WO2009071463A3 - Oxidative methankopplung via membranreaktor - Google Patents

Oxidative methankopplung via membranreaktor Download PDF

Info

Publication number
WO2009071463A3
WO2009071463A3 PCT/EP2008/066120 EP2008066120W WO2009071463A3 WO 2009071463 A3 WO2009071463 A3 WO 2009071463A3 EP 2008066120 W EP2008066120 W EP 2008066120W WO 2009071463 A3 WO2009071463 A3 WO 2009071463A3
Authority
WO
WIPO (PCT)
Prior art keywords
membrane reactor
coupling via
via membrane
methane coupling
oxidative methane
Prior art date
Application number
PCT/EP2008/066120
Other languages
English (en)
French (fr)
Other versions
WO2009071463A2 (de
Inventor
Ekkehard Schwab
Hartwig Voss
Frank Kiesslich
Otto Machhammer
Andrea Dittmar
Manfred Noack
Uwe Dingerdissen
Gabriele Georgi
Original Assignee
Basf Se
Ekkehard Schwab
Hartwig Voss
Frank Kiesslich
Otto Machhammer
Andrea Dittmar
Manfred Noack
Uwe Dingerdissen
Gabriele Georgi
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Se, Ekkehard Schwab, Hartwig Voss, Frank Kiesslich, Otto Machhammer, Andrea Dittmar, Manfred Noack, Uwe Dingerdissen, Gabriele Georgi filed Critical Basf Se
Publication of WO2009071463A2 publication Critical patent/WO2009071463A2/de
Publication of WO2009071463A3 publication Critical patent/WO2009071463A3/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C07C2/82—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling
    • C07C2/84—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen oxidative coupling catalytic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/34—Manganese

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

Die vorliegende Erfindung betrifft die oxidative Kopplung von Methan zu höheren Alkanen und Alkenen, bei der der Sauerstoff durch eine gasdichte, gemischt leitende Membran der Reaktionszone zugeführt wird. Die oxidative Kopplung erfolgt katalytisch, wobei die gasdichte Membran als Katalysator dienen kann, aber auch zusätzlich ein bei der oxidativen Kopplung von Methan aktiver Katalysator eingesetzt werden kann.
PCT/EP2008/066120 2007-12-03 2008-11-25 Oxidative methankopplung via membranreaktor WO2009071463A2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07122130.3 2007-12-03
EP07122130 2007-12-03

Publications (2)

Publication Number Publication Date
WO2009071463A2 WO2009071463A2 (de) 2009-06-11
WO2009071463A3 true WO2009071463A3 (de) 2009-07-23

Family

ID=40451272

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/066120 WO2009071463A2 (de) 2007-12-03 2008-11-25 Oxidative methankopplung via membranreaktor

Country Status (1)

Country Link
WO (1) WO2009071463A2 (de)

Families Citing this family (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2326417A1 (de) 2008-09-10 2011-06-01 Basf Se Integriertes verfahren zur herstellung von carbonyleisenpulver und von kohlenwasserstoffen
WO2011054738A1 (de) 2009-11-06 2011-05-12 Basf Se Eisenhaltiger heterogenkatalysator und verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff
CN102665899B (zh) 2009-11-06 2015-08-12 巴斯夫欧洲公司 含铁和铜的多相催化剂和通过用氢气转化一氧化碳制备烯烃的方法
WO2011054734A1 (de) 2009-11-06 2011-05-12 Basf Se Eisen- und manganhaltiger heterogenkatalysator und verfahren zur herstellung von olefinen durch umsetzung von kohlenmonoxid mit wasserstoff
EP2501781B1 (de) 2009-11-19 2014-03-19 Basf Se Verfahren zur selektiven herstellung von leichten olefinen
AU2011258422C1 (en) 2010-05-24 2017-03-30 Lummus Technology Llc Nanowire catalysts
CA2837201C (en) 2011-05-24 2018-02-13 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
DE102011080294A1 (de) * 2011-08-02 2013-02-07 Technische Universität Berlin Verfahren zur oxidativen Umwandlung von gasförmigen Alkanen in einem Wirbelschicht-Membran-Reaktor und ein Reaktor zur Durchführung dieses Verfahrens
EA029490B1 (ru) * 2011-11-29 2018-04-30 Силурия Текнолоджиз, Инк. Катализаторы из нанопроволоки и способы их применения и получения
US9133079B2 (en) 2012-01-13 2015-09-15 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
US9446397B2 (en) 2012-02-03 2016-09-20 Siluria Technologies, Inc. Method for isolation of nanomaterials
CA2874526C (en) 2012-05-24 2022-01-18 Siluria Technologies, Inc. Oxidative coupling of methane systems and methods
EP2855011A2 (de) 2012-05-24 2015-04-08 Siluria Technologies, Inc. Katalytische formen und formulierungen
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
US9598328B2 (en) 2012-12-07 2017-03-21 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
US20140274671A1 (en) 2013-03-15 2014-09-18 Siluria Technologies, Inc. Catalysts for petrochemical catalysis
EP3074119B1 (de) 2013-11-27 2019-01-09 Siluria Technologies, Inc. Reaktoren und systeme zur oxidativen kupplung von methan
CA3123783A1 (en) 2014-01-08 2015-07-16 Lummus Technology Llc Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
EP3097068A4 (de) 2014-01-09 2017-08-16 Siluria Technologies, Inc. Oxidative kupplung von methanimplementierungen zur olefinherstellung
CN103736491B (zh) * 2014-01-17 2015-10-07 河北工业大学 一种复合石墨烯的甲烷催化剂及其制备方法
EP3137211A2 (de) 2014-05-02 2017-03-08 Siluria Technologies, Inc. Heterogene katalysatoren
EP3194070B1 (de) 2014-09-17 2020-12-23 Lummus Technology LLC Katalysatoren zur oxidativen kupplung von methan und oxidativen dehydrierung von ethan
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US20160289143A1 (en) 2015-04-01 2016-10-06 Siluria Technologies, Inc. Advanced oxidative coupling of methane
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US20170107162A1 (en) 2015-10-16 2017-04-20 Siluria Technologies, Inc. Separation methods and systems for oxidative coupling of methane
CA3019396A1 (en) 2016-04-13 2017-10-19 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
CN110382108A (zh) * 2016-09-12 2019-10-25 北卡罗来纳州立大学 用于碳氢化合物氧化脱氢的载氧催化剂及其制备方法及应用方法
WO2018118105A1 (en) 2016-12-19 2018-06-28 Siluria Technologies, Inc. Methods and systems for performing chemical separations
ES2960342T3 (es) 2017-05-23 2024-03-04 Lummus Technology Inc Integración de procedimientos de acoplamiento oxidativo del metano
WO2019010498A1 (en) 2017-07-07 2019-01-10 Siluria Technologies, Inc. SYSTEMS AND METHODS FOR OXIDIZING METHANE COUPLING

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4827071A (en) * 1986-06-09 1989-05-02 Arco Chemical Technology, Inc. Ceramic membrane and use thereof for hydrocarbon conversion
DE102005060171A1 (de) * 2005-12-14 2007-06-21 Uhde Gmbh Oxidationsreaktor und Oxidationsverfahren

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4827071A (en) * 1986-06-09 1989-05-02 Arco Chemical Technology, Inc. Ceramic membrane and use thereof for hydrocarbon conversion
DE102005060171A1 (de) * 2005-12-14 2007-06-21 Uhde Gmbh Oxidationsreaktor und Oxidationsverfahren

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
SHERMAN J. XU AND WILLIAM J. THOMSON: "Perovskite-Type Oxide Membranes for the Oxidative Coupling of Methane", AICHE JOURNAL, vol. 43, no. S11, 1997, pages 2731 - 2740, XP002528305 *
WANG H ET AL: "Oxidative coupling of methane in Ba0.5Sr0.5Co0.8Fe0.2O3-delta tubular membrane reactors", CATALYSIS TODAY, ELSEVIER, vol. 104, no. 2-4, 17 May 2005 (2005-05-17), pages 160 - 167, XP025356889, ISSN: 0920-5861 *
XIAOYAO TAN, K. LI: "Oxidative Coupling of Methane in a Perovskite Hollow-Fiber Membrane Reactor", IND. ENG. CHEM. RES., vol. 45, 2006, pages 142 - 149, XP002528307 *
YAPING LU, ANTHONY G. DIXON, WILLIAM R. MOSER, YI HUA MA: "Oxidative coupling of methane in a modi"ed c-alumina membrane reactor", CHEMICAL ENGINEERING SCIENCE, vol. 55, 2000, pages 4901 - 4912, XP002528306 *

Also Published As

Publication number Publication date
WO2009071463A2 (de) 2009-06-11

Similar Documents

Publication Publication Date Title
WO2009071463A3 (de) Oxidative methankopplung via membranreaktor
WO2013177433A3 (en) Oxidative coupling of methane systems and methods
CL2011002588A1 (es) Metodo de produccion de un producto de carbon solido, en que se mezcla una corriente de gas que contiene oxido de carbono y una corriente de gas que contiene un agente reductor, en que se hace reaccionar la mezcla de gases en una zona de reaccion en presencia de un catalizador; y composicion de materia.
WO2010069488A8 (de) Verfahren zur oxidativen kupplung von methan und herstellung von synthesegas
WO2015031357A3 (en) Catalytic alkane conversion
MY157440A (en) Catalyst composition for selective catalytic reduction of exhaust gases
MX2007012666A (es) Proceso catalitico integrado para convertir alcanos en alquenos, y los catalizadores utiles para el mismo.
TW200611889A (en) Process for preparing tert-butanol from isobutene-containing hydrocarbon mixtures
EP2086913A4 (de) Verfahren zur herstellung von kohlendioxid und methan durch katalytische gasreaktion
MX2010002725A (es) Produccion de oxido de etileno utilizando concentracion moderadora fija.
WO2007123932A3 (en) Alkylene oxide catalyst and use thereof
WO2010024975A8 (en) Process for producing phenol
EA201390915A1 (ru) Реактор для проведения автотермической дегидрогенизации газовой фазы
EA201100960A1 (ru) Способ увеличения содержания монооксида углерода в синтез-газе
PT1989172E (pt) Aminação direta de hidrocarbonetos
MY149735A (en) Styrene monomer process based on oxidative dehydrogenation of ethylbenzene using co2 as a soft oxidant
TW200635665A (en) Charging of a reactor
GB0605232D0 (en) Oxygen removal
IN2015DN00736A (de)
CL2011001311A1 (es) Reactor y proceso para reacciones exotermicas de fase gaseosa que comprende una zona de regreso, una zona de reaccion que comprende al menos un catalizador, una zona de salida para el gas de gasogeno y una linea de alimentacion para una mezcla gaseosa; proceso para efectuar reacciones de fase gaseosa usando dicho reactor; y uso del reactor.
MX2009000282A (es) Catalizador apoyado para la conversion de propano en propeno y su uso en un proceso para esta conversion.
WO2008012249A3 (de) Verfahren zum langzeitbetrieb einer kontinuierlich betriebenen heterogen katalysierten partiellen dehydrierung eines zu dehydrierenden kohlenwasserstoffs
CA2556280A1 (en) Process for reforming hydrocarbons with carbon dioxide by the use of a selectively permeable membrane reactor
TW200602300A (en) Process for production of cumene hydroperoxide
WO2008135398A3 (en) A process for the preparation of an olefin oxide

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08857767

Country of ref document: EP

Kind code of ref document: A2

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 08857767

Country of ref document: EP

Kind code of ref document: A2