WO2009029419A1 - Process for production of an olefin oxide - Google Patents
Process for production of an olefin oxide Download PDFInfo
- Publication number
- WO2009029419A1 WO2009029419A1 PCT/US2008/073095 US2008073095W WO2009029419A1 WO 2009029419 A1 WO2009029419 A1 WO 2009029419A1 US 2008073095 W US2008073095 W US 2008073095W WO 2009029419 A1 WO2009029419 A1 WO 2009029419A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- olefin
- silver
- catalyst
- pores
- reactor
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 69
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 50
- 230000008569 process Effects 0.000 title claims abstract description 40
- 238000004519 manufacturing process Methods 0.000 title description 7
- 239000003054 catalyst Substances 0.000 claims abstract description 101
- 239000011148 porous material Substances 0.000 claims abstract description 62
- 229910052709 silver Inorganic materials 0.000 claims abstract description 59
- 239000004332 silver Substances 0.000 claims abstract description 59
- 238000006735 epoxidation reaction Methods 0.000 claims abstract description 28
- 229910052702 rhenium Inorganic materials 0.000 claims abstract description 22
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 18
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 18
- 230000001737 promoting effect Effects 0.000 claims abstract description 18
- 230000002902 bimodal effect Effects 0.000 claims abstract description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 57
- 150000001875 compounds Chemical class 0.000 claims description 31
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 30
- 229910052760 oxygen Inorganic materials 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 30
- 238000006243 chemical reaction Methods 0.000 claims description 28
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 19
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 17
- 238000009826 distribution Methods 0.000 claims description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 239000002184 metal Substances 0.000 claims description 12
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 229910052723 transition metal Inorganic materials 0.000 claims description 11
- 150000003624 transition metals Chemical class 0.000 claims description 11
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 7
- 229910001882 dioxygen Inorganic materials 0.000 claims description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052792 caesium Inorganic materials 0.000 claims description 6
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 5
- 239000010937 tungsten Substances 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000011733 molybdenum Substances 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 4
- 239000010457 zeolite Substances 0.000 claims description 4
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000011651 chromium Substances 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 239000000395 magnesium oxide Substances 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052788 barium Inorganic materials 0.000 claims description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052790 beryllium Inorganic materials 0.000 claims description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000003610 charcoal Substances 0.000 claims description 2
- 229910052735 hafnium Inorganic materials 0.000 claims description 2
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052758 niobium Inorganic materials 0.000 claims description 2
- 239000010955 niobium Substances 0.000 claims description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000008262 pumice Substances 0.000 claims description 2
- 229910052701 rubidium Inorganic materials 0.000 claims description 2
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229910052712 strontium Inorganic materials 0.000 claims description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 1
- 229910052776 Thorium Inorganic materials 0.000 claims 1
- 239000011574 phosphorus Substances 0.000 claims 1
- 229910052698 phosphorus Inorganic materials 0.000 claims 1
- 230000007704 transition Effects 0.000 claims 1
- 239000000243 solution Substances 0.000 description 23
- 239000000203 mixture Substances 0.000 description 21
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 239000007789 gas Substances 0.000 description 18
- 229940117927 ethylene oxide Drugs 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 230000003197 catalytic effect Effects 0.000 description 11
- 238000005470 impregnation Methods 0.000 description 10
- 239000012298 atmosphere Substances 0.000 description 9
- 239000011261 inert gas Substances 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 238000007254 oxidation reaction Methods 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 230000007423 decrease Effects 0.000 description 8
- -1 fuller's earth Chemical compound 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 229910002092 carbon dioxide Inorganic materials 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 230000003647 oxidation Effects 0.000 description 7
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 238000001354 calcination Methods 0.000 description 5
- 239000001569 carbon dioxide Substances 0.000 description 5
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 5
- 229960003750 ethyl chloride Drugs 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 4
- 150000001342 alkaline earth metals Chemical class 0.000 description 4
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000536 complexating effect Effects 0.000 description 4
- 239000008139 complexing agent Substances 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 230000001590 oxidative effect Effects 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- 229910021641 deionized water Inorganic materials 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000001307 helium Substances 0.000 description 3
- 229910052734 helium Inorganic materials 0.000 description 3
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 3
- 230000006872 improvement Effects 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 229940100890 silver compound Drugs 0.000 description 3
- 150000003379 silver compounds Chemical class 0.000 description 3
- XNGYKPINNDWGGF-UHFFFAOYSA-L silver oxalate Chemical compound [Ag+].[Ag+].[O-]C(=O)C([O-])=O XNGYKPINNDWGGF-UHFFFAOYSA-L 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012018 catalyst precursor Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- MVLVMROFTAUDAG-UHFFFAOYSA-N ethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC MVLVMROFTAUDAG-UHFFFAOYSA-N 0.000 description 2
- 150000004820 halides Chemical class 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052743 krypton Inorganic materials 0.000 description 2
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 229910001923 silver oxide Inorganic materials 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- PAAZPARNPHGIKF-UHFFFAOYSA-N 1,2-dibromoethane Chemical compound BrCCBr PAAZPARNPHGIKF-UHFFFAOYSA-N 0.000 description 1
- ZXSQEZNORDWBGZ-UHFFFAOYSA-N 1,3-dihydropyrrolo[2,3-b]pyridin-2-one Chemical compound C1=CN=C2NC(=O)CC2=C1 ZXSQEZNORDWBGZ-UHFFFAOYSA-N 0.000 description 1
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- QSHYGLAZPRJAEZ-UHFFFAOYSA-N 4-(chloromethyl)-2-(2-methylphenyl)-1,3-thiazole Chemical compound CC1=CC=CC=C1C1=NC(CCl)=CS1 QSHYGLAZPRJAEZ-UHFFFAOYSA-N 0.000 description 1
- 238000004438 BET method Methods 0.000 description 1
- AXVCDCGTJGNMKM-UHFFFAOYSA-L C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] Chemical compound C(C=1C(C(=O)[O-])=CC=CC1)(=O)[O-].[Ag+2] AXVCDCGTJGNMKM-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
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- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
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- 125000005263 alkylenediamine group Chemical group 0.000 description 1
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- 239000002019 doping agent Substances 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
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- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
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- 229910052736 halogen Inorganic materials 0.000 description 1
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- 150000005826 halohydrocarbons Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
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- 229910052809 inorganic oxide Inorganic materials 0.000 description 1
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- 229910021645 metal ion Inorganic materials 0.000 description 1
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- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- VLZLOWPYUQHHCG-UHFFFAOYSA-N nitromethylbenzene Chemical compound [O-][N+](=O)CC1=CC=CC=C1 VLZLOWPYUQHHCG-UHFFFAOYSA-N 0.000 description 1
- 239000012457 nonaqueous media Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-M octadecanoate Chemical class CCCCCCCCCCCCCCCCCC([O-])=O QIQXTHQIDYTFRH-UHFFFAOYSA-M 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical class CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N octadecanoic acid methyl ester Natural products CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003018 phosphorus compounds Chemical class 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 150000003282 rhenium compounds Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- LKZMBDSASOBTPN-UHFFFAOYSA-L silver carbonate Substances [Ag].[O-]C([O-])=O LKZMBDSASOBTPN-UHFFFAOYSA-L 0.000 description 1
- 229910001958 silver carbonate Inorganic materials 0.000 description 1
- 229940071575 silver citrate Drugs 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- LMEWRZSPCQHBOB-UHFFFAOYSA-M silver;2-hydroxypropanoate Chemical compound [Ag+].CC(O)C([O-])=O LMEWRZSPCQHBOB-UHFFFAOYSA-M 0.000 description 1
- JKOCEVIXVMBKJA-UHFFFAOYSA-M silver;butanoate Chemical compound [Ag+].CCCC([O-])=O JKOCEVIXVMBKJA-UHFFFAOYSA-M 0.000 description 1
- CYLMOXYXYHNGHZ-UHFFFAOYSA-M silver;propanoate Chemical compound [Ag+].CCC([O-])=O CYLMOXYXYHNGHZ-UHFFFAOYSA-M 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- ZUHZGEOKBKGPSW-UHFFFAOYSA-N tetraglyme Chemical compound COCCOCCOCCOCCOC ZUHZGEOKBKGPSW-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- QUTYHQJYVDNJJA-UHFFFAOYSA-K trisilver;2-hydroxypropane-1,2,3-tricarboxylate Chemical compound [Ag+].[Ag+].[Ag+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QUTYHQJYVDNJJA-UHFFFAOYSA-K 0.000 description 1
- 235000020234 walnut Nutrition 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/69—Pore distribution bimodal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/66—Silver or gold
- B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/688—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with manganese, technetium or rhenium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
Definitions
- the present invention pertains to a process for the epoxidation of an olefin to an olefin oxide by contacting a feed gas comprising an olefin and oxygen with a catalyst comprising a silver compound and a rhenium compound deposited on a carrier with bimodal pore size distribution, wherein the concentration of the olefin oxide in the reactor outlet is greater than about 2.2 % by volume. More particularly, the invention pertains to an improved catalyst useful for the epoxidation of ethylene to ethylene oxide at high catalyst work rates.
- olefin epoxidation is carried out by continuously contacting a feed gas comprising oxygen and an olefin with a catalyst under defined operating conditions.
- a feed gas comprising oxygen and an olefin
- the resulting product mixture of olefin oxide and typically un-reacted oxygen and olefin as well as the total combustion products undergoes a separation procedure wherein the un-reacted feed gas components are separated from the products and undesired by-products.
- the catalyst work rate has to be increased which is usually achieved by either raising the flow rate, i.e., Gas Hourly Space Velocity, at fixed olefin oxide concentration at the reactor outlet and/or changing the concentration of the olefin oxide in the reactor outlet by adjusting the olefin and oxygen conversion.
- These catalysts typically comprise a porous refractory support such as alpha alumina, which has on its surface a catalytic amount of silver and at least one promoter that helps to increase selectivity in the epoxidation process.
- a porous refractory support such as alpha alumina
- the use of alkali metals and transition metals as promoters for silver catalysts is well known for the production of ethylene oxide by the partial oxidation of ethylene in the vapor phase.
- the catalyst may comprise further elements like alkali metals, as are described in U.S. Patent Nos. 3,962,136 and 4,010,115.
- the ' 136 and the ' 115 patents disclose Ag/alkali metal catalysts without rhenium, Re.
- catalysts are disclosed, for example, in U.S. Patent Nos. 4,010,155; 4,012,425; 4,123,385; 4,066,575; 4,039,561 and 4,350,616.
- Such highly selective catalysts contain, in addition to silver, selectivity-enhancing promoters such as rhenium, molybdenum, tungsten and/or nitrate- or nitrite-forming compounds, as are discussed in U.S. Patent Nos. 4,761,394 and 4,766,105.
- U.S. Patent Application Publication No. 20060009647 Al discloses a process for the epoxidation of an olefin with a catalyst comprising a silver component deposited on a fluoride-mineralized carrier, wherein the partial pressure of olefin oxide in the product mix is greater than 60 kPa.
- this printed publication discloses a similar process utilizing a catalyst comprising a silver component and one or more high-selectivity dopants, wherein the partial pressure of olefin oxide in the product mix is greater than 20 kPa.
- the disclosure of the '647 publication does not teach about the influence of the pore size distribution on the catalyst performance at high productivities.
- the physical characteristics of the finished catalyst as well the support have been an integral part of catalyst development.
- the silver-based catalyst support shows a characteristic pore volume and pore size distribution.
- the surface area and the water absorption are well-known characteristics for such catalyst supports. It has now been found that the physical characteristics of the finished catalyst and the impact of the characteristics on the catalyst performance are more complicated than heretofore believed, especially if the catalyst is promoted with rhenium.
- the pattern of the pore size distribution especially the number and the specific characteristics of different modes, has now been found to have a significant positive impact on the catalyst selectivity. In particular, this effect is especially distinguished when the catalyst is operated at very high work rates, i.e., high levels of olefin oxide production.
- An increased productivity (expressed herein by the concentration of ethylene oxide in the reactor outlet gas) catalyst containing silver and rhenium supported by a carrier with a bimodal pore size distribution is provided that shows improved performance.
- the catalyst according to the invention shows a minor loss in selectivity at higher productivities whereas conventional catalysts with monomodal pore size distribution show a significant loss in selectivity at higher productivities.
- the invention provides a process for the epoxidation of an olefin to an olefin oxide which comprises contacting a feed including at least oxygen and an olefin in a reactor with a catalyst that includes a support having a bimodal pore size distribution, a catalytically effective amount of silver or a silver-containing compound, a promoting amount of rhenium or a rhenium-containing compound, and a promoting amount of one or more alkali metals or alkali-metal-containing compounds, said reactor including at least a reactor outlet and said olefin oxide produced by said contacting has a concentration in the reactor outlet that is greater than about 2.2 % by volume.
- the support having the bimodal pore size distribution that is employed in the present invention includes a pore size distribution with a first mode of pores which has a mean diameter ranging from about 0.01 ⁇ m to about 5 ⁇ m, and a second mode of pores which has a mean diameter ranging from about 5 ⁇ m to about 30 ⁇ m.
- the olefin oxide concentration in the reactor outlet is greater than about 2.4 % by volume. In yet other embodiments of the present invention, the ethylene oxide concentration in the reactor outlet is greater than about 2.6 % by volume.
- the olefin oxide concentration in the reactor outlet is obtained by adjusting the olefin and oxygen conversion. That is, the olefin oxide concentration in the reactor is obtained by increasing the reaction temperature during the epoxidation reaction. An increase of the reaction temperature has always a negative effect on the catalyst selectivity. This decrease in catalyst selectivity is economically undesired and reduces the benefit of the higher productivity.
- the selectivity decrease can be significant, i.e., more points of selectivity for less than one point increase of the olefin oxide concentration in the reactor outlet. It was found, that catalysts according to the invention show only a minor selectivity decrease at higher productivities, i.e., higher olefin and oxygen conversion, and, therefore, have a significant economical benefit compared to state of the art catalysts.
- the invention also provides a process for the oxidation of ethylene to ethylene oxide which comprises the vapor phase oxidation of ethylene with molecular oxygen in a fixed bed, tubular reactor, in the presence of the aforementioned catalyst.
- the ethylene oxide concentration in the reactor outlet is greater than about 2.2 % by volume.
- the sole drawing of the present invention shows a comparison of catalyst performances for the inventive supported Ag-based catalyst and a prior art Ag-based catalyst in applications in which the ethylene oxide concentration at the reactor outlet was equal or greater than about 2.2.
- the present invention provides a process for the epoxidation of an olefin, preferably ethylene, to an olefin oxide, preferably ethylene oxide, which comprises contacting a feed including at least oxygen and an olefin in a reactor with a catalyst that includes a support having a bimodal pore size distribution, a catalytically effective amount of silver or a silver-containing compound, a promoting amount of rhenium or a rhenium- containing compound, and a promoting amount of one or more alkali metals or alkali-metal- containing compounds, said reactor including at least a reactor outlet and said olefin oxide produced by said contacting has a concentration in the reactor outlet that is greater than about 2.2, preferably greater than about 2.4, more preferably, greater than about 2.6, % by volume.
- the olefin oxide concentration in the reactor outlet is obtained by adjusting the olefin and oxygen conversion. That is, the olefin oxide concentration in the reactor is obtained by increasing the reaction temperature during the epoxidation reaction. An increase of the reaction temperature has always a negative effect on the catalyst selectivity. This decrease in catalyst selectivity is economically undesired and reduces the benefit of the higher productivity.
- the selectivity decrease can be significant, i.e., more points of selectivity for less than one point increase of the olefin oxide concentration in the reactor outlet. It was found, that catalysts according to the invention show only a minor selectivity decrease at higher productivities, i.e., higher olefin and oxygen conversion, and, therefore, have a significant economical benefit compared to state of the art catalysts.
- the support employed in this invention may be selected from a large number of solid, refractory supports that may be porous and may provide the preferred pore structure.
- Alumina is well known to be useful as a catalyst support for the epoxidation of an olefin and is the preferred support.
- the alumina support may also contain various impurities and additives that may or may not influence the catalytic epoxidation reaction.
- high-purity aluminum oxide preferably alpha- alumina
- the temporary binders known as burnout materials, are thermally decomposable organic compounds of moderate to high molecular weight which, on decomposition, alter the pore structure of the support.
- the permanent binders are typically inorganic clay-type materials having fusion temperatures below that of the alumina and impart mechanical strength to the finished support. After thorough dry-mixing, sufficient water and/or other suitable liquid is added to help form the mass into a paste-like substance. Catalyst support particles are formed from the paste by conventional means such as extrusion. The particles are then dried and are subsequently calcined at an elevated temperature.
- the support may comprise materials such as alpha-alumina, charcoal, pumice, magnesia, zirconia, titania, kieselguhr, fuller's earth, silicon carbide, silica, silicon carbide, clays, artificial zeolites, natural zeolites, silicon dioxide and/or titanium dioxide, ceramics and combination thereof.
- the preferred support is comprised of alpha-alumina having a very high purity; i.e., at least 95 wt. % pure, or more preferably, at least 98 wt. % alpha-alumina.
- the remaining components may include inorganic oxides other than alpha-alumina, such as silica, alkali metal oxides (e.g., sodium oxide) and trace amounts of other metal-containing or non-metal-containing additives or impurities.
- the solid support employed in the present invention has a bimodal pore size distribution. More particular, the solid support employed in the present invention has a surface including a first mode of pores which have a mean diameter ranging from about 0.01 ⁇ m to about 5 ⁇ m. Preferably, the first mode of pores has a mean diameter ranging from about 0.1 ⁇ m to about 4 ⁇ m.
- the surface of solid support employed in the present invention also has a second mode of pores which is different from the first mode of pores.
- the second mode of pores has a mean diameter ranging from about 5 ⁇ m to about 30 ⁇ m.
- the second mode of pores has a mean diameter ranging from about 5 ⁇ m to about 20.
- the first mode of pores comprises from about at most about 50 % of the total pore volume and the second mode provides at least about 50 % of the total pore volume.
- the first mode of pores comprises at most about 45 % of the total pore volume and the second mode provides at least about 55 % of the total pore volume. It is believed, without limiting the scope of the invention, that a catalyst with the described bimodal pore size distribution provides advantageous pore structure with reaction chambers separated by diffusion channels.
- the final support typically, but not necessarily always, has a water absorption value ranging from about 0.2 cc/g to about 0.8 cc/g, preferably from about 0.25 cc/g to about 0.6 cc/g.
- the BET surface area of the finished support is preferred to be in the range from about 0.3 to about 4.0 m 2 /g, more preferably from about 0.3 to about 1.5 m 2 /g, and most preferably from about 0.3 m 2 /g to about 1 m 2 /g.
- Suitable porosity volumes measured by mercury intrusion techniques are generally in the range from about 0.2 ml/g to about 0.8 ml/g, and preferably from about 0.25 ml/g to about 0.60 ml/g.
- the support used is usually shaped into particles, chunks, pieces, pellets, rings, spheres, wagon wheels, cross-partitioned hollow cylinders, and the like, of a size suitable for employment in a fixed-bed epoxidation reactor.
- the type of reactor is not limited as long as it is capable of producing an olefin oxide by the catalytic oxidation of an olefin.
- the support particles may have equivalent diameters in the range from about 3 mm to about 12 mm, and preferably in the range from about 5 mm to about 10 mm, which are usually compatible with the internal diameter of the tubular reactors in which the catalyst is placed. Equivalent diameter is the diameter of a sphere having the same external surface (i.e., neglecting surface within the pores of the particle) to volume ratio as the support particles being employed.
- a suitable catalyst support of the present invention can be prepared by mixing the refractory material, such as alumina, water or other suitable liquid, a burnout material or suitable porosity-controlling agent, and a binder.
- Burnout materials include cellulose, substituted celluloses, e.g., methylcellulose, ethylcellulose, and carboxyethylcellulose, stearates, such as organic stearate esters, e.g., methyl or ethyl stearate, waxes, granulated polyolefms, particularly polyethylene and polypropylene, walnut shell flour, and the like which are decomposable at the firing temperatures used in preparation of the support.
- the burnout material is used to modify the porosity of the support and it is essentially totally removed during the firing to produce the finished support.
- Supports of the present invention are preferably made with the inclusion of a bonding material such as silica with an alkali metal compound in sufficient amount to substantially prevent the formation of crystalline silica compounds.
- binders include inorganic clay-type materials.
- a particularly convenient binder material is a mixture of boehmite, an ammonia stabilized silica sol, and a soluble sodium salt.
- a paste is formed by mixing the dry ingredients of the support with water or another suitable liquid, and the paste is usually extruded or molded into the desired shape, and then fired or calcined at a temperature from about 1200 0 C to about 1600 0 C to form the support.
- extrusion aids When the particles are formed by extrusion, it may be desirable to also include extrusion aids. The amounts of extrusion aids required would depend on a number of factors that relate to the equipment used. However these matters are well within the general knowledge of a person skilled in the art of extruding ceramic materials.
- the support is preferably washed to remove soluble residues. Washing is most commonly done with water, but washing with other solvents or aqueous/non-aqueous solutions can also be beneficial.
- Suitable supports having a bimodal pore size distribution are available from Saint- Gobain Norpro Co., Sud Chemie AG, Noritake Co., CeramTec AG, and Industrie Bitossi S.p.A.
- a support having the above characteristics is then provided with a catalytically effective amount of silver on its surface.
- the catalyst is prepared by impregnating the support with a silver compound, complex or salt dissolved in a suitable solvent sufficient to cause deposition of a silver-precursor compound onto the support.
- a suitable solvent sufficient to cause deposition of a silver-precursor compound onto the support.
- an aqueous silver solution is used. After impregnation, the excess solution is removed from the impregnated support, and the impregnated support is heated to evaporate the solvent and to deposit the silver or silver compound on the support as is known in the art.
- Preferred catalysts prepared in accordance with this invention contain up to about 45% by weight of silver, expressed as metal, based on the total weight of the catalyst including the support.
- the silver is deposited upon the surface and throughout the pores of a porous refractory support.
- Silver contents, expressed as metal from about 1% to about 40% based on the total weight of the catalyst are preferred, while silver contents from about 8% to about 35% are more preferred.
- the amount of silver deposited on the support or present on the support is that amount which is a catalytically effective amount of silver, i.e., an amount which economically catalyzes the reaction of ethylene and oxygen to produce ethylene oxide.
- the term "catalytically effective amount of silver” refers to an amount of silver that provides a measurable conversion of ethylene and oxygen to ethylene oxide.
- Useful silver containing compounds which are silver precursors non-exclusively include silver oxalate, silver nitrate, silver oxide, silver carbonate, a silver carboxylate, silver citrate, silver phthalate, silver lactate, silver propionate, silver butyrate and higher fatty acid salts and combinations thereof.
- a promoting amount of a rhenium component which may be a rhenium-containing compound or a rhenium-containing complex.
- the rhenium promoter may be present in an amount from about 0.001 wt. % to about 1 wt. %, preferably from about 0.005 wt. % to about 0.5 wt. %, and more preferably from about 0.01 wt. % to about 0.1 wt. % based on the weight of the total catalyst including the support, expressed as the rhenium metal.
- promoting amounts of an alkali metal or mixtures of two or more alkali metals are also deposited on the support either prior to, coincidentally with, or subsequent to the deposition of the silver and rhenium.
- promoting amounts of an alkali metal or mixtures of two or more alkali metals are also deposited on the support either prior to, coincidentally with, or subsequent to the deposition of the silver and rhenium, as well as optional promoting amounts of a Group HA alkaline earth metal component or mixtures of two or more Group IIA alkaline earth metal components, and/or a transition metal component or mixtures of two or more transition metal components, all of which may be in the form of metal ions, metal compounds, metal complexes and/or metal salts dissolved in an appropriate solvent.
- the support may be impregnated at the same time or in separate steps with the various catalyst promoters.
- the particular combination of support, silver, alkali metal promoter(s), rhenium component, and optional additional promoter(s) of the instant invention will provide an improvement in one or more catalytic properties over the same combination of silver and support and none, or only one of the promoters.
- the term "promoting amount" of a certain component of the catalyst refers to an amount of that component that works effectively to improve the catalytic performance of the catalyst when compared to a catalyst that does not contain that component.
- concentrations employed will depend on, among other factors, the desired silver content, the nature of the support, the viscosity of the liquid, and solubility of the particular compound used to deliver the promoter into the impregnating solution.
- catalytic properties include, inter alia, operability (resistance to runaway), selectivity, activity, conversion, stability and yield.
- one or more of the individual catalytic properties may be enhanced by the "promoting amount" while other catalytic properties may or may not be enhanced or may even be diminished. It is further understood that different catalytic properties may be enhanced at different operating conditions. For example, a catalyst having enhanced selectivity at one set of operating conditions may be operated at a different set of conditions wherein the improvement shows up in the activity rather than the selectivity. In the epoxidation process, it may be desirable to intentionally change the operating conditions to take advantage of certain catalytic properties even at the expense of other catalytic properties. The preferred operating conditions will depend upon, among other factors, feedstock costs, energy costs, by-product removal costs and the like.
- Suitable alkali metal promoters may be selected from lithium, sodium, potassium, rubidium, cesium or combinations thereof, with cesium being preferred, and combinations of cesium with other alkali metals being especially preferred.
- the amount of alkali metal deposited or present on the support is to be a promoting amount. Preferably, the amount ranges from about 10 ppm to about 3000 ppm, more preferably from about 15 ppm to about 2000 ppm, and even more preferably from about 20 ppm to about 1500 ppm, and as especially preferred from about 50 ppm to about 1000 ppm by weight of the total catalyst, measured as the metal.
- Suitable alkaline earth metal promoters comprise elements from Group HA of the Periodic Table of the Elements, which may be beryllium, magnesium, calcium, strontium, and barium or combinations thereof.
- Suitable transition metal promoters may comprise elements from Groups IVA, VA, VIA, VIIA and VIIIA of the Periodic Table of the Elements, and combinations thereof. Most preferably the transition metal comprises an element selected from Groups IVA, VA or VIA of the Periodic Table of the Elements.
- Preferred transition metals that can be present include molybdenum, tungsten, chromium, titanium, hafnium, zirconium, vanadium, tantalum, niobium, or combinations thereof.
- the amount of alkaline earth metal promoters) and/or transition metal promoter(s) deposited on the support is a promoting amount.
- the transition metal promoter may typically be present in an amount from about 0.1 micromoles per gram to about 10 micromoles per gram, preferably from about 0.2 micromoles per gram to about 5 micromoles per gram, and more preferably from about 0.5 micromoles per gram to about 4 micromoles per gram of total catalyst, expressed as the metal.
- the catalyst may further comprise a promoting amount of one or more sulfur compounds, one or more phosphorus compounds, one or more boron compounds, one or more halogen-containing compounds, or combinations thereof.
- the silver solution used to impregnate the support may also comprise an optional solvent or a complexing/solubilizing agent such as are known in the art.
- solvents or complexing/solubilizing agents may be employed to solubilize silver to the desired concentration in the impregnating medium.
- Useful complexing/solubilizing agents include amines, ammonia, oxalic acid, lactic acid and combinations thereof.
- Amines include an alkylene diamine having from 1 to 5 carbon atoms.
- the solution comprises an aqueous solution of silver oxalate and ethylene diamine.
- the complexing/solubilizing agent may be present in the impregnating solution in an amount from about 0.1 to about 5.0 moles per mole of silver, preferably from about 0.2 to about 4.0 moles, and more preferably from about 0.3 to about 3.0 moles for each mole of silver.
- a solvent when used, it may be an organic solvent or water, and may be polar or substantially or totally non-polar. In general, the solvent should have sufficient solvating power to solubilize the solution components. At the same time, it is preferred that the solvent be chosen to avoid having an undue influence on or interaction with the solvated promoters.
- organic solvents include, but are not limited to, alcohols, in particular alkanols; glycols, in particular alkyl glycols; ketones; aldehydes; amines; tetrahydrofuran; nitrobenzene; nitrotoluene; glymes, in particular glyme, diglyme and tetraglyme; and the like.
- Organic-based solvents which have 1 to about 8 carbon atoms per molecule are preferred. Mixtures of several organic solvents or mixtures of organic solvent(s) with water may be used, provided that such mixed solvents function as desired herein.
- the concentration of silver in the impregnating solution is typically in the range from about 0.1% by weight up to the maximum solubility afforded by the particular solvent/solubilizing agent combination employed. It is generally very suitable to employ solutions containing from 0.5% to about 45% by weight of silver, with concentrations from 5 to 35% by weight of silver being preferred.
- Impregnation of the selected support is achieved using any of the conventional methods; for example, excess solution impregnation, incipient wetness impregnation, spray coating, etc.
- the support material is placed in contact with the silver-containing solution until a sufficient amount of the solution is absorbed by the support.
- the quantity of the silver-containing solution used to impregnate the porous support is no more than is necessary to fill the pores of the support.
- a single impregnation or a series of impregnations, with or without intermediate drying, may be used, depending, in part, on the concentration of the silver component in the solution. Impregnation procedures are described, for example, in U.S. Patent Nos.
- the impregnated support is calcined for a time sufficient to convert the silver containing compound to an active silver species and to remove the volatile components from the impregnated support to result in a catalyst precursor.
- the silver-containing compound i.e., a silver precursor, a rhenium component, an alkali metal component, and the optional other promoters
- the calcination may be accomplished by heating the impregnated support, preferably at a gradual rate, to a temperature in the range from about 200 0 C to about 600 0 C, preferably from about 200 0 C to about 500 0 C, and more preferably from about 200 0 C to about 450 0 C, at a pressure in the range from about 0.5 to about 35 bar.
- a temperature in the range from about 200 0 C to about 600 0 C, preferably from about 200 0 C to about 500 0 C, and more preferably from about 200 0 C to about 450 0 C, at a pressure in the range from about 0.5 to about 35 bar.
- the higher the temperature the shorter the required heating period.
- a wide range of heating periods have been suggested in the art; e.g., U.S. Patent No. 3,563,914 discloses heating for less than 300 seconds, and U.S. Patent No.
- 3,702,259 discloses heating from 2 to 8 hours at a temperature of from 100° C to 375 0 C, usually for duration of from about 0.5 to about 8 hours. However, it is only important that the heating time be correlated with the temperature such that substantially all of the contained silver is converted to the active silver species. Continuous or step-wise heating may be used for this purpose.
- the impregnated support may be exposed to a gas atmosphere comprising an inert gas or a mixture of an inert gas with from about 10 ppm to 21% by volume of an oxygen-containing oxidizing component.
- an inert gas is defined as a gas that does not substantially react with the catalyst or catalyst precursor under the conditions chosen for the calcination.
- Non-limiting examples include nitrogen, argon, krypton, helium, and combinations thereof, with the preferred inert gas being nitrogen.
- Non-limiting examples of the oxygen-containing oxidizing component include molecular oxygen (O 2 ), CO 2 , NO, NO 2 , N 2 O, N 2 O 3 , N 2 O 4 , or N 2 O 5 , or a substance capable of forming NO, NO 2 , N 2 O, N 2 O 3 , N 2 O 4 , or N 2 Os under the calcination conditions, or combinations thereof, and optionally comprising SO 3 , SO 2 or combinations thereof.
- molecular oxygen is a useful embodiment
- a combination of O 2 with NO or NO 2 is another useful embodiment.
- the atmosphere comprises from about 10 ppm to about 1% by volume of an oxygen-conlaining oxidizing component.
- the atmosphere comprises from about 50 ppm to about 500 ppm of an oxygen-containing oxidizing component.
- the impregnated support which has been calcined as disclosed above, may optionally thereafter be contacted with an atmosphere comprising a combination of oxygen and steam, which atmosphere is substantially absent of an olefin, and preferably, completely absent of an olefin.
- the atmosphere usually comprises from about 2% to about 15% steam by volume, preferably from about 2% to about 10% steam by volume, and more preferably from about 2% to about 8% steam by volume.
- the atmosphere usually comprises from about 0.5% to about 30% oxygen by volume, preferably from about 1% to about 21% oxygen by volume, and more preferably from about 5% to about 21% oxygen by volume.
- the balance of the gas atmosphere may be comprised of an inert gas.
- Non-limiting examples of the inert gas include nitrogen, argon, krypton, helium, and combinations thereof, with the preferred inert gas being nitrogen.
- the contacting is usually conducted at a temperature from about 200 0 C or higher. In one embodiment the contacting is conducted at a temperature from about 200 0 C to about 350 0 C. In another embodiment the contacting is conducted at a temperature from about 230 0 C to about 300 0 C. In another embodiment the contacting is conducted at a temperature from about 250 0 C to about 280 0 C. In another embodiment the contacting is conducted at a temperature from about 260 0 C to about 280 0 C. Usually the contacting is conducted for from about 0.15 hour or more. In one embodiment, the contacting is conducted for from about 0.5 hour to about 200 hours. In another embodiment, the contacting is conducted for from about 3 hours to about 24 hours. In another embodiment, the contacting is conducted for from about 5 hours to about 15 hours.
- the epoxidation process may be carried out by continuously contacting an oxygen- containing gas with an olefin, which is preferably ethylene, in the presence of the catalyst produced by the invention.
- Oxygen may be supplied to the reaction in substantially pure molecular form or in a mixture such as air.
- Molecular oxygen employed as a reactant may be obtained from conventional sources.
- reactant feed mixtures may contain from about 0.5% to about 45% ethylene and from about 3% to about 15% oxygen, with the balance comprising comparatively inert materials including such substances as carbon dioxide, water, inert gases, other hydrocarbons, and one or more reaction modifiers such as organic halides.
- inert gases include nitrogen, argon, helium and mixtures thereof.
- Non-limiting examples of the other hydrocarbons include methane, ethane, propane and mixtures thereof. Carbon dioxide and water are byproducts of the epoxidation process as well as common contaminants in the feed gases. Both have adverse effects on the catalyst, so the concentrations of these components are usually kept at a minimum.
- Non- limiting examples of reaction moderators include organic halides such as Cj to Cs halohydrocarbons.
- the reaction moderator is methyl chloride, ethyl chloride, ethylene dichloride, ethylene dibromide, vinyl chloride or mixtures thereof. Most preferred reaction moderators are ethyl chloride and ethylene dichloride. Usually such reaction moderators are employed in an amount from about 0.3 to about 20 ppmv, and preferably from about 1 to about 15 ppmv of the total volume of the feed gas.
- a usual method for the ethylene epoxidation process comprises the vapor-phase oxidation of ethylene with molecular oxygen, in the presence of the inventive catalyst, in a fixed-bed tubular reactor.
- Conventional, commercial fixed-bed ethylene-oxide reactors are typically in the form of a plurality of parallel elongated tubes (in a suitable shell) approximately 0.7 to 2.7 inches O.D. and 0.5 to 2.5 inches I.D. and 15-53 feet long filled with catalyst.
- Such reactors include a reactor outlet which allows the olefin oxide, un-used reactant, and byproducts to exit the reactor chamber.
- Typical operating conditions for the ethylene epoxidation process involve temperatures in the range from about 180 0 C to about 330 0 C, and preferably, from about 200 0 C to about 325 0 C, and more preferably from about 225 0 C to about 280 0 C.
- the operating pressure may vary from about atmospheric pressure to about 30 atmospheres, depending on the mass velocity and productivity desired. Higher pressures may be employed within the scope of the invention.
- Residence times in commercial-scale reactors are generally on the order of about 0.1 to about 5 seconds. The present catalysts are effective for this process when operated within these ranges of conditions.
- the resulting ethylene oxide which exits the reactor through the reactor outlet, is separated and recovered from the reaction products using conventional methods.
- the ethylene epoxidation process may include a gas recycle wherein substantially all of the reactor effluent is readmitted to a reactor inlet after substantially or partially removing the ethylene oxide product and the byproducts including carbon dioxide.
- carbon dioxide concentrations in the gas inlet to the reactor may be, for example, from about 0.3 to about 5 volume percent.
- the inventive catalysts have been shown to be particularly selective for oxidation of ethylene with molecular oxygen to ethylene oxide especially at high ethylene and oxygen conversion rates.
- the conditions for carrying out such an oxidation reaction in the presence of the catalysts of the present invention broadly comprise those described in the prior art. This applies to suitable temperatures, pressures, residence times, diluent materials, moderating agents, and recycle operations, or applying successive conversions in different reactors to increase the yields of ethylene oxide.
- the use of the present catalysts in ethylene oxidation reactions is in no way limited to the use of specific conditions among those which are known to be effective.
- GHSV gas hourly space velocity
- reactor inlet pressure 150-400 psig
- coolant temperature 180-315 0 C
- oxygen conversion level 10-60%
- EO production rate work rate
- the feed composition at the reactor inlet may typically comprises 1- 40% ethylene, 3-12% O 2 , 0.3-40% CO 2 , 0-3% ethane, 0.3-20 ppmv total concentration of organic chloride moderator(s), and the balance of the feed being comprised of argon, methane, nitrogen or mixtures thereof.
- Aluminum oxides [0054] The following aluminas designed as A and B in Table 1 were used for the preparation of the catalysts. The different types of alumina supports are commercially available.
- a 150 g portion of alumina support A was placed in a flask and evacuated to approximately 0.1 torr prior to impregnation.
- aqueous solutions of cesium hydroxide, perrhenic acid, and ammonium sulfate were added in order to prepare a catalyst composition according to examples 3-10 through 7-20 of U.S. Patent No. 4,766,105.
- the promoted silver solution was aspirated into the evacuated flask to cover the carrier while maintaining the pressure at approximately 0.1 torr. The vacuum was released after about 5 minutes to restore ambient pressure, hastening complete penetration of the solution into the pores. Subsequently, the excess impregnation solution was drained from the impregnated carrier.
- Calcination of the wet catalyst was done on a moving belt calciner.
- the wet catalyst is transported on a stainless steel belt through a multi-zone furnace. All zones of the furnace are continuously purged with pre-heated, ultra-high purity nitrogen and the temperature is increased gradually as the catalyst passes from one zone to the next. The heat is radiated from the furnace walls and from the preheated nitrogen.
- the wet catalyst entered the furnace at ambient temperature. The temperature was then increased gradually to a maximum of about 450 0 C as the catalyst passed through the heated zones. In the last (cooling) zone, the temperature of the now activated was immediately lowered to less than 100 0 C before it emerged into ambient atmosphere. The total residence time in the furnace was approximately 45 minutes.
- EXAMPLE 2 CATALYST B (COMPARATIVE EXAMPLE)
- Catalyst B was prepared with alumina support B following the procedure of Catalyst A.
- the catalyst was charged into a fixed-bed stainless steel tube reactor (!4 inch approximate inner diameter), which was embedded in a heated copper block.
- the catalyst charge consisted of 12 g crushed catalyst (1.0 - 1.4 mm particle size) and the inlet gas flow was adjusted to 0.75 Nl/min.
- the feed gas composition by volume was 25% ethylene, 7 % oxygen, 2 % carbon dioxide, 0.5 - 5 ppmv ethyl chloride, and nitrogen ballast. Reaction pressure was maintained at 300 psig.
- the reactor effluent was analyzed by mass spectrometry at roughly 1-hour intervals.
- the feed gas was introduced at 200 0 C and increased by 1 °C/h until the EO concentration in the reactor outlet reached 3.8 % by volume.
- the ethyl chloride concentration in the inlet gas was adjusted until the maximum selectivity was achieved.
- the EO concentration in the outlet was lowered to 3 % by volume and the ethyl chloride concentration re-adjusted until peak selectivity was observed.
- this procedure was repeated at an EO outlet concentration of 2.2 % by volume.
- the specific surface area is determined according to the BET method: See J. Am. Chem. Soc. 60, 3098-16 (1938).
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Abstract
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Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
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JP2010523027A JP2010537993A (en) | 2007-08-27 | 2008-08-14 | Olefin oxide production process |
EP08797845A EP2190576A4 (en) | 2007-08-27 | 2008-08-14 | Process for production of an olefin oxide |
BRPI0815825-8A2A BRPI0815825A2 (en) | 2007-08-27 | 2008-08-14 | PROCESS FOR THE PRODUCTION OF OLEFINE OXIDE |
EP16151306.4A EP3059013B1 (en) | 2007-08-27 | 2008-08-14 | Process for production of an olefin oxide |
CN2008801050354A CN101795763B (en) | 2007-08-27 | 2008-08-14 | Process for production of an olefin oxide |
KR1020107006551A KR101528879B1 (en) | 2007-08-27 | 2008-08-14 | Process for production of an olefin oxide |
CA2697818A CA2697818C (en) | 2007-08-27 | 2008-08-14 | Process for the epoxidation of an olefin using a supported catalyst |
RU2010111801/04A RU2476266C2 (en) | 2007-08-27 | 2008-08-14 | Method of producing olefin oxide |
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US11/845,180 US7507845B1 (en) | 2007-08-27 | 2007-08-27 | Process for production of an olefin oxide |
US11/845,180 | 2007-08-27 |
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WO2009029419A1 true WO2009029419A1 (en) | 2009-03-05 |
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US (1) | US7507845B1 (en) |
EP (2) | EP2190576A4 (en) |
JP (1) | JP2010537993A (en) |
KR (1) | KR101528879B1 (en) |
CN (1) | CN101795763B (en) |
BR (1) | BRPI0815825A2 (en) |
CA (1) | CA2697818C (en) |
RU (1) | RU2476266C2 (en) |
TW (1) | TWI409258B (en) |
WO (1) | WO2009029419A1 (en) |
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Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3563914A (en) | 1967-03-22 | 1971-02-16 | Shell Oil Co | Silver catalyst |
US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
US3962136A (en) | 1972-01-07 | 1976-06-08 | Shell Oil Company | Catalyst for production of ethylene oxide |
US4010155A (en) | 1973-11-28 | 1977-03-01 | Meiji Seika Kaisha, Ltd. | Antibiotic SF-1623 substance |
US4010115A (en) | 1972-01-07 | 1977-03-01 | Shell Oil Company | Catalyst for the oxidation of ethylene to ethylene oxide |
US4039561A (en) | 1973-09-07 | 1977-08-02 | Nippon Shokubai Kagaku Kogyo | Process for preparing ethylene oxide |
US4066575A (en) | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
US4123385A (en) | 1976-08-14 | 1978-10-31 | Hoechst Aktiengesellschaft | Process for improving the activity of used supported silver catalysts |
US4350616A (en) | 1980-07-03 | 1982-09-21 | The Dow Chemical Company | Method of making catalysts for the production of ethylene oxide |
US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4808738A (en) | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
US4820675A (en) | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
US4833261A (en) | 1986-10-31 | 1989-05-23 | Shell Oil Company | Ethylene oxide process |
US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5011807A (en) | 1988-08-30 | 1991-04-30 | Imperial Chemical Industries Plc | Catalysts for the production of ethylene oxide |
US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
US5935898A (en) * | 1995-09-12 | 1999-08-10 | Basf Aktiengesellschaft | Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production |
US20060009647A1 (en) | 2004-06-18 | 2006-01-12 | Yeates Randall C | Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
US20070111886A1 (en) * | 2003-10-16 | 2007-05-17 | Serafin Juliana G | Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4168247A (en) * | 1976-05-28 | 1979-09-18 | Imperial Chemical Industries Limited | Catalysts for the production of alkylene oxides |
FR2412538A1 (en) * | 1977-12-22 | 1979-07-20 | Ugine Kuhlmann | SILVER BASED CATALYZERS FOR ETHYLENE OXIDE PRODUCTION |
US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
US4350618A (en) * | 1979-11-16 | 1982-09-21 | Electro Materials Corp. Of America | Thick film conductors for use in microelectronic packaging |
DE3528313A1 (en) | 1985-08-07 | 1987-02-12 | Basf Ag | SILVER CATALYST, ITS PRODUCTION AND USE |
IN169589B (en) * | 1986-10-31 | 1991-11-16 | Shell Int Research | |
DE3643248A1 (en) | 1986-12-18 | 1988-06-30 | Basf Ag | SILVER CATALYST, ITS PRODUCTION AND USE |
CN1009437B (en) * | 1988-02-03 | 1990-09-05 | 中国石油化工总公司 | High-efficiency silver catalyst for oxidizing ethylene into epoxy ethane |
CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
DE4106508A1 (en) * | 1991-03-01 | 1992-09-03 | Basf Ag | SILVER CATALYST |
US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
US5864047A (en) | 1997-04-10 | 1999-01-26 | Arco Chemical Technology, L.P. | Propylene oxide process using alkaline earth metal compound-supported silver catalysts containing rhenium and potassium promoters |
US5770746A (en) | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
CN1101272C (en) * | 1997-11-12 | 2003-02-12 | 中国石油化工集团公司北京燕山石油化工公司研究院 | Mfg. for producing alumina carrier and use thereof |
RU2342190C2 (en) * | 2002-02-25 | 2008-12-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Catalyst and method of its application |
US6831037B2 (en) * | 2002-02-25 | 2004-12-14 | Saint-Gobain Norpro Corporation | Catalyst carriers |
BR0312244B1 (en) * | 2002-06-28 | 2013-06-25 | Method for improving catalyst selectivity and an olefin epoxidation process | |
DE10240128A1 (en) | 2002-08-30 | 2004-03-11 | Basf Ag | Silver catalyst for the epoxidation of propylene |
US20040224841A1 (en) * | 2003-05-07 | 2004-11-11 | Marek Matusz | Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof |
WO2006133183A2 (en) * | 2005-06-07 | 2006-12-14 | Shell Internationale Research Maatschappij B.V. | A catalyst, a process for preparing the catalyst, and a process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
US7553795B2 (en) | 2006-03-21 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Activation of high selectivity ethylene oxide catalyst |
JP4267015B2 (en) * | 2006-09-29 | 2009-05-27 | 株式会社日本触媒 | Catalyst for producing ethylene oxide and method for producing ethylene oxide |
US7977274B2 (en) * | 2006-09-29 | 2011-07-12 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Catalyst with bimodal pore size distribution and the use thereof |
US7932408B2 (en) | 2006-09-29 | 2011-04-26 | Scientific Design Company, Inc. | Catalyst with bimodal pore size distribution and the use thereof |
US7507845B1 (en) * | 2007-08-27 | 2009-03-24 | Sd Lizenzverwertungsgesellschaft Mbh & Co Kg | Process for production of an olefin oxide |
US9115104B2 (en) | 2009-01-27 | 2015-08-25 | Scientific Design Company, Inc. | Ethylene oxide catalyst with optimized cesium content |
TWI590867B (en) * | 2011-10-14 | 2017-07-11 | 聖高拜陶器塑膠公司 | A catalyst and catalyst carrier |
US10208005B2 (en) | 2014-12-30 | 2019-02-19 | Dow Technology Investments Llc | Process for manufacturing ethylene oxide using scaled selectivity values |
-
2007
- 2007-08-27 US US11/845,180 patent/US7507845B1/en active Active
-
2008
- 2008-08-14 KR KR1020107006551A patent/KR101528879B1/en active IP Right Grant
- 2008-08-14 BR BRPI0815825-8A2A patent/BRPI0815825A2/en not_active IP Right Cessation
- 2008-08-14 JP JP2010523027A patent/JP2010537993A/en not_active Ceased
- 2008-08-14 WO PCT/US2008/073095 patent/WO2009029419A1/en active Application Filing
- 2008-08-14 EP EP08797845A patent/EP2190576A4/en not_active Withdrawn
- 2008-08-14 CN CN2008801050354A patent/CN101795763B/en active Active
- 2008-08-14 EP EP16151306.4A patent/EP3059013B1/en not_active Revoked
- 2008-08-14 CA CA2697818A patent/CA2697818C/en active Active
- 2008-08-14 RU RU2010111801/04A patent/RU2476266C2/en not_active IP Right Cessation
- 2008-08-27 TW TW097132758A patent/TWI409258B/en active
Patent Citations (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3563914A (en) | 1967-03-22 | 1971-02-16 | Shell Oil Co | Silver catalyst |
US3702259A (en) | 1970-12-02 | 1972-11-07 | Shell Oil Co | Chemical production of metallic silver deposits |
US3962136A (en) | 1972-01-07 | 1976-06-08 | Shell Oil Company | Catalyst for production of ethylene oxide |
US4010115A (en) | 1972-01-07 | 1977-03-01 | Shell Oil Company | Catalyst for the oxidation of ethylene to ethylene oxide |
US4012425A (en) | 1972-01-07 | 1977-03-15 | Shell Oil Company | Ethylene oxide process |
US3962136B1 (en) | 1972-01-07 | 1983-11-15 | ||
US4039561A (en) | 1973-09-07 | 1977-08-02 | Nippon Shokubai Kagaku Kogyo | Process for preparing ethylene oxide |
US4010155A (en) | 1973-11-28 | 1977-03-01 | Meiji Seika Kaisha, Ltd. | Antibiotic SF-1623 substance |
US4066575A (en) | 1976-07-26 | 1978-01-03 | Halcon International, Inc. | Process for the preparation of a supported silver catalyst |
US4123385A (en) | 1976-08-14 | 1978-10-31 | Hoechst Aktiengesellschaft | Process for improving the activity of used supported silver catalysts |
US4350616A (en) | 1980-07-03 | 1982-09-21 | The Dow Chemical Company | Method of making catalysts for the production of ethylene oxide |
US4766105A (en) | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4761394A (en) | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
US4808738A (en) | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
US4820675A (en) | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
US4833261A (en) | 1986-10-31 | 1989-05-23 | Shell Oil Company | Ethylene oxide process |
US5057481A (en) | 1987-02-20 | 1991-10-15 | Union Carbide Chemicals And Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US4908343A (en) | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5011807A (en) | 1988-08-30 | 1991-04-30 | Imperial Chemical Industries Plc | Catalysts for the production of ethylene oxide |
US5099041A (en) | 1988-08-30 | 1992-03-24 | Imperial Chemical Industries Plc | Production of ethylene oxide and catalysts therefor |
US5187140A (en) | 1989-10-18 | 1993-02-16 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts containing high silver content |
US5102848A (en) | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
US5407888A (en) | 1992-05-12 | 1995-04-18 | Basf Aktiengesellschaft | Silver catalyst |
US5935898A (en) * | 1995-09-12 | 1999-08-10 | Basf Aktiengesellschaft | Monomodal and polymodal catalyst supports and catalysts having narrow pore size distributions and their production |
US20070111886A1 (en) * | 2003-10-16 | 2007-05-17 | Serafin Juliana G | Catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production |
US20060009647A1 (en) | 2004-06-18 | 2006-01-12 | Yeates Randall C | Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
Non-Patent Citations (3)
Title |
---|
DRAKE; RITTER, IND. ENG. CHEM. ANAL. ED, vol. 17, 1945, pages 787 |
J. AM. CHEM. SOC., vol. 60, 1938, pages 3098 - 3016 |
See also references of EP2190576A1 |
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Also Published As
Publication number | Publication date |
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US7507845B1 (en) | 2009-03-24 |
KR20100065164A (en) | 2010-06-15 |
KR101528879B1 (en) | 2015-06-16 |
CA2697818A1 (en) | 2009-03-05 |
EP3059013A1 (en) | 2016-08-24 |
US20090062557A1 (en) | 2009-03-05 |
EP2190576A4 (en) | 2011-08-31 |
CN101795763B (en) | 2012-09-05 |
JP2010537993A (en) | 2010-12-09 |
CA2697818C (en) | 2015-10-06 |
EP3059013B1 (en) | 2021-04-21 |
TWI409258B (en) | 2013-09-21 |
TW200916451A (en) | 2009-04-16 |
BRPI0815825A2 (en) | 2015-02-18 |
RU2476266C2 (en) | 2013-02-27 |
CN101795763A (en) | 2010-08-04 |
EP2190576A1 (en) | 2010-06-02 |
RU2010111801A (en) | 2011-10-10 |
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