WO2009037212A1 - Additive für wasserbasierte bohrspülmittel - Google Patents
Additive für wasserbasierte bohrspülmittel Download PDFInfo
- Publication number
- WO2009037212A1 WO2009037212A1 PCT/EP2008/062200 EP2008062200W WO2009037212A1 WO 2009037212 A1 WO2009037212 A1 WO 2009037212A1 EP 2008062200 W EP2008062200 W EP 2008062200W WO 2009037212 A1 WO2009037212 A1 WO 2009037212A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- fatty acids
- oligoglycerol
- water
- esters
- use according
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/03—Specific additives for general use in well-drilling compositions
- C09K8/035—Organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/14—Clay-containing compositions
- C09K8/18—Clay-containing compositions characterised by the organic compounds
- C09K8/22—Synthetic organic compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/02—Well-drilling compositions
- C09K8/04—Aqueous well-drilling compositions
- C09K8/26—Oil-in-water emulsions
- C09K8/28—Oil-in-water emulsions containing organic additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S507/00—Earth boring, well treating, and oil field chemistry
- Y10S507/904—Process of making fluids or additives therefor
Definitions
- the present application relates to the use of certain esters as an additive in water-based drilling fluids, as well as water-based drilling fluids containing these additives.
- the additives according to the invention serve in particular to improve the lubricating effect of the drilling fluids.
- Liquid flushing systems for sinking rock boreholes with application of the detached cuttings are possibly thickened, water-based or oil-based systems.
- the class of purely water-based flushing systems goes back the longest in historical development in the past. However, their use is associated with deficits, in particular, the too low lubricating effect of the flushing is to be highlighted as a disadvantage.
- Working with purely water-based systems therefore requires the use of lubricating components.
- lubricants include e.g. Mineral oils or animal and vegetable oils, ie triglycerides of fatty acids and carboxylic acid esters of mono-alcohols.
- Soybean oil sulfonate can be used in water- and oil-based systems, but it shows a significant foaming, especially in water-based rinses, which limits the performance properties.
- esters of monocarboxylic acids with monohydric alcohols as a suitable lubricant for water-based drilling fluid systems.
- a 2-Ethylhexyloleat as a suitable lubricant for silicate-containing aqueous rinses disclosed.
- DE 196 47 598 describes C12-30 fatty alcohols and their blending with fatty acid esters as suitable lubricants for purely water-based, silicate-containing drilling fluids.
- esters are triglycerides of fatty acids.
- carboxylic acid esters have a particularly pronounced lubricating effect for the purpose of soil breakdown, which is used in many ways.
- their use in water-based systems, and in particular in comparatively high alkaline waterglass systems can lead to considerable difficulties.
- ester cleavage components with a strong foaming tendency can arise as secondary products, which then introduce undesirable problems into the rinsing system.
- the invention relates to the use of oligoglycerol fatty acid esters prepared from (a) an acid component selected from
- a polyol component selected from oligoglycerols or alkoxylates of oligoglycerols as an additive in water-based drilling fluids, preferably to improve the lubricity of the muds.
- the oligoglycerol esters according to the invention are compounds known per se, which can be prepared, for example, by acid or base-catalyzed esterification directly from oligoglycerides. can be obtained with the fatty acids.
- the oligoglycerol esters are also referred to as oligoglycerol fatty acid esters or oligoglycerides.
- EP 064 697 A1 describes various oligoglycerol esters as lubricants for PVC. In this document, the preparation of Oligolycerinester by basic catalysis of fatty acids and poly- or oligoglycerols is described.
- oligoglycerol esters within the meaning of the invention are generally liquid compounds at room temperature, which consist of a mixture of different oligoglycerol esters, wherein starting materials, in particular glycerol, may also be present Depending on the quality of the oligoglycerols, these may contain between 20 and 45% by weight of glycerol, between 20 and 40% by weight of diglycerin, between oligoglycerol esters and oligoglycerol esters 10 and 20 wt .-% of triglycerol and between 1 to 10 wt .-% of tetraglycerol and between 0.5 to 5 wt .-% of pentaglycerol.
- esters of this document are necessarily diesters of these C10-C20 fatty acids with di- or triglycerol or polyglycerols, wherein in particular only the polyglycerol-2-diisostearate and polyglycerol-3-diisostearate are disclosed. These esters are used according to the teachings of US 2003/0114316 as emulsifiers to produce the desired invert emulsion.
- Suitable acid components (a) of the esters according to the invention are in particular the fatty acids of the type (a1) which follow the formula (I).
- caproic acid caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, linoleic acid, linolenic acid, elaeostearic acid, arachidic acid, gadoleic acid, behenic acid and Erucic acid and mixtures thereof, for example, due to technical reasons, in the pressure splitting of natural fats and oils, in the reduction of aldehydes from the Roelen oxo synthesis.
- oligoglycerol esters in which the fatty acid component (a1) is selected from mono- or polyunsaturated, preferably linear, fatty acids and preferably the linear unsaturated monocarboxylic acids, with oleic acid, even in technical qualities, being particularly preferred.
- oligoglycerol esters whose component (a1) is selected from tall oil fatty acids.
- Tall oil fatty acids contain in particular mixtures of linoleic acid and conjugated C18 fatty acids (45-65% by weight), oleic acid (25-45% by weight), octadeca-5,9,12-trienoic acid (5-12% by weight) and saturated fatty acids (1-3% by weight).
- dicarboxylic acids (a2) and / or dimer fatty acids or oligomeric fatty acids of the type (a3) or (a4) are also suitable.
- suitable acid components are the dicarboxylic acids (a2). These are those carboxylic acids which contain two -COOH functions in the molecule, with the saturated dicarboxylic acids in particular being preferred.
- the dicarboxylic acids (a2) preferably contain between 4 and 22 C atoms, in particular between 6 and 18 C atoms. Examples which may be mentioned are the oxalic, malonic, succinic, glutaric, adipic, pimelinic, suberic, azealic or sebacic acid. Also unsaturated dicarboxylic acids are possible, e.g. the fumar or
- the dicarboxylic acids of group (a2) do not include the dimer fatty acids according to group (a3).
- Dimer fatty acids (a3) are at room temperature (21 0 C) liquid, oxidationsstabili- catalyzed dicarboxylic acids, for example, be obtained by catalytic dimerization of unsaturated fatty acids such as oleic acid, ricinene fatty acid or tall oil fatty acid with exclusion of oxygen. Depending on the fatty acid used, the linkage gives rise to linear, monocyclic or aromatic structures. The reaction proceeds with isomerization of isolated double bonds predominantly after addition of the Diels-Alder type.
- dimerized fatty acids are worked up by distillation and consist of a mixture which, in addition to small amounts of linear and branched cis-monocarboxylic acids (mono meric fatty acid), predominantly C36-dicarboxylic acids and, depending on the complexity of the work-up, different proportions of Cs4-tricarboxylic acid (trimer fatty acid) Contains traces of higher polymer fatty acids.
- dimeric fatty acids predominantly 97% by weight of dicarboxylic acid content and hydrogenated, completely yellowing-free types are industrially produced.
- Oligomeric fatty acids (a4) represent reaction products of unsaturated fatty acids with one another, with more than 2 and a maximum of 5 fatty acid molecules having to react with one another. This acid component likewise represents a mixture of different oligomers with one another.
- mixtures of oligoglycerol esters prepared in the antisense of different fatty acid sources, or obtained by mixing, are preferred as the polyol component for the esterification.
- hydroxy fatty acids may be used as component (a5), e.g. the ricinoleic acid and more preferably the hydroxystearic acid are representatives of this class of fatty acids.
- Component (b) that is to say the oligoglycerols in the context of the present teaching, contain between 2 and 10 glycerol monomers in the molecule, mixtures of different oligomers being present side by side, depending on the preparation process (for example the reaction temperature or time or the catalysts used). Molecules with more than 10 monomers glycerol are called polyglycerols.
- the polyol component (b) of the esters according to the invention ie the oligoglycerols, can preferably be described by the following general formula (II):
- n is a number between 2 and 10.
- oligoglycerols can be used as the polyol component (b) containing between 4 and 10 glycerol monomers.
- the esters then preferably follow the general formula (III):
- n numbers between 2 and 10 and R represents either a hydrogen atom or a radical CO-R ', where R' then represents a saturated or unsaturated alkyl or alkenyl radical having 7 to 21 C atoms, wherein at least an OH function of the oligoglycerol must be esterified.
- R represents either a hydrogen atom or a radical CO-R ', where R' then represents a saturated or unsaturated alkyl or alkenyl radical having 7 to 21 C atoms, wherein at least an OH function of the oligoglycerol must be esterified.
- R represents either a hydrogen atom or a radical CO-R '
- R' then represents a saturated or unsaturated alkyl or alkenyl radical having 7 to 21 C atoms, wherein at least an OH function of the oligoglycerol must be esterified.
- R represents either a hydrogen atom or a radical CO-R ', where R' then represents a saturated or
- the formula (III) shown above represents oligoglycerol ester with the acid component (al). If hydroxyfatty acids (a5) are used for esterification, the radicals R may of course also contain alkyl or alkenyl radicals which have one or more free hydroxyl functions.
- oligoglycerols In addition to the oligoglycerols, their alkoxylates, ie reaction products of oligoglycerols with ethylene oxide and / or oligomers of alkoxylated glycerol with ethylene oxide and / or propylene oxide, can also be used as the alcohol component for the esters according to the invention. Preference is given here to the ethoxylated oligoglycerols.
- the molar ratio of fatty acids: oligoglycerol in the range of 5: 1 to 1: 1, preferably 4: 1 to 1: 1 and in particular in the range of 4: 1 to 1.5: 1.
- dimer fatty acids (a2) or the oligomeric fatty acids (a3) are used as the fatty acid component, the range of fatty acid to oligoglycerol of from 1: 1 to 1: 2 is particularly preferred.
- the number of carboxyl groups is the sum of the Carboxyl deficit all acid components. If mixtures of several polyol components are used, the number of hydroxy groups is the sum of the hydroxyl groups of all polyol components.
- full esters or mixtures of the different partial esters can be present next to one another.
- the Oligogylcerinester in the context of the present technical teaching are predominantly partial esters, with oligoglycerol triester and / or tetra- and / or pentaester are preferred.
- oligoglycerol esters of the invention are used in water-based rinses as an additive, in particular for smearing.
- the effect of Oligolglycerinester invention is preferred as a lubricant.
- Use as a lubricant, in particular for lubrication, is defined so that the friction of the mud, e.g. with the drill string and / or the formation - is reduced measurable by addition of the agent.
- Another object of the invention therefore relates to the use of the oligoglycerol fatty acid esters according to the invention as lubricants for water-based
- Drilling fluid preferably for lubricating, preferably for Bohr Hughesstoff the at least 70 wt .-%, and preferably at least 80 wt .-% and most preferably at least 90 wt .-% water - based on at room temperature
- Water-based drilling muds are understood below to mean those systems which preferably contain more than 60% by weight of water, based on the liquid phase at room temperature (21 ° C.), preferably more as 70 wt .-% and in particular more than 80 wt .-% and particularly preferably more than 90 wt .-% water as the liquid phase contain. Pure water rinses may furthermore be particularly preferred (100% by weight of the liquid phase is water). In addition to fresh water, synthetic or natural seawater is also suitable as water.
- the present teaching explicitly includes, as stated above, also those water-based rinses which form emulsions, but only those of the oil-in-water (O / W) type - water thus forms the outer phase in these systems according to the invention.
- Emulsions within the meaning of the present teaching preferably also contain only minor amounts of an oil phase, for example less than 20 wt .-%, preferably less than 10 wt .-% or in particular less than 5 wt .-%, based on the total liquid phase.
- oil phases in the water-based rinses for the purposes of the present invention are formed, for example, by non-water-soluble oils, which are required for dissolving or dispersing additives.
- Water-based drilling fluids contain, in addition to the water as a carrier liquid usually at least one means for generating an increased viscosity, to which both mineral and organic compound can be used.
- the mineral viscosity agents used for rheology control in the context of aqueous drilling fluids are swellable clays of natural and / or synthetic origin. Examples include corresponding smectites such as montmorillonite, bentonite, Glasgowlitt, hectorite, saponite and stevensite named. Attapulgite is another important water-swellable auxiliary of the species concerned.
- a number of proposals are concerned with the synthetic production of finely divided clay-like minerals, in particular corresponding compounds of the hectorite and / or saponite type.
- organic compounds preferably polymers. Called his here e.g. Xanthan gum or various cellulose derivatives. Bentonite is particularly preferred.
- oligoglycerol esters described above can either be used alone or in admixture with further, preferably oil-soluble components in drilling fluid as an additive, in particular for lubricating, wherein the friction of the mud, for example with the drill string and / or the formation - is reduced measurably by addition of the agent used.
- Suitable and preferred are hydrocarbons, fatty acid esters, fatty acids, fatty alcohols, surfactants, glycerol, triglycerides, glycols or any mixtures of these compounds.
- hydrocarbons according to the invention in particular linear or branched paraffins are used with 5 to 22 carbon atoms.
- Further suitable hydrocarbons are internal olefins (hereinafter abbreviated as IO).
- IOs are also compounds known per se, which can be prepared by all methods known to the person skilled in the art.
- EP 0 787 706 A1 describes e.g. a process for the synthesis of IOs by isomerization of alpha-olefins to sulfonic or persulfonic acids. It is characteristic that the so-called IOs are linear and contain at least one olefinic double bond which is not in the alpha position of the alkyl chain.
- such IO or IO mixtures which contain IO having 12 to 30 C atoms in the molecule, preferably having 14 to 24 C atoms and in particular having up to 20 C atoms in the molecule.
- the olefins used according to the invention preferably have only one olefinic double bond.
- esters of the general formula R '--COO - R "in which R' is a linear or branched, saturated or unsaturated alkyl radical having 15 to 25 carbon atoms and R" is a saturated, linear or branched alkyl radical having 6 to 22 C-atoms means part of the compositions of the invention.
- esters are known chemical compounds. Their principal use in drilling fluids is, for example, the subject of EP 0 374 672 A1 or EP 0 374 671 A1.
- esters whose radical R 'is a saturated or unsaturated alkyl radical having 15 to 25 and R "is a saturated alkyl radical having 3 to 10 carbon atoms, the saturated compounds being particularly preferred - hold branched alcohols, in particular 2-ethylhexyl radicals.
- Particularly preferred as a compounding component together with the oligoglycerol esters is a 2-ethylhexyl lauryl ester.
- fatty alcohols are suitable mixture components.
- Fatty alcohols follow the general formula R '"--OH, where R'" is a saturated or unsaturated, branched or unbranched alkyl or alkenyl radical having 4 to 22 carbon atoms. Preference is given to fatty alcohols having 16 to 22 and in particular 16 to 18 C atoms. Also preferred are linear and independently saturated fatty alcohols. Particularly preferred are linear, unsaturated fatty alcohols having 16 to 18 carbon atoms.
- Surfactants are also suitable admixing components for the oligoglycerol esters.
- all types of surfactants whether anionic, nonionic, zwitterionic or cationic surfactants, can be used.
- anionic surfactants are soaps, alkylbenzenesulfonates, alkanesulfonates, olefinsulfonates, alkyl ether sulfonates, glycerol ether sulfonates, methyl ester sulfonates, sulfo fatty acids, alkyl sulfates, fatty alcohol ether sulfates, glycerol ether sulfates, fatty acid ether sulfates, hydroxy mixed ether sulfates, monoglyceride sulfates, fatty acid amide (ether) sulfates , Mono- and dialkylsulfosuccinates, mono- and dialkylsulfosuccinamates, sulfotriglycerides, amide soaps, ether carboxylic acids and their salts.
- the latter are particularly preferred surfactant components within the meaning of the present technical teaching.
- nonionic surfactants are fatty alcohol polyglycol ethers, alkylphenol polyglycol ethers, fatty acid polyglycol esters, fatty acid amide polyglycol ethers, fatty amine polyglycol ethers, alkoxylated triglycerides, mixed ethers or mixed formals, optionally partially oxidized alk (en) yloligoglycosides or glucuronic acid derivatives, fatty acid N-glycerides. alkyl glucamides, polyol fatty acid esters, sugar esters, sorbitan esters, polysorbates and amine oxides.
- nonionic surfactants contain polyglycol ether chains, these may have a conventional, but preferably a narrow homolog distribution.
- the surfactants are an optional ingredient in the additives. They are preferably used in amounts of from 0.05 to 5% by weight, in particular from 0.1 to 3 and preferably from 1 to 2.5% by weight, in each case based on the total rinse.
- esters of C 1-5 monocarboxylic acids and 1- and / or polyfunctional alcohols where radicals of monohydric alcohols have at least 6, preferably at least 8 carbon atoms and the polyhydric alcohols preferably have 2 to 6 carbon atoms in the molecule .
- the oligoglycerol esters and the other components are preferably combined in weight ratios of from 20: 1 to 1: 1, preferably from 8: 1 to 6: 1, and more preferably from 5: 1 to 1: 1 used.
- the additives if appropriate only the oligolgycerin ester or mixtures of different oligoglycerol esters) are preferably used in the meaning of the invention in amounts of from 10 to 0.1% by weight, based on the total weight of the rinse. Advantageous ranges are 5 to 1 wt .-%, and in particular 3 to 1.5 wt .-%.
- compositions according to the invention also optionally contain further additives, for example weighting agents, fluid-loss additives, viscosity-regulating additives, wetting agents, salts, biocides, corrosion inhibitors, and / or an alkali reserve.
- further additives for example weighting agents, fluid-loss additives, viscosity-regulating additives, wetting agents, salts, biocides, corrosion inhibitors, and / or an alkali reserve.
- the additives may be water-soluble, oil-soluble and / or water- or oil-dispersible.
- Classic additives may be: fluid additives, structural viscosity-forming soluble and / or insoluble substances, alkali reserves, means for inhibiting unwanted water exchange between drilled formations - eg. B water swellable clays and / or salt layers - and the z. B. water-based rinsing liquid, wetting agent for better absorption of the emulsified oil phase on solid surfaces, eg. B. to improve the lubricity, but also to improve the oleophilic closure of exposed Ge stone formations, or rock surfaces, biocides, for example, for inhibiting the bacterial infestation of O / W emulsions and the like. Only excerpts are quoted accordingly: Fine dispersants to increase the mud density: Widely used is the barium sulfate (barite), but also calcium carbonate (calcite) or the mixed carbonate of calcium and magnesium (dolomite)
- Bentonite or hydrophobized bentonite should be mentioned here in the first place.
- other comparable clays in particular attapulgite and sepiolite, are of considerable importance in practice.
- organic polymer compounds of natural and / or synthetic origin may also be of considerable importance in this context.
- starch or chemically modified starches cellulose derivatives such as carboxymethyl cellulose, guar gum, synthangum or purely synthetic water-soluble and / or water-dispersible polymer compounds, in particular of the type of high molecular weight polyacrylamide compounds with or without anionic or cationic modification.
- Thinner for viscosity control can be organic or inorganic in nature, examples of organic thinners are tannins and / or Qebracho extract. Further examples of these are lignite and lignite derivatives, in particular lignosulfonates.
- Another object of the present invention relates to water-based drilling muds, in amounts of 1 to 10 wt .-%, based on the total flushing, of an additive containing or consisting of oligoglycerol esters as described above, and water, weighting agents, inorganic salts, thickeners and pH regulants.
- further additives customary in drilling fluids may be present.
- the present technical teaching also includes a method for improving the lubricity of water-based drilling fluids, preferably for lubricating drilling fluids, wherein the leaching Oligoglycerinester in amounts of 0.1 to 10 wt .-%, based on the total flushing, are added as an additive ,
- purely aqueous drilling fluids are provided with the additive.
- WBM based on synthetic or natural seawater are preferred.
- the water-based rinses may preferably also contain silicates.
- the pH of the water-based rinses is preferably in the range of 8 to 13, and more preferably in the range of 9 to 11.
- Another object of the present invention relates to the use of above Oligoglycerinester as a lubricant, preferably in the above-described water-based Bohr réelleffenn.
- the friction of Bohr mecanicstoffs for example, with the drill string and / or the formation - by adding the agent is measurably reduced compared to the Bohr réellestoff without the Oligoglycerinester invention. This is often associated with a reduction in the viscosity of the detergent by adding the Oligoglycerinester invention.
- the following water-based drilling fluid was prepared for testing the lubricity.
- the mixing was carried out in a Silverson mixer:
- Example 2 In a further experiment, those formulations were tested which contained the oligonoglycerol esters in admixture with paraffin oil (weight ratio in each case 1: 1). Specifically, the additives (1) and (5) were investigated and compared with a non-additivated rinse. It can be seen from the graph of FIG. 2 that the rinse which contains the additives according to the invention achieves significantly better values than the non-additivated rinse.
- FIG. 3 shows tests in which the non-additized comparative rinse was compared with rinses containing either the oligoglycerides alone or as an additive mixture together with saturated 2-ethylhexyl esters of the fatty acid cut C8-C14 in a weight ratio of 1: 1.
- the rinse provided with additives according to the invention has better lubricating action than the non-additive rinse and also shows better values when 3% by weight of the ester are added alone.
- Figure 4 shows the result of the lubricant test for a similar one
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08804161.1A EP2201081B1 (de) | 2007-09-14 | 2008-09-12 | Additive für wasserbasierte bohrspülmittel |
AU2008300599A AU2008300599B2 (en) | 2007-09-14 | 2008-09-12 | Additives for water-based drilling fluids |
BRPI0816337 BRPI0816337A2 (pt) | 2007-09-14 | 2008-09-12 | Uso de ésteres de ácidos graxos oligogliceróis e composição de lama de perfuração baseada em água |
US12/677,874 US8148305B2 (en) | 2007-09-14 | 2008-09-12 | Oligoglyercol fatty acid ester additives for water-based drilling fluids |
CA2699587A CA2699587C (en) | 2007-09-14 | 2008-09-12 | Additives for water-based drilling mud compositions |
CN200880115996.3A CN101855312B (zh) | 2007-09-14 | 2008-09-12 | 用于水基钻探流体的添加剂 |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07018086A EP2036962A1 (de) | 2007-09-14 | 2007-09-14 | Additive für wasserbasierte Bohrspülmittel |
EP07018086.4 | 2007-09-14 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2009037212A1 true WO2009037212A1 (de) | 2009-03-26 |
WO2009037212A9 WO2009037212A9 (de) | 2010-04-15 |
Family
ID=39032270
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2008/062200 WO2009037212A1 (de) | 2007-09-14 | 2008-09-12 | Additive für wasserbasierte bohrspülmittel |
Country Status (7)
Country | Link |
---|---|
US (1) | US8148305B2 (de) |
EP (2) | EP2036962A1 (de) |
CN (1) | CN101855312B (de) |
AU (1) | AU2008300599B2 (de) |
CA (1) | CA2699587C (de) |
MY (1) | MY153746A (de) |
WO (1) | WO2009037212A1 (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108117639A (zh) * | 2016-11-30 | 2018-06-05 | 中国石油天然气股份有限公司 | 不饱和脂肪醇聚氧丙烯聚氧乙烯嵌段共聚物及其制备方法与应用 |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2053111B1 (de) | 2007-10-24 | 2016-12-07 | Emery Oleochemicals GmbH | Bohrzusammensetzung, Herstellungsverfahren dafür und Anwendungen davon |
US20100294501A1 (en) * | 2007-11-20 | 2010-11-25 | Peter Daute | Process for the preparation of an organic composition comprising an n-nonyl ester |
DE102010050917A1 (de) | 2010-11-11 | 2012-05-16 | Emery Oleochemicals Gmbh | Verfahren zur Herstellung von Carbonsäureestern während eines Transports |
CN102703051B (zh) * | 2012-05-11 | 2013-09-25 | 厦门大学 | 一种蒸汽驱添加剂 |
BR112015001600A2 (pt) | 2012-07-26 | 2017-07-04 | Amril Ag | emulsão e uso de um éster |
US9238783B2 (en) | 2012-11-20 | 2016-01-19 | Chevron U.S.A. Inc. | Monoester-based lubricants and methods of making same |
US9115303B2 (en) | 2012-11-20 | 2015-08-25 | Chevron U.S.A. Inc. | Biologically-derived monoesters as drilling fluids |
US9115556B2 (en) | 2012-11-20 | 2015-08-25 | Chevron U.S.A. Inc. | Method of using biologically-derived monoesters as drilling fluids |
US9115326B2 (en) | 2012-11-20 | 2015-08-25 | Chevron U.S.A. Inc. | Monoester-based lubricants and methods of making same |
US9234124B2 (en) * | 2013-08-09 | 2016-01-12 | Halliburton Energy Services, Inc. | Dimer acid grafted polymer for stabilizing particulate in a well |
WO2015062656A1 (en) | 2013-10-31 | 2015-05-07 | Amril Ag | Environmental friendly well treatment fluids comprising an ester |
CN104194743B (zh) * | 2014-08-19 | 2015-06-10 | 北京培康佳业技术发展有限公司 | 油田钻井液用防塌剂及其制备方法与应用 |
CA2966794C (en) | 2014-11-12 | 2023-03-14 | Lamberti Spa | Method of increasing lubricity of wellbore fluids |
WO2016110323A1 (en) | 2015-01-07 | 2016-07-14 | Amril Ag | Hydrophilic ether carboxylic acids as lubricant for salt based drilling systems |
CA2968451A1 (en) * | 2015-01-07 | 2016-07-14 | Emery Oleochemicals Gmbh | New additives for oilfield and industrial applications |
WO2016153866A2 (en) * | 2015-03-20 | 2016-09-29 | Resinate Materials Group, Inc. | Drilling fluids containing polyester polyols |
CN106543990B (zh) * | 2015-09-23 | 2019-10-29 | 中国石油化工股份有限公司 | 一种提高泥岩钻进速度的钻井液及其制备方法和应用 |
US10723931B2 (en) | 2015-11-19 | 2020-07-28 | Cnpc Usa Corporation | Thinner for oil-based drilling fluids |
GB201803610D0 (en) * | 2018-03-07 | 2018-04-18 | Croda Int Plc | Drilling fluid |
CA3040187C (en) | 2018-07-13 | 2022-05-31 | Emery Oleochemicals Gmbh | Environmentally friendly ester-structures as viscosifier for oil based drilling fluids |
CN109824882A (zh) * | 2019-01-08 | 2019-05-31 | 西南科技大学 | 一种用于稳定氧化锌纳米晶嵌段共聚物的制备方法 |
BR112023000433A2 (pt) | 2020-07-15 | 2023-03-28 | Totalenergies Onetech | Composição lubrificante, uso da dita composição e lama com base em água |
CN112175591A (zh) * | 2020-10-22 | 2021-01-05 | 库尔勒郑豫石油物资有限公司 | 一种钻井液用高效抗温抗盐润滑剂及其生产和检测方法 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3622826A1 (de) | 1986-07-08 | 1988-01-21 | Henkel Kgaa | Pulverfoermige schmiermittel-additive fuer bohrspuelungen auf wasserbasis |
EP0579159A2 (de) | 1992-07-16 | 1994-01-19 | Solvay Fluor und Derivate GmbH | Verfahren zur Herstellung von Polyglycerinfettsäureestergemischen, und die Verwedung in kosmetischen, pharmazeutischen und/oder chemisch-technischen Zubereitungen |
DE4226174A1 (de) | 1992-08-07 | 1994-02-10 | Solvay Fluor & Derivate | Polyglycerinfettsäureestergemisch |
DE19647598A1 (de) | 1996-11-18 | 1998-05-20 | Henkel Kgaa | Verwendung ausgewählter Fettalkohole und ihrer Abmischungen mit Carbonsäureestern als Schmiermittelkomponente in wasserbasierten Bohrspülsystem zum Erdreichaufschluß |
DE19852971A1 (de) | 1998-11-17 | 2000-05-18 | Cognis Deutschland Gmbh | Schmiermittel für Bohrspülungen |
WO2007068404A1 (de) | 2005-12-17 | 2007-06-21 | Cognis Oleochemicals Gmbh | Ethercarbonsäuren als additive zur verbesserung der schmierwirckung von wasserbasierten bohrspülungen |
Family Cites Families (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3118417A1 (de) | 1981-05-09 | 1982-11-25 | Basf Ag, 6700 Ludwigshafen | Gleitmittel fuer die formgebende verarbeitung von polyvinylchlorid, die veresterte oligomere mehrwertige alkohole enthalten |
USRE36066E (en) * | 1988-12-19 | 1999-01-26 | Henkel Kgaa | Use of selected ester oils in drilling fluids and muds |
DE3842659A1 (de) | 1988-12-19 | 1990-06-28 | Henkel Kgaa | Verwendung ausgewaehlter esteroele in bohrspuelungen insbesondere zur off-shore-erschliessung von erdoel- bzw. erdgasvorkommen (i) |
US5232910A (en) * | 1988-12-19 | 1993-08-03 | Henkel Kommanditgesellschaft Auf Aktien | Use of selected ester oils in drilling fluids and muds |
US5252554A (en) * | 1988-12-19 | 1993-10-12 | Henkel Kommanditgesellschaft Auf Aktien | Drilling fluids and muds containing selected ester oils |
DE3842703A1 (de) | 1988-12-19 | 1990-06-21 | Henkel Kgaa | Verwendung ausgewaehlter esteroele in bohrspuelungen insbesondere zur off-shore-erschliessung von erdoel- bzw. erdgasvorkommen (ii) |
US5254531A (en) * | 1989-02-09 | 1993-10-19 | Henkel Kommanditgesellschaft Auf Aktien | Oleophilic basic amine compounds as an additive for invert drilling muds |
US5318954A (en) * | 1989-03-08 | 1994-06-07 | Henkel Kommanditgesellschaft Auf Aktien | Use of selected ester oils of low carboxylic acids in drilling fluids |
DE3907392A1 (de) * | 1989-03-08 | 1990-09-13 | Henkel Kgaa | Ester von carbonsaeuren mittlerer kettenlaenge als bestnadteil der oelphase in invert-bohrspuelschlaemmen |
DE3911238A1 (de) * | 1989-04-07 | 1990-10-11 | Henkel Kgaa | Oleophile alkohole als bestandteil von invert-bohrspuelungen |
US5318956A (en) * | 1989-05-16 | 1994-06-07 | Henkel Kommanditgesellschaft Auf Aktien | Use of selected ester oils in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability |
DE4018228A1 (de) * | 1990-06-07 | 1991-12-12 | Henkel Kgaa | Fliessfaehige bohrlochbehandlungsmittel auf basis von kohlensaeurediestern |
DE4019266A1 (de) * | 1990-06-16 | 1992-01-23 | Henkel Kgaa | Fliessfaehige bohrlochbehandlungsmittel auf basis von polycarbonsaeureestern |
DE4200502A1 (de) * | 1992-01-13 | 1993-07-15 | Henkel Kgaa | Verbesserte entsorgung von kontaminiertem bohrklein aus geologischen bohrungen mit mineraloel-enthaltenden bohrspuelsystemen |
DE4224537A1 (de) * | 1992-07-27 | 1994-02-03 | Henkel Kgaa | Mineralische Additive zur Einstellung und/oder Regelung der Rheologie und Gelstruktur wässriger Flüssigphasen und ihre Verwendung |
DE4324474A1 (de) * | 1993-07-21 | 1995-01-26 | Henkel Kgaa | Verwendung ausgewählter Polyvinylacetat-Dispersionen für die Oberflächenverfestigung von Sand und/oder Erdreich |
DE4420455A1 (de) * | 1994-06-13 | 1995-12-14 | Henkel Kgaa | Lineare alpha-Olefine enthaltende fließfähige Bohrlochbehandlungsmittel insbesondere entsprechende Bohrspülungen |
EP0770661A1 (de) | 1995-10-27 | 1997-05-02 | B W Mud Limited | Schmierstoff für Bohrschlamm |
DE19548314A1 (de) * | 1995-12-22 | 1997-06-26 | Henkel Kgaa | Verbessertes Verfahren zur Intensivierung der Oberflächenverfestigung erosionsgefährdeten Erdreichs durch Eintrag wasserbasierter und haftvermittelnder Bindemittell auf Basis von Polyvinylalkohol-Estern |
EP0787706B1 (de) | 1996-01-30 | 2000-11-22 | BP Amoco Corporation | Verfahren zur Isomerisierung von Olefinen |
TW354352B (en) * | 1996-10-30 | 1999-03-11 | Henkel Kgaa | A process for easier cleaning on the basis of water/oil inversion emulifier |
DE19643857A1 (de) * | 1996-10-30 | 1998-05-07 | Henkel Kgaa | Verwendung biologisch abbaubarer Alkoxylierungsprodukte zum Reinigen von Bohrlöchern, Bohrgeräten oder Bohrklein |
US6022833A (en) * | 1996-10-30 | 2000-02-08 | Henkel Kommanditgesellschaft Auf Aktien | Multicomponent mixtures for use in geological exploration |
DE19701127A1 (de) * | 1997-01-15 | 1998-07-16 | Henkel Kgaa | Schaumarme Tensidkonzentrate für den Einsatz im Bereich der Förderung des Pflanzenwachstums |
US6828279B2 (en) * | 2001-08-10 | 2004-12-07 | M-I Llc | Biodegradable surfactant for invert emulsion drilling fluid |
CA2431748C (en) * | 2002-07-09 | 2010-11-09 | Clariant Gmbh | Oxidation-stabilized oily liquids based on vegetable or animal oils |
DE50307929D1 (de) * | 2002-07-09 | 2007-09-27 | Clariant Produkte Deutschland | Oxidationsstabilisierte Schmieradditive für hochentschwefelte Brennstofföle |
ES2399626T3 (es) * | 2002-07-09 | 2013-04-02 | Clariant Produkte (Deutschland) Gmbh | Agente mejorador de la fluidez en frío para aceites combustibles de procedencia vegetal o animal |
DE10252973A1 (de) | 2002-11-14 | 2004-05-27 | Clariant Gmbh | Oxidationsstabilisierte Schmieradditive für hochentschwefelte Brennstofföle |
DE10243312A1 (de) * | 2002-09-18 | 2004-04-01 | Cognis Deutschland Gmbh & Co. Kg | Bohrlochbehandlungsmittel mit niedrig-toxischer Ölphase |
DE10334441A1 (de) * | 2003-07-29 | 2005-02-17 | Cognis Deutschland Gmbh & Co. Kg | Bohrlochbehandlungsmittel, enthaltend Ethercarbonsäuren |
DE10342870A1 (de) * | 2003-09-15 | 2005-05-12 | Clariant Gmbh | Flüssige Zusammensetzungen enthaltend oxalkylierte Polyglycerinester |
DE10349807A1 (de) * | 2003-10-24 | 2005-05-25 | Cognis Deutschland Gmbh & Co. Kg | Emulgatoren für Bohrspülmittel |
DE10349808A1 (de) * | 2003-10-24 | 2005-05-25 | Cognis Deutschland Gmbh & Co. Kg | Emulgatoren für Bohrspülmittel |
JP4397286B2 (ja) * | 2003-11-28 | 2010-01-13 | 日清オイリオグループ株式会社 | 水中油型乳化化粧料及びその製造方法 |
DE102004034141A1 (de) * | 2004-07-15 | 2006-02-09 | Cognis Ip Management Gmbh | Verwendung von Lithiumsalzen von Fettalkoholsulfaten zum Reinigen von Bohrlöchern, Bohrgeräten oder Bohrklein |
EP1918354A1 (de) * | 2006-10-13 | 2008-05-07 | Cognis Oleochemicals GmbH | Brennstoffzubereitungen die Glycerin enthalten |
EP1958931A1 (de) * | 2007-02-02 | 2008-08-20 | Cognis IP Management GmbH | Oxidationsstabile Carbonsäureester und deren Verwendung |
EP2036964A1 (de) * | 2007-09-14 | 2009-03-18 | Cognis Oleochemicals GmbH | Verdicker für ölbasierte Bohrspülmittel |
EP2036963A1 (de) * | 2007-09-14 | 2009-03-18 | Cognis Oleochemicals GmbH | Schmiermitteladditive für Bohrspülmittel |
-
2007
- 2007-09-14 EP EP07018086A patent/EP2036962A1/de not_active Withdrawn
-
2008
- 2008-09-12 CN CN200880115996.3A patent/CN101855312B/zh not_active Expired - Fee Related
- 2008-09-12 US US12/677,874 patent/US8148305B2/en active Active
- 2008-09-12 AU AU2008300599A patent/AU2008300599B2/en not_active Ceased
- 2008-09-12 MY MYPI2010001097A patent/MY153746A/en unknown
- 2008-09-12 CA CA2699587A patent/CA2699587C/en not_active Expired - Fee Related
- 2008-09-12 WO PCT/EP2008/062200 patent/WO2009037212A1/de active Application Filing
- 2008-09-12 EP EP08804161.1A patent/EP2201081B1/de active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3622826A1 (de) | 1986-07-08 | 1988-01-21 | Henkel Kgaa | Pulverfoermige schmiermittel-additive fuer bohrspuelungen auf wasserbasis |
EP0579159A2 (de) | 1992-07-16 | 1994-01-19 | Solvay Fluor und Derivate GmbH | Verfahren zur Herstellung von Polyglycerinfettsäureestergemischen, und die Verwedung in kosmetischen, pharmazeutischen und/oder chemisch-technischen Zubereitungen |
DE4226174A1 (de) | 1992-08-07 | 1994-02-10 | Solvay Fluor & Derivate | Polyglycerinfettsäureestergemisch |
DE19647598A1 (de) | 1996-11-18 | 1998-05-20 | Henkel Kgaa | Verwendung ausgewählter Fettalkohole und ihrer Abmischungen mit Carbonsäureestern als Schmiermittelkomponente in wasserbasierten Bohrspülsystem zum Erdreichaufschluß |
DE19852971A1 (de) | 1998-11-17 | 2000-05-18 | Cognis Deutschland Gmbh | Schmiermittel für Bohrspülungen |
WO2007068404A1 (de) | 2005-12-17 | 2007-06-21 | Cognis Oleochemicals Gmbh | Ethercarbonsäuren als additive zur verbesserung der schmierwirckung von wasserbasierten bohrspülungen |
DE102005060549A1 (de) | 2005-12-17 | 2007-06-28 | Cognis Ip Management Gmbh | Ethercarbonsäuren als Additive zur Verbesserung der Schmierwirkung von wasserbasierten Bohrspülungen |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108117639A (zh) * | 2016-11-30 | 2018-06-05 | 中国石油天然气股份有限公司 | 不饱和脂肪醇聚氧丙烯聚氧乙烯嵌段共聚物及其制备方法与应用 |
Also Published As
Publication number | Publication date |
---|---|
MY153746A (en) | 2015-03-13 |
US8148305B2 (en) | 2012-04-03 |
EP2201081B1 (de) | 2014-08-13 |
AU2008300599A1 (en) | 2009-03-26 |
WO2009037212A9 (de) | 2010-04-15 |
CN101855312A (zh) | 2010-10-06 |
US20100305009A1 (en) | 2010-12-02 |
CA2699587A1 (en) | 2009-03-26 |
EP2036962A1 (de) | 2009-03-18 |
EP2201081A1 (de) | 2010-06-30 |
AU2008300599B2 (en) | 2014-03-06 |
CA2699587C (en) | 2016-02-09 |
CN101855312B (zh) | 2014-05-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP2201081B1 (de) | Additive für wasserbasierte bohrspülmittel | |
EP2201082B1 (de) | Schmiermitteladditive für bohrspülmittel | |
EP2201083B1 (de) | Verdicker für ölbasierte bohrspülmittel | |
EP2240531B1 (de) | Vernetzte glycerin- oder oligoglycerinester und deren verwendung als additiv in bohrspülungen | |
EP1137736B1 (de) | Schmiermittel für bohrspülungen | |
EP2411483B1 (de) | Emulsionsbasierte reinigungszusammensetzung für ölfeldanwendungen | |
EP1654337B1 (de) | Bohrlochbehandlungsmittel, enthaltend ethercarbonsäuren | |
DE4019266A1 (de) | Fliessfaehige bohrlochbehandlungsmittel auf basis von polycarbonsaeureestern | |
DE3916550A1 (de) | Verwendung ausgewaehlter oleophiler ether in wasser-basierten bohrspuelungen vom o/w-emulsionstyp sowie entsprechende bohrspuelfluessigkeiten mit verbesserter oekologischer vertraeglichkeit | |
WO2004029175A1 (de) | Bohrlochbehandlungsmittel mit niedrig-toxischer ölphase | |
WO2007137709A1 (de) | Bohrspülungen mit geringer toxizität | |
WO2008046554A1 (de) | Propylalkylester als ölphase in bohrlochbehandlungsmitteln | |
DE4024658A1 (de) | Verwendung oberflaechenaktiver alkylglycosidverbindungen in wasser- und oel-basierten bohrspuelungen und anderen bohrlochbehandlungsmitteln | |
WO2006045456A1 (de) | Verwendung von ethoxylierten amidoaminen als emulgatoren in bohrspülungen | |
WO2007068404A1 (de) | Ethercarbonsäuren als additive zur verbesserung der schmierwirckung von wasserbasierten bohrspülungen | |
EP1358298A1 (de) | Additiv für ölbasierte invert-bohrspülungen | |
EP0542808B1 (de) | Verwendung oberflächenaktiver estersulfonat-salze in wasser- und öl-basierten bohrspülungen und anderen bohrlochbehandlungsmitteln | |
EP0541605B1 (de) | Verwendung oberflächenaktiver alpha-sulfofettsäure-di-salze in wasser- und öl-basierten bohrspülungen und anderen bohrlochbehandlungsmitteln |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200880115996.3 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 08804161 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2699587 Country of ref document: CA Ref document number: 1760/DELNP/2010 Country of ref document: IN |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008300599 Country of ref document: AU |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
ENP | Entry into the national phase |
Ref document number: 2008300599 Country of ref document: AU Date of ref document: 20080912 Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2008804161 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: PI 2010001097 Country of ref document: MY |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12677874 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: PI0816337 Country of ref document: BR Kind code of ref document: A2 Effective date: 20100315 |