WO2009027633A1 - Combined fuel burner and fuel cell - Google Patents
Combined fuel burner and fuel cell Download PDFInfo
- Publication number
- WO2009027633A1 WO2009027633A1 PCT/GB2008/002829 GB2008002829W WO2009027633A1 WO 2009027633 A1 WO2009027633 A1 WO 2009027633A1 GB 2008002829 W GB2008002829 W GB 2008002829W WO 2009027633 A1 WO2009027633 A1 WO 2009027633A1
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- WO
- WIPO (PCT)
- Prior art keywords
- fuel
- burner
- cell assembly
- fuel cell
- heat
- Prior art date
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04007—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids related to heat exchange
- H01M8/04014—Heat exchange using gaseous fluids; Heat exchange by combustion of reactants
- H01M8/04022—Heating by combustion
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/243—Grouping of unit cells of tubular or cylindrical configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M2008/1293—Fuel cells with solid oxide electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/40—Combination of fuel cells with other energy production systems
- H01M2250/405—Cogeneration of heat or hot water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02B90/10—Applications of fuel cells in buildings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a fuel burner, in particular a fuel burner that can provide both heat and electrical power.
- Fuel burners for generation of heat by burning fuels such as methane, propane, butane or gas mixtures are well known. However, such devices cannot usually provide electrical power unless they are used to drive a heat engine or similar complicated energy conversion device.
- thermoelectric converters have been used on oil and gas pipelines to achieve combined heat and electrical power generation, these have a high cost and low efficiency and therefore are not. generally applicable. There is therefore a need for an easy and economically achievable solution to the desire for combined heat and electrical power generation.
- the flame temperature of the burner can be very high, up to 2000 0 C, which melts or corrodes the fuel cell materials.
- Another problem is that the flame system has to be modified to incorporate the fuel cells, such that the device becomes too expensive or difficult to ignite.
- An additional problem is the issue of stacking of cells in the burner to raise the voltage to suitable levels.
- the present invention provides, in a first aspect, a fuel burner that can provide both heat and electrical power, the burner comprising: a main burner body including one or more burner ports; a fuel inlet for providing the burner ports with fuel; a heat transmitter, wherein a portion of the heat transmitter is located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited; a fuel cell assembly that causes the generation of an electrical output when it is heated and supplied with fuel and oxidiser; a fuel inlet for providing the fuel cell assembly with fuel; and an oxidiser inlet for providing the fuel cell assembly with oxidiser; wherein a portion of the heat transmitter is located in the vicinity of the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter.
- the fuel burner of the present invention can therefore provide heat from the burning of the burner port fuel at the burner ports , whilst the fuel cell assembly can generate an electrical output.
- the temperature of a main gas burner can be very high, which can cause problems for fuel cell materials.
- the fuel cell device described in US 2007/0020494 there is no heat transmitter; the fuel cell is directly exposed to the premix gas flame. In the present claimed invention it is the heat transmitter that is exposed to the flame, rather than the fuel cell.
- the use of a heat transmitter to transfer heat from the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited to the fuel cell assembly means that the fuel cell assembly (e.g. SOFC assembly) is heated, as required to generate an electrical output, but is not overheated by close contact with the hot flames of the burner, thus avoiding potential melting or corrosion of the fuel cell materials.
- the fuel cell assembly can operate in the correct temperature environment, which generally is 900 0 C or less, e.g. it may range from 700 to 900 0 C or from 500 to 800 0 C.
- the fuel burner of the present invention can also be prepared by relatively straightforward modification of an existing flame burner that comprises a main burner body including one or more burner ports and a fuel inlet for providing the burner ports with fuel.
- US 2007/0166587 relates to a methanol fuel cell for powering small electrical apparatus such as a mobile phone - it does not relate to a combined heat and power device.
- the device uses a catalytic combustor and not a main burner body including one or more burner ports as in the product of the present invention.
- a catalytic combustor is not the same as a burner body with burner ports as there is no flame generated. In a catalytic combustor there is oxidation of combustibles on a catalytic surface accompanied by the release of heat but without a flame.
- a catalytic combustor operates at lower temperature than a main burner body (which would have a flame temperature of 1000 0 C or higher, in particular 1200 0 C or higher, such as 1500 0 C or higher, for example up to 2000 0 C) .
- the reaction occurs on the surface of a catalytic material.
- the main burner body including one or more burner ports does not include any catalytic material.
- WO 2006/116638 describes apparatus that includes a fuel cell assembly and a tail gas burner which can burn and extract heat from any fuel in the exhaust stream not already converted or consumed by the fuel cell assembly. This is therefore fundamentally different from the present claimed device which burns inlet gas, not tail gas, to generate heat. Essentially WO 2006/116638 describes a flue gas recycling which is quite different from the present claimed invention where there is no recycling of gas. Recycling is more complex and costly.
- the planar fuel cell device described in EP 1619737 also makes use of tail gas from the fuel cell assembly to generate heat; it uses the tail gas to pass through a heat exchanger to heat the incoming air.
- a main burner is used with a fuel cell assembly to generate heat and electricity, with the main burner providing the required heat to the fuel cell assembly for it to function.
- the main burner is used with a fuel cell to generate heat and electricity to be directed to external applications.
- the main burner also provides the required heat to the fuel cell assembly for it to function.
- the device is designed so as to allow it to provide heat to external applications as well as to the fuel cell.
- the device may include a heat outlet, such as a channel or funnel, which diverts heat to external applications from the burner.
- the heat generated by the burning of the burner port fuel at the burner port when the burner port fuel is ignited is only directed in two directions: (1) to the fuel cell assembly via the heat transmitter and (2) to external applications requiring heat.
- the burner is preferably designed as a straight through device that does not recuperate heat but rather only directs heat in two directions: (1) to the fuel cell assembly and (2) to external applications requiring heat.
- the device does not include any channels or pathways for directing heat from the burner ports other than to: (1) the fuel cell assembly and (2) external applications requiring heat.
- the device does not include an exhaust gas discharge unit for recycling heat from the exhaust gas from the fuel cell assembly. Ideally, no internal heat recuperation components are present. This makes it extremely simple for applying the heat to the external applications (e.g. an expander or drier) . A significant benefit of the present device is that it is simpler and more economic than other designs.
- a main burner is not fed with tail gas fuel recycled from the fuel cell assembly but rather a main burner is fed with inlet gas.
- a main burner which burns unused gas, will have a high flame temperature, e.g. it may have a flame temperature of 1000 0 C or higher, in particular 1200 0 C or higher, such as 1500 0 C or higher, for example up to 2000 0 C.
- the burner is a flame burner that comprises a main flame burner body including one or more burner ports and a fuel inlet for providing the burner ports with unused fuel, the burner body being able to burn the unused fuel with the generation of a flame with a flame temperature of 1000 0 C or higher.
- the present burner is a flame burner that comprises a main flame burner body including one or more burner ports and a fuel inlet for providing the burner ports with unused fuel, the burner body being able to burn the unused fuel with the generation of heat and a flame, e.g. with a flame temperature of 1000 0 C or higher, in particular 1200 0 C or higher, such as 1500°C or higher, for example up to 2000 0 C.
- the fuel inlet for the burner ports provides the burner ports with fuel upstream of the fuel cell assembly.
- the burner ports are provided with fuel that has not been via the fuel cell assembly. Accordingly, the burner ports of the main burner are provided with inlet gas, rather than tail gas from the fuel cell assembly.
- the fuel inlet for providing the burner ports with fuel, the main burner body and the fuel cell assembly are suitably arranged such that the fuel reaches the burner ports from the fuel inlet without having contacted the fuel cell assembly beforehand.
- the fuel burner includes a channel between the fuel inlet for providing the burner ports with fuel and the main burner body, which channels fuel from the fuel inlet to the burner ports upstream of the fuel cell assembly. Accordingly, the channel is arranged such that it channels fuel from the fuel inlet to the burner without channelling the fuel through the fuel cell assembly.
- the fuel inlet for the burner ports is directly supplied with fuel from a fuel supply such as a container of liquid or gaseous fuel, for example a bottled supply of methane, propane, butane or mixtures thereof.
- a fuel supply such as a container of liquid or gaseous fuel, for example a bottled supply of methane, propane, butane or mixtures thereof.
- the main burner body is located between the fuel inlet. for providing the burner ports with fuel and the fuel cell assembly.
- WO 2007/136077 uses a heat exchanger that uses heat from the exhaust gas to heat the incoming oxygen-containing gas.
- This is therefore a well-known tail-gas burner or heat exchanger system, which has been described many times.
- DE 10326265A1 uses a normal burner to heat a reformer which then feeds the fuel cell. The burner also feeds a heat exchanger which heats the air feeding to the fuel cell for rapid start-up.
- the burner device of the present invention does not require the use of heat exchangers. Accordingly, in one embodiment, the burner device of the present invention does not include any heat exchangers.
- the heat from the burner device of the invention is directed to external applications (expanders, driers, boilers etc) so a heat exchanger is not necessary to recuperate heat within the device.
- the present device is thus simpler and cheaper than the prior art.
- the heat exchanger would usually be integrated into the fuel cell stack; e.g. a flat plate heat exchanger is attached to the bottom of the flat plate fuel cell stack.
- the device of US 2007/0166587 also relies on conduction (and therefore contact) between the combustor chamber and the fuel cell units .
- heat is radiated from the heat transmitter to the fuel cell assembly.
- the heat transmitter and the fuel cell assembly are not in contact. This lack of direct contact means that only radiant heat is transmitted.
- the presence of a gap between the heat transmitter and the fuel cell assembly, and therefore the use of radiative heat rather than conductive heat, may make it easier to regulate the temperature of fuel cell.
- the gap between the heat transmitter and the fuel cell assembly is important because, in use, the main burner body gets very hot (frequently from 1000 to 2000 0 C) , in turn making the heat transmitter very hot. Direct contact with this heat could degrade the fuel cell assembly, which tends to operate at 900 0 C or less, such as from around 500 to 800°C.
- the size of the gap may be chosen appropriately depending upon various criteria, such as the intended application of the device, the size of the device, the heat generated at the burner body, the material used for the heat transmitter and its length, and the exact nature of the fuel cells.
- the fuel cell assembly can comprise individual fuel cells connected in series to give a high voltage, in parallel to give high c ⁇ rrent, or in a combination of series and parallel connections. This permits a solution to the problem of needing to stack cells in the burner to raise the voltage to suitable levels.
- the heat transmitter preferably does not include, or connect to, a heat exchanger.
- the heat transmitter is a single component made of a heat transmitting material, which extends from a location in the vicinity of one or more of the burner ports, to a location in the vicinity of the fuel cell assembly.
- the heat transmitter may suitably be a metal or metal alloy.
- the heat transmitter may preferably be a metal alloy, in particular an alloy that can withstand the flame temperature, such as an alloy that can withstand temperatures of at least 700 0 C 1 e.g. at least 1000 0 C; in particular an alloy that can withstand temperatures of at least 1200 0 C, e.g. an alloy that can withstand temperatures of at least 1500 0 C, such as up to 2000°C.
- the heat transmitter may, in one embodiment, be selected from: steel, nickel -chromium alloys, and superalloys.
- the nickel-chromium alloy may in particular be a non-magnetic nickel- chromium alloy, and it may be, for example, 70-90% nickel and 10-30% chromium, such as an 80% nickel and 20% chromium alloy, e.g. Nichrome.
- the superalloy may, for example, be a nickel based, cobalt based or nickel-iron based superalloy.
- the superalloy may in one embodiment be a nickel based superalloy and may contain alloying elements selected from chromium, aluminium, titanium, molybdenum, tungsten, niobium, tantalum, manganese, zirconium, carbon, iron, copper, ruthemium and cobalt.
- Examples of superalloys include Hastelloy, Inconel, Haynes alloys, Incoloy, MP98T, TMS alloys, and CMSX single crystal alloys.
- the heat transmitter is a perforated plate or mesh, such as a steel, nickel-chromium alloy or superalloy perforated plate or mesh.
- the fuel cell assembly is located close enough to the burner ports to reach its operating temperature - due in particular to heating of the fuel cell assembly by the heat transmitter when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited - but not too close to cause overheating.
- the distance chosen in this regard will of course depend upon the exact flame temperature of the burner, and the exact operating temperature of the fuel cell assembly, as well as the precise ability of the heat transmitter to transmit heat.
- the fuel cell assembly is located at a distance from the burner ports such that it is heated to a temperature of 900 0 C or less (e.g. from 700 to 900 0 C or from 500 to 800 0 C) when the burner port fuel is burnt at the burner ports.
- the fuel cell assembly is at least lcm from the burner ports, for example 2cm or more, e.g. 3cm or more, such as 4cm or more, e.g. 5cm or more.
- the portion of the heat transmitter located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited, may suitably be at a distance of 2cm or less from a burner port, e.g. lcm or less, such as 0.5cm or less from a burner port.
- the portion of the heat transmitter located in the vicinity of the fuel cell assembly may suitably be at a distance of 5cm or less from the fuel cell assembly, for example 3cm or less, such as 2cm or less, e.g. lcm or less, such as 0.5cm or less from the fuel cell assembly.
- the fuel inlet for the burner ports may be a pipe that feeds fuel into the main burner body, from where it flows to the burner ports.
- the fuel inlet for the burner ports may be supplied with fuel from a fuel source.
- the fuel source may be any suitable source, in particular those known in the art for supplying fuel to fuel cells, for example a bottle or other container of liquid or gaseous fuel.
- the fuel may be, for example, natural gas, hydrogen, methane, ethane, propane, butane, or combinations thereof.
- the burner ports may be supplied with oxidiser.
- the fuel inlet for providing the burner ports with fuel may be used to provide fuel only or may be used to provide a mixture of fuel and oxidiser.
- the fuel burner may be provided with means for mixing fuel and oxidiser.
- the main burner body may comprise a chamber in communication with the fuel inlet and in communication with the or each burner port.
- the chamber is further provided with an oxidiser inlet, for example a gas inlet hole that allows gaseous oxidiser to be provided, more preferably an air inlet hole that allows air to be provided.
- fuel may be provided into the chamber from the fuel inlet and oxidiser may be provided into the chamber from the oxidiser inlet, and the fuel and oxidiser can be mixed in the chamber before reaching the burner ports.
- the fuel burner may be provided with a valve, to control the supply of fuel from the fuel inlet to the burner ports.
- the main burner body may be provided with any suitable number of burner ports, for example two or more, three or more, or four or more burner ports, such as ten or more or twenty or more. Typically there would be from twenty to forty burner ports, but there could be many more depending on the burner design.
- the fuel burner may further comprise an igniter for igniting the burner port fuel. Any conventional electric ignition system may be used.
- the fuel burner may further comprise a piezoelectric ignition system.
- the fuel inlet for the fuel cell assembly may supply fuel to the fuel cell assembly from the main burner body.
- the fuel inlet for the fuel cell assembly is the same as the fuel inlet for the. burner ports.
- the fuel cell assembly has a separate fuel supply, i.e. the fuel inlet for the fuel cell assembly is not the same as the fuel inlet for the burner ports. Otherwise the efficiency may drop, e.g. to as low as about 1%, which is usually not economic.
- the fuel inlet for the fuel cell assembly may supply fuel to the fuel cell assembly directly from a fuel source, for example a bottle or other container of liquid or gaseous fuel.
- the fuel source may be the same as or different to the fuel source used for the fuel inlet for the burner ports.
- the oxidiser supplied to the fuel cell assembly and any oxidiser supplied to the burner ports may each be any suitable oxidiser and they may be the same or different. Oxidisers known in the art for use in fuel cells may particularly be mentioned; in particular oxygen in pure form, in substantially pure form, or in the form of a mixture with other gases.
- the oxidizer can be a mixture of nitrogen and oxygen (e.g. air) , a mixture of oxygen and another gas, pure oxygen, oxygen enriched air, or other gases containing sufficient amounts of oxygen as the oxidizer.
- the preferred oxidiser is air.
- the fuel burner is provided with one or more gas inlet holes that allow gaseous oxidiser to be provided to the fuel cell assembly, more preferably one or more air inlet holes that allow air to be provided from the environment to the fuel cell assembly.
- the fuel cell assembly may in particular be a solid oxide fuel cell (SOFC) assembly.
- SOFC solid oxide fuel cell
- the fuel cell assembly is a micro tubular fuel cell assembly.
- the fuel cell assembly may be tubular.
- the fuel cell assembly may suitably comprise one or more ceramic tubes, for example the fuel cell assembly may comprise two or three or four ceramic tubes. If more than one ceramic tube is present, these tubes may suitably be stacked parallel to each other.
- the tubes may suitably be of the form standardly known in the art for use in fuel cells.
- the ceramic may be zirconium oxide, ceria, gadolinia, or other oxide materials, and may be doped with a dopant such as yttria, scandia, magnesia or calcia.
- the preferred ceramic is zirconium oxide, doped with yttria, as this provides good ionic conductivity, especially when anode supported.
- the fuel cell assembly is suitably attached to a power output component that acts to transfer the electrical power output of the fuel cell assembly to the desired application.
- the fuel cell assembly may be attached to one or more current collector wire to transfer the electrical power to desired applications.
- the power output component e.g. current collector wire, may be brought out of the hot zone through the fuel cell burner assembly, for example through the burner top plate or through the gas feed tube, where the gas is cooler.
- fuel is supplied via the fuel inlet into the main burner body where it flows to the one or more burner ports. At these ports the fuel is ignited, for example by an igniter that is included in the burner. The burning of the fuel at these ports provides heat to desired applications .
- the burning of the fuel at these ports heats the portion of the heat transmitter that is located in the vicinity of the burner ports.
- the fuel cell assembly is then in turn heated by the heat transmitter, to reach its operating temperature.
- the fuel cell assembly is supplied with fuel via the fuel inlet and oxidiser via the oxidiser inlet. This causes the generation of an electrical output, which may be transferred to desired applications via a power output component.
- the benefits of this fuel burner include:
- Typical applications of this device include heaters which are used away from grid electrical supply, such that the fuel cell assembly can provide electrical power for lighting, battery charging, music, TV or any other electrically powered application in remote locations.
- the device could provide both heat and light.
- the device could give heat, light and music.
- the device could charge batteries and provide electricity for lighting and entertainment as well as providing heat.
- the present invention also provides, in a second aspect, the use of a fuel burner in accordance with the first aspect to generate heat.
- the fuel burner may suitably be used to generate heat that is used for heating a space, such as a room, a vehicle interior, an exterior area such as a patio area, or some or all of a building.
- the fuel cell device may also be used to generate heat for other applications that require heat, for example for use in cooking or heating water.
- a fuel burner in accordance with the first aspect to generate electrical power.
- the fuel burner may be used to generate electrical power for powering systems, for example for powering lights, control systems, computers, communication systems, radios, TVs, stereo systems, battery chargers, engines, or clocks.
- the fuel burner in accordance with the first aspect of the invention may preferably be used both to generate heat and to generate electricity.
- the burner may be used to generate heat for heating a space, cooking or heating water, whilst also being used to generate electricity for powering a lighting system, a communication system, an entertainment system or an engine.
- the present invention also provides, in a fourth aspect, an appliance comprising a fuel burner in accordance with the first aspect of the invention.
- a heat generating appliance is provided, such as a heater for a vehicle (e.g. a car or caravan) , a patio heater, or a greenhouse heater, that comprises a fuel burner in accordance with the first aspect.
- the heat generating appliance may be portable or stationary.
- the appliance is portable, such that it may suitably be used when travelling at home or abroad and in particular when camping or caravanning or the like.
- the heat generating appliance has some, most, substantially all, or all of its heat generating requirements fulfilled by the heat generated by the fuel burner. Additional heat may be generated using the electrical power generated by the fuel cell device, and/or other functions of the appliance may be powered by the electrical power generated by the fuel cell device, for example a lighting system, communication system, entertainment system or an engine may be powered by the electrical power generated by the fuel cell device.
- Figure 1 is a schematic representation of a fuel burner according to the present invention, which illustrates the principle of the invention.
- FIG. 1 schematically illustrates the principle of the fuel burner of the invention.
- the fuel burner shown in Figure 1 includes a main burner body 1 including one or more burner ports 2.
- a fuel inlet 3 provides the burner ports with fuel from fuel source 4.
- a fuel and oxidant mixture may be provided.
- An ignition system 5 is present to ignite the fuel at the burner ports 2.
- a fuel cell assembly 6 is also included. This is suitably a micro tubular fuel cell assembly. Air inlet holes (not shown) may also be provided, to allow air to be provided from the environment to the fuel cell assembly.
- the assembly is supplied with fuel from the fuel inlet 3, via the main burner body.
- Oxidant may be provided to the assembly from the main burner body, and/or from air inlet holes.
- the fuel inlet 3 provides the burner ports 2 with fuel upstream of the fuel cell assembly 6.
- the fuel cell assembly is attached to current collector wires 7 to transfer the electrical power to desired applications.
- a heat transmitter 8 which is a radiant metal mesh, is also present.
- a portion of the heat transmitter 8 is located in the vicinity of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited, whilst a portion of the heat transmitter is located in the vicinity of (but not in direct contact with) the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter.
- radiative heat is transferred from the heat transmitter to the fuel cell assembly.
- fuel is supplied from fuel source 4 via the fuel inlet 3 into the main burner body 1, where it flows to the burner ports 2. At these ports the fuel is ignited, by ignition system 5. The burning of the fuel at these ports provides heat to desired applications . Additionally, the burning of the fuel at these ports heats the portion of the heat transmitter 8 that is located in the vicinity of the burner ports 2. The fuel cell assembly 6 is then in turn heated by the heat transmitter 8 to reach its operating temperature.
- the fuel cell assembly 6 is supplied with fuel from the fuel inlet 3, via the main burner body 1 , and oxidiser from the fuel inlet 3, via the main burner body 1 and/or from air inlet holes.
- the heating of the fuel cell assembly 6, together with supply of fuel and oxidiser, causes the generation of an electrical output, which is transferred to desired applications via the current collector wires 7.
- the device provides both heat and electricity to external applications .
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Abstract
A fuel burner is provided that can provide both heat and electrical power to external applications, the burner comprising: (a) a main burner body including one or more burner ports; (b) a fuel inlet for providing the burner ports with fuel; (c) a heat transmitter, wherein a portion of the heat transmitter is located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited; (d) a fuel cell assembly that causes the generation of an electrical output when it is heated and supplied with fuel and oxidiser; (e) a fuel inlet for providing the fuel cell assembly with fuel; and (f) an oxidiser inlet for providing the fuel cell assembly with oxidiser; wherein a portion of the heat transmitter is located in the vicinity of the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter; and wherein the fuel inlet for providing the burner ports with fuel provides the burner ports with fuel upstream of the fuel cell assembly.
Description
COMBINED FUEL BURNER AND FUEL CELL
The present invention relates to a fuel burner, in particular a fuel burner that can provide both heat and electrical power.
Fuel burners for generation of heat by burning fuels such as methane, propane, butane or gas mixtures are well known. However, such devices cannot usually provide electrical power unless they are used to drive a heat engine or similar complicated energy conversion device.
It would be very desirable to produce heat and electrical power together from a single device because combined heat and power is known to be beneficial. Applications where combined heat and electrical power is desired include: leisure, where heat is needed for cooking and electricity is needed for communications; buildings, where electricity is used for lighting and heat is used for warmth, and vehicles, in which electricity drives the engine while heat is used to warm the occupants .
Although thermoelectric converters have been used on oil and gas pipelines to achieve combined heat and electrical power generation, these have a high cost and low efficiency and therefore are not. generally applicable. There is therefore a need for an easy and economically achievable solution to the desire for combined heat and electrical power generation.
Various modifications to burner devices have been proposed to enable combined production of both heat and power. In particular, fuel cells have been used in combination with fuel burner devices . For example, a modified burner has been proposed incorporating tubular solid oxide fuel cells (SOFCs) (Kendall et al, J. Materials Science, 36 (2001) 1119-1124) . WO 2005/112 158 discloses a catalytic burner system incorporating
tubular fuel cells to provide hot gases as well as electrical power. It has also been proposed to insert a planar SOFC into a flame to produce combined heat and power (Horiuchi et al, J. Electrochemical Soc. , 151(2004) A1402-5) .
However, there are several problems with these devices. In particular, the flame temperature of the burner can be very high, up to 20000C, which melts or corrodes the fuel cell materials. Another problem is that the flame system has to be modified to incorporate the fuel cells, such that the device becomes too expensive or difficult to ignite. An additional problem is the issue of stacking of cells in the burner to raise the voltage to suitable levels.
There is therefore a need for a further solution to provide easy and economic combined heat and electrical power generation.
The present invention provides, in a first aspect, a fuel burner that can provide both heat and electrical power, the burner comprising: a main burner body including one or more burner ports; a fuel inlet for providing the burner ports with fuel; a heat transmitter, wherein a portion of the heat transmitter is located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited; a fuel cell assembly that causes the generation of an electrical output when it is heated and supplied with fuel and oxidiser; a fuel inlet for providing the fuel cell assembly with fuel; and an oxidiser inlet for providing the fuel cell assembly with oxidiser; wherein a portion of the heat transmitter is located in the vicinity of the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner
port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter.
The fuel burner of the present invention can therefore provide heat from the burning of the burner port fuel at the burner ports , whilst the fuel cell assembly can generate an electrical output.
As noted above, the temperature of a main gas burner can be very high, which can cause problems for fuel cell materials. In the fuel cell device described in US 2007/0020494, there is no heat transmitter; the fuel cell is directly exposed to the premix gas flame. In the present claimed invention it is the heat transmitter that is exposed to the flame, rather than the fuel cell.
The use of a heat transmitter to transfer heat from the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited to the fuel cell assembly means that the fuel cell assembly (e.g. SOFC assembly) is heated, as required to generate an electrical output, but is not overheated by close contact with the hot flames of the burner, thus avoiding potential melting or corrosion of the fuel cell materials. Instead, the fuel cell assembly can operate in the correct temperature environment, which generally is 9000C or less, e.g. it may range from 700 to 9000C or from 500 to 8000C.
The fuel burner of the present invention can also be prepared by relatively straightforward modification of an existing flame burner that comprises a main burner body including one or more burner ports and a fuel inlet for providing the burner ports with fuel.
US 2007/0166587 relates to a methanol fuel cell for powering small electrical apparatus such as a mobile phone - it does not relate to a
combined heat and power device. Also, the device uses a catalytic combustor and not a main burner body including one or more burner ports as in the product of the present invention. A catalytic combustor is not the same as a burner body with burner ports as there is no flame generated. In a catalytic combustor there is oxidation of combustibles on a catalytic surface accompanied by the release of heat but without a flame.
Indeed, a catalytic combustor operates at lower temperature than a main burner body (which would have a flame temperature of 10000C or higher, in particular 12000C or higher, such as 15000C or higher, for example up to 20000C) .
In a catalytic combustor the reaction occurs on the surface of a catalytic material. In one embodiment, in the present apparatus, the main burner body including one or more burner ports does not include any catalytic material.
In the prior art the combination of a fuel cell assembly with a tail gas burner is known, so as to use up left over fuel from the fuel cell assembly.
For example, WO 2006/116638 describes apparatus that includes a fuel cell assembly and a tail gas burner which can burn and extract heat from any fuel in the exhaust stream not already converted or consumed by the fuel cell assembly. This is therefore fundamentally different from the present claimed device which burns inlet gas, not tail gas, to generate heat. Essentially WO 2006/116638 describes a flue gas recycling which is quite different from the present claimed invention where there is no recycling of gas. Recycling is more complex and costly.
The planar fuel cell device described in EP 1619737 also makes use of tail gas from the fuel cell assembly to generate heat; it uses the tail gas to pass through a heat exchanger to heat the incoming air. This type of recycling is described in the book High Temperature Solid Oxide Fuel Cells, SC Singhal & K Kendall, Elsevier 2003, Fig 1.9. It is very common in many SOFC systems to have a recuperator of this sort, which is also common on gas turbines.
In the present claimed invention a main burner is used with a fuel cell assembly to generate heat and electricity, with the main burner providing the required heat to the fuel cell assembly for it to function. Specifically, the main burner is used with a fuel cell to generate heat and electricity to be directed to external applications. The main burner also provides the required heat to the fuel cell assembly for it to function.
The device is designed so as to allow it to provide heat to external applications as well as to the fuel cell. In one embodiment, the device may include a heat outlet, such as a channel or funnel, which diverts heat to external applications from the burner.
Preferably, the heat generated by the burning of the burner port fuel at the burner port when the burner port fuel is ignited is only directed in two directions: (1) to the fuel cell assembly via the heat transmitter and (2) to external applications requiring heat.
Specifically, the burner is preferably designed as a straight through device that does not recuperate heat but rather only directs heat in two directions: (1) to the fuel cell assembly and (2) to external applications requiring heat.
Accordingly, in a preferred embodiment, the device does not include any channels or pathways for directing heat from the burner ports other than to: (1) the fuel cell assembly and (2) external applications requiring heat. In one embodiment, the device does not include an exhaust gas discharge unit for recycling heat from the exhaust gas from the fuel cell assembly. Ideally, no internal heat recuperation components are present. This makes it extremely simple for applying the heat to the external applications (e.g. an expander or drier) . A significant benefit of the present device is that it is simpler and more economic than other designs.
A main burner is not fed with tail gas fuel recycled from the fuel cell assembly but rather a main burner is fed with inlet gas. A main burner, which burns unused gas, will have a high flame temperature, e.g. it may have a flame temperature of 10000C or higher, in particular 12000C or higher, such as 15000C or higher, for example up to 20000C.
Preferably, the burner is a flame burner that comprises a main flame burner body including one or more burner ports and a fuel inlet for providing the burner ports with unused fuel, the burner body being able to burn the unused fuel with the generation of a flame with a flame temperature of 10000C or higher.
Specifically, the present burner is a flame burner that comprises a main flame burner body including one or more burner ports and a fuel inlet for providing the burner ports with unused fuel, the burner body being able to burn the unused fuel with the generation of heat and a flame, e.g. with a flame temperature of 10000C or higher, in particular 12000C or higher, such as 1500°C or higher, for example up to 20000C.
Therefore in the present claimed invention the fuel inlet for the burner ports provides the burner ports with fuel upstream of the fuel cell
assembly. Thus the burner ports are provided with fuel that has not been via the fuel cell assembly. Accordingly, the burner ports of the main burner are provided with inlet gas, rather than tail gas from the fuel cell assembly.
Therefore the fuel inlet for providing the burner ports with fuel, the main burner body and the fuel cell assembly are suitably arranged such that the fuel reaches the burner ports from the fuel inlet without having contacted the fuel cell assembly beforehand.
Preferably, the fuel burner includes a channel between the fuel inlet for providing the burner ports with fuel and the main burner body, which channels fuel from the fuel inlet to the burner ports upstream of the fuel cell assembly. Accordingly, the channel is arranged such that it channels fuel from the fuel inlet to the burner without channelling the fuel through the fuel cell assembly.
In one embodiment, the fuel inlet for the burner ports is directly supplied with fuel from a fuel supply such as a container of liquid or gaseous fuel, for example a bottled supply of methane, propane, butane or mixtures thereof.
In one embodiment, the main burner body is located between the fuel inlet. for providing the burner ports with fuel and the fuel cell assembly.
In the prior art fuel cell devices that utilize heat exchangers are known. For example, WO 2007/136077 uses a heat exchanger that uses heat from the exhaust gas to heat the incoming oxygen-containing gas. This is therefore a well-known tail-gas burner or heat exchanger system, which has been described many times.
DE 10326265A1 uses a normal burner to heat a reformer which then feeds the fuel cell. The burner also feeds a heat exchanger which heats the air feeding to the fuel cell for rapid start-up.
The present invention does not require the use of heat exchangers. Accordingly, in one embodiment, the burner device of the present invention does not include any heat exchangers. The heat from the burner device of the invention is directed to external applications (expanders, driers, boilers etc) so a heat exchanger is not necessary to recuperate heat within the device. The present device is thus simpler and cheaper than the prior art.
Additionally, in the prior art, the heat exchanger would usually be integrated into the fuel cell stack; e.g. a flat plate heat exchanger is attached to the bottom of the flat plate fuel cell stack. The device of US 2007/0166587 also relies on conduction (and therefore contact) between the combustor chamber and the fuel cell units .
In contrast, in the device of the present invention, it is preferred that there is not direct contact between the heat transmitter and the fuel cell assembly.
Preferably, there is no contact between the heat transmitter and the fuel cell assembly, such that only radiant heat is transmitted from the heat transmitter to the fuel cell assembly.
Specifically, it is preferred in the present device that heat is radiated from the heat transmitter to the fuel cell assembly. The heat transmitter and the fuel cell assembly are not in contact. This lack of direct contact means that only radiant heat is transmitted.
The presence of a gap between the heat transmitter and the fuel cell assembly, and therefore the use of radiative heat rather than conductive heat, may make it easier to regulate the temperature of fuel cell.
Significantly, the gap between the heat transmitter and the fuel cell assembly is important because, in use, the main burner body gets very hot (frequently from 1000 to 20000C) , in turn making the heat transmitter very hot. Direct contact with this heat could degrade the fuel cell assembly, which tends to operate at 9000C or less, such as from around 500 to 800°C.
In one embodiment, there is a gap of 0.1cm or more between the heat transmitter and the fuel cell assembly, such as 0.2cm or more, preferably 0.3cm or more, such as 0.4cm or more, for example 0.5cm or more. As the skilled man would appreciate, the size of the gap may be chosen appropriately depending upon various criteria, such as the intended application of the device, the size of the device, the heat generated at the burner body, the material used for the heat transmitter and its length, and the exact nature of the fuel cells.
In one embodiment, there is a gap of from 0.1cm to 5cm between the heat transmitter and the fuel cell assembly, such as from 0.2cm to 4cm, preferably from 0.3cm to 3cm, such as from 0.4cm to 2cm, for example from 0.5cm to lcm.
The fuel cell assembly can comprise individual fuel cells connected in series to give a high voltage, in parallel to give high cμrrent, or in a combination of series and parallel connections. This permits a solution to the problem of needing to stack cells in the burner to raise the voltage to suitable levels.
The heat transmitter preferably does not include, or connect to, a heat exchanger.
Preferably, the heat transmitter is a single component made of a heat transmitting material, which extends from a location in the vicinity of one or more of the burner ports, to a location in the vicinity of the fuel cell assembly.
The heat transmitter may suitably be a metal or metal alloy. The heat transmitter may preferably be a metal alloy, in particular an alloy that can withstand the flame temperature, such as an alloy that can withstand temperatures of at least 7000C1 e.g. at least 10000C; in particular an alloy that can withstand temperatures of at least 12000C, e.g. an alloy that can withstand temperatures of at least 15000C, such as up to 2000°C.
The heat transmitter may, in one embodiment, be selected from: steel, nickel -chromium alloys, and superalloys.
The nickel-chromium alloy may in particular be a non-magnetic nickel- chromium alloy, and it may be, for example, 70-90% nickel and 10-30% chromium, such as an 80% nickel and 20% chromium alloy, e.g. Nichrome.
The superalloy may, for example, be a nickel based, cobalt based or nickel-iron based superalloy. The superalloy may in one embodiment be a nickel based superalloy and may contain alloying elements selected from chromium, aluminium, titanium, molybdenum, tungsten, niobium, tantalum, manganese, zirconium, carbon, iron, copper, ruthemium and cobalt. Examples of superalloys include Hastelloy, Inconel, Haynes alloys, Incoloy, MP98T, TMS alloys, and CMSX single crystal alloys.
In one embodiment, the heat transmitter is a perforated plate or mesh, such as a steel, nickel-chromium alloy or superalloy perforated plate or mesh.
Preferably, the fuel cell assembly is located close enough to the burner ports to reach its operating temperature - due in particular to heating of the fuel cell assembly by the heat transmitter when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited - but not too close to cause overheating. The distance chosen in this regard will of course depend upon the exact flame temperature of the burner, and the exact operating temperature of the fuel cell assembly, as well as the precise ability of the heat transmitter to transmit heat.
Preferably, the fuel cell assembly is located at a distance from the burner ports such that it is heated to a temperature of 9000C or less (e.g. from 700 to 9000C or from 500 to 8000C) when the burner port fuel is burnt at the burner ports. In one embodiment, the fuel cell assembly is at least lcm from the burner ports, for example 2cm or more, e.g. 3cm or more, such as 4cm or more, e.g. 5cm or more.
The portion of the heat transmitter located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited, may suitably be at a distance of 2cm or less from a burner port, e.g. lcm or less, such as 0.5cm or less from a burner port.
The portion of the heat transmitter located in the vicinity of the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter,
may suitably be at a distance of 5cm or less from the fuel cell assembly, for example 3cm or less, such as 2cm or less, e.g. lcm or less, such as 0.5cm or less from the fuel cell assembly.
The fuel inlet for the burner ports may be a pipe that feeds fuel into the main burner body, from where it flows to the burner ports.
The fuel inlet for the burner ports may be supplied with fuel from a fuel source. The fuel source may be any suitable source, in particular those known in the art for supplying fuel to fuel cells, for example a bottle or other container of liquid or gaseous fuel. The fuel may be, for example, natural gas, hydrogen, methane, ethane, propane, butane, or combinations thereof.
The burner ports may be supplied with oxidiser.
The fuel inlet for providing the burner ports with fuel may be used to provide fuel only or may be used to provide a mixture of fuel and oxidiser.
The fuel burner may be provided with means for mixing fuel and oxidiser. In one embodiment, the main burner body may comprise a chamber in communication with the fuel inlet and in communication with the or each burner port. The chamber is further provided with an oxidiser inlet, for example a gas inlet hole that allows gaseous oxidiser to be provided, more preferably an air inlet hole that allows air to be provided. Accordingly, fuel may be provided into the chamber from the fuel inlet and oxidiser may be provided into the chamber from the oxidiser inlet, and the fuel and oxidiser can be mixed in the chamber before reaching the burner ports.
The fuel burner may be provided with a valve, to control the supply of fuel from the fuel inlet to the burner ports.
The main burner body may be provided with any suitable number of burner ports, for example two or more, three or more, or four or more burner ports, such as ten or more or twenty or more. Typically there would be from twenty to forty burner ports, but there could be many more depending on the burner design.
The fuel burner may further comprise an igniter for igniting the burner port fuel. Any conventional electric ignition system may be used. For example, the fuel burner may further comprise a piezoelectric ignition system.
The fuel inlet for the fuel cell assembly may supply fuel to the fuel cell assembly from the main burner body. In one embodiment, the fuel inlet for the fuel cell assembly is the same as the fuel inlet for the. burner ports.
Preferably, however, the fuel cell assembly has a separate fuel supply, i.e. the fuel inlet for the fuel cell assembly is not the same as the fuel inlet for the burner ports. Otherwise the efficiency may drop, e.g. to as low as about 1%, which is usually not economic.
In one embodiment, the fuel inlet for the fuel cell assembly may supply fuel to the fuel cell assembly directly from a fuel source, for example a bottle or other container of liquid or gaseous fuel. The fuel source may be the same as or different to the fuel source used for the fuel inlet for the burner ports.
The oxidiser supplied to the fuel cell assembly and any oxidiser supplied to the burner ports may each be any suitable oxidiser and they may be the same or different. Oxidisers known in the art for use in fuel cells may particularly be mentioned; in particular oxygen in pure form, in substantially pure form, or in the form of a mixture with other gases. The oxidizer can be a mixture of nitrogen and oxygen (e.g. air) , a mixture of oxygen and another gas, pure oxygen, oxygen enriched air, or other gases containing sufficient amounts of oxygen as the oxidizer. The preferred oxidiser is air.
Preferably, the fuel burner is provided with one or more gas inlet holes that allow gaseous oxidiser to be provided to the fuel cell assembly, more preferably one or more air inlet holes that allow air to be provided from the environment to the fuel cell assembly.
The fuel cell assembly may in particular be a solid oxide fuel cell (SOFC) assembly. Preferably, the fuel cell assembly is a micro tubular fuel cell assembly.
The fuel cell assembly may be tubular. The fuel cell assembly may suitably comprise one or more ceramic tubes, for example the fuel cell assembly may comprise two or three or four ceramic tubes. If more than one ceramic tube is present, these tubes may suitably be stacked parallel to each other. The tubes may suitably be of the form standardly known in the art for use in fuel cells. The ceramic may be zirconium oxide, ceria, gadolinia, or other oxide materials, and may be doped with a dopant such as yttria, scandia, magnesia or calcia. The preferred ceramic is zirconium oxide, doped with yttria, as this provides good ionic conductivity, especially when anode supported.
The fuel cell assembly is suitably attached to a power output component that acts to transfer the electrical power output of the fuel cell assembly to the desired application. For example, the fuel cell assembly may be attached to one or more current collector wire to transfer the electrical power to desired applications. The power output component, e.g. current collector wire, may be brought out of the hot zone through the fuel cell burner assembly, for example through the burner top plate or through the gas feed tube, where the gas is cooler.
In use, fuel is supplied via the fuel inlet into the main burner body where it flows to the one or more burner ports. At these ports the fuel is ignited, for example by an igniter that is included in the burner. The burning of the fuel at these ports provides heat to desired applications .
Additionally, the burning of the fuel at these ports heats the portion of the heat transmitter that is located in the vicinity of the burner ports. The fuel cell assembly is then in turn heated by the heat transmitter, to reach its operating temperature. The fuel cell assembly is supplied with fuel via the fuel inlet and oxidiser via the oxidiser inlet. This causes the generation of an electrical output, which may be transferred to desired applications via a power output component.
The benefits of this fuel burner include:
• It is easy and economic to make from existing burners • It is readily ignited with conventional electric ignition systems
• It uses conventional fuels such as methane, natural gas, propane
• The burner heats up and cools down rapidly to give convenient operation.
Typical applications of this device include heaters which are used away from grid electrical supply, such that the fuel cell assembly can provide
electrical power for lighting, battery charging, music, TV or any other electrically powered application in remote locations. For example, in a greenhouse heater, the device could provide both heat and light. In a patio heater the device could give heat, light and music. In a caravan heater or gas cooker the device could charge batteries and provide electricity for lighting and entertainment as well as providing heat.
The present invention also provides, in a second aspect, the use of a fuel burner in accordance with the first aspect to generate heat. The fuel burner may suitably be used to generate heat that is used for heating a space, such as a room, a vehicle interior, an exterior area such as a patio area, or some or all of a building. The fuel cell device may also be used to generate heat for other applications that require heat, for example for use in cooking or heating water.
Also provided, in a third aspect, is the use of a fuel burner in accordance with the first aspect to generate electrical power. In particular, the fuel burner may be used to generate electrical power for powering systems, for example for powering lights, control systems, computers, communication systems, radios, TVs, stereo systems, battery chargers, engines, or clocks.
The fuel burner in accordance with the first aspect of the invention may preferably be used both to generate heat and to generate electricity. For example, the burner may be used to generate heat for heating a space, cooking or heating water, whilst also being used to generate electricity for powering a lighting system, a communication system, an entertainment system or an engine.
The present invention also provides, in a fourth aspect, an appliance comprising a fuel burner in accordance with the first aspect of the
invention. In particular, a heat generating appliance is provided, such as a heater for a vehicle (e.g. a car or caravan) , a patio heater, or a greenhouse heater, that comprises a fuel burner in accordance with the first aspect. The heat generating appliance may be portable or stationary. In one embodiment, the appliance is portable, such that it may suitably be used when travelling at home or abroad and in particular when camping or caravanning or the like.
Preferably, the heat generating appliance has some, most, substantially all, or all of its heat generating requirements fulfilled by the heat generated by the fuel burner. Additional heat may be generated using the electrical power generated by the fuel cell device, and/or other functions of the appliance may be powered by the electrical power generated by the fuel cell device, for example a lighting system, communication system, entertainment system or an engine may be powered by the electrical power generated by the fuel cell device.
The present invention will now be further described, by means of example only, with reference to the accompanying drawing in which:
Figure 1 is a schematic representation of a fuel burner according to the present invention, which illustrates the principle of the invention.
Figure 1 schematically illustrates the principle of the fuel burner of the invention. The fuel burner shown in Figure 1 includes a main burner body 1 including one or more burner ports 2. A fuel inlet 3 provides the burner ports with fuel from fuel source 4. Optionally, a fuel and oxidant mixture may be provided. An ignition system 5 is present to ignite the fuel at the burner ports 2.
A fuel cell assembly 6 is also included. This is suitably a micro tubular fuel cell assembly. Air inlet holes (not shown) may also be provided, to allow air to be provided from the environment to the fuel cell assembly.
The assembly is supplied with fuel from the fuel inlet 3, via the main burner body. Oxidant may be provided to the assembly from the main burner body, and/or from air inlet holes.
The fuel inlet 3 provides the burner ports 2 with fuel upstream of the fuel cell assembly 6.
The fuel cell assembly is attached to current collector wires 7 to transfer the electrical power to desired applications.
A heat transmitter 8, which is a radiant metal mesh, is also present.
A portion of the heat transmitter 8 is located in the vicinity of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited, whilst a portion of the heat transmitter is located in the vicinity of (but not in direct contact with) the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter. In this regard, radiative heat is transferred from the heat transmitter to the fuel cell assembly.
In use, fuel is supplied from fuel source 4 via the fuel inlet 3 into the main burner body 1, where it flows to the burner ports 2. At these ports the fuel is ignited, by ignition system 5. The burning of the fuel at these ports provides heat to desired applications .
Additionally, the burning of the fuel at these ports heats the portion of the heat transmitter 8 that is located in the vicinity of the burner ports 2. The fuel cell assembly 6 is then in turn heated by the heat transmitter 8 to reach its operating temperature.
Therefore the heat from the burning of the fuel at the ports is directed only: (1) to the fuel cell assembly and (2) to external applications requiring heat.
No heat exchanger is present, or any other component to regenerate heat within the device.
The fuel cell assembly 6 is supplied with fuel from the fuel inlet 3, via the main burner body 1 , and oxidiser from the fuel inlet 3, via the main burner body 1 and/or from air inlet holes. The heating of the fuel cell assembly 6, together with supply of fuel and oxidiser, causes the generation of an electrical output, which is transferred to desired applications via the current collector wires 7.
Therefore the device provides both heat and electricity to external applications .
Claims
1. A fuel burner that can provide both heat and electrical power to external applications, the burner comprising: a main burner body including one or more burner ports; a fuel inlet for providing the burner ports with fuel; a heat transmitter, wherein a portion of the heat transmitter is located in the vicinity of one or more of the burner ports, such that it is heated by the burning of the burner port fuel at said burner port when the burner port fuel is ignited; a fuel cell assembly that causes the generation of an electrical output when it is heated and supplied with fuel and oxidiser; a fuel inlet for providing the fuel cell assembly with fuel; and an oxidiser inlet for providing the fuel cell assembly with oxidiser; wherein a portion of the heat transmitter is located in the vicinity of the fuel cell assembly, such that when the heat transmitter is heated by the burning of the burner port fuel at the or each burner port when the burner port fuel is ignited, the fuel cell assembly is in turn heated by the heat transmitter; and wherein the fuel inlet for providing the burner ports with fuel provides the burner ports with fuel upstream of the fuel cell assembly.
2. The fuel burner according to claim 1, wherein the heat generated by the burning of the burner port fuel at the burner port when the burner port fuel is ignited is only directed in two directions: (1) to the fuel cell assembly via the heat transmitter and (2) to external applications requiring heat.
3. The fuel burner according to claim 1 or claim 2, wherein the burner is a flame burner that comprises a main flame burner body including one or more burner ports and a fuel inlet for providing the burner ports with unused fuel, the burner body being able to burn the unused fuel with the generation of a flame with a flame temperature of 10000C or higher.
4. The fuel burner according to any one of the preceding claims wherein there is no contact between the heat transmitter and the fuel cell assembly, such that only radiant heat is transmitted from the heat transmitter to the fuel cell assembly.
5. The fuel burner according to claim 4, wherein there is a gap of 0.1cm or more between the heat transmitter and the fuel cell assembly.
6. The fuel burner according to any one of the preceding claims, wherein the fuel burner does not include any heat exchangers.
7. The fuel burner according to any one of the preceding claims further comprising a channel between the fuel inlet for providing the burner ports with fuel and the main burner body, which channels fuel from the fuel inlet to the burner ports upstream of the fuel cell assembly.
8. The fuel burner according to any one of the preceding claims, wherein the fuel inlet for the burner ports is directly supplied with fuel from a container of liquid or gaseous fuel.
9. The fuel burner according to any one of the preceding claims, wherein the main burner body is located between the fuel inlet for providing the burner ports with fuel and the fuel cell assembly.
10. The fuel burner according to a ny one of the preceding claims, wherein the heat transmitter is an alloy that can withstand temperatures of at least 7000C.
11. The fuel burner according to any one of the preceding claims wherein the fuel cell assembly is located at a distance from the burner ports such that it is heated to a temperature of from 700 to 9000C when the burner port fuel is burnt at the burner ports.
12. The fuel burner according to any one of the preceding claims wherein the fuel cell assembly is at least lcm from the burner ports.
13. The fuel burner according to any one of the preceding claims wherein the portion of the heat transmitter located in the vicinity of one or more of the burner ports is at a distance of 2cm or less from a burner port.
14. The fuel burner according to any one of the preceding claims wherein the main burner body is provided with ten or more burner ports.
15. The fuel burner according to any one of the preceding claims wherein the fuel cell assembly is a solid oxide fuel cell assembly.
16. The fuel burner according to any one of the preceding claims wherein the fuel cell assembly is a micro tubular fuel cell assembly.
17. The fuel burner according to any one of the preceding claims wherein the fuel cell assembly is attached to a power output component that acts to transfer the electrical power output of the fuel cell assembly to the desired application.
18. The use of a fuel burner in accordance with any one of the preceding claims to generate heat.
19. The use of claim 18 wherein the fuel burner is used to generate heat that is used for heating a space.
20. The use of a fuel burner in accordance with any one of claims 1 to 17 to generate electrical power.
21. The use of claim 20 wherein the fuel burner is used both to generate heat and to generate electricity.
22. An appliance comprising a fuel burner in accordance with any one of claims 1 to 17.
23. The appliance of claim 22, which is a heat generating appliance.
24. The appliance of claim 23, which is a heater for a vehicle, a patio heater, or a greenhouse heater.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0716759A GB0716759D0 (en) | 2007-08-25 | 2007-08-25 | Fuel burner |
GB0716759.6 | 2007-08-25 | ||
GB0805445A GB0805445D0 (en) | 2008-03-26 | 2008-03-26 | Fuel burner |
GB0805445.4 | 2008-03-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009027633A1 true WO2009027633A1 (en) | 2009-03-05 |
Family
ID=40039915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2008/002829 WO2009027633A1 (en) | 2007-08-25 | 2008-08-21 | Combined fuel burner and fuel cell |
Country Status (1)
Country | Link |
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WO (1) | WO2009027633A1 (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005078842A1 (en) * | 2004-02-13 | 2005-08-25 | Alberta Research Council Inc. | Heating solid oxide fuel cell stack |
WO2006051830A1 (en) * | 2004-11-09 | 2006-05-18 | Dai Nippon Printing Co., Ltd. | Cogeneration system using fuel cell |
-
2008
- 2008-08-21 WO PCT/GB2008/002829 patent/WO2009027633A1/en active Application Filing
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005078842A1 (en) * | 2004-02-13 | 2005-08-25 | Alberta Research Council Inc. | Heating solid oxide fuel cell stack |
WO2006051830A1 (en) * | 2004-11-09 | 2006-05-18 | Dai Nippon Printing Co., Ltd. | Cogeneration system using fuel cell |
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