A (en) 1983-05-04 1984-11-20 西山ステンレスケミカル株式会社 Cleaning liquid for grip portion
US4534873A (en) * 1983-09-28 1985-08-13 Clark Gary G Automotive friction reducing composition
US4844825A (en) * 1985-03-20 1989-07-04 Pro-Long Technology Of Canada Ltd. Extreme pressure additive for use in metal lubrication
US4968853A (en) * 1987-12-29 1990-11-06 The Lubrizol Corporation Alpha-olefin polymers
US4859359A (en) * 1988-03-25 1989-08-22 Dyna-5, Inc. Hard surface cleaning and polishing compositions
JP2804271B2 (en) 1988-09-30 1998-09-24 出光興産株式会社 Lubricating oil composition for two-stroke engine
US5120358A (en) * 1989-08-24 1992-06-09 Pippett Robert J Golf practice aid
US5202040A (en) * 1990-06-12 1993-04-13 Texaco Chemical Company Synthetic lubricant base stocks by co-reaction of olefins and anisole compounds
US5136118A (en) * 1990-08-23 1992-08-04 Mobil Oil Corporation High VI synthetic lubricants from cracked refined wax
US5332516A (en) * 1992-04-27 1994-07-26 Stephens James C Friction reducing composition and lubricant for motors
US5431841A (en) * 1993-06-23 1995-07-11 Lockhart; Ronald R. Golf equipment cleaner formulation
US5672572A (en) * 1993-05-27 1997-09-30 Arai; Katsuya Lubricating oil composition
JP2854791B2 (en) * 1993-11-01 1999-02-03 株式会社三協精機製作所 Lubricating oil for sintered oil-impregnated bearings
JP2000503041A (en) 1995-11-22 2000-03-14 エクソン ケミカル パテンツ インコーポレイテッド Two-cycle synthetic lubricating oil
SG64414A1 (en) * 1996-01-16 1999-04-27 Lubrizol Corp Lubricating compositions
US5681797A (en) * 1996-02-29 1997-10-28 The Lubrizol Corporation Stable biodegradable lubricant compositions
IT1282788B1 (en) 1996-06-04 1998-03-31 Euron Spa LUBRICANT COMPOSITIONS WITH LOW PARTICULATE EMISSIONS FOR INTERNAL COMBUSTION ENGINES
US5741764A (en) * 1996-10-15 1998-04-21 The Lubrizol Corporation Two-cycle lubricant containing solvent and high molecular weight polymer
US6074943A (en) * 1997-04-16 2000-06-13 Texas Instruments Incorporated Sidewalls for guiding the via etch
US6774091B2 (en) * 1997-08-27 2004-08-10 Ashland Inc. Lubricant and additive formulation
US5885942A (en) * 1997-09-23 1999-03-23 Nch Corporation Multifunctional lubricant additive
US5972853A (en) * 1997-11-12 1999-10-26 Exxon Chemical Patents Inc. Wear control with dispersants employing poly alpha-olefin polymers
US6046142A (en) * 1998-02-20 2000-04-04 Zilonis; Stephen A. Composition to substantially reduce hooks or slices in golf shots
US6143701A (en) * 1998-03-13 2000-11-07 Exxon Chemical Patents Inc. Lubricating oil having improved fuel economy retention properties
US6008164A (en) * 1998-08-04 1999-12-28 Exxon Research And Engineering Company Lubricant base oil having improved oxidative stability
US6919300B2 (en) * 1999-07-15 2005-07-19 Ashland Inc. Penetrating lubricant composition
US6413916B1 (en) * 1999-07-15 2002-07-02 Ashland Inc. Penetrating lubricant composition
ES2386297T3 (en) * 1999-07-22 2012-08-16 Diversey, Inc. Use of lubricant composition to lubricate a conveyor belt
US6074993A (en) * 1999-10-25 2000-06-13 Infineuma Usa L.P. Lubricating oil composition containing two molybdenum additives
US20040060229A1 (en) 1999-12-10 2004-04-01 Todd Thomas A. Fuel additive systems
WO2001059043A1 (en) * 2000-02-09 2001-08-16 Citizen Watch Co., Ltd. Lubricating oil compositions and watch containing the same
US6761645B1 (en) * 2000-02-18 2004-07-13 Lawrence J. Weber Golf ball lubricant
JP2001271077A (en) 2001-03-30 2001-10-02 Idemitsu Kosan Co Ltd Diesel gas oil composition
US7022766B2 (en) * 2001-05-31 2006-04-04 Mitsui Chemicals, Inc. Olefin block copolymer, viscosity index improver for lubricating oils and lubricating oil composition
US7018960B2 (en) * 2001-06-11 2006-03-28 Fuji Photo Film Co., Ltd. Lubricant composition, method for using and preparing thereof and molecular complex compound used for the same
US6624124B2 (en) * 2001-07-13 2003-09-23 Renewable Lubricants, Inc. Biodegradable penetrating lubricant
US6992049B2 (en) 2002-01-31 2006-01-31 Exxonmobil Research And Engineering Company Lubricating oil compositions
US7018958B2 (en) * 2002-10-22 2006-03-28 Infineum International Limited Lubricating oil compositions
US7124728B2 (en) * 2003-01-24 2006-10-24 Exxonmobil Research And Engineering Company Modification of lubricant properties in an operating all loss lubricating system
WO2005016562A2 (en) * 2003-08-05 2005-02-24 Grip Kleen, Llc Golf grip cleaning wipe
JP4515797B2 (en) 2004-03-19 2010-08-04 新日本石油株式会社 Lubricating oil composition for diesel engines
DE102004038113A1 (en) * 2004-08-05 2006-03-16 Basf Ag Nitrogen-containing heterocyclic compounds as Reibverschleißvermindernder addition to fuels
US8022020B2 (en) * 2005-01-18 2011-09-20 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US8071522B2 (en) * 2005-01-18 2011-12-06 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US8334244B2 (en) * 2005-01-18 2012-12-18 Bestline International Research, Inc. Universal synthetic water displacement multi-purpose penetrating lubricant, method and product-by-process
US7745382B2 (en) * 2005-01-18 2010-06-29 Bestline International Research Inc. Synthetic lubricant additive with micro lubrication technology to be used with a broad range of synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US7931704B2 (en) * 2005-01-18 2011-04-26 Bestline International Research Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8268022B2 (en) * 2005-01-18 2012-09-18 Bestline International Research, Inc. Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8404624B2 (en) 2005-03-21 2013-03-26 Ciba Specialty Chemicals Corporation Antiwear lubricant compositions for use in combustion engines
CA2710326C (en) 2007-12-19 2015-10-20 Bestline International Research, Inc. Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07233001A (en) * 1994-02-22 1995-09-05 Takeda Chem Ind Ltd Aerosol composition
EP1203803A1 (en) * 2000-10-24 2002-05-08 Oil Invest Ltd. Premium/Eurosuper leadfree gasoline
WO2007004789A1 (en) * 2005-07-01 2007-01-11 Pure Life Co Ltd Fuel composition containing bioethanol and biodiesel for internal combustion engine

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8415280B2 (en) 2005-01-18 2013-04-09 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US8022020B2 (en) 2005-01-18 2011-09-20 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US8491676B2 (en) 2005-01-18 2013-07-23 Bestline International Research, Inc. Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US8039424B2 (en) 2005-01-18 2011-10-18 Bestline International Research, Inc. Universal synthetic lubricant additive with micro lubrication technology to be used with synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US8062388B2 (en) 2005-01-18 2011-11-22 Bestline International Research, Inc. Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US8071522B2 (en) 2005-01-18 2011-12-06 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US8071513B2 (en) 2005-01-18 2011-12-06 Bestline International Research, Inc. Universal synthetic penetrating lubricant, method and product-by-process
US8268022B2 (en) 2005-01-18 2012-09-18 Bestline International Research, Inc. Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8623807B2 (en) 2005-01-18 2014-01-07 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US8377861B2 (en) 2005-01-18 2013-02-19 Bestline International Research, Inc. Universal synthetic golf club cleaner and protectant, method and product-by-process to clean, protect golf club faces and rejuvenate golf clubs grips
US7745382B2 (en) 2005-01-18 2010-06-29 Bestline International Research Inc. Synthetic lubricant additive with micro lubrication technology to be used with a broad range of synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US7931704B2 (en) 2005-01-18 2011-04-26 Bestline International Research Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8334244B2 (en) 2005-01-18 2012-12-18 Bestline International Research, Inc. Universal synthetic water displacement multi-purpose penetrating lubricant, method and product-by-process
US8771384B2 (en) 2005-01-18 2014-07-08 Bestline International Research, Inc. Universal synthetic diesel fuel additive product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US9034808B2 (en) 2005-01-18 2015-05-19 Bestline International Research, Inc. Universal synthetic lubricant additive with micro lubrication technology to be used with synthetic or miner host lubricants from automotive, trucking, marine, heavy industry to turbines including, gas, jet and steam
US9284507B2 (en) 2005-01-18 2016-03-15 Bestline International Research, Inc. Universal synthetic diesel fuel additive product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US9309482B2 (en) 2005-01-18 2016-04-12 Bestline International Research, Inc. Universal synthetic water displacement multi-purpose penetrating lubricant, method and product-by-process
US9834735B2 (en) 2007-12-19 2017-12-05 Bestline International Research, Inc. Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US9932538B2 (en) 2010-09-22 2018-04-03 Bestline International Research, Inc. Universal synthetic water displacement multi-purpose penetrating lubricant, method and product-by-process
US11473031B2 (en) 2010-09-22 2022-10-18 Bestline International Research, Inc. Motor oil blend and method for reducing wear on steel and eliminating ZDDP in motor oils by modifying the plastic response of steel
US11377616B2 (en) 2015-01-29 2022-07-05 Bestline International Research Inc. Motor oil blend and method for reducing wear on steel and eliminating ZDDP in motor oils by modifying the plastic response of steel
US10400192B2 (en) 2017-05-17 2019-09-03 Bestline International Research, Inc. Synthetic lubricant, cleaner and preservative composition, method and product-by-process for weapons and weapon systems

Also Published As

Publication number Publication date
JP2011508022A (en) 2011-03-10
US8071513B2 (en) 2011-12-06
CA2710530C (en) 2016-07-05
US20080182769A1 (en) 2008-07-31
CA2710403A1 (en) 2009-07-09
EP2242821A1 (en) 2010-10-27
US8022020B2 (en) 2011-09-20
CA2710403C (en) 2016-02-02
EP2245122A1 (en) 2010-11-03
HK1192900A1 (en) 2014-09-05
CA2710530A1 (en) 2009-07-09
CN101952399B (en) 2014-01-01
CN103865609A (en) 2014-06-18
CN101952399A (en) 2011-01-19
HK1153498A1 (en) 2012-03-30
WO2009085967A1 (en) 2009-07-09
CN103865609B (en) 2015-12-30
US20100273688A1 (en) 2010-10-28

Similar Documents

Publication Publication Date Title
CA2710403C (en) Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US7931704B2 (en) Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US8268022B2 (en) Universal synthetic gasoline fuel conditioner additive, method and product-by-process
US9834735B2 (en) Universal synthetic lubricant, method and product-by-process to replace the lost sulfur lubrication when using low-sulfur diesel fuels
US8415280B2 (en) Universal synthetic penetrating lubricant, method and product-by-process
AU2005316551A1 (en) Composition and methods for improved lubrication, pour point, and fuel performance
CA2647538A1 (en) Fuel additives
BE1027021B1 (en) Marine Fuel Compositions and Methods for Preparing Them
WO2006032012A2 (en) Composition and methods for improved lubrication, pour point, and fuel performance
Miksic et al. Biodegradable VPCI building block for biofuels
CN103923713A (en) Universal synthetic lubricant realizing sulfur lubrication effect lost in use of low sulfur diesel fuel, production method thereof, and products obtained through method

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08867084

Country of ref document: EP

Kind code of ref document: A1

DPE1 Request for preliminary examination filed after expiration of 19th month from priority date (pct application filed from 20040101)
WWE Wipo information: entry into national phase

Ref document number: 12747230

Country of ref document: US

WWE Wipo information: entry into national phase

Ref document number: 2710403

Country of ref document: CA

NENP Non-entry into the national phase

Ref country code: DE

REEP Request for entry into the european phase

Ref document number: 2008867084

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2008867084

Country of ref document: EP