WO2009085783A1 - Compositions donnant du volume - Google Patents

Compositions donnant du volume Download PDF

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Publication number
WO2009085783A1
WO2009085783A1 PCT/US2008/087062 US2008087062W WO2009085783A1 WO 2009085783 A1 WO2009085783 A1 WO 2009085783A1 US 2008087062 W US2008087062 W US 2008087062W WO 2009085783 A1 WO2009085783 A1 WO 2009085783A1
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WO
WIPO (PCT)
Prior art keywords
composition
eyelashes
liposoluble
wax
compositions
Prior art date
Application number
PCT/US2008/087062
Other languages
English (en)
Inventor
Hy Si Bui
Mohamed Kanji
Balanda Atis
Original Assignee
L'oreal S.A.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by L'oreal S.A. filed Critical L'oreal S.A.
Priority to JP2010540784A priority Critical patent/JP5455928B2/ja
Priority to EP20080867867 priority patent/EP2224896A4/fr
Publication of WO2009085783A1 publication Critical patent/WO2009085783A1/fr
Priority to US12/825,003 priority patent/US9278060B2/en

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/10—Preparations containing skin colorants, e.g. pigments for eyes, e.g. eyeliner, mascara
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8164—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers, e.g. poly (methyl vinyl ether-co-maleic anhydride)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/59—Mixtures
    • A61K2800/594—Mixtures of polymers

Definitions

  • the present invention generally relates to compositions for keratin materials (hair or eyelashes) such as, for example, mascaras comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer.
  • Such compositions when applied to keratin materials, can impart synergistically improved volume or thickening to the keratin materials.
  • Such compositions can also possess improved properties and characteristics such as, for example, improved transfer-resistance of the composition, improved waterproofing characteristics, and/or improved long- wear properties.
  • cosmetic compositions particularly mascaras, which possess significantly improved cosmetic properties, particularly with respect to volumizing or thickening eyelashes.
  • one aspect of the present invention is a makeup, care and/or treatment composition for keratin materials such as hair or eyelashes which is able to provide significantly improved volumizing or thickening properties to the keratin materials.
  • compositions for keratin materials for example, hair or eyelashes
  • mascaras comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer.
  • the present invention also relates to methods of increasing the volume (thickness), strength and/or length of keratin materials (for example, hair or eyelashes) comprising applying to the keratin material a keratin material volume-, strength- and/or length-increasing effective amount of a composition comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer.
  • the present invention further relates to methods of making-up keratin materials comprising applying a keratin material making- up effective amount of a composition comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer to keratin materials in need of such making-up.
  • the present invention also relates to methods of inhibiting or reducing flaking off of a composition which has been applied to a keratin material (for example, hair or eyelashes) comprising combining at least one polar modified wax and at least one liposoluble or dispersible rheological polymer prior to application.
  • a keratin material for example, hair or eyelashes
  • the present invention also relates to methods of treating or caring for keratin materials by applying compositions of the present invention to the keratin materials in an amount sufficient to treat and/or care for the keratin materials.
  • the present invention further relates to methods of enhancing the appearance of keratin materials by applying compositions of the present invention to the keratin materials in an amount sufficient to enhance the appearance of the keratin materials.
  • the present invention also relates to methods of making a composition comprising mixing at least one liposoluble or dispersible rheological polymer with at least one polar modified wax to form a composition.
  • the expression “at least one” means one or more and thus includes individual components as well as mixtures/combinations.
  • Transfer resistance refers to the quality exhibited by compositions that are not readily removed by contact with another material, such as, for example, a glass, an item of clothing or the skin, for example, when eating or drinking. Transfer resistance may be evaluated by any method known in the art for evaluating such. For example, transfer resistance of a composition may be evaluated by a modified "kiss” test. The modified "kiss" test may involve application of the composition to human eyelashes followed by "kissing" or rubbing a material with the eyelashes, for example, a sheet of paper, after expiration of a certain amount of time following application, such as 2 minutes after application.
  • transfer resistance of a composition may be evaluated by the amount of product transferred from a wearer to any other substrate, such as transfer from the eyelashes of an individual to clothing after the expiration of a certain amount of time following application.
  • the amount of composition transferred to the substrate e.g., clothing or paper
  • a composition may be transfer resistant if a majority of the product is left on the eyelashes.
  • the amount transferred may be compared with that transferred by other compositions, such as commercially available compositions.
  • Long wear compositions refers to compositions where at least one property chosen from consistency, texture, and color remains the same as at the time of application, as viewed by the naked eye, after an extended period of time, such as, for example, 1 hour, 2 hours, and further such as 8 hours.
  • Long wear properties may be evaluated by any method known in the art for evaluating such properties. For example, long wear may be evaluated by a test involving the application of a composition to eyelashes and evaluating the consistency, texture and color of the composition after an extended period of time. For example, the consistency, texture and color of a mascara composition may be evaluated immediately following application and these characteristics may then be re- evaluated and compared after an individual has worn the mascara composition for a certain amount of time. Further, these characteristics may be evaluated with respect to other compositions, such as commercially available compositions.
  • Waterproof refers to the ability to repel water and permanence with respect to water. Waterproof properties may be evaluated by any method known in the art for evaluating such properties. For example, a mascara composition may be applied to false eyelashes, which may then be placed in water for a certain amount of time, such as, for example, 20 minutes. Upon expiration of the pre-ascertained amount of time, the false eyelashes may be removed from the water and passed over a material, such as, for example, a sheet of paper. The extent of residue left on the material may then be evaluated and compared with other compositions, such as, for example, commercially available compositions.
  • a mascara composition may be applied to false eyelashes, which may then be placed in water for a certain amount of time, such as, for example, 20 minutes. Upon expiration of the pre-ascertained amount of time, the false eyelashes may be removed from the water and passed over a material, such as, for example, a sheet of paper. The extent of residue left on the material may then be evaluated and compared with other compositions
  • a composition may be applied to skin, and the skin may be submerged in water for a certain amount of time. The amount of composition remaining on the skin after the pre-ascertained amount of time may then be evaluated and compared.
  • a composition may be waterproof if a majority of the product is left on the wearer, e.g., eyelashes.
  • Tackiness refers to the adhesion between two substances. For example, the more tackiness there is between two substances, the more adhesion there is between the substances. To quantify “tackiness,” it is useful to determine the "work of adhesion” as defined by IUPAC associated with the two substances. Generally speaking, the work of adhesion measures the amount of work necessary to separate two substances. Thus, the greater the work of adhesion associated with two substances, the greater the adhesion there is between the substances, meaning the greater the tackiness is between the two substances.
  • compositions and methods of the present invention can comprise, consist of, or consist essentially of the essential elements and limitations of the invention described herein, as well as any additional or optional ingredients, components, or limitations described herein or any otherwise useful ingredient found in personal care compositions intended for application to keratin materials.
  • composition of the present invention may be in any form suitable for use on eyelashes such as, for example, non-solid anhydrous, oil-free or emulsion compositions (for example, water-in-oil emulsion, oil-in-water emulsion, multiple emulsion (W/O/W or O/W/O), nanoemulsions, etc.).
  • the compositions of the present invention can be mascaras. Generally speaking, mascaras contain colorants such as pigments. Additionally, the compositions of the present invention can be clear or transparent: that is, they can contain little or no colorants.
  • the compositions of the present invention, particularly those with little or no colorants can be used as a basecoat and/or topcoat for application beneath and/or onto other products applied to eyelashes.
  • stability is tested by placing the composition in a controlled environment chamber for 8 weeks at 25 0 C.
  • the physical condition of the sample is inspected as it is placed in the chamber.
  • the sample is then inspected again at 24 hours, 3 days, 1 week, 2 weeks, 4 weeks and 8 weeks.
  • the sample is examined for abnormalities in the composition such as phase separation if the composition is in the form of an emulsion.
  • the stability is further tested by repeating the 8-week test at 4O 0 C, 37 0 C, 45 0 C, 5O 0 C and/or under freeze- thaw conditions.
  • a composition is considered to lack stability if in any of these tests an abnormality that impedes functioning of the composition is observed.
  • compositions comprising at least one liposoluble or dispersible rheological polymer are provided.
  • a “rheological polymer” is a polymer which increases viscosity of a composition.
  • a “liposoluble or dispersible rheological polymer” is a rheological polymer which is compatible with fatty materials. However, the polymer is not a wax.
  • Suitable examples of acceptable liposoluble polymers include, but are not limited to, polyalkylenes, in particular polybutene, poly(meth)acrylates, alkylcelluloses with a linear or branched, saturated or unsaturated Ci to C 8 alkyl radical, such as ethylcellulose and propylcellulose, silicone polymers that are compatible with the fatty phase, polyvinylpyrrolidone (PVP) or vinylpyrrolidone (VP) homopolymers or copolymers, copolymers of a C 2 to C30, such as C3 to C22 alkene, and combinations thereof.
  • PVP polyvinylpyrrolidone
  • VP vinylpyrrolidone
  • VP copolymers which can be used in the invention, mention may be made of VP/vinyl acetate, VP/ethyl methacrylate, butylated polyvinylpyrrolidone (PVP), VP/ethyl methacrylate/methacrylic acid, VP/eicosene, VP/hexadecene, VP/triacontene, VP/styrene or VP/acrylic acid/lauryl methacrylate copolymer.
  • PVP polyvinylpyrrolidone
  • the liposoluble or dispersible rheological polymer(s) represent from about 0.5% to about 20% of the total weight of the composition, more preferably from about 0.75% to about 15% of the total weight of the composition, and most preferably from about 1 % to about 10%, including all ranges and subranges therebetween.
  • compositions comprising at least one polar modified wax are provided.
  • “Polar modified wax” as used herein refers to waxes made using metallocene catalysis which have been modified to include polar groups or units. Suitable polar modified waxes include those disclosed in U.S. patent application publication no. 20070031361 , the entire contents of which is hereby incorporated by reference.
  • the polar modified wax is based upon a homopolymer and/or copolymer wax of ethylene and/or propylene monomers having a weight-average molecular weight Mw of less than or equal to 25 000 g/mol, preferably of 1000 to 22 000 g/mol and particularly preferably of 2,000 to 20,000 g/mol, a number-average molecular weight Mn of less than or equal to 15 000 g/mol, preferably of 500 to 12 000 g/mol and particularly preferably of 1000 to 5000 g/mol, a molar mass distribution Mw/Mn in the range from 1.5 to 10, preferably from 1.5 to 5, particularly preferably from 1.5 to 3 and especially preferably from 2 to 2.5, which have been obtained by metallocene catalysis.
  • a copolymer wax it is preferable to have, based on the total weight of the copolymer wax, 0.1 to 30.0% by weight of structural units originating from the one monomer and 70.0 to 99.9% by weight of structural units originating from the other monomer.
  • Such homopolymer and copolymer waxes can be made, for example, by the process described in EP 571 882, the entire contents of which is hereby incorporated by reference, using the metallocene catalysts specified therein. Suitable preparation processes include, for example, suspension polymerization, solution polymerization and gas-phase polymerization of olefins in the presence of metallocene catalysts, with polymerization in the monomers also being possible.
  • Polar modified waxes can be produced in a known manner from the homopolymers and copolymers described above by oxidation with oxygen-containing gases, for example air, or by graft reaction with polar monomers, for example maleic acid or acrylic acid or derivatives of these acids.
  • oxygen-containing gases for example air
  • polar monomers for example maleic acid or acrylic acid or derivatives of these acids.
  • the polar modification of metallocene polyolefin waxes by oxidation with air is described, for example, in EP 0 890 583 A1
  • the modification by grafting is described, for example, in U.S. Pat. No. 5,998,547, the entire contents of both of which are hereby incorporated by reference in their entirety.
  • particularly preferred polar modified waxes are hydrophilically modified waxes (that is, waxes which have been modified to provide the waxes with hydrophilic properties).
  • Suitable examples include, but are not limited to, homopolymers and copolymers of hydrophobic groups such as C2-C30 groups, for example ethylene, propylene, C18-C30, etc. which have been modified with hydrophilic units such as, for example, maleic anhydride, acrylate, methacrylate, polyvinylpyrrolidone (PVP), etc.
  • Particularly preferred hydrophilically modified waxes are ethylene and propylene homopolymers and copolymers which have been modified with acrylate and/or maleic anhydride units. .
  • particularly preferred polar modified waxes also include hydrophobically modified waxes (that is, waxes which have been modified to provide the waxes with hydrophobic properties).
  • hydrophobically modified waxes that is, waxes which have been modified to provide the waxes with hydrophobic properties.
  • Suitable examples include, but are not limited to, hyrdrophilic homopolymers and copolymers of maleic anhydride, acrylate, methacrylate, polyvinylpyrrolidone (PVP), etc. which have been modified with hydrophobic groups such as C2-C30 groups, for example ethylene, propylene, C18-C30, etc.
  • Particularly preferred polar modified waxes for use in the present invention are polypropylene-maleic anhydride modified waxes ("PPMA") commercially available from Clariant under the trade name LICOCARE, and C26-C28 alpha olefin maleic acid anhydride copolymer modified waxes.
  • PPMA polypropylene-maleic anhydride modified waxes
  • Such waxes are also known as polypropylene-ethylene- maleic anhydride copolymers and C26-C28 alpha olefin-ethylene-maleic anhydride copolymers due to inclusion of ethylene group(s) resulting from the reaction of the hydrophobic group with the hydrophilic maleic anhydride group.
  • Specific examples of such waxes include products marketed by Clariant under the LicoCare name having designations such as PP207 LP3349, CM401 LP3345, CA301 LP 3346, and CA302 LP 3347.
  • the polar modified wax(es) represent from about 0.1 % to about 30% of the total weight of the composition, more preferably from about 0.5% to about 25% of the total weight of the composition, and most preferably from about 1 % to about 15%, including all ranges and subranges therebetween such as, for example, about 5% to about 15% and about 10% to about 20%.
  • the ratio of liposoluble or dispersible rheological polymer to polar modified wax ranges from about 10:1 to about 1 :10, more preferably from about 1 :5 to about 5:1 , more preferably from about 1 :3 to about 3:1 , and most preferably in a ratio of about 1 :1.
  • more polar modified wax is present in a composition than dispersible rheological polymer.
  • compositions comprising liposoluble or dispersible rheological polymer and at least one polar modified wax possess synergistically improved properties with respect to volumizing (that is, thickening) keratin materials such as hair or eyelashes. That is, surprisingly, the combination of liposoluble or dispersible rheological polymer and polar modified wax results in increased volume (or thickness) of keratin materials such as hair or eyelashes in an amount which is more than additive.
  • the composition may also contain elastomeric compounds such as those sold or made under the names KSG6 from Shin- Etsu, Trefil E-505C or Trefil E-506C from Dow-Corning, Gransil from Grant Industries (SR-CYC, SR DMF10, SR-DC556) or those marketed in the form of preconstituted gels (KSG15, KSG17, KSG16, KSG18, KSG21 from Shin- Etsu, Gransil SR 5CYC gel, Gransil SR DMF 10 gel, Gransil SR DC556 gel, SF 1204 and JK 113 from General Electric or emulsifying elastomers such as those sold under the names of KSG-210, KSG-30, KSG-31 , KSG-32, KSG-33, KSG-40, KSG 41 , KSG-42, KSG-43 and KSG-44 from Shin-Etsu.
  • elastomeric compounds such as those sold or made under the names KSG6 from Shin- Et
  • the composition may also contain modified clays such as, for example, hectorites modified with an ammonium chloride of a C 10 to C 22 fatty acid, such as hectorite modified with distearyldimethylammonium chloride, also known as quatermium-18 bentonite, such as the products sold or made under the names Bentone 34 by the company Rheox, Claytone XL, Claytone 34 and Claytone 40 sold or made by the company Southern Clay, the modified clays known under the name quaternium-18 benzalkonium bentonites and sold or made under the names Claytone HT, Claytone GR and Claytone PS by the company Southern Clay, the clays modified with stearyldimethylbenzoylammonium chloride, known as steralkonium bentonites, such as the products sold or made under the names Claytone APA and Claytone AF by the company Southern Clay, and Baragel 24 sold or made by the company Rheox.
  • modified clays such as, for example, hectorites modified with
  • the composition may also contain silica, such as fumed silica.
  • the fumed silica may have a particle size, which may be nanomethc to micrometric, for example ranging from about 5 nm to 200 nm.
  • the fumed silicas may be obtained by high-temperature hydrolysis of a volatile silicon compound in a hydrogen-oxygen flame, producing a finely divided silica. This process makes it possible to obtain hydrophilic silicas that have a large number of silanol groups at their surface.
  • hydrophilic silicas are sold or made, for example, under the names “Aerosil 130®”, “Aerosil 200®”, “Aerosil 255®”, “Aerosil 300®” and “Aerosil 380®” by the company Degussa, and "CAB-O-SIL HS-55®", “CAB- O-SIL EH-5®”, “CAB-O-SIL LM-130®”, “CAB-O-SIL MS-55® 11 and “CAB-O- SIL M-5®” by the company Cabot.
  • hydrophobic silica may be (a) thmethylsiloxyl groups, which are obtained in particular by treating fumed silica in the presence of hexamethyldisilazane. Silicas thus treated are known as "silica silylate" according to the CTFA (6th edition, 1995).
  • hydrophobic silicas such as fumed silica
  • makes can help in obtaining a translucent or even transparent composition, in particular in the form of a stick, which does not exude, in the absence of opacifying particles such as waxes, fillers and pigments (including nacres).
  • the composition may also contain at least one typical wax.
  • a typical wax is a lipophilic fatty compound that is solid at room temperature (25°C) and atmospheric pressure (760 mmHg, i.e. 101 KPa), which undergoes a reversible solid/liquid change of state, having a melting point of greater than 40 0 C and further such as greater than 55°C and which may be up to 200 0 C.
  • the waxes are those generally used in cosmetics and dermatology; they are, for example, of natural origin, for instance beeswax, ozokerite, carnauba wax, candelilla wax, ouricury wax, Japan wax, cork fiber wax, sugar cane wax, paraffin wax, lignite wax, microcrystalline waxes, lanolin wax, montan wax, ozokerites and hydrogenated oils such as hydrogenated jojoba oil as well as waxes of synthetic origin, for instance polyethylene waxes derived from the polymerization of ethylene, waxes obtained by Fischer-Tropsch synthesis, fatty acid esters and glycerides that are solid at 40 0 C, for example, at above 55°C, fatty alcohol waxes such as those sold by Baker Petrolite under the Performacol name (Performacol 350, 425 and 550) including C30-C50 alcohols, silicone waxes such as alkyl- and alkoxy-poly(di)
  • the melting point values correspond to the melting peak measured by the "Differential Scanning Calorimetry" method with a temperature rise of 5 or 10°C/min.
  • the composition may also include polysilicone-polyamide copolymers such as those disclosed in U.S. patent application publication no. 2004/0170586, a tackifier (for example, those sold under the Regalite name) and/or a block copolymer (for example, those sold under the Kraton name).
  • a tackifier for example, those sold under the Regalite name
  • a block copolymer for example, those sold under the Kraton name.
  • the compositions contain so little of the viscosity increasing agents discuss above that the presence of such agents does not affect the cosmetic properties of the composition.
  • compositions are substantially free of such viscosity increasing agents (i.e., contain less than about 1 % viscosity increasing agents), essentially free of such viscosity increasing agents (i.e., contain less than about 0.5% viscosity increasing agents) or free of such viscosity increasing agents (i.e., contain less than about 0.1 % viscosity increasing agents).
  • the compositions contain so little elastomer and/or wax that the presence of such elastomers and/or waxes does not affect the cosmetic properties of the composition.
  • the compositions are substantially free of such elastomers and/or waxes (i.e., contain less than about 0.5% elastomers and/or waxes), essentially free of such elastomers and/or waxes (i.e., contain less than about 0.25% elastomers and/or waxes) or free of such elastomers and/or waxes (i.e., contain less than about 0.1 % elastomers and/or waxes).
  • compositions optionally further comprising at least one volatile oil are provided.
  • the at least one volatile oil is a silicone volatile oil, a hydrocarbon volatile oil, or a mixture thereof.
  • the composition may contain one or more volatile silicone oils.
  • volatile silicone oils include linear or cyclic silicone oils having a viscosity at room temperature less than or equal to 6cSt and having from 2 to 7 silicon atoms, these silicones being optionally substituted with alkyl or alkoxy groups of 1 to 10 carbon atoms.
  • Other volatile oils which may be used include KF 96A of 6 cSt viscosity, a commercial product from Shin Etsu having a flash point of 94°C.
  • the volatile silicone oils have a flash point of at least 40 0 C.
  • Non-limiting examples of volatile silicone oils are listed in Table 1 below.
  • a volatile linear silicone oil may be employed in the compositions of the present invention.
  • Suitable volatile linear silicone oils include those described in U.S. patent no. 6,338,839 and WO03/042221 , the contents of which are incorporated herein by reference.
  • the volatile linear silicone oil is decamethyltetrasiloxane.
  • the decamethyltetrasiloxane is further combined with another solvent that is more volatile than decamethyltetrasiloxane.
  • the composition may contain one or more non-silicone volatile oils and may be selected from volatile hydrocarbon oils, volatile esters and volatile ethers.
  • volatile non-silicone oils include, but are not limited to, volatile hydrocarbon oils having from 8 to 16 carbon atoms and their mixtures and in particular branched Ce to Ci6 alkanes such as Cs to Ci ⁇ isoalkanes (also known as isoparaffins), isododecane, isodecane, isohexadecane, and for example, the oils sold under the trade names of lsopar or Permethyl, the C 8 to C 16 branched esters such as isohexyl or isodecyl neopentanoate and their mixtures.
  • the volatile non- silicone oils have a flash point of at least 40 0 C.
  • the volatility of the solvents/oils can be determined using the evaporation speed as set forth in U.S. patent no. 6,338,839.
  • the volatile oil(s), when present, represent from about 5% to about 90% of the total weight of the composition, more preferably from about 10% to about 80% of the total weight of the composition, and most preferably from about 20% to about 75%, including all ranges and subranges therebetween.
  • the compositions may optionally comprise at least one coloring agent (colorant).
  • suitable coloring agents include but are not limited to pigments, dyes, such as liposoluble dyes, nacreous pigments, and pearling agents.
  • a make-up composition such as a mascara composition.
  • the composition does not contain colorants, it is a clear or transparent composition which can be used as a basecoat (or topcoat) prior to (or after) application of a make-up composition such as a mascara to eyelashes, or it can be used as a hair treatment composition such as, for example, a hair conditioner or mousse.
  • topcoats, basecoats, hair treatment products and the like could contain colorants, and/or that a mascara or make-up composition could contain little or no colorant.
  • Representative liposoluble dyes which may be used according to the present invention include Sudan Red, DC Red 17, DC Green 6, ⁇ -carotene, soybean oil, Sudan Brown, DC Yellow 11 , DC Violet 2, DC Orange 5, annatto, and quinoline yellow.
  • the liposoluble dyes, when present, generally have a concentration ranging up to 20% by weight of the total weight of the composition, such as from 0.0001 % to 6%.
  • the nacreous pigments which may be used according to the present invention may be chosen from white nacreous pigments such as mica coated with titanium or with bismuth oxychloride, colored nacreous pigments such as titanium mica with iron oxides, titanium mica with ferric blue or chromium oxide, titanium mica with an organic pigment chosen from those mentioned above, and nacreous pigments based on bismuth oxychloride.
  • the pigments which may be used according to the present invention, may be chosen from white, colored, inorganic, organic, polymeric, nonpolymeric, coated and uncoated pigments.
  • Representative examples of mineral pigments include titanium dioxide, optionally surface- treated, zirconium oxide, zinc oxide, cerium oxide, iron oxides, chromium oxides, manganese violet, ultramarine blue, chromium hydrate, and ferric blue.
  • Representative examples of organic pigments include carbon black, pigments of D & C type, and lakes based on cochineal carmine, barium, strontium, calcium, and aluminum.
  • the pigments may be present in the composition in a concentration ranging up to 50 % by weight of the total weight of the composition, such as from 0,5% to 40%, and further such as from 2% to 30%.
  • the pigments, including nacreous pigments may, for example, represent up to 50% by weight of the composition.
  • compositions optionally further comprising at least one at least one film forming agent are provided.
  • Acceptable film forming agents are known in the art and include, but are not limited to, those disclosed in U.S. patent application publication no. 2004/0170586, the entire contents of which is hereby incorporated by reference.
  • Non-limiting representative examples of such film forming agents include silicone resins such as, for example, MQ resins (for example, trimethylsiloxysilicates), T- propyl silsesquioxanes and MK resins (for example, polymethylsilsesquioxanes), silicone esters such as those disclosed in U.S. Pat. Nos.
  • polymers comprising a backbone chosen from vinyl polymers, methacrylic polymers, and acrylic polymers and at least one chain chosen from pendant siloxane groups and pendant fluorochemical groups such as those disclosed in U.S. Pat. Nos. 5,209,924, 4,693,935, 4,981 ,903, 4,981 ,902, and 4,972,037, and WO 01/32737, the disclosures of which are hereby incorporated by reference, polymers such as those described in U.S. Pat. No.
  • the film former when present, is present in the composition in an amount ranging from 0.1 % to 30% by weight relative to the total weight of the composition.
  • the film former is present in an amount ranging from 0.5% to 20% by weight relative to the total weight of the composition, and more preferably from 2% to 15%, including all ranges and subranges therebetween.
  • the film former of the present invention may be commercially available, and may come from suppliers in the form of a dilute solution. The amounts of the film former disclosed herein therefore reflect the weight percent of active material.
  • the compositions of the present invention further comprise water.
  • water is preferably present in an amount ranging from about 0.6 to about 70 %, preferably from about 3.0 to 60%, and more preferably from about 5 to about 50 % relative to the total weight of the composition.
  • water-containing cosmetic compositions are mascaras, and are emulsions or dispersions.
  • the compositions of the present invention are in the form of an emulsion.
  • Suitable emulsion forms include but are not limited to oil-in-water, water-in- oil, oil-in-water-in-oil, water-in-oil-in-water and nanoemulsions (emulsions whose oil globules are of very fine particle size, that is to say that they have a number-average size of less than about 100 nanometers (nm)).
  • Emulsions contain at least one oil phase and at least one aqueous phase.
  • emulsions contain surfactants or surfactant-like materials which provide stability to the emulsions and inhibit de-phasing of the emulsions.
  • composition of the invention can also comprise any additive usually used in the field under consideration.
  • dispersants such as poly(12-hydroxystearic acid), antioxidants, essential oils, sunscreens, preserving agents, fragrances, fillers, neutralizing agents, cosmetic and dermatological active agents such as, for example, emollients, moisturizers, vitamins, essential fatty acids, surfactants, pasty compounds and mixtures thereof can be added.
  • emollients such as, moisturizers, vitamins, essential fatty acids, surfactants, pasty compounds and mixtures thereof
  • additional components can be found in the other references which have been incorporated by reference in this application. Still further examples of such additional ingredients may be found in the International Cosmetic Ingredient Dictionary and Handbook (9 th ed. 2002).
  • These substances may be selected variously by the person skilled in the art in order to prepare a composition which has the desired properties, for example, consistency or texture.
  • These additives may be present in the composition in a proportion from 0% to 99% (such as from 0.01 % to 90%) relative to the total weight of the composition and further such as from 0.1 % to 50% (if present), including all ranges and subranges therebetween.
  • composition of the invention should be cosmetically or dermatologically acceptable, i.e., it should contain a nontoxic physiologically acceptable medium and should be able to be applied to the eyelashes of human beings.
  • Non-limiting examples of such additional components include non-volatile oils such as silicone oils (for example, dimethicone, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, etc) or hydrocarbon oils (for example, esters).
  • non-volatile oils such as silicone oils (for example, dimethicone, phenyl trimethicone, trimethyl pentaphenyl trisiloxane, etc) or hydrocarbon oils (for example, esters).
  • the compositions of the present invention are substantially free of silicone oils (i.e., contain less than about 0.5 % silicone oils).
  • the compositions are substantially free of non-silicone oils (i.e., contain less than about 0.5% non-silicone oils).
  • the compositions are substantially free of non-volatile oils (i.e., contain less than about 0.5% non-volatile oils).
  • methods of increasing keratin material for example, hair or eyelash
  • keratin material for example, hair or eyelash
  • a keratin material volume-, strength- and/or length-increasing effective amount of a composition comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer are provided.
  • the compositions may be applied to the keratin materials as needed, preferably once or twice daily, more preferably once daily and then preferably allowed to dry before subjecting to contact such as with clothing or other objects.
  • sufficient polar modified wax is combined with sufficient liposoluble or dispersible rheological polymer such that the performance properties of the compositions are greater than the performance properties of compositions containing either ingredient individually (that is, synergism exists with respect to the at least one polar modified wax and at least one liposoluble or dispersible rheological polymer).
  • a composition provides to a keratin material (for example, hair or eyelashes) after or upon application to the keratin material comprising combining at least one polar modified wax and at least one liposoluble or dispersible rheological polymer prior to application.
  • a keratin material for example, hair or eyelashes
  • Such a combination of the required elements in a single composition at any time prior to application of the composition to the keratin material results in increasing of the volume, strength and/or length of the keratin material after application to the keratin material.
  • methods of making-up keratin materials comprising applying a keratin material making-up effective amount of a composition comprising at least one polar modified wax and at least one liposoluble or dispersible rheological polymer to keratin materials in need of such making-up are provided.
  • "making up" the keratin material includes applying at least one coloring agent to the keratin material in an amount sufficient to provide color to the keratin material
  • compositions of the present invention are provided.
  • compositions of the present invention by applying compositions of the present invention to the keratin materials in an amount sufficient to enhance the appearance of the keratin materials are provided.
  • compositions of the present invention are applied topically to keratin materials (for example, hair or eyelashes) in an amount sufficient to treat, care for and/or make up the keratin materials, or to enhance the appearance of the keratin materials.
  • the compositions may be applied to eyelashes as needed, preferably once or twice daily, more preferably once daily and then preferably allowed to dry before subjecting to contact such as with clothing or other objects.
  • compositions having improved cosmetic properties such as, for example, improved feel upon application (for example, deposit), flake resistance, long wear, transfer resistance or waterproof properties are provided.
  • improved properties may also be chosen from improved flexibility, wearability, drying time or retention as well as reduced tackiness or migration over time
  • polar modified wax is in an an oil phase
  • liposoluble or dispersible rheological polymer is in an aqueous phase
  • the liposoluble or dispersible rheological polymer and the polar modified wax are combined when the aqueous phase and the oil phase are combined.
  • Such preferred procedures can allow, among other things, the preparation of emulsions which are substantially or essentially free of surfactants, if desired.
  • methods of inhibiting or reducing flaking off of a composition which has been applied to a keratin material comprising combining at least one polar modified wax and at least one liposoluble or dispersible rheological polymer in the composition prior to application are provided.
  • a keratin material for example, hair or eyelashes
  • Such a combination of the required elements in a single composition at any time prior to application of the composition to the keratin material results in inhibition and/or reduction of flaking off of the composition from the keratin material after application to the keratin material.
  • Example 1-6 Mascara

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  • Veterinary Medicine (AREA)
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Abstract

La présente invention concerne une composition, en particulier une composition cosmétique, comprenant au moins une cire modifiée polaire et au moins un polymère rhéologique liposoluble ou que l'on peut disperser. L'invention concerne également des procédés d'utilisation de telles compositions.
PCT/US2008/087062 2007-12-28 2008-12-17 Compositions donnant du volume WO2009085783A1 (fr)

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JP2010540784A JP5455928B2 (ja) 2007-12-28 2008-12-17 ボリュームを出すための組成物
EP20080867867 EP2224896A4 (fr) 2007-12-28 2008-12-17 Compositions donnant du volume
US12/825,003 US9278060B2 (en) 2007-12-28 2010-06-28 Composition containing a polar modified polymer

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US1740707P 2007-12-28 2007-12-28
US61/017,407 2007-12-28

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PCT/US2008/087314 Continuation WO2009085888A1 (fr) 2007-12-28 2008-12-18 Composition contenant un polymère polyorganosiloxane et une cire modifiée polaire

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EP2359805A1 (fr) * 2009-12-18 2011-08-24 L'oreal S.A. Composition contenant une dispersion aqueuse de polyuréthane et un polymère à modifcation polaire soluble dans l'huile
WO2012024375A3 (fr) * 2010-08-18 2013-10-10 Kao Corporation Compositions qui donnent du volume aux cheveux
EP2322245A3 (fr) * 2009-06-29 2014-03-12 L'oreal S.A. Base de crème hydratante sous forme d'émulsion
US20140194535A1 (en) * 2011-09-30 2014-07-10 L'oreal Anhydrous emulsions containing polylysine and polar modified polymer

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US20070031361A1 (en) * 2005-06-08 2007-02-08 Hans-Friedrich Herrmann Cosmetic, pharmaceutical and dermatological preparations comprising homopolymer and/or copolymer waxes of the monomers ethylene and/or propylene
US20070256700A1 (en) * 2006-04-21 2007-11-08 Sophie Bodelin Eyelash makeup kit and process therefor

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JPH06279236A (ja) * 1993-03-24 1994-10-04 Noda Wax:Kk 変性ワックス及びこれを含有する化粧料
NZ314346A (en) * 1996-03-15 1998-02-26 Unilever Plc Mascara composition comprising natural beeswax
JP4548685B2 (ja) * 2000-07-12 2010-09-22 信越化学工業株式会社 固形化粧料
US7879316B2 (en) * 2002-06-12 2011-02-01 L'oreal Cosmetic composition containing a polyorganosiloxane polymer
JP4815136B2 (ja) * 2004-03-26 2011-11-16 株式会社コーセー 含水睫用化粧料
EP1681046A3 (fr) * 2004-11-13 2008-07-30 Clariant Produkte (Deutschland) GmbH Compositions cosmétiques, pharmaceutiques et dermatologiques contenant des cires copolymères
DE102005007980A1 (de) * 2005-02-22 2006-02-23 Clariant Gmbh Kosmetische, pharmazeutische oder dermatologische Zubereitungen enthaltend Copolymerwachse

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US20070031361A1 (en) * 2005-06-08 2007-02-08 Hans-Friedrich Herrmann Cosmetic, pharmaceutical and dermatological preparations comprising homopolymer and/or copolymer waxes of the monomers ethylene and/or propylene
US20070256700A1 (en) * 2006-04-21 2007-11-08 Sophie Bodelin Eyelash makeup kit and process therefor

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2322245A3 (fr) * 2009-06-29 2014-03-12 L'oreal S.A. Base de crème hydratante sous forme d'émulsion
EP2359805A1 (fr) * 2009-12-18 2011-08-24 L'oreal S.A. Composition contenant une dispersion aqueuse de polyuréthane et un polymère à modifcation polaire soluble dans l'huile
US9078835B2 (en) 2009-12-18 2015-07-14 L'oreal Composition containing an aqueous dispersion of polyurethane and an oil-soluble polar modified polymer
WO2012024375A3 (fr) * 2010-08-18 2013-10-10 Kao Corporation Compositions qui donnent du volume aux cheveux
AU2011292052B2 (en) * 2010-08-18 2014-01-16 Kao Corporation Hair volumizing compositions
US20140194535A1 (en) * 2011-09-30 2014-07-10 L'oreal Anhydrous emulsions containing polylysine and polar modified polymer
US9763859B2 (en) * 2011-09-30 2017-09-19 L'oreal Anhydrous emulsions containing polylysine and polar modified polymer

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JP2011508741A (ja) 2011-03-17
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JP5455928B2 (ja) 2014-03-26

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