WO2009031747A1 - Power plant having pure oxygen combustor - Google Patents

Power plant having pure oxygen combustor Download PDF

Info

Publication number
WO2009031747A1
WO2009031747A1 PCT/KR2008/002600 KR2008002600W WO2009031747A1 WO 2009031747 A1 WO2009031747 A1 WO 2009031747A1 KR 2008002600 W KR2008002600 W KR 2008002600W WO 2009031747 A1 WO2009031747 A1 WO 2009031747A1
Authority
WO
WIPO (PCT)
Prior art keywords
steam
turbine
power plant
combustor
unit
Prior art date
Application number
PCT/KR2008/002600
Other languages
French (fr)
Inventor
Kook Young Ahn
Young Duk Lee
Han Seok Kim
Sang Seok Yu
Sang Min Lee
Ju Hyeong Cho
Kwan Sik Ahn
Hyun Il Jeong
Original Assignee
Korea Institute Of Machinery And Materials
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from KR1020070090395A external-priority patent/KR100779609B1/en
Priority claimed from KR1020070090394A external-priority patent/KR100814940B1/en
Priority claimed from KR1020070130109A external-priority patent/KR100817898B1/en
Application filed by Korea Institute Of Machinery And Materials filed Critical Korea Institute Of Machinery And Materials
Priority to CN2008800003746A priority Critical patent/CN101542077B/en
Priority to EP08753396.4A priority patent/EP2074290A4/en
Publication of WO2009031747A1 publication Critical patent/WO2009031747A1/en

Links

Classifications

    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
    • F01K7/16—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type
    • F01K7/22—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type the turbines having inter-stage steam heating
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
    • F01K7/00—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating
    • F01K7/16—Steam engine plants characterised by the use of specific types of engine; Plants or engines characterised by their use of special steam systems, cycles or processes; Control means specially adapted for such systems, cycles or processes; Use of withdrawn or exhaust steam for feed-water heating the engines being only of turbine type
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F22—STEAM GENERATION
    • F22G—SUPERHEATING OF STEAM
    • F22G1/00—Steam superheating characterised by heating method
    • F22G1/16—Steam superheating characterised by heating method by using a separate heat source independent from heat supply of the steam boiler, e.g. by electricity, by auxiliary combustion of fuel oil
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/32—Direct CO2 mitigation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00—Combustion technologies with mitigation potential
    • Y02E20/34—Indirect CO2mitigation, i.e. by acting on non CO2directly related matters of the process, e.g. pre-heating or heat recovery

Definitions

  • the present invention relates to a high efficiency power plant, and more particularly, to a power plant equipped with a pure oxygen combustor to improve thermal efficiency using pure oxygen combustion.
  • the Rankine cycle which is applied to a thermal power plant is also called a steam cycle or a vapor cycle and uses steam as a working fluid.
  • the Rankine cycle is realized by each element, such as a water supplying pump (adiabatic compression), a boiler and a superheater (isobaric heating), a turbine (adiabatic expansion), and a steam condenser (isobaric heat dissipation).
  • fuel cells convert chemical energy into electrical energy by electrochemical reaction in anode and cathode.
  • a reactant is supplied continuously from the outside and reaction products are continuously removed to the outside of a fuel cell system.
  • Fuel cells use various fuels, such as a fossil fuel, a liquid fuel, and a gaseous fuel.
  • Fuel cells can be classified into low temperature type fuel cells of less than 100 0 C, intermediate temperature type fuel cells of about 150 to 300 0 C, and high temperature type fuel cells of 600 0 C or higher according to its working temperature.
  • fuel cells can be classified into phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), polymer electrolyte fuel cells (PEFC), etc. according to the type of an electrolyte.
  • PAFC phosphoric acid fuel cells
  • MCFC molten carbonate fuel cells
  • SOFC solid oxide fuel cells
  • PEFC polymer electrolyte fuel cells
  • Low temperature type PEFC are mainly used for transportation or home power generator, and high temperature type MCFC or SOFC are mainly used for large scale power generation.
  • a conventional method of additionally using an exhaust gas of a fuel cell has been devised.
  • a high temperature gas exhausted in an MCFC system or a PAFC system is used for cooling/heating, etc. so as to use heat more efficiently.
  • additional power generation is not easy in the conventional method of additionally using the exhaust gas of the fuel cell. So, it is needed to invent a new system to make more electric power generation in order to use the heat more efficiently.
  • a conventional fuel cell system has a high efficiency.
  • the development of a hybrid system with other engines is needed to take superiority over competitive technologies.
  • the present invention provides a power plant having a pure oxygen combustor to improve thermal efficiency and separate carbon dioxide (CO ) from exhausted gas.
  • the present invention also provides a power plant having a pure oxygen combustor which is more economical and is designed to achieve high efficiency in connection with other systems.
  • a power plant having a pure oxygen combustor has the following advantages.
  • FIG. 1 schematically illustrates a power plant having a pure oxygen combustor according to an embodiment of the present invention.
  • FIG. 2 illustrates a formula when methane is supplied as a fuel from the power plant having a pure oxygen combustor of FIG. 1 and pure oxygen combustion is performed.
  • FIG. 3 schematically illustrates a first combustor of the power plant having the pure oxygen combustor of FIG. 1.
  • FIG. 4 is a graph showing the Rankine cycle of the power plant having the pure oxygen combustor of FIG. 1.
  • FIG. 5 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • FIG. 6 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • FIG. 7 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • invented power plant with pure oxygen combustor is composed of: a heat supplying unit supplying a heated steam; a turbine unit generating mechanical energy by rotating a turbine using the heated steam supplied by the heat supplying unit; a power generator converting mechanical energy generated by the turbine unit into electrical energy; a steam condenser condensing steam passing through the turbine unit; and a first combustor disposed at one side of the turbine unit and reheating the steam supplied to the turbine unit by using pure oxygen combustion.
  • the turbine unit may include a high pressure turbine, an intermediate pressure turbine, and a low pressure turbine according to operating pressure and temperature of the supplied steam.
  • the first combustor may be interposed between the intermediate pressure turbine and the low pressure turbine, may reheat the steam passing through the intermediate pressure turbine by using pure oxygen combustion, and may supply the reheated steam to the low pressure turbine.
  • Pressure of steam supplied by the heat supplying unit may be 3 to 10 bar, and temperature of an inlet of the low pressure turbine may be 300 to 500 0 C.
  • the power plant may further include: a water supplying pump delivering water condensed by the steam condenser to the heat supplying unit; and a pump actuator comprising a second combustor dividing a portion of the steam passing through the intermediate pressure turbine and reheating the divided steam, a second turbine unit actuating the water supplying pump by rotating the turbine by using the steam reheated by the second combustor, and a second power generator actuating the water supplying pump by converting mechanical energy generated by the second turbine unit into electrical energy.
  • a water supplying pump delivering water condensed by the steam condenser to the heat supplying unit
  • a pump actuator comprising a second combustor dividing a portion of the steam passing through the intermediate pressure turbine and reheating the divided steam, a second turbine unit actuating the water supplying pump by rotating the turbine by using the steam reheated by the second combustor, and a second power generator actuating the water supplying pump by converting mechanical energy generated by the second turbine unit into
  • the second combustor may include: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion into which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in the side of the main body portion.
  • the heat supplying unit may supply a waste steam generated from one facility selected from the group consisting of an incinerator furnace, a heating furnace, a factory, and a thermal power plant, to the first combustor, and the steam condenser may be installed in the ground and may condense the steam passing through the turbine unit by using geothermal heat.
  • the heat supplying unit may include a heat exchanger discharging high temperature and high pressure steam due to an exhaust gas generated in a fuel cell system.
  • Pressure of the steam passing through the heat exchanger may be 5 to 20 bar, and temperature of an inlet of the turbine unit may be 300 to 600 0 C.
  • the first combustor may include: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion into which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in the side of the main body portion.
  • the power plant may further include a recovery pump recovering carbon dioxide
  • FIGS. 1 through 4 A power plant having a pure oxygen combustor according to an embodiment of the present invention will now be described with reference to FIGS. 1 through 4.
  • FIG. 1 schematically illustrates a power plant having a pure oxygen combustor according to an embodiment of the present invention
  • FIG. 2 illustrates a formula when methane is supplied as a fuel to the pure oxygen combustor of the power plant illustrated in FIG. 1
  • a power plant 100 having a pure oxygen combustor comprises a heat supplying unit 110, a turbine unit 120, a first combustor 130, a power generator 140, a steam condenser 150, a recovery pump 160, and a water supplying pump 170.
  • the heat supplying unit 110 comprises a heater 111 and a boiler 113, and the heater
  • 111 supplies heat generated by combusting a fuel, such as a fossil fuel, etc., to the boiler 113.
  • a fuel such as a fossil fuel, etc.
  • the heater 111 may comprise all of heat supplying units which are not limited to generation of heat by combusting a fuel, such as a fossil fuel, etc., but are able to use heat of a waste gas generated in factory, etc. or supply heat so that heat exchange occurs in the boiler 113 for the purpose of the invention.
  • the boiler 113 heats water accommodated therein by using heat supplied by the heater 111 to generate high temperature and high pressure steam.
  • the turbine unit 120 comprises a high pressure turbine 121, an intermediate pressure turbine 123, and a low pressure turbine 125 according to the pressure and temperature of an induced steam.
  • the high pressure turbine 121 rotates a turbine by expanding the supplied high- temperature and high-pressure steam through a nozzle and thus converts energy of high-temperature and high-pressure steam into mechanical energy.
  • the intermediate-pressure and intermediate-temperature steam passing through the high pressure turbine 121 is re-supplied to the boiler 113 according to the principle of a reheat system.
  • the temperature of the steam is increased by reheating, and the steam is supplied to the intermediate pressure turbine 123.
  • the turbine is rotated using the same principle as the high temperature turbine 121, and the energy of the steam is converted into mechanical energy.
  • the low-pressure and low-temperature steam passing through the intermediate pressure turbine 123 is supplied to the low pressure turbine 125, and the turbine is rotated using the same principle as the high temperature turbine 121, and mechanical energy is generated.
  • the first combustor 130 is interposed between the intermediate pressure turbine 123 and the low pressure turbine 125, and low pressure and low temperature steam passing through the intermediate pressure turbine 123 is directly reheated using pure oxygen combustion, and the heated steam is supplied to the low pressure turbine 125.
  • the first combustor 130 must use one of either the process byproduct or fossil-fuel excluding nitrogen as a fuel and pure oxygen as an oxidizer.
  • the fossil fuel may include all fossil fuels, such as solid, liquid, and gaseous fossil fuels.
  • a waste gas or a digester gas excluding nitrogen may be used as the process byproducts.
  • oxygen and methane are supplied to the first combustor 130 of the power planet 100 having the pure oxygen combustor shown in FIG. 1, together with the steam. Since only carbon dioxide (CO ) and water vapor exist in a combustion gas generated using pure oxygen combustion between oxygen and methane, when water vapor in the combustion gas is condensed by the steam condenser 150, water vapor may be separated from condensed water and high concentration CO may be recovered by the recovery pump 160.
  • CO carbon dioxide
  • a fossil fuel supplied to the first combustor 130 is not limited to methane, and a variety of types of fossil fuels that cause pure oxygen combustion may be supplied to the first combustor 130 together with oxygen according to the purpose of the invention.
  • the first combustor 130 reduces a thermal loss by directly mixing the combustion gas with the steam and, therefore, has high thermal efficiency.
  • FIG. 3 schematically illustrates the first combustor of the power plant having the pure oxygen combustor of FIG. 1.
  • the first combustor 130 comprises an inlet portion 131 having a plurality of nozzles through which steam, oxygen, and a fossil fuel are injected, and a main body portion 135 into which the remaining steam excluding the steam injected through the inlet portion 131 is injected through an injection hole 133 formed in the side of the main body portion 135.
  • a portion of a fuel, oxygen, and water vapor is injected through the nozzles of the inlet portion 131, and pure oxygen combustion is performed between the injected oxygen and fuel so that a high temperature combustion gas can be obtained.
  • the high temperature combustion gas and steam injected through the inlet portion 131 are mixed so that a desired temperature combustion gas can be obtained.
  • FIG. 4 is a graph showing the Rankine cycle of the power plant having the pure oxygen combustor of FIG. 1.
  • a low pressure turbine used in a conventional thermal power plant operates with the Rankine cycle having the condition of 1-2-3-5-1.
  • the inlet of the low pressure turbine 125 is reheated by using the first combustor 130 performing pure oxygen combustion, the low pressure turbine 125 operates with the
  • the low pressure turbine 125 operates with the condition of a wet vapor at point 5 of FIG. 4 corresponding to the outlet of the low pressure turbine 125.
  • dryness fraction must be maintained at 90% or greater to prevent erosion of a turbine blade.
  • the low pressure turbine 125 may operate at point 6 of FIG. 4 indicating a lower turbine outlet pressure while dryness fraction is maintained at 90% or greater.
  • the pressure of the steam supplied by the heat supplying unit 110 may be 3 to 10 bar, and the temperature of the inlet of the low pressure turbine 125 may be 300 to 500 0 C.
  • the pressure of the outlet of the low pressure turbine 125 is an absolute pressure of approximately 0.04 kgf/cm , and the temperature of the inlet of the low pressure turbine 125 is 300 to 400 0 C.
  • FIG. 4 when the thermal power plant 100 having the pure oxygen combustor of FIG. 1 is used, more efficient operation is possible at point 6.
  • the power generator 140 converts mechanical energy generated by the turbine unit
  • the steam condenser 150 condenses the steam passing through the turbine unit 120 by using cooling water.
  • the steam is re-condensed by the steam condenser 150 into water.
  • seawater, etc. may be used as cooling water but the present invention is not limited to this. All cooling units may be used that condense the steam according to other purposes of the invention.
  • CO that is discharged through the steam condenser 150 is separated from water and is recovered by the recovery pump 160, and water condensed by the steam condenser
  • a power plant 200 having a pure oxygen combustor according to another embodiment of the present invention will now be described with reference to FIG. 5.
  • FIG. 5 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • the power plant 200 having the pure oxygen combustor according to current embodiment comprises a heat supplying unit 210, a turbine unit
  • the pump actuator 280 comprises a second combustor 281 which divides the steam passing through the intermediate pressure turbine 223 and reheats the divided steam, a second turbine unit 283 which generates mechanical energy by rotating the turbine by using steam passing through the second combustor 281, and a second power generator 285 which actuates the water supplying pump 270 by converting mechanical energy generated by the second turbine unit 283 into electrical energy.
  • the second combustor 281 of the pump actuator 280 heats the steam passing through the intermediate pressure turbine 223 by pure oxygen combustion, supplies the heated steam to the second turbine unit 283, and converts energy of the steam into mechanical energy by using the second turbine unit 283.
  • the water supplying pump 270 may be directly actuated using mechanical energy generated by the second turbine unit 283, and mechanical energy generated by the second turbine unit 283 is converted by the second power generator 285 into electrical energy. And the water supplying pump 270 may be actuated using electrical energy.
  • a mixture of low-pressure and low-temperature steam and CO that is exhausted by the second turbine unit 283 of the pump actuator 280 is supplied to the steam condenser 250 and is processed in the same manner as a mixture of a combustion gas and the steam exhausted by the low pressure turbine 225.
  • the heat supplying unit 210, the turbines unit 220, the first combustor 230, the first power generator 240, the steam condenser 250, the recovery pump 260, and the water supplying pump 270 of the power plant 200 having the pure oxygen combustor illustrated in FIG. 5 are the same elements as the heat supplying unit 110, the turbines unit 120, the first combustor 130, the power generator 140, the steam condenser 150, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor illustrated in FIG. 1, and thus, a description thereof will be omitted.
  • the second combustor 281 has the same configuration as the first combustor 130 and performs the same function as the first combustor 130.
  • the second turbine unit 283 and the second power generator 285 have the same configuration as the turbine unit 220 and perform the same function as the turbine unit 220 and the first power generator 240, respectively, and thus, a description thereof will be omitted.
  • FIG. 6 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • the power plant 300 having the pure oxygen combustor and using a waste steam comprises a heat supplying unit 310, a turbine unit 320, a first combustor 330, a power generator 340, a steam condenser 350, and a recovery pump 360.
  • the heat supplying unit 310 supplies a waste steam generated from one facility selected from the group consisting of an incinerator furnace, a heating furnace, a factory, and a thermal power plant, to the first combustor 330.
  • the heat supplying unit 310 supplying the waste steam in this way is not limited to the incinerator furnace described above, but various industry facilities may be used in the supplying unit 310 to supply the waste steam to the first combustor 330 according to the purpose of the invention.
  • a plurality of turbine units 320 such as a high temperature turbine, an intermediate temperature turbine, and a low pressure turbine, may be provided according to the temperature and pressure of the supplied steam. However, since a power generation system is actuated using the waste steam discharged from other facility, only one turbine 320 may be provided so as to prevent an increase in costs due to an unnecessary increase in the number of turbines.
  • the steam condenser 350 may be installed in the ground and condense the steam passing through the turbine unit 320 using geothermal heat.
  • a conventional method of condensing the steam by using cooling water supplied by a cooling tower may be used instead of using the steam condenser 350.
  • a facility for discharging the waste steam such as an incinerator furnace, etc. is a previously-equipped facility.
  • cooling water such as seawater, etc.
  • the conventional method of condensing steam by using cooling water supplied by a cooling tower is not economical.
  • [I l l] CO that is discharged by the steam condenser 350 is separated from water and is recovered by the recovery pump 360, and water condensed by the steam condenser 350 may be discarded or reused by including an additional water supplying pump (not shown).
  • the first combustor 330, the power generator 340, and the recovery pump 360 of the power plant 300 having the pure oxygen combustor of FIG. 6 are the same elements as the first combustor 130, the power generator 140, and the recovery pump 160 of the power plant 100 having the pure oxygen combustor of FIG. 1, respectively, and thus a description thereof will be omitted.
  • a power plant 400 having a pure oxygen combustor according to another embodiment of the present invention will now be described with reference to FIG. 7.
  • FIG. 7 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
  • the power plant 400 having the pure oxygen combustor comprises a heat supplying unit 410, a turbine unit 420, a first combustor 430, a power generator 440, a steam condenser 450, a recovery pump 460, and a water supplying pump 470.
  • the heat supplying unit 410 may comprise a heat exchanger 413 which exhausts the steam heated by an exhaust gas generated in a fuel cell system 411.
  • the fuel cell system 411 is a system which converts chemical energy into electrical energy by electrochemical reaction in anode and cathode. A high temperature gas is discharged by the fuel cell system 411 to the outside of the fuel cell system 411.
  • Examples of the fuel cell system 411 include phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), polymer electrolyte fuel cells (PEFC), etc. according to the type of an electrolyte.
  • An MCFC system 411 is used in the power plant 400 having the pure oxygen combustor of FIG. 7.
  • the fuel cell system 411 exhausts a high temperature gas of approximately 300 to
  • the heat from the high temperature gas is recovered by the heat exchanger 413 and generates high temperature steam.
  • the power plant 400 having the pure oxygen combustor of FIG. 7 is actuated using high temperature steam.
  • the heat exchanger 413 may be a heat recovery steam generator (HRSG).
  • HRSG is a heat exchanger which has been utilized in the field of an industry plant, such as a steam generator, a chemical plant, steel making, an incinerator system, etc..
  • the HRSG is a waste heat recovery device which recovers the residual heat of a gas turbine exhaust gas and generates the steam for power generation and processes.
  • the high temperature and high pressure steam generated in the heat exchanger 413 is injected into the first combustor 430 and is reheated using pure oxygen combustion, and the higher temperature steam is supplied to the turbine unit 420.
  • the turbine unit 420 may be the same element as the turbine unit 120 of the power plant 100 having the pure oxygen combustor of FIG. 1, and an appropriate number of turbines may be provided according to the temperature and pressure of the supplied steam.
  • the pressure of the steam supplied from the heat exchanger 413 may be 5 to 20 bar, and the temperature of the inlet of the turbine unit 420 may be 300 to 600 0 C.
  • the first combustor 430, the power generator 440, the recovery pump 460, and the water supplying pump 470 of the power plant 400 having the pure oxygen combustor of FIG. 7 are the same elements as the first combustor 130, the power generator 140, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor of FIG. 1, respectively, and thus a description thereof will be omitted.
  • the power plant having the pure oxygen combustor according to embodiments of the present invention can be used in a combined cycle thermal power plant.
  • the combined cycle thermal power plant is a plant in which, firstly, electricity is generated by rotating a gas turbine by using a fuel, such as a natural gas, a light oil, etc. and exhaust gas heat generated in the gas turbine is recovered by using the HRSG and high temperature steam is produced and secondly, electricity is generated by rotating a steam turbine.
  • a fuel such as a natural gas, a light oil, etc.
  • exhaust gas heat generated in the gas turbine is recovered by using the HRSG and high temperature steam is produced and secondly, electricity is generated by rotating a steam turbine.
  • the thermal power plant having a pure oxygen combustor according to the current embodiment of the present invention is used in the combined cycle thermal power plant, recovers the residual heat of the exhaust gas generated in the gas turbine by using the HRSG to generate high temperature and high pressure steam, and steam passing through the HRSG is supplied to a turbine unit (not shown), and then, the thermal power plant may be realized by using the same process as that performed by the turbine unit 120, the first combustor 130, the power generator 140, the steam condenser 150, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor of FIG. 1.

Abstract

Provided is a power plant having a pure oxygen combustor. The power plant includes a heat supplying unit supplying a heated steam; a turbine unit generating mechanical energy by rotating a turbine using the heated steam supplied by the heat supplying unit; a power generator converting mechanical energy generated by the turbine unit into electrical energy; a steam condenser condensing steam passing through the turbine unit; and a first combustor disposed at one side of the turbine unit and reheating the steam supplied to the turbine unit by using pure oxygen combustion.

Description

Description POWER PLANT HAVING PURE OXYGEN COMBUSTOR
Technical Field
[1] The present invention relates to a high efficiency power plant, and more particularly, to a power plant equipped with a pure oxygen combustor to improve thermal efficiency using pure oxygen combustion. Background Art
[2] From the related art, a research for designing an efficient power plant has proceeded.
Various power plants to obtain high efficiency have been designed. Among them the Rankine cycle, which is applied to a thermal power plant is also called a steam cycle or a vapor cycle and uses steam as a working fluid. The Rankine cycle is realized by each element, such as a water supplying pump (adiabatic compression), a boiler and a superheater (isobaric heating), a turbine (adiabatic expansion), and a steam condenser (isobaric heat dissipation).
[3] There have been many efforts to apply the principle of a regenerative cycle, a reheat cycle, etc. to a power plant to improve the thermal efficiency of the plant. However, even when such a regenerative cycle or reheat cycle is used, the used steam is not directly heated. Thus, the thermal efficiency of the thermal power plant is not fully achieved. In a conventional power generation system, when steam is reheated using heat exchange of a combustion gas, the temperature of a discharged combustion gas is high, and a thermal loss is large.
[4] Meanwhile, there also have been many efforts for designing a more efficient power plant in connection with other systems, such as fuel cells.
[5] In general, fuel cells convert chemical energy into electrical energy by electrochemical reaction in anode and cathode. In fuel cells, a reactant is supplied continuously from the outside and reaction products are continuously removed to the outside of a fuel cell system.
[6] Fuel cells use various fuels, such as a fossil fuel, a liquid fuel, and a gaseous fuel.
Fuel cells can be classified into low temperature type fuel cells of less than 1000C, intermediate temperature type fuel cells of about 150 to 3000C, and high temperature type fuel cells of 6000C or higher according to its working temperature. In addition, fuel cells can be classified into phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), polymer electrolyte fuel cells (PEFC), etc. according to the type of an electrolyte.
[7] Low temperature type PEFC are mainly used for transportation or home power generator, and high temperature type MCFC or SOFC are mainly used for large scale power generation.
[8] A conventional method of additionally using an exhaust gas of a fuel cell has been devised. In other words, a high temperature gas exhausted in an MCFC system or a PAFC system is used for cooling/heating, etc. so as to use heat more efficiently. However, additional power generation is not easy in the conventional method of additionally using the exhaust gas of the fuel cell. So, it is needed to invent a new system to make more electric power generation in order to use the heat more efficiently.
[9] When the steam is produced by heat exchanging with the exhausted gas from a fuel cell and the steam is used to drive conventional steam turbine, the amount of electric power generation is not large. A hybrid system can also be constituted by connecting a gas turbine to the fuel cell. However, it is very difficult to constitute such a hybrid system due to some technical problems.
[10] A conventional fuel cell system has a high efficiency. However, the development of a hybrid system with other engines is needed to take superiority over competitive technologies.
[11] As an example, when such a fuel cell system is connected to a gas turbine, higher efficiency can be obtained. However, it is difficult to redesign the inside of the conventional fuel cell system and simultaneous operations that link the fuel cell and the gas turbine is very complicated.
[12] When a high temperature exhausted gas from the fuel cell system is used as a heat supplying source of the bottoming system, total power generation efficiency can be increased. Thus, the needs for development of a high efficiency power plant combining the thermal power plant with the fuel cell system are increasing.
[13] As such, the development of a power plant designed to more efficiently increase thermal efficiency is needed.
[14] In addition, in various general industry field, such as power plants, motor vehicles, boilers, etc., a lot of fossil fuel, such as petroleum, coal, etc., are combusted as a heat source. Thus, an enormous amount of a combustion gas is exhausted to the atmosphere from various exhaust sources so that the content of carbon dioxide (CO ) in the atmosphere increases gradually.
[15] As such, global warming due to the so-called greenhouse effect becomes serious, and the development of a method of reducing CO that is inevitably dissipated from the power plant using a fossil fuel, etc. is in urgent need.
[16] Accordingly, the development of a system for obtaining high efficiency and for reducing CO generated in the power plant without dissipating CO to the atmosphere is required.
Disclosure of Invention Technical Problem
[17] The present invention provides a power plant having a pure oxygen combustor to improve thermal efficiency and separate carbon dioxide (CO ) from exhausted gas.
[18] The present invention also provides a power plant having a pure oxygen combustor which is more economical and is designed to achieve high efficiency in connection with other systems. Technical Solution
[19] In a power plant having a pure oxygen combustor according to the present invention, steam supplied to a turbine unit is directly heated by using the pure oxygen combustor so that higher thermal efficiency can be obtained. In addition, an additional recovery pump is provided so that high concentration carbon dioxide (CO ) can be recovered from a gas exhausted by a steam condenser and a power plant that is more economical and has higher efficiency can be provided in connection with other systems.
Advantageous Effects
[20] As described above, a power plant having a pure oxygen combustor according to the present invention has the following advantages. [21] First, the steam is directly heated using pure oxygen combustion such that a high efficiency power plant is designed and high concentration carbon dioxide (CO ) is separated from an exhausted gas. [22] Second, since the combustor is designed such that a portion of steam is injected directly into the combustor, the temperature of the combustor is lowered and overheating of a particular portion can be prevented. [23] Third, since a waste steam of other facilities is supplied to obtain energy, a power plant can be designed that is economical and environment-friendly by using a simple, economical cooling unit. [24] Fourth, system can have high efficiency because steam is generated by the high temperature exhausted gas from fuel cell and only a small amount of additional fuel is needed in pure oxygen combustor of the invented system. [25] Fifth, intermediate pressure and intermediate temperature steam passing through an intermediate pressure turbine is reheated using pure oxygen combustion such that a low pressure turbine can operate with the degree of dryness at 90% or greater at a lower turbine outlet pressure.
Brief Description of the Drawings [26] FIG. 1 schematically illustrates a power plant having a pure oxygen combustor according to an embodiment of the present invention. [27] FIG. 2 illustrates a formula when methane is supplied as a fuel from the power plant having a pure oxygen combustor of FIG. 1 and pure oxygen combustion is performed. [28] FIG. 3 schematically illustrates a first combustor of the power plant having the pure oxygen combustor of FIG. 1.
[29] FIG. 4 is a graph showing the Rankine cycle of the power plant having the pure oxygen combustor of FIG. 1.
[30] FIG. 5 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
[31] FIG. 6 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
[32] FIG. 7 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
[33] <Explanation of Reference Numerals Designating the Major Elements of the
Drawings>
[34] 100, 200, 300, 400 : power plant having pure oxygen combustors
[35] 110, 210, 310, 410 : heat supplying unit
[36] 111, 211 : heater 113, 213 : boiler
[37] 120, 220, 320, 420 : turbine unit 121, 221 : high pressure turbine
[38] 123, 223 : intermediate turbine 125, 225 : low pressure turbine
[39] 130, 230, 330, 430 : first combustor 131 : inlet portion
[40] 133 : injection hole 135 : main body portion
[41] 140, 240, 340, 440 : power generator
[42] 150, 250, 350, 450 : steam condenser
[43] 160, 260, 360, 460 : recovery pump
[44] 170, 270, 470 : water supplying pump
[45] 280 : pump actuator 281 : second combustor
[46] 283 : second turbine unit 285 : second power generator
[47] 411 : fuel cell system 413 : heat exchanger
Best Mode for Carrying Out the Invention
[48] According to an aspect of the present invention, invented power plant with pure oxygen combustor is composed of: a heat supplying unit supplying a heated steam; a turbine unit generating mechanical energy by rotating a turbine using the heated steam supplied by the heat supplying unit; a power generator converting mechanical energy generated by the turbine unit into electrical energy; a steam condenser condensing steam passing through the turbine unit; and a first combustor disposed at one side of the turbine unit and reheating the steam supplied to the turbine unit by using pure oxygen combustion.
[49] The turbine unit may include a high pressure turbine, an intermediate pressure turbine, and a low pressure turbine according to operating pressure and temperature of the supplied steam. The first combustor may be interposed between the intermediate pressure turbine and the low pressure turbine, may reheat the steam passing through the intermediate pressure turbine by using pure oxygen combustion, and may supply the reheated steam to the low pressure turbine.
[50] Pressure of steam supplied by the heat supplying unit may be 3 to 10 bar, and temperature of an inlet of the low pressure turbine may be 300 to 5000C.
[51] The power plant may further include: a water supplying pump delivering water condensed by the steam condenser to the heat supplying unit; and a pump actuator comprising a second combustor dividing a portion of the steam passing through the intermediate pressure turbine and reheating the divided steam, a second turbine unit actuating the water supplying pump by rotating the turbine by using the steam reheated by the second combustor, and a second power generator actuating the water supplying pump by converting mechanical energy generated by the second turbine unit into electrical energy.
[52] The second combustor may include: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion into which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in the side of the main body portion.
[53] The heat supplying unit may supply a waste steam generated from one facility selected from the group consisting of an incinerator furnace, a heating furnace, a factory, and a thermal power plant, to the first combustor, and the steam condenser may be installed in the ground and may condense the steam passing through the turbine unit by using geothermal heat.
[54] The heat supplying unit may include a heat exchanger discharging high temperature and high pressure steam due to an exhaust gas generated in a fuel cell system.
[55] Pressure of the steam passing through the heat exchanger may be 5 to 20 bar, and temperature of an inlet of the turbine unit may be 300 to 6000C.
[56] The first combustor may include: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion into which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in the side of the main body portion.
[57] The power plant may further include a recovery pump recovering carbon dioxide
(CO ) from exhausted gas by condensing the water in the exhausted gas. Mode for the Invention
[58] The present invention will now be described more fully with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. First, terms or words used in the present specification and the claims should not be construed as being limited to general or literal meaning, and the inventor should construe his/her own invention in meaning and concept that coincide with the technical spirit of the invention based on the principle for properly defining the concept of the terms so as to describe his/her own invention in the best manner.
[59] Thus, configurations shown in embodiments and the drawings of the present invention is rather an example of the most exemplary embodiment and does not represent all of the technical spirit of the invention. Thus, it will be understood that various equivalents and modifications that replace the configurations are possible when filing the present application.
[60] A power plant having a pure oxygen combustor according to an embodiment of the present invention will now be described with reference to FIGS. 1 through 4.
[61] FIG. 1 schematically illustrates a power plant having a pure oxygen combustor according to an embodiment of the present invention, and FIG. 2 illustrates a formula when methane is supplied as a fuel to the pure oxygen combustor of the power plant illustrated in FIG. 1
[62] Referring to FIG. 1, a power plant 100 having a pure oxygen combustor according to the current embodiment of the present invention comprises a heat supplying unit 110, a turbine unit 120, a first combustor 130, a power generator 140, a steam condenser 150, a recovery pump 160, and a water supplying pump 170.
[63] The heat supplying unit 110 comprises a heater 111 and a boiler 113, and the heater
111 supplies heat generated by combusting a fuel, such as a fossil fuel, etc., to the boiler 113.
[64] The heater 111 may comprise all of heat supplying units which are not limited to generation of heat by combusting a fuel, such as a fossil fuel, etc., but are able to use heat of a waste gas generated in factory, etc. or supply heat so that heat exchange occurs in the boiler 113 for the purpose of the invention.
[65] The boiler 113 heats water accommodated therein by using heat supplied by the heater 111 to generate high temperature and high pressure steam.
[66] The turbine unit 120 comprises a high pressure turbine 121, an intermediate pressure turbine 123, and a low pressure turbine 125 according to the pressure and temperature of an induced steam.
[67] The high pressure turbine 121 rotates a turbine by expanding the supplied high- temperature and high-pressure steam through a nozzle and thus converts energy of high-temperature and high-pressure steam into mechanical energy.
[68] The intermediate-pressure and intermediate-temperature steam passing through the high pressure turbine 121 is re-supplied to the boiler 113 according to the principle of a reheat system. The temperature of the steam is increased by reheating, and the steam is supplied to the intermediate pressure turbine 123. The turbine is rotated using the same principle as the high temperature turbine 121, and the energy of the steam is converted into mechanical energy.
[69] In addition, the low-pressure and low-temperature steam passing through the intermediate pressure turbine 123 is supplied to the low pressure turbine 125, and the turbine is rotated using the same principle as the high temperature turbine 121, and mechanical energy is generated.
[70] In this case, the first combustor 130 is interposed between the intermediate pressure turbine 123 and the low pressure turbine 125, and low pressure and low temperature steam passing through the intermediate pressure turbine 123 is directly reheated using pure oxygen combustion, and the heated steam is supplied to the low pressure turbine 125.
[71] The first combustor 130 must use one of either the process byproduct or fossil-fuel excluding nitrogen as a fuel and pure oxygen as an oxidizer.
[72] The fossil fuel may include all fossil fuels, such as solid, liquid, and gaseous fossil fuels. A waste gas or a digester gas excluding nitrogen may be used as the process byproducts.
[73] Referring to FIG. 2, oxygen and methane are supplied to the first combustor 130 of the power planet 100 having the pure oxygen combustor shown in FIG. 1, together with the steam. Since only carbon dioxide (CO ) and water vapor exist in a combustion gas generated using pure oxygen combustion between oxygen and methane, when water vapor in the combustion gas is condensed by the steam condenser 150, water vapor may be separated from condensed water and high concentration CO may be recovered by the recovery pump 160.
[74] However, this is just an exemplary embodiment of the present invention. Thus, a fossil fuel supplied to the first combustor 130 is not limited to methane, and a variety of types of fossil fuels that cause pure oxygen combustion may be supplied to the first combustor 130 together with oxygen according to the purpose of the invention.
[75] In this way, the first combustor 130 reduces a thermal loss by directly mixing the combustion gas with the steam and, therefore, has high thermal efficiency.
[76] In addition, when the combustion gas is mixed with the steam by installing a combustor using the air, a large amount of nitrogen in the air is flown in, and CO cannot be recovered, and the amount of an uncondensed gas that must be discharged to the outlet of the turbine increases, and thus the case is not appropriate to a power generation system. On the other hand, when the first combustor 130 is installed as in the power plant 100 having the pure oxygen combustor shown in FIG. 1, an uncondensed gas discharged to the rear end of the turbine unit 120 includes only CO . Thus, the amount of discharge of the uncondensed gas is small and high concentration CO may be recovered. [77] The structure of the first combustor 130 of the power plant 100 having the pure oxygen combustor of FIG. 1 will now be described with reference to FIG. 3 in more detail. FIG. 3 schematically illustrates the first combustor of the power plant having the pure oxygen combustor of FIG. 1.
[78] Referring to FIG. 3, the first combustor 130 comprises an inlet portion 131 having a plurality of nozzles through which steam, oxygen, and a fossil fuel are injected, and a main body portion 135 into which the remaining steam excluding the steam injected through the inlet portion 131 is injected through an injection hole 133 formed in the side of the main body portion 135.
[79] A portion of a fuel, oxygen, and water vapor is injected through the nozzles of the inlet portion 131, and pure oxygen combustion is performed between the injected oxygen and fuel so that a high temperature combustion gas can be obtained. The high temperature combustion gas and steam injected through the inlet portion 131 are mixed so that a desired temperature combustion gas can be obtained.
[80] In other words, a mixture of the combustion gas and the steam generated using pure oxygen combustion is supplied to the low pressure turbine 125 to generate mechanical energy, and the mixture of the combustion gas and steam passing through the low pressure turbine 125 passes the steam condenser 150. In this case, water vapor is condensed and discharged in the form of water. CO that is not condensed by the steam condenser 150 is recovered by the recovery pump 160 interposed between the steam condenser 150 and the water supplying pump 170.
[81] Since a portion of the steam is injected into the first combustor 130 through the nozzles of the inlet portion 131 together with oxygen and a fossil fuel, overheating of the inlet portion 131 due to pure oxygen combustion between oxygen and the fossil fuel can be prevented, and nitrogen oxide (NO ) due to overheating can be prevented from being generated. [82] In addition, unlike heating using other heat exchangers, the steam is directly injected into the first combustor 130, and heated by pure oxygen combustion which leads to an enhanced thermal efficiency. [83] In order to describe how to increase the thermal efficiency of the power plant 100 having the pure oxygen combustor according to the present invention, the Rankine cycle due to the power plant 100 having the pure oxygen combustor shown in FIG. 1 is illustrated in FIG. 4. [84] FIG. 4 is a graph showing the Rankine cycle of the power plant having the pure oxygen combustor of FIG. 1. [85] Referring to FIG. 4, a low pressure turbine used in a conventional thermal power plant operates with the Rankine cycle having the condition of 1-2-3-5-1. On the other hand, like in the power plant 100 having the pure oxygen combustor of FIG. 1, when the inlet of the low pressure turbine 125 is reheated by using the first combustor 130 performing pure oxygen combustion, the low pressure turbine 125 operates with the
Rankine cycle having the condition of 7-1-2-3-4-6-7. [86] In other words, in the conventional power plant due to the Rankine cycle, the low pressure turbine 125 operates with the condition of a wet vapor at point 5 of FIG. 4 corresponding to the outlet of the low pressure turbine 125. Thus, dryness fraction must be maintained at 90% or greater to prevent erosion of a turbine blade. [87] However, when the inlet of the turbine is reheated using pure oxygen combustion, the low pressure turbine 125 may operate at point 6 of FIG. 4 indicating a lower turbine outlet pressure while dryness fraction is maintained at 90% or greater. [88] The pressure of the steam supplied by the heat supplying unit 110 may be 3 to 10 bar, and the temperature of the inlet of the low pressure turbine 125 may be 300 to 5000C. [89] For example, the pressure of the outlet of the low pressure turbine 125 is an absolute pressure of approximately 0.04 kgf/cm , and the temperature of the inlet of the low pressure turbine 125 is 300 to 4000C. [90] Thus, as illustrated in FIG. 4, when the thermal power plant 100 having the pure oxygen combustor of FIG. 1 is used, more efficient operation is possible at point 6.
Thus, electrical efficiency is improved by about 2 to 3% for the low pressure turbine
125 only. [91] The power generator 140 converts mechanical energy generated by the turbine unit
120 into electrical energy. [92] The steam condenser 150 condenses the steam passing through the turbine unit 120 by using cooling water. The steam is re-condensed by the steam condenser 150 into water. [93] In addition, seawater, etc. may be used as cooling water but the present invention is not limited to this. All cooling units may be used that condense the steam according to other purposes of the invention. [94] CO that is discharged through the steam condenser 150 is separated from water and is recovered by the recovery pump 160, and water condensed by the steam condenser
150 is delivered to the boiler 113 through the water supplying pump 170. [95] A power plant 200 having a pure oxygen combustor according to another embodiment of the present invention will now be described with reference to FIG. 5.
FIG. 5 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention. [96] Referring to FIG. 5, the power plant 200 having the pure oxygen combustor according to current embodiment comprises a heat supplying unit 210, a turbine unit
220, a first combustor 230, a first power generator 240, a steam condenser 250, a recovery pump 260, a water supplying pump 270, and a pump actuator 280. [97] The pump actuator 280 comprises a second combustor 281 which divides the steam passing through the intermediate pressure turbine 223 and reheats the divided steam, a second turbine unit 283 which generates mechanical energy by rotating the turbine by using steam passing through the second combustor 281, and a second power generator 285 which actuates the water supplying pump 270 by converting mechanical energy generated by the second turbine unit 283 into electrical energy.
[98] The second combustor 281 of the pump actuator 280 heats the steam passing through the intermediate pressure turbine 223 by pure oxygen combustion, supplies the heated steam to the second turbine unit 283, and converts energy of the steam into mechanical energy by using the second turbine unit 283.
[99] The water supplying pump 270 may be directly actuated using mechanical energy generated by the second turbine unit 283, and mechanical energy generated by the second turbine unit 283 is converted by the second power generator 285 into electrical energy. And the water supplying pump 270 may be actuated using electrical energy.
[100] A mixture of low-pressure and low-temperature steam and CO that is exhausted by the second turbine unit 283 of the pump actuator 280 is supplied to the steam condenser 250 and is processed in the same manner as a mixture of a combustion gas and the steam exhausted by the low pressure turbine 225.
[101] The heat supplying unit 210, the turbines unit 220, the first combustor 230, the first power generator 240, the steam condenser 250, the recovery pump 260, and the water supplying pump 270 of the power plant 200 having the pure oxygen combustor illustrated in FIG. 5 are the same elements as the heat supplying unit 110, the turbines unit 120, the first combustor 130, the power generator 140, the steam condenser 150, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor illustrated in FIG. 1, and thus, a description thereof will be omitted.
[102] In addition, the second combustor 281 has the same configuration as the first combustor 130 and performs the same function as the first combustor 130. In addition, the second turbine unit 283 and the second power generator 285 have the same configuration as the turbine unit 220 and perform the same function as the turbine unit 220 and the first power generator 240, respectively, and thus, a description thereof will be omitted.
[103] A power plant 300 having a pure oxygen combustor according to another embodiment of the present invention will now be described with reference to FIG. 6. FIG. 6 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
[104] Referring to FIG. 6, the power plant 300 having the pure oxygen combustor and using a waste steam according to the current embodiment of the present invention comprises a heat supplying unit 310, a turbine unit 320, a first combustor 330, a power generator 340, a steam condenser 350, and a recovery pump 360.
[105] The heat supplying unit 310 supplies a waste steam generated from one facility selected from the group consisting of an incinerator furnace, a heating furnace, a factory, and a thermal power plant, to the first combustor 330.
[106] The heat supplying unit 310 supplying the waste steam in this way is not limited to the incinerator furnace described above, but various industry facilities may be used in the supplying unit 310 to supply the waste steam to the first combustor 330 according to the purpose of the invention.
[107] A plurality of turbine units 320, such as a high temperature turbine, an intermediate temperature turbine, and a low pressure turbine, may be provided according to the temperature and pressure of the supplied steam. However, since a power generation system is actuated using the waste steam discharged from other facility, only one turbine 320 may be provided so as to prevent an increase in costs due to an unnecessary increase in the number of turbines.
[108] In addition, the steam condenser 350 may be installed in the ground and condense the steam passing through the turbine unit 320 using geothermal heat.
[109] A conventional method of condensing the steam by using cooling water supplied by a cooling tower may be used instead of using the steam condenser 350. However, a facility for discharging the waste steam, such as an incinerator furnace, etc. is a previously-equipped facility. Thus, it may be difficult to use cooling water, such as seawater, etc., in a sea region and an inland region in which water supply is not easy, and a high cost is needed in supply of a large amount of cooling water used in cond ensation using a cooling tower. Thus, the conventional method of condensing steam by using cooling water supplied by a cooling tower is not economical.
[110] When the steam condenser 350 is installed under the ground as shown in the power plant 300 having the pure oxygen combustor of FIG. 6, the steam may be cooled down and condensed in a simple and efficient manner, and continuous reuse is possible without an additional cost.
[I l l] CO that is discharged by the steam condenser 350 is separated from water and is recovered by the recovery pump 360, and water condensed by the steam condenser 350 may be discarded or reused by including an additional water supplying pump (not shown).
[112] The first combustor 330, the power generator 340, and the recovery pump 360 of the power plant 300 having the pure oxygen combustor of FIG. 6 are the same elements as the first combustor 130, the power generator 140, and the recovery pump 160 of the power plant 100 having the pure oxygen combustor of FIG. 1, respectively, and thus a description thereof will be omitted. [113] A power plant 400 having a pure oxygen combustor according to another embodiment of the present invention will now be described with reference to FIG. 7. FIG. 7 schematically illustrates a power plant having a pure oxygen combustor according to another embodiment of the present invention.
[114] Referring to FIG. 7, the power plant 400 having the pure oxygen combustor according to the current embodiment of the present invention comprises a heat supplying unit 410, a turbine unit 420, a first combustor 430, a power generator 440, a steam condenser 450, a recovery pump 460, and a water supplying pump 470.
[115] The heat supplying unit 410 may comprise a heat exchanger 413 which exhausts the steam heated by an exhaust gas generated in a fuel cell system 411.
[116] The fuel cell system 411 is a system which converts chemical energy into electrical energy by electrochemical reaction in anode and cathode. A high temperature gas is discharged by the fuel cell system 411 to the outside of the fuel cell system 411.
[117] Examples of the fuel cell system 411 include phosphoric acid fuel cells (PAFC), molten carbonate fuel cells (MCFC), solid oxide fuel cells (SOFC), polymer electrolyte fuel cells (PEFC), etc. according to the type of an electrolyte. An MCFC system 411 is used in the power plant 400 having the pure oxygen combustor of FIG. 7.
[118] The fuel cell system 411 exhausts a high temperature gas of approximately 300 to
37O0C. The heat from the high temperature gas is recovered by the heat exchanger 413 and generates high temperature steam.
[119] The power plant 400 having the pure oxygen combustor of FIG. 7 is actuated using high temperature steam.
[120] The heat exchanger 413 may be a heat recovery steam generator (HRSG). An HRSG is a heat exchanger which has been utilized in the field of an industry plant, such as a steam generator, a chemical plant, steel making, an incinerator system, etc.. The HRSG is a waste heat recovery device which recovers the residual heat of a gas turbine exhaust gas and generates the steam for power generation and processes.
[121] In other words, the residual heat of the exhaust gas generated in the fuel cell system 411 is recovered by the heat exchanger 413, and high temperature and high pressure steam is generated.
[122] In addition, the high temperature and high pressure steam generated in the heat exchanger 413 is injected into the first combustor 430 and is reheated using pure oxygen combustion, and the higher temperature steam is supplied to the turbine unit 420.
[123] The turbine unit 420 may be the same element as the turbine unit 120 of the power plant 100 having the pure oxygen combustor of FIG. 1, and an appropriate number of turbines may be provided according to the temperature and pressure of the supplied steam.
[124] The pressure of the steam supplied from the heat exchanger 413 may be 5 to 20 bar, and the temperature of the inlet of the turbine unit 420 may be 300 to 6000C.
[125] The first combustor 430, the power generator 440, the recovery pump 460, and the water supplying pump 470 of the power plant 400 having the pure oxygen combustor of FIG. 7 are the same elements as the first combustor 130, the power generator 140, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor of FIG. 1, respectively, and thus a description thereof will be omitted.
[126] In addition, the power plant having the pure oxygen combustor according to embodiments of the present invention can be used in a combined cycle thermal power plant.
[127] The combined cycle thermal power plant is a plant in which, firstly, electricity is generated by rotating a gas turbine by using a fuel, such as a natural gas, a light oil, etc. and exhaust gas heat generated in the gas turbine is recovered by using the HRSG and high temperature steam is produced and secondly, electricity is generated by rotating a steam turbine.
[128] In other words, the thermal power plant having a pure oxygen combustor according to the current embodiment of the present invention is used in the combined cycle thermal power plant, recovers the residual heat of the exhaust gas generated in the gas turbine by using the HRSG to generate high temperature and high pressure steam, and steam passing through the HRSG is supplied to a turbine unit (not shown), and then, the thermal power plant may be realized by using the same process as that performed by the turbine unit 120, the first combustor 130, the power generator 140, the steam condenser 150, the recovery pump 160, and the water supplying pump 170 of the power plant 100 having the pure oxygen combustor of FIG. 1.
[129] While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims.

Claims

Claims
[1] A power plant having a pure oxygen combustor, the power plant comprising: a heat supplying unit supplying a heated steam; a turbine unit generating mechanical energy by rotating a turbine using the heated steam supplied by the heat supplying unit; a power generator converting mechanical energy generated by the turbine unit into electrical energy; a steam condenser condensing steam passing through the turbine unit; and a first combustor disposed at one side of the turbine unit and reheating the steam supplied to the turbine unit by using pure oxygen combustion.
[2] The power plant of claim 1, wherein the turbine unit comprises a high pressure turbine, an intermediate pressure turbine, and a low pressure turbine according to pressure and temperature of the supplied steam, and the first combustor is interposed between the intermediate pressure turbine and the low pressure turbine, reheats the steam passing through the intermediate pressure turbine by using pure oxygen combustion, and supplies the reheated steam to the low pressure turbine.
[3] The power plant of claim 2, wherein pressure of steam supplied by the heat supplying unit is 3 to 10 bar, and a temperature of an inlet of the low pressure turbine is 300 to 5000C.
[4] The power plant of claim 2, further comprising: a water supplying pump delivering water condensed by the steam condenser to the heat supplying unit; and a pump actuator comprising a second combustor dividing a portion of the steam passing through the intermediate pressure turbine and reheating the divided steam, a second turbine unit actuating the water supplying pump by rotating the turbine by using the steam reheated by the second combustor, and a second power generator actuating the water supplying pump by converting mechanical energy generated by the second turbine unit into electrical energy.
[5] The power plant of claim 4, wherein the second combustor comprises: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion into which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in a side of the main body portion.
[6] The power plant of claim 1 , wherein the heat supplying unit supplies the first combustor with a waste steam generated from one facility selected from the group consisting of an incinerator furnace, a heating furnace, a factory, and a thermal power plant, and the steam condenser is installed under the ground and condenses the steam passing through the turbine unit by using geothermal heat. [7] The power plant of claim 1 , wherein the heat supplying unit comprises a heat exchanger discharging high temperature and high pressure steam due to an exhaust gas generated in a fuel cell system. [8] The power plant of claim 7, wherein pressure of the steam supplied by the heat exchanger is 5 to 20 bar, and temperature of an inlet of the turbine unit is 300 to
6000C. [9] The power plant of one of claims 1 through 8, wherein the first combustor comprises: an inlet portion having a plurality of nozzles through which steam, oxygen, and a fuel are injected; and a main body portion in which the remaining steam excluding the steam injected through the inlet portion is injected through an injection hole formed in the side of the main body portion. [10] The power plant of claim 9, further comprising a recovery pump recovering carbon dioxide (CO ) separated from water condensed by the steam condenser.
PCT/KR2008/002600 2007-09-06 2008-05-08 Power plant having pure oxygen combustor WO2009031747A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN2008800003746A CN101542077B (en) 2007-09-06 2008-05-08 Power plant having pure oxygen combustor
EP08753396.4A EP2074290A4 (en) 2007-09-06 2008-05-08 Power plant having pure oxygen combustor

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
KR1020070090395A KR100779609B1 (en) 2007-09-06 2007-09-06 Thermal power plant having pure oxygen combustor and using waste steam
KR1020070090394A KR100814940B1 (en) 2007-09-06 2007-09-06 Thermal power plant having pure oxygen combustor
KR10-2007-0090395 2007-09-06
KR10-2007-0090394 2007-09-06
KR1020070130109A KR100817898B1 (en) 2007-12-13 2007-12-13 Fuel cell-linked power generation plant using pure oxygen combustion
KR10-2007-0130109 2007-12-13

Publications (1)

Publication Number Publication Date
WO2009031747A1 true WO2009031747A1 (en) 2009-03-12

Family

ID=40429043

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/KR2008/002600 WO2009031747A1 (en) 2007-09-06 2008-05-08 Power plant having pure oxygen combustor

Country Status (2)

Country Link
EP (1) EP2074290A4 (en)
WO (1) WO2009031747A1 (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2447479B1 (en) * 2010-10-26 2016-08-17 Siemens Aktiengesellschaft Methods for cooling a carrier fluid of a solar power plant and solar power plant
JP2018193612A (en) * 2015-11-16 2018-12-06 フュエルセル エナジー， インコーポレイテッドＦｕｅｌｃｅｌｌ Ｅｎｅｒｇｙ， Ｉｎｃ． Energy storage using REP with engine
US10465305B2 (en) 2015-11-17 2019-11-05 Fuelcell Energy, Inc. Hydrogen and carbon monoxide generation using an REP with partial oxidation
US10608272B2 (en) 2015-11-16 2020-03-31 Fuelcell Energy, Inc. System for capturing CO2 from a fuel cell
US10892507B2 (en) 2014-01-31 2021-01-12 Fuelcell Energy, Inc. Reformer-electrolyzer-purifier (REP) assembly for hydrogen production, systems incorporating same and method of producing hydrogen
US10897055B2 (en) 2017-11-16 2021-01-19 Fuelcell Energy, Inc. Load following power generation and power storage using REP and PEM technology
US11043684B2 (en) 2015-11-17 2021-06-22 Fuelcell Energy, Inc. Fuel cell system having enhanced CO2 capture
US11339333B2 (en) 2016-04-21 2022-05-24 Fuelcell Energy, Inc. Fluidized catalytic cracking unit system with integrated reformer-electrolyzer-purifier
US11495806B2 (en) 2019-02-04 2022-11-08 Fuelcell Energy, Inc. Ultra high efficiency fuel cell power generation system

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07293207A (en) * 1994-04-27 1995-11-07 Central Res Inst Of Electric Power Ind Hydrogen combustion turbine system
JPH08254107A (en) * 1995-03-16 1996-10-01 Toshiba Corp Turbine system
JPH102205A (en) * 1996-06-18 1998-01-06 Toshiba Corp Hydrogen combustion turbine plant
JP2003269188A (en) * 2002-03-19 2003-09-25 Ishikawajima Harima Heavy Ind Co Ltd Steam injection reheating gas turbine generating set
US6742336B2 (en) * 2001-08-31 2004-06-01 Hitachi, Ltd. Steam turbine power plant

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4074708A (en) * 1976-06-07 1978-02-21 Combustion Engineering, Inc. Burning hydrogen and oxygen to superheat steam
US4148185A (en) * 1977-08-15 1979-04-10 Westinghouse Electric Corp. Double reheat hydrogen/oxygen combustion turbine system
US4498289A (en) * 1982-12-27 1985-02-12 Ian Osgerby Carbon dioxide power cycle
US5260640A (en) * 1992-01-28 1993-11-09 The United States Of America As Represented By The United States Department Of Energy Method of and system for producing electrical power
DE4409196A1 (en) * 1994-03-17 1995-09-21 Siemens Ag Process for operating a gas and steam turbine plant and plant operating thereafter
US5775091A (en) * 1996-10-21 1998-07-07 Westinghouse Electric Corporation Hydrogen fueled power plant
US6021569A (en) * 1997-04-30 2000-02-08 Siemens Westinghouse Power Corporation Retrofitting coal-fired power generation systems with hydrogen combustors
US7284362B2 (en) * 2002-02-11 2007-10-23 L'Air Liquide, Société Anonyme à Directoire et Conseil de Surveillance pour l'Étude et l'Exploitation des Procedes Georges Claude Integrated air separation and oxygen fired power generation system
US6775987B2 (en) * 2002-09-12 2004-08-17 The Boeing Company Low-emission, staged-combustion power generation
JP4521202B2 (en) * 2004-02-24 2010-08-11 株式会社東芝 Steam turbine power plant

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07293207A (en) * 1994-04-27 1995-11-07 Central Res Inst Of Electric Power Ind Hydrogen combustion turbine system
JPH08254107A (en) * 1995-03-16 1996-10-01 Toshiba Corp Turbine system
JPH102205A (en) * 1996-06-18 1998-01-06 Toshiba Corp Hydrogen combustion turbine plant
US6742336B2 (en) * 2001-08-31 2004-06-01 Hitachi, Ltd. Steam turbine power plant
JP2003269188A (en) * 2002-03-19 2003-09-25 Ishikawajima Harima Heavy Ind Co Ltd Steam injection reheating gas turbine generating set

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2074290A4 *

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2447479B1 (en) * 2010-10-26 2016-08-17 Siemens Aktiengesellschaft Methods for cooling a carrier fluid of a solar power plant and solar power plant
US10892507B2 (en) 2014-01-31 2021-01-12 Fuelcell Energy, Inc. Reformer-electrolyzer-purifier (REP) assembly for hydrogen production, systems incorporating same and method of producing hydrogen
JP2018193612A (en) * 2015-11-16 2018-12-06 フュエルセル エナジー， インコーポレイテッドＦｕｅｌｃｅｌｌ Ｅｎｅｒｇｙ， Ｉｎｃ． Energy storage using REP with engine
JP2018537817A (en) * 2015-11-16 2018-12-20 フュエルセル エナジー， インコーポレイテッドＦｕｅｌｃｅｌｌ Ｅｎｅｒｇｙ， Ｉｎｃ． Energy storage using REP with engine
US10608272B2 (en) 2015-11-16 2020-03-31 Fuelcell Energy, Inc. System for capturing CO2 from a fuel cell
US10680265B2 (en) 2015-11-16 2020-06-09 Fuelcell Energy, Inc. Energy storage using an REP with an engine
US10465305B2 (en) 2015-11-17 2019-11-05 Fuelcell Energy, Inc. Hydrogen and carbon monoxide generation using an REP with partial oxidation
US11043684B2 (en) 2015-11-17 2021-06-22 Fuelcell Energy, Inc. Fuel cell system having enhanced CO2 capture
US11339333B2 (en) 2016-04-21 2022-05-24 Fuelcell Energy, Inc. Fluidized catalytic cracking unit system with integrated reformer-electrolyzer-purifier
US10897055B2 (en) 2017-11-16 2021-01-19 Fuelcell Energy, Inc. Load following power generation and power storage using REP and PEM technology
US11495806B2 (en) 2019-02-04 2022-11-08 Fuelcell Energy, Inc. Ultra high efficiency fuel cell power generation system

Also Published As

Publication number Publication date
EP2074290A4 (en) 2017-06-21
EP2074290A1 (en) 2009-07-01

Similar Documents

Publication Publication Date Title
WO2009031747A1 (en) Power plant having pure oxygen combustor
US7862938B2 (en) Integrated fuel cell and heat engine hybrid system for high efficiency power generation
US9435230B2 (en) Fuel cell hybrid system
US20080115500A1 (en) Combustion of water borne fuels in an oxy-combustion gas generator
US20080314741A1 (en) Electrolysis apparatus
CN112585088A (en) High energy nitric acid recovery process using liquid oxygen-containing fluid
KR101568067B1 (en) Fuel cell hybrid system
JP2008287940A (en) Power generation equipment
JPH11297336A (en) Composite power generating system
JP3924243B2 (en) Fuel cell combined power generation system
KR101128829B1 (en) Heat recovery type cogeneration system of fuel cell and generating method thereof
JPH1126004A (en) Power generating system
CN107018674B (en) Fuel cell system with waste heat recovery for producing high pressure steam
KR100814940B1 (en) Thermal power plant having pure oxygen combustor
JP5294291B2 (en) Power generation equipment
KR102029421B1 (en) Fuel cell hybrid generation system
KR101067509B1 (en) A fuel cell-linked power generation plant using pure oxygen combustion and a control method thereof
JP2000200617A (en) Fuel-cell composite power generating plant system
KR101397622B1 (en) Waste heat recovery system for cooling tower of power plant by using feul cell
KR100817898B1 (en) Fuel cell-linked power generation plant using pure oxygen combustion
WO2010084525A1 (en) Hybrid power generation system
Steinfeld et al. High efficiency carbonate fuel cell/turbine hybrid power cycle
AU2022204009B2 (en) Hybrid power plant with CO2 capture
US20120159924A1 (en) System and method for increasing efficiency and water recovery of a combined cycle power plant
CN114068991A (en) Power generation system with hydrogen fuel cell coupled with steam turbine and gas turbine

Legal Events

Date Code Title Description
WWE Wipo information: entry into national phase

Ref document number: 200880000374.6

Country of ref document: CN

WWE Wipo information: entry into national phase

Ref document number: 2008753396

Country of ref document: EP

121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08753396

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE