WO2009022237A3 - Procédé de récupération d'un catalyseur d'oxydation par des résines d'échange d'ions - Google Patents

Procédé de récupération d'un catalyseur d'oxydation par des résines d'échange d'ions Download PDF

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Publication number
WO2009022237A3
WO2009022237A3 PCT/IB2008/003112 IB2008003112W WO2009022237A3 WO 2009022237 A3 WO2009022237 A3 WO 2009022237A3 IB 2008003112 W IB2008003112 W IB 2008003112W WO 2009022237 A3 WO2009022237 A3 WO 2009022237A3
Authority
WO
WIPO (PCT)
Prior art keywords
exchange resin
recovery
anion exchange
contacting
ion exchange
Prior art date
Application number
PCT/IB2008/003112
Other languages
English (en)
Other versions
WO2009022237A2 (fr
WO2009022237A9 (fr
Inventor
Marzio Monagheddu
Luciano Piras
Giovanni Cocco
Original Assignee
Dow Italia S.R.L.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Italia S.R.L. filed Critical Dow Italia S.R.L.
Priority to BRPI0811377-7A2A priority Critical patent/BRPI0811377A2/pt
Priority to JP2010509919A priority patent/JP5296781B2/ja
Priority to EP08827459A priority patent/EP2158039A2/fr
Priority to CN200880017856.2A priority patent/CN101952039B/zh
Publication of WO2009022237A2 publication Critical patent/WO2009022237A2/fr
Publication of WO2009022237A9 publication Critical patent/WO2009022237A9/fr
Publication of WO2009022237A3 publication Critical patent/WO2009022237A3/fr

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/74—Regeneration or reactivation of catalysts, in general utilising ion-exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J39/00—Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
    • B01J39/04—Processes using organic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
    • B01J41/04—Processes using organic exchangers
    • B01J41/05—Processes using organic exchangers in the strongly basic form
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/05—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds
    • B01J49/08—Regeneration or reactivation of ion-exchangers; Apparatus therefor of fixed beds containing cationic and anionic exchangers in separate beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/53—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for cationic exchangers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J49/00—Regeneration or reactivation of ion-exchangers; Apparatus therefor
    • B01J49/50—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents
    • B01J49/57—Regeneration or reactivation of ion-exchangers; Apparatus therefor characterised by the regeneration reagents for anionic exchangers
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
    • C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/08—Halides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treatment Of Water By Ion Exchange (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

La présente invention concerne un procédé de séparation et de récupération d'au moins un métal lourd et d'au moins un halogène à partir d'un effluent liquide dans un procédé chimique. Ledit procédé comprend les étapes de mise en contact de l'effluent liquide avec une résine d'échange d'anions de type base forte ; et de mise en contact d'un effluent de décharge provenant de la première étape avec une résine d'échange de cations de chélation. Le procédé de récupération comprend éventuellement une étape de régénération de la résine d'échange d'anions par mise en contact de ladite résine avec une solution de régénération de résine d'échange d'anions pour former les métaux lourds et les halogènes récupérés. Pour être optimal, le procédé de récupération de la présente invention comprend également une étape de régénération de la résine d'échange de cations de chélation pour former les métaux lourds et les halogènes récupérés.
PCT/IB2008/003112 2007-05-31 2008-05-16 Procédé de récupération d'un catalyseur d'oxydation par des résines d'échange d'ions WO2009022237A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
BRPI0811377-7A2A BRPI0811377A2 (pt) 2007-05-31 2008-05-16 "processo para a remoção e recuperação de pelo menos um metal pesado"
JP2010509919A JP5296781B2 (ja) 2007-05-31 2008-05-16 イオン交換樹脂を使用する酸化触媒の回収方法
EP08827459A EP2158039A2 (fr) 2007-05-31 2008-05-16 Procédé de récupération d'un catalyseur d'oxydation par des résines d'échange d'ions
CN200880017856.2A CN101952039B (zh) 2007-05-31 2008-05-16 使用离子交换树脂回收氧化催化剂的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US93240007P 2007-05-31 2007-05-31
US60/932,400 2007-05-31

Publications (3)

Publication Number Publication Date
WO2009022237A2 WO2009022237A2 (fr) 2009-02-19
WO2009022237A9 WO2009022237A9 (fr) 2009-08-13
WO2009022237A3 true WO2009022237A3 (fr) 2009-10-01

Family

ID=40351232

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IB2008/003112 WO2009022237A2 (fr) 2007-05-31 2008-05-16 Procédé de récupération d'un catalyseur d'oxydation par des résines d'échange d'ions

Country Status (7)

Country Link
EP (1) EP2158039A2 (fr)
JP (1) JP5296781B2 (fr)
KR (1) KR101467603B1 (fr)
CN (1) CN101952039B (fr)
BR (1) BRPI0811377A2 (fr)
RU (1) RU2009149338A (fr)
WO (1) WO2009022237A2 (fr)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101839774B1 (ko) * 2010-02-19 2018-03-19 미쯔비시 가스 케미칼 컴파니, 인코포레이티드 테레프탈산 제조 프로세스의 촉매 회수에 사용하는 피리딘환 함유 킬레이트 수지의 전처리 방법
WO2011102479A1 (fr) * 2010-02-19 2011-08-25 三菱瓦斯化学株式会社 Procédé pour traitement préalable de résine de chélate comportant un noyau pyridine convenant pour la récupération du catalyseur dans un procédé de production d'acide carboxylique aromatique
DE102013001972A1 (de) * 2013-02-05 2014-08-07 Thyssenkrupp Industrial Solutions Ag Verfahren zur selektiven Entfernung von Katalysatorbestandteilen aus Abströmen von Oxidationsreaktionen aromatischer Verbindungen, dafür geeignete Anlage und Verwendung
EP2774490B1 (fr) * 2013-03-06 2018-04-25 Cargill, Incorporated Purification de sirop par déionisation capacitive
EP3348596B1 (fr) 2016-03-11 2019-08-21 LG Chem, Ltd. Procédé de production économique d'une composition de résine comprenant du poly(carbonate d'alkylène) présentant une stabilité thermique et une aptitude au traitement améliorées
CN107555654A (zh) * 2017-09-25 2018-01-09 浙江绿维环境科技有限公司 一种用于金属工业冷却系统的中水回用工艺

Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0618185A1 (fr) * 1993-03-22 1994-10-05 BP Chemicals Limited Procédé de séparation de métaux corrosifs contaminant à partir de compositions liquides
US5840643A (en) * 1995-01-07 1998-11-24 Yukong Limited Recovery of oxidation catalysts used for the production of trimellitic acid
US5880313A (en) * 1997-09-09 1999-03-09 Mitsubishi Gas Chemical Company, Inc. Process for producing aromatic carboxylic acid
US5955394A (en) * 1996-08-16 1999-09-21 Mobile Process Technology, Co. Recovery process for oxidation catalyst in the manufacture of aromatic carboxylic acids

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JPS53104590A (en) * 1977-02-24 1978-09-11 Asahi Chem Ind Co Ltd Recovery method for liquid-phase oxidation catalyst and solvent
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JPH05221655A (ja) * 1992-02-15 1993-08-31 Mitsubishi Heavy Ind Ltd 塩酸水溶液中の塩化鉄の回収方法
JPH10176532A (ja) * 1996-12-16 1998-06-30 Sanshin Seisakusho:Kk エンジン冷却液の再生方法
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Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0618185A1 (fr) * 1993-03-22 1994-10-05 BP Chemicals Limited Procédé de séparation de métaux corrosifs contaminant à partir de compositions liquides
US5840643A (en) * 1995-01-07 1998-11-24 Yukong Limited Recovery of oxidation catalysts used for the production of trimellitic acid
US5955394A (en) * 1996-08-16 1999-09-21 Mobile Process Technology, Co. Recovery process for oxidation catalyst in the manufacture of aromatic carboxylic acids
US5880313A (en) * 1997-09-09 1999-03-09 Mitsubishi Gas Chemical Company, Inc. Process for producing aromatic carboxylic acid

Non-Patent Citations (1)

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THE DOEW CHEMICAL COMPANY: "DOWEX Resins for Trace Contaminant Removal: A Portfolio of Options for Potable Water Applications", INTERNET ARTICLE, 2006, pages 1 - 6, XP002530805, Retrieved from the Internet <URL:http://web.archive.org/web/20060617234612/http://www.dow.com/liquidseps/prod/sp_tracecontam.htm> [retrieved on 20090605] *

Also Published As

Publication number Publication date
JP2010527785A (ja) 2010-08-19
CN101952039B (zh) 2015-05-20
RU2009149338A (ru) 2011-07-10
KR20100017447A (ko) 2010-02-16
EP2158039A2 (fr) 2010-03-03
WO2009022237A2 (fr) 2009-02-19
WO2009022237A9 (fr) 2009-08-13
KR101467603B1 (ko) 2014-12-01
JP5296781B2 (ja) 2013-09-25
CN101952039A (zh) 2011-01-19
BRPI0811377A2 (pt) 2014-12-09

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