WO2009027882A3 - Hydrocarbon decomposition catalyst, process for obtaining said catalyst, and a process for obtaining hydrogen and syngas employing said catalyst - Google Patents

Hydrocarbon decomposition catalyst, process for obtaining said catalyst, and a process for obtaining hydrogen and syngas employing said catalyst Download PDF

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Publication number
WO2009027882A3
WO2009027882A3 PCT/IB2008/052789 IB2008052789W WO2009027882A3 WO 2009027882 A3 WO2009027882 A3 WO 2009027882A3 IB 2008052789 W IB2008052789 W IB 2008052789W WO 2009027882 A3 WO2009027882 A3 WO 2009027882A3
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WO
WIPO (PCT)
Prior art keywords
catalyst
obtaining
hydrogen
employing
syngas
Prior art date
Application number
PCT/IB2008/052789
Other languages
French (fr)
Other versions
WO2009027882A2 (en
Inventor
Norma Elvira Amadeo
Miguel Angel Laborde
Pablo Javier Arena
Graciela Teresita Baronetti
Matías JOBBAGY
Fernando Javier MARIÑO
Verónica Alejandra MAS
Roberto Daniel Tejeda
Original Assignee
Consejo Nacional De Investigaciones Cientificas Y Tecnicas (Conicet)
Inis Biotech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Consejo Nacional De Investigaciones Cientificas Y Tecnicas (Conicet), Inis Biotech Llc filed Critical Consejo Nacional De Investigaciones Cientificas Y Tecnicas (Conicet)
Publication of WO2009027882A2 publication Critical patent/WO2009027882A2/en
Publication of WO2009027882A3 publication Critical patent/WO2009027882A3/en

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/007—Mixed salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1217—Alcohols
    • C01B2203/1229—Ethanol
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/14—Pore volume

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

A process for the production of catalysts useful for hydrocarbon decomposition comprising the stages of : a) -f orming a mixed urea solution comprising soluble salts of metal ion selected from the group consisting in: a group I transition divalent metal (Me (II) ) selected between Co, Ni, Cu, and Zn; Al (III), and Mn(II), at pH between 3 and 6, b) -ageing the mixed solution containing urea-Me(II)- magnesium ( II ) -aluminum ( III ) at a temperature between 70 and 100° C; c) - precipitating from the aged solution a double laminar hydroxide (HDL) consisting of said divalent metal (Me (II) ), magnesium, and aluminum, in order to form a catalyst precursor, d) -activating the catalyst precursor obtained in stage c) by reduction in an atmosphere containing hydrogen at atmospheric pressure, and at a temperature between 600 and 750° C. Catalysts obtained by said process, and a hydrogen and syngas production process employing said catalysts are also disclosed.
PCT/IB2008/052789 2007-07-11 2008-07-10 Hydrocarbon decomposition catalyst, process for obtaining said catalyst, and a process for obtaining hydrogen and syngas employing said catalyst WO2009027882A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ARP070103088A AR062824A1 (en) 2007-07-11 2007-07-11 CATALYST FOR THE DECOMPOSITION OF HYDROCARBONS, A PROCESS FOR THE OBTAINING OF SUCH CATALYST AND A PROCESS FOR THE OBTAINING OF HYDROGEN AND SYNTHESIS GAS THAT USES SUCH CATALYST.
ARP070103088 2007-07-11

Publications (2)

Publication Number Publication Date
WO2009027882A2 WO2009027882A2 (en) 2009-03-05
WO2009027882A3 true WO2009027882A3 (en) 2009-09-03

Family

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Family Applications (1)

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PCT/IB2008/052789 WO2009027882A2 (en) 2007-07-11 2008-07-10 Hydrocarbon decomposition catalyst, process for obtaining said catalyst, and a process for obtaining hydrogen and syngas employing said catalyst

Country Status (2)

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AR (1) AR062824A1 (en)
WO (1) WO2009027882A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2251080B1 (en) 2008-03-06 2022-05-18 Toda Kogyo Corp. A porous catalytic body that decomposes hydrocarbons and a manufacturing method thereof, a method for manufacturing mixed reformed gas that comprises hydrogen from hydrocarbon, and a fuel cell system
RU2678007C1 (en) * 2017-12-05 2019-01-22 Федеральное государственное бюджетное учреждение науки Федеральный исследовательский центр "Кольский научный центр Российской академии наук" (ФИЦ КНЦ РАН) Method of obtaining layered hydroxide of magnesium and aluminum
CN116393138B (en) * 2023-04-20 2024-04-05 河南师范大学 Preparation method of copper-nickel-tin nano metal glass catalyst for nitrate reduction ammonia conversion

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4124629A (en) * 1975-10-14 1978-11-07 Union Oil Company Of California Thermally stable coprecipitated catalysts useful for methanation and other reactions
US4354960A (en) * 1979-03-01 1982-10-19 Hans Hammer Process for the production of boron-containing nickel-aluminum oxide catalysts

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4124629A (en) * 1975-10-14 1978-11-07 Union Oil Company Of California Thermally stable coprecipitated catalysts useful for methanation and other reactions
US4354960A (en) * 1979-03-01 1982-10-19 Hans Hammer Process for the production of boron-containing nickel-aluminum oxide catalysts

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CARREÑO ET AL.: "SYNTHESIS OF METAL OXIDE MATRIX WITH EMBEDDED NICKEL NANOPARTICLES BY A BOTTOM-UP CHEMICAL PROCESS", JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, vol. 3, 2003, pages 516 - 520, XP002535568 *

Also Published As

Publication number Publication date
WO2009027882A2 (en) 2009-03-05
AR062824A1 (en) 2008-12-10

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