WO2009024312A3 - Method for the production and stabilization of functional metal nanoparticles in ionic liquids - Google Patents

Method for the production and stabilization of functional metal nanoparticles in ionic liquids Download PDF

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Publication number
WO2009024312A3
WO2009024312A3 PCT/EP2008/006768 EP2008006768W WO2009024312A3 WO 2009024312 A3 WO2009024312 A3 WO 2009024312A3 EP 2008006768 W EP2008006768 W EP 2008006768W WO 2009024312 A3 WO2009024312 A3 WO 2009024312A3
Authority
WO
WIPO (PCT)
Prior art keywords
stabilization
metal nanoparticles
production
ionic liquids
functional metal
Prior art date
Application number
PCT/EP2008/006768
Other languages
German (de)
French (fr)
Other versions
WO2009024312A2 (en
Inventor
Christoph Janiak
Engelbert Redel
Marco Klingele
Thomas Schubert
Tom Beyersdorff
Original Assignee
Albert-Ludwigs-Universität Freiburg
Iolitec Ionic Liquids Technologies Gmbh & Co. Kg
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Albert-Ludwigs-Universität Freiburg, Iolitec Ionic Liquids Technologies Gmbh & Co. Kg filed Critical Albert-Ludwigs-Universität Freiburg
Publication of WO2009024312A2 publication Critical patent/WO2009024312A2/en
Publication of WO2009024312A3 publication Critical patent/WO2009024312A3/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0282—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aliphatic ring, e.g. morpholinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0277—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature
    • B01J31/0278—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre
    • B01J31/0281—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member
    • B01J31/0284—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides comprising ionic liquids, as components in catalyst systems or catalysts per se, the ionic liquid compounds being used in the molten state at the respective reaction temperature containing nitrogen as cationic centre the nitrogen being a ring member of an aromatic ring, e.g. pyridinium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/14—Treatment of metallic powder
    • B22F1/145—Chemical treatment, e.g. passivation or decarburisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/10—Complexes comprising metals of Group I (IA or IB) as the central metal
    • B01J2531/17—Silver
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00—Making metallic powder or suspensions thereof
    • B22F9/16—Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
    • B22F2009/245—Reduction reaction in an Ionic Liquid [IL]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00—Treatment of water, waste water, or sewage
    • C02F1/50—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505—Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

The present invention relates to a method for the reductive production and stabilization of functional metal nanoparticles under mild conditions in ionic liquids from the associated soluble salt sources by using elemental hydrogen in the presence of a proton catcher, allowing to adjust the particle size and the size distribution thereof by the appropriate choice of the used ionic liquid.
PCT/EP2008/006768 2007-08-17 2008-08-18 Method for the production and stabilization of functional metal nanoparticles in ionic liquids WO2009024312A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102007038879A DE102007038879A1 (en) 2007-08-17 2007-08-17 Process for the preparation and stabilization of functional metal nanoparticles in ionic liquids
DE102007038879.0 2007-08-17

Publications (2)

Publication Number Publication Date
WO2009024312A2 WO2009024312A2 (en) 2009-02-26
WO2009024312A3 true WO2009024312A3 (en) 2009-12-23

Family

ID=40279507

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/006768 WO2009024312A2 (en) 2007-08-17 2008-08-18 Method for the production and stabilization of functional metal nanoparticles in ionic liquids

Country Status (2)

Country Link
DE (1) DE102007038879A1 (en)
WO (1) WO2009024312A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2350351B2 (en) 2010-07-30 2012-02-02 Universidade De Santiago De Compostela PROCEDURE FOR THE PREPARATION OF NANOPARTICLES IN ION LIQUIDS.
FR2999956B1 (en) 2012-12-21 2015-12-25 Centre Nat Rech Scient NANO-METAL CATALYSTS IN GLYCEROL AND APPLICATIONS IN ORGANIC SYNTHESIS
CN103691966B (en) * 2014-01-06 2015-07-29 中南大学 A kind of method preparing nano silver particles based on poly-(2-acrylamide-2-methylpro panesulfonic acid)
CN109490522B (en) * 2018-12-04 2022-03-11 北京倍肯恒业科技发展股份有限公司 Nano colloidal gold and preparation method and application thereof
CN111203545B (en) * 2020-01-16 2022-09-13 河南科技大学 Preparation method of chrysanthemum-shaped Pd nanoparticles regulated and controlled by ionic liquid
CN111922360B (en) * 2020-10-19 2021-01-01 西安宏星电子浆料科技股份有限公司 Preparation method of nano copper powder

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032572A2 (en) * 1998-12-04 2000-06-08 Symyx Technologies Combinatorial discovery and testing of ionic liquids
WO2007001355A2 (en) * 2004-09-08 2007-01-04 Rensselaer Polytechnic Institute Enhanced stability of proteins immobilized on nanoparticles
WO2008145835A2 (en) * 2007-04-26 2008-12-04 I.F.P. Method for hydrogenating an aromatic charge using as a catalyst a suspension of metal nanoparticles containing a nitrogen ligand in an ionic liquid

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE10108893C5 (en) 2001-02-23 2011-01-13 Rolf Prof. Dr. Hempelmann Process for the production of metals and their alloys
US20070101824A1 (en) * 2005-06-10 2007-05-10 Board Of Trustees Of Michigan State University Method for producing compositions of nanoparticles on solid surfaces

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000032572A2 (en) * 1998-12-04 2000-06-08 Symyx Technologies Combinatorial discovery and testing of ionic liquids
WO2007001355A2 (en) * 2004-09-08 2007-01-04 Rensselaer Polytechnic Institute Enhanced stability of proteins immobilized on nanoparticles
WO2008145835A2 (en) * 2007-04-26 2008-12-04 I.F.P. Method for hydrogenating an aromatic charge using as a catalyst a suspension of metal nanoparticles containing a nitrogen ligand in an ionic liquid

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
FONSECA ET AL: "Synthesis and characterization of catalytic iridium nanoparticles in imidazolium ionic liquids", JOURNAL OF COLLOID AND INTERFACE SCIENCE, ACADEMIC PRESS, NEW YORK, NY, US, vol. 301, no. 1, 1 September 2006 (2006-09-01), pages 193 - 204, XP005569349, ISSN: 0021-9797 *
FONSECA G S ET AL: "The use of imidazolium ionic liquids for the formation and stabilization of Ir DEG and Rh DEG nanoparticles: efficient catalysts for the hydrogenation of arenes", CHEMISTRY - A EUROPEAN JOURNAL, WILEY - V C H VERLAG GMBH & CO. KGAA, WEINHEIM, DE, vol. 9, 1 January 2003 (2003-01-01), pages 3263 - 3269, XP002462143, ISSN: 0947-6539 *
REDEL E., E.A.: "First correlation of nanoparticle size-dependent formation with the ionic liquid anion molecular volume", INORGANIC CHEMISTRY, vol. 47, no. 1, 12 August 2007 (2007-08-12), pages 14 - 16, XP002552684 *

Also Published As

Publication number Publication date
WO2009024312A2 (en) 2009-02-26
DE102007038879A1 (en) 2009-02-19

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